Éditeur(s) : HAL CCSD
Résumé : International audience
The Cenozoic weathering of peninsular India has been advocated as a major driver of globalcooling, however, its timing remains virtually unconstrained such that proposed links betweentropical weathering of the Deccan Traps, regional monsoonal intensity and global climate remainsspeculative. To solve this conundrum we present here a revised weathering chronologybased on the identification of lateritic paleosurfaces and their dating using 40Ar/39Ar on supergeneK-rich manganese oxides. We focus on the Indian western passive margin where theWestern Ghats Escarpment (WGE) – a ~1000 m high topographic barrier resulting from thecontinental break up of Greater India – exposes exceptionally preserved weathering profilesfrom the western coastal lowlands to the eastern highland plateaus above the WGE. Four mainlateritic paleosurfaces have been identified: Three in the highland; a high landsurface (Al-Femostly bauxite) at elevation 1200-1000 m asl, an intermediate landsurface covered by a Feduricrustat 1000-900 m asl and a lower pediment landsurface at 850-600 m asl; and one inthe coastal lowland underneath a pediment landsurface at 150-50 m asl. The 40Ar/39Ar agesdocument three major weathering periods over the Cenozoic. The oldest weathering period(W1) is recorded between 53 Ma to 45 Ma both in the highland and the lowland. This correlatesto the Global Eocene climatic Optimum, and allows defining a bauxitic paleolandsurface acrossthe escarpment. Intense bauxitic weathering between ~ 45 and 47 Ma in the lowland indicatethat the WGE was stabilized before ~ 47 Ma on its margin and also implies low denudation rateat the foot of the WGE (<5 m Ma-1) since that time. The second weathering period between37 Ma to 19 Ma (W2) occurred in two distinctive stages (W2a and W2b). From 37 to 26 (W2a),weathering is only recorded in the highland and affect intermediate surfaces. The intensityof chemical weathering decreased sensibly between 32 and 29 Ma – potentially linked to theEarly Oligocene cooling – and resulted in the formation of the lower pediment surface. From~26 Ma to 19 Ma (W2b), only the western coastal lowland weathered while the highland surfacesare mostly dissected. This change and the highland/lowland weathering mitigation after~26 Ma documents a change in climatic patterns over peninsular India that signs the onset ofmodern-like monsoon regime. These results are being interpolated to the Deccan Traps basaltsto quantify their weathering and ultimately estimate of the contribution to CO2 fluxes of thesethree weathering periods and their potential link to Asian Monsoons and global cooling.
Source to Sink: a long term perspective of sediment budgets and sources characterization, Abstracts
Rennes, France

insu-01406455
https://hal-insu.archives-ouvertes.fr/insu-01406455

Éditeur(s) : HAL CCSD Société géologique de France
Résumé : U-Pb ages obtained from detrital zircon from terrigenous sediments are used to determine the sources. Present fluvial sand-bars of the Ogooue river yield age spectra of detrital zircons in agreement with Archean and Early Proterozoic Sources found in the drainage. The large proportion of Late Proterozoic zircons cannot be derived from primary erosion of the watershed basement rocks, since there is no formation of that age in the area. This later group of zircons is in good agreement with reworking of the aeolian Paleogene Bateke Sands, by regressive erosion in the upper reaches of the Ogooue river, as they contain a majority of Late Proterozoic age zircons. The sources of Late Proterozoic zircons in the Bateke Sand are very distant, and transported and reworked - at least in part - by aeolian processes. Our results, together with the widely distributed Paleogene sediments over continental Africa, suggests that Paleogene was it time of subdued erosion of the cratonic areas and extensive reworking, transport and deposition within continental Africa. In contrast, our results from the Ogooue river indicate active present incision of the cratonic area, erosion of the previous continental sediments, and export of the river bed-load to the continental margin. This temporal evolution of erosion-transport-deposition is correlated with the drastic climate change that occurred during the Cenozoic, leading to a more efficient mechanical erosion, and it correlates with the increase of terrigenous flux to the margin, observed during the Neogene.
EISSN: 1777-5817

hal-00411165
https://hal.archives-ouvertes.fr/hal-00411165
DOI : 10.2113/gssgfbull.179.1.29

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In pre-drift reconstructions, the central and southern parts of the Borborema Province, northeastern Brazil, belong to a large Brasiliano-Pan-African orogenic realm situated to the north of the São Francisco-Congo Craton. In order to better understand the timing and geodynamic setting under which this orogenic system developed, a structural, geochemical and geochronological study was conducted across the east Pernambuco shear zone (EPSZ) system, which separates the Pernambuco-Alagoas Domain (PEAL) from the Central Domain. A sample of the Pinhões orthogneiss (GE-1), in the Central Domain, one sample of a syenitic orthogneiss (CA-34) wrapped by the EPSZ, and one sample of orthogneiss named Altinho (CA-40), in the northern portion of the PEAL, were dated by LA-ICP-MS. The Pinhões orthogneiss yielded an age of 869 ± 9 Ma, interpreted as the emplacement age of the protolith during a late Tonian magmatic episode. Samples CA-40 and CA-34 yielded 206Pb/238U weighted mean ages of 652 ± 6 Ma and 636 ± 3 Ma, respectively, which are interpreted as dating emplacement and crystallization of the magmatic protoliths. However, it is also possible that these rocks were formed during the same magmatic event in view of the identical ages of 646 ± 13 Ma and 646 ± 11 Ma, respectively, given by the less precise upper intercept of the discordia lines. The metaluminous and magnesian nature of the Altinho orthogneiss is akin to the calc-alkalic suite. However, some samples plot in the intraplate field in tectonic discrimination diagrams and the Nd TDM model age of 1.36 Ga is unlike that of juvenile magmas in convergent settings. The Altinho orthogneiss is quite similar in terms of trace elements geochemistry to the syenitic orthogneiss, which has a clearer intraplate affinity, and the dated samples have identical initial Sr isotope ratios (0.7047). Therefore, emplacement in an extensional setting is preferred over a convergent one. Two samples of paragneisses (SB-1 and BB-9) from the PEAL were also dated. The ages of the youngest zircon grains in sample BB-9 (655–642 Ma) overlap the crystallization age of the Altinho orthogneiss, implying that sedimentation is younger than or, at best, synchronous with magmatism. The age of low Th/U grains in samples CA-34 (615 ± 8 Ma) and SB-1 (587 ± 12 Ma) are related to a subsequent metamorphic overprint, which is loosely constrained between 580 and 620 Ma. These observations, combined with evidence provided by previous studies, suggest that the change from an extensional to a contracional setting occurred at ca. 640–630 Ma. In contrast with most collisional orogens, where a long period of oceanic subduction precedes collision, the inferred tectonic evolution suggests that the Brasiliano Orogeny resulted from inversion of continental and/or proto oceanic rifts.
ISSN: 0895-9811

hal-01174182
https://hal.archives-ouvertes.fr/hal-01174182
DOI : 10.1016/j.jsames.2014.06.004

Éditeur(s) : HAL CCSD Elsevier Masson
Résumé : Reconstruction of Northern African monsoon between 6.2 and 4.9 Ma and possible relationships with Late Miocene events. Mineralogical and geochemical investigations have been realized on ODP Site 659 in order to better understand the detrital sedimentation of the Cap Verde plateau and to reconstruct African monsoon intensity variations between 6.2 and 4.9 Ma. Time intervals corresponding to an intensification of the summer African monsoon rainfall are associated to a reduction of eolian input from the Sahara and an intensification of the African river input. The reflooding of the Mediterranean Sea at the end of the Messinian salinity crisis (MSC) (5.33 Ma) is correlated to a greater aridity in the Sahara.
ISSN: 1631-0713

hal-00412151
https://hal.archives-ouvertes.fr/hal-00412151
DOI : 10.1016/j.crte.2008.07.005

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
The processes active in the deep crust above an oceanic subduction zone during its evolution have been constrained through a detailed geochemical study (major and trace elements and Sr, Nd and Pb isotopes) of representative samples through an 30 km thick exhumed crustal section of the Cretaceous Kohistan oceanic island arc (Northern Pakistan). The use of both trace elements and radiogenic isotopes reveals two distinct geochemical suites (suites A and B) within the JijalPatanKiruKamila (JPKK) complex. Suite A is characterized by a progressive enrichment in Pb-207 and a decrease in Nd-143/Nd-144 with increasing La-N/Sm-N. Suite B has higher Pb-207/Pb-204 and lower Nd-143/Nd-144 ratios with approximately constant La-N/Sm-N. By combining trace elements with different partitioning behaviour it is demonstrated that there is an increasing contribution of the subduction component in the magmas with time. It is also possible to distinguish a slab component imprint carried by aqueous fluids from one corresponding to sediment melts. Intrusive granites are abundant in the upper levels of the JPKK section. All were generated at the arc root level (Jijal crustal section) during dehydration-melting of hornblende-rich plutonic rocks. A three-stage geodynamic model is proposed for the evolution of the arc over a period of 30 Myr. The first stage (117105 Ma) starts with the onset of subduction, which was followed by the building of the volcanic arc. The second stage (10599 Ma to 9691 Ma) corresponds to a major igneous event, which was characterized by abundant magma underplating and granulite-facies metamorphism at the arc base. Recycling of the residualcumulative lower crust into the convective asthenospheric mantle was efficient during this stage, and was probably related to thermo-mechanical erosion of the base of the crust. The last stage (9585 Ma) corresponds to a period of low magmatic activity, which marked the end of the intra-oceanic subduction. This is related to the formation of a cold blanket above the slab surface as a result of thermo-mechanical erosion of the cold walls of the subduction zone (i.e. the upper part of the slab and the base of the overriding plate), and corner flow dragging the cold material into the zone of melt generation. Ultimately, a voluminous magmatic pulse occurred around 85 Ma (forming the Chilas complex), before arccontinent collision.
ISSN: 0022-3530

hal-00420068
https://hal.archives-ouvertes.fr/hal-00420068
DOI : 10.1093/petrology/egp010

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The eastern part of the Cordillera Occidental of Ecuador comprises thick buoyant oceanic plateaus associated with island-arc tholeiites and subduction-related calc-alkaline series, accreted to the Ecuadorian Continental Margin from Late Cretaceous to Eocene times. One of these plateau sequences, the Guaranda Oceanic Plateau is considered as remnant of the Caribbean–Colombian Oceanic Province (CCOP) accreted to the Ecuadorian Margin in the Maastrichtien. Samples studied in this paper were taken from four cross-sections through two arc-sequences in the northern part of the Cordillera Occidental of Ecuador, dated as (Río Cala) or ascribed to (Macuchi) the Late Cretaceous and one arc-like sequence in the Chogòn-Colonche Cordillera (Las Orquídeas). These three island-arcs can clearly be identified and rest conformably on the CCOP. In all four localities, basalts with abundant large clinopyroxene phenocrysts can be found, mimicking a picritic or ankaramitic facies. This mineralogical particularity, although not uncommon in island arc lavas, hints at a contribution of the CCOP in the genesis of these island arc rocks. The complete petrological and geochemical study of these rocks reveals that some have a primitive island-arc nature (MgO values range from 6 to 11 wt.%). Studied samples display marked Nb, Ta and Ti negative anomalies relative to the adjacent elements in the spidergrams characteristic of subduction-related magmatism. These rocks are LREE-enriched and their clinopyroxenes show a tholeiitic affinity (FeOT–TiO2 enrichment and CaO depletion from core to rim within a single crystal). The four sampled cross-sections through the island-arc sequences display homogeneous initial Nd, and Pb isotope ratios that suggest a unique mantellic source for these rocks resulting from the mixing of three components: an East-Pacific MORB end-member, an enriched pelagic sediment component, and a HIMU component carried by the CCOP. Indeed, the ankaramite and Mg-basalt sequences that form part of the Caribbean-Colombian Oceanic Plateau are radiogenically enriched in 206Pb/204Pb and 207Pb/204Pb and contain a HIMU component similar to that observed in the Gorgona basalts and Galápagos lavas. The subduction zone that generated the Late Cretaceous arcs occurred far from the continental margin, in an oceanic environment. This implies that no terrigenous detrital sediments interacted with the source at this period. Thus, the enriched component can only result from the melting of subducted pelagic sediments. We have thus defined the East-Pacific MORB, enriched (cherts, pelagic sediments) and HIMU components in an attempt to constrain and model the genesis of the studied island-arc magmatism, using a compilation of carefully selected isotopic data from literature according to rock age and paleogeographic location at the time of arc edification. Tripolar mixing models reveal that proportions of 12–15 wt.% of the HIMU component, 7–15 wt.% of the pelagic sediment end-member and 70–75 wt.% of an East-pacific MORB end-member are needed to explain the measured isotope ratios. These surprisingly high proportions of the HIMU/CCOP component could be explained by the young age of the oceanic plateau (5–15 Ma) during the Late Cretaceous arc emplacement. The CCOP, basement of these arc sequences, was probably still hot and easily assimilated at the island-arc lava source.
ISSN: 0895-9811

insu-00353692
https://hal-insu.archives-ouvertes.fr/insu-00353692
DOI : 10.1016/j.jsames.2008.06.003

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Kimberlites of the Udachnaya-East pipe (Siberia) include a uniquely dry and serpentine-free rock type with anomalously high contents of chlorine (Cl ≤ 6.1 wt%), alkalies (Na2O + K2O ≤ 10 wt%) and sulfur (S ≤ 0.50 wt%), referred to as a “salty” kimberlite. The straightforward interpretation is that the Na-, K-, Cl- and S-rich components originate directly from a carbonate-chloride kimberlitic magma that is anhydrous and alkali-rich. However, because brines and evaporites are present on the Siberian craton, previous studies proposed that the kimberlitic magma was contaminated by the assimilation of salt-rich crustal rocks. To clarify the origin of high Cl, alkalies and S in this unusual kimberlite, here we determine its sulfur speciation and isotopic composition and compare it to that of non-salty kimberlites and kimberlitic breccia from the same pipe, as well as potential contamination sources (hydrothermal sulfides and sulfates, country-rock sediment and brine collected in the area). The average δ34S of sulfides is − 1.4 ± 2.2‰ in the salty kimberlite, 2.1 ± 2.7‰ in the non-salty kimberlites and 14.2 ± 5.8‰ in the breccia. The average δ34S of sulfates in the salty kimberlites is 11.1 ± 1.8‰ and 27.3 ± 1.6‰ in the breccia. In contrast, the δ34S of potential contaminants range from 20 to 42‰ for hydrothermal sulfides, from 16 to 34‰ for hydrothermal sulfates, 34‰ for a country-rock sediment (Chukuck suite) and the regional brine aquifer. Our isotope analyses show that (1) in the salty kimberlites, neither sulfates nor sulfides can be simply explained by brine infiltration, hydrothermal alteration or the assimilation of known salt-rich country rocks and instead, we propose that they are late magmatic phases; (2) in the non-salty kimberlite and breccia, brine infiltration lead to sulfate reduction and the formation of secondary sulfides – this explains the removal of salts, alkali-carbonates and sulfates, as well as the minor olivine serpentinization; (3) hydrothermal sulfur was added to the kimberlitic breccia, but not to the massive kimberlites. In situ measurements of sulfides confirm this scenario, clearly showing the addition of two sulfide populations in the breccia (pyrite-pyrrhotites with average δ34S of 7.9 ± 3.4‰ and chalcopyrites with average δ34S of 38.0 ± 0.4‰) whereas the salty and non-salty kimberlites preserve a unique population of djerfisherites (Cl- and K-rich sulfides) with δ34S values within the mantle range. This study provides the first direct evidence of alkaline igneous rocks in which magmatic sulfate is more abundant than sulfide. Although sulfates have been rarely reported in mantle materials, sulfate-rich melts may be more common in the mantle than previously thought and could balance the sulfur isotope budget of Earth's mantle.
ISSN: 0009-2541

hal-01571982
https://hal.archives-ouvertes.fr/hal-01571982
DOI : 10.1016/j.chemgeo.2016.10.037

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We present reconstructions of late Holocene changes in the source of organic matter and siliceous export production in the Relocanví Fjord (41°S, 72°W), Northern Chilean Patagonia, based on organic carbon content, δ13Corg, N/C ratio, diatom assemblages and biogenic silica contents from three sediment cores. The age models are based on a combination of 210Pb profiles, AMS 14C dating, and on the first occurrence of the diatom Rhizosolenia setigera f. pungens, as a stratigraphic marker in the fjords. The cores span the last 300 to 700 yr. Diatoms dominate the siliceous assemblages in the three cores (98% on average). Our results suggest that precipitation seasonality in the region of Reloncaví was high in CE 1300–1400 and CE 1700–1850, with a clear decreasing trend since CE 1850. The latter trend is in agreement with instrumental records and tree-ring reconstructions. These fluctuations seem to be associated with the Southern Annular Mode (SAM).
ISSN: 0033-5894

hal-01217176
https://hal.archives-ouvertes.fr/hal-01217176
DOI : 10.1016/j.yqres.2015.05.006

Éditeur(s) : HAL CCSD Société géologique de France
Résumé : International audience
– The 300 km long allochthonous sheet of oceanic mantle forming the New Caledonia ophiolite displays three specific characters: 1) the ophiolite pile lacks concordant sheeted dykes and pillow basalt layers; 2) the ophiolite, refered to as the Peridotite nappe, is thrusted over the basaltic formations of the Poya terrane which are classicaly thought to originate from a different oceanic environment; 3) The basal contact of the ultramafic sheet is remarkably flat all along New-Caledonia and the Peridotite nappe has not been thickened during obduction, rather it experienced significant extension. This suggests that the peridotites have not been emplaced by a tectonic force applied to the rear. New petrological and geochemical results obtained from mantle rocks finally show that the Poya terrane may originate from the same oceanic basin as the peridotites. In this article, we consider such possible cogenetic links and we propose a simple model for the obduction of the New Caledonia ophiolite in which the Poya basalts represent the original cover of the Peridotite nappe. We infer that continuous uplift of the subducted units buried beneath the oceanic lithosphere in the northern part of New Caledonia drove passive uplift of the ophiolite and led to erosion and to initiation of sliding of the basaltic layer. During the Priabonian (latest Eocene), products of the erosion of the basaltic layer were deposited together with sediments derived from the Norfolk passive oceanic margin. These sediments are involved as tectonic slices into an accretionary wedge formed in response to plate convergence. The volcaniclastic sedimentation ends up with the emplacement of large slided blocks of basalts and rafted mafic units that progressively filled up the basin. Obduction process ended with the gravity sliding of the oceanic mantle sheet, previously scalped from its mafic cover. This process is contemporaneous with the exhumation of the HP-LT units of Pouebo and Diahot. Gravity sliding was facilitated by the occurrence of a continuous serpentine sole resulting from metasomatic hydratation of mantle rocks, which developed during the uplift of the Norfolk basement and overlying Diahot and Pouébo units. Progressive emersion of the obducted lithosphere allowed subsequent weathering under subaerial, tropical conditions. Obduction passive et mise en place gravitaire des grandes nappes ophiolitiques : les ophiolites de Nouvelle-Calédonie (SW Pacifique) sont-elles un cas d'école ? Résumé. – La nappe de manteau de Nouvelle-Calédonie, s'étendant sur 300 km de long montre trois caractéristiques im-portantes: 1) La succession ophiolitique ne contient ni dykes, ni basaltes en coussin, 2) l'ophiolite est charriée sur des formations basaltiques (nappe de Poya) que l'on considère classiquement comme originaires d'un bassin océanique dif-férent de celui d'où est issu le manteau, et 3) le contact basal de la nappe ultrabasique est remarquablement plat tout le long de l'île et celle-ci n'a pas été épaissie durant l'obduction. Cela suggère que les péridotites n'ont pas été mises en place en réponse à une poussée tectonique arrière. De nouveaux résultats pétrologiques et géochimiques obtenus sur l'ophiolite montrent en réalité que les basaltes de Poya peuvent être extraits de la fusion du manteau de l'ophiolite. Nous proposons donc un nouveau modèle pour l'obduction, dans lequel les basaltes de Poya forment la couver-ture initiale primitive du manteau de la nappe des péridotites. La surrection progressive des unités profondes enfouies lors de la subduction de la lithosphère du bassin sud-Loyauté à l'Eocène, a permis le soulèvement passif de l'ophiolite et l'érosion puis le glissement des unités basaltiques. Durant le Priabonien, l'accumulation des produits de l'érosion de la couche des basaltes et de la marge passive de Norfolk ont formé les séquences de flysch comprenant localement des débris basaltiques grossiers. Ces sédiments font partie d'un prisme d'accrétion tectonique construit en réponse à la convergence au front de la subduction. La sédimentation détritique se termine par la mise en place de grandes unités ba-saltiques glissées qui comblent le bassin. Le processus de l'obduction se termine par le glissement gravitaire de l'écaille de manteau océanique sur les basaltes. Cet événement est contemporain de l'exhumation des unités HP-BT de Pouébo et du Diahot. Le glissement gravitaire a été facilité par la présence sous l'ophiolite, d'une semelle continue de serpentines résultant de l'interaction du manteau avec des fluides métasomatiques remontant durant l'exhumation des unités en-fouies pendant la subduction continentale. L'émersion progressive de la lithosphère obduite a placé le manteau dans des conditions d'altération supergène tropicale.
EISSN: 1777-5817

hal-01257702
https://hal.archives-ouvertes.fr/hal-01257702
https://hal.archives-ouvertes.fr/hal-01257702/document
https://hal.archives-ouvertes.fr/hal-01257702/file/Lagabrielleetal-BSGF-2012-revised-light.pdf
DOI : 10.2113/gssgfbull.184.6.545

Éditeur(s) : HAL CCSD Elsevier
Résumé : Integrated field, LA-MC-ICP-MS geochronology and geochemical data from the Novo Oriente Group have been investigated in order to determine their provenance and possible tectonic setting. This group in the southwestern portion of the Ceara Central Domain, is a well-preserved metavolcanosedimentary sequence, in part exhalative, composed of two distinct formations. The proximal coastal Bonsucesso Formation comprises mainly quartzite and minor basic metavolcanic rocks and is in gradational contact with the distal Caranbas Formation which constitutes a metapelitic-volcanic-carbonate sequence, including metabasic rocks with pillow structure and sheared serpentinized ultrabasic rocks. The youngest detrital zircon found in the quartzite of the Bonsucesso Formation yielded an age of ca. 2.1 Ga and well-defined peaks around 2.2.2.3-2.4 and 2.5 Ga. In addition, zircons from a related metabasalt yielded an upper intercept age of 2083 +/- 28 Ma. We interpret the zircons found in this metabasalt as inherited from the host quartzite. This fact is supported by depleted-mantle Nd model ages (T-DM age) from correlated metabasic and metaultrabasic rocks from other places in the Novo Oriente sequence, which have yielded ages between 1.36 and 1.69 Ga, that is younger than the zircon age obtained in the metabasalt extruded over the Bonsucesso quartzite. Geochemical data of the metasedimentary rocks from the Caraubas Formation indicates a provenance composed of a mixture of felsic and intermediate sources typical of old stable cratons and older continental roots of active tectonic settings. The rocks of the Crania (Medio Coreau Domain) and Bacaja Complexes (southeastern Amazonian Craton) exposed to the west of the Novo Oriente Group, and largely covered by the Phanerozoic Parnaiba intracratonic basin, are the most likely source rocks. Since the precise age of the Novo Oriente Group is not yet well constrained, two distinct settings may be proposed: (1) it may represent a more evolved basin developed from extensional processes during the Mesoproterozoic (ca. 1.5-1.3 Ga); and (2) it could constitute part of the passive margin systems developed during the break-up of the Rodinia crown copyright supercontinent (ca. 0.95-0.8 Ga), associated with a pre-Brasiliano/Pan-African ocean (e.g. Pharusian Ocean). Crown.
ISSN: 1342-937X

hal-00512825
https://hal.archives-ouvertes.fr/hal-00512825
DOI : 10.1016/j.gr.2010.02.001

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In pre-drift reconstructions, the central and southern parts of the Borborema Province, northeastern Brazil, belong to a large Brasiliano-Pan-African orogenic realm situated to the north of the São Francisco-Congo Craton. In order to better understand the timing and geodynamic setting under which this orogenic system developed, a structural, geochemical and geochronological study was conducted across the east Pernambuco shear zone (EPSZ) system, which separates the Pernambuco-Alagoas Domain (PEAL) from the Central Domain. A sample of the Pinhões orthogneiss (GE-1), in the Central Domain, one sample of a syenitic orthogneiss (CA-34) wrapped by the EPSZ, and one sample of orthogneiss named Altinho (CA-40), in the northern portion of the PEAL, were dated by LA-ICP-MS. The Pinhões orthogneiss yielded an age of 869 ± 9 Ma, interpreted as the emplacement age of the protolith during a late Tonian magmatic episode. Samples CA-40 and CA-34 yielded 206Pb/238U weighted mean ages of 652 ± 6 Ma and 636 ± 3 Ma, respectively, which are interpreted as dating emplacement and crystallization of the magmatic protoliths. However, it is also possible that these rocks were formed during the same magmatic event in view of the identical ages of 646 ± 13 Ma and 646 ± 11 Ma, respectively, given by the less precise upper intercept of the discordia lines. The metaluminous and magnesian nature of the Altinho orthogneiss is akin to the calc-alkalic suite. However, some samples plot in the intraplate field in tectonic discrimination diagrams and the Nd TDM model age of 1.36 Ga is unlike that of juvenile magmas in convergent settings. The Altinho orthogneiss is quite similar in terms of trace elements geochemistry to the syenitic orthogneiss, which has a clearer intraplate affinity, and the dated samples have identical initial Sr isotope ratios (0.7047). Therefore, emplacement in an extensional setting is preferred over a convergent one. Two samples of paragneisses (SB-1 and BB-9) from the PEAL were also dated. The ages of the youngest zircon grains in sample BB-9 (655–642 Ma) overlap the crystallization age of the Altinho orthogneiss, implying that sedimentation is younger than or, at best, synchronous with magmatism. The age of low Th/U grains in samples CA-34 (615 ± 8 Ma) and SB-1 (587 ± 12 Ma) are related to a subsequent metamorphic overprint, which is loosely constrained between 580 and 620 Ma. These observations, combined with evidence provided by previous studies, suggest that the change from an extensional to a contracional setting occurred at ca. 640–630 Ma. In contrast with most collisional orogens, where a long period of oceanic subduction precedes collision, the inferred tectonic evolution suggests that the Brasiliano Orogeny resulted from inversion of continental and/or proto oceanic rifts.
ISSN: 0895-9811

hal-01174177
https://hal.archives-ouvertes.fr/hal-01174177
DOI : 10.1016/j.jsames.2014.09.007

Éditeur(s) : HAL CCSD
Résumé : International audience
The late stages of the Variscan orogeny in western and central Europe are characterized by the emplacement of numerous Carboniferous granitic intrusions. In the southern part of the Armorican massif, volcanic and plutonic rocks occur within the Carboniferous series of the Ancenis basin. Chemical analyses indicate that they belong to the same magmatic high-K calc-alkaline association of peraluminous composition, which likely derives from crustal melting of an igneous source. A LA-ICPMS U-Pb/zircon age of 319.3 ± 3.1 Ma dates, for the first time, this magmatic event and, by there, constrains the maximum age of both the end of the sedimentation and the northward tilting of the sediments in the Ancenis basin. This magmatic event is coeval with the sedimentation of the coal-bearing Namurian basins located along the Nort-sur-Erdre fault. These intrusions are interpreted as the feeding conduits of the volcano-sedimentary layers encountered in these basins. This would imply a minimal dextral displacement of ca. 20-25 km along the Nort-sur-Erdre fault.
Bulletin de la Socciété Géologique de France

insu-00656606
https://hal-insu.archives-ouvertes.fr/insu-00656606

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Almost all Red Sea deeps contain metal-rich sediments covered by brine pools. It is generally agreed that these metal-rich deposits precipitated from overlying metal-rich brines that originated from migrating hydrothermal fluids. No brine pool has ever been reported in Thetis Deep, inciting us to evaluate if such a brine layer ever occurred in the deep during the past. In order to address that questioning, a study combining mineralogical, geochemical (major-, minor-, rare-earth elements) and isotopic (Sr. Nd. Pb) approaches was completed on cored sediments and extracted interstitial waters from inside and outside the deep.;The sediments have an overall hydrothermal origin, as shown by the REE concentrations and patterns, metal contents, and Pb-Nd isotopic data, all pointing to a mantle signature. The intensity of the hydrothermal activity varied with time in the deep; the most intense episode resulting in an almost pure Fe-oxi-hydroxide layer. Varied chemical arguments, especially the Zr and REE data of the sediments, favor the fact that the whole sedimentation in Thetis Deep occurred in the absence of a stable, salt-rich and mineralized brine pool, and that no brine layer ever existed. This conclusion is supported by the constant Sr isotope composition of the sediment and its interstitial waters that are almost identical to that of the Red Sea seawater. The study also suggests that hydrothermal activity monitored fluid supplies that interacted differently with seawater in the different Red Sea deeps, resulting in an overall formation of metal-rich sediments, but along varied local conditions. (C) 2009 Elsevier B.V. All rights reserved.
ISSN: 0375-6742

hal-00475646
https://hal.archives-ouvertes.fr/hal-00475646
DOI : 10.1016/j.gexplo.2009.10.001

Éditeur(s) : HAL CCSD American Chemical Society
Résumé : 8 pages
International audience
In the protected area of the Cévennes National Park (Southern France), 114 wild brown trout (Salmo trutta fario) were captured at six locations affected to different extents by historical mining and metallurgy dating from the Iron Age to Modern Times. Cadmium and lead in trout livers and muscles reflect high sediment contamination, although an age-related effect was also detected for hepatic metal concentrations. Lead isotope signatures confirm exposure to drainage from mining and metallurgical waste. Developmental instability, assessed by fluctuating asymmetry, is significantly correlated with cadmium and lead concentrations in trout tissues, suggesting that local contamination may have affected fish development. Nowadays, the area is among the least industrialized in France. However, our results show that 60% of the specimens at one site exceed EU maximum allowed cadmium or lead concentration in foodstuffs. The mining heritage should not be neglected when establishing strategies for long-term environmental management.
ISSN: 0013-936X

hal-00621255
https://hal.archives-ouvertes.fr/hal-00621255
DOI : 10.1021/es200755n
PUBMED : 21739978