Éditeur(s) : Oxford Univ Press
Résumé : In subduction zones, melting and dehydration of the subducted slab introduce material into the mantle wedge and modify its chemical and isotopic composition. As a consequence, island arc lavas differ significantly from mid-ocean ridge basalts and ocean island basalts. In some arcs, the composition of lavas is strongly influenced by the sedimentary material introduced with the slab; in others, magma composition is mainly affected by aqueous fluids released by the slab. The Lesser Antilles arc is known for its extreme continental-crust-like signature but for some Lesser Antilles lavas subducted sediments are barely involved and enrichment in fluid-mobile elements (Ba, U, Sr, Pb, etc.) is the dominant feature. Here we evaluate whether La/Sm is a quantitative proxy of sediment involvement in volcanic arcs, and we relate dehydration and melting processes to the temperature and pressure conditions of the slab. We use Martinique as a case study because in this island both dehydration and sediment melting fingerprints coexist. We measured major and trace elements for about 130 age-constrained samples, carefully chosen to cover all volcanic phases of Martinique (25 Ma to present). Using these results we demonstrate that: (1) weathering does not modify the La/Sm ratio; (2) fractional crystallization of amphibole and/or garnet does not increase La/Sm by more than 20%; (3) rare earth element transfer from wall-rock to magma during fractionation is not significant; (4) melting of the mantle source increases La/Sm by only about 20%. As a consequence, we show that the proportion of slab sediment incorporated in the mantle wedge controls the La/Sm ratio of the source. The observed correlations between La/Sm and Nd and Hf isotopic compositions indicate that the effect of sediment addition is the overwhelming factor: La/Sm is a good proxy for slab sediment proportion in Martinique. We observe a geographical gradient between slab dehydration and sediment melting on the island. Whereas lavas located on the western side of the island display a clear sedimentary input in their source, lavas located on the eastern side of the island, closer to the trench, are clearly influenced by dehydration of the subducted slab. In addition, the aqueous fluids clearly come from the subducted basalt and they did not interact with the overlying sediments. The influence of sediment added to the source of the magmas increases from the eastern part to the western part of the island. We relate this geographical change to the pressure and temperature conditions at the slab surface. Sediments probably cross their solidus under Martinique and hydrous melting is triggered. Finally, we show that under all volcanic arcs where the signature of sediments overwhelms the signature of fluids, the slab surface reaches P-T conditions that allow the subducted sediments to melt. Inversely, under most volcanic arcs where the signal of aqueous fluids dominates over sediment melts, the subducted slab is not hot enough for the sedimentary pile to melt.
Journal Of Petrology (0022-3530) (Oxford Univ Press), 2012-12 , Vol. 53 , N. 12 , P. 2441-2464

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/00113/22392/20234.pdf
DOI:10.1093/petrology/egs055
http://archimer.ifremer.fr/doc/00113/22392/

Éditeur(s) : HAL CCSD Elsevier
Résumé : Primary arc melts may form through fluxed or adiabatic decompression melting in the mantle wedge, or via a combination of both processes. Major limitations to our understanding of the formation of primary arc melts stem from the fact that most arc lavas are aggregated blends of individual magma batches, further modified by differentiation processes in the sub-arc mantle lithosphere and overlying crust. Primary melt generation is thus masked by these types of second-stage processes. Magma-hosted peridotites sampled as xenoliths in subduction zone magmas are possible remnants of sub-arc mantle and magma generation processes, but are rarely sampled in active arcs. Published studies have emphasised the predominantly harzburgitic lithologies with particularly high modal orthopyroxene in these xenoliths; the former characteristic reflects the refractory nature of these materials consequent to extensive melt depletion of a lherzolitic protolith whereas the latter feature requires additional explanation.Here we present major and minor element data for pristine, mantle-derived, lava-hosted spinel-bearing harzburgite and dunite xenoliths and associated primitive melts from the active Kamchatka and Bismarck arcs. We show that these peridotite suites, and other mantle xenoliths sampled in circum-Pacific arcs, are a distinctive peridotite type not found in other tectonic settings, and are melting residues from hydrous melting of silica-enriched mantle sources. We explore the ability of experimental studies allied with mantle melting parameterisations (pMELTS, Petrolog3) to reproduce the compositions of these arc peridotites, and present a protolith (‘hybrid mantle wedge’) composition that satisfies the available constraints. The composition of peridotite xenoliths recovered from erupted arc magmas plausibly requires their formation initially via interaction of slab-derived components with refractory mantle prior to or during the formation of primary arc melts. The liquid compositions extracted from these hybrid sources are higher in normative quartz and hypersthene (i.e., they have a more silica-saturated character) in comparison with basalts derived from prior melt-depleted asthenospheric mantle beneath ridges. These primary arc melts range from silica-rich picrite to boninite and high-Mg basaltic andesite along a residual spinel harzburgite cotectic. Silica enrichment in the mantle sources of arc-related, subalkaline picrite-boninite-andesite suites coupled with the amount of water and depth of melting, are important for the formation of medium-Fe (‘calc-alkaline’) andesite-dacite-rhyolite suites, key lithologies forming the continental crust.
ISSN: 0016-7037

hal-01553520
https://hal.archives-ouvertes.fr/hal-01553520
DOI : 10.1016/j.gca.2016.09.030

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Major and trace element signatures and Sr-Nd-Pb isotope data for muscovite (Ms)-bearing amphibolite blocks and associated muscovite-bearing trondhjemite and quartz-muscovite rocks from the Sierra del Convento melange (eastern Cuba) indicate that Proto-Caribbean oceanic crust underwent wet partial melting processes during Mesozoic subduction and after accretion to the upper plate. Trace element normalized patterns of Ms-bearing amphibolites are enriched in light rare earth elements (LREE) and large-ion lithophile elements (LILE) and evidence variable trace element transfer from the Proto-Caribbean subducting slab to the mantle wedge. Ms-bearing trondhjemites show LREE enrichment and HREE depletion and have geochemical features similar to adakites, including SiO2>56 wt.%, high Na2O contents (5.5-9.0 wt.%) and high Sr/Y (16-644). We consider that the trondhjemites represent primary and natural melts formed by deep partial melting of the subducting slab which did not significantly react with the mantle wedge before intrusion in the subduction channel. The Ms-bearing trondhjemites show different geochemical and petrological signatures compared with the Ms-free tonalites-trondhjemites from Sierra del Convent, that are interpreted as primary slab melts. These differences support the idea that partial melting processes in the Sierra del Convento subduction channel were triggered by the infiltration of fluids derived from three distinct subducted sources: sediments, altered mid-ocean ridge basalts (MORB), and serpentinites. In this scenario, the pegmatitic quartz-muscovite rocks, which are highly enriched in LILE, probably represent the crystallization products of fluids derived by differentiation of the trondhjemitic melts.
ISSN: 0024-4937

hal-00669881
https://hal.archives-ouvertes.fr/hal-00669881
DOI : 10.1016/j.lithos.2011.07.011

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We report chlorine (Cl) and fluorine (F) abundances in minerals, interstitial glasses, and melt inclusions in 12 andesite-hosted, spinel harzburgite xenoliths and crosscutting pyroxenite veins exhumed from the sub-arc lithospheric mantle beneath Avacha volcano in the Kamchatka Arc (NE Russia). The data are used to calculate equilibrium mineral-melt partition coefficients (Dmineral/meltDmineral/melt) for Cl and F relevant to subduction-zone processes and unravel the history of volatile depletion and enrichment mechanisms in an arc setting.Chlorine is ∼100 times more incompatible in pyroxenes (View the MathML sourceDClmineral/melt = 0.005–0.008 [±0.002–0.003]) than F (View the MathML sourceDFmineral/melt = 0.50–0.57 [±0.21–0.24]), which indicates that partial melting of mantle sources leads to strong depletions in Cl relative to F in the residues. The data set in this study suggests a strong control of melt composition on View the MathML sourceDCl,Fpyroxene/melt, in particular H2O contents and Al/(Al + Si), which is in line with recent experiments. Fluorine is compatible in Ca-amphibole in the ‘wet’ sub-arc mantle (View the MathML sourceDFamphibole/melt = 3.5–3.7 [±1.5]) but not Cl (View the MathML sourceDClamphibole/melt = 0.03–0.05 [±0.01–0.03]), indicating that amphibole may fractionate F from Cl in the mantle wedge. The inter-mineral partition coefficients for Cl and F in this study are consistent amongst different harzburgite samples, whether they contain glass or not. In particular, disseminated amphibole hosts much of the Cl and F bulk rock budgets of spinel harzburgites (View the MathML sourceDClamphibole/pyroxene up to 14 and View the MathML sourceDFamphibole/pyroxene up to 40). Chlorine and fluorine are variably enriched (up to 1500 ppm Cl and 750 ppm F) in the parental arc picrite and boninite melts of primitive pyroxenite veins (and related melt inclusions) crosscutting spinel harzburgites.Based on the data in this study, the main inferences on the behaviour of Cl and F during melting and metasomatic processes in the sub-arc mantle are as follow:(i) Melting models show that most depleted mantle protoliths of intra-oceanic arc sources can have extremely low Cl/F (0.002–0.007) before being overprinted by subduction-derived components.(ii) Chlorine has a higher percolation distance in the mantle than F. Even for small fluid or melt volumes, Cl and F signatures of partial melting are overprinted by those of pervasive percolation, which increases Cl/F in percolating agents and bulk peridotites during chromatographic interaction and/or amphibole-forming metasomatic reactions. These processes ultimately control the bulk Cl and F compositions of the residual mantle lithosphere beneath arcs, and likely in other tectonic settings.(iii) Fluxed melting models suggest that Cl enrichment in arc picrite and boninite melts in this study, and in many arc melt inclusions reported in the literature, could be related to the infiltration of high Cl/F fluids derived from subducted serpentinite or altered crust in mantle wedge sources. However, these high Cl/F signatures should be re-evaluated with new models in light of the possible overprint of pervasive percolation effects in the mantle. The breakdown of amphibole (and/or mica) in the deep metasomatised mantle at higher pressure and temperature conditions than in the slab may explain, at least in part, the positive correlations between F abundances and Cl/F in primitive arc melt inclusions and slab depth.
ISSN: 0016-7037

hal-01553610
https://hal.archives-ouvertes.fr/hal-01553610
DOI : 10.1016/j.gca.2016.10.035

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Miocene (17-11 Ma) magmatic activity in the Kabylies emplaced K-rich (and minor medium-K) calc-alkaline plutonic and volcanic rocks in five zones, delineating a ∼450 km long EW trending strip located along the northern coast of Algeria, between Annaba and Algiers. Their most likely source is the Kabylian subcontinental lithospheric mantle previously metasomatized during the Paleogene subduction of the Tethys oceanic lithosphere. Our preferred tectono-magmatic model involves a Tethyan slab detachment combined with African mantle delamination and crustal stacking, leading to the superimposition of the African continental crust over the Kabylian metasomatized lithospheric mantle. At ca. 17 Ma, the asthenospheric upwelling arising from lithospheric delamination and Tethyan slab tear triggered the thermal erosion of the latter mantle, inducing its partial melting. The corresponding mafic medium-K calc-alkaline magmas interacted with the African basement units during their ascent, generating intermediate to felsic K-rich calc-alkaline melts that display a characteristic trace element and isotopic crustal signature. Later on, slab tears propagated eastward and westward, promoting slab rollback perpendicular to plate convergence and inducing the emplacement of magmatic rocks of decreasing ages from central-eastern Algeria towards Tunisia and Morocco.
ISSN: 0899-5362

hal-01467997
https://hal.archives-ouvertes.fr/hal-01467997
DOI : 10.1016/j.jafrearsci.2016.10.005

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
We show here that the Amalaoulaou complex, in the Pan-African belt of West Africa (Gourma, Mali), corresponds to the lower and middle sections of a Neoproterozoic intra-oceanic arc. This complex records a 90-130-Ma-long evolution of magmatic inputs and differentiation above a subducting oceanic slab. Early c. 793 Ma-old metagabbros crystallised at lower crustal or uppermost mantle depths (25-30 km) and have geochemical characteristic of high-alumina basalts extracted from a depleted mantle source slightly enriched by slab-derived sedimentary components ((La/Sm)(N) < 1; epsilon(Nd): +5.4-6.2; Sr-87/Sr-86: 0.7027-0.7029). In response to crustal thickening, these mafic rocks were recrystallised into garnet-granulites (850-1,000A degrees C; 10-12 kbar) and subject to local dehydration-melting reactions, forming trondhjemititic leucosomes with garnet-clinopyroxene-rutile residues. Slightly after the granulitic event, the arc root was subject to strong HT shearing during partial exhumation (detachment faults/rifting or thrusting), coeval with the emplacement of spinel- and garnet-pyroxenite dykes crystallised from a high-Mg andesitic parental magma. Quartz and hornblende-gabbros (700-660 Ma) with composition typical of hydrous volcanic rocks from mature arcs ((La/Sm)(N): 0.9-1.8; epsilon(Nd): +4.6 to +5.2; Sr-87/Sr-86: 0.7028-0.7031) were subsequently emplaced at mid-arc crust levels (similar to 15 km). Trace element and isotopic data indicate that magmas tapped a depleted mantle source significantly more enriched in oceanic sedimentary components (0.2%). Exhumation occurred either in two stages (700-660 and 623 Ma) or in one stage (623 Ma) with a final exhumation of the arc root along cold P-T path (550A degrees C, 6-9 kbar; epidote-amphibolite and greenschist facies conditions) during the main Pan-African collision event (620-580 Ma). The composition of magmas forming the Cryogenian Amalaoulaou arc and the processes leading to intra-arc differentiation are strikingly comparable to those observed in the deep section of exposed Mezosoic oceanic arcs, namely the Kohistan and Talkeetna complex. This evolution of the Amalaoulaou oceanic arc and its accretion towards the West African craton belong to the life and closure of the Pharusian Ocean that eventually led to the formation of the Greater Gondwana supercontinent, a similar story having occurred on the other side of the Sahara with the Mozambique Ocean.
ISSN: 0010-7999

hal-00639447
https://hal.archives-ouvertes.fr/hal-00639447
DOI : 10.1007/s00410-011-0624-5

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
A variety of atypical plume-like structures and focused upwellings that are not rooted in the lower mantle have recently been discussed, and seismological imaging has shown ubiquitous small-scale convection in the uppermost mantle in regions such as the Mediterranean region, the western US, and around the western Pacific. We argue that the three-dimensional return flow and slab fragmentation associated with complex oceanic subduction trajectories within the upper mantle can generate focused upwellings and that these may play a significant role in regional tectonics. The testable surface expressions of this process are the outside-arc alkaline volcanism, topographic swell, and low-velocity seismic anomalies associated with partial melt. Using three-dimensional, simplified numerical subduction models, we show that focused upwellings can be generated both ahead of the slab in the back-arc region (though -five times further inward from the trench than arc-volcanism) and around the lateral edges of the slab (in the order of 100 km away from slab edges). Vertical mass transport, and by inference the associated decompression melting, in these regions appears strongly correlated with the interplay between relative trench motion and subduction velocities. The upward flux of material from the depths is expected to be most pronounced during the first phase of slab descent into the upper mantle or during slab fragmentation. We discuss representative case histories from the Pacific and the Mediterranean where we find possible evidence for such slab-related volcanism.
ISSN: 0012-821X

hal-00553075
https://hal.archives-ouvertes.fr/hal-00553075
DOI : 10.1016/j.epsl.2010.08.012

Éditeur(s) : American Geophysical Union
Résumé : Magmatism associated with subducting plate edges or slab tears has been suggested in the southern Okinawa Trough. The cross back-arc volcanic trail, which consists of a cluster of about 70 seamounts, is located above a Ryukyu slab tear lying along the 123.3°E meridian. In November 2003, more than 3300 earthquakes recorded in this area by 15 ocean bottom seismometers and surrounding land stations during a period of 12 days were used to determine the three-dimensional Vp and Vs velocity structures and Vp/Vs ratios. A mantle inflow characterized by low Vp and Vs and high Vp/Vs passing through the slab tear is imaged. The fluid and/or melt component is rising obliquely from the slab tear in the directions of the cross back-arc volcanic trail, the northern slope of the southern Okinawa Trough and to north of Iriomote Island. The asthenospheric intake is also imaged by an inclined chip-like high Vp/Vs and low Vp and Vs body dipping northerly, which might be linked to the slab retreat. West of the slab tear, most of the earthquakes are located around low Vp and Vs and high Vp/Vs bodies, which suggests that the seismicity is related to magmatic and/or fluid activities. East of it, earthquakes are concentrated in an area characterized by high Vp and Vs velocities and low Vp/Vs, suggesting that the magma chamber is absent beneath the axial part of the trough and that normal faulting is the main factor controlling the seismicity.
Journal of Geophysical Research ( JGR ) - Solid earth (0148-0227) (American Geophysical Union), 2007-08 , Vol. 112 , N. B8 , P. NIL_13-NIL_32

Droits : 2007 AGU
http://archimer.ifremer.fr/doc/2007/publication-3032.pdf
DOI:10.1029/2006JB004703
http://archimer.ifremer.fr/doc/00000/3032/

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We report gabbroic dikes in the plagioclase tectonite domains of the Ojén and Ronda massifs (Betic Cordillera, southern Spain), which record crystallization at low-pressure syn-, or slightly postkinematic to the late ductile history of the Betic Peridotite in the westernmost Mediterranean. We present mineral major and trace element compositional data of discordant gabbroic dikes in the Ojén massif and gabbroic patches in the Ronda massif, complemented by the whole rock and electron backscattered diffraction (EBSD) data of the Ojén occurrence. In the Ojén massif, gabbro occurs as 1–3 centimeter wide discordant dikes that crosscut the plagioclase tectonite foliation at high angle. These dikes are composed of cm-scale igneous plagioclase and clinopyroxene crystals that show shape preferred orientations subparallel to the lineation of the host peridotite and oblique to the trend of the dike. Intrusion of Ojén gabbro dikes is coherent with the stress field that formed the high temperature, ductile plagioclase tectonite foliation and then attests for a mantle igneous event prior to the intracrustal emplacement of the massif. In the Ronda massif, gabbroic rocks crystallized in subcentimeter wide anastomozing veins, or as interstitial patches in the host dunite. They are mostly composed of plagioclase and clinopyroxene. Plagioclase composition is bytownitic in the Ojén, and andesinic in the Ronda massif. Clinopyroxene in both places shows identical, light Rare-Earth Element (LREE) depleted trace element patterns. The calculated trace element composition of melts in exchange equilibrium with the studied igneous clinopyroxenes reflects LREE-enriched character coupled with negative Eu anomaly, and indicates that gabbro-forming melts in Ronda and Ojén share a common melt source with an island arc tholeiitic affinity. Geothermobarometric data and liquidus mineralogy indicate that gabbro crystallization occurred at shallow depths (0.2–0.5 GPa) in a 7–16 km thick lithospheric section. These data suggest that gabbro-forming melts in the Betic Peridotite record a mantle igneous event at very shallow depths and provide evidence for the hyperextension of the continental lithosphere compatible with extreme backarc basin extension induced by the slab rollback of the Cenozoic subduction system in the westernmost Mediterranean.
ISSN: 0040-1951

hal-01172246
https://hal.archives-ouvertes.fr/hal-01172246
DOI : 10.1016/j.tecto.2015.03.011

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
The mantle above a subducting slab is the site of complex interactions between deformation, partial melting, fluid migration and magma transport. To constrain these interactions and their effects on olivine deformation, we analyze microstructures, crystal preferred orientations, and water contents of peridotite xenoliths entrained by andesites of the Avacha volcano, southern Kamchatka arc. These xenoliths are refractory spinel harzburgites that have coarse-grained microstructures with widely spaced subgrain boundaries and sinuous grain boundaries in olivine, consistent with deformation by dislocation creep under low deviatoric stress (< 13 MPa) and with a significant contribution from diffusional processes. Analysis of crystal preferred orientations (CPO) indicates dominant activation of high-temperature, low-stress {0kl}[100] slip systems in olivine and of(100)[001] in orthopyroxene. In most samples, coarse opx crystals, elongated parallel to the lineation, enclose small olivine grains in crystallographic continuity with neighbouring crystals, indicating crystallization of orthopyroxene at the expense of olivine as a result of reactive percolation of Si-rich fluids coeval with the high-temperature deformation. Secondary crystallization of interstitial orthopyroxene led locally to development of opx-rich lenses parallel to the foliation, characterized by a decrease in olivine grain size and dispersion of the olivine CPO without changing the dominant slip systems. Half of the samples also show acicular orthopyroxene aggregates with which is associated a fine-grained matrix composed of rounded strain-free olivine, orthopyroxene, spinel, and rare amphibole crystals. This matrix occurs pervasively along grain boundaries or forms millimeter-scale irregular lenses and anastomosing veinlets that crosscut the coarse crystals and their ductile deformation structures. Both acicular orthopyroxene and the fine-grained matrix are interpreted as resulting from reactive transport of H2O-rich fluids under static conditions, probably in the lithospheric mantle. Infrared analyses show that olivine contains 1-8 center dot 6 ppm by weight of water. These low water contents are similar to those observed in spinel peridotites from other subduction zones and probably record both the low solubility of water in olivine at low pressure and dehydration during exhumation of the xenoliths. Water contents in orthopyroxene are highly variable (25-506 ppm H2O), probably recording spatially heterogeneous interaction with fluids or melts and compositional disequilibrium in the studied samples. Change in the dominant percolation mechanism from porous flow to fracturing suggests cooling, consistent with the low temperatures estimated from pyroxene thermometry (< 800-900 degrees C). The Avacha xenoliths therefore record pervasive deformation of a region of the mantle under asthenospheric conditions, followed by its accretion to the base of the lithosphere, probably as a result of cooling of the mantle wedge. Percolation of Si-rich fluids or hydrous melts is recorded at all stages; this probably enhanced diffusion and lowered deviatoric stresses during ductile deformation, but did not change the dominant slip direction in olivine from [100] to [001].
ISSN: 0022-3530

hal-00456053
https://hal.archives-ouvertes.fr/hal-00456053
DOI : 10.1093/petrology/egp085

Éditeur(s) : HAL CCSD Elsevier
Résumé : The uppermost mantle in back arc regions is the site of complex interactions between partial melting, melt percolation, and fluid migration. To constrain these interactions and evaluate their consequences on geochemical cycles, we carried out an in situ trace element and water study of a suite of spinel peridotite xenoliths from two regions of the Japan back arc system, Ichinomegata (NE Japan) and Oki-Dogo (SW Japan), using LA-ICPMS and FTIR spectrometry, respectively. This study provides the first full dataset of trace element and hydrogen compositions in peridotites including analyses of all their main constitutive silicate minerals: olivine, orthopyroxene and clinopyroxene. The Ichinomegata peridotites sample a LREE-depleted refractory mantle (Mg# olivine = 0.90; Cr# spinel = 0.07–0.23; Yb clinopyroxene = 7.8–13.3 × C1-chondrite, and La/Yb clinopyroxene = 0.003–0.086 × C1-chondrite), characterized by Th-U positive anomalies and constant values of Nb/Ta. The composition of the studied Ichinomegata samples is consistent with that of an oceanic mantle lithosphere affected by cryptic metasomatic interactions with hydrous/aqueous fluids (crypto-hydrous metasomatism). In contrast, the Oki-Dogo peridotites have low Mg# olivine (0.86–0.93) and a broad range of compositions with clinopyroxene showing “spoon-shaped” to flat, and LREE-enriched patterns. They are also characterized by their homogeneous compositions in the most incompatible LILE (e.g., Rb clinopyroxene = 0.01–0.05 × primitive mantle) and HFSE (e.g., Nb clinopyroxene = 0.01–2.16 × primitive mantle). This characteristic is interpreted as resulting from various degrees of melting and extensive melt-rock interactions. FTIR spectroscopy shows that olivine in both Ichinomegata and Oki-Dogo samples has low water contents ranging from 2 to 7 ppm wt. H2O. In contrast, the water contents of pyroxenes from Ichinomegata peridotites (113–271 ppm wt. H2O for orthopyroxene, and 292–347 ppm wt. H2O for clinopyroxene) are significantly higher than in Oki-Dogo peridotites (9–35 ppm wt. H2O for orthopyroxene, and 15–98 ppm wt. H2O for clinopyroxene). This indicates a relationship between melt-rock interaction and water concentrations in pyroxenes. Our study suggests that the water content of the Japan mantle wedge is controlled by the late melt/fluid/rock interactions evidenced by trace element geochemistry: a mechanism triggered by magma-rock interactions may have acted as an efficient dehydrating process in the Oki-Dogo region while the Ichinomegata mantle water content is controlled by slab-derived crypto-hydrous metasomatism.
ISSN: 0016-7037

hal-01553105
https://hal.archives-ouvertes.fr/hal-01553105
DOI : 10.1016/j.gca.2017.03.042

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Before attaining the mantle wedge, where they trigger partial melting, volatiles released from dehydration reactions in the slab have to migrate across a relatively cold (<750 degrees C), peridotite-layer above the incoming slab. In order to unravel the mechanisms allowing for this initial stage of fluid transport, we performed a detailed field and microstructural study of metamorphic prograde peridotites in the Cerro del Almirez ultramafic massif (Betic Cordillera, Spain), where evidences of one of the most important dehydration reactions in subduction zones, the high-pressure antigorite breakdown (P = 1.6-1.9 GPa and T approximate to 680 degrees C), can be mapped in the field. This reaction led to arborescent growth of centimeter-size olivine and orthopyroxene, producing a chlorite-harzburgite with a spinifex-like texture. Microstructural observations and crystal preferred (CPO) mapping show no evidences of solid-state deformation during the prograde growth of olivine and orthopyroxene at the expenses of antigorite. However, a few tens to a hundred meters away from the reaction front, the metamorphic texture is partially obliterated by grain-size reduction in roughly planar conjugate zones, a few mm to meters wide. Grain size reduction zones (GSRZ) are characterized by (1) sharp contacts with undeformed spinifex-like texture domains, (2) important reduction of the olivine grain size (60-250 mu m), (3) olivine color change from brownish to colorless, (4) decrease in the modal amount of orthopyroxene, and (5) at the mm- to cm-scale, irregular shapes and abrupt terminations. Field and microstructural observations exclude that relative displacement took place across these GSRZ. Changes in modal composition imply reactions with fluids undersaturated in silica. Analysis of olivine crystal-preferred orientations (CPO) in GSRZ shows patterns similar, but more dispersed, than those in neighboring spinifex-like domains. It also reveals mm- to cm-scale discrete domains with rather homogeneous crystallographic orientations suggesting inheritance from the preexisting spinifex-like olivines in the host peridotite. Misorientation angles between neighboring grains in the GSRZ show peaks at similar to 5-10 degrees and similar to 20 degrees, but rotations are not crystallographically controlled. Based on these observations, we rule out the formation of the GSRZ by dynamic recrystallization during dislocation creep and propose that they record brittle deformation (microcraking) of the spinifex-like chlorite-harzburgite, probably induced by hydrofracturing at high pressure and relative low temperature conditions (680-710 degrees C). High-pressure hydrofracturing can, thus, be invoked as an efficient mechanism for fluid flow across the cold top-slab mantle layer, hence allowing the slab-derived fluids to ingress in the wedge.
ISSN: 0012-821X

hal-00534035
https://hal.archives-ouvertes.fr/hal-00534035
DOI : 10.1016/j.epsl.2010.06.029

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Sapat peridotite in Kohistan (NW Pakistan) is a 12x1 km sized body of meta-harzburgites, dunites, pyroxenites and meta-gabbros in the hanging wall of the Indus Suture Zone. Field relations, micro-textures, bulk and mineral chemistry document melt-rock reactions producing dunites at the expense of meta-harzburgites, and a consecutive olivine-clinopyroxenite formation from the same melt type. The association of mesa-gabbros, dunites, and pyroxenites is interpreted as a crust-mantle transition zone produced by the percolation of highly depleted primitive arc melt. The meta-harzburgites represent large portions of refractoty mantle that have suffered melt extraction and metasomatism prior to their interaction with the dunite-forming primitive arc melt and the establishment of the crust-mantle transition zone. Uncommon vein assemblages in the dunites that include Cr-clinochlore, calcite and olivine document a late percolation of slab-related, volatile-rich fluids. Taking into account the highly refractory composition of the Sapat mantle, its structural position, the evidence for interaction with highly depleted arc melts and the sub-solidus interaction with volatile-rich arc fluids, the Sapat ultramafic rocks are interpreted as being derived from the frontal Kohistan arc, representing a crust-mantle transition formed by arc magmatism.
ISSN: 0024-4937

hal-00424515
https://hal.archives-ouvertes.fr/hal-00424515
DOI : 10.1016/j.lithos.2008.07.004

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : We present whole-rock major- and trace-element and Nd–Sr–Pb radiogenic isotope data for Cretaceous igneous suites from eastern Cuba. These rocks are related to the Greater Antilles paleo-island arc magmatism and have three different igneous styles. Group 1 consists of tholeiitic basalts and rare basaltic andesites that have normal mid-ocean ridge basalt (N-MORB)-like compositions similar to those found in back-arc basin basalts (TiO2 = 1·2–2·9 wt%; La/Yb(N) = 0·7–0·9, Th/Nb = 0·06–0·08, and initial 208Pb/ 204Pb = 37·65–37·74). Group 2 comprises basaltic and rare basaltic andesitic subvolcanic dykes with major- and trace-element and isotopic compositions similar to those of island arc tholeiites (TiO2 = 0·7–1·4 wt%; La/Yb(N) = 0·6–0·9, Th/Nb = 0·06–0·68, and initial 208Pb/ 204Pb = 37·74–38·25). Group 3 is composed of low-Ti (TiO2 = 0·3–0·9 wt%) calcalkaline igneous rocks that have an unambiguous subduction-related character (La/Yb(N) = 1·1–5·0, Th/Nb = 0·35–1·55, and initial 208Pb/ 204Pb = 37·94–38·39). The parental magmas of the three groups formed by variable melting degrees (< 5–25%) of spinel lherzolite, with more depleted mantle sources for Groups 2 and 3 than Group 1. The trace-element and radiogenic isotope compositions of primitive Group 3 samples are strongly bimodal. One subgroup of samples is characterized by low Ta/Yb (0·02–0·03) and Th/La (0·10–0·13), slightly subchondritic Nb/Ta (13·3–17·3), and relatively high initial 206Pb/204Pb (18·57–18·62) and {varepsilon}Nd (7·6–9·4). The remaining primitive Group 3 samples have higher Ta/Yb (0·06–0·11) and Th/La (0·24–0·32), and highly subchondritic Nb/Ta (7·6–9·1), coupled with lower initial 206Pb/204Pb (18·24–18·29) and {varepsilon}Nd (3·4–5·5). These signatures were induced by two distinct slab components that mainly reflect the contributions of Cretaceous Atlantic marine and North American continental sediments, respectively. Nb/Ta in the first subgroup was influenced by melting of rutile-bearing subducted crust, whereas in the second it was inherited from recycled continental sediments. The involvement of Atlantic and North American sediments in Cuban Cretaceous magmatism indicates that the Proto-Caribbean (North American-Proto Atlantic) lithosphere subducted beneath the Greater Antilles arc during the Late Cretaceous (pre-Campanian), consistent with geotectonic models involving onset of SW-dipping subduction beneath the Greater Antilles paleo-arc during the Aptian. The variable mantle source depletion and magnitude of the subduction component probably reflect different settings across the arc, from the arc front to a back-arc spreading ridge.
ISSN: 0022-3530

hal-00406373
https://hal.archives-ouvertes.fr/hal-00406373
DOI : 10.1093/petrology/egm040

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
The processes active in the deep crust above an oceanic subduction zone during its evolution have been constrained through a detailed geochemical study (major and trace elements and Sr, Nd and Pb isotopes) of representative samples through an 30 km thick exhumed crustal section of the Cretaceous Kohistan oceanic island arc (Northern Pakistan). The use of both trace elements and radiogenic isotopes reveals two distinct geochemical suites (suites A and B) within the JijalPatanKiruKamila (JPKK) complex. Suite A is characterized by a progressive enrichment in Pb-207 and a decrease in Nd-143/Nd-144 with increasing La-N/Sm-N. Suite B has higher Pb-207/Pb-204 and lower Nd-143/Nd-144 ratios with approximately constant La-N/Sm-N. By combining trace elements with different partitioning behaviour it is demonstrated that there is an increasing contribution of the subduction component in the magmas with time. It is also possible to distinguish a slab component imprint carried by aqueous fluids from one corresponding to sediment melts. Intrusive granites are abundant in the upper levels of the JPKK section. All were generated at the arc root level (Jijal crustal section) during dehydration-melting of hornblende-rich plutonic rocks. A three-stage geodynamic model is proposed for the evolution of the arc over a period of 30 Myr. The first stage (117105 Ma) starts with the onset of subduction, which was followed by the building of the volcanic arc. The second stage (10599 Ma to 9691 Ma) corresponds to a major igneous event, which was characterized by abundant magma underplating and granulite-facies metamorphism at the arc base. Recycling of the residualcumulative lower crust into the convective asthenospheric mantle was efficient during this stage, and was probably related to thermo-mechanical erosion of the base of the crust. The last stage (9585 Ma) corresponds to a period of low magmatic activity, which marked the end of the intra-oceanic subduction. This is related to the formation of a cold blanket above the slab surface as a result of thermo-mechanical erosion of the cold walls of the subduction zone (i.e. the upper part of the slab and the base of the overriding plate), and corner flow dragging the cold material into the zone of melt generation. Ultimately, a voluminous magmatic pulse occurred around 85 Ma (forming the Chilas complex), before arccontinent collision.
ISSN: 0022-3530

hal-00420068
https://hal.archives-ouvertes.fr/hal-00420068
DOI : 10.1093/petrology/egp010

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Kekem shoshonitic gabbro-norite association is part of the high-K calc-alkaline (HKCA) post-collisional magmatism, a major feature of the Pan-African Belt in Cameroon. LA-ICP-MS U-Pb zircon analyses provide an age of 576 ± 4 Ma for the Kekem complex. This age is interpreted as dating the emplacement of the massif during the waning stage of the Pan-African orogeny. The latter is related to dextral movements along the Central Cameroon Shear Zone (CCSZ). The REE patterns display enriched LREE (LaN/YbN = 14.2-23.5) while HREE present a nearly flat profile (DyN/YbN = 1.3-1.7), and the La/Sm and Sm/Yb ratios led to propose that the Kekem gabbro-norites have been derived from the partial melting of a garnet-spinel lherzolite mantle source. The negative Nb-Ta and Ti anomalies and the positive Pb anomalies indicate that this mantle source was modified by contribution of a subduction-related material. The low Ce/Pb (2.6-10.4) and Th/Yb ratios associated to high Ba/La ratios, indicate that source enrichment could be related to slab derived fluids. As a whole, the Kekem geochemical features suggest that primary gabbro-noritic magmas derived from a subduction-modified mantle source (metasomatised lithospheric mantle). Moderately high 86Sr/87Sr initial ratios (0.7068-0.7082), low εNd (−5 to −9) and old Nd TDM model ages (1.6-1.8 Ga) are interpreted to result from contamination of Neoproterozoic mantle by the Paleoproterozoic crust. The ca. 576 Ma movements along the CCSZ are related to a Neoproterozoic metacratonization of the northern margin of the Congo craton during the Pan-African orogeny. This metacratonization led to vertical planar lithospheric delamination along lithospheric transcurrent faults, asthenospheric uprise and partial melting of the Paleoproterozoic lithospheric mantle.
ISSN: 0899-5362

hal-00903665
https://hal.archives-ouvertes.fr/hal-00903665
DOI : 10.1016/j.jafrearsci.2013.03.010

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We provide results of a detailed study of the first peridotite xenoliths of proven mantle origin reported from Bezymyanny volcano in the Klyuchevskoy Group, northern Kamchatka arc. The xenoliths are coarse spinel harzburgites made up mainly of Mg-rich olivine as well as subhedral orthopyroxene (opx) and Cr-rich spinel, and also contain fine-grained interstitial pyroxenes, amphibole and feldspar. The samples are unique in preserving the evidence for both initial arc mantle substrate produced by high-degree melt extraction and subsequent enrichment events. We show that the textures, modal and major oxide compositions of the Bezymyanny xenoliths are generally similar to those of spinel harzburgite xenoliths from Avacha volcano in southern Kamchatka. However, coarse opx from the Bezymyanny harzburgites has higher abundances of light and medium rare earth elements and other highly incompatible elements than coarse opx from the Avacha harzburgites. We infer that (1) the sub-arc lithospheric mantle beneath both Avacha and Bezymyanny (and possibly between these volcanoes) consists predominantly of harzburgitic melting residues, which experienced metasomatism by slab-related fluids or low-fraction, fluid-rich melts and (2) the degrees of metasomatism are higher beneath Bezymyanny. By contrast, xenolith suites from Shiveluch and Kharchinsky volcanoes 50-100 km north of the Klyuchevskoy Group include abundant cumulates and products of reaction of mantle rocks with silicate melts at high melt/rock ratios. The high melt flux through the lithospheric mantle beneath Shiveluch and Kharchinsky may be related to the asthenospheric flow around the northern edge of the sinking Pacific plate; lateral propagation of fluids in the mantle wedge south of the plate edge may contribute to metasomatism in the mantle lithosphere beneath the Klyuchevskoy Group volcanoes.
ISSN: 0377-0273

hal-00941258
https://hal.archives-ouvertes.fr/hal-00941258
DOI : 10.1016/j.jvolgeores.2012.12.022

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We present new groundmass K–Ar ages obtained using the Cassignol–Gillot technique, together with whole-rock major and trace elements, from Les Saintes islands (Terre-de-Haut and Terre-de-Bas). They are located along the northern Lesser Antilles inner arc, between Basse-Terre Island (western Guadeloupe) to the North and Dominica Island to the South. Ages reveal that the main volcanic phase in Terre-de-Haut occurred between 2.98 ± 0.04 and 2.00 ± 0.03 Ma, and show that the onset of sub-aerial volcanism in Terre-de-Haut is slightly older (~ 0.2 Myr) than that of northern Basse-Terre. Volcanism in Les Saintes resumed to the west, with the rapid construction of Terre-de-Bas Island at 0.888 ± 0.009 Ma. Major elements analyses show that most lavas from Les Saintes belong to a sub-alkaline medium-K magmatic series and are mainly andesites, with relatively rare basaltic andesites and dacites. Rare earth elements spectra reveal a strong enrichment in light elements, as observed for Dominica lavas, and significantly higher than observed for Basse-Terre lavas. Noticeably, Terre-de-Bas spectra display more enriched patterns relative to those from Terre-de-Haut lavas, suggesting a lower degree of partial melting or a stronger sedimentary component incorporated to the subducting slab. Overall, geochemical signatures of Les Saintes and Dominica magmas display common characteristics, which we interpret as reflecting strong petrogenetic affinities, while both are significantly different from that of Basse-Terre lavas. Finally, this study provides a precise timing of subaerial volcanism of Les Saintes Islands, which can be used to better constrain through time the development of the tectonic half-graben where these islands lie, which is part of the arc-parallel en-echelon faults system accommodating the oblique convergence of the North American plate from Montserrat to Dominica. In addition, these results reveal that the initiation of Terre-de-Haut volcanism is presently the oldest dated volcanism from the northern part of the Lesser Antilles active arc.
ISSN: 0377-0273

hal-01067336
https://hal.archives-ouvertes.fr/hal-01067336

Éditeur(s) : HAL CCSD Elsevier
Résumé : The ultramafic–mafic complexes located at the base of obducted paleo-island arcs are commonly interpreted as evidence for intra-crustal fractionation of primitive (high-Mg#) mantle melts. The present study, realized on the Jijal mafic–ultramafic basal section of the Cretaceous Kohistan oceanic arc (N Pakistan), discards a crystal fractionation model from a single parental magma to take into account the geochemical and isotope variations observed between the plutonic crust and the underlying ultramafic section. The basal ultramafic rocks, i.e. dunites, wehrlites and clinopyroxenites, show high Mg#, extremely depleted REE patterns, no marked HFSE anomalies and high LILE enrichment. Cpx and leached whole rocks from this unit yield restricted εNd values (+ 5.5 to + 6.8), a large εSr range (− 5.9 to + 8.8) and mainly radiogenic 207Pb/204Pb ratios. The overlying mafic section, i.e. gabbroic rocks, displays low Mg# (46 < Mg# < 54), enriched REE patterns and marked HFSE anomalies. These plutonic rocks have also very homogeneous Sr and Pb isotopic compositions defining a restricted domain, which does not overlap that of the ultramafic samples. Moreover, Cpx from the basal ultramafics yield an Sm–Nd isochron at 117 ± 7 Ma interpreted as dating crystallization of the ultramafic section. Together, these results indicate that the mafic rocks on one hand and the ultramafic rocks on the other hand, originate from separate sources with specific emplacement underneath the subduction zone. A lherzolite lens, collected from the top of the mafic section, plots on the early Cretaceous Sm–Nd isochron and therefore yields the same 143Nd/144Nd initial ratio. This suggests that the ultramafic part of the lower Kohistan arc complex sampled the initiation stages of the subduction with production of magmas with boninite-like features. At this stage, the mantle wedge has been already modified by percolation of the first slab-derived fluids. On such a scenario the lherzolite lens would correspond to the lithospheric mantle underneath the arc before its initiation. A multi-stage history is proposed for the evolution for the Kohistan arc through not, vert, similar 30 Ma. Stage #1 reflects the spontaneous initiation of subduction associated with extensive boninitic affinity magmatism, stages #2 and #3 are related to arc building by tholeiitic melts and, a fourth step (stage #4) corresponds to the intra-crustal differentiation.
ISSN: 0012-821X

hal-00407206
https://hal.archives-ouvertes.fr/hal-00407206
DOI : 10.1016/j.epsl.2007.06.026

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
This study presents new geochemical data on 26 mafic lavas from the Middle Atlas and Central Morocco volcanic provinces, including Miocene nephelinites and Pliocene-Quaternary (3.9-0.6Ma) nephelinites, basanites, alkali and subalkaline basalts. Most of them represent near-primary magmas, although some alkali basalts were derived from the minor fractionation of olivine and diopside phenocrysts. These evolved samples and the subalkaline basalt display higher 207Pb/204Pb and Zr/Nb ratios and lower εNd consistent with their contamination by lower crustal granulites during an open fractionation process. The progressive enrichment in incompatible elements observed from alkali basalts to nephelinites suggests their derivation from decreasing partial melting degrees of an enriched mantle source located at the garnet-spinel transition zone. The strong negative spikes observed for K in multielement patterns indicate that this source contained a residual pargasitic amphibole. We propose that partial melting occurred at around 2GPa, i.e. near the lithosphere-asthenosphere boundary beneath the Middle Atlas (60-80km).The trace element and isotopic Sr-Nd-Pb-Hf signature of the uncontaminated lavas displays a geochemical flavour intermediate between those of high μ (HIMU), "C", and enriched mantle components. It is very similar to that of abundant metasomatic amphibole- and clinopyroxene-rich lithospheric peridotites and pyroxenites carried by Middle Atlas lavas, which likely represent an analog of the source of these lavas. It is therefore not necessary to postulate the contribution of a "fresh" asthenospheric mantle to their genesis. We propose that they resulted from the partial melting of the base of a veined lithospheric mantle metasomatised during the late Cretaceous by alkaline melts from the Central Atlantic plume, the ancestor of the Canary plume. Melting was probably triggered by the flux of a hot mantle within a regional SW-NE sub-lithospheric channel, in response to either the Alboran slab retreat or edge-driven convection around the West African craton.
ISSN: 0024-4937

insu-01056523
https://hal-insu.archives-ouvertes.fr/insu-01056523
DOI : 10.1016/j.lithos.2014.07.009