Éditeur(s) : HAL CCSD Wiley-Blackwell
Résumé : International audience
The Lanzo peridotite massif is a fragment of oceanic lithosphere generated in an ocean-continent transition context and eclogitized during alpine collision. Despite the subduction history, the massif has preserved its sedimentary oceanic cover, suggesting that it may have preserved its oceanic structure. It is an exceptional case for studying the evolution of a fragment of the lithosphere from its oceanization to its subduction and then exhumation. We present a field and petrological study retracing the different serpentinization episodes and their impact on the massif structure. The Lanzo massif is composed of slightly serpentinized peridotites (<20% serpentinization) surrounded by an envelope of foliated serpentinites (100% serpentinization) bordered by oceanic metabasalts and metasedimentary rocks. The limit between peridotites and serpentinites defines the front of serpentinization. This limit is sharp: it is marked by the presence of massive serpentinites (80% serpentinization) and, locally, by dykes of metagabbros and mylonitic gabbros. The deformation of these gabbros is contemporaneous with the emplacement of the magma. The presence of early lizardite in the peridotites testifies that serpentinization began during the oceanization, which is confirmed by the presence of meta-ophicarbonates bordering the foliated serpentinite envelope. Two additional generations of serpentine occur in the ultramafic rocks. The first is a prograde antigorite that partially replaced the lizardite and the relict primary minerals of the peridotite during subduction, indicating that serpentinization is an active process at the ridge and in the subduction zone. Locally, this episode is followed by the deserpentinization of antigorite at peak P-T (estimated in eclogitized metagabbros at 2-2.5 GPa and 550-620 °C): it is marked by the crystallization of secondary olivine associated with chlorite and/or antigorite and of clinopyroxene, amphibole and chlorite assemblages. A second antigorite formed during exhumation partially to completely obliterating previous textures in the massive and foliated serpentinites. Serpentinites are an important component of the oceanic lithosphere generated in slow to ultraslow spreading settings, and in these settings, there is a serpentinization gradient with depth in the upper mantle. The seismic Moho limit could correspond to a serpentinization front affecting the mantle. This partially serpentinized zone constitutes a less competent level where, during subduction and exhumation, deformation and fluid circulation are localized. In this zone, the reaction kinetics are increased and the later steps of serpentinization obliterate the evidence of this progressive zone of serpentinization. In the Lanzo massif, this zone fully recrystallized into serpentinite during alpine subduction and collision. Thus, the serpentinite envelope represents the oceanic crust as defined by geophysicists, and the sharp front of serpentinization corresponds to an eclogitized seismic palaeo-Moho.
ISSN: 0263-4929

hal-00823051
https://hal.archives-ouvertes.fr/hal-00823051
DOI : 10.1111/jmg.12008

Éditeur(s) : HAL CCSD Oxford University Press (OUP): Policy B - Oxford Open Option A Oxford University Press (OUP)
Résumé : International audience
Peridotites exhumed in the footwall of axial detachment faults at slow-spreading ridges are highly serpentinized. Most mid-ocean ridge detachment settings are magmatically active and hydrous fluid circulation in and near the fault has been shown to be influenced by the presence of melt or magmatic lithologies. Our working area along the Southwest Indian Ridge (62–65°E) is nearly amagmatic and represents an end-member to study the hydrous alteration of exhumed peridotites without these magmatic influences. We use an integrated petrological approach combining microstructural, mineralogical and chemical observations to unravel the sequence of serpentinization in 272 dredged samples of variably serpentinized peridotites and to document the circulation of serpentinizing fluids in and near the exhumation faults. We find that serpentine recrystallization and veins overprint the initial serpentinite mesh texture in ∼25% of the samples. Oxygen isotope data suggest that this sequence developed at relatively high temperatures (271–336°C) and under increasing fluid–rock ratios, from near stoichiometry for mesh texture formation to >10 during recrystallization. Increasing fluid supersaturation relative to serpentine favors the replacement of mesh texture lizardite by chrysotile and polygonal or polyhedral serpentine. We attribute local recrystallization into antigorite to moderate Si-metasomatism, possibly following pyroxene serpentinization. We do not observe the more pronounced Si-metasomatism leading to talc replacing serpentine that is reported for the more magmatically active Mid-Atlantic Ridge detachment settings and is attributed to prior leaching of magmatic rocks. Scales of preferential fluid pathways in our samples evolved from pervasive and close-spaced (<500 µm) microfractures during the formation of the initial serpentine mesh texture, to centimeter-thick planar domains of enhanced fluid flux, spaced at ∼10 cm intervals and probably grouped in corridors that may be up to ∼100 m across. Serpentine minerals are enriched in some fluid-mobile elements (Cl, B, U) relative to the peridotite protolith, and several elements (Al, Fe, Si, Cu, As, Sb, REE) are redistributed at the millimeter to decimeter scale. Serpentinizing fluids were seawater-derived, probably mildly alkaline (small to no europium anomalies), reducing and H2-enriched (formation of magnetite). These fluids may have been similar to, though warmer than, those venting at the ultramafic-hosted Lost City hydrothermal fluid (30°N, Mid-Atlantic Ridge).
ISSN: 0022-3530

hal-01174047
https://hal.archives-ouvertes.fr/hal-01174047
DOI : 10.1093/petrology/egv014

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
At Cima di Gagnone, garnet peridotite and chlorite harzburgite lenses within pelitic schists and gneisses correspond to eclogite-facies breakdown products of hydrated peridotites and are suitable for studying dehydration of serpentinized mantle. Thermobarometry and pseudosection modelling yield peak temperatures of 750-850°C and pressures <3 GPa. The minimum temperature recorded by the garnet peridotite corresponds to the maximum conditions experienced by the chlorite harzburgite, suggesting that these rocks recrystallized cofacially at ∼800°C. Alternatively, they might have decoupled during subduction, as achieved in tectonically active plate interface boundaries. The major and rare earth element (REE) variability of the peridotites was mostly acquired during pre-subduction mantle evolution as a result of partial melting and reactive melt flow. The ultramafic suite is also characterized by fluid-mobile element enrichments (B, Pb, As, Sb, Cs, Li, U, Be), which confirm derivation from variably serpentinized protoliths. Similarity in the U, Pb, B, Li and Sr contents of the Gagnone peridotites to present-day oceanic serpentinites suggests that these elements were partly taken up during initial serpentinization by seawater-derived fluids. Positive Be, As and Sb anomalies suggest involvement of fluids equilibrated with crustal (metasedimentary) reservoirs during subsequent subduction metamorphism and peridotite entrainment in (meta)sediments. Fluid-mobile element enrichment characterizes all peak eclogitic minerals, implying that multiple hydration events and element influx pre-dated the eclogite-facies dehydration. Peak anhydrous minerals retain B, Li, As and Sb concentrations exceeding primitive mantle values and may introduce geochemical anomalies into the Earth's mantle. The relatively low contents of large ion lithophile elements and light REE in the Gagnone peridotites with respect to much higher enrichments shown by metasomatized garnet peridotite pods hosted in migmatites (Ulten Zone, Eastern Alps) suggest that the crustal rocks at Gagnone did not experience partial melting. The Gagnone garnet peridotite, despite showing evidence for chlorite dehydration, retains significant amounts of fluid-mobile elements documenting that no partial melting occurred upon chlorite breakdown. We propose that the Gagnone ultramafic rocks represent a prime example of multi-stage peridotite hydration and subsequent dehydration in a plate interface setting.
ISSN: 0022-3530

hal-01054319
https://hal.archives-ouvertes.fr/hal-01054319
DOI : 10.1093/petrology/egt068

Résumé : Written on front: "______a del Carnaval. Habana. __een of the Carnival. Havana." Written on verso: "#2", "The Queen of the Carnival with her Maids in the break in which they ride during the Carnival parades. They have stopped for a moment in front of the official reviewing stand located on the Malecon drive. Note the 'serpentinas' which have been thrown at the Queen and her party are hanging on the break." Also, "Used 1919." Probably used by the Munson Steamship Line in their publication, The Cuba Review.
1900-1920
CHC5017
Havana (Cuba)

Droits : http://merrick.library.miami.edu/digitalprojects/copyright.html
chc50170001300001001
1353

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
A reactive percolation experiment was conducted by injecting seawater into a permeable olivine aggregate at 190 °C and 19 MPa to explore the relationships between hydration reactions and hydrodynamic properties during the onset of serpentinization in the ultramafic lithosphere exposed at mid-ocean ridges. The experiment was stopped after 23 days when the sample became impermeable. The initial flow rate was 0.2 mL/h and then was decreased down to 0.06 mL/h after 8 days. Permeability decreased continuously throughout the experiment. The analyses of fluid chemistry time series and of the mineralogy and structure of the reacted sample showed olivine dissolution and precipitation of proto-serpentine, brucite and Fe-oxides. These reactions are controlled by coupled hydrodynamic and chemical processes interacting at different time and spatial scales. Their first characteristic is the production of silica rich outlet fluids in disequilibrium with the observed reacted mineral assemblages. These compositions are interpreted as resulting from a suite of coupled dissolution-precipitation reactions, controlled at the pore scale by surface kinetic processes, that rapidly reaches steady-state (constant fluid composition independent of fluid flux). Hence, the effective rate of serpentinization was controlled, to the first order, by the transport of reactants during the experiment. Mass balance calculations show that the rate of olivine conversion was fast (0.2-0.5 wt%/day), yet only ∼8 wt% of the olivine sample reacted, because the permeability drop limited fluid circulation. Porosity varied little during the experiment compared to permeability changes: the decrease of permeability was explained by the structure of the newly formed serpentine favouring the clogging of fluid paths. The rate at which permeability decreased was the fastest at low flux conditions. This suggests that permeability changes were not controlled simply by the kinetics of the serpentinization reactions, but mainly reflected the development of low Peclet pore scale zones forming micro-environments that control the serpentinization reaction-paths. These results outline the need to take into account the coupling of hydrodynamic and chemical processes when modelling the effects of reactive transport within the hydrating oceanic lithosphere.
ISSN: 0012-821X

hal-00855043
https://hal.archives-ouvertes.fr/hal-00855043
DOI : 10.1016/j.epsl.2013.03.052

Éditeur(s) : HAL CCSD Springer Verlag (Germany) Springer Verlag
Résumé : International audience
La Cabaña peridotite is part of a dismembered ophiolite complex located within the metamorphic basement of the Coastal Cordillera of south-central Chile, and is the only location in Chile were Cr-spinels have been described so far. The La Cabaña peridotite is part of the Western Series unit, which comprises meta-sedimentary rocks, metabasites, and serpentinized ultramafic rocks. This unit has been affected by greenschist-facies metamorphism with reported peak PT conditions of 7.0–9.3 kbar and 380°–420 °C. Within La Cabaña peridotite Cr-spinels are present in two localities: Lavanderos and Centinela Bajo. In Lavanderos, Cr-spinel occurs in small chromitite pods and as accessory/disseminated grains with a porous or spongy texture in serpentinite, whereas in Centinela Bajo Cr-spinel is present as accessory zoned grains in partly serpentinized dunites, and in chromitite blocks. All Cr-spinels display variable degrees of alteration to Fe2+-rich chromite with a variation trend of major elements from chromite to Fe2+-rich chromite similar to those observed in other locations, i.e., an increase in Fe2O3 and FeO, a decrease in Al2O3 and MgO. Cr2O3 content increases from chromite to Fe2+-rich chromite in chromitite pods from Lavanderos and chromitite blocks from Centinela Bajo, but decreases in ferrian chromite zones in accessory grains from Centinela Bajo. The minor element (Ti, V, Zn, Ni) content is mostly low and does not exceed 0.4 wt.%, with the exception of MnO (<0.9 wt.%), which shows a correspondence with increasing degree of alteration. Cr# (Cr/Cr + Al) versus Mg# (Mg/Mg + Fe2+) and Fe3+/Fe3++Fe2+ versus Mg# plots are used to illustrate the Cr-spinel alteration process. Overall, the Cr-spinels from Lavanderos (chromitite pods and disseminated grains) exhibit Cr# values ranging from 0.6 to 1.0, Mg# (Mg/Mg + Fe2+) below 0.5, and (Fe3+/Fe3++Fe2+) <0.4. Cr-spinels from chromitites in Centinela Bajo have Cr# and Mg# values that range from 0.65 to 1.0, and 0.7-0.3, respectively, and (Fe3+/Fe3++Fe2+) < 0.4. Accessory Cr-spinels from Centinela Bajo have Cr# and Mg# values that range from 0.55 to 1.0, and 0.6- < 0.1, respectively. The (Fe3+/Fe3++Fe2+) ratio is less than 0.4 in chromite cores and Fe2+-rich chromite, and >0.5 in ferrian chromite and Cr-magnetite. Interpretation of the data obtained and Cr-spinel textures indicate that the alteration of Cr-spinel is a progressive process that involves in its initial stages the reaction of chromite with olivine under water-saturated conditions to produce clinochlore and Fe2+-rich chromite. During this stage the chromite can also incorporate Ni, Mn, and/or Zn from the serpentinization fluids. As alteration progresses, Fe2+-rich chromite loses mass resulting in the development of a spongy texture. In a later stage and under more oxidizing conditions Fe3+ is incorporated in chromite/Fe2+-rich chromite shifting its composition to an Fe3+-rich chromite (i.e., ferrian chromite). Depending on the fluid/rock and Cr-spinel/silicate ratios, Cr-magnetite can also form over Fe2+-rich chromite and/or ferrian chromite as a secondary overgrowth. The compositional changes observed in Cr-spinels from La Cabaña reflect the initial stages of alteration under serpentinization conditions. Results from this study show that the alteration of Cr-spinels is dependent on temperature. The degree and extent of alteration (formation of Fe2+-rich and/or ferrian chromite) are controlled by the redox nature of the fluids, the Cr-spinel/silicate and the fluid/rock ratios.
ISSN: 0930-0708

hal-01172266
https://hal.archives-ouvertes.fr/hal-01172266
DOI : 10.1007/s00710-014-0335-5

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Tso Morari serpentinites in the Ladakh area, northwest Himalaya, originated from the forearc mantle overlying the northward subducting Neo-Tethys lithosphere and the margin of the Indian continent. The serpentinites are characterized by high concentration of fluid-mobile elements (FME: As, Sb, B, Li, and U) compared to ophiolitic or abyssal serpentinites. The Pb isotopic compositions of serpentinites show influence of the subducted Indian continental lithosphere. Trace element concentrations of antigorite determined in situ with Laser Ablation High Resolution Inductively Coupled Mass Spectrometer (LA-HR-ICP-MS) show high contents of FME including Pb, in contrast to the spatially associated iron oxides. Rare earth elements (REE) and compatible elements, such as Sc and Co, remained immobile during the hydration, allowing the identification of the primary minerals (olivine or orthopyroxene) from which serpentine formed. Serpentinized olivine displays higher Sb and As concentrations (up to 1000 x PM) than serpentinized orthopyroxenes that are enriched in Pb, Cs and Li (2 to up to 10 x PM).;We propose that the observed FME distribution in two types of serpentine reflect the differential incorporation of FME during the downward movement of the serpentinite along the subduction plane. At temperature lower than 400 degrees C, at shallow depths, olivine is preferentially serpentinized and incorporates elements that are fluid soluble at low temperatures, such as Sb and As. Above 400 degrees C, orthopyroxene is hydrated and incorporates Pb, Cs, Li and possibly Ba. Boron and U are incorporated in both types of serpentine suggesting that they are released from slabs at temperatures around 300-400 degrees C. The serpentine acts as a sink for water, but also for FME and transports them to deeper and hotter levels in the mantle, down to the isotherm 600-650 degrees C where dehydration occurs.
ISSN: 0009-2541

hal-00475565
https://hal.archives-ouvertes.fr/hal-00475565
DOI : 10.1016/j.chemgeo.2009.10.002

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Over the last decades, numerous studies have emphasized the role of serpentinites in the subduction zone geodynamics. Their presence and role in subduction environments are recognized through geophysical, geochemical and field observations of modern and ancient subduction zones and large amounts of geochemical database of serpentinites have been created. Here, we present a review of the geochemistry of serpentinites, based on the compilation of ~ 900 geochemical data of abyssal, mantle wedge and exhumed serpentinites after subduction. The aim was to better understand the geochemical evolution of these rocks during their subduction as well as their impact in the global geochemical cycle. When studying serpentinites, it is essential to determine their protoliths and their geological history before serpentinization. The geochemical data of serpentinites shows little mobility of compatible and rare earth elements (REE) at the scale of hand-specimen during their serpentinization. Thus, REE abundance can be used to identify the protolith for serpentinites, as well as magmatic processes such as melt/rock interactions before serpentinization. In the case of subducted serpentinites, the interpretation of trace element data is difficult due to the enrichments of light REE, independent of the nature of the protolith. We propose that enrichments are probably not related to serpentinization itself, but mostly due to (sedimentary-derived) fluid/rock interactions within the subduction channel after the serpentinization. It is also possible that the enrichment reflects the geochemical signature of the mantle protolith itself which could derive from the less refractory continental lithosphere exhumed at the ocean-continent transition. Additionally, during the last ten years, numerous analyses have been carried out, notably using in situ approaches, to better constrain the behavior of fluid-mobile elements (FME; e.g. B, Li, Cl, As, Sb, U, Th, Sr) incorporated in serpentine phases. The abundance of these elements provides information related to the fluid/rock interactions during serpentinization and the behavior of FME, from their incorporation to their gradual release during subduction. Serpentinites are considered as a reservoir of the FME in subduction zones and their role, notably on arc magma composition, is underestimated presently in the global geochemical cycle.
ISSN: 0024-4937

hal-00903601
https://hal.archives-ouvertes.fr/hal-00903601
DOI : 10.1016/j.lithos.2013.05.019

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Serpentinites are one of the major components of the oceanic lithosphere and are stable in the slab and the mantle wedge up to 100-150 km depth in subduction zones. During oceanic mantle hydration and alteration, they trap trace and fluid mobile (FME: B, Li, As, Sb, Rb, Ba, Cs, Sr, U and Pb) elements that participate to elemental transfer occurring between the dehydrating slab and the mantle wedge in subduction context. The Lanzo massif is an eclogitized oceanic lithosphere that preserved its oceanic structure and recorded different steps of serpentinization/de-serpentinization from oceanic lizardite to prograde antigorite in subduction context, up to its dehydration and secondary olivine crystallization, and finally retrograde antigorite during massif exhumation. It constitutes a suitable place to study trace element behavior during serpentinization/de-serpentinization processes and associated chemical transfers between the different envelopes of the oceanic lithosphere and the mantle wedge. Geochemical analyses of serpentine and associated minerals show that the serpentinization/de-serpentinization of the Lanzo massif took place in a relatively closed system without significant trace element transfer between the different parts of the oceanic lithosphere. In the deeper part of the lithosphere, from the slightly serpentinized mantle peridotites (SSP, < 20% serpentinization) to the paleo-Moho, composed of massive serpentinites (MS, 80% serpentinization), the trace elements mobility is reduced. The chemical composition of lizardite and antigorite is homogenized with the local degree of serpentinization: in SSP, serpentine veins composition is inherited from the host mineral while, in MS, their composition is homogenous between destabilized phases at the scale of the outcrop (~ 5 m). In the shallowest part of the oceanic lithosphere, from the paleo-Moho to the oceanic paleo-seafloor, the serpentinites are foliated (FS, > 90% serpentinization). In that zone, the alpine deformation enhances the mobility of trace elements and permits their redistribution and the homogenization of antigorite composition at massif scale. Locally, in the SSP and MS, the crystallization of metamorphic veins of ~ 1-2 m corresponds to channelized fluid flows that allowed fluid transfers - and thereby trace elements - to longer distance. The successive crystallizations of antigorite and then olivine are accompanied by a diminution of some FME (B, Li, As, Sb, Ba, Rb) and Eu contents attesting that these elements are removed from slab to mantle wedge during subduction.
ISSN: 0009-2541

hal-00937661
https://hal.archives-ouvertes.fr/hal-00937661
DOI : 10.1016/j.chemgeo.2013.08.025

Éditeur(s) : HAL CCSD Ocean Drilling Programm
Résumé : This paper provides a summary of postcruise scientific results from Ocean Drilling Program (ODP) Leg 209 available to date, building upon shipboard observations and syntheses summarized in the Leg 209 Initial Results volume. During Leg 209, 19 holes were drilled at 8 sites along the Mid-Atlantic Ridge from 14°43´ to 15°44´N, mainly in residual mantle peridotite intruded by gabbroic rocks, in order to understand the tectonic and structural processes responsible for formation of oceanic lithosphere with abundant residual peridotite exposed on the seafloor coupled with a relatively low proportion of volcanic rocks. Based on proportions of recovered lithologies, the entire area may be underlain by mantle peridotite with ~20%–40% gabbroic intrusions and impregnations. Impregnated peridotites with olivine + two pyroxenes + plagioclase + spinel that apparently formed in equilibrium probably record crystallization from primitive mid-ocean-ridge basalt at pressures of 0.5–0.6 GPa. Metamorphic equilibria record isobaric cooling to ~1100°C at this pressure. Thus, the conductively cooled thermal boundary layer beneath the Mid-Atlantic Ridge in this region is >15 km thick. Combined crystallization and reaction with residual peridotite formed a series of impregnated peridotites recording increasing Na content at nearly constant Mg#; this process could explain some of the variation in fractionation-corrected Na (e.g., Na = 8.0) observed in mid-ocean-ridge basalts. Clinopyroxene textures and compositions record such impregnation processes, and they are particularly well documented for Site 1274. Other Leg 209 gabbroic rocks formed from extensive crystallization of highly evolved melts, indicating that a substantial proportion of melt entering the thermal boundary layer crystallizes entirely beneath the seafloor, with no volcanic equivalent. Alteration of peridotites occurred over a range of temperatures and is the result of three distinct processes: rock-dominated serpentinization with formation of brucite in olivine-rich lithologies, fluid-dominated serpentinization with formation of magnetite and no brucite, and fluid-dominated talc alteration with addition of SiO2 as well as H2O and oxygen. The latter two processes also exhibit detectable trace element metasomatism that is distinct in its character from the igneous impregnation described in the previous paragraph. Microstructures show that most residual peridotites were not ductilely deformed at temperatures less than ~1200°C. Structural and paleomagnetic data require tectonic rotations of relatively undeformed blocks; some rotations probably exceeded 60° around nearly horizontal axes parallel to the rift axis. Rotations occurred along several generations of high-temperature mylonitic shear zones extending deeper than 15 km depth and numerous faults at lower temperature. Early formed shear zones and faults were passively rotated around later features; such a process could have produced low-angle fault surfaces without slip on low-angle faults. This region provides end-member examples of processes that are common at many or most slow-spreading ridges. Osmium isotope ratios indicate an ancient history of depletion for residual peridotites from the 14°–16°N region along the Mid-Atlantic Ridge. Though depleted Os isotope ratios in peridotite have been reported elsewhere along the global ridge system, the values from this region are among the most depleted. In general, Os isotope ratios from mid-ocean-ridge basalts are systematically more radiogenic than Os isotope ratios from ridge peridotite samples, suggesting a polygenetic heterogeneous source for mid-ocean-ridge basalts. Geochemical studies of zircons from Leg 209 gabbroic rocks and impregnated peridotites, together with other ridge and arc-related zircons, indicate that ridge zircons have systematically lower fractionation-corrected U and Th concentrations compared to arc zircons. This observation provides a tool for interpreting the tectonic provenance of ancient detrital zircons and indicates an arclike provenance for Hadean detrital zircons. Geobiological studies and aerobiological studies were also undertaken during Leg 209. The geobiological work found no measurable microbial enhancement of olivine dissolution rate, possibly because the samples from Leg 209 were sterile. The aerobiological study determined that dust from North Africa, collected from the derrick of the JOIDES Resolution during Leg 209, contains a variety of abundant microorganisms.
Proceedings ODP, scientific results, 209

hal-00407966
https://hal.archives-ouvertes.fr/hal-00407966
DOI : 10.2973/odp.proc.sr.209.001.2007

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
To better understand the microstructural evolution of a "serpentinized" mantle rock and the influence of various hydrous phases on the seismic properties of the mantle wedge, we have conducted the detailed microstructural analyses of a sample of tremolite-chlorite-antigorite schist collected from the Moses Rock dike (central part of the Colorado Plateau). We performed differential effective media (DEM) modelling to study the effect of three hydrous phases forming two-phase aggregates with olivine, considering the crystallographic preferred orientation (CPO) of each phase and the shape ratio of the hydrous phases. We have demonstrated that in a partially serpentinized peridotite, the olivine CPO characteristic of [100](010) dislocation glide is still preserved, and the high-temperature asthenospheric flow is preserved with a foliation normal to that of antigorite schist. The transformation of olivine into antigorite occurs predominantly (~ 75%) by the relationship (100)ol || (001)atg with [001]ol || [010]atg, with the (010)ol || (001)atg and [001]ol || [010]atg relationship observed in areas of weak antigorite CPO. Chlorite results from the phase transformation of olivine in a relatively static environment, as shown by the correlation between the olivine-chlorite CPOs with (100)ol || (100)ch, (010)ol || (001)ch and (001)ol || (010)ch. The fluid percolation that caused the localized metasomatism and partial hydration of the mantle occurred possibly along trans-lithospheric shear zones. The presence of chlorite induces the most important drop on the P-wave velocities and may help to explain some local low velocities in the fore-arc mantle wedges, but is unlikely to be of global importance due to its very high Vp/Vs ratio ~ 1.9. On the other hand, antigorite is the only phase that causes important modification on the propagation directions of P and S-waves, and the only phase to explain the polarization of the fastest shear waves parallel to the subduction trench.
ISSN: 0040-1951

hal-00858061
https://hal.archives-ouvertes.fr/hal-00858061
DOI : 10.1016/j.tecto.2013.03.022

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
We report on microstructural data obtained by optical microscopy and transmission electron microscopy concerning the crystallographic relationships of serpentine minerals with their host olivine in two contrasting situations. In the first case, mesh-textured lizardite (liz) is developed in a standard 60% serpentinized oceanic harzburgite from the Oman ophiolite where olivine converts to columnar lizardite. The joined columns are perpendicular to the basal plane (001)(liz), corresponding to the pseudofibres observed optically. The plane (001)(liz) is locally parallel to the narrow boundary ol-liz; thus column orientations register the interface of serpentinization. The ol-liz relationships are not strictly topotactic, but reflect preferred cracking orientations in olivine, parallel to (010)(ol). In the second case, antigorite (atg) develops in a rare sample of antigorite schist in a kimberlite from Moses Rock (Colorado Plateau), representative of a suprasubduction-zone mantle wedge. High-resolution transmission electron microscopy (HRTEM) images along [010](atg) show domains of very regular modulation with a 43 center dot 5 A wavelength (m = 17, where m is the number of silicate tetrahedra along the wave), with few defects, indicative of HP-HT antigorite, and also heavily kinked regions as fingerprints of strong tectonic shear. TEM imaging and electron diffraction patterns reveal two topotactic relationships between antigorite and olivine: [100](atg)//[010](ol) and < 100 >(atg)//< 100 >(ol); the planes in contact are (001)(atg)//(100)(ol) and (001)(atg)//(010)(ol), respectively. The [010](atg)//[001](ol) and antigorite lamellae are parallel to the forsterite b-axis. In both cases, the topography of olivine-serpentine interfaces is controlled by open fluid pathways along microcracks oriented according to the anisotropy of the olivine aggregate. In the cases studied, the serpentine aggregate exhibits a preferred orientation inherited from that of the peridotite. These results have some relevance to the seismic anisotropy of serpentinized mantle. Anisotropy of propagation of seismic waves as a result of the olivine fabric is maintained and reinforced with the development of lizardite. Conversely, the development of antigorite produces a trench-parallel fast S-wave polarization and an anisotropy that is lowered at low degrees of serpentinization and then increased with increasing serpentinization.
ISSN: 0022-3530

hal-00456061
https://hal.archives-ouvertes.fr/hal-00456061
DOI : 10.1093/petrology/egp049

Éditeur(s) : HAL CCSD
Résumé : International audience
The geology of the North Pyrenean Zone in the central Pyrenees allows for the observation in the field of theentire section of the Pyrenean rift, from the mantle to the crust and the Mesozoic cover (pre, syn and post rift).The good knowledge we have of the pre-Alpine history of the Pyrenees allows us to properly constrain the Alpinegeological evolution of the pre-Triassic rocks which record both Variscan and Alpine orogenic cycles.The mantle outcrop as kilometric to centimetric fragments of peridotite dispersed within a carbonate metamorphicbreccia. The study of peridotite serpentinisation shows several events of low-temperature serpentinisation, incontact with seawater. In some locallities, we can observe a mixture of fragments of variously serpentinizedperidotites. This suggests a tectonic context where fragments of peridotites from different structural levels weresampled more or less synchronously.The granulitic basement is characterized by a Variscan syndeformational HT event (300-280 Ma). So farwe have not found any trace of a Cretaceous HT event (> 500C). On the other hand, the basement is affectedby a regional metasomatism that began during the Jurassic and became more spatially focused with time until itwas restricted to the Pyrenean rift during the Aptien, Albian and Cenomanian. The talc-chlorite metasomatism(120-95 Ma) shows an evolution from a static toward a syn-deformation hydrothermal event, under a more or lessnormal geothermal gradient. Extensional deformation is recorded by the reworking of several inherited low-angleVariscan tectonic contacts, but also by dispersed high-angle extensional shear zones formed under greenshistconditions.The metamorphic Mesozoic cover of the basement massifs, which constitute the so-called Internal MetamorphicZone, is an allochtonous unit made of lenses of Mesozoic rocks enclosed into the breccia, whichlocally contains peridotite and basement clasts. The Mesozoic metamorphic carbonates show a first phase ofsyn-metamorphic (450-600C, P < 2 kb) ductile deformation, and subsequent phases of folding and fracturing.The datation of neoformed minerals give a 108-85 Ma time span for the metamorphism. We interpret this brecciaas an abandonment breccia which marks the emergence of the main detachment. The basal contact of the Mesozoiccover has a complex 3D geometry traced by Triassic evaporites. It corresponds to a major pre- and synorogenicpolyphased tectonic contact.All these data show a geometrically complex hyper-extended rift where the crust was not stretched under ahigh geothermal gradient but thinned by the tectonic extraction of relatively thin lenses and perhaps cut by highangle low-grade shear zones. The 3D geometry, as well as the strain records and the breccia lithologies stronglysuggest a non-cylindricity for the exhumation process, probably within a transtentional system
Geophysical Research Abstracts
Vienne, Austria

insu-01510371
https://hal-insu.archives-ouvertes.fr/insu-01510371

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Imaging deep active volcanic areas remains a challenge in our understanding of their activity and evolution, especially in subduction zones. Study of magnetic anomalies is appropriate to access such dynamics in depth. The magnetic anomaly pattern of the Lesser Antilles Arc (LAA) subduction is studied through Curie Point Depth (CPD), interpreted as the depth of the 580 °C isotherm, and developed to better assess the deep thermal structure of the arc. The depth of the estimated CPD exhibits a complex topography. Keeping in mind the overall uncertainty associated with this method, a main doming is evidenced below the Guadeloupe archipelago. Its apex is shifted towards the ancient arc, suggesting a very hot state of the fore-arc/arc domain. To better understand the LAA thermal state, we perform 2D thermo-mechanical simulations of the subduction zone. Recalling that magnetite is a serpentinization by-product, we simulate water transfer triggered by slab dehydration to test the assumption of fore-arc serpentinization suggested by the positive magnetic anomaly in the vicinity of the Guadeloupe archipelago. In this area, the subduction-induced arc lithosphere hydration and related weakening trigger a fast heating of the upper plate by basal convective removal. This process of fast arc lithosphere thinning may apply where simultaneously the volcanic arc is split in two and normal convergence is high enough. As serpentinization strongly decreases P-wave velocity, we propose a new interpretation of a published seismic profile below Guadeloupe. The seismic layer previously interpreted as the arc lower crust may rather be a layer of serpentinized mantle, as supported by spatial correlations between gravimetric and magnetic anomalies. Consequently, at the scale of Guadeloupe Island, the fore-arc Moho would be shallower than initially assumed, with a dome shape more consistent with both the extensive deformation active since the Oligocene in the inner fore-arc and the CPD doming.
ISSN: 0040-1951

Droits : http://creativecommons.org/licenses/by-nc-nd/
insu-01505300
https://hal-insu.archives-ouvertes.fr/insu-01505300
https://hal-insu.archives-ouvertes.fr/insu-01505300/document
https://hal-insu.archives-ouvertes.fr/insu-01505300/file/Gailler-2017.pdf
DOI : 10.1016/j.tecto.2017.03.014

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Tectonic mixing of slab- and mantle-derived materials at the interface between converging plates highly enhances fluid-mediated mass transfer from the slab to the overlying mantle. Subduction mélanges can provide information about the interaction among different slices accreted at plate interface domains, with implications on the tectonic and geochemical evolution of the plate-interface itself. At Cima di Gagnone, pelitic schists and gneiss enclose chlorite harzburgite and garnet peridotite lenses, like in subduction mélanges located in-between downgoing slabs and overlying mantle. These peridotites host MORB-type eclogite and metarodingite, and derive from dehydration of serpentinized mantle protoliths. Their enrichment in fluid-mobile B, As, Sb, U, Th is the result of an early-stage oceanic serpentinization, followed by interaction with host metasediments during subduction burial. Here we define the element exchange process in the Gagnone mélange by means of the B, Sr and Pb isotope analysis of its main lithologies (ultramafic, mafic rocks and paragneiss). The 87Sr/86Sr and 206Pb/204Pb ratios of ultramafic rocks (0.7090–0.7124 and 18.292–18.837, respectively) show enrichments in radiogenic Sr and Pb after exchange with the host paraschist (up to 0.7287 87Sr/86Sr; 18.751 206Pb/204Pb). The δ11B values of peridotites (down to −10‰) point to a combined effect of (1) 11B release to deserpentinization fluids (serpentinized protoliths likely had positive δ11B and lower radiogenic Sr, Pb), and of (2) exchange with fluids from the surrounding metasediments. The whole Gagnone rock-suite is finally overprinted by retrograde fluids that essentially bring to an increase in radiogenic Pb (about 19.0 206Pb/204Pb) and to values of 0.710 87Sr/86Sr and of −10‰ δ11B. The recognition of different stages of interaction between mantle rocks and sedimentary/crustal reservoirs allows us to define the geochemical effects related to the early coupling of such rocks along the plate-interface. Our study shows that ultramafic rocks involved in subduction-zone metamorphism and serpentinization uptake radiogenic Pb and Sr released by associated sedimentary reservoirs. The exchange process envisioned here is not only representative of subduction mélanges: it can also be a proxy of mass transfer between slab and serpentinized supra-subduction mantle, as occurs in forearcs. Dehydration of the Gagnone-type serpentinized mantle releases crust-derived components to arcs, without direct involvement of metasediment dehydration and/or melting in subarc environments. The retention of appreciable amounts of fluid-mobile elements, radiogenic Pb and Sr in dehydrated Gagnone peridotites has implications on element recycling in the deep Earth’s mantle.
ISSN: 0016-7037

hal-01174137
https://hal.archives-ouvertes.fr/hal-01174137
DOI : 10.1016/j.gca.2015.04.024

Éditeur(s) : Ofioliti
Résumé : Serpentinisation of mantle rocks, leading to natural venting of hydrogen and methane, has been reported to occur at the global scale, wherever fluids percolate in ultramafic formations. Here we compare gas composition from two on-land, low-temperature, and hyper-alkaline springs hosted on ultramafic rocks in the ophiolite massifs of the Sultanate of Oman and the Ligurian Alps (Voltri Group, Genoa region, Northern Italy). These two settings exhibit similar chemical and mineralogical features but show diverse styles of gas venting. Commonly to all hyper-alkaline springs, gases are characterised by relatively high N-2, very low O-2 and CO2 concentrations, and a strong enrichment in H-2 and CH4. The comparison between Oman and Liguria highlights a high variability of the H-2/CH4 ratios whereby the gas phase of the Oman Ophiolite is enriched in H-2 whereas being CH4 enriched in the Voltri Ophiolite. These results combined with literature data define three groups that may reflect different stages of serpentinisation producing fluids from hydrogen-dominated to methane-dominated. The origin of these distinct groups might lie in the difference of the mineralogical composition of the rocks within which the fluids circulate, on the degree of alteration of the rocks and finally on the geological/metamorphic history of the ophiolite.
Ofioliti (0391-2612) (Ofioliti), 2013-12 , Vol. 38 , N. 2 , P. 143-156

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/00175/28634/27059.pdf
DOI:10.4454/ofioliti.v38i2.423
http://archimer.ifremer.fr/doc/00175/28634/

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Serpentinization of olivine-rich troctolite from core 227, Integrated Ocean Drilling Program (IODP) Hole U1309D ranges from 10 to 90. Two episodes of serpentinization are recognized. The first, dominant in weakly serpentinized samples, is an approximately isochemical (except for water) replacement of olivine (Fo(8485)) by a mixture of serpentine (antigorite, Mg-number 92) and brucite (amakinite-rich; Mg-number 65). The compositions of the minerals in type 1 veins are a reflection of FeMg exchange between olivine and the brucite serpentine formed during early serpentinization. The early serpentinite veins (type 1) are thin ( 005 mm), irregular, and exploit pre-existing cracks in olivine. The presence of antigorite suggests that early serpentinization occurred at T 300C. Type 1 veins reflect rock-dominated serpentinization, became isolated early in their history, and persist as relicts in all but the most altered samples. The main episode of serpentinization is manifested by through-going lizardite (average Mg-number 96)magnetite veins (type 2). Type 2 veins define an anastomosing foliation, may be several millimeters in width and appear to exploit pre-existing, favorably oriented type 1 veins. Type 2 veins reflect open-system serpentinization. Magnetite in these veins formed by oxidation of the Fe in brucite and serpentine, whereas addition of silica to the system converted the Mg-component of the brucite to serpentine. Magnetite forms one or more distinct bands in the interior of the vein and is never in direct contact with relict olivine. A bruciteserpentine mixture, similar to that found in type 1 veins, but with lizardite instead of antigorite, is commonly present at the margins of type 2 veins (i.e. where they are in reaction contact with relict olivine). We interpret type 2 veins as a steady-state system where brucite continually forms at the olivinevein contact and then reacts out in the interior of the vein. This continual formation and destruction of brucite imposes an exceptionally low a(SiO2) on the system. Magnetite and olivine are never in contact in type 2 veins (or anywhere else) because the olivine-out reaction yields ferroan brucite and not magnetite. The desilication of serpentine in the type 2 veins is a reflection of the inherent instability of Fe-rich serpentine with respect to magnetite at low silica activity. Thus, the composition of serpentine in equilibrium with magnetite in serpentinites is a function of serpentinemagnetite and not serpentineolivine equilbria.
ISSN: 0022-3530

hal-00420931
https://hal.archives-ouvertes.fr/hal-00420931
DOI : 10.1093/petrology/egp004

Éditeur(s) : Wiley / Blackwell
Résumé : P>New seismic reflection data from the Grand Banks of Newfoundland and the Newfoundland Basin add to the growing knowledge of the composition, structure and history of this non-volcanic margin. Geophysical imaging is now approaching the extent of that done previously on the conjugate margin along Iberia, providing a valuable database for the development of rifting models. Two parallel profiles over the shelf platform image deep crustal fabric representing Precambrian or possibly Appalachian deformation as well as Mesozoic extension. Progressively more intense extension of continental crust is imaged oceanwards without the highly reflective detachments frequently seen on profiles off Galicia. A landward-dipping event 'L' is imaged sporadically and appears to be analogous to a similar event on the Iberian IAM9 profile. The transition zone is probably exposed serpentinized mantle as interpreted off the Iberian margin although there appears to be a difference in the character of ridge development and reflectivity. The distinctive 'U' reflection identified previously at the base of the Newfoundland Basin deep water sedimentary section and recently identified as one or more thin basalt sills is imaged on newly presented profiles that connect previously published profiles SCR3 and SCR2 showing that 'U' is highly regular and continuous except where interrupted by basement highs. 'U' is also seen to have a major impact on the ability to image underlying basement. A full transect beginning over completely unextended continental crust through to oceanic crust has provided a data set from which estimates of extension and the pre-rifting location of the present continental edge can be made. Two estimates were obtained; 85 km based on faulting and 120 km based on crustal thickness.
Geophysical Journal International (0956-540X) (Wiley / Blackwell), 2009-08 , Vol. 178 , N. 2 , P. 1004-1020

Droits : 2009 Wiley / Blackwell
http://archimer.ifremer.fr/doc/2009/publication-6919.pdf
DOI:10.1111/j.1365-246X.2009.04162.x
http://archimer.ifremer.fr/doc/00000/6919/

Éditeur(s) : Wiley-blackwell Publishing, Inc
Résumé : We present the results from processing and interpreting five lines from the 1992 Erable multichannel seismic reflection experiment extending from the southeastern margin of Flemish Cap into the northern Newfoundland Basin. These profiles reveal significant along strike variations in the rifting styles experienced by Flemish Cap. In the southwest, a 100-km-wide transition zone is identified between thinned continental crust and thin oceanic crust. Similar to the conjugate Galicia Bank and Iberian margins, this transition zone contains a section of deep basement adjacent to a series of shallower ridges and is interpreted as exhumed serpentinized mantle. Along strike towards the northeast, this transition zone pinches out completely within 100 km and is replaced by thin oceanic crust directly adjacent to thinned continental crust. By interpreting nearby seismic profiles and profiles on the conjugate margins using the same classification criteria, we construct regional maps of the distribution of crustal domains on both sides of the North Atlantic. These maps reveal significant variations in rifting style on the conjugate margins and along strike of each margin and also highlight the role of ancient transfer zones in compartmentalizing these rifting variations into four distinct regions. We propose that the limited localization of shallow topographically high serpentinized peridotite ridges on the Newfoundland-Iberia and Flemish Cap-Galicia Bank conjugate margins, was directly related to an increase in the rate of extension following the separation of Flemish Cap and Galicia Bank which exhumed deeper, less serpentinized mantle.
Geophysical Journal International (0956-540X) (Wiley-blackwell Publishing, Inc), 2010-03 , Vol. 180 , N. 3 , P. 976-U4

Droits : 2010 RAS
http://archimer.ifremer.fr/doc/00001/11202/7876.pdf
DOI:10.1111/j.1365-246X.2009.04477.x
http://archimer.ifremer.fr/doc/00001/11202/

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
The southwestern Tianshan (China) metamorphic belt records high-pressure (HP) to ultrahigh-pressure (UHP) conditions corresponding to a cold oceanic subduction-zone setting. Serpentinites enclosing retrogressed eclogite and rodingite occur as lenses within metapelites in the UHP unit, which also hosts coesite-bearing eclogites. Based on the petrology and petrography of these serpentinites, five events are recognized: (1) formation of a wehrlite–harzburgite–dunite association in the mantle; (2) retrograde metamorphism and partial hydration during exhumation of the mantle rocks close to the seafloor; (3) oceanic metamorphism leading to the first serpentinization and rodingitization; (4) UHP metamorphism during subduction; (5) retrograde metamorphism during exhumation together with a second serpentinization. The peak metamorphic mineral assemblage of the serpentinized wehrlite comprises Ti-chondrodite + olivine + antigorite + chlorite + magnetite + brucite. A computed pseudosection for this serpentinized wehrlite shows that the Al content in antigorite is mostly sensititive to temperature but can also be used to constrain pressure. The average XAl = 0·204 ± 0·026 of antigorite (XAl = Al (a.p.f.u.)/8, where Al is in atoms per formula unit for a structural formula M48T34O85(OH)62, and M and T are octahedral and tetrahedral sites, respectively) included in Ti-chondrodite and average XAl = 0·203 ± 0·019 of antigorite in the matrix result in a well-constrained peak metamorphic temperature of 510–530°C. Peak pressures are less precisely constrained at 37 ± 7 kbar. The Tianshan serpentinites thus record UHP metamorphic conditions and represent the deepest subducted serpentinites discovered so far. The retrograde evolution occurs within the stability field of brucite + antigorite + olivine + chlorite and formation of Ti-clinohumite at the expense of Ti-chondrodite has been observed, suggesting isothermal decompression. The resulting P–T path is in excellent agreement with the metamorphic evolution of country rocks, indicating that the UHP unit in Tianshan was subducted and exhumed as a coherent block. To refine the metamorphic path of the ultramafic rocks, we have investigated the stability fields of Ti-chondrodite and Ti-clinohumite using piston-cylinder experiments. A total of 11 experiments were conducted at 25–55 kbar and 600–750°C in a F-free natural system. Combined with previous experiments and information from natural rocks we constructed a petrogenetic grid for the stability of Ti-chondrodite and Ti-clinohumite in F-free peridotite compositions. The formation of Ti-chondrodite in serpentinites requires a minimum pressure of about 26 kbar, whereas in Ti-rich systems it can form at considerably lower pressures. A key finding is that at UHP conditions, F-free Ti-chondrodite or Ti-clinohumite breaks down in the presence of orthopyroxene between 700 and 750°C, at temperatures that are significantly lower than those of the terminal breakdown reactions of these humite minerals. These breakdown reactions are an additional source of fluid during prograde subduction of serpentinites.
ISSN: 0022-3530

hal-01243507
https://hal.archives-ouvertes.fr/hal-01243507
DOI : 10.1093/petrology/egv042