Éditeur(s) : HAL CCSD
Résumé : East African Rift (EAR) is the divergent plate boundary. EAR exposes different stages of extension, from early stage rifting in Tanzania to oceanic accretion in Afar (Ethiopia). Manyara basin is the southernmost rift system of the east branch of EAR with recent volcanism (< 1.5 Ma) and a seismic swarm in the lower crust (20 – 40 km). Due to its location and tectonic setting, the Manyara basin offers the opportunity to study the earliest stage of rift initiation. Manyara volcanism is composed of several types of hyper-alkaline lavas as Mg-nephelinites (Mg# > 55) (Labait, Kwaraha), calciocarbonatite (Kwaraha) and evolved nephelinites (Mg# < 35) (Hanang).Mg-nephelinites (Labait and Kwaraha) are primary lavas mainly composed of olivine and clinopyroxene (cpx). Geochemical modelling from trace elements suggests that these primary magmas result from a degree of partial melting < 1 % from a CO2-garnet-phlogopite-bearing peridotite. These magmas have an asthenospheric source at depth > 120 km (lava carries xenoliths with equilibrium conditions > 4 GPa). The minerals were crystallized from a magma with a low H2O content (0.1 and 0.5 wt% H2O). The calciocarbonatite and evolved nephelinites are derived from Mg-nephelinites by fractional crystallization and immiscibility processes. Hanang nephelinites are silica- and alkaline-rich lavas (44.2 – 46.7 wt % SiO2, 9.5 –12.1 wt % Na2O+K2O, respectively) composed by cpx, Ti-garnet, nepheline, apatite and titanite. Complex zonation of cpx (e.g. abrupt change of Mg#, Nb/Ta, and H2O) and trace element patterns of nephelinites record magmatic differentiation involving open system with carbonate-silicate immiscibility and primary melt replenishment. The low H2O content of cpx (3 – 25 ppm wt. H2O) indicates that at least 0.3 wt % H2O was present at depth during carbonate-rich nephelinite crystallization at 340 – 640 MPa and 1050 – 1100 °C. The study of hosted-nepheline melt inclusions from Hanang allows constraining the late magmatic evolution of nephelinites during storage and magma ascent. Melt inclusions are composed by a silicate trachytic glass, a carbonate phase and a shrinkage bubble. Trachytic glass contains high content in CO2 (0.43 wt %, SIMS analyses), sulfur (0.21 – 0.92 wt % S), chlorine (0.28 –0.84 wt % Cl) and H2O low content (< 0.1 wt %, Raman analyses). Immiscibility process leading to the formation of carbonate occurs in a closed system during rapid magma ascent between 200 – 500 MPa. The carbonate phase is a Ca-Na-K-S-rich and anhydrous carbonate (33 wt % CaO, 20 wt % Na2O, 3 wt % K2O, and 3 wt % S). The pre-immiscible liquid has a phonolitic composition with 6 ± 1.5 wt % CO2 at 700 MPa. A preliminary study of melt inclusions by XANES spectroscopy and whole rocks by Mössbauer spectroscopy was used to determine these Manyara lavas were formed at oxidizing conditions (~ ΔFMQ +1.5).The early stage rifting volcanism (Manyara Basin) is characterized by CO2-rich and H2O-poor magmas from at least 120 km below the rift escarpment. The presence of CO2-rich magmas and the small amount of volcanic rocks erupted at the surface may indicate that the storage and percolation of these magmas at depth is a potential trigger for deep seismic swarms.
Le rift Est africain (REA) est une frontière de plaque en extension. Ce rift présente plusieurs stades d’extension, de l’initiation du rift en Tanzanie jusqu’à l’accrétion océanique en Afar. Le bassin de Manyara se situe le plus au sud de branche Est du REA. Il est caractérisé par la présence de volcanisme récent (< 1,5 Ma) et d’un essaim sismique dans la croûte inférieure (20 – 40 km). De par sa localisation et son contexte tectonique, le bassin de Manyara offre l’opportunité d’étudier le stade le plus précoce de l’initiation du rift. Le bassin de Manyara est composé de plusieurs types de laves hyperalcalines, les néphélinites magnésiennes (Mg# > 55) (Labait, Kwaraha), de calciocarbonatite (Kwaraha) et des néphélinites différenciées (Mg# < 35) (Hanang).Les néphélinites magnésiennes (Labait et Kwaraha) sont des laves primaires composées d’olivines et de clinopyroxènes (cpx). La modélisation géochimique des éléments en trace suggère que ces magmas primaires résultent d'un degré de fusion partielle ≤ 1 % à partir d'une péridotite à grenat et phlogopite. Ces magmas proviennent d’une profondeur > 120 km (présence de xénolites avec des conditions d’équilibre > 4 GPa). Les minéraux ont cristallisés à partir d’un magma pauvre en eau (0,1 et 0,5 pds % H2O). La calciocarbonatite et les néphélinites différenciés sont issues des néphélinites magnésiennes par cristallisation fractionnée et processus d’immiscibilité. Les néphélinites du Hanang sont riches en éléments alcalins (9,5 – 12,1 pds % Na2O+K2O) et en silice (44,2 – 46,7 pds% SiO2) et sont composés de cpx, grenat, néphéline, titanite et apatite. La zonation complexe dans les cpx (par exemple, changement brusque de Mg#, Nb/Ta, et H2O) implique une différenciation magmatique en système ouvert avec immiscibilité de liquide carbonaté et silicaté ainsi qu’un remplissage de la chambre magmatique avec des liquides primaires. La faible teneur en eau des cpx (3 – 25 ppm H2O) indique la présence d’un magma pauvre en eau (0,3 pds % H2O) lors de la cristallisation des cpx à des conditions crustales (340 – 640 MPa et 1050 – 1100 °C). L’étude des inclusions vitreuses dans les néphélines de Hanang permet de contraindre l'évolution magmatique tardive des néphélinites et le comportement des éléments volatils (CO2, H2O, S, F, Cl) lors du stockage et de la remontée du magma. Les inclusions vitreuses sont composées d’un verre trachytique, d’une phase carbonatée et d’une bulle de rétraction. Le verre trachytique contient du CO2 (0,43 pds % CO2, analyses SIMS), du soufre (0,21 à 0,92 pds% S), du chlore (0,28 – 0,84 pds % Cl) et très peu d’H2O (< 0,1 pds % H2O, analyses Raman). Le processus d’immiscibilité conduisant à la formation du carbonate se produit dans un système fermé pendant l'ascension rapide du magma, entre 200 – 500 MPa. La phase carbonatée est un carbonate anhydre et riche en Ca-Na-K-S (33 pds % CaO, 20 pds % Na2O, 3 pds % K2O, et 3 pds % S). Le liquide pré-immiscible a une composition phonolitique avec 6 ± 1,5 pds % CO2 à une pression de 700 MPa. Une étude préliminaire des inclusions par spectroscopie XANES et des roches par spectroscopie Mössbauer a permis de déterminer que les laves de Manyara se sont formées à conditions oxydantes (~ ∆FMQ +1,5).À l’initiation du rift, le volcanisme dans le bassin de Manyara est caractérisé par des magmas riches en CO2 et pauvres en H2O issus d’au moins 120 km de profondeur sous l'escarpement du rift. La présence de ces magmas riches en CO2 et la faible quantité de roches volcaniques émises à la surface peuvent indiquer que le piégeage et la percolation de ces magmas en profondeur est un déclencheur potentiel des essaims sismiques profonds.
https://tel.archives-ouvertes.fr/tel-01563231

NNT : 2016MONTT114
tel-01563231
https://tel.archives-ouvertes.fr/tel-01563231
https://tel.archives-ouvertes.fr/tel-01563231v2/document
https://tel.archives-ouvertes.fr/tel-01563231/file/2016_BAUDOUIN_archivage.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : Primary arc melts may form through fluxed or adiabatic decompression melting in the mantle wedge, or via a combination of both processes. Major limitations to our understanding of the formation of primary arc melts stem from the fact that most arc lavas are aggregated blends of individual magma batches, further modified by differentiation processes in the sub-arc mantle lithosphere and overlying crust. Primary melt generation is thus masked by these types of second-stage processes. Magma-hosted peridotites sampled as xenoliths in subduction zone magmas are possible remnants of sub-arc mantle and magma generation processes, but are rarely sampled in active arcs. Published studies have emphasised the predominantly harzburgitic lithologies with particularly high modal orthopyroxene in these xenoliths; the former characteristic reflects the refractory nature of these materials consequent to extensive melt depletion of a lherzolitic protolith whereas the latter feature requires additional explanation.Here we present major and minor element data for pristine, mantle-derived, lava-hosted spinel-bearing harzburgite and dunite xenoliths and associated primitive melts from the active Kamchatka and Bismarck arcs. We show that these peridotite suites, and other mantle xenoliths sampled in circum-Pacific arcs, are a distinctive peridotite type not found in other tectonic settings, and are melting residues from hydrous melting of silica-enriched mantle sources. We explore the ability of experimental studies allied with mantle melting parameterisations (pMELTS, Petrolog3) to reproduce the compositions of these arc peridotites, and present a protolith (‘hybrid mantle wedge’) composition that satisfies the available constraints. The composition of peridotite xenoliths recovered from erupted arc magmas plausibly requires their formation initially via interaction of slab-derived components with refractory mantle prior to or during the formation of primary arc melts. The liquid compositions extracted from these hybrid sources are higher in normative quartz and hypersthene (i.e., they have a more silica-saturated character) in comparison with basalts derived from prior melt-depleted asthenospheric mantle beneath ridges. These primary arc melts range from silica-rich picrite to boninite and high-Mg basaltic andesite along a residual spinel harzburgite cotectic. Silica enrichment in the mantle sources of arc-related, subalkaline picrite-boninite-andesite suites coupled with the amount of water and depth of melting, are important for the formation of medium-Fe (‘calc-alkaline’) andesite-dacite-rhyolite suites, key lithologies forming the continental crust.
ISSN: 0016-7037

hal-01553520
https://hal.archives-ouvertes.fr/hal-01553520
DOI : 10.1016/j.gca.2016.09.030

Éditeur(s) : HAL CCSD Springer Verlag (Germany) Springer Verlag
Résumé : International audience
Replenished axial melt lenses at fast-spreading mid-oceanic ridges may move upward and intrude into the overlying hydrothermally altered sheeted dikes, resulting in high-grade contact metamorphism with the potential to trigger anatexis in the roof rocks. Assumed products of this process are anatectic melts of felsic composition and granoblastic, two-pyroxene hornfels, representing the residue after partial melting. Integrated Ocean Drilling Program Expeditions 309, 312, and 335 at Site 1256 (eastern equatorial Pacific) sampled such a fossilized oceanic magma chamber. In this study, we simulated magma chamber roof rock anatectic processes by performing partial melting experiments using six different protoliths from the Site 1256 sheeted dike complex, spanning a lithological range from poorly to strongly altered basalts to partially or fully recrystallized granoblastic hornfels. Results show that extensively altered starting material lacking primary magmatic minerals cannot reproduce the chemistry of natural felsic rocks recovered in ridge environments, especially elements sensitive to hydrothermal alteration (e.g., K, Cl). Natural geochemical trends are reproduced through partial melting of moderately altered basalts from the lower sheeted dikes. Two-pyroxene hornfels, the assumed residue, were reproduced only at low melting degrees (<20 vol%). The overall amphibole absence in the experiments confirms the natural observation that amphibole is not produced during peak metamorphism. Comparing experimental products with the natural equivalents reveals that water activity (aH2O) was significantly reduced during anatectic processes, mainly based on lower melt aluminum oxide and lower plagioclase anorthite content at lower aH2O. High silica melt at the expected temperature (1000–1050 °C; peak thermal overprint of two-pyroxene hornfels) could only be reproduced in the experimental series performed at aH2O = 0.1.
ISSN: 0010-7999

hal-01174139
https://hal.archives-ouvertes.fr/hal-01174139
DOI : 10.1007/s00410-015-1136-5

Éditeur(s) : HAL CCSD Springer Verlag (Germany) Springer Verlag
Résumé : International audience
We report here U-series and trace element data for an olivine-melilitite lava flow, erupted in 1957 in the Virunga volcanic field and known as the Mugogo eruption. Petrological and geochemical data show that the Mugogo magma represents a primary mantle melt, derived from a low degree of melting of a metasomatised mantle source. It is highly enriched in very incompatible trace elements (e.g. more than 300-fold compared to primitive mantle for Th), with a distinctly lower enrichment in Rb, Ba and Sr. The high Th/U and low (230Th/232Th) ratios (4.4 and 0.750, respectively, with a (230Th/238U) ratio of 1.09) are close to the values found for the Nyamuragira basanites. But the most striking feature is the very low (226Ra/230Th) ratio of 0.48, the lowest ever measured in a mafic volcanic rock. The most probable origin of this Ra deficit is the presence of phlogopite (having a high Ra partition coefficient) in the lithospheric mantle, either as a residual phase during low-degree isobaric melting (in batch-melting or a diffusion-controlled melting models), or in a phlogopite-bearing upper mantle through which the melt migrates and equilibrates (in an equilibrium porous flow model commonly used to describe adiabatic melting). The disequilibrium pattern (230Th) > (238U) > (210Pb) ≫ (226Ra), reversed compared to the pattern observed in the Oldoinyo Lengai natrocarbonatite, suggests that a carbonatite melt might have been involved to explain the Ra deficit. We thus discuss the possibility of an early separation of a Ra-enriched carbonate melt either from the olivine-melilitite melt or from a carbonated mantle source, followed by the production of a low-degree melt of olivine-melilitite composition, but the lack of available experimental, petrological and geochemical evidences makes this process somewhat speculative at present. Further studies of recent (<5 ky) olivine-melilitites are needed to check whether the large Ra deficit is a general characteristic of this type of magma that can be used to constrain models of its formation.
ISSN: 0010-7999

hal-01174173
https://hal.archives-ouvertes.fr/hal-01174173
DOI : 10.1007/s00410-015-1124-9

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Major and trace element signatures and Sr-Nd-Pb isotope data for muscovite (Ms)-bearing amphibolite blocks and associated muscovite-bearing trondhjemite and quartz-muscovite rocks from the Sierra del Convento melange (eastern Cuba) indicate that Proto-Caribbean oceanic crust underwent wet partial melting processes during Mesozoic subduction and after accretion to the upper plate. Trace element normalized patterns of Ms-bearing amphibolites are enriched in light rare earth elements (LREE) and large-ion lithophile elements (LILE) and evidence variable trace element transfer from the Proto-Caribbean subducting slab to the mantle wedge. Ms-bearing trondhjemites show LREE enrichment and HREE depletion and have geochemical features similar to adakites, including SiO2>56 wt.%, high Na2O contents (5.5-9.0 wt.%) and high Sr/Y (16-644). We consider that the trondhjemites represent primary and natural melts formed by deep partial melting of the subducting slab which did not significantly react with the mantle wedge before intrusion in the subduction channel. The Ms-bearing trondhjemites show different geochemical and petrological signatures compared with the Ms-free tonalites-trondhjemites from Sierra del Convent, that are interpreted as primary slab melts. These differences support the idea that partial melting processes in the Sierra del Convento subduction channel were triggered by the infiltration of fluids derived from three distinct subducted sources: sediments, altered mid-ocean ridge basalts (MORB), and serpentinites. In this scenario, the pegmatitic quartz-muscovite rocks, which are highly enriched in LILE, probably represent the crystallization products of fluids derived by differentiation of the trondhjemitic melts.
ISSN: 0024-4937

hal-00669881
https://hal.archives-ouvertes.fr/hal-00669881
DOI : 10.1016/j.lithos.2011.07.011

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : The Oman ophiolite consists of several massifs cropping out along a 500 km long band trending NW-SE along the coast of Oman; it is one of the best exposed sections of oceanic crust and mantle in the world. There is a gradient in igneous processes and composition in the ophiolite, with the northern massifs recording a polygenetic igneous history involving an increasingly important subduction component, whereas the southern massifs were formed primarily via a mid-ocean ridge basalt (MORB)-like, single-stage process at a submarine spreading ridge. In this study we use geochemical data from Wadi Tayin, which is one of the southern massifs of the Oman ophiolite, to constrain the composition and genesis of oceanic crust and upper mantle. The Wadi Tayin harzburgites are residues of partial melting that are as depleted as the most depleted mid-ocean ridge peridotites. They have low middle- to heavy rare earth element ratios, most probably reflecting melting close to and beyond the exhaustion of clinopyroxene. Like many abyssal peridotites, the Wadi Tayin samples show enrichment in highly incompatible elements, giving rise to U-shaped MORB-normalized trace element patterns. We favor the idea that this is caused by enrichment of highly incompatible elements along grain boundaries in peridotite, which may be the result of near-equilibrium partitioning between grain boundaries and grain interiors, rather than disequilibrium processes. Equilibrium partitioning between crystals and grain boundaries during melting and melt extraction is also our preferred explanation for ubiquitous high Pb contents relative to Ce and La in our samples as well as in most abyssal peridotites. The Wadi Tayin samples record substantial variability in terms of osmium isotopic composition and platinum group element (PGE) concentrations. The more radiogenic nature of the dunites and impregnated peridotites compared with the residual harzburgites may be due to relatively high Os-187/Os-188 in melt transported through the dunites. The presence of residual peridotites with whole-rock osmium isotopic compositions less radiogenic than MORB may be explained by melting of a veined (upwelling) mantle forming mixed melts in which much of the Os derives from veins with high Re/Os in a matrix of previously depleted peridotite. An important result of this study is that the shallowest samples are refertilized (i.e. anomalously enriched in incompatible elements), and record relatively high metamorphic closure temperatures. These observations suggest that migrating melt underwent crystallization during rapid cooling in the uppermost mantle during and immediately after ridge magmatism. A variety of geothermometers all yield the result that the stratigraphically highest harzburgites equilibrated at higher temperature than the deeper ones. The systematic decrease in closure temperature with increasing depth below the Moho transition zone probably reflects systematic variation in cooling rate as a function of depth in the mantle section. We hypothesize that the refertilization and higher closure temperatures recorded by the uppermost mantle samples are linked. More rapid cooling led to higher closure temperatures, and to partial crystallization of migrating melts in the shallowest part of the mantle section, yielding slightly elevated abundances of elements such as Ca and Na, and incompatible trace elements.
ISSN: 0022-3530

hal-00456056
https://hal.archives-ouvertes.fr/hal-00456056
DOI : 10.1093/petrology/egp077

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Island arc picrites and boninites are magnesian magmatic rocks believed to be generated by high degrees of melting of depleted mantle sources fluxed by subduction-derived, volatile-rich components. These magmas can be probes of both the mantle wedge protoliths and subduction components, but are rare among other, usually more evolved, types of arc lavas. Furthermore, many arc picrites and boninites show evidence for late-stage differentiation prior to or during eruption, masking their primary, mantle-derived geochemical signatures. We report textural and chemical data on spinel-hosted melt inclusions of mantle origin in amphibole-bearing websterite veins cross-cutting spinel harzburgite xenoliths from the active andesitic Avacha volcano (south Kamchatka, Russia). The data are used to constrain the composition and origin of melts that formed the websterite veins in the sub-arc lithospheric mantle. The melt inclusions typically contain euhedral orthopyroxene and clinopyroxene and occasionally minor amphibole in silicate glass. The melt inclusions were homogenized using heating stages and gas-mixing furnaces. The homogenized glasses range from subalkaline primitive silica-rich picrite and high-Ca boninite (>15 wt % MgO, 48–54 wt % SiO2) to rhyolite. High-Ca boninite glasses have moderate volatile and low heavy rare earth element contents and elevated Cs, Rb, Ba, U, Sr, and Li abundances, with extremely high U/Th. In turn, the glasses display no negative spikes in the high field strength elements Nb, Ta, Zr, Hf, and Ti. We show that the silica-rich picrite and high-Ca boninite liquids in this study formed by high degrees of melting (>25%), at volatile under-saturation, of hybrid melt-depleted but silica-rich mantle sources at ≥1·5 GPa. The hybrid sources formed in two stages: first, by extraction of ∼15% melt from the convecting mantle to form a refractory protolith, which was subsequently enriched in silica via interaction with subduction-derived components prior to or during remelting in the mantle wedge. The subduction-derived components were enriched in fluid-mobile elements and probably oxidized. Overall, our results suggest that silica-rich picrites and high-Ca boninites can be primary melts in mature subduction zones and differentiate within the mantle wedge and the deep arc crust to form more evolved andesite magmas.
ISSN: 0022-3530

hal-01553676
https://hal.archives-ouvertes.fr/hal-01553676
DOI : 10.1093/petrology/egw066

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
At Cima di Gagnone, garnet peridotite and chlorite harzburgite lenses within pelitic schists and gneisses correspond to eclogite-facies breakdown products of hydrated peridotites and are suitable for studying dehydration of serpentinized mantle. Thermobarometry and pseudosection modelling yield peak temperatures of 750-850°C and pressures <3 GPa. The minimum temperature recorded by the garnet peridotite corresponds to the maximum conditions experienced by the chlorite harzburgite, suggesting that these rocks recrystallized cofacially at ∼800°C. Alternatively, they might have decoupled during subduction, as achieved in tectonically active plate interface boundaries. The major and rare earth element (REE) variability of the peridotites was mostly acquired during pre-subduction mantle evolution as a result of partial melting and reactive melt flow. The ultramafic suite is also characterized by fluid-mobile element enrichments (B, Pb, As, Sb, Cs, Li, U, Be), which confirm derivation from variably serpentinized protoliths. Similarity in the U, Pb, B, Li and Sr contents of the Gagnone peridotites to present-day oceanic serpentinites suggests that these elements were partly taken up during initial serpentinization by seawater-derived fluids. Positive Be, As and Sb anomalies suggest involvement of fluids equilibrated with crustal (metasedimentary) reservoirs during subsequent subduction metamorphism and peridotite entrainment in (meta)sediments. Fluid-mobile element enrichment characterizes all peak eclogitic minerals, implying that multiple hydration events and element influx pre-dated the eclogite-facies dehydration. Peak anhydrous minerals retain B, Li, As and Sb concentrations exceeding primitive mantle values and may introduce geochemical anomalies into the Earth's mantle. The relatively low contents of large ion lithophile elements and light REE in the Gagnone peridotites with respect to much higher enrichments shown by metasomatized garnet peridotite pods hosted in migmatites (Ulten Zone, Eastern Alps) suggest that the crustal rocks at Gagnone did not experience partial melting. The Gagnone garnet peridotite, despite showing evidence for chlorite dehydration, retains significant amounts of fluid-mobile elements documenting that no partial melting occurred upon chlorite breakdown. We propose that the Gagnone ultramafic rocks represent a prime example of multi-stage peridotite hydration and subsequent dehydration in a plate interface setting.
ISSN: 0022-3530

hal-01054319
https://hal.archives-ouvertes.fr/hal-01054319
DOI : 10.1093/petrology/egt068

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Spinel lherzolite xenoliths from Mont Briancon, French Massif Central, retain evidence for multiple episodes of melt depletion and melt/fluid infiltration (metasomatism). Evidence for primary melt depletion is still preserved in the co-variation of bulk-rock major elements (MgO 38.7-46.1 wt.%; CaO 0.9-3.6 wt.%), and many samples yield unradiogenic bulk-rock Os isotope ratios (Os-187/Os-188 = 0.11541-0.12626). However, many individual xenoliths contain interstitial glasses and melt inclusions that are not in equilibrium with the major primary minerals. Incompatible trace element mass balance calculations demonstrate that metasomatic components comprise a significant proportion of the bulk-rock budget for these elements in some rocks, ranging to as much as 25%, of Nd and 40% of Sr Critically, for Re-Os geochronology, melt/fluid infiltration is accompanied by the mobilisation of Sulfide. Consequently, bulk-rock isotope measurements, whether using lithophile (e.g. Rb-Sr, Sm-Nd) or siderophile (Re-Os) based isotope systems, may only yield a perturbed and/or homogenised average of these multiple events.;Osmium mass balance calculations demonstrate that bulk-rock Os in peridotite is dominated by contributions from two populations of sulfide grain: (i) interstitial, metasomatic Sulfide with low [Os] and radiogenic Os-187/Os-188, and (ii) primary sulfides with high [Os] and unradiogenic Os-187/Os-188, which have been preserved within host silicate grains and shielded from interaction with transient melts and fluid. The latter can account for >97% of bulk-rock Os and preserve geochronological information of the melt from which they originally precipitated as an immiscible liquid. The Re-depletion model ages of individual primary sulfide grains preserve evidence for melt depletion beneath the Massif Central from at least 1.8 Gyr ago despite the more recent metasomatic event(s). (C) 2009 Elsevier Ltd. All rights reserved.
ISSN: 0016-7037

hal-00454537
https://hal.archives-ouvertes.fr/hal-00454537
DOI : 10.1016/j.gca.2009.09.031

Éditeur(s) : HAL CCSD AGU and the Geochemical Society
Résumé : International audience
Peridotite xenoliths brought up to the surface by the volcanism of the Kerguelen Islands represent a mantle that has been affected by a high degree of partial melting followed by intense melt percolation above the Kerguelen plume. These xenoliths are therefore particularly suitable to investigate effects of melt-rock interaction on crystallographic fabrics (lattice-preferred orientation (LPO)) of peridotite minerals and on the LPO-induced seismic properties of peridotites above a mantle plume. We have studied a suite of 16 ultramafic samples representative of different degrees of partial melting and magma-rock interaction among which the protogranular harzburgites are the least metasomatised xenoliths and dunites are the ultimate stage of metasomatism. Olivine LPO is characterized by high concentration of [010] axes perpendicular to the foliation and [100] axes close to the lineation or distributed in the foliation plane in harzburgites, whereas the high concentration of [100] axes is parallel to the lineation and [010] axes is perpendicular to the assumed foliation in dunites. Olivine LPO in harzburgites is interpreted as being due to a deformation regime in axial compression or transpression. The fabric strength of olivine decreases progressively from protogranular to poikilitic harzburgites and finally to dunites, for which it remains nevertheless significant (J index 3.8). Seismic properties calculated from LPO of minerals indicate that metasomatism at higher melt/rock ratio lowers the P wave velocities. The most significant difference between harzburgites and dunites corresponds to the distribution of S wave anisotropy. Harzburgites display the maximum of anisotropy within the foliation plane and the minimum of anisotropy perpendicular to the foliation plane, whereas the lowest anisotropy is parallel to the lineation for dunites. These modifications of seismic properties as a result of metasomatic processes may induce seismic heterogeneities in the mantle above the Kerguelen plume. In addition, assuming a lithospheric mantle primarily harzburgitic and structured with a horizontal foliation, the seismic properties calculated for the Kerguelen xenoliths reconcile the rather high anisotropy evidenced by the horizontally propagating surface waves with the apparent isotropy revealed by the absence of splitting of vertically propagating teleseismic SKS waves recorded by the GEOSCOPE Kerguelen station.
ISSN: 1525-2027

hal-00366222
https://hal.archives-ouvertes.fr/hal-00366222
https://hal.archives-ouvertes.fr/hal-00366222/document
https://hal.archives-ouvertes.fr/hal-00366222/file/bascou_Kerguelen_2007GC001879_hal.pdf
DOI : 10.1029/2007GC001879

Éditeur(s) : HAL CCSD AGU and the Geochemical Society
Résumé : International audience
In the Wadi Haymiliyah of the Oman ophiolite (Haylayn block), discordant wehrlite bodies ranging in size from tens to hundreds of meters intrude the lower crust at different levels. We combined investigations on natural wehrlites from the Wadi Haymiliyah section with an experimental study on the phase relations in a wehrlitic system in order to constrain the petrogenesis of the crustal wehrlites of the Oman ophiolite. Secondary ion mass spectrometry analyses of clinopyroxenes from different wehrlite bodies imply that the clinopyroxenes were crystallized from tholeiitic, mid-ocean ridge (MORB)-type melts. The presence of primary magmatic amphiboles in some wehrlites suggests a formation under hydrous conditions. Significantly enhanced Sr-87/Sr-86 isotope ratios of separates from these amphiboles imply that the source of the corresponding magmatic fluids was either seawater or subduction zone-related. The experiments revealed that under wet conditions at relatively low temperatures, a MORB magma has the potential to produce wehrlite in the ocean crust by accumulation of early olivine and clinopyroxene. These show typically high Mg# which is a consequence of the oxidizing effect of the prevailing high aH(2)O. First plagioclases crystallizing after clinopyroxene under wet conditions are high in An content, in contrast to the corresponding dry system. Trace element compositions of clinopyroxenes of those wehrlites from the Moho transition zone are too depleted in HREE to be in equilibrium with present-day MORB, implying a genetic relation to the V2 lavas of the Oman ophiolite, which are interpreted to be the result of fluid-enhanced melting of previously depleted mantle. We present a model on the petrogenesis of the crustal wehrlites in an upper mantle wedge above an initial, shallow subduction zone at the beginning of the intraoceanic thrusting.
ISSN: 1525-2027

hal-00429373
https://hal.archives-ouvertes.fr/hal-00429373
DOI : 10.1029/2009GC002488

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Kekem shoshonitic gabbro-norite association is part of the high-K calc-alkaline (HKCA) post-collisional magmatism, a major feature of the Pan-African Belt in Cameroon. LA-ICP-MS U-Pb zircon analyses provide an age of 576 ± 4 Ma for the Kekem complex. This age is interpreted as dating the emplacement of the massif during the waning stage of the Pan-African orogeny. The latter is related to dextral movements along the Central Cameroon Shear Zone (CCSZ). The REE patterns display enriched LREE (LaN/YbN = 14.2-23.5) while HREE present a nearly flat profile (DyN/YbN = 1.3-1.7), and the La/Sm and Sm/Yb ratios led to propose that the Kekem gabbro-norites have been derived from the partial melting of a garnet-spinel lherzolite mantle source. The negative Nb-Ta and Ti anomalies and the positive Pb anomalies indicate that this mantle source was modified by contribution of a subduction-related material. The low Ce/Pb (2.6-10.4) and Th/Yb ratios associated to high Ba/La ratios, indicate that source enrichment could be related to slab derived fluids. As a whole, the Kekem geochemical features suggest that primary gabbro-noritic magmas derived from a subduction-modified mantle source (metasomatised lithospheric mantle). Moderately high 86Sr/87Sr initial ratios (0.7068-0.7082), low εNd (−5 to −9) and old Nd TDM model ages (1.6-1.8 Ga) are interpreted to result from contamination of Neoproterozoic mantle by the Paleoproterozoic crust. The ca. 576 Ma movements along the CCSZ are related to a Neoproterozoic metacratonization of the northern margin of the Congo craton during the Pan-African orogeny. This metacratonization led to vertical planar lithospheric delamination along lithospheric transcurrent faults, asthenospheric uprise and partial melting of the Paleoproterozoic lithospheric mantle.
ISSN: 0899-5362

hal-00903665
https://hal.archives-ouvertes.fr/hal-00903665
DOI : 10.1016/j.jafrearsci.2013.03.010

Éditeur(s) : HAL CCSD American Geophysical Union - AGU
Résumé : IODP Expedition 335 "Superfast Spreading Rate Crust 4" returned to ODP Hole 1256D with the intent of deepening this reference penetration of intact ocean crust several hundred meters into cumulate gabbros. This was the fourth cruise of the superfast campaign to understand the formation of oceanic crust accreted at fast spreading ridges, by exploiting the inverse relationship between spreading rate and the depth to low velocity zones seismically imaged at active mid-ocean zones, thought to be magma chambers. Site 1256 is located on 15-million-year-old crust formed at the East Pacific Rise during an episode of superfast ocean spreading (>200 mm/yr full rate). Three earlier cruises to Hole 1256D have drilled through the sediments, lavas and dikes and 100 m into a complex dike-gabbro transition zone. The specific objectives of IODP Expedition 335 were to: (1) test models of magmatic accretion at fast spreading ocean ridges; (2) quantify the vigor of hydrothermal cooling of the lower crust; (3) establish the geological meaning of the seismic Layer 2-3 boundary at Site 1256; and (4) estimate the contribution of lower crustal gabbros to marine magnetic anomalies. It was anticipated that even a shortened IODP Expedition could deepen Hole 1256D a significant distance (300 m) into cumulate gabbros. Operations on IODP Expedition 335 proved challenging from the outset with almost three weeks spent re-opening and securing unstable sections of the Hole. When coring commenced, the destruction of a hard-formation C9 rotary coring bit at the bottom of the hole required further remedial operations to remove junk and huge volumes of accumulated drill cuttings. Hole-cleaning operations using junk baskets returned large samples of a contact-metamorphic aureole between the sheeted dikes and a major heat source below. These large (up to 3.5 kg) irregular samples preserve magmatic, hydrothermal and structural relationships hitherto unseen because of the narrow diameter of drill core and previous poor core recovery. Including the ~60 m-thick zone of granoblastic dikes overlying the uppermost gabbro, the dike-gabbro transition zone at Site 1256 is over 170 m thick, of which more than 100 m are recrystallized granoblastic basalts. This zone records a dynamically evolving thermal boundary layer between the principally hydrothermal domain of the upper crust and a deeper zone of intrusive magmatism. The recovered samples document a sequence of evolving geological conditions and the intimate coupling between temporally and spatially intercalated intrusive, hydrothermal, contact-metamorphic, partial melting and retrogressive processes. Despite the operational challenges, we achieved a minor depth advance to 1522 m, but this was insufficient penetration to complete any of the primary objectives. However, Hole 1256D has been thoroughly cleared of junk and drill cuttings that have hampered operations during this and previous Expeditions. At the end of Expedition 335, we briefly resumed coring and stabilized problematic intervals with cement. Hole 1256D is open to its full depth and ready for further deepening in the near future.
InterRidge News

hal-00688821
https://hal.archives-ouvertes.fr/hal-00688821

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
This study presents new geochemical data on 26 mafic lavas from the Middle Atlas and Central Morocco volcanic provinces, including Miocene nephelinites and Pliocene-Quaternary (3.9-0.6Ma) nephelinites, basanites, alkali and subalkaline basalts. Most of them represent near-primary magmas, although some alkali basalts were derived from the minor fractionation of olivine and diopside phenocrysts. These evolved samples and the subalkaline basalt display higher 207Pb/204Pb and Zr/Nb ratios and lower εNd consistent with their contamination by lower crustal granulites during an open fractionation process. The progressive enrichment in incompatible elements observed from alkali basalts to nephelinites suggests their derivation from decreasing partial melting degrees of an enriched mantle source located at the garnet-spinel transition zone. The strong negative spikes observed for K in multielement patterns indicate that this source contained a residual pargasitic amphibole. We propose that partial melting occurred at around 2GPa, i.e. near the lithosphere-asthenosphere boundary beneath the Middle Atlas (60-80km).The trace element and isotopic Sr-Nd-Pb-Hf signature of the uncontaminated lavas displays a geochemical flavour intermediate between those of high μ (HIMU), "C", and enriched mantle components. It is very similar to that of abundant metasomatic amphibole- and clinopyroxene-rich lithospheric peridotites and pyroxenites carried by Middle Atlas lavas, which likely represent an analog of the source of these lavas. It is therefore not necessary to postulate the contribution of a "fresh" asthenospheric mantle to their genesis. We propose that they resulted from the partial melting of the base of a veined lithospheric mantle metasomatised during the late Cretaceous by alkaline melts from the Central Atlantic plume, the ancestor of the Canary plume. Melting was probably triggered by the flux of a hot mantle within a regional SW-NE sub-lithospheric channel, in response to either the Alboran slab retreat or edge-driven convection around the West African craton.
ISSN: 0024-4937

insu-01056523
https://hal-insu.archives-ouvertes.fr/insu-01056523
DOI : 10.1016/j.lithos.2014.07.009

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
A suite of eclogite xenoliths from the Roberts Victor kimberlite (South Africa) is remarkable for its high abundances of base metal sulfides (BMS; up to 2 modal %). However, while sulfides are nearly ubiquitous in Type I eclogites (garnet > 0.07% Na2O), Type II eclogites (garnet < 0.07% Na2O) systematically lack sulfides. Two different sulfide assemblages are recognised within the Type I xenolith suite. Both populations are polyphase Cu-Ni-Fe sulfides, one characterised by the pyrrhotite (Po) + pentlandite (Pn) + chalcopyrite (Cp) assemblage and the other by the smythite/violarite (Smy/Vi) + (Ni)pyrite (Py) + Cp assemblage. The latter is the most abundant assemblage and reflects the supergene alteration of the "primary" Po + Pn + Cp assemblage. This process overprints the original composition of the sulfides by remobilising elements such as S, Fe, Ni, Se and Te. In the Type I eclogites, BMS occur as inclusions within silicates (garnet and clinopyroxene) and as interstitial grains. No chemical differences were observed between enclosed and interstitial sulfides. However, their relative abundances are correlated, indicating a similar origin. The Po + Pn + Cp assemblage is identical to eclogitic sulfides previously described in some Roberts Victor diamonds. Silicate-enclosed sulfides could appear to be early phases, but they are restricted to the outer parts of the silicate grains, suggesting a late incorporation during partial recrystallisation of silicate phases, induced by fluid-rock percolation-reaction during a metasomatic event. Positive whole-rock correlations between Se and (La/Sm)N⁎ and between Cu and ΣLREEN⁎ indicate a direct link between sulfide content and the enrichment of Mg + incompatible elements in the Type I eclogites, further supporting a metasomatic origin of the sulfide component. Similarly, a negative correlation between ΣLREEN⁎ and Cucpx implies that the metasomatic agent was at least partially composed of S-rich fluid (e.g. H2S, SO2) that reacted with the rock and leached Cu out of the silicates. The coupling between sulfides and LREE in the Type I eclogites, as well as the absence of sulfides and metasomatic features (e.g. unequilibrated grain boundaries, melt pockets, fluid inclusions, phlogopite) in the Type II eclogites, demonstrate that Type II eclogites did not undergo such a metasomatic event and therefore may represent the less-modified protoliths of Type I eclogites.
ISSN: 0009-2541

hal-00903856
https://hal.archives-ouvertes.fr/hal-00903856
DOI : 10.1016/j.chemgeo.2013.06.015

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : Solidus phase relations of carbon dioxide-saturated (CO2 vapor) model peridotite in the system CaO-MgO-Al2O3-SiO2-CO2 in the 1.1-2.1 GPa pressure range are reported. The solidus has a positive slope in pressure-temperature (PT) space from 1.1 to 2 GPa. Between 2 and 2.1 GPa, the melting curve changes to a negative slope. From 1.1 to 1.9 GPa, the liquid, best described as CO2-bearing silicate liquid, is in equilibrium with forsterite, orthopyroxene, clinopyroxene, spinel, and vapor. At 2 GPa, the same crystalline phase assemblage plus vapor is in equilibrium with two liquids, which are silicate and carbonatitic in composition, making the solidus at 2 GPa PT invariant. The presence of two liquids is interpreted as being due to liquid immiscibility. Melting reactions written over 1.1-1.9 GPa are peritectic, with forsterite being produced upon melting, and the liquid is silicate in composition. Upon melting at 2.1 GPa, orthopyroxene is produced, and the liquid is carbonatitic in composition. Hence, the invariance between 1.9 and 2.1 GPa is not only the reason for the dramatic change in the liquid composition over an interval of 0.2 GPa, but the carbonated peridotite solidus ledge itself most likely appears because of this PT invariance. It is suggested that because carbonatitic liquid is produced at the highest solidus temperature at 2 GPa in PT space in the system studied, such liquids, in principle, can erupt through liquid immiscibility, as near-primary magmas from depths of approximately 60 km.
ISSN: 0148-0227

hal-00939406
https://hal.archives-ouvertes.fr/hal-00939406
DOI : 10.1002/jgrb.50249

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
North Tanzanian Divergence is the first stage of continental break-up of East African Rift (<6 Ma) and is one of the most concentrated areas of carbonatite magmatism on Earth, with singular Oldoinyo Lengai and Kerimasi volcanoes. Hanang volcano is the southernmost volcano in the North Tanzanian Divergence and the earliest stage of rift initiation. Hanang volcano erupted silica-undersaturated alkaline lavas with zoned clinopyroxene, nepheline, andradite-schorlomite, titanite, apatite, and pyrrhotite. Lavas are low MgO-nephelinite with low Mg# and high silica content (Mg# = 22.4–35.2, SiO2 = 44.2–46.7 wt%, respectively), high incompatible element concentrations (e.g. REE, Ba, Sr) and display Nb–Ta fractionation (Nb/Ta = 36–61). Major elements of whole rock are consistent with magmatic differentiation by fractional crystallization from a parental melt with melilititic composition. Although fractional crystallization occurred at 9–12 km and can be considered as an important process leading to nephelinite magma, the complex zonation of cpx (e.g. abrupt change of Mg#, Nb/Ta, and H2O) and trace element patterns of nephelinites recorded magmatic differentiation involving open system with carbonate–silicate immiscibility and primary melilititic melt replenishment. The low water content of clinopyroxene (3–25 ppm wt. H2O) indicates that at least 0.3 wt% H2O was present at depth during carbonate-rich nephelinite crystallization at 340–640 MPa and 1050–1100 °C. Mg-poor nephelinites from Hanang represent an early stage of the evolution path towards carbonatitic magmatism as observed in Oldoinyo Lengai. Paragenesis and geochemistry of Hanang nephelinites require the presence of CO2-rich melilititic liquid in the southern part of North Tanzanian Divergence and carbonate-rich melt percolations after deep partial melting of CO2-rich oxidized mantle source.
ISSN: 0010-7999

hal-01467390
https://hal.archives-ouvertes.fr/hal-01467390
DOI : 10.1007/s00410-016-1273-5

Éditeur(s) : American Geophysical Union
Résumé : We present new high-resolution bathymetry and backscatter data acquired in 2006 with the ROV Victor 6000 over the Lucky Strike hydrothermal field, Mid-Atlantic Ridge. As long-term monitoring of the Lucky Strike area (MoMAR project) is being implemented, these new high-resolution data offer an unprecedented view of the distribution of hydrothermal edifices, eruptive facies, and small-scale tectonic features in the Lucky Strike vent field. We show that vents located in the NW and NE correspond with wide expanses of lumpy seafloor which we interpret as primarily made of broken chimneys and sulfide edifices. They are found above scarps with relief > 50 m or on associated mass wasting deposits. By contrast, the SE and SW vents correspond with small expanses of lumpy seafloor and are located near smaller scarps which we interpret as more recent faults. Hydrothermal edifices in the SW venting area appear very recent, postdating the emplacement and faulting of the most recent lava. We propose that this difference in the age of hydrothermal edifices does not mean that hydrothermal venting itself is more recent in the southern part of the Lucky Strike field because preexisting sulfide deposits there may have been buried by recent volcanic deposits. Instead, the older edifices in the northern part of the hydrothermal field may have been allowed more time to grow because they are set above the level of recent lava flows. The formation of a lava lake is the most recent eruptive event detected at Lucky Strike. Lava drainback is evidenced by benches and lava pillars, suggesting a close connection with an underlying magma reservoir, which probably corresponds to the melt body imaged by Singh et al. (2006). We have found no evidence that this lake was active for months to decades, as lava lakes at terrestrial volcanoes. It may instead have formed as a lava pond, with successive lava flows covering the eruptive vents, as proposed for similar features at the EPR. The horizontal surface of the lake is deformed only near its southwestern shore, along a NNE-trending set of faults and fissures, which appear to control the distribution of hydrothermal chimneys.
Geochemistry Geophysics Geosystems (1525-2027) (American Geophysical Union), 2009-02 , Vol. 10 , N. 2 , P. 1-18

Droits : 2009 American Geophysical Union
http://archimer.ifremer.fr/doc/2009/publication-6161.pdf
DOI:10.1029/2008GC002171
http://archimer.ifremer.fr/doc/00000/6161/

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The present study aims at better deciphering the different mechanisms involved in the functioning of the subduction interplate. A 2D thermo-mechanical model is used to simulate a subduction channel, made of oceanic crust, free to evolve. Convergence at constant rate is imposed under a 100 km thick upper plate. Pseudo-brittle and non-Newtonian behaviours are modelled. The influence of the subduction channel strength, parameterized by the difference in activation energy between crust and mantle () is investigated to examine in detail the variations in depth of the subduction plane down-dip extent, . First, simulations show that numerical resolution may be responsible for an artificial and significant shallowing of if the weak crustal layer is not correctly resolved. Second, if the age of the subducting plate is 100 Myr, subduction occurs for any . The stiffer the crust is, that is, the lower is, the shallower is (60 km depth if kJ/mol) and the hotter the fore-arc base is. Conversely, imposing a very weak subduction channel ( J/mol) leads there to an extreme mantle wedge cooling and inhibits mantle melting in wet conditions. Partial kinematic coupling at the fore-arc base occurs if kJ/mol. If the incoming plate is 20 Myr old, subduction can occur under the conditions that the crust is either stiff and denser than the mantle, or weak and buoyant. In the latter condition, cold crust plumes rise from the subduction channel and ascend through the upper lithosphere, triggering (1) partial kinematic coupling under the fore-arc, (2) fore-arc lithosphere cooling, and (3) partial or complete hindrance of wet mantle melting. then ranges from 50 to more than 250 km depth and is time-dependent if crust plumes form. Finally, subduction plane dynamics is intimately linked to the regime of subduction-induced corner flow. Two different intervals of are underlined: 80–120 kJ/mol to reproduce the range of slab surface temperature inferred from geothermometry, and 10–40 kJ/mol to reproduce the shallow hot mantle wedge core inferred from conditions of last equilibration of near-primary arc magmas and seismic tomographies. Therefore, an extra process controlling mantle wedge dynamics is needed to satisfy simultaneously the aforementioned observations. A mantle viscosity reduction, by a factor 4–20, caused by metasomatism in the mantle wedge is proposed. From these results, I conclude that the subduction channel down-dip extent, , should depend on the subduction setting, to be consistent with the observed variability of sub-arc depths of the subducting plate surface.
ISSN: 0031-9201

hal-01623155
https://hal.archives-ouvertes.fr/hal-01623155
DOI : 10.1016/j.pepi.2017.05.008

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In East Asia, widespread extensional sedimentary basins together with the close association of Metamorphic Core Complexes and magmatism are prominent features of the large-scale wide rift system developed during late Mesozoic times. This region thus appears as a proper place to study continental extension as well as questions about the link between continental extension and magmatism. This paper primarily provides pioneer exhumation time-constraints on the Linglong MCC (Jiaodong Peninsula) including cooling and deformation ages. MCC cooling at mid-crustal levels occurred at ca. 143 Ma. Besides, last ductile deformation occurred at ca. 134 Ma while final exhumation stages, under brittle 2 conditions, occurred as late as ca. 128 Ma. Continuous crustal stretching were then recorded by the emplacement of a synkinematic pluton in the upper crust at ca. 128 Ma that cooled fast below an intracrustal shear zone crossing the ductile-brittle transition at ca. 123 Ma. The ca. 120-118 Ma age cluster is ascribed to the fast cooling of undeformed plutons marking the end of extension that lasted, in the area, over a minimum period of ca. 30 My. Combining other MCC exhumation constraints and the onset of subsidence in the sedimentary basins, total duration of late Mesozoic extension in East Asia could be estimated at ca. 60 My, related with a rather long process for extension from 160 to at least 100 Ma. East Asian continental extension is heterogeneously distributed in space and time as revealed by fundamental differences between two end-member classes of migmatite-cored MCC already described in other wide rift systems. Extension seems to have first favoured partial melting which subsequently, in turn, maintained continental extension.
ISSN: 1342-937X

insu-00752551
https://hal-insu.archives-ouvertes.fr/insu-00752551
https://hal-insu.archives-ouvertes.fr/insu-00752551/document
https://hal-insu.archives-ouvertes.fr/insu-00752551/file/Charles_et_al_Gondwana_Research_2012.pdf
DOI : 10.1016/j.gr.2012.10.011