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<title lang=en>Redox state of iron during high-pressure serpentinite dehydration</title>
<creator>Debret, Baptiste</creator>
<creator>Bolfan-Casanova, Nathalie</creator>
<creator>PADRON NAVARTA, Jose alberto</creator>
<creator>Martin-Hernandez, Fatima</creator>
<creator>Andreani, Muriel</creator>
<creator>Garrido, C. J.</creator>
<creator>Lopez Sanchez-Vizcaino, Vicente</creator>
<creator>Gomez-Pugnaire, M. T.</creator>
<creator>Munoz, Manuel</creator>
<creator>Trcera, Nicolas</creator>
<contributor>Laboratoire Magmas et Volcans (LMV) ; Université Blaise Pascal - Clermont-Ferrand 2 (UBP) - Institut national des sciences de l'Univers (INSU - CNRS) - Université Jean Monnet [Saint-Étienne] (UJM) - Centre National de la Recherche Scientifique (CNRS)</contributor>
<contributor>Géosciences Montpellier ; Université des Antilles et de la Guyane (UAG) - Institut national des sciences de l'Univers (INSU - CNRS) - Université de Montpellier (UM) - Centre National de la Recherche Scientifique (CNRS)</contributor>
<contributor>Manteau et Interfaces ; Géosciences Montpellier ; Université des Antilles et de la Guyane (UAG) - Institut national des sciences de l'Univers (INSU - CNRS) - Université de Montpellier (UM) - Centre National de la Recherche Scientifique (CNRS) - Université des Antilles et de la Guyane (UAG) - Institut national des sciences de l'Univers (INSU - CNRS) - Université de Montpellier (UM) - Centre National de la Recherche Scientifique (CNRS)</contributor>
<contributor>Instituto de Geociencias IGEO, Madrid ; Université du Québec</contributor>
<contributor>Laboratoire de Géologie de Lyon - Terre, Planètes, Environnement [Lyon] (LGL-TPE) ; École normale supérieure - Lyon (ENS Lyon) - Université Claude Bernard Lyon 1 (UCBL) - Institut national des sciences de l'Univers (INSU - CNRS) - Centre National de la Recherche Scientifique (CNRS)</contributor>
<contributor>Instituto Andaluz de Ciencias de la Tierra (IACT) ; Universidad de Granada (UGR) - Consejo Superior de Investigaciones Científicas [Spain] (CSIC)</contributor>
<contributor>Departamento de Geología [Jaén] ; Universidad de Jaén (UJA)</contributor>
<contributor>Departamento De Mineralogía Y Petrología, Facultad De Ciencias, Universidad De Granada ; Université du Québec</contributor>
<contributor>Institut des Sciences de la Terre (ISTerre) ; Université Joseph Fourier - Grenoble 1 (UJF) - Institut Français des Sciences et Technologies des Transports, de l'Aménagement et des Réseaux (IFSTTAR) - Institut national des sciences de l'Univers (INSU - CNRS) - Institut de recherche pour le développement [IRD] : UR219 - PRES Université de Grenoble - Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry]) - Centre National de la Recherche Scientifique (CNRS)</contributor>
<description>International audience</description>
<source>ISSN: 0010-7999</source>
<source>EISSN: 1432-0967</source>
<source>Contributions to Mineralogy and Petrology</source>
<publisher>Springer Verlag (Germany)</publisher>
<publisher>Springer Verlag</publisher>
<identifier>hal-01172310</identifier>
<identifier>https://hal.archives-ouvertes.fr/hal-01172310</identifier>
<source>https://hal.archives-ouvertes.fr/hal-01172310</source>
<source>Contributions to Mineralogy and Petrology, Springer Verlag, 2015, 169 (4), pp.36. 〈10.1007/s00410-015-1130-y〉</source>
<identifier>DOI : 10.1007/s00410-015-1130-y</identifier>
<relation>info:eu-repo/semantics/altIdentifier/doi/10.1007/s00410-015-1130-y</relation>
<language>en</language>
<subject lang=en>Antigorite breakdown</subject>
<subject lang=en>Redox</subject>
<subject lang=en>Iron</subject>
<subject lang=en>XANES</subject>
<subject lang=en>Subduction</subject>
<subject>[SDU.STU.GC] Sciences of the Universe [physics]/Earth Sciences/Geochemistry</subject>
<type>info:eu-repo/semantics/article</type>
<type>Journal articles</type>
<description lang=en>The Cerro del Almirez massif (Spain) represents a unique fragment of serpentinized oceanic lithosphere that has been first equilibrated in the antigorite stability field (Atg-serpentinites) and then dehydrated into chlorite–olivine–orthopyroxene (Chl-harzburgites) at eclogite facies conditions during subduction. The massif preserves a dehydration front between Atg-serpentinites and Chl-harzburgites. It constitutes a suitable place to study redox changes in serpentinites and the nature of the released fluids during their dehydration. Relative to abyssal serpentinites, Atg-serpentinites display a low Fe3+/FeTotal(BR) (=0.55) and magnetite modal content (=2.8–4.3 wt%). Micro-X-ray absorption near-edge structure (μ-XANES) spectroscopy measurements of serpentines at the Fe–K edge show that antigorite has a lower Fe3+/FeTotal ratio (=0.48) than oceanic lizardite/chrysotile assemblages. The onset of Atg-serpentinites dehydration is marked by the crystallization of a Fe3+-rich antigorite (Fe3+/FeTotal = 0.6–0.75) in equilibrium with secondary olivine and by a decrease in magnetite amount (=1.6–2.2 wt%). This suggests a preferential partitioning of Fe3+ into serpentine rather than into olivine. The Atg-breakdown is marked by a decrease in Fe3+/FeTotal(BR) (=0.34–0.41), the crystallization of Fe2+-rich phases and the quasi-disappearance of magnetite (=0.6–1.4 wt.%). The observation of Fe3+-rich hematite and ilmenite intergrowths suggests that the O2 released by the crystallization of Fe2+-rich phases could promote hematite crystallization and a subsequent increase in fo2 inside the portion of the subducted mantle. Serpentinite dehydration could thus produce highly oxidized fluids in subduction zones and contribute to the oxidization of the sub-arc mantle wedge.</description>
<date>2015-04</date>
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