Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Most peridotite massifs and mantle xenoliths show a wide range of isotopic variations, often involving significant decoupling between Hf, Nd and Sr isotopes. These variations are generally ascribed either to mingling of individual components of contrasted isotopic compositions or to time integration of parent-element enrichment by percolating melts/fluids, superimposed onto previous depletion event(s). However, strong isotopic decoupling may also arise during porous flow as a result of daughter-elements fractionation during solid-liquid interaction. Although porous flow is recognized as an important process in mantle rocks, its effects on mantle isotopic variability have been barely investigated so far. The peridotites of the Lherz massif (French Pyrenees) display a frozen melt percolation front separating highly refractory harzburgites from refertilized lherzolites. Isotopic signatures observed at the melt percolation front show a strong decoupling of Hf from Nd and Sr isotopes that cannot be accounted for by simple mixing involving the harzburgite protolith and the percolating melt. Using one dimensional percolation-diffusion and percolation-reaction modeling, we show that these signatures represent transient isotopic compositions generated by porous flow. These signatures are governed by a few critical parameters such as daughter element concentrations in melt and peridotite, element diffusivity, and efficiency of isotopic homogenization rather than by the chromatographic effect of melt transport and the refertilization reaction. Subtle variations in these parameters may generate significant inter-isotopic decoupling and wide isotopic variations in mantle rocks. (C) 2009 Elsevier B.V. All rights reserved.
ISSN: 0012-821X

hal-00413135
https://hal.archives-ouvertes.fr/hal-00413135
DOI : 10.1016/j.epsl.2008.12.033

Éditeur(s) : HAL CCSD
Résumé : Differentiation of the lithospheric mantle occurred principally through partial melting and extraction of melts. Harzburgites are generally considered as melting residues whereas lherzolites are regarded as pristine mantle weakly affected by melting. However, some orogenic peridotites show evidence of igneous refertilization. In this context, this work re-investigates the nature of the Lherz lherzolites (Pyrenees), type-locality of lherzolites, described as a piece of preserved fertile mantle. Structural and geochemical data show that these lherzolites are not pristine but formed through a refertilization reaction between MORB-like melts and refractory lithosphere. Moreover, the Lherz peridotites were partly used to infer the composition of the primitive upper mantle and these results may have important implications for the nature of the late veneer. Additionally, crystal-preferred orientations of minerals (CPO) highlight a strong feedback between melt percolation and finite strain in the percolated rocks. CPO variations are ruled by a subtle balance between instantaneous melt fraction and local strain rate. This work also investigated the effect of melt percolation on Hf, Nd and Sr isotopes. Isotope systematics in Lherz shows that strong isotopic decoupling may arise in a percolation front. The modelling suggests that decoupled isotopic signatures are generated during porous flow and governed by the melt/matrix elements concentrations, chemical diffusivities or efficiency of isotopic homogenization. Melt-rock interactions can generate “intraplate-like” isotopic signatures. This suggests that a part of isotopic signatures of mantle-related rocks could be generated by diffusional processes associated with melt transport.
La différenciation du manteau lithosphérique s'est principalement effectuée par fusion partielle et extraction de magmas. Les harzburgites sont généralement considérées comme des résidus de fusion tandis que les lherzolites représentent un manteau originel peu affecté par la fusion. Cependant, certaines péridotites orogéniques montrent des évidences de refertilisation magmatique. Dans ce contexte, ce travail remet en cause la nature primitive des lherzolites de Lherz (Pyrénées), lithotype de la lherzolite. Les données structurales et géochimiques montrent que ces lherzolites ne représentent pas du manteau préservé mais qu'elles se sont formées par une réaction de refertilisation entre un liquide de type MORB et une lithosphère réfractaire. De plus, les orientations préférentielles de réseau (OPR) des minéraux montrent une forte interdépendance entre la percolation magmatique et la déformation finie observée dans les roches percolées. Les variations d'OPR semblent contrôlées par un équilibre subtil entre fraction de liquide instantanée et taux de déformation local. Ce travail a également abordé les effets de la percolation magmatique sur la variabilité isotopique des roches mantelliques. Les résultats montrent qu'un fort découplage isotopique peut s'observer dans un front de percolation. Les modèles suggèrent que le découplage des signatures isotopiques se produit pendant la percolation, gouverné par le rapport des concentrations en éléments (magma/matrice), la diffusivité et le processus d'homogénéisation isotopique. Les réactions magma/roche peuvent générer des signatures isotopiques de type intraplaque. Ceci suggère qu'une part des signatures isotopiques des roches ou laves dérivées du manteau pourrait être produite par des processus diffusionnels associés à du transport de magma.
https://tel.archives-ouvertes.fr/tel-00431325

tel-00431325
https://tel.archives-ouvertes.fr/tel-00431325
https://tel.archives-ouvertes.fr/tel-00431325/document
https://tel.archives-ouvertes.fr/tel-00431325/file/theseleroux08.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Alkali feldspar thermochronologic modeling with the 40Ar/39Ar method has generated marked advances in knowledge of the mechanisms for argon diffusion in feldspars. While the goal in many cases has been to extrapolate the observed and modeled argon behavior in feldspars to natural geological settings, scientific debate surrounding the true feasibility of such extrapolations and indeed, the validity of thermochronologic modeling in itself, have provided much impetus to improve laboratory techniques to test, and increase basic understanding of, argon diffusion. Two cornerstones for the debate over the feasibility of alkali feldspar thermochronology for modeling natural, geologic processes have been: 1. is volume diffusion the main mechanism for argon movement in feldspars? and 2. if volume diffusion is a viable mechanism, does argon then reside in discrete ‘domains' within the feldspar lattice? We describe a study of alkali feldspars from a profile through a well-controlled brittle fault zone in western Norway; the feldspars document argon loss during deformation and strongly suggest the existence of argon ‘domains' within the feldspars, at least during laboratory step heating. The progressive change in the character of argon diffusion is recognizable in the logr/ro diffusion data from the feldspars and is mimicked by physical changes observed optically in the feldspars through progressive degrees of brittle deformation. Modeling results indicate a reduction in size of the biggest domains and the appearance of smaller domains during the strongest stages of deformation. Whether or not this reveals the existence and the transformation of the domain structure in naturo is difficult to prove from our data alone, but interestingly, this behaviour corresponds directly to the physical (optical) appearance of more intense crack networks and subgrains in progressively more brecciated feldspars. Because the thermochronologic histories derived from modeling the feldspar data conform very well to the known tectonic history of the area, the feldspars appear to have successfully retained physical (optical and isotopic) records of episodic tectonic processes operating from ductile through lowtemperature brittle regimes in rocks with a Caledonian history overprinted by several later (younger) geologic events. However, because the ‘cold' brecciation is the last tectonothermal event recorded by these rocks, it is impossible to truly test for the existence of diffusion domains in naturo. Argon loss appears to have been effective only in the most highly brecciated (deformed) samples where the combination of the connected crack network, increased fluid flow and higher temperatures enhanced diffusion via fast diffusion pathways and thus, volume diffusion from the lattice. Only minor argon loss occurred in zones of lower brittle strain, although some development of cracks and brittle features is evident. Independent of the existence of diffusion domains, this study highlights the possible pitfalls when cooling histories are deduced from brecciated feldspars in which age and diffusion charateristics have been decoupled: while the geochronological memory has survived and is identical to that of nonbrecciated feldspars (suggesting no loss and minor effects of deformation), the diffusion characteristics have been completely transposed by brecciation and the appearance of new domains. Modeling feldspars with these latter characteristics would effectively utilise a new feldspar diffusion structure with an ‘old' (relict) age memory.
ISSN: 0016-7037

hal-00198283
https://hal.archives-ouvertes.fr/hal-00198283
https://hal.archives-ouvertes.fr/hal-00198283/document
https://hal.archives-ouvertes.fr/hal-00198283/file/KsparBreccia_Arnaud_Eide_GCA_2000.pdf