![]() | Mesure automatisée de la respiration du sol : caractérisation et comparaison de deux systèmes Auteur(s) : Goret, Jean-Yves Burban, Benoît BURLETT, Régis Bosc, Alexandre Ponton, Stéphane Auteurs secondaires : Ecologie des forêts de Guyane (ECOFOG) ; Ecole Nationale du Génie Rural, des Eaux et des Forêts (ENGREF) - Institut National de la Recherche Agronomique (INRA) - Université des Antilles et de la Guyane (UAG) - Centre National de la Recherche Scientifique (CNRS) Écologie fonctionnelle et physique de l'environnement (EPHYSE - UR1263) ; Institut National de la Recherche Agronomique (INRA) Ecologie et Ecophysiologie Forestières (EEF) ; Institut National de la Recherche Agronomique (INRA) - Université de Lorraine (UL) Éditeur(s) : HAL CCSD INRA Résumé : Afin de mesurer en continu la respiration du sol, deux laboratoires de l'INRA ont développé deux systèmes automatiques basés sur des designs et automatismes très similaires. Le choix de la mesure des échanges gazeux s'est porté sur les deux principes bien connus des méthodes dynamiques, à savoir, le système ouvert ou fermé (Field et al. 1989). Ces deux méthodes présentent chacune leurs avantages et leurs inconvénients et chaque équipe a fait ses choix en fonction du matériel disponible, des conditions environnementales de mesure, des budgets ou des techniques maîtrisées. La prise en compte poussée (calculs préalables, vérification a postériori) des problèmes potentiels de mesure rapportés dans la littérature a conduit à réaliser deux systèmes correctement dimensionnés. ISSN: 0762-7339 hal-01032041 https://hal.archives-ouvertes.fr/hal-01032041 | Partager |
![]() | New occurrence of UHP eclogites in Limousin (French Massif Central): Age, tectonic setting and fluid-rock interactions Auteur(s) : Berger, Julien Femenias, Olivier Ohnenstetter, Daniel Bruguier, Olivier Plissart, Gaelle Mercier, Jean-Claude C. Demaiffe, Daniel Auteurs secondaires : Département d'Informatique [Bruxelles] (ULB) ; Université Libre de Bruxelles [Bruxelles] (ULB) Centre de Recherches Pétrographiques et Géochimiques (CRPG) ; Université de Lorraine (UL) - Centre National de la Recherche Scientifique (CNRS) Géosciences Montpellier ; Université des Antilles et de la Guyane (UAG) - Institut national des sciences de l'Univers (INSU - CNRS) - Université de Montpellier (UM) - Centre National de la Recherche Scientifique (CNRS) LIttoral ENvironnement et Sociétés - UMR 7266 (LIENSs) ; Université de La Rochelle (ULR) - Centre National de la Recherche Scientifique (CNRS) Éditeur(s) : HAL CCSD Elsevier Résumé : Kyanite and zoisite eclogites from the Limousin area in the Variscan French Massif Central (FMC) have been formed by deep subduction to 100 km depth at peak pressure-temperature conditions around 660 degrees C and 2.9 GPa. They belong to a thin tectonic unit comprising ophiolitic bodies devoid of HP-UHP markers and forming a transported suture zone now separating the two main lithotectonic units of the FMC with contrasted tectono-metamorphic features (namely the lower and upper allochthons). Composition of kyanite-eclogites is similar to supra-subduction-zone basalts found in back-arc basins or island arcs (LREE depleted, negative Nb-Ta anomalies, epsilon Nd: +6 to + 9). Zoisite eclogites have the major-element fingerprint of ultrabasic iron-rich plagioclase cumulates common in continental intrusions or forming Fe-Ti oceanic gabbros. The distribution of immobile trace-elements is however more comparable to alkaline Si-undersaturated rocks, but the Sr-Nd isotopic composition (Sr-87/Sr-86: 0.706; epsilon Nd: -3 to -5) suggests the intervention of an old radiogenic crustal component during their petrogenesis. The chemical composition of hydrous zoisite eclogites does not correspond closely to a common magmatic precursor. It is thus suggested that, by analogy with well exposed worldwide HP-UHP terranes, at least a part of the trace-element signature and the isotopic compositions are controlled by channelled fluid-rock interaction at UHP conditions, leading to localised segregation of zoisite that hosts nearly all Sr and LREE budgets of the bulk eclogite. Sr-Nd isotopic composition of these samples is thus controlled by zoisite and probably represents the isotopic composition of the fluid phase present during UHP recrystallisation. Zircons extracted from a zoisite eclogite were dated in-situ by LA-ICP-MS. Crystallisation of the magmatic precursor is bracketed between 489 and 475 Ma and the UHP event is dated at 412 +/- 10 Ma, in agreement with published ages for the Eo-Variscan HP stage in the FMC. A late resetting of the U-Pb isotopic system at 382 +/- 7 Ma is related to an anatectic high pressure-medium pressure event, well known in the Limousin area. The oceanic eclogites dated in this study are tentatively linked to the Galicia-South Brittany Lower Paleozoic Ocean; they show evidence of the existence of an intra-oceanic subduction zone at the Lower Ordovician and of partial closure of this oceanic domain by ocean-continent subduction during Early Devonian. ISSN: 0024-4937 hal-00512835 https://hal.archives-ouvertes.fr/hal-00512835 DOI : 10.1016/j.lithos.2010.05.013 | Partager |
![]() | Rare earth elements and neodymium isotopes in sedimentary organic matter Auteur(s) : Freslon, Nicolas Bayon, Germain Toucanne, Samuel Bermell, Sylvain Bollinger, Claire Cheron, Sandrine Etoubleau, Joel Germain, Yoan Éditeur(s) : Pergamon-elsevier Science Ltd Résumé : We report rare earth element (REE) and neodymium (Nd) isotope data for the organic fraction of sediments collected from various depositional environments, i.e. rivers (n=25), estuaries (n=18), open-ocean settings (n=15), and cold seeps (n=12). Sedimentary Organic Matter (SOM) was extracted using a mixed hydrogen peroxide/nitric acid solution (20%-H2O2 – 0.02M-HNO3), after removal of carbonate and oxy-hydroxide phases with dilute hydrochloric acid (0.25M-HCl). A series of experimental tests indicate that extraction of sedimentary organic compounds using H202 may be complicated occasionally by partial dissolution of sulphide minerals and residual carbonates. However, this contamination is expected to be minor for REE because measured concentrations in H2O2 leachates are about two-orders of magnitude higher than in the above mentioned phases. The mean REE concentrations determined in the H2O2 leachates for samples from rivers, estuaries, coastal seas and open-ocean settings yield relatively similar levels, with ΣREE = 109 ± 86 ppm (mean ± s; n=58). The organic fractions leached from cold seep sediments display even higher concentration levels (285 ± 150 ppm; mean ± s; n=12). The H2O2 leachates for most sediments exhibit remarkably similar shale-normalized REE patterns, all characterized by a mid-REE enrichment compared to the other REE. This suggests that the distribution of REE in leached sedimentary organic phases is controlled primarily by biogeochemical processes, rather than by the composition of the source from which they derive (e.g. pore, river or sea- water). The Nd isotopic compositions for organic phases leached from river sediments are very similar to those for the corresponding detrital fractions. In contrast, the SOM extracted from marine sediments display εNd values that typically range between the εNd signatures for terrestrial organic matter (inferred from the analysis of the sedimentary detrital fractions) and marine organic matter (inferred from the analysis of local surface seawater). A notable exception is the case of organic matter (OM) fractions leached from cold seep sediment samples, which sometimes exhibit εNd values markedly different from both terrigenous and surface seawater signatures. This suggests that a significant fraction of organic compounds in these sediments may be derived from chemosynthetic processes, recycling pore water REE characterized by a distinct isotopic composition. Overall, our results confirm that organic matter probably plays an important role in the oceanic REE budget, through direct scavenging and remineralization within the water column. Both the high REE abundances and the shape of shale-normalized patterns for leached SOM also suggest that OM degradation in sub-surface marine sediments during early diagenesis could control, to a large extent, the distribution of REE in pore waters. Benthic fluxes of organic-bound REE could hence substantially contribute to the exchange processes between particulates and seawater that take place at ocean margins. Neodymium isotopes could provide useful information for tracing the origin (terrestrial versus marine) and geographical provenance of organic matter, with potential applications in paleoceanography. In particular, future studies should further investigate the potential of Nd isotopes in organic compounds preserved in sedimentary records for reconstructing past variations of surface ocean circulation. Geochimica Et Cosmochimica Acta (0016-7037) (Pergamon-elsevier Science Ltd), 2014-09 , Vol. 140 , P. 177-198 Droits : 2014 Elsevier Ltd. All rights reserved. http://archimer.ifremer.fr/doc/00191/30250/28682.pdf DOI:10.1016/j.gca.2014.05.016 http://archimer.ifremer.fr/doc/00191/30250/ | Partager |
![]() | Towards the Determination of Mytilus edulis Food Preferences Using the Dynamic Energy Budget (DEB) Theory Auteur(s) : Picoche, Coralie Le Gendre, Romain Flye-sainte-marie, Jonathan Francoise, Sylvaine Maheux, Frank Simon, Benjamin Gangnery, Aline Éditeur(s) : Public Library Science Résumé : The blue mussel, Mytilus edulis, is a commercially important species, with production based on both fisheries and aquaculture. Dynamic Energy Budget (DEB) models have been extensively applied to study its energetics but such applications require a deep understanding of its nutrition, from filtration to assimilation. Being filter feeders, mussels show multiple responses to temporal fluctuations in their food and environment, raising questions that can be investigated by modeling. To provide a better insight into mussel–environment interactions, an experiment was conducted in one of the main French growing zones (Utah Beach, Normandy). Mussel growth was monitored monthly for 18 months, with a large number of environmental descriptors measured in parallel. Food proxies such as chlorophyll a, particulate organic carbon and phytoplankton were also sampled, in addition to non-nutritious particles. High-frequency physical data recording (e.g., water temperature, immersion duration) completed the habitat description. Measures revealed an increase in dry flesh mass during the first year, followed by a high mass loss, which could not be completely explained by the DEB model using raw external signals. We propose two methods that reconstruct food from shell length and dry flesh mass variations. The former depends on the inversion of the growth equation while the latter is based on iterative simulations. Assemblages of food proxies are then related to reconstructed food input, with a special focus on plankton species. A characteristic contribution is attributed to these sources to estimate nutritional values for mussels. M. edulis shows no preference between most plankton life history traits. Selection is based on the size of the ingested particles, which is modified by the volume and social behavior of plankton species. This finding reveals the importance of diet diversity and both passive and active selections, and confirms the need to adjust DEB models to different populations and sites. Plos One (1932-6203) (Public Library Science), 2014-10 , Vol. 9 , N. 10 , P. 1-13 Droits : 2014 Picoche et al. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited http://archimer.ifremer.fr/doc/00218/32895/31380.pdf http://archimer.ifremer.fr/doc/00218/32895/31381.pdf http://archimer.ifremer.fr/doc/00218/32895/31382.pdf http://archimer.ifremer.fr/doc/00218/32895/31383.pdf http://archimer.ifremer.fr/doc/00218/32895/31384.pdf | Partager |
![]() | Fluid flow regimes and growth of a giant pockmark Auteur(s) : Marcon, Yann Ondreas, Helene Sahling, Heiko Bohrmann, Gerhard Olu, Karine Éditeur(s) : Geological Soc Amer, Inc Résumé : Pockmarks are seafloor depressions commonly associated with fluid escape from the seabed and are believed to contribute noticeably to the transfer of methane into the ocean and ultimately into the atmosphere. They occur in many different areas and geological contexts, and vary greatly in size and shape. Nevertheless, the mechanisms of pockmark growth are still largely unclear. Still, seabed methane emissions contribute to the global carbon budget, and understanding such processes is critical to constrain future quantifications of seabed methane release at local and global scales. The giant Regab pockmark (9 degrees 42.6' E, 5 degrees 47.8' S), located at 3160 m water depth near the Congo deep-sea channel (offshore southwestern Africa), was investigated with state-of-the-art mapping devices mounted on IFREMER's (French Research Institute for Exploitation of the Sea) remotely operated vehicle (ROV) Victor 6000. ROV-borne micro-bathymetry and backscatter data of the entire structure, a high-resolution photo-mosaic covering 105,000 m(2) of the most active area, sidescan mapping of gas emissions, and maps of faunal distribution as well as of carbonate crust occurrence are combined to provide an unprecedented detailed view of a giant pockmark. All data sets suggest that the pockmark is composed of two very distinctive zones in terms of seepage intensity. We postulate that these zones are the surface expression of two fluid flow regimes in the subsurface: focused flow through a fractured medium and diffuse flow through a porous medium. We conclude that the growth of giant pockmarks is controlled by self-sealing processes and lateral spreading of rising fluids. In particular, partial redirection of fluids through fractures in the sediments can drive the pockmark growth in preferential directions. Geology (0091-7613) (Geological Soc Amer, Inc), 2014-01 , Vol. 42 , N. 1 , P. 63-66 Droits : 2013 Geological Society of America http://archimer.ifremer.fr/doc/00186/29731/28293.pdf DOI:10.1130/G34801.1 http://archimer.ifremer.fr/doc/00186/29731/ | Partager |
![]() | La réponse des forêts tropicales humides aux variations climatiques : évolution de la structure et de la dynamique des peuplements forestiers guyanais ; The response of tropical forests to climate variations : evolution of the structure and dynamic of the guianian forest populations. Auteur(s) : Wagner, Fabien Auteurs secondaires : Antilles-Guyane Hérault, Bruno Rossi, Vivien Résumé : L'importance des forêts tropicales dans le cycle du carbone à l'échelle planétaire est majeure, tant en terme de stock qu’en terme de flux de CO2. Plusieurs études mettent en évidence des changements au sein des forêts tropicales au cours des 20 dernières années, notamment des changements de la dynamique forestière et une augmentation de la biomasse aérienne. Les déterminants de ces variations sont aujourd’hui discutés et nous proposons ici d’apporter une contribution à ce débat. Les données utilisées dans ce travail proviennent du dispositif de suivi forestier à long terme de Paracou, Guyane Française, mis en place en 1984 et qui recouvre plus de 120 ha de forêt tropicale humide. Les données météorologiques proviennent de la tour à flux du dispositif, Guyaflux. Les mesures de diamètre proviennent de la base Guyafor pour les données annuelles et bisannuelles, et des mesures de 260 arbres à proximité de la tour à flux pour les mesures diamétriques intra-annuelles.Cette thèse se divise en deux grandes parties. La première concerne l’analyse de la biomasse du dispositif de suivi forestier de Paracou en Guyane et l’implication des changements de structure de cette forêt sur le bilan de carbone. Cette partie est constituée de deux points. (i) Quelles échelles temporelles et spatiales sont pertinentes pour analyser les composantes de structure (biomasse, aire basale et nombre de tiges) et de dynamique (croissance, recrutement et mortalité) des forêts tropicales afin de minimiser les effets d’échantillonnage ? Nous avons établi une méthodologie permettant de relier les intervalles de temps et la surface de mesure aux coefficients de variation de chacune des variables de structure et de dynamique de la forêt. (ii) Quels processus démographiques sont prépondérants dans l’explication des variations de biomasse et comment se redistribue la biomasse accumulée dans le système ? L’augmentation de la biomasse observée sur le dispositif de Paracou serait liée à la rareté des évènements de mortalité des gros arbres qui portent une part très importante de la biomasse.La deuxième partie de la thèse concerne l’analyse de l’effet du climat à moyen terme, inter et intra-annuel, et les effets directs du climat dans les changements de dynamique de la forêt. Cette partie se divise en 3 points. (i) Comment quantifier le stress hydrique en forêt tropicale humide ? Nous avons réalisé un modèle journalier de réserve en eau du sol pour les arbres en forêt tropicale. (ii) Quelles variables sont explicatives de la croissance des arbres en forêt guyanaise ? Nous avons montré que l’eau dans le sol est le facteur le plus explicatif du déterminisme climatique parmi un panel de variables climatiques. (iii) Quels traits fonctionnels sont prédicteurs de la réponse des arbres aux variations climatique ? Nous avons déterminé que des traits spécifiques, densité du bois et la hauteur maximale, ainsi que le diamètre de l'arbre au moment de la mesure, modulent la croissance des arbres en réponse au climat. At a global scale tropical forest play a major role in term of carbon stock as well as in term of CO2 fluxes. Several studies have highlighted changes in tropical forest functioning during the last 20 years including a faster turnover and an increase of above ground biomass. The drivers of these changes are discussed and throughout this thesis we propose to contribute to this debate. We use the data from the Paracou experimental site in French Guiana established in 1984 on 120 hectares of moist tropical forest. Meteorological data come from the flux tower of the site, Guyaflux. We use annual and bisannual diameter measurements from the Guyafor database, and intra-annual diameter increments from the measurements of 260 trees near the flux tower.This thesis has two main parts. In the first part we present the biomass analysis of the Paracou permanent plots and the impact of structural changes in this forest on the carbon budget. The first part is constituted by two points. (i) Which temporal and spatial scale used to analyze the structure (biomass, basal area and stem density) and dynamics (tree growth, recruitment and mortality)components of tropical forest in order to minimized sample bias ? We establish a simple method to rely measurement interval between census and surface of measurement to the coefficient of variation of forests structure and dynamic components (ii) Which demographic process are involved in the explanation of biomass variation and how the biomass is distributed in the system ? The observed increase of biomass at Paracou could be link to the rarity of big trees mortality events. These big trees represent the larger part of the biomass. In the second part, we present the analysis of intra and inter-annual climate variation effects on forest dynamic changes. This part is divided in two points. (i) How to model drought stress in moist tropical forest ? We built a daily water balance model for tropical trees. (ii) Which climate variables explain the tree growth in guianian forests? We shown that soil water availability is the determinant factor of tree growth among a panel of climate variables. (iii) Which functional traits are involved in the tropical tree growth responses to climate? In this analysis, we determined that wood specific gravity, maximum tree height and tree diameter modulate the tree growth response to climate variations. http://www.theses.fr/2011AGUY0481/document | Partager |
![]() | Monnaie et inflation dans les économies en développement : Emphase sur Haïti ; Credibility and efficiency of monetary policy Auteur(s) : Labossiere, Eddy Auteurs secondaires : Antilles-Guyane Célimène, Fred Résumé : A partir de 1996 pour combattre une inflation galopante, Haïti a mis en place une politique de ciblage de la masse monétaire avec un objectif d’inflation. La forte inflation a pris naissance dans l’accumulation du déficit budgétaire et le financement monétaire de celui-ci par le seigneuriage. Cette pratique du financement par l’impôt inflationniste engendre donc un problème de crédibilité, en dépit de la double circulation monétaire caractérisée par un niveau élevé de dollarisation de l’économie qui a atteint 50% dès 2004. La politique monétaire mise en œuvre vise à éviter le biais inflationniste et différentes approches pour améliorer la crédibilité ont été considérées. La crise économique commencée en 2007 dans les pays développés, est née de l’instabilité des marchés financiers et a obligé la mise en place de politique monétaire non conventionnelle afin d’éviter la trappe de liquidité. Cette crise a donné lieu à une accumulation de réserves internationales et un faible taux d’intérêt dans les économies des pays émergents et les économies des pays sous-développés. Il devenait évident que le fondement théorique de la stratégie de politique monétaire demeure la recherche à la fois de la stabilité monétaire et la stabilité des marchés financiers afin de conserver la crédibilité et l’efficacité de la politique monétaire des banques centrales. L’utilisation abusive faite par la FED aux USA de l’assouplissement quantitatif, fait craindre une crise de la dette souveraine des Etats, la création de bulle spéculative, et un retour à la récession. Avec le cas d’Haïti, les anticipations ne sont pas rationnelles à cause des erreurs de prévisions. Une analyse jointe des taux des banques, en utilisant un modèle VECM, ne nous a pas permis de trouver un taux d’équilibre de long terme entre eux. Le test de Seo conclu que les chocs ont affecté la dynamique de ces taux. Les accords avec le FMI ont permis une très faible amélioration de l’efficacité de la politique monétaire avec l’accumulation de réserves dans la foulée de la crise qui a démarré en 2007. Since 1996 in order to fight inflation, Haiti put in place a monetary policy targeting money supply with inflation target. Inflation high gets started from budget deficit accumulation and monetary financing by seigniorage. This practice of financing by inflationary taxes implies a problem of credibility of monetary policy even with a double monetary circulation and a dollarization of the economy reaching 50% since 2004. The monetary policy implementation aims to avoid inflation bias and different approaches for improving credibility has been considered. The economic crisis started in 2007 created by the instability of the financial markets, forced the establishment of non-conventional monetary policy to avoid the liquidity trap. This crisis has resulted in an accumulation of international reserves and low interest rate in emerging economies and the economies of underdeveloped countries. It became more and more evident that the theoretical basis of the monetary policy strategy remains looking for both, monetary stability and the stability of the financial markets, in order to maintain the credibility and efficiency of the monetary policy of central banks. The misuse made by the FED in the USA of quantitative easing, rise concerns about a crisis of sovereign debt of the Sates, the creation of speculative bubble, and a possible return to the recession. With the case of Haiti, the expectations are not rationales because of forecast errors. A joint analysis of banks interests’ rates using a VECM model has not enabled us to find a long run equilibrium rate between them. The Seo test concluded that chocks affect the dynamic of both rates. The agreements with the IMF allowed improving weakly the monetary policy efficiency with the accumulation of international reserves in the wake of the crisis which started in 2007. http://www.theses.fr/2013AGUY0701/document | Partager |
![]() | Spatio-temporal variability in benthic silica cycling in two macrotidal estuaries: Causes and consequences for local to global studies Auteur(s) : Raimonet, Melanie Ragueneau, Olivier Andrieux Loyer, Francoise Philippon, Xavier Kerouel, Roger Le Goff, Manon Memery, Laurent Éditeur(s) : Academic Press Ltd- Elsevier Science Ltd Résumé : The high heterogeneity of silica cycling in coastal margins and the lack of silica data (compared to nitrogen and phosphorus) prevent the estimation of global silica retention in estuaries. In this study, the spatial and temporal variability of porewater silicic acid (Si(OH)4) profiles e that integrate benthic transport and reaction processes e was investigated at different spatial (metre, longitudinal and crosssection, intra-estuary) and temporal (tidal, seasonal) scales in two macrotidal estuaries, very close geographically but essentially differing in their shape. Studying the spatial and temporal variability of Si(OH)4 concentrations in porewaters provided evidence for the importance of transport processes, e.g. bio-irrigation, tidal pumping, resuspension and any combination of these processes, in affecting Si(OH)4 concentrations and fluxes and therefore temporary or permanent retention along the landeocean continuum. We confirm that aSiO2 (amorphous silicate) transported by rivers and estuaries clearly needs to be better characterized as it provides an important source of reactive aSiO2 to sediments. This study allows us to: (1) interrogate spatial and temporal scales, although both are most often in complete interaction; (2) design the most appropriate sampling schemes to be representative of any given system and to extrapolate at the scale of the whole estuary; (3) quantify uncertainty associated to the estimations of Si(OH)4 stocks and fluxes in this type of ecosystem, essential for budget calculations. We showed that two adjacent small macrotidal estuaries, may exhibit different behaviours regarding Si retention. Temporary retention has been observed in the meanders of the Aulne Estuary and not along the more linear Elorn Estuary, demonstrating the importance of the morphology and hydrodynamic components of the estuarine filter. Research is needed in other systems and climatic zones, but our study suggests that the typology should not only account for the different types of landeocean continuum (fjord, delta, mangrove.), but also incorporate the physical or biological attributes of the estuarine filter. Estuarine Coastal And Shelf Science (0272-7714) (Academic Press Ltd- Elsevier Science Ltd), 2013-03 , Vol. 119 , P. 31-43 Droits : 2013 Elsevier Ltd. All rights reserved. http://archimer.ifremer.fr/doc/00124/23529/22370.pdf DOI:10.1016/j.ecss.2012.12.008 http://archimer.ifremer.fr/doc/00124/23529/ | Partager |
![]() | Hf and Nd isotopes in marine sediments: Constraints on global silicate weathering Auteur(s) : Bayon, Germain Burton, K. W. Soulet, Guillaume Vigier, N. Dennielou, Bernard Etoubleau, Joel Ponzevera, Emmanuel German, C. R. Éditeur(s) : Elsevier Résumé : The combined use of Lu-Hf and Sm-Nd isotope systems potentially offers a unique perspective for investigating continental erosion, but little is known about whether, and to what extent, the Hf-Nd isotope composition of sediments is related to silicate weathering intensity. In this study, Hf and Nd elemental and isotope data are reported for marine muds, leached Fe-oxide fractions and zircon-rich turbidite sands collected off the Congo River mouth, and from other parts of the SE Atlantic Ocean. All studied samples from the Congo fan (muds, Fe-hydroxides, sands) exhibit indistinguishable Nd isotopic composition (epsilon(Nd)similar to - 16), indicating that Fe-hydroxides leached from these sediments correspond to continental oxides precipitated within the Congo basin. In marked contrast, Hf isotope compositions for the same samples exhibit significant variations. Leached Fe-hydroxide fractions are characterized by epsilon(Hf) values (from -1.1 to +13) far more radiogenic than associated sediments (from -7.1 to -12.0) and turbidite sands (from -27.2 to -31.6). epsilon(Hf) values for Congo fan sediments correlate very well with Al/K (i.e. a well-known index for the intensity of chemical weathering in Central Africa). Taken together, these results indicate that (1) silicate weathering on continents leads to erosion products having very distinctive Hf isotope signatures, and (2) a direct relationship exists between epsilon(Hf) of secondary clay minerals and chemical weathering intensity. These results combined with data from the literature have global implications for understanding the Hf-Nd isotope variability in marine precipitates and sediments. Leached Fe-hydroxides from Congo fan sediments plot remarkably well on an extension of the 'seawater array' (i.e. the correlation defined by deep-sea Fe-Mn precipitates), providing additional support to the suggestion that the ocean Hf budget is dominated by continental inputs. Fine-grained sediments define a diffuse trend, between that for igneous rocks and the,seawater array', which we refer to as the 'zircon-free sediment array' (epsilon(Hf)=0-91 epsilon(Nd)+3.10). Finally, we show that the Hf-Nd arrays for seawater, unweathered igneous rocks, zircon-free and zircon-bearing sediments (epsilon(Hf)= 1.80 epsilon(Nd)+2.35) can all be reconciled, using Monte Carlo simulations, with a simple weathering model of the continental crust. (C) 2008 Elsevier B.V. All rights reserved. Earth and Planetary Science Letters (0012-821X) (Elsevier), 2009 , Vol. 277 , N. 3-4 , P. 318-326 Droits : 2009 Elsevier B.V. All rights reserved. http://archimer.ifremer.fr/doc/2009/publication-6451.pdf DOI:10.1016/j.epsl.2008.10.028 http://archimer.ifremer.fr/doc/00000/6451/ | Partager Voir aussi Congo fan Seawater array Continental erosion Silicate weathering Hafnium isotopes Neodymium isotopes Télécharger |
![]() | Discours prononcé par M. Albert Grodet,... séances des 13 et 16 décembre 1912 : discussion générale du budget du ministère des colonies pour l'exercice 1913 Auteur(s) : Grodet, Albert (1853-1933) Année de publication : Éditeur(s) : Paris : Imprimerie des Journaux officiels Résumé : Extrait du Journal Officiel des 14 et 17 décembre 1912 Siècle(s) traité(s) : 20 Droits : Domaine public Provenance : Collectivité territoriale de Guyane. Bibliothèque Alexandre-Franconie Permalien : http://www.manioc.org/patrimon/FRA12050 FRA12050 | Partager |
![]() | Rapport sur le projet de budget de 1930, présenté au nom de la commission financière Auteur(s) : Gouvernement de la Guyane française Auteurs secondaires : Rambaud, F. Année de publication : Éditeur(s) : Cayenne : Imprimerie du gouvernement Résumé : Pas de page de titre Siècle(s) traité(s) : 20 Droits : Domaine public Provenance : Archives territoriales de Guyane Permalien : http://www.manioc.org/patrimon/GAD12014 GAD12014 | Partager |