Éditeur(s) : HAL CCSD Taylor & Francis
Résumé :  
We compared floral odour profiles among populations of two Arum species which show different degrees of specificity for their fly pollinators. Insects were collected from inflorescences in four populations of Arum italicum and two populations of Arum maculaturn. In six Arum populations, we compared inflorescences odour profiles collected by Solid Phase Micro Extraction (SPME) and analysed by gas chromatography. We confirmed that from a pollination point of view, A. italicum is an opportunist species, as it is mainly pollinated by insects of the families Psychodidae, Chironomidae and Sciaridae, whereas A. maculatum is a specialist species, as it is 90% pollinated by Psychodidae. In all populations, Arum italicum was less attractive to pollinators than Arum maculatum. Floral odour profiles of A. italicum were not geographically structured among populations, suggesting a high gene flow or adaptation to a fluctuant guild of pollinators. On the contrary, odour profiles of A. maculatum varied between the two populations studied suggesting a lower gene flow or adaptation to different local pollinator preferences
ISSN: 0037-9271

hal-01019003
https://hal.archives-ouvertes.fr/hal-01019003

Éditeur(s) : HAL CCSD Wiley Open Access
Résumé : International audience
Plant responses to natural enemies include formation of secondary metabolites acting as direct or indirect defenses. Volatile terpenes represent one of the most diverse groups of secondary metabolites. We aimed to explore evolutionary patterns of volatile terpene emission. We measured the composition of damage-induced volatile terpenes from 202 Amazonian tree species, spanning the angiosperm phylogeny. Volatile terpenes were extracted with solid-phase micro extraction and desorbed in a gas chromatography–mass spectrometry for compound identification. The chemical diversity of the terpene blend showed a strong phylogenetic signal as closely related species emitted a similar number of compounds. Closely related species also tended to have compositionally similar blends, although this relationship was weak. Meanwhile, the ability to emit a given compound showed no significant phylogenetic signal for 200 of 286 compounds, indicating a high rate of diversification in terpene synthesis and/or great variability in their expression. Three lineages (Magnoliales, Laurales, and Sapindales) showed exceptionally high rates of terpene diversification. Of the 70 compounds found in >10% of their species, 69 displayed significant correlated evolution with at least one other compound. These results provide insights into the complex evolutionary history of volatile terpenes in angiosperms, while highlighting the need for further research into this important class of compounds.
ISSN: 2045-7758

Droits : http://creativecommons.org/licenses/by/
hal-01296640
http://hal.upmc.fr/hal-01296640
http://hal.upmc.fr/hal-01296640/document
http://hal.upmc.fr/hal-01296640/file/ece31810.pdf
DOI : 10.1002/ece3.1810

Éditeur(s) : HAL CCSD
Résumé : This thesis is devoted to the study of the geodynamic evolution of the panafrican belt in NW Angola, lying on the western margin of the Congo craton. This orogenic belt, resulting from the late neoproterozoic - early paleozoic convergence of the São Francisco and Congo cratons, can be subdivided into two main domains: 1) an eastern foreland made of folded neoproterozoic sediments and 2) a western hinterland made of magmatic and metamorphic rocks. Our structural, petrological, geochemical and geochronological studies lead to the recognition of two main units within this hinterland : 1) an upper eastern unit made of gneiss and micaschists (PTmax : 8-12 kbar, 650-680°C) that preserves D1 deformation structures related to the ENE transport of nappes and 2) a western lower unit made of gneiss and migmatites (P-Tmax : 7-9 kbar, 700-750°C) that were affected by a polyphased deformation. Our geochronological study shows that this belt contains ~2Ga old granites that were involved in a polyphased panafrican evolution between 540 Ma for syn-D1 peak metamorphic conditions and 480 Ma for the last stages of recrystallization and exhumation of high grade rocks. The synthesis of all data leads to a precise reconstruction of P-T-D-t paths in both tectonometamorphic units and to comparison of this panafrican belt with similar belts distributed on both sides of the Atlantic ocean. This work attests of the complexity of the geodynamic processes resulting in the Gondwana assembly and implying both large cratonic landmasses and intercalated microplates.
Cette thèse est consacrée à l'étude de l'évolution géodynamique de la chaîne panafricaine au NW de l'Angola, sur la marge occidentale du craton du Congo. Ce segment orogénique, conséquence de la convergence des cratons du São Francisco et du Congo à la fin du Néoprotérozoïque et début du Paléozoïque, peut être subdivisé en un domaine externe plissé et peu métamorphique et un domaine interne formé de roches magmatiques et métamorphiques. Les études structurales, pétrologiques, géochimiques et géochronologiques conduisent à distinguer deux unités principales dans le domaine interne : - l'unité supérieure de gneiss et micaschistes (P-Tmax : 8-12 kbar, 650-680°C) dont la déformation D1 est synchrone de la mise en place des nappes vers l'ENE; - l'unité inférieure dans la partie occidentale constituée de gneiss et migmatites (P-Tmax : 7-9 kbar, 700-750°C) affectés par une déformation polyphasée. L'étude géochronologique démontre l'existence de protolithes granitiques datés à ~2 Ga impliqués dans l'orogénèse pan africaine caractérisée par une histoire polyphasée entre 540 Ma pour le pic du métamorphisme syn-D1 et 480 Ma pour les dernières phases de recristallisation et d'exhumation des roches métamorphiques de haut grade. La synthèse des données permet ainsi de reconstruire précisément les deux chemins P-T-D-t de ces deux unités tectono-métamorphiques et de comparer ce segment panafricain à ceux présents de part et d'autre de l'Atlantique Sud. Ce travail témoigne de la complexité des processus géodynamiques de convergence amenant à l'assemblage du Gondwana impliquant à la fois de larges masses cratoniques et des microplaques intercalées entre ces masses.
https://tel.archives-ouvertes.fr/tel-00770757

Droits : info:eu-repo/semantics/OpenAccess
tel-00770757
https://tel.archives-ouvertes.fr/tel-00770757
https://tel.archives-ouvertes.fr/tel-00770757/document
https://tel.archives-ouvertes.fr/tel-00770757/file/these2012-Nsungani.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Recent research has demonstrated the importance of dermal exposure for some semivolatile organic compounds (SVOCs) present in the gas phase of indoor air. Though models for estimating dermal intake from gaseous SVOCs exist, their predictions can be subject to variations in input parameters, which can lead to large variation in exposure estimations. In this sensitivity analysis for a steady state model, we aimed to assess these variations and their determinants using probabilistic Monte Carlo sampling for 8 SVOCs from different chemical families: phthalates, bisphenols, polycyclic aromatic hydrocarbons (PAHs), organophosphorus (OPs), organochlorines (OCs), synthetic musks, polychlorinated biphenyls (PCBs) and polybromodiphenylethers (PBDEs). Indoor SVOC concentrations were found to be the most influential parameters. Both Henry's law constant (H) and octanol/water partition coefficient (Kow) uncertainty also had significant influence. While exposure media properties such as volume fraction of organic matter in the particle phase (fom-part), particle density (ρpart), concentration ([TSP]) and transport coefficient (ɣd) had a slight influence for some compounds, human parameters such as body weight (W), body surface area (A) and daily exposure (t) make a marginal or null contribution to the variance of dermal intake for a given age group. Inclusion of a parameter sensitivity analysis appears essential to reporting uncertainties in dermal exposure assessment.
ISSN: 0160-4120

hal-01526430
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01526430
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01526430/file/Dermal%20absorption%20of%20semivolatile%20organic%20compounds_accepted.pdf
DOI : 10.1016/j.envint.2017.02.005
PUBMED : 28249739

Éditeur(s) : HAL CCSD
Résumé : The presence of obstacles met in natural environment by the flow, influences the dispersion of air pollutants which it carries. This thesis, based on spatiotemporal micro-meteorological measurements in tropical region, aims at studying the dispersion of compounds emitted by the ecosystem mangrove according to the weather conditions. At a daily scale, the meteorological analysis reveals, besides the presence of Trade Winds, the existence of thermal flows of which nocturnal thermodynamic parameters have been defined. The field observation has shown that the weak intensity of the wind disadvantages the dispersion of compounds emitted during the night. At a finer scale, the existence of a spectral gap separating large scale phenomena of those related to turbulence has been demonstrated. These last ones were treated by spectral and statistical approaches to quantify the turbulent fluxes of momentum and sensible heat during the night, for an averaged duration of 13 minutes. The stratification of the surface layer has been considered and determined by Monin-Obukhov similarity theory. The measurements acquired at night and the application of Kolmogorov theory allowed us to deduct the dissipation rate of energy and the size of the vortices at 5.5 meters in height. This work has also led us, by gas chromatography coupled to mass spectrometry, to identify, in mangrove, sulphurated volatil organic compounds, organohalogen, BTEX, ... All these results will later serve to feed dispersion models related to the studied ecosystem.
La présence d'obstacles rencontrés en milieu naturel par l'écoulement, influence la dispersion des polluants qu'il transporte. Cette thèse, fondée sur des mesures micro-météorologiques spatio-temporelles en région tropicale, vise à étudier la dispersion de composés émis par l'écosystème mangrove en fonction des conditions météorologiques. A l'échelle journalière, l'analyse météorologique révèle, outre la présence des Alizés, l'existence d'écoulements thermiques dont des paramètres thermodynamiques nocturnes ont été définis. L'observation terrain nous a montré que la faible intensité du vent défavorise la dispersion des composés émis durant la nuit. A une échelle plus fine, l'existence d'un trou spectral séparant les phénomènes de grande échelle de ceux liés à la turbulence a été mise en évidence. Ces derniers ont été traités par des approches spectrale et statistique pour quantifier les flux turbulents de quantité de mouvement et de chaleur sensible, pendant la nuit, pour une durée de moyenne de l'ordre de 13 minutes. L'état de stratification de la couche de surface a été pris en compte et déterminé par la théorie de similitude de Monin-Obukhov. Les mesures nocturnes effectuées et l'application de la théorie de Kolmogorov ont permis de déduire les taux de dissipation de l'énergie et la taille des tourbillons à 5,5 m d'altitude. Ce travail a également conduit, par l'analyse chromatographique en phase gazeuse couplée à la spectrométrie de masse, à l'identification, en mangrove, de composés organiques volatils soufrés, des organohalogénés, des BTEX, ... L'ensemble de ces résultats servira ultérieurement à alimenter les modèles de dispersion spécifiques liés aux écosystèmes étudiés.
https://tel.archives-ouvertes.fr/tel-00665882

Droits : info:eu-repo/semantics/OpenAccess
NNT : 11AGUY0438
tel-00665882
https://tel.archives-ouvertes.fr/tel-00665882
https://tel.archives-ouvertes.fr/tel-00665882/document
https://tel.archives-ouvertes.fr/tel-00665882/file/ThA_seCdAlexis.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : While most rocks from active volcanoes display ((210)pb/Ra-226) activity ratios lower than or close to the equilibrium value of 1, several other have ratios much higher than 1. Transfer of Rn-222 by magmatic volatiles has often been advocated to explain both Pb-210 deficits and excesses. We develop here a model to account for Pb-210 excesses through Rn-222 accumulation. We show that large Pb-210 excesses can be readily obtained, even for moderate ratios of degassing magma over accumulating magma, in a closed-system model where the Rn-222 atoms produced by decay of Ra-226 in the degassing magma are continuously extracted by a gas phase. For a given duration of volatile transfer, relative Pb-210 excesses are expected to be much larger than Pb-210 deficits. This model is applied to samples from Santorini (Aegean arc) and Surtsey (Iceland) both of which show high ((210)pb/Ra-226) ratios of 6.7 and 2.3 respectively at the time of eruption. The agreement with field data suggests that Rn-222 accumulation leading to Pb-210 excesses might be a rather common process in zoned magma chambers as well as in individual lava flows, and that it can be described by a closed-system model.
ISSN: 0012-821X

hal-00496398
https://hal.archives-ouvertes.fr/hal-00496398
DOI : 10.1016/j.epsl.2010.02.048

Éditeur(s) : HAL CCSD Elsevier
Résumé : Detailed sedimentological investigations on numerous outcrops and drill-core sections in the 2.1-Ga-old Franceville basin, Gabon, provide evidence for a large-scale injectite network. The injectites were formed by the injection of sands through a thickness of about 150 m of the FB1 Member, and now cover a minimum area of 70 km2 corresponding to the Bangombé plateau, but are also recognized close to Franceville 35 km farther south-east. The injectite lithology corresponds to a mud- or carbonate-supported sandstone characterized by a loose and uncompacted fabric contrasting with the host-rock. Because the injectites are often parallel to subparallel to the stratification, they were misinterpreted as depositional beds by previous authors. At outcrop, the injectite bodies exhibit sill, dyke, wing and protrusive geometries emplaced during early burial within poorly compacted material, with partial wall erosion and dissociation. The source of the sand material is attributed to a channel-levee turbidite depositional system located in the lower part of the FB1 Member. These deposits were buried by a thick biochemical muddy cap deposited during a starvation phase, which increased the seal capacity of the system. This type of architecture has a high potential to develop compaction disequilibrium during burial. Moreover, in the case of the Francevillian injectites, the abundance of microbial organic matter favoured early methane degassing and lateral charging of the sand reservoir. The overpressure in the channels was periodically released during early burial, through the effect of rapid sedimentary and tectonic loading, and possible seismic activity. The fluidized sand was injected according to a symmetrical wing pattern. Thus, the injected masses caused a local decrease in the grade of the lateritic manganese ore deposit of the Bangombé plateau.
ISSN: 0301-9268

hal-01667217
https://hal.archives-ouvertes.fr/hal-01667217
DOI : 10.1016/j.precamres.2017.09.022

Éditeur(s) : HAL CCSD Nature Publishing Group
Résumé : International audience
Epigenetics, as a DNA signature that affects gene expression and enables rapid reaction of an organism to environmental changes, is likely involved in the process of biological invasions. DNA methylation is an epigenetic mechanism common to plants and animals for regulating gene expression. In this study we show, for the first time in any marine species, significant reduction of global methylation levels during the expansive phase of a pygmy mussel (Xenostrobus securis) recent invasion in Europe (twoyear old), while in older introductions such epigenetic signature of invasion was progressively reduced. Decreased methylation was interpreted as a rapid way of increasing phenotypic plasticity that would help invasive populations to thrive. This epigenetic signature of early invasion was stronger than the expected environmental signature of environmental stress in younger populations sampled from ports, otherwise detected in a much older population (>90 year old) of the also invasive tubewormFicopomatus enigmaticus established in similar locations. Higher epigenetic than genetic diversity found in X. securis was confirmed from F. enigmaticus samples. As reported for introduced plants and vertebrates, epigenetic variation could compensate for relatively lower genetic variation caused by founder effects. These phenomena were compared with epigenetic mechanisms involved in metastasis, as parallel processes of community (biological invasion) and organism (cancer) invasions.
ISSN: 2045-2322

hal-01488962
https://hal-univ-perp.archives-ouvertes.fr/hal-01488962
https://hal-univ-perp.archives-ouvertes.fr/hal-01488962/document
https://hal-univ-perp.archives-ouvertes.fr/hal-01488962/file/Epigenetic.pdf
DOI : 10.1038/srep42193

Éditeur(s) : HAL CCSD Elsevier
Résumé : In situ analysis of major elements, platinum-group elements and Os isotope composition data for 170 grains of Ru–Os–Ir alloys from podiform chromitites in the Luobusa and Dongqiao ophiolites, Tibet, provide new constraints on the sources of the alloy grains, the Os-isotope composition of the Neo-Tethyan oceanic upper mantle, and the timing of melt–rock reactions in the ultramafic peridotites of the host ophiolites. Most alloy grains are osmiridium and iridosmine. Based on elemental and isotopic compositions, two populations can be identified. Group I, found in both ophiolite bodies, has fractionated PGE patterns typical of alloys and homogeneous 187Os/188Os 0.12645 ± 4 (2s; n = 145). Group II alloys from the Dongqiao ophiolites show smooth PGE patterns and 187Os/188Os ranges from 0.12003 to 0.12194 (yielding Re-depletion ages ≥ 1.1 Ga). Both the PGE patterns and the Os isotopic compositions of Group II resemble those of sulfides residual after melting. Group I alloys represent an early cumulate phase during the crystallization of magmas and are interpreted as derived from an asthenospheric melt. In contrast, Group II alloys are inferred to derive from the breakdown of residual sulfides from the mantle section of the ophiolite, which may represent relics of a sub-continental lithospheric mantle. The coexistence of the two groups of alloys in Dongqiao samples reflects interaction between asthenosphere-derived melts and old depleted lithospheric mantle and suggests that the chromitites originated through melt–rock reactions. The data on the Group I alloys support the hypothesis that the Re–Os evolution of the convective oceanic mantle resembles that of enstatite chondrites.
ISSN: 0012-821X

hal-00404967
https://hal.archives-ouvertes.fr/hal-00404967
DOI : 10.1016/j.epsl.2007.05.044

Éditeur(s) : HAL CCSD Wiley
Résumé : International audience
We report trace element analyses from mineral phases in chondrules from carbonaceous chondrites (Vigarano, Renazzo, and Acfer 187), carried out by laser ablation inductively coupled plasma-mass spectrometry. Results are similar in all three meteorites. Mesostasis has rare earth element (REE) concentrations of 10-20 × CI. Low-Ca pyroxene has light REE (LREE) concentrations near 0.1 × CI and heavy REE (HREE) near 1 × CI, respectively. Olivine has HREE concentrations at 0.1-1 × CI and LREE around 10−2 × CI. The coarsest olivine crystals tend to have the most fractionated REE patterns, indicative of equilibrium partitioning. Low-Ca pyroxene in the most pyroxene-rich chondrules tends to have the lowest REE concentrations. Type I chondrules seem to have undergone a significant degree of batch crystallization (as opposed to fractional crystallization), which requires cooling rates slower than 1-100 K h−1. This would fill the gap between igneous calcium-aluminum-rich inclusions (CAIs) and type II chondrules. The anticorrelation between REE abundances and pyroxene mode may be understood as due to dilution by addition of silica to the chondrule melt, as in the gas-melt interaction scenario of Libourel et al. (2006). The rapid cooling rate (of the order of 1000 K h−1) which seems recorded by low-Ca pyroxene, contrasted with the more diverse record of olivine, may point to a nonlinear cooling history or suggest that formation of pyroxene-rich chondrule margins was an event distinct from the crystallization of the interior.
ISSN: 1086-9379

hal-00795434
https://hal.archives-ouvertes.fr/hal-00795434
DOI : 10.1111/maps.12005