![]() | Evidence for intense REE scavenging at cold seeps from the Niger Delta margin Auteur(s) : Bayon, Germain Birot, Dominique Ruffine, Livio Caprais, Jean-claude Ponzevera, Emmanuel Bollinger, C. Donval, Jean-pierre Charlou, Jean-luc Éditeur(s) : Elsevier Science Bv Résumé : For many trace elements, continental margins are the location of intense exchange processes between sediment and seawater, which control their distribution in the water column, but have yet to be fully understood. In this study, we have investigated the impact of fluid seepage at cold seeps on the marine cycle of neodymium. We determined dissolved and total dissolvable (TD) concentrations for REE and well-established tracers of fluid seepage (CH4, TDFe, TDMn), and Nd isotopic compositions in seawater samples collected above cold seeps and a reference site (i.e. away from any fluid venting area) from the Niger Delta margin. We also analyzed cold seep authigenic phases and various core-top sediment fractions (pore water, detrital component, easily leachable phases, uncleaned foraminifera) recovered near the hydrocast stations. Methane, TDFe and TDMn concentrations clearly indicate active fluid venting at the studied seeps, with plumes rising up to about 100 m above the seafloor. Depth profiles show pronounced REE enrichments in the non-filtered samples (TD concentrations) within plumes, whereas filtered samples (dissolved concentrations) exhibit slight REE depletion in plumes relative to the overlying water column and display typical seawater REE patterns. These results suggest that the net flux of REE emitted into seawater at cold seeps is controlled by the presence of particulate phases, most probably Fe-Mn oxyhydroxides associated to resuspended sediments. At the reference site, however, our data reveal significant enrichment for dissolved REE in bottom waters, that clearly relates to diffusive benthic fluxes from surface sediments. Neodymium isotopic ratios measured in the water column range from epsilon(Nd) similar to-15.7 to -10.4. Evidence that the epsilon(Nd) values for Antarctic Intermediate waters (AAIW) differed from those reported for the same water mass at open ocean settings shows that sediment/water interactions take place in the Gulf of Guinea. At each site, however, the bottom water epsilon(Nd) signature generally differs from that for cold seep minerals, easily leachable sediment phases, and detrital fractions from local sediments, ruling out the possibility that seepage of methane-rich fluids and sediment dissolution act as a substantial source of dissolved Nd to seawater in the Gulf of Guinea. Taken together, our data hence suggest that co-precipitation of Fe-Mn oxyhydroxide phases in sub-surface sediments leads to quantitative scavenging of dissolved REE at cold seeps, preventing their emission into bottom waters. Most probably, it is likely that diffusion from suboxic surface sediments dominates the exchange processes affecting the marine Nd cycle at the Niger Delta margin. (C) 2011 Elsevier B.V. All rights reserved. Earth And Planetary Science Letters (0012-821X) (Elsevier Science Bv), 2011-12 , Vol. 312 , N. 3-4 , P. 443-452 Droits : 2011 Elsevier B.V. All rights reserved. http://archimer.ifremer.fr/doc/00066/17754/15571.pdf DOI:10.1016/j.epsl.2011.10.008 http://archimer.ifremer.fr/doc/00066/17754/ | Partager Voir aussi rare earth elements neodymium isotopes seawater cold seeps Fe-Mn oxyhydroxides benthic fluxes Télécharger |
![]() | Post-glacial persistence of turbiditic activity within the Rhone deep-sea turbidite system (Gulf of Lions, Western Mediterranean): Linking the outer shelf and the basin sedimentary records Auteur(s) : Dennielou, Bernard Jallet, Laurent Sultan, Nabil Jouet, Gwenael Giresse, Pierre Voisset, Michel Berne, Serge Éditeur(s) : Elsevier Résumé : Emplacement of post-glacial turbidites is commonly controlled by rapid changes in sea level or by seismicity. On the continental rise of the Gulf of Lions (Western Mediterranean), an aseismic area, we identified turbiditic beds deposited during the rising stage and highstand of sea level. Swath bathymetry, sediment cores, in situ Cone Penetrating Tests (CPTU), heavy mineral associations and radiocarbon dating determined the source, composition, distribution and age of the turbiditic beds. Turbidites are composed of homogeneous to positively graded silts to medium sand with quartz (up to 90%), shell debris and shelfal benthic faunas. Their distribution on the sea floor is very patchy and controlled by abundant inherited erosional bedforms. Their source is found in relict regressive sands at the outershelf. Their deposition occurred just after the onset of the post-glacial sea level rise and the concomitant sediment starvation of the Rhone deep sea turbiditic system until recently. Whilst canyons are fed with sand by strong seasonal hydro-sedimentary dynamics on the outershelf, the emplacement of post-glacial turbidites is not controlled by sea level changes but probably by the periodic flushing of the canyons. Our study revealed that this low energy aseismic margin undergoes significant transport of sand, down to the base of slope, during the sea-level rise and the Holocene highstand. Marine Geology (0025-3227) (Elsevier), 2009-02 , Vol. 257 , N. 1-4 , P. 65-86 Droits : 2009 Published by Elsevier Ltd. http://archimer.ifremer.fr/doc/2009/publication-6316.pdf DOI:10.1016/j.margeo.2008.10.013 http://archimer.ifremer.fr/doc/00000/6316/ | Partager |
![]() | Premières observations sur la morphologie et les processus sédimentaires récents de l'Éventail celtique Auteur(s) : Auffret, Gérard-andré Zaragosi, S Voisset, Michel Droz, Laurence Loubrieu, Benoit Pelleau, Pascal Savoye, R Bourillet, Jean-francois Éditeur(s) : Elsevier Résumé : During the SEDIFAN 1 cruise we surveyed the bathymetry and the acoustic properties of the surface sediment of the Celtic Deep Sea Fan. We also collected Kullenberg cores in order to study recent sedimentary processes. From the bathymetry survey it is relatively easy to recognize the main areas of modern fan. The upper fan included a large sedimentary ridge which constitutes the right levee of the prominent meandering Whittard valley. After its confluence with the Shamrock valley the course of the Whittard valley is abruptly deflected to the south. At a short distance to the south the valley divides into two upper-fan channels, the Celtic channel to the west being the deeper one. This point constitutes the centre of a radiating pattern which is developed on a 150 degrees quadrant and a radius of about 100 km. The acoustic imagery displays contrasted features, related to change in lithology within the first metre beneath the sea bottom and to the sea floor roughness. The Austell ridge exhibits a contrasted pattern of elongated areas with high and low acoustic backscattering levels. This pattern is related to the development of abyssal dunes, the amplitude of which is of metric order. Particularly remarkable is a lobe-shaped low back-scattering area in the western part of the middle fan, also noteworthy are a lineated facies to the west and a braided facies to the east of the fan. The laminated silty-clayey sequences deposited on the Whittard ridge and on the Trevelyan levee were deposited during the deglaciation. We interpret these as turbidity currents overflow deposits from the Whittard valley. At the end of isotopic stage 3 and during stage 2, the English Channel was a large plain flooded by the Channel River. During this period a broad delta developed at 100 m below the present-day depth and a wide spectrum of material was bound to be supplied to the deep sea and contributed particularly to the deposition of the Whittard ridge silty-clayey sequences. The stage 2 deposits are characterized by rhythmic levels enriched in monosulfides. These types of deposits are common in areas affected by fluvial discharges. Excluding the sedimentary ridge and the channel levees the surface deposits sampled with the Kullenberg corer are sandy. These sands are deposited in various contexts on the interfluve between the western and eastern channels and at channel mouths. They were emplaced during high sea level stands as a result of high energy gravity processes. The precise sources of these sands have not yet been identified, however benthic foraminifers from included ooze pebbles have living depths of between 500 and 1 000 m. The gravity processes which eroded this marry ooze may have been triggered on the upper slope. The Celtic shelf is presently a high energy platform where the conjunction of storms and spring tides call lead to enhanced sediment transport from near-shore to the deep sea. The relict or palimpsest deposits of the glacial delta also constitute a large reservoir of sandy material which can also be subject to reworking. Le programme Enam 2 (European North Atlantic Margin) concerne l'étude des processus sédimentaires quaternaires du Spitzberg au golfe de Gascogne. Dans le cadre de ce programme, la reconnaissance de l'Éventail profond celtique était l'objectif de la campagne Sedifan 1 au cours de laquelle nous avons établi la morphologie de l'éventail et obtenu une image acoustique des fonds sédimentaires. La morphologie permet de mettre en évidence une organisation en éventail. On note aussi le développement remarquable d'une ride sédimentaire au niveau de l'éventail supérieur. Les sédiments prélevés révèlent la présence de dépôts sableux, témoins d'une activité récente qui pourrait être liée à l'importance de l'hydrodynamisme sur les Grands Bancs de la plate-forme celtique. Oceanologica Acta (0399-1784) (Elsevier), 2000 , Vol. 23 , N. 1 , P. 109-116 Droits : 2000 Ifremer/CNRS/IRD/Editions scientifiques et medicales Elsevier SAS http://archimer.ifremer.fr/doc/2000/publication-525.pdf DOI:10.1016/S0399-1784(00)00116-X http://archimer.ifremer.fr/doc/00000/525/ | Partager Voir aussi Paléoclimat Turbidité Sédiment Quaternaire Eventail profond Palaeoclimate Turbidity Sediment Quaternary Deep sea fan Télécharger |