Éditeur(s) : ANR : Agence Nationale de la Recherche CNRS : Centre National de la Recherche Scientifique LC2S : Laboratoire Caribéen de Sciences Sociales
Extrait de : "Histoires orales alternatives dans la Caraïbe, 19ème-21ème siècle" : colloque de clôture, du 19 au 21 novembre 2018. Agence nationale de la recherche, Centre national de la recherche scientifique, LC2S.
Description : En quête de souvenirs et récits concernant les 10 552 hommes et femmes recrutés en Afrique par le gouvernement français et conduits en Martinique quelques années après l'abolition de l'esclavage de 1848, dans le cadre de l'engagisme, ce ne sont pas des « engagés africains » que l'intervenante a rencontré dans les mémoires mais des « Africains ». Forte de sa recherche doctorale sur l'engagisme africain, elle s'attendait à trouver dans les mémoires familiales des éléments sur ce système par lequel le ou les aïeux de ses interlocuteurs avaient été conduits sur cette île, système qui avait défini leur statut juridique à vie et leurs conditions de travail et de vie pour de nombreuses années. Sa surprise fut grande de ne pas en trouver traces. Ainsi, l'intervention posera-t-elle les différentes hypothèses qui permettent d'appréhender les raisons de cet effacement de l'expérience de l'engagisme.

Droits : CC-BY-NC-ND - Attribution - Pas d'utilisation commerciale - Pas de modification
Permalien : http://www.manioc.org/fichiers/V18323
V18323

Éditeur(s) : HAL CCSD
Résumé : East African Rift (EAR) is the divergent plate boundary. EAR exposes different stages of extension, from early stage rifting in Tanzania to oceanic accretion in Afar (Ethiopia). Manyara basin is the southernmost rift system of the east branch of EAR with recent volcanism (< 1.5 Ma) and a seismic swarm in the lower crust (20 – 40 km). Due to its location and tectonic setting, the Manyara basin offers the opportunity to study the earliest stage of rift initiation. Manyara volcanism is composed of several types of hyper-alkaline lavas as Mg-nephelinites (Mg# > 55) (Labait, Kwaraha), calciocarbonatite (Kwaraha) and evolved nephelinites (Mg# < 35) (Hanang).Mg-nephelinites (Labait and Kwaraha) are primary lavas mainly composed of olivine and clinopyroxene (cpx). Geochemical modelling from trace elements suggests that these primary magmas result from a degree of partial melting < 1 % from a CO2-garnet-phlogopite-bearing peridotite. These magmas have an asthenospheric source at depth > 120 km (lava carries xenoliths with equilibrium conditions > 4 GPa). The minerals were crystallized from a magma with a low H2O content (0.1 and 0.5 wt% H2O). The calciocarbonatite and evolved nephelinites are derived from Mg-nephelinites by fractional crystallization and immiscibility processes. Hanang nephelinites are silica- and alkaline-rich lavas (44.2 – 46.7 wt % SiO2, 9.5 –12.1 wt % Na2O+K2O, respectively) composed by cpx, Ti-garnet, nepheline, apatite and titanite. Complex zonation of cpx (e.g. abrupt change of Mg#, Nb/Ta, and H2O) and trace element patterns of nephelinites record magmatic differentiation involving open system with carbonate-silicate immiscibility and primary melt replenishment. The low H2O content of cpx (3 – 25 ppm wt. H2O) indicates that at least 0.3 wt % H2O was present at depth during carbonate-rich nephelinite crystallization at 340 – 640 MPa and 1050 – 1100 °C. The study of hosted-nepheline melt inclusions from Hanang allows constraining the late magmatic evolution of nephelinites during storage and magma ascent. Melt inclusions are composed by a silicate trachytic glass, a carbonate phase and a shrinkage bubble. Trachytic glass contains high content in CO2 (0.43 wt %, SIMS analyses), sulfur (0.21 – 0.92 wt % S), chlorine (0.28 –0.84 wt % Cl) and H2O low content (< 0.1 wt %, Raman analyses). Immiscibility process leading to the formation of carbonate occurs in a closed system during rapid magma ascent between 200 – 500 MPa. The carbonate phase is a Ca-Na-K-S-rich and anhydrous carbonate (33 wt % CaO, 20 wt % Na2O, 3 wt % K2O, and 3 wt % S). The pre-immiscible liquid has a phonolitic composition with 6 ± 1.5 wt % CO2 at 700 MPa. A preliminary study of melt inclusions by XANES spectroscopy and whole rocks by Mössbauer spectroscopy was used to determine these Manyara lavas were formed at oxidizing conditions (~ ΔFMQ +1.5).The early stage rifting volcanism (Manyara Basin) is characterized by CO2-rich and H2O-poor magmas from at least 120 km below the rift escarpment. The presence of CO2-rich magmas and the small amount of volcanic rocks erupted at the surface may indicate that the storage and percolation of these magmas at depth is a potential trigger for deep seismic swarms.
Le rift Est africain (REA) est une frontière de plaque en extension. Ce rift présente plusieurs stades d’extension, de l’initiation du rift en Tanzanie jusqu’à l’accrétion océanique en Afar. Le bassin de Manyara se situe le plus au sud de branche Est du REA. Il est caractérisé par la présence de volcanisme récent (< 1,5 Ma) et d’un essaim sismique dans la croûte inférieure (20 – 40 km). De par sa localisation et son contexte tectonique, le bassin de Manyara offre l’opportunité d’étudier le stade le plus précoce de l’initiation du rift. Le bassin de Manyara est composé de plusieurs types de laves hyperalcalines, les néphélinites magnésiennes (Mg# > 55) (Labait, Kwaraha), de calciocarbonatite (Kwaraha) et des néphélinites différenciées (Mg# < 35) (Hanang).Les néphélinites magnésiennes (Labait et Kwaraha) sont des laves primaires composées d’olivines et de clinopyroxènes (cpx). La modélisation géochimique des éléments en trace suggère que ces magmas primaires résultent d'un degré de fusion partielle ≤ 1 % à partir d'une péridotite à grenat et phlogopite. Ces magmas proviennent d’une profondeur > 120 km (présence de xénolites avec des conditions d’équilibre > 4 GPa). Les minéraux ont cristallisés à partir d’un magma pauvre en eau (0,1 et 0,5 pds % H2O). La calciocarbonatite et les néphélinites différenciés sont issues des néphélinites magnésiennes par cristallisation fractionnée et processus d’immiscibilité. Les néphélinites du Hanang sont riches en éléments alcalins (9,5 – 12,1 pds % Na2O+K2O) et en silice (44,2 – 46,7 pds% SiO2) et sont composés de cpx, grenat, néphéline, titanite et apatite. La zonation complexe dans les cpx (par exemple, changement brusque de Mg#, Nb/Ta, et H2O) implique une différenciation magmatique en système ouvert avec immiscibilité de liquide carbonaté et silicaté ainsi qu’un remplissage de la chambre magmatique avec des liquides primaires. La faible teneur en eau des cpx (3 – 25 ppm H2O) indique la présence d’un magma pauvre en eau (0,3 pds % H2O) lors de la cristallisation des cpx à des conditions crustales (340 – 640 MPa et 1050 – 1100 °C). L’étude des inclusions vitreuses dans les néphélines de Hanang permet de contraindre l'évolution magmatique tardive des néphélinites et le comportement des éléments volatils (CO2, H2O, S, F, Cl) lors du stockage et de la remontée du magma. Les inclusions vitreuses sont composées d’un verre trachytique, d’une phase carbonatée et d’une bulle de rétraction. Le verre trachytique contient du CO2 (0,43 pds % CO2, analyses SIMS), du soufre (0,21 à 0,92 pds% S), du chlore (0,28 – 0,84 pds % Cl) et très peu d’H2O (< 0,1 pds % H2O, analyses Raman). Le processus d’immiscibilité conduisant à la formation du carbonate se produit dans un système fermé pendant l'ascension rapide du magma, entre 200 – 500 MPa. La phase carbonatée est un carbonate anhydre et riche en Ca-Na-K-S (33 pds % CaO, 20 pds % Na2O, 3 pds % K2O, et 3 pds % S). Le liquide pré-immiscible a une composition phonolitique avec 6 ± 1,5 pds % CO2 à une pression de 700 MPa. Une étude préliminaire des inclusions par spectroscopie XANES et des roches par spectroscopie Mössbauer a permis de déterminer que les laves de Manyara se sont formées à conditions oxydantes (~ ∆FMQ +1,5).À l’initiation du rift, le volcanisme dans le bassin de Manyara est caractérisé par des magmas riches en CO2 et pauvres en H2O issus d’au moins 120 km de profondeur sous l'escarpement du rift. La présence de ces magmas riches en CO2 et la faible quantité de roches volcaniques émises à la surface peuvent indiquer que le piégeage et la percolation de ces magmas en profondeur est un déclencheur potentiel des essaims sismiques profonds.
https://tel.archives-ouvertes.fr/tel-01563231

NNT : 2016MONTT114
tel-01563231
https://tel.archives-ouvertes.fr/tel-01563231
https://tel.archives-ouvertes.fr/tel-01563231v2/document
https://tel.archives-ouvertes.fr/tel-01563231/file/2016_BAUDOUIN_archivage.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
IODP Site U1309 was drilled at Atlantis Massif, an oceanic core complex, at 30 degrees N on the Mid-Atlantic Ridge (MAR). We present the results of a bulk rock geochemical study (major and trace elements) carried out on 228 samples representative of the different lithologies sampled at this location. Over 96% of Hole U1309D is made up of gabbroic rocks. Diabases and basalts cross-cut the upper part of the section; they have depleted MORB compositions similar to basalts sampled at MAR 30 degrees N. Relics of mantle were recovered at shallow depth. Mantle peridotites show petrographic and geochemical evidence of extensive melt-rock interactions. Gabbroic rocks comprise: olivine-rich troctolites (>70% modal olivine) and troctolites having high Mg# (82-89), high Ni (up to 2300 ppm) and depleted trace element compositions (Yb 0.06-0.8 ppm); olivine gabbros and gabbros (including gabbronorites) with Mg# of 60-86 and low trace element contents (Yb 0.125-2.5 ppm); and oxide gabbros and leucocratic dykes with low Mg# (<50), low Ni (similar to 65 ppm) and high trace element contents (Yb up to 26 ppm). Troctolites and gabbros are amongst the most primitive and depleted oceanic gabbroic rocks. The main geochemical characteristics of Site U1309 gabbroic rocks are consistent with a formation as a cumulate sequence after a common parental MORB melt, although (lack of systematic) downhole variations indicate that the gabbroic series were built by multiple magma injections. In detail, textural and geochemical variations in olivine-rich troctolites and gabbronorites suggest chemical interaction (assimilation?) between the parental melt and the intruded lithosphere. Site U1309 gabbroic rocks do not represent the complementary magmatic product of 30 degrees N volcanics, although they sample the same mantle source. The bulk trace element composition of Site U1309 gabbroic rocks is similar to primitive MORB melt compositions; this implies that there was no large scale removal of melts from this gabbro section. The occurrence of such a large magmatic sequence implies that a high magmatic activity is associated with the formation of Atlantis Massif. Our results suggest that almost all melts feeding this magmatic system stays trapped into the intruded lithosphere.
ISSN: 0012-821X

hal-00413562
https://hal.archives-ouvertes.fr/hal-00413562
DOI : 10.1016/j.epsl.2008.12.034

Éditeur(s) : HAL CCSD Oxford University Press (OUP): Policy B - Oxford Open Option A Oxford University Press (OUP)
Résumé : International audience
Peridotite xenoliths exhumed by Quaternary alkaline magmatism in the Tahalgha district, southern Hoggar, represent fragments of the subcontinental lithospheric mantle beneath the boundary between the two major structural domains of the Tuareg Shield: the ‘Polycyclic Central Hoggar’ to the east and the ‘Western Hoggar’, or ‘Pharusian Belt’, to the west. Samples were collected from volcanic centres located on both sides of a major lithospheric shear zone at 4°35' separating these two domains. Although showing substantial variations in their deformation microstructures, equilibrium temperatures and modal and chemical compositions, the studied samples do not display any systematic changes of these features across the 4°35' fault. The observed variations rather record small-scale heterogeneities distributed throughout the study area and reflecting the widespread occurrence of vein conduits and metasomatized wall-rocks related to trans-lithospheric melt circulation during the Cenozoic. These features include partial annealing of pre-existing deformation microstructures, post-deformation metasomatic reactions, and trace-element enrichment, coupled with heating from 750–900°C (low-temperature lherzolites) to 900–1150°C (intermediate-T lherzolites and high-T harzburgites and wehrlites). Trace-element modelling confirms that the range of rare earth element (REE) variations observed in the Tahalgha clinopyroxenes may be accounted for by reactive porous flow involving a single stage of basaltic melt infiltration into a light REE (LREE)-depleted protolith. Whole-rock compositions record the final entrapment of disequilibrium metasomatic melts upon thermal relaxation of the veins–wall-rock system. The striking correlations between equilibrium temperatures and trace-element enrichment favor a scenario in which the high-temperature peridotites record advective heat transport along melt conduits, whereas the intermediate- and low-temperature lherzolites reflect conductive heating of the host Mechanical Boundary Layer. This indicates that the lithosphere did not reach thermal equilibrium, suggesting that the inferred heating event was transient and was rapidly erased by thermal relaxation down to the relatively low-temperature present-day geotherm. The low-T (<900°C) deformed lherzolites (porphyroclastic to equigranular) are characterized by only incipient annealing and LREE-depleted clinopyroxene compositions. They were only weakly affected by the Cenozoic events and could represent relatively well-preserved samples from rejuvenated Pan-African lithosphere. Extensive lithospheric rejuvenation occurred either regionally during the Pan-African orogeny, as a result of lithospheric delamination or thermomechanical erosion after thickening, or more locally along the meridional shear zones. The low-T Tahalgha lherzolites are comparable with lherzolites from Etang de Lherz, southern France, interpreted as lithospheric mantle rejuvenated by melt-induced refertilization during a late stage of the Variscan orogeny.
ISSN: 0022-3530

hal-01107410
https://hal.archives-ouvertes.fr/hal-01107410
DOI : 10.1093/petrology/egu056

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : The activity of the Damavand volcano (Central Alborz, northern Iran) began 1.8 Ma ago and continued up to 7 ka BP. Although the volcanic suite is clearly of shoshonitic affinity, only two petrographic types can be distinguished in the studied lavas: (1) weakly differentiated absarokites (49 < %SiO2 < 51), scattered around the volcano but with a regional extension, (2) highly differentiated banakites (59 < %SiO2 < 63), which form the bulk of the 4,000 m thick volcanic pile. All lavas are alkalic (3.7 < %K2O < 5), REE and LILE-rich (e.g., 85 < La < 148 ppm; 9 < Th < 32 ppm) and show highly fractionated REE patterns (69 < La/Yb < 115) and pronounced Nb-Ta negative anomalies. The absarokites are characterised by Sr (0.7045-0.7046) and Nd (0.51266-0.51269) isotope compositions close to the Bulk Earth values, and distinct from those of the banakites (0.7047 < Sr-87/Sr-86 < 0.7049, 0.51258 < Nd-143/Nd-144 < 0.51262). The Pb isotope ratios are also slightly lower in the absarokites than in the banakites (18.71 < Pb-206/Pb-204 < 18.77, 15.62 < Pb-207/Pb-204 < 15.63, 38.85 < Pb-208/Pb-204 < 38.91, and 18.77 < Pb-206/Pb-204 < 18.84, 15.62 < Pb-207/Pb-204 < 15.64, 38.94 < Pb-208/Pb-204 < 39.06, respectively). Overall, there is a clear tendency towards higher Sr, Pb and lower Nd isotope ratios with increasing degree of differentiation. This study suggests that the absarokites result from a low degree of partial melting (similar to 5%) of a highly metasomatized mantle source, which inherited its characteristics from an old subduction setting. The initiation of volcanic activity 1.8 Ma ago results from variations in the lithospheric thermal regime, probably related to lithospheric delamination as proposed for Anatolia (Pearce et al. 1990). The banakites are mainly generated by extensive fractional crystallisation (similar to 70%) of the absarokitic magma, with a limited amount (a few percents) of assimilation of an old crustal component, in the form of bulk assimilation or AFC processes, which both can explain the Sr, Nd and Pb isotope data.
ISSN: 1437-3254

hal-00411553
https://hal.archives-ouvertes.fr/hal-00411553
DOI : 10.1007/s00531-006-0159-6

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The In-Ezzane volcanic district (EZD), located at the triple junction of Algeria, Niger and Libya belongs to the Eastern Hoggar, covers 350 km2 and includes 9 volcanic edifices that are probably aligned along NW-SE faults, parallel to the Tafassasset valley. The low volume (0.7 and 1 km3) of emitted lavas, the similar morphology of the monogenic cones and the lack of differentiated rocks indicate that the volcanic activity of the EZD was restricted in time and volume. The new K-Ar age (i.e. 2.86 ± 0.07 Ma) indicates that the EZD is contemporaneous with the last alkali volcanism paroxysm in Hoggar and with the nearby Libyan volcanics. The EZD alkali basalts (mainly basanite) show a remarkable homogeneous compositions both in major elements (44.8 ⩽ SiO2 ⩽ 45.8 wt.%; 5.2 ⩽ (Na2O + K2O) ⩽ 6.2 wt.%), trace elements (4.3 ⩽ Th ⩽ 5.5 ppm; 34.7 ⩽ La ⩽ 44.7 ppm; 16.1 < La/Yb(N) < 21.6) and radiogenic isotopes (0.70285 < 87Sr/86Sr < 0.70303; 0.51298 < 143Nd/144Nd < 0.51301; (19.212 < 206Pb/204Pb < 19.340, 15.589 < 207Pb/204Pb < 15.602 and 38.834 < 208Pb/204Pb < 38.903). Relative to the Hoggar alkaly basalts the EZD basalts appear systematically impoverished in incompatible elements and show a depleted signature both in Sr and Nd isotopes (almost MORB-like). The Pb isotopes are relatively enriched and intermediate between tholeiites and alkali basalts of the Hoggar. This unusual geochemical signature, is uneasy to reconcile with the known characteristics of the Hoggar swell, and would rather fingerprint a circum cratonic mantle lying beneath the west border of the Murzuq craton (Libya).
ISSN: 0899-5362

hal-01054340
https://hal.archives-ouvertes.fr/hal-01054340
DOI : 10.1016/j.jafrearsci.2013.12.001

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Tso Morari serpentinites in the Ladakh area, northwest Himalaya, originated from the forearc mantle overlying the northward subducting Neo-Tethys lithosphere and the margin of the Indian continent. The serpentinites are characterized by high concentration of fluid-mobile elements (FME: As, Sb, B, Li, and U) compared to ophiolitic or abyssal serpentinites. The Pb isotopic compositions of serpentinites show influence of the subducted Indian continental lithosphere. Trace element concentrations of antigorite determined in situ with Laser Ablation High Resolution Inductively Coupled Mass Spectrometer (LA-HR-ICP-MS) show high contents of FME including Pb, in contrast to the spatially associated iron oxides. Rare earth elements (REE) and compatible elements, such as Sc and Co, remained immobile during the hydration, allowing the identification of the primary minerals (olivine or orthopyroxene) from which serpentine formed. Serpentinized olivine displays higher Sb and As concentrations (up to 1000 x PM) than serpentinized orthopyroxenes that are enriched in Pb, Cs and Li (2 to up to 10 x PM).;We propose that the observed FME distribution in two types of serpentine reflect the differential incorporation of FME during the downward movement of the serpentinite along the subduction plane. At temperature lower than 400 degrees C, at shallow depths, olivine is preferentially serpentinized and incorporates elements that are fluid soluble at low temperatures, such as Sb and As. Above 400 degrees C, orthopyroxene is hydrated and incorporates Pb, Cs, Li and possibly Ba. Boron and U are incorporated in both types of serpentine suggesting that they are released from slabs at temperatures around 300-400 degrees C. The serpentine acts as a sink for water, but also for FME and transports them to deeper and hotter levels in the mantle, down to the isotherm 600-650 degrees C where dehydration occurs.
ISSN: 0009-2541

hal-00475565
https://hal.archives-ouvertes.fr/hal-00475565
DOI : 10.1016/j.chemgeo.2009.10.002

Éditeur(s) : Elsevier Science Bv
Résumé : Climatic and anthropogenic changes are able to engender modifications in the aerosol composition at different geographical and temporal scales The present study addresses this question for the trace metal concentrations (TM = Al, Fe, Mn, Co, Ni, Cu, Pb, Cd and Zn) of aerosol from the North-western Mediterranean coast of France (Cap Ferrat, nearby Nice) between 1986 and 2008. From seasonal variations (2006-08) and decadal trends (1986-2008) of TM concentrations. three groups of elements can be distinguished They consist of different aerosol sources: crustal-derived elements (Al, Fe. Mn and Co), trace metals of anthropogenic origin (Pb, Cd and Zn) and a third, intermediate, group of trace metals that presented both anthropogenic and natural/crustal influences (Ni and Cu). Reproducible seasonal patterns were observed for crustal and intermediate elements with highest concentrations between May and November. while anthropogenic trace metals did not show a pronounced seasonal cycle Nevertheless, highest concentrations of anthropogenic trace metals occurred mostly in autumn/winter. Aerosol concentrations of anthropogenic TMs decreased remarkably over the last two decades, while crustal trace metals did not show any evolution Nickel and copper aerosol concentrations remained constant, as well. Lead concentrations decreased from 1986 (29.34 ng m(-3)) to 2008 (3.33 ng m(-3)). overall by 90%. Cadmium and zinc aerosol concentrations decreased by 66 and 54%, respectively, between 1998 and 2006-08. from 0.27 to 0.09 ng m(-3) and from 23.9 to 10.9 ng m(-3). respectively. These findings demonstrate the response of the atmospheric environment to the implementation of antipollution policies Possible changes of trace metal emissions sources and local influences are discussed (C) 2010 Elsevier B V. All rights reserved.
Science Of The Total Environment (0048-9697) (Elsevier Science Bv), 2010-06 , Vol. 408 , N. 13 , P. 2629-2638

Droits : 2010 Elsevier B.V. All rights reserved.
http://archimer.ifremer.fr/doc/00006/11688/8503.pdf
DOI:10.1016/j.scitotenv.2010.02.042
http://archimer.ifremer.fr/doc/00006/11688/

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Major and trace element signatures and Sr-Nd-Pb isotope data for muscovite (Ms)-bearing amphibolite blocks and associated muscovite-bearing trondhjemite and quartz-muscovite rocks from the Sierra del Convento melange (eastern Cuba) indicate that Proto-Caribbean oceanic crust underwent wet partial melting processes during Mesozoic subduction and after accretion to the upper plate. Trace element normalized patterns of Ms-bearing amphibolites are enriched in light rare earth elements (LREE) and large-ion lithophile elements (LILE) and evidence variable trace element transfer from the Proto-Caribbean subducting slab to the mantle wedge. Ms-bearing trondhjemites show LREE enrichment and HREE depletion and have geochemical features similar to adakites, including SiO2>56 wt.%, high Na2O contents (5.5-9.0 wt.%) and high Sr/Y (16-644). We consider that the trondhjemites represent primary and natural melts formed by deep partial melting of the subducting slab which did not significantly react with the mantle wedge before intrusion in the subduction channel. The Ms-bearing trondhjemites show different geochemical and petrological signatures compared with the Ms-free tonalites-trondhjemites from Sierra del Convent, that are interpreted as primary slab melts. These differences support the idea that partial melting processes in the Sierra del Convento subduction channel were triggered by the infiltration of fluids derived from three distinct subducted sources: sediments, altered mid-ocean ridge basalts (MORB), and serpentinites. In this scenario, the pegmatitic quartz-muscovite rocks, which are highly enriched in LILE, probably represent the crystallization products of fluids derived by differentiation of the trondhjemitic melts.
ISSN: 0024-4937

hal-00669881
https://hal.archives-ouvertes.fr/hal-00669881
DOI : 10.1016/j.lithos.2011.07.011

Éditeur(s) : HAL CCSD Wiley
Résumé : International audience
The natural river water certified reference material SLRS-5 (NRC-CNRC) was routinely analysed in this study for major and trace elements by ten French laboratories. Most of the measurements were made using ICP-MS. Because no certified values are assigned by NRC-CNRC for silicon and 35 trace element concentrations (rare earth elements, Ag, B, Bi, Cs, Ga, Ge, Li, Nb, P, Rb, Rh, Re, S, Sc, Sn, Th, Ti, Tl, W, Y and Zr), or for isotopic ratios, we provide a compilation of the concentrations and related uncertainties obtained by the participating laboratories. Strontium isotopic ratios are also given. Le matériau de référence certifié d'eau de rivière naturelle SLRS-5 (NRC-CNRC) est analysé régulièrement comme contrôle qualité par dix laboratoires français étudiant les éléments majeurs et en trace dans les solutions naturelles. La plupart des mesures sont réalisées par ICP-MS. Le silicium et 35 éléments en trace (terres rares, Ag, B, Bi, Cs, Ga, Ge, Li, Nb, P, Rb, Rh, Re, S, Sc, Sn, Th, Ti, Tl, W, Y et Zr) ne sont pas certifiés par NRC-CNRC. Aucun rapport isotopique n'est disponible. Nous proposons, pour ces éléments, des valeurs moyennes et leurs incertitudes associées obtenues par les différents laboratoires participants. Le rapport isotopique de Sr est aussi mesuré.
ISSN: 1639-4488

hal-00906166
https://hal.archives-ouvertes.fr/hal-00906166
DOI : 10.1111/j.1751-908X.2013.00232.x

Éditeur(s) : HAL CCSD Mineralogical Society of America
Résumé : International audience
Accessory phases are important hosts of trace elements; allanite may contain >90% of the REE in a bulk rock. The mobility and redistribution of several trace elements, notably HREE, Th, U, and Y is thus controlled by reactions involving allanite and other REE phases, as well as several rock-forming minerals. As these elements are commonly concentrated in mature elastic sediments, a suite of impure quartzite was studied. Two eclogite facies samples from the Monometamorphic Cover Complex of the Sesia Zone (Western Italian Alps) are presented in some detail, as they reveal a remarkably rich spectrum of reaction relationships that involve REE phases.;Two allanite-forming reactions were inferred from textures and phase compositions;(1) monazite + Ca-silicate(?) + fluid -> allanite + apatite + thorite;;(2) monazite + thorite + Ca-silicate(?) + fluid -> Th-rich allanite + auerlite +/- apatite.;Petrographic observations and thermodynamic models suggest that allanite entered the HP assemblage at similar to 530 degrees C and 17-18 kbar during prograde metamorphism.;In one sample, allanite is rimmed by epidote rich in Y and HREE that grew at the expense of xenotime. Two net transfer reactions were derived;(3) xenotime + allanite + fluid -> Y-rich epidote + apatite + thorite;;(4) xenotime + allanite + fluid -> Y-rich epidote + aeschynite + thorite + (phosphate?).;Textural relationships and trace element analyses of coexisting allanite/monazite and xenotime/Y-rich epidote reveal systematic partitioning of the REE. Partition coefficients for the HREE are compatible with equilibrium fractionation, whereas those for the LREE show patterns that seem to be inherited from the precursor phases, in this case zircon with variable LREE composition.
ISSN: 0003-004X

hal-00745674
https://hal.archives-ouvertes.fr/hal-00745674
DOI : 10.2138/am.2012.3832

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We provide new insights into the geochemistry of serpentinites from the Alpine orogenic wedge representing a paleo-subduction zone. These serpentinites are derived from similar oceanic protoliths, but they have experienced different metamorphic conditions related to three different structural levels of the paleo-subduction zone ((1) obducted: Chenaillet ophiolite, (2) accretionary wedge: Queyras Schistes lustrés complex and (3) serpentinite channel: Monviso ophiolite). Metamorphism undergone by these three units is well defined, increasing eastward from sub-greenschist to eclogite facies conditions, and allows us to examine trace element behavior from the oceanic ridge environment to subduction. Serpentinites first record moderate trace element enrichment due to seawater interaction resulting in the replacement of olivine and pyroxene by chrysotile and lizardite below 300 °C. In the sediment-dominated accretionary wedge, serpentinites are strongly enriched in fluid-mobile-elements (B, Li, As, Sb, and Cs) and act as a trapping system following the metamorphic gradient (from 300 to 390 °C) up to total replacement of the lizardite/chrysotile assemblage by antigorite. Under higher temperature conditions (T > 390 °C), no enrichment was observed, and some fluid-mobile elements were released (B, Li, Cs, and Sr). Moreover, in the serpentinite channel (T > 460 °C), most of the fluid-mobile elements are absent due to the scarcity of metasediments which prevent geochemical exchange between metasediments and serpentinites. This is also due to the onset of antigorite breakdown and the release of fluid-mobile elements. Thus, we emphasize that the geochemistry of Alpine serpentinites is strongly dependent on (1) the grade of metamorphism and (2) the ability of metasediments to supply fluid-mobile elements. We conclude that serpentinites act as a trap-and-release system for fluid-mobile elements in a subduction context.
ISSN: 0009-2541

hal-00996839
https://hal.archives-ouvertes.fr/hal-00996839
DOI : 10.1016/j.chemgeo.2013.02.008

Éditeur(s) : Inter-research
Résumé : Chemical tracers (e. g. stable isotopes or trace metals) are increasingly used to study trophic ecology and feeding habits of marine organisms and various factors can affect their values. The aim of the present study was to provide information on ontogenic effects on stable carbon and nitrogen values (delta C-13 and delta N-15) and on cadmium (Cd) and mercury (Hg) concentrations in 5 cephalopod species from the Bay of Biscay (North-East Atlantic Ocean). To this end, individuals belonging to 3 species showing the widest range of sizes were analysed for muscle delta C-13 and delta N-15 values and muscle Hg, and digestive gland Cd concentrations. Results showed that stable isotope ratios allowed discrimination of specific feeding strategies during ontogenesis. Segregation between 5 cephalopod species in terms of trophic ecology was also evidenced (different isotopic niches). In contrast, Hg concentrations varied over the same order of magnitude in these 5 cephalopod species, despite higher levels in the benthic octopus Eledone cirrhosa. Consistently, Hg concentrations followed the same ontogenic pattern and increased with increasing body size/age of cephalopods. Finally, Cd concentrations varied over 3 orders of magnitude among the 5 species. Despite possible effects of physiology in terms of metal bioaccumulation, Cd concentrations were likely to reflect specific feeding preferences or feeding zones and ontogenic variability within a single species. Thus, ontogenic effects have to be taken into account when stable isotope ratios of carbon and nitrogen or trace metals are used as ecological tracers; the best recommendation being to focus on a given class age.
Marine Ecology Progress Series (0171-8630) (Inter-research), 2011 , Vol. 433 , P. 107-120

Droits : Inter-Research 2011 · www.int-res.com
http://archimer.ifremer.fr/doc/00166/27761/25938.pdf
DOI:10.3354/meps09159
http://archimer.ifremer.fr/doc/00166/27761/

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We present new groundmass K–Ar ages obtained using the Cassignol–Gillot technique, together with whole-rock major and trace elements, from Les Saintes islands (Terre-de-Haut and Terre-de-Bas). They are located along the northern Lesser Antilles inner arc, between Basse-Terre Island (western Guadeloupe) to the North and Dominica Island to the South. Ages reveal that the main volcanic phase in Terre-de-Haut occurred between 2.98 ± 0.04 and 2.00 ± 0.03 Ma, and show that the onset of sub-aerial volcanism in Terre-de-Haut is slightly older (~ 0.2 Myr) than that of northern Basse-Terre. Volcanism in Les Saintes resumed to the west, with the rapid construction of Terre-de-Bas Island at 0.888 ± 0.009 Ma. Major elements analyses show that most lavas from Les Saintes belong to a sub-alkaline medium-K magmatic series and are mainly andesites, with relatively rare basaltic andesites and dacites. Rare earth elements spectra reveal a strong enrichment in light elements, as observed for Dominica lavas, and significantly higher than observed for Basse-Terre lavas. Noticeably, Terre-de-Bas spectra display more enriched patterns relative to those from Terre-de-Haut lavas, suggesting a lower degree of partial melting or a stronger sedimentary component incorporated to the subducting slab. Overall, geochemical signatures of Les Saintes and Dominica magmas display common characteristics, which we interpret as reflecting strong petrogenetic affinities, while both are significantly different from that of Basse-Terre lavas. Finally, this study provides a precise timing of subaerial volcanism of Les Saintes Islands, which can be used to better constrain through time the development of the tectonic half-graben where these islands lie, which is part of the arc-parallel en-echelon faults system accommodating the oblique convergence of the North American plate from Montserrat to Dominica. In addition, these results reveal that the initiation of Terre-de-Haut volcanism is presently the oldest dated volcanism from the northern part of the Lesser Antilles active arc.
ISSN: 0377-0273

hal-01067336
https://hal.archives-ouvertes.fr/hal-01067336

Éditeur(s) : HAL CCSD
Résumé : IODP Hole U1309D (IODP Exp. 304-305, 30°N) and ODP Site 1275 (ODP Lag 209, 15°45?N) sampled two oceanic core complexes, at the Mid-Atlantic Ridge. The recovered rocks are mostly gabbroic with some very primitive and olivine rich (Ol>70%). In Hole U1309D, trace element compositions of clinopyroxene and plagioclase poikiloblasts from olivine-rich rocks ndicate that they crystallized from the same melt in all lithologies. Olivine trace element compositions are in disequilibrium with the two other minerals. Olivine crystallographic preferred orientations are weak, with a relatively strong uncommon [001] concentration but consistent with deformation by dislocation creep with activation of the high temperature (010) [100] slip system, commonly described in asthenospheric mantle. The joint study of geochemical processes and microstructures in these rocks suggest a complex crystallization history in an open system with percolation of large volume of MORBtype melt and interaction with the depleted shallow mantle. Olivine-rich rocks are interpreted as the ultimate residue of these melt-mantle reaction processes. At Site 1275, the formation of the more evolved rocks of the gabbroic series is not related to the impregnation event creating olivine-rich rocks.
These rocks represent late magmatic injections, which are completely crystallized at depth as intrusivegabbroic bodies. The results presented in this thesis are consistent with the formation of oceanic core complexes associated with relatively strong magmatic activity, and with the crystallization of most of melt in the lithosphere without basaltic counterpart erupted on the seafloor.
Le puits IODP U1309D (Exp. IODP 304-305, 30°N) et le Site ODP 1275 (Leg ODP 209, 15°45'N) ont permis d'échantillonner deux core complexes océaniques de la dorsale Médio-Atlantique. Les roches récupérées sont principalement gabbroïques dont certaines très primitives et riches en olivine (ol >70%). Dans le puits U1309D, les compositions en éléments en trace des poeciloblastes de clinopyroxène et de plagioclase des roches riches en olivine indiquent qu'ils précipitent depuis le même magma dans toutes les lithologies. La composition en éléments en trace des olivines est en déséquilibre avec ces deux minéraux. Les fabriques cristallographiques de l'olivine sont faibles avec une concentration sur [001] inhabituelle, néanmoins compatibles avec une déformation plastique de haute température, avec l'activation du système de glissement (010) [100] communément décrit dans le manteau asthénosphérique. L'étude conjointe des caractéristiques géochimiques et microstructurales de ces roches met en lumière une histoire complexe de cristallisation dans un système ouvert où de larges volumes de magma de type MORB ont percolé et interagi avec le manteau appauvri superficiel. Ces roches riches en olivine représenteraient le résidu ultime de ces réactions liquide-manteau. Au site 1275, la formation des roches les plus évoluées de la série n'apparaît pas liée à l'événement d'imprégnation formant les roches riches en olivine. Ces roches correspondent à des injections tardives de magma qui ont entièrement cristallisé en profondeur sous forme de plutons intrusifs. Les résultats présentés dans ce mémoire sont compatibles avec une formation des core complexes océaniques associée à une activité magmatique relativement importante, et à une cristallisation complète de tout ou partie de ces magmas dans la lithosphère sans contre-partie volcanique en surface.
https://tel.archives-ouvertes.fr/tel-00354807

tel-00354807
https://tel.archives-ouvertes.fr/tel-00354807
https://tel.archives-ouvertes.fr/tel-00354807/document
https://tel.archives-ouvertes.fr/tel-00354807/file/these_MD.pdf

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
At Cima di Gagnone, garnet peridotite and chlorite harzburgite lenses within pelitic schists and gneisses correspond to eclogite-facies breakdown products of hydrated peridotites and are suitable for studying dehydration of serpentinized mantle. Thermobarometry and pseudosection modelling yield peak temperatures of 750-850°C and pressures <3 GPa. The minimum temperature recorded by the garnet peridotite corresponds to the maximum conditions experienced by the chlorite harzburgite, suggesting that these rocks recrystallized cofacially at ∼800°C. Alternatively, they might have decoupled during subduction, as achieved in tectonically active plate interface boundaries. The major and rare earth element (REE) variability of the peridotites was mostly acquired during pre-subduction mantle evolution as a result of partial melting and reactive melt flow. The ultramafic suite is also characterized by fluid-mobile element enrichments (B, Pb, As, Sb, Cs, Li, U, Be), which confirm derivation from variably serpentinized protoliths. Similarity in the U, Pb, B, Li and Sr contents of the Gagnone peridotites to present-day oceanic serpentinites suggests that these elements were partly taken up during initial serpentinization by seawater-derived fluids. Positive Be, As and Sb anomalies suggest involvement of fluids equilibrated with crustal (metasedimentary) reservoirs during subsequent subduction metamorphism and peridotite entrainment in (meta)sediments. Fluid-mobile element enrichment characterizes all peak eclogitic minerals, implying that multiple hydration events and element influx pre-dated the eclogite-facies dehydration. Peak anhydrous minerals retain B, Li, As and Sb concentrations exceeding primitive mantle values and may introduce geochemical anomalies into the Earth's mantle. The relatively low contents of large ion lithophile elements and light REE in the Gagnone peridotites with respect to much higher enrichments shown by metasomatized garnet peridotite pods hosted in migmatites (Ulten Zone, Eastern Alps) suggest that the crustal rocks at Gagnone did not experience partial melting. The Gagnone garnet peridotite, despite showing evidence for chlorite dehydration, retains significant amounts of fluid-mobile elements documenting that no partial melting occurred upon chlorite breakdown. We propose that the Gagnone ultramafic rocks represent a prime example of multi-stage peridotite hydration and subsequent dehydration in a plate interface setting.
ISSN: 0022-3530

hal-01054319
https://hal.archives-ouvertes.fr/hal-01054319
DOI : 10.1093/petrology/egt068

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
To understand the deep cycle of water, upper mantle water content and distribution between nominally anhydrous minerals (NAMs) and hydrous minerals (e.g., amphibole) must be constrained. We need then to understand H behaviour during mantle melting and metasomatism. Major, minor and trace element compositions including water contents were obtained on ten xenoliths of spinel-bearing peridotites from the Ray Pic locality, in the Southern part of the Massif Central (France). The sample suite investigated here is composed of rather fertile lherzolites (89.4 ≤ Fo ≤ 90.8%; 11.3 ≤ cr# in spinel ≤ 21.1%; 0.942 ≤ [Yb]cpx ≤ 1.90 ppm; cpx: clinopyroxene), which can be best explained by batch melting, with degree of melting between 3 and 10%. These xenoliths contain up to 8% modal amphibole. Three groups are defined as a function of the amphibole modal abundance (above or below 1%) and equilibrium temperature (above or below 1000 °C). Results show no clear positive correlation between modal metasomatism (amphibole) and incompatible element enrichment in cpx. Trace element compositions in cpx show strong enrichments of the most incompatible elements (e.g., (La/Sm)PM as high as 15.7; PM: normalised to primitive mantle values), but strong negative anomalies of the high field strength elements (e.g., (Th/Nb)PM as high as ~ 680). Such trace element fractionations are usually ascribed to the so-called carbonatitic metasomatism involving the percolation of small volume melts which are enriched in volatiles. The hydrogen concentrations in cpx range from 203 to 330 ppm wt. H2O, in orthopyroxene from 66 to 160 ppm wt. H2O and in olivine from 2 to 6 ppm wt. H2O. These values are within the common concentration range of other spinel-bearing peridotites. Amphiboles contain 1.9 ± 0.5 wt.% of H2O.The effect of metasomatism on water abundances in NAMs is not straightforward. Hydrous metasomatism (i.e., leading to the crystallisation of OH-bearing amphibole) has no effect on the water content of the co-existing NAMs. This suggests thus that the occurrence of hydrous minerals, such as amphibole, does not systematically imply that the coexisting NAMs are water-rich (saturated). Further, the percolation of volatile-rich small volume melts, which is fingerprinted by the strong enrichment of the incompatible elements, has also no clear effect on the water content of the NAMs. These data are thus difficult to reconcile with the admitted highly incompatible behaviour of H in upper mantle minerals.
ISSN: 0024-4937

hal-01278062
https://hal.archives-ouvertes.fr/hal-01278062
DOI : 10.1016/j.lithos.2015.08.013

Éditeur(s) : HAL CCSD Elsevier
Résumé : Understanding chemical element mobility during high-pressure metamorphism is paramount to the knowledge of the transformations occurring during the course of eclogite-facies metamorphism. In particular, the role of deformation and fluid circulation appear essential. In order to better decipher this role, we investigated two eclogite-facies samples from the Lindas Nappe in the Bergen arcs (Norwegian Caledonides), which are related to a fluid/deformation metamorphic event. This study, based on detailed microtextural investigations, coupled with major and trace element analyses, either in situ EMPA and LA-ICP-MS or by conventional ICP-MS nebulisation on mineral fractions, illustrates the complexity of chemical reactions accompanying the eclogite- and amphibolite-facies metamorphism. A single eclogite-facies mineral species two eclogite-facies (i.e. phengite and epidote) depicts various chemical features depending on its textural location at thin-section scale. The correlation with the mineralogical reaction occurring in each textural site demonstrates that the compositional variations are inherited from the precursor minerals. Thus, the composition of eclogite-facies minerals is locally controlled by the composition of few hundred-micron domains. On the contrary, alteration phases of the amphibolite facies (symplectite and calcic amphibole) display clear enrichment in LILE, Pb, Sr and LREE compared to their precursor minerals (omphacite and garnet). This supports that the transport of elements at hand-sample scale was enhanced during the retrogression and elements were efficiently delocalised from one textural site to another. The contrasting behaviour of element mobility between peak eclogite-facies metamorphism and retrogression can be explained in terms of rate processes and fluid/deformation activity. During eclogitisation,deformation allows the formation of textural and mineralogical microdomains. Contemporaneously the fluid circulation favours the development of heterogeneities by transport of elements in excess towards areas protected from deformation where phengite-bearing quartz lenses crystallise. This, together with the very fast recrystallisation of eclogite-facies minerals, results in a heterogeneous redistribution of elements at sample scale and in a chemical disequilibrium between different microdomains of hundred-micron size. During retrogression in the amphibolite facies, coeval with long-term ductile deformation, the fluids act as an efficient vector to redistribute the elements from a given textural site to another and, thus, allow to reach, at hand-sample scale, a new chemical equilibrium between the different crystallising phases.
ISSN: 0024-4937

hal-00404602
https://hal.archives-ouvertes.fr/hal-00404602
DOI : 10.1016/j.lithos.2006.10.001

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
A subject of continuing debate is how the Earth's lithospheric portion of the upper mantle has remained the thickest (> 200 km) and oldest (> 3 Gy) beneath cratons and is yet surrounded by a vigorously convecting asthenosphere. It is generally admitted that water is a key parameter in the strength and longevity of cratonic roots, because olivine, the main phase of the lithospheric mantle, becomes stronger if its water content decreases. Expanding upon the work presented in Novella et al. (2015) and Taylor et al. (2016), we report new water contents for additional olivine inclusions in diamonds together with the trace-element composition for all olivine inclusions, as well as for mantle xenoliths from various kimberlite pipes located on the Siberian craton. The olivine diamond inclusions from this study have systematically low-water contents (< 50 ppmw H2O), moderate to high forsterite (e.g., Fo91–94) contents and low Ni, Co, and Zn ppm contents (e.g., < 2848, < 108, and < 47 ppm, respectively). In contrast, olivines from Siberian craton mantle xenoliths have a wide range of water contents (6–323 ppmw H2O) and extend to lower-Fo (91–92), Ni, Co, and Zn-rich compositions, compared to the diamond inclusions. Depleted incompatible trace-element concentrations in olivine (0.1–0.001 × Primitive Mantle) advance our hypothesis for the protogenetic origins for the majority of Siberian diamond inclusions. These observations are consistent with the peridotite xenoliths as representing a part of the cratonic lithosphere that has experienced melt re-fertilization, which has also transported water. The olivine diamond inclusions, on the other hand, preserve “micro-samples” of an initial, dry cratonic lithosphere, mostly resulting from melting events. These inclusions are likely sourced from the initial cratonic mantle lithosphere, which thereby, resisted delamination over time, due to its buoyancy and strength, imparted from melt and water depletion, respectively. And thus, our data provides a major argument that the kimberlite-hosted mantle xenoliths may be more metasomatized than common rocks at the base of the Siberian and other cratonic roots away from kimberlite fields.
ISSN: 0024-4937

hal-01467731
https://hal.archives-ouvertes.fr/hal-01467731
DOI : 10.1016/j.lithos.2016.07.023

Éditeur(s) : HAL CCSD Wiley
Résumé : International audience
Digestive tubules of Strombidae are composed by three cell types: digestive cells, vacuolated cells, and crypt cells. The last one is characterized by the presence of intracellular granules identified as spherocrystals. Such structures are known to occur in basophilic cells of gastropod digestive gland, where they are supposed to be involved in the regulation of some minerals and in detoxification. In this study, energy-dispersive X-ray analysis (EDX) and energy filtered transmission electron microscopy (EFTEM) were used to determine the elemental content of spherocrystals in two Strombidae, Strombus gigas and Strombus pugilis. In freshly collected individuals of both species, the following elements were detected: Ca, Fe, Mg, P, and Zn. Aluminum and Mn were also detected in S. gigas. Their presence in spherocrystals indicates that, in Strombidae, spherocrystals are involved in the regulation of minerals and essential trace metals. In order to answer the question ''are spherocrystals involved in nonessential trace metals scavenging?,'' artificial cadmium and lead exposure by both waterborne and dietary pathways was applied to S. pugilis. No evidence of cadmium (Cd(NO3)2) or lead (Pb(NO3)2) provided by food was found in spherocrystals. Cadmium provided in water (Cd(NO3)2 and CdCl2) causes structural modifications of the digestive gland; however, this element was not trapped in spherocrystals. These results suggest that spherocrystals are not involved in detoxification of such nonessential trace metals.
ISSN: 1059-910X

hal-00743762
https://hal.univ-antilles.fr/hal-00743762
DOI : 10.1002/jemt.21073