Éditeur(s) : HAL CCSD
Résumé : East African Rift (EAR) is the divergent plate boundary. EAR exposes different stages of extension, from early stage rifting in Tanzania to oceanic accretion in Afar (Ethiopia). Manyara basin is the southernmost rift system of the east branch of EAR with recent volcanism (< 1.5 Ma) and a seismic swarm in the lower crust (20 – 40 km). Due to its location and tectonic setting, the Manyara basin offers the opportunity to study the earliest stage of rift initiation. Manyara volcanism is composed of several types of hyper-alkaline lavas as Mg-nephelinites (Mg# > 55) (Labait, Kwaraha), calciocarbonatite (Kwaraha) and evolved nephelinites (Mg# < 35) (Hanang).Mg-nephelinites (Labait and Kwaraha) are primary lavas mainly composed of olivine and clinopyroxene (cpx). Geochemical modelling from trace elements suggests that these primary magmas result from a degree of partial melting < 1 % from a CO2-garnet-phlogopite-bearing peridotite. These magmas have an asthenospheric source at depth > 120 km (lava carries xenoliths with equilibrium conditions > 4 GPa). The minerals were crystallized from a magma with a low H2O content (0.1 and 0.5 wt% H2O). The calciocarbonatite and evolved nephelinites are derived from Mg-nephelinites by fractional crystallization and immiscibility processes. Hanang nephelinites are silica- and alkaline-rich lavas (44.2 – 46.7 wt % SiO2, 9.5 –12.1 wt % Na2O+K2O, respectively) composed by cpx, Ti-garnet, nepheline, apatite and titanite. Complex zonation of cpx (e.g. abrupt change of Mg#, Nb/Ta, and H2O) and trace element patterns of nephelinites record magmatic differentiation involving open system with carbonate-silicate immiscibility and primary melt replenishment. The low H2O content of cpx (3 – 25 ppm wt. H2O) indicates that at least 0.3 wt % H2O was present at depth during carbonate-rich nephelinite crystallization at 340 – 640 MPa and 1050 – 1100 °C. The study of hosted-nepheline melt inclusions from Hanang allows constraining the late magmatic evolution of nephelinites during storage and magma ascent. Melt inclusions are composed by a silicate trachytic glass, a carbonate phase and a shrinkage bubble. Trachytic glass contains high content in CO2 (0.43 wt %, SIMS analyses), sulfur (0.21 – 0.92 wt % S), chlorine (0.28 –0.84 wt % Cl) and H2O low content (< 0.1 wt %, Raman analyses). Immiscibility process leading to the formation of carbonate occurs in a closed system during rapid magma ascent between 200 – 500 MPa. The carbonate phase is a Ca-Na-K-S-rich and anhydrous carbonate (33 wt % CaO, 20 wt % Na2O, 3 wt % K2O, and 3 wt % S). The pre-immiscible liquid has a phonolitic composition with 6 ± 1.5 wt % CO2 at 700 MPa. A preliminary study of melt inclusions by XANES spectroscopy and whole rocks by Mössbauer spectroscopy was used to determine these Manyara lavas were formed at oxidizing conditions (~ ΔFMQ +1.5).The early stage rifting volcanism (Manyara Basin) is characterized by CO2-rich and H2O-poor magmas from at least 120 km below the rift escarpment. The presence of CO2-rich magmas and the small amount of volcanic rocks erupted at the surface may indicate that the storage and percolation of these magmas at depth is a potential trigger for deep seismic swarms.
Le rift Est africain (REA) est une frontière de plaque en extension. Ce rift présente plusieurs stades d’extension, de l’initiation du rift en Tanzanie jusqu’à l’accrétion océanique en Afar. Le bassin de Manyara se situe le plus au sud de branche Est du REA. Il est caractérisé par la présence de volcanisme récent (< 1,5 Ma) et d’un essaim sismique dans la croûte inférieure (20 – 40 km). De par sa localisation et son contexte tectonique, le bassin de Manyara offre l’opportunité d’étudier le stade le plus précoce de l’initiation du rift. Le bassin de Manyara est composé de plusieurs types de laves hyperalcalines, les néphélinites magnésiennes (Mg# > 55) (Labait, Kwaraha), de calciocarbonatite (Kwaraha) et des néphélinites différenciées (Mg# < 35) (Hanang).Les néphélinites magnésiennes (Labait et Kwaraha) sont des laves primaires composées d’olivines et de clinopyroxènes (cpx). La modélisation géochimique des éléments en trace suggère que ces magmas primaires résultent d'un degré de fusion partielle ≤ 1 % à partir d'une péridotite à grenat et phlogopite. Ces magmas proviennent d’une profondeur > 120 km (présence de xénolites avec des conditions d’équilibre > 4 GPa). Les minéraux ont cristallisés à partir d’un magma pauvre en eau (0,1 et 0,5 pds % H2O). La calciocarbonatite et les néphélinites différenciés sont issues des néphélinites magnésiennes par cristallisation fractionnée et processus d’immiscibilité. Les néphélinites du Hanang sont riches en éléments alcalins (9,5 – 12,1 pds % Na2O+K2O) et en silice (44,2 – 46,7 pds% SiO2) et sont composés de cpx, grenat, néphéline, titanite et apatite. La zonation complexe dans les cpx (par exemple, changement brusque de Mg#, Nb/Ta, et H2O) implique une différenciation magmatique en système ouvert avec immiscibilité de liquide carbonaté et silicaté ainsi qu’un remplissage de la chambre magmatique avec des liquides primaires. La faible teneur en eau des cpx (3 – 25 ppm H2O) indique la présence d’un magma pauvre en eau (0,3 pds % H2O) lors de la cristallisation des cpx à des conditions crustales (340 – 640 MPa et 1050 – 1100 °C). L’étude des inclusions vitreuses dans les néphélines de Hanang permet de contraindre l'évolution magmatique tardive des néphélinites et le comportement des éléments volatils (CO2, H2O, S, F, Cl) lors du stockage et de la remontée du magma. Les inclusions vitreuses sont composées d’un verre trachytique, d’une phase carbonatée et d’une bulle de rétraction. Le verre trachytique contient du CO2 (0,43 pds % CO2, analyses SIMS), du soufre (0,21 à 0,92 pds% S), du chlore (0,28 – 0,84 pds % Cl) et très peu d’H2O (< 0,1 pds % H2O, analyses Raman). Le processus d’immiscibilité conduisant à la formation du carbonate se produit dans un système fermé pendant l'ascension rapide du magma, entre 200 – 500 MPa. La phase carbonatée est un carbonate anhydre et riche en Ca-Na-K-S (33 pds % CaO, 20 pds % Na2O, 3 pds % K2O, et 3 pds % S). Le liquide pré-immiscible a une composition phonolitique avec 6 ± 1,5 pds % CO2 à une pression de 700 MPa. Une étude préliminaire des inclusions par spectroscopie XANES et des roches par spectroscopie Mössbauer a permis de déterminer que les laves de Manyara se sont formées à conditions oxydantes (~ ∆FMQ +1,5).À l’initiation du rift, le volcanisme dans le bassin de Manyara est caractérisé par des magmas riches en CO2 et pauvres en H2O issus d’au moins 120 km de profondeur sous l'escarpement du rift. La présence de ces magmas riches en CO2 et la faible quantité de roches volcaniques émises à la surface peuvent indiquer que le piégeage et la percolation de ces magmas en profondeur est un déclencheur potentiel des essaims sismiques profonds.
https://tel.archives-ouvertes.fr/tel-01563231

NNT : 2016MONTT114
tel-01563231
https://tel.archives-ouvertes.fr/tel-01563231
https://tel.archives-ouvertes.fr/tel-01563231v2/document
https://tel.archives-ouvertes.fr/tel-01563231/file/2016_BAUDOUIN_archivage.pdf

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Island arc picrites and boninites are magnesian magmatic rocks believed to be generated by high degrees of melting of depleted mantle sources fluxed by subduction-derived, volatile-rich components. These magmas can be probes of both the mantle wedge protoliths and subduction components, but are rare among other, usually more evolved, types of arc lavas. Furthermore, many arc picrites and boninites show evidence for late-stage differentiation prior to or during eruption, masking their primary, mantle-derived geochemical signatures. We report textural and chemical data on spinel-hosted melt inclusions of mantle origin in amphibole-bearing websterite veins cross-cutting spinel harzburgite xenoliths from the active andesitic Avacha volcano (south Kamchatka, Russia). The data are used to constrain the composition and origin of melts that formed the websterite veins in the sub-arc lithospheric mantle. The melt inclusions typically contain euhedral orthopyroxene and clinopyroxene and occasionally minor amphibole in silicate glass. The melt inclusions were homogenized using heating stages and gas-mixing furnaces. The homogenized glasses range from subalkaline primitive silica-rich picrite and high-Ca boninite (>15 wt % MgO, 48–54 wt % SiO2) to rhyolite. High-Ca boninite glasses have moderate volatile and low heavy rare earth element contents and elevated Cs, Rb, Ba, U, Sr, and Li abundances, with extremely high U/Th. In turn, the glasses display no negative spikes in the high field strength elements Nb, Ta, Zr, Hf, and Ti. We show that the silica-rich picrite and high-Ca boninite liquids in this study formed by high degrees of melting (>25%), at volatile under-saturation, of hybrid melt-depleted but silica-rich mantle sources at ≥1·5 GPa. The hybrid sources formed in two stages: first, by extraction of ∼15% melt from the convecting mantle to form a refractory protolith, which was subsequently enriched in silica via interaction with subduction-derived components prior to or during remelting in the mantle wedge. The subduction-derived components were enriched in fluid-mobile elements and probably oxidized. Overall, our results suggest that silica-rich picrites and high-Ca boninites can be primary melts in mature subduction zones and differentiate within the mantle wedge and the deep arc crust to form more evolved andesite magmas.
ISSN: 0022-3530

hal-01553676
https://hal.archives-ouvertes.fr/hal-01553676
DOI : 10.1093/petrology/egw066

Éditeur(s) : HAL CCSD wiley
Résumé : International audience
The slow advance of a crack in sodo-silicate glasses was studied at nanometer scale by in-situ atomic force microscopy (AFM) in a well-controlled atmosphere (N2 and H2O). An enhanced diffusion of sodium ions in the stress-gradient field at the sub-micrometric vicinity of the crack tip was revealed through several effects: growth of nodules in height images, changes in the AFM tip–sample energy dissipation as detected in phase images. Ex-situ chemical micro-analyses completed the AFM measurements. The nodules patterns revealed a dewetting phenomenon evidenced by “breath figures”, i.e. analog to the fogging that occurs when a vapour condenses onto a 'cold' surface [D. Beysens et al., Phys. Rev. Let. 57, 1433 (1986)]. These experimental results were explained by a two-step process: i) a fast migration of sodium ions towards the fracture surfaces as proposed by Langford et al. [J. Mat. Res. 6, 1358 (1991)], ii) a slow backwards diffusion of the cations as evidenced in these AFM experiments (typical time: few minutes). Measurements of the diffusion coefficient of that relaxing process were done at room temperature. Our results strengthen the theoretical concept of a near-surface structural relaxation due to the stress-gradient at the vicinity of the crack tip. Raman and SIMS studies revealed that nodules – for samples studied after exposition to common air - are preferentially covered by an organic overlayer of a carboxylate salt with a long aliphatic chain. The catalytic role of sodium ions in that chemical process is suspected.
Fractography of glasses an ceramics V
Rochester, United States

hal-00408605
https://hal.archives-ouvertes.fr/hal-00408605

Éditeur(s) : HAL CCSD Elsevier
Résumé : Water molecules play a fundamental role in the physics of slow crack propagation in glasses. It is commonly understood that, during stress-corrosion, water molecules that move in the crack cavity effectively reduce the bond strength at the strained crack tip and, thus, support crack propagation. Yet the details of the environmental condition at the crack tip in moist air are not well determined. In a previous work, we reported direct evidence of the presence of a 100 nm long liquid condensate at the crack tip in fused silica glass during very slow crack propagation (10(-9)-10(-10) m/s). These observations are based on in situ AFM phase imaging techniques applied on DCDC glass specimens in controlled atmosphere. Here, we discuss the physical origin of the AFM phase contrast between the liquid condensate and the glass surface in relation to tip-sample adhesion induced by capillary bridges. We then report new experimental data on the water condensation length increase with relative humidity in the atmosphere. The measured condensation lengths were much larger than what predicted using the Kelvin equation and expected geometry of the crack tip.
ISSN: 0022-3093

hal-00412153
https://hal.archives-ouvertes.fr/hal-00412153
DOI : 10.1016/j.jnoncrysol.2007.06.090

Éditeur(s) : HAL CCSD American Physical Society
Résumé : We study the equilibrium properties of a liquid phase condensed at the nanoscale between the surfaces of a sharp crack in fused silica in a moist controlled atmosphere. The extension of the condensed phase along the fracture is measured by in situ atomic force microscopy phase imaging and it is shown to be determined by a critical distance between the opposite crack surfaces, which is an increasing function of humidity. The present technique is very promising for measuring the properties of confined liquids at the nanoscale as well as for modeling the physics and chemistry of slow crack propagation in glasses.
ISSN: 0031-9007

hal-00411946
https://hal.archives-ouvertes.fr/hal-00411946
DOI : 10.1103/PhysRevLett.100.165505

Éditeur(s) : HAL CCSD Elsevier
Résumé : The slow advance of a crack in soda-silicate glasses was studied at nanometer scale by in-situ and real-time atomic force microscopy (AFM) in a well-controlled atmosphere. An enhanced diffusion of sodium ions in the stress-gradient field at the sub-micrometric vicinity of the crack tip was revealed through several effects: growth of nodules in AFM height images, changes in the AFM tip–sample energy dissipation. The nodules patterns revealed a dewetting phenomenon evidenced by ‘breath figures'. Complementary chemical micro-analyses were done. These experimental results were explained by a two-step process: (i) a fast migration (typical time: few milliseconds) of sodium ions towards the fracture surfaces as proposed by Langford et al. [J. Mat. Res. 6 (1991) 1358], (ii) a slow backwards diffusion of the cations as evidenced in these AFM experiments (typical time: few minutes). Measurements of the diffusion coefficient of that relaxing process were done at room temperature. Our results strengthen the theoretical concept of a near-surface structural relaxation due to the stress-gradient at the vicinity of the crack tip. The inhomogeneous migration of sodium ions might be a direct experimental evidence of the presence of sodium-rich channels in the silicate structure [A. Meyer et al., Phys. Rev. Let. 93 (2004) 027801].
ISSN: 0022-3093

hal-00407634
https://hal.archives-ouvertes.fr/hal-00407634
DOI : 10.1016/j.jnoncrysol.2006.09.034

Éditeur(s) : HAL CCSD Springer
Résumé : International audience
NWA2268 is a polymict eucrite discovered in the Sahara, at southwest Algeria, close to the region of Tindouf. This meteorite weighs 65 g and presents a thin black fusion crust. The rock is fine- to medium-grained breccia and contains mineral fragments of plagioclases, pyroxenes, spinel, olivine and silica. The rock contains some basaltic fragments with sub-ophitic or cumulative textures, constituted by plagioclases and exsolved pigeonite. Pyroxferroite grains are present and locally destabilised in an association of hedenbergite, fayalite and silica. It also presents unequilibrated eucritic clast with heterogeneous pyroxenes and plagioclases compositions. Pyroxenes in the all of the other clasts have equilibrated composition, with exolved pigeonites with augite lamellaes. This polymict eucrite contains also partially devitrified glass that represents impact melts linked to impact event. None recrystallization of this glass confirms a lack of post-brecciation metamorphism. Diogenitic fragments are less abundant than 10 %. The oxygen isotopic composition of NWA2268 is Δ17O (−0.43). This meteorite is interpreted as belonging to the HED group attributed to the 4-Vesta asteroid.
ISSN: 1866-7411

hal-00903591
https://hal.archives-ouvertes.fr/hal-00903591
DOI : 10.1007/s12517-012-0624-4

Éditeur(s) : HAL CCSD Geological Society
Résumé : Gem opals from Wegel Tena, Wollo Province, Ethiopia, occur in Oligocene rhyolitic ignimbrites. They display a unique geochemistry, with some samples yielding the highest Ba concentrations ever recorded. They are generally much richer in chemical impurities than opals from other localities. For example, the sum Al+Fe or the sum Na+Mg+Ca+K+Ba are often higher. These geochemical features make them easy to distinguish from other opals worldwide. We observed strong geochemical variations and some good positive correlations in our samples, such as Al+Fe vs. Na+Mg+Ca+K+Ba, Al vs Ca, or Ba vs Ca. This shows that the crystallography of opal has controlled, at least in part, the incorporation of chemical impurities, although opal is not well-crystallized. In addition, the multimodal distributions of several chemical impurities (e.g. U vs Sr, Al vs Ca, Ba vs Ca, etc.) suggest at least two origins of silica: weathering of feldspars and weathering of volcanic glass. In addition, opals from Wegel Tena contain numerous well-preserved microscopic plant fossils. Moreover, their host rock exhibits features typical of pedogenesis (abundant clays, desiccation cracks, and grain size sorting). We propose that the opals at Wegel Tena formed during the Oligocene period when volcanic emissions stopped for a time long enough to allow weathering of ingimbrites and therefore liberation of silica. This accompanied the formation of soil and development of plant life, and some plants were trapped in opal.
ISSN: 1467-7873

hal-00767555
https://hal.archives-ouvertes.fr/hal-00767555
DOI : 10.1144/1467-7873/10-MINDEP-058

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Anisotropy of low-field magnetic susceptibility (AMS) of basaltic lava flows can give some clues about post-emplacement tilting occurring in volcanic sequences. Such a study has been carried out on a sequence of 19 successive lava flows from Kerguelen Archipelago. Surprisingly, two different patterns were observed. The first one - herein called normal fabric - is consistent with the lava-flow direction inferred from geological observations, whereas the second one observed for about 70 per cent of the analysed samples - herein called abnormal fabric - appears to be unrelated to the shear history of the lava flows during their emplacements. These abnormal fabrics are not strictly inverse fabric but seem to have a more complex origin. The unusual nature of these abnormal fabrics has been confirmed by lattice preferred orientation of plagioclases obtained from high-resolution electron backscattered diffraction measurements. The aim of this study is to propose a physical interpretation of these fabrics. A first step in our understanding was to clearly identify the nature and the magnetic properties of the Fe-Ti oxides assemblage. Thus, we present a comprehensive rock magnetic analysis relying on low- and high-temperature thermomagnetic curves (K-T), crossover diagrams, first-order reversal curves, ore-microscopy, Mössbauer measurements and electron backscattered images. We found that in the present case the abnormal fabrics are probably linked to a mixture of prevailing single domain (SD) strongly interacting grains population and a subsidiary multidomain grains population. SD grains are identified as small magnetite crystallized within the interstitial glass in globular aggregates along the silicate framework. Then a question arises: to what extent such SD interacting grains in globular aggregates can affect the magnetic susceptibility and its anisotropy? To answer this question, we developed a physical model in which the total energy density of an SD grain with an uniaxial anisotropy is minimized. In this model, the distribution function of the direction of the magnetic interaction field is comprised between two boundary states. It is either isotropic, which formally corresponds to the thermal demagnetized state, or it is ordered, which formally corresponds to the Alternative Field demagnetized state. We show that in both cases the degree of anisotropy decreases as the interaction field increases. Thus, we conclude that the abnormal fabric encountered in this study can be simply explained by strong magnetostatic interactions that would explain the large scattering of AMS often observed in basaltic lava flows.
ISSN: 0956-540X

hal-00716449
https://hal.archives-ouvertes.fr/hal-00716449
https://hal.archives-ouvertes.fr/hal-00716449/document
https://hal.archives-ouvertes.fr/hal-00716449/file/gji-S-12-HAL.pdf
DOI : 10.1111/J.1365-246X.2012.05421.X

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We developed a new granular material (MatIV) to study experimentally landscape evolution in active mountain belt piedmonts. Its composition and related physical properties have been determined using empirical criteria derived from the scaling of deformation, erosion-transport and sedimentation natural processes. MatIV is a water-saturated composite material made up with 4 granular components (silica powder, glass microbeads, plastic powder and graphite) whose physical, mechanical and erosion-related properties were measured with different laboratory tests. Mechanical measurements were made on a modified Hubbert-type direct shear apparatus. Erosion-related properties were determined using an experimental set-up that allows quantifying the erosion/sedimentation budget from tilted relaxation topographies. For MatIV, we also investigated the evolution of mean erosion rates and stream power erosion law exponents in 1D as a function of slope.;Our results indicate that MatIV satisfies most of the defined criteria. It deforms brittlely according to the linear Mohr-Coulomb failure criterion and localizes deformation along discrete faults. Its erosion pattern is characterized by realistic hillslope and channelized processes (slope diffusion, mass wasting, channel incision). During transport, eroded particles are sorted depending on their density and shape, which results in stratified alluvial deposits displaying lateral fades variations. To evaluate the degree of similitude between model and nature, we used a new experimental device that combines accretionary wedge deformation mechanisms and surface runoff erosion processes. Results indicate that MatIV succeeded in producing detailed morphological and sedi-mentological features (drainage basin, channel network, terrace, syntectonic alluvial fan). Geometric, kinematic and dynamic similarity criteria have been investigated to compare precisely model to nature. Although scaling is incomplete, it yields particularly informative orders of magnitude. With all these characteristics, MatIV appears as a very promising material to investigate experimentally a wide range of scientific questions dealing with relief dynamics and interactions between tectonics, erosion and sedimentation processes.
ISSN: 0040-1951

hal-00669904
https://hal.archives-ouvertes.fr/hal-00669904
DOI : 10.1016/j.tecto.2011.09.029

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Spinel lherzolite xenoliths from Mont Briancon, French Massif Central, retain evidence for multiple episodes of melt depletion and melt/fluid infiltration (metasomatism). Evidence for primary melt depletion is still preserved in the co-variation of bulk-rock major elements (MgO 38.7-46.1 wt.%; CaO 0.9-3.6 wt.%), and many samples yield unradiogenic bulk-rock Os isotope ratios (Os-187/Os-188 = 0.11541-0.12626). However, many individual xenoliths contain interstitial glasses and melt inclusions that are not in equilibrium with the major primary minerals. Incompatible trace element mass balance calculations demonstrate that metasomatic components comprise a significant proportion of the bulk-rock budget for these elements in some rocks, ranging to as much as 25%, of Nd and 40% of Sr Critically, for Re-Os geochronology, melt/fluid infiltration is accompanied by the mobilisation of Sulfide. Consequently, bulk-rock isotope measurements, whether using lithophile (e.g. Rb-Sr, Sm-Nd) or siderophile (Re-Os) based isotope systems, may only yield a perturbed and/or homogenised average of these multiple events.;Osmium mass balance calculations demonstrate that bulk-rock Os in peridotite is dominated by contributions from two populations of sulfide grain: (i) interstitial, metasomatic Sulfide with low [Os] and radiogenic Os-187/Os-188, and (ii) primary sulfides with high [Os] and unradiogenic Os-187/Os-188, which have been preserved within host silicate grains and shielded from interaction with transient melts and fluid. The latter can account for >97% of bulk-rock Os and preserve geochronological information of the melt from which they originally precipitated as an immiscible liquid. The Re-depletion model ages of individual primary sulfide grains preserve evidence for melt depletion beneath the Massif Central from at least 1.8 Gyr ago despite the more recent metasomatic event(s). (C) 2009 Elsevier Ltd. All rights reserved.
ISSN: 0016-7037

hal-00454537
https://hal.archives-ouvertes.fr/hal-00454537
DOI : 10.1016/j.gca.2009.09.031

Éditeur(s) : HAL CCSD Royal Society of Chemistry
Résumé : International audience
LA-ICP-MS analysis of the chemical composition of biogenic carbonate has many applications in the environmental sciences but the characteristics of the material produced by the ablation process are largely unknown. To fill this gap, we have undertaken a study of the chemical and physical nature of particles produced by laser ablation of biogenic carbonates. SEM imaging suggests that laser ablation produces two distinct particle populations, one consisting of microsize particles and the other of nanosize particles. A 213 nm laser gives rise to a higher proportion of microsize particles than a 193 nm laser, probably because the 213 nm laser couples less completely with carbonate material. The microsize particles appear to form by photomechanical fracturing along lines of cleavage or weakness, rather than by hydrodynamic sputtering (as is generally observed for silicates). Chemical analysis of the carbonate particles suggests that little chemical fractionation of biogenic carbonates occurs during the ablation process or during transport to the plasma. This is supported by the constancy of the fractionation factor ([X/Ca](measured)/[X/Ca] true) during the course of an ablation of a carbonate standard. In contrast, changes in the fractionation factor during the first few seconds of ablation of the NIST 612 are observed for some elements. This difference in fractionation is likely to result from the different formation mechanisms of the microsize particles.
ISSN: 0267-9477

hal-00411933
https://hal.archives-ouvertes.fr/hal-00411933
DOI : 10.1039/b706727e