Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Sedimentary rocks and detrital minerals sample large areas of the continental crust, and they are increasingly seen as a reliable archive for its global evolution. This study presents two approaches to model the growth of the continental crust through the sedimentary archive. The first builds on the variations in U-Pb, Hf and O isotopes in global databases of detrital zircons. We show that uncertainty in the Hf isotope composition of the mantle reservoir from which new crust separated, in the 176Lu/177Hf ratio of that new crust, and in the contribution in the databases of zircons that experienced ancient Pb loss(es), adds some uncertainty to the individual Hf model ages, but not to the overall shape of the calculated continental growth curves. The second approach is based on the variation of Nd isotopes in 645 worldwide fine-grained continental sedimentary rocks with different deposition ages, which requires a correction of the bias induced by preferential erosion of younger rocks through an erosion parameter referred to as K. This dimensionless parameter relates the proportions of younger to older source rocks in the sediment, to the proportions of younger to older source rocks present in the crust from which the sediment was derived. We suggest that a Hadean/Archaean value of K = 1 (i.e., no preferential erosion), and that post-Archaean values of K = 4–6, may be reasonable for the global Earth system. Models built on the detrital zircon and the fine-grained sediment records independently suggest that at least 65% of the present volume of continental crust was established by 3 Ga. The continental crust has been generated continuously, but with a marked decrease in the growth rate at ~ 3 Ga. The period from > 4 Ga to ~ 3 Ga is characterised by relatively high net rates of continental growth (2.9–3.4 km3 yr− 1 on average), which are similar to the rates at which new crust is generated (and destroyed) at the present time. Net growth rates are much lower since 3 Ga (0.6–0.9 km3 yr− 1 on average), which can be attributed to higher rates of destruction of continental crust. The change in slope in the continental growth curve at ~ 3 Ga is taken to indicate a global change in the way bulk crust was generated and preserved, and this change has been linked to the onset of subduction-driven plate tectonics. At least 100% of the present volume of the continental crust has been destroyed and recycled back into the mantle since ~ 3 Ga, and this time marks a transition in the average composition of new continental crust. Continental crust generated before 3 Ga was on average mafic, dense, relatively thin (< 20 km) and therefore different from the calc-alkaline andesitic crust that dominates the continental record today. Continental crust that formed after 3 Ga gradually became more intermediate in composition, buoyant and thicker. The increase in crustal thickness is accompanied by increasing rates of crustal reworking and increasing input of sediment to the ocean. These changes may have been accommodated by a change in lithospheric strength at around 3 Ga, as it became strong enough to support high-relief crust. This time period therefore indicates when significant volumes of continental crust started to become emergent and were available for erosion and weathering, thus impacting on the composition of the atmosphere and the oceans.
ISSN: 0037-0738

hal-01622696
https://hal.archives-ouvertes.fr/hal-01622696
DOI : 10.1016/j.sedgeo.2017.06.001

Éditeur(s) : Elsevier
Résumé : Dissolved and particulate Hg fluxes in the Lot-Garonne-Gironde fluvial-estuarine system were obtained from observation of daily discharge and suspended particulate matter (SPM) concentrations. In addition to the measurements of the total dissolved (< 0.45 gm) and particulate Hg (> 0.45 gm), called HgTD and HgTp respectively, the dissolved inorganic Hg species (HgRD) were determined monthly. Geochemical background values for HgTp in sediments and SPM were similar to crustal values and to typical concentrations in SPM of non-contaminated river systems, respectively. The Riou Mort watershed already known as the origin of important historical polymetallic (e.g., Cd, Zn) pollution was identified as an important Hg point source. In the downstream Lot River, Hg concentrations were clearly higher than those in other moderately contaminated systems. The mean relative contribution of HgRD to HgTD in the Lot River and in the Garonne River was close to 25% and 50%, respectively, and showed no correlation with water discharge or SPM concentration. Depending on the origin and nature of SPM, HgTp concentrations were correlated or not with particulate organic C (POC). Maximum HgTp concentrations were measured in samples containing low POC concentrations and were attributed to sediment resuspension. In contrast, high POC concentrations (6-17%) during algal blooms were associated with low/moderate HgTp concentrations (< 0.5 mg kg(-1)) at different sites, suggesting that Hg concentrations in fluvial phytoplankton may be limited by bioavailability of dissolved Hg and/or physiologically controlled Hg accumulation. Mercury was mostly (up to 98%) transported in the particulate phase with estimated annual Hg fluxes at the outlet of the Lot River system ranging from 35 to 530 kg a(-1) for the past decade. The minimum anthropogenic component (58-84% of total Hg fluxes) could not be explained by present Riou Mort point source contributions, suggesting important Hg release from contaminated sediment as a major source and from downstream point sources (e.g., coal-fired power plants and/or metal processing industries). HgTp concentrations and fluxes were strongly related to hydrologic variations and were clearly increased by riverbed dredging during lock construction. Therefore, the estimated Hg stocks in the Lot River sediment (5-13 tons) represent an important potential Hg source for the downstream fluvial-estuarine system.
Applied Geochemistry (0883-2927) (Elsevier), 2006-03 , Vol. 21 , N. 3 , P. 515-527

Droits : 2006 Elsevier Ltd All rights reserved
http://archimer.ifremer.fr/doc/2006/publication-1343.pdf
DOI:10.1016/j.apgeochem.2005.12.004
http://archimer.ifremer.fr/doc/00000/1343/

Éditeur(s) : HAL CCSD University of Arizona
Résumé : International audience
Taiwan is a young and seismically active mountain belt, where a series of strong earthquakes (M>7) have occurred over the past hundred years. Identifying historical earthquakes around Taiwan is a key to better constrain the geodynamic of this active region. Sedimentological and geochemical analyses of surface sediments from one station offshore east Taiwan revealed the presence of coarse-grained layers interpreted as turbidites. The age of these layers have been determined by 210Pb, 137Cs, and 241Am chronology. Dating of the three most recent turbidites provides ages of AD 2001±3, AD 1950±5, and AD 1928±10. The results show striking temporal correspondence of turbidite layers to large (M≥6.8) earthquakes recorded in the region since the 20th century. The chronologies of sediment layers lead us to believe that turbidites resulted from the 2003 Taitung earthquake (M 6.8), the 1951 Chengkong earthquake (M 7.1), and the 1935 Lutao earthquake (M 7.0), respectively. Such a good correlation between turbidites and high-magnitude (M≥6.8) historical and instrumental seismic events suggests that turbidite paleoseismology constitutes a valuable tool for earthquake assessment in the eastern Taiwan margin. Moreover, the modern reservoir radiocarbon age and the regional marine reservoir correction (ΔR) of the Kuroshio Current off Taiwan were estimated by comparing accelerator mass spectrometry (AMS) 14C ages with ages derived from corrected 210Pb profiles and historical accounts of identifiable seismic events. Such a determination is important to calibrate the 14C ages of marine materials for accurate comparison of marine and continental geological records. Our calculated mean ΔR value of 232±54 14C yr (n=2) is higher than its modern value of 86±40 14C yr. This high value can be explained by the presence of local upwelling cells and turbulence in the Kuroshio Current, north of Green Island. These upwelling cells bring 14C-depleted water to the surface, resulting in an increase of the modern ΔR value in this portion of the Kuroshio Current.
ISSN: 0033-8222

hal-01306986
https://hal.archives-ouvertes.fr/hal-01306986
DOI : 10.1017/RDC.2015.3

Éditeur(s) : Elsevier
Résumé : We report on a multidisciplinary study of cold seeps explored in the Central Nile deep-sea fan of the Egyptian margin. Our approach combines in situ seafloor observation, geophysics, sedimentological data, measurement of bottom-water methane anomalies, pore-water and sediment geochemistry, and Th-230/U dating of authigenic carbonates. Two areas were investigated, which correspond to different sedimentary provinces. The lower slope, at similar to 2100 m water depth, indicates deformation of sediments by gravitational processes, exhibiting slope-parallel elongated ridges and seafloor depressions. In contrast, the middle slope, at similar to 1650 m water depth, exhibits a series of debris-flow deposits not remobilized by post-depositional gravity processes. Significant differences exist between fluid-escape structures from the two studied areas. At the lower slope, methane anomalies were detected in bottom-waters above the depressions, whereas the adjacent ridges show a frequent coverage of fractured carbonate pavements associated with chemosynthetic vent communities. Carbonate U/Th age dates (similar to 8 kyr BP), pore-water sulphate and solid phase sediment data suggest that seepage activity at those carbonate ridges has decreased over the recent past. In contrast, large (similar to 1 km(2)) carbonate-paved areas were discovered in the middle slope, with U/Th isotope evidence for ongoing carbonate precipitation during the Late Holocene (since similar to 5 kyr BP at least). Our results suggest that fluid venting is closely related to sediment deformation in the Central Nile margin. It is proposed that slope instability leads to focused fluid flow in the lower slope and exposure of 'fossil' carbonate ridges, whereas pervasive diffuse flow prevails at the unfailed middle slope.
Marine Geology (0025-3227) (Elsevier), 2009-06 , Vol. 261 , N. 1-4 , P. 92-104

Droits : 2009 Elsevier B.V. All rights reserved.
http://archimer.ifremer.fr/doc/2009/publication-6586.pdf
DOI:10.1016/j.margeo.2008.10.008
http://archimer.ifremer.fr/doc/00000/6586/

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Multi-proxy analysis of two marine sediment cores (MS27PT and MD04-2726) from the Nile continental slope provides evidence of changes in Nile sediment discharge related to changes in Ethiopian African Monsoon (EAM) precipitation, and allows us to reconstruct changes in Nile River runoff, vegetation and erosion in the Nile headwaters. Sediment element composition and neodymium isotopic composition reveal significant changes in clastic sediment provenance, with sources oscillating between a Saharan aeolian contribution during the Last Glacial Maximum/deglacial transition and during the Late Holocene, and a Blue/Atbara Nile fluvial contribution during the African Humid Period (AHP). This study provides a new understanding of past environmental changes. Between 14.6 and 14.13 ka there was a major input of sediments from the Ethiopian Highlands, consistent with a stronger EAM at that time. Climate in the Nile basin was wetter between 14.8 and 8.4 ka, with a corresponding increase in Blue Nile water and sediment discharge via the main Nile into the Eastern Mediterranean. The gradual climatic transition from the AHP to the present-day dry climate was reflected in a decrease in Blue Nile sediment deposition and flood discharge between 8.4 and 3.7 ka, with aridity at a maximum between 3.7 and 2.6 ka. The onset of drier conditions in the Blue Nile basin seems to have begun before the 8.2 ka cooling event in the North Atlantic. We speculate that the climatic change from the wet AHP to the dry late Holocene may have been a result of a break in the low latitude dynamic equilibrium between climate, vegetation and erosion, which may in turn have affected the climate in higher latitudes. Reduced Nile flow may also have had an impact on Levantine Intermediate Water originating in the Eastern Mediterranean through an increase in intermediate water formation.
ISSN: 0277-3791

hal-01277950
https://hal.archives-ouvertes.fr/hal-01277950
DOI : 10.1016/j.quascirev.2015.10.030

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Recent geochemical work shows that subduction-zone serpentinites are repositories for fluid-mobile elements absorbed during interaction with sediment-derived fluids. Unraveling the geochemical fingerprint of these rocks helps to define timing of tectonic accretion of sediments along the subduction interface and the role of serpentinite in element recycling to volcanic arcs. Here we present the trace element and isotopic composition (B–O–H, Sr, Pb) of high-pressure serpentinites from the Voltri Massif (Ligurian Western Alps, Italy), to discuss their role as incompatible element carriers and their contribution to recycling of sediment-derived components in subduction zones.The serpentinites presented here record metamorphic olivine growth during eclogite-facies metamorphism and show undeformed and mylonitic textures. Field relations show that undeformed rocks are enclosed in deformed ones and that no metasedimentary rocks are present nearby. Undeformed serpentinite has very high δ11BSRM951 (from +26‰ to +30‰), low Sr and Pb isotope ratios (87Sr/86Sr = 0.7053–0.7069; 206Pb/204Pb = 18.131–18.205) and low As and Sb contents (0.1 and 0.01 μg/g, respectively). Oxygen and hydrogen isotope compositions are +4.5‰ and −67‰, respectively. In contrast, mylonitic serpentinite shows lower δ11B (from +22‰ to +17‰), significant enrichment in radiogenic Sr and Pb isotopes (87Sr/86Sr up to 0.7105; 206Pb/204Pb up to 18.725), and enrichment in As and Sb (1.3 and 0.39 μg/g, respectively). δ18O of the mylonitic serpentinites reaches values of +5.9‰, whereas δD is comparable with that of undeformed rocks (approximately −70‰). In mylonitic serpentinites, the B and Sr isotopic values and the fluid-mobile element (FME) concentrations are near those for the Voltri metasedimentary rocks (calc- and mica-schists). Pb systematics also reveal influx of a crust-derived component.Our dataset shows that undeformed serpentinite still preserves an oceanic geochemical fingerprint, whereas mylonitic serpentinite is reset in its concentrations of FME and its B, Sr and Pb isotope compositions, due to interaction with sediment- and crust-derived fluids. The environment of this interaction is either compatible with (i) an outer-rise zone setting, with percolation of seawater-derived fluids enriched in sedimentary components into bending-related fault structures, or with (ii) subduction channel domains, where ascending sediment-derived slab fluids infiltrate slices of former oceanic serpentinite accreted to the plate interface domain. Influx of sediment-derived subduction fluids along major deformation zones in serpentinite modifies the element budget of the rocks, with important implications for element recycling and the tectonic history of serpentinite. The B, Sr and Pb isotopic systematics, coupled with FME concentration in serpentinites are particularly helpful geochemical tracers of interaction between different reservoirs in subduction-interface environments, and are more sensitive than the traditionally applied stable oxygen and hydrogen isotope compositions.
ISSN: 0016-7037

hal-01419940
https://hal.archives-ouvertes.fr/hal-01419940
DOI : 10.1016/j.gca.2016.06.034

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Serpentinites form by hydration of mantle peridotite and constitute the largest potential reservoir of fluid-mobile elements entering subduction zones. Isotope ratios of one such element, boron, distinguish fluid contributions from crustal versus serpentinite sources. Despite 85% of boron hosted within abyssal peridotite being lost at the onset of subduction at the lizardite-to-antigorite transition, a sufficient cargo of boron to account for the composition of island arc magma is retained (c. 7 μg g− 1, with a δ11B of + 22‰) until the down-going slab reaches the antigorite-out isograd. At this point a 11B-rich fluid, capable of providing the distinctive δ11B signature of island arc basalts, is released. Beyond the uniquely preserved antigorite-out isograd in serpentinites from Cerro del Almirez, Betic Cordillera, Spain, the prograde lithologies (antigorite–chlorite–orthopyroxene–olivine serpentinite, granofels-texture chlorite-harzburgite and spinifex-texture chlorite-harzburgite) have very different boron isotope signatures (δ11B = − 3 to + 6‰), but with no significant difference in boron concentration compared to the antigorite-serpentinite on the low P–T side of the isograd. 11B-rich fluid, which at least partly equilibrated with pelagic sediments, is implicated in the composition of these prograde lithologies, which dehydrated under open-system conditions. Serpentinite-hosted boron lost during the early stages of dehydration is readily incorporated into forearc peridotite. This, in turn, may be dragged to sub-arc depths as a result of subduction erosion and incorporated in a mélange comprising forearc serpentinite, altered oceanic crust and pelagic sediment. At the antigorite-out isograd it dehydrates, thus potentially providing an additional source of 11B-rich fluids.
ISSN: 0009-2541

hal-01172276
https://hal.archives-ouvertes.fr/hal-01172276
DOI : 10.1016/j.chemgeo.2014.03.015

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
This study presents the geochemical composition of superficial sediment under oxic and suboxic bottom water conditions along the Chilean continental margin (SE Pacific), where evidence for benthic chemosynthetic activity associated with diffuse seeping of chemically reduced fluids has been reported. The exploration was carried out at: (1) the Chilean Triple Junction (CTJ), at a water depth of ∼2900 m, with the additional indication of hydrothermal activity near a methane-rich cold-seep area (46°S) (German et al., 2010); and (2) the El Quisco methane seep site (EQSS), at ∼340 m water depth (33°S) (Melo et al., 2007; Krylova et al., 2014). While the deeper CTJ is located within an oxic environment (dissolved oxygen in the bottom waters: 164 μM), the shallower EQSS lies within a suboxic environment (dissolved oxygen in bottom water: 23 μM), located within the lower limit of the SE Pacific oxygen minimum zone (OMZ).Pore water from short cores was analyzed for dissolved major, minor, and trace elements (Cl, Na, Mg, K, Ca, Sr, Si, B, P, Ba, Pb, Mn, Fe, Cd, U, and Mo), δ13DIC, sulfide, sulfate, and methane. The solid sediment fraction was likewise analyzed for total organic carbon (TOC), metals, and redox potential. Elevated sediment temperatures were found in superficial sediments (5–13 °C) at the CTJ site, which could be due to warm fluids associated with the proximity of the ridge, where hydrothermal vents may occur. Reduced fluids were also present here, indicated by higher Mn fluxes toward the water column even in oxidized sediments (RPD > 8 cm), which contrasted with the lower fluxes in reduced sediments of the EQSS site (RPD ∼ 2 cm). 13C-depleted DIC, anomalously low pore water Cl (∼15 ppb), and low concentrations of other major elements may be the result of dilution by fluid seeping and precipitation of major elements, producing authigenic enrichment (Ca, Mg, Sr). The fluid could also: (a) be diluted by pure water produced during methane hydrate dissociation, as observed in other cold-seep areas; and (b) correspond to clay mineral dehydration, as reported in plate subduction systems. The reducing conditions established at the CTJ conduct the Cd enrichment at a similar magnitude of that seen at the shallower suboxic site (EQSS). Evidence of chimney or vent fauna was not observed. At the EQSS, higher TOC and total sulfide contents were consistent with enhanced deposition of organic matter and reducing conditions developed in the OMZ, favoring the authigenic enrichment of Cd, U and Pb. The geochemical evidence, based only on methane concentrations and δ13DIC, is insufficient to establish the presence of methane seeps, as previously reported.
ISSN: 0079-6611

hal-01412700
https://hal.archives-ouvertes.fr/hal-01412700
DOI : 10.1016/j.pocean.2016.09.002

Éditeur(s) : HAL CCSD Springer
Résumé : The analysis of three different regions of the South- Pyrenean fold-and-thrust belt reveals that during the Tertiary compression the hydrological system was compartmentalised in time and space. During the early-middle Eocene, when the thrust front affected marine soft-sediments in the Ainsa basin, the thrust fault zones were dominated by formation fluids derived from Eocene marine waters trapped in the underlying Eocene marls, although influences of meteoric waters were also present. During the middle-late Eocene, when the thrust front emplaced marine rocks over continental redbeds in the eastern Catalan basin (L'Escala thrust), the thrust fault zones were dominated by meteoric fluids. These fluids flowed preferentially along these faults, draining laterally the meteoric fluids and acting as barriers hindering their flowing towards more external parts of the belt. During the Oligocene, the most external part of the fold-and-thrust belt in the eastern Catalan basin developed on top of a salt detachment horizon. The thrust front affected continental materials of late Eocene-Oligocene age. At this moment, the thrusts were conduits for meteoric fluids arriving from the surface and also for evolved meteoric fluids migrating over short distance upwards after being in contact with the underlying evaporitic beds. Most of the fractures show a similar sequence of microfractures. Microfractures of stage 1 formed when the sediment was poorly lithified. Microfractures of stage 2 represent the main episode of vein formation which developed when a progressive induration of the host sediment occurred. During microfracture stage 3, formed in an extensional regime, the host sediment was more indurated. The repetition of this sequence of microfractures in different fracture generations of the same outcrop indicates that the sediment induration was restricted to the vicinity of the vein. Away from the veins, the sediment remained poorly lithified during the entire deformation cycle. Calcite cement within the host rock precipitated later than the syn-compressive veins, when the sediment was more indurated. Elemental geochemistry and stable isotopes of the calcite veins indicates that early generation of microfractures is infilled by local fluids (either marine or meteoric), whereas external fluids (meteoric or evolved meteoric) infilled the main compressive stage of microfractures. The hot temperature of these fluids (157°C to 183°C in the Atiart-Arro example) indicates their circulation through deep parts of the thrust belt. The progressive increase of the 87Sr/86Sr ratio through time is due to the progressive uplift, exposure and erosion of the internal Pyrenean Axial Zone.
Thrust belts and foreland basins, from fold kinematics to hydrocarbon systems

hal-00408001
https://hal.archives-ouvertes.fr/hal-00408001
DOI : 10.1007/978-3-540-69426-7_5

Éditeur(s) : HAL CCSD American Geophysical Union (AGU)
Résumé : International audience
Apatite fission track analysis (AFTA) data are used to bring new light on the long-term and recent history of the Baikal rift region (Siberia). We describe the evolution of the topography along a NW-SE profile from the Siberian platform to the Barguzin range across the Baikal-southern Patom range and the northern termination of Lake Baikal. Our results show that the Baikal-Patom range started to form in the Early Carboniferous and was reactivated in Middle Jurassic-Lower Cretaceous times during the orogenic collapse of the Mongol-Okhotsk belt. Samples located in the Siberian platform recorded a continuous sedimentation up to the early Carboniferous but remain unaffected by later tectonic episodes. The Barguzin basin probably started to form as early as Late Cretaceous, suggesting a continuum of deformation between the postorogenic collapse and the opening of the Baikal Rift System (BRS). The initial driving mechanism for the opening of the BRS is thus independent from the India-Asia collision. AFTA show a late Miocene-early Pliocene increase in tectonic extension in the BRS that confirms previous thoughts and might reflect the first significant effect of the stress field generated by the India-Asia collision.
ISSN: 0278-7407

hal-00420895
https://hal.archives-ouvertes.fr/hal-00420895
DOI : 10.1029/2008TC002404

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The paleostorm history of coastal lagoon environments (Pierre Blanche Lagoon, central part of the Gulf of Lions) has been established by integrating clay mineralogy and geochemical analysis. Clay mineralogy combined with bulk major and trace elements concentrations allow for the definition of four different end members: the Mosson drainage basin, the sandy barrier, the biogenic and the anthropic components. The two main sedimentary sources of the lagoonal system are the Mosson drainage basin which has a high concentration of smectite and Al2O3, and the sandy barrier characterized by high contents of illite, chlorite, SiO2 and Zr. Smectite/(illite + chlorite), SiO2/Al2O3 and Zr/Al2O3 ratios can be used to reconstruct the past storm history of the Pierre Blanche Lagoon. Our results indicate that the sensitivities of the clay mineralogy and geochemistry proxies are different. These sensitivities could be related: 1) first, to the comparison between different grain size for geochemistry and for clay mineralogy: 2) second, to the complexity of the mix (four end-members for the geochemistry and two end-members for the clay minerals): and 3) third, by the storm's ability to transport sediment of different sizes. (C) 2010 Elsevier B.V. All rights reserved.
ISSN: 0037-0738

hal-00512614
https://hal.archives-ouvertes.fr/hal-00512614
DOI : 10.1016/j.sedgeo.2010.04.012

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We provide new insights into the geochemistry of serpentinites from the Alpine orogenic wedge representing a paleo-subduction zone. These serpentinites are derived from similar oceanic protoliths, but they have experienced different metamorphic conditions related to three different structural levels of the paleo-subduction zone ((1) obducted: Chenaillet ophiolite, (2) accretionary wedge: Queyras Schistes lustrés complex and (3) serpentinite channel: Monviso ophiolite). Metamorphism undergone by these three units is well defined, increasing eastward from sub-greenschist to eclogite facies conditions, and allows us to examine trace element behavior from the oceanic ridge environment to subduction. Serpentinites first record moderate trace element enrichment due to seawater interaction resulting in the replacement of olivine and pyroxene by chrysotile and lizardite below 300 °C. In the sediment-dominated accretionary wedge, serpentinites are strongly enriched in fluid-mobile-elements (B, Li, As, Sb, and Cs) and act as a trapping system following the metamorphic gradient (from 300 to 390 °C) up to total replacement of the lizardite/chrysotile assemblage by antigorite. Under higher temperature conditions (T > 390 °C), no enrichment was observed, and some fluid-mobile elements were released (B, Li, Cs, and Sr). Moreover, in the serpentinite channel (T > 460 °C), most of the fluid-mobile elements are absent due to the scarcity of metasediments which prevent geochemical exchange between metasediments and serpentinites. This is also due to the onset of antigorite breakdown and the release of fluid-mobile elements. Thus, we emphasize that the geochemistry of Alpine serpentinites is strongly dependent on (1) the grade of metamorphism and (2) the ability of metasediments to supply fluid-mobile elements. We conclude that serpentinites act as a trap-and-release system for fluid-mobile elements in a subduction context.
ISSN: 0009-2541

hal-00996839
https://hal.archives-ouvertes.fr/hal-00996839
DOI : 10.1016/j.chemgeo.2013.02.008

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The active collision zone around Taiwan orogen receives a variety of sedimentary inputs, including terrigenous flux from Taiwan and Chinese rivers, oceanic currents and atmospheric dust. In order to determine the present-day respective contributions of these different sources, we analysed the Pb and Sr isotopic compositions of late Quaternary sediments accumulated offshore east Taiwan. Samples from the Taiwan Coastal Range (andesites, sandstones, conglomerate and Peinan River terraces and suspended loads) have also been analysed to constrain the mean Taiwan isotopic signature. Mixing lines between the different sources of material indicate that the core located in the Okinawa Trough represents a mixture of about 60% of Taiwan, 30% of Chinese Loess and 10% of Yangtze River contributions. The southernmost core, located close to Luzon Are, is influenced by Taiwan (60%) and volcanic material (40%). The Sr and Pb isotopic compositions of samples cored in the Manila Trench and in the Huatung Basin are strongly influenced by the Taiwan signature, while the Ryukyu Trench core samples point to significant but variable contributions of Chinese Loess and Yangtze River. This work also reports Zn isotopic variations in the silicate fraction of these marine core samples. The overall variation in Zn isotopic compositions (expressed as 666 Zn) is greater than 0.3 per mil (parts per thousand) for an analytical precision of +/- 0.05 parts per thousand. The Zn isotopic signal for most of the marine core samples is similar to the literature data measured on sedimentary material, except for the Manila Trench core samples and the older sample from the Huatung Basin: they present values heavier by 0.2-0.3 parts per thousand, close to those obtained on all Taiwan rocks and Peinan River particulates. These results show: 1- the particular characteristics of Taiwan Zn isotopic compositions on a large scale; and: 2- the possible use of Zn isotopes as a tracer of material sources.
ISSN: 0009-2541

hal-00412214
https://hal.archives-ouvertes.fr/hal-00412214
DOI : 10.1016/j.chemgeo.2007.10.024

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
A high-resolution record of paleostorm events along the French Mediterranean coast over the past 7000 years was established from a lagoonal sediment core in the Gulf of Lions. Integrating grain size, faunal analysis, clay mineralogy and geochemistry data with a chronology derived from radiocarbon dating, we recorded seven periods of increased storm activity at 6300-6100, 5650-5400, 4400-4050, 3650-3200, 2800-2600, 1950-1400 and 400-50 cal yr BP (in the Little Ice Age). In contrast, our results show that the Medieval Climate Anomaly (1150-650 cal yr BP) was characterised by low storm activity.;The evidence for high storm activity in the NW Mediterranean Sea is in agreement with the changes in coastal hydrodynamics observed over the Eastern North Atlantic and seems to correspond to Holocene cooling-in the North Atlantic. Periods of low SSTs there may have led to a stronger meridional temperature gradient and a southward migration of the westerlies. We hypothesise that the increase in storm activity during Holocene cold events over the North Atlantic and Mediterranean regions was probably due to an increase in the thermal gradient that led to an enhanced lower tropospheric baroclinicity over a large Central Atlantic-European domain. (C) 2011 University of Washington. Published by Elsevier Inc. All rights reserved.
ISSN: 0033-5894

hal-00760909
https://hal.archives-ouvertes.fr/hal-00760909
DOI : 10.1016/j.yqres.2011.09.002

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Blake excursion was among the first recognized with directional and intensity behavior known mainly from marine sediment and Chinese loess. Age estimates for the directional shifts in sediments are poorly constrained to about 118−100 ka, i.e., at the marine isotope stage (MIS) 5e/5d boundary. Moreover, sediments at Lac du Bouchet maar, France and along the Portuguese margin reveal what may be a "post-Blake" excursion at about 105−95 ka. The excursional directions are associated with a prominent paleointensity minimum between about 125 and 95 ka in global stacked records. Lava flow recordings of the Blake excursion(s) have, however, been questionable because precise ages required for correlation with these sediment records are lacking. To establish new, independent records of the Blake excursion, and link these into a larger Quaternary GITS, we have undertaken 40Ar/39Ar incremental heating and unspiked K-Ar experiments on groundmass from the transitionally magnetized Inzolfato flow on Lipari Island. We also obtained 40Ar/39Ar incremental heating results for a lava flow on Amsterdam Island originally thought to record the Mono Lake excursion and from the transitionally magnetized El Calderon basalt flow, New Mexico that was K-Ar dated by Champion et al. (1988) at 128 ± 66 ka. Unspiked K-Ar ages of four samples from the Inzolfato flow are 102.5 ± 4.7, 101.3 ± 3.3, 97.1 ± 2.6, and 96.8 ± 3.1 ka and thus indistinguishable from one another. 40Ar/39Ar results are more complex, with three samples yielding discordant age spectra. Based on incremental heating data obtained in both the UW-Madison and Gif-sur-Yvette 40Ar/39Ar laboratories, a fourth sample yields six concordant age plateaus and a weighted mean age of 105.2 ± 1.4 ka that we take as the best estimate of time since the flow erupted. Five 40Ar/39Ar incremental heating experiments on the Amsterdam Island lava yield a plateau age of 120 ± 12 ka, whereas ages from two sites in the Calderon flow are 112 ± 23 and 101 ± 14 ka, together giving a weighted mean of 104 ± 12 ka. The age of 120 ± 12 ka from Amsterdam Island, though imprecise, correlates with the Blake excursion. In contrast, the 104-105 ka age obtained from both Lipari and New Mexico indicates that these lavas record a younger period of dynamo instability, most probably associated with the post-Blake excursion. These radioisotopic ages are consistent with the astronomical ages of two paleointensity minima in the PISO-1500 global stack. Our findings indicate that the Blake and post-Blake excursions are both global features of past geodynamo behavior and support the hypothesis that Brunhes chron excursions are temporally clustered into two groups of at least a half-dozen each spanning over 220 to 30 ka and 720 to 520 ka.
ISSN: 1871-1014

hal-01054336
https://hal.archives-ouvertes.fr/hal-01054336
DOI : 10.1016/j.quageo.2012.12.005

Éditeur(s) : Actes de colloques. Ifremer. Brest [ACTES COLLOQ. IFREMER.]. 1986
Résumé : Five topics are developed in this synthesis: (1) multi elements analysis in geochemistry; (2) iron geochemical behavior; (3) complexing properties of waters; (4) copper behavior in estuarine waters; (5) impact of sediment dynamics on dissolved metals concentration.

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/1985/acte-1290.pdf
http://archimer.ifremer.fr/doc/00000/1290/

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Trace metals (Cd, U, Co, Ni, Cu, Ba, Fe, Mn), total organic carbon (TOC) and C and N stable isotope signatures (delta C-313 and delta N-15) were determined in short sediments cores from the inner and outer shelf off Concepcion, Chile (similar to 36 degrees S). The objectives were to establish the effect of environmental conditions on trace metal distributions at two shelf sites, one affected by seasonal oxygenation and the other by permanent low oxygen conditions due to the presence of the oxygen minimum zone (OMZ). We evaluate trace metals as proxies of past changes in primary productivity and the bottom water oxygen regime. Concentrations of pore water sulfides and NH4+ were also measured as indicators of the main diagenetic pathways at each site. Our results for the inner shelf (seasonal suboxia) suggest that the oxidative state of the sediments responds to seasonal pulses of organic matter and that seasonal oxygenation develops during high and low primary productivity in the water column. Here, positive fluxes (to the water column) estimated from pore water concentrations of several elements were observed (Ba, Co, Ni, Fe and Mn). The less reduced environment at this site produces authigenic enrichment of Cu associated with the formation of oxides in the oxic surface sediment layer, and the reduction of U within deeper sediment sections occur consistently with negative estimated pore water fluxes. In the outer shelf sediments (permanent suboxia, OMZ site), negative fluxes (to the sediment) were estimated for all elements, but these sediments showed authigenic enrichments only for Cd, Cu and U. The short oxygenation period during the winter season did not affect the accumulation of these metals on the shelf. The distribution of Cu, Cd and U have been preserved within the sediments and the authigenic accumulation rates estimated showed a decrease from the deep sections of the core to the surface sediments. This could be explained by a gradual decrease in the strength of the OMZ in the last 100 years, in combination with periods of strong oxygenations during El Nino events. (C) 2011 Elsevier Ltd. All rights reserved.
ISSN: 0278-4343

hal-00745672
https://hal.archives-ouvertes.fr/hal-00745672
DOI : 10.1016/j.csr.2011.11.006

Éditeur(s) : Amer Geophysical Union
Résumé : In this study, we undertook a reconnaissance study of sediments provenance in the Gulf of Lions focusing over the last 16 ka. We used geochemical and isotopic tracers to determine the source of sediments and give insight into the weathering conditions prevailing. Sediments samples were selected both onshore and offshore from the western, eastern, and central part of the Gulf of Lions. We analyzed bulk sediments, coarse and fine silt, and clay fractions. Elemental and Nd isotope compositions appeared to differ from one grain size fraction to another one. These are interpreted in terms of zircon addition in the coarse silt fraction for the elemental concentrations and variable sources influences for the Nd isotope compositions. Our results indicate that sediments in the Gulf of Lions mainly originated from the Rhone River watershed although a contribution of Saharan dust is seen in one sample. Influence of Pyrenean small rivers is minor in these samples. Some Sr isotope compositions shifts are interpreted as reflecting variable amounts of chemical weathering that are consistent with published paleoclimatic reconstructions.
Geochemistry Geophysics Geosystems (1525-2027) (Amer Geophysical Union), 2011-08 , Vol. 12 , N. Q08006 , P. 20 p.

Droits : 2011 by the American Geophysical Union
http://archimer.ifremer.fr/doc/00043/15376/12734.pdf
DOI:10.1029/2011GC003523
http://archimer.ifremer.fr/doc/00043/15376/

Éditeur(s) : HAL CCSD Wiley-Blackwell
Résumé : Combined petrographic study and apatite fission track analysis (apatite FTA) across the Gres d'Annot basin document maximum temperatures reached by this turbiditic sandstone formation, from around 60 degrees C at the SW basin margin up to around 200 degrees C below the Penninic frontal thrust, in relation to burial below the front of Alpine nappes. Increasing diagenetic grade across the basin is primarily expressed by the development of silica transfer by pressure solution and correlated porosity loss. We infer the nappe thickness profile, from the nappe front in the SW up to around 8-10 km in the NE. Apatite FTA dates exhumation of the Gres d'Annot during the Late Miocene, in relation to thrusting of the underlying Argentera and Barrot Palaeozoic massifs. This study illustrates the influence of thrust front propagation on foreland basin diagenesis and exhumation, and highlights potential implications for the evolution of sediment reservoir properties in this context.
ISSN: 0954-4879

hal-00411860
https://hal.archives-ouvertes.fr/hal-00411860
DOI : 10.1111/j.1365-3121.2008.00793.x

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
Purpose: Marine mangrove sediments in the Manche-à-Eau lagoon (Guadeloupe, Caribbean Sea) harbor locally extensive, white microbial mats. These mats cover the surface of reduced sediments near the roots of red mangrove trees, Rhizophora mangle, and are mainly composed of sulfur-oxidizing bacteria belonging to the Beggiatoaceae family, with some filamentous cyanobacteria. The goal of this study was to investigatethe possible influence of sediment characteristics on the presence of these microbial mats. Materials and methods: Four push cores were collected in April 2013, two from zones with microbial mats and two from zones without mats. Sediment characteristics (grain-size distribution, mineralogy, total organic carbon (TOC) and total nitrogen (TN) contents, atomic TOC/TN ratios, and organic matter (OM) δ13C values) were compared for all four cores.Results and discussion: Significant differences were observed between sediments below microbial mats and those without mats. Sediments with microbial mats contained greater amounts of clay, and higher TOC, TN, and TOC/TN ratios, with lower total carbonate content andδ13C values. The higher clay content most likely results from lower fluid flow velocity near to mangrove roots, while higher TOC/TN ratiosand lower δ13C values indicate higher inputs of OM from mangrove trees. These results are consistent with the fact that microbial mats were observed near the roots of mangrove trees, which trap OM from terrestrial vegetation and fine sediments.Conclusions: The grain-size distribution of sediment particles, the total carbonate content, and the δ13C values are the main parameters discriminating between zones with microbial mats and those without mats. Variations in total carbonate content, which is mainly of biogenic origin, result from conditions that are more favorable for benthic organisms in zones without microbial mats. Variations of the TOC/TN ratios are controlled by the presence of a non-negligible amount of inorganic nitrogen bound to surface clay mineral particles and/or by microbial processes.
ISSN: 1439-0108

hal-01682110
https://hal.univ-antilles.fr/hal-01682110
DOI : 10.1007/s11368-016-1555-6