Éditeur(s) : Gauthier-Villars
Résumé : During RV Gaveshani cruise No. 235 (August-September, 1993), particulate matter was collected from euphotic and deeper waters in the Bay of Bengal and analysed for biogenic silica (BSi), lithogenic silica (LSi) and particulate organic carbon (POC). Mean depth profiles of BSi showed a minimum in the surface waters and a maximum in the middle depths of the euphotic zone. The deepening of BSi maxima from north to south coincides with the deepening of the thermocline and thickening of the surface layer. In coastal waters, the contribution of BSi to total particulate silica was high (> 80 %); in offshore waters it was 60-70 %. BSi/POC (0.086) and LSi/POC (0.023) ratios show that particulate matter consists mostly of biogenic material, while the BSi/LSi (1.61) ratio revealed the dominance of siliceous phytoplankton in the euphotic zone. High concentrations of BSi (0.49 mu mol l(-1)) and LSi (1.89 mu mol l(-1)) in deeper waters are due to a high sedimentation rate, the resuspension of bottom sediments and the flow of large amounts of riverine siliceous material.
Oceanologica Acta (0399-1784) (Gauthier-Villars), 1997 , Vol. 20 , N. 3 , P. 493-500

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/00093/20459/18131.pdf
http://archimer.ifremer.fr/doc/00093/20459/

Éditeur(s) : Elsevier
Résumé : To elucidate the origin of the silicic acid (DSi) anomaly observed along the 4000 isobath on the Congo margin, we have established a benthic Si mass balance and performed direct measurements of biogenic silica (bSiO(2)) dissolution in the deep waters and in the sediments. Results strongly suggest that the anomaly originates from the sediments; the intensity of DSi recycling is consistent with the degradation of organic matter, as observed from Si:O-2 ratios in the benthic fluxes compared to that ratio observed in the anomalies. Strong imbalances, observed in both the Si and C mass balances, suggest that the biogenic matter that degrades and dissolves in these sediments near 4000 m does not come from pelagic sedimentation. It is probably not coming also from the deep channel, because observations were similar in the deep channel vicinity (site D) and further south, far from its influence (site C). The composition of the sediments, with an Si:C ratio close to that observed on continental shelves, suggests that this matter is coming from downslope transport. A first estimate of the magnitude of this flux at global scale, close to 12 T mol Si yr(-1), suggests that it may be an important path for transferring Si from land to ocean.
Deep Sea Research Part II: Topical Studies in Oceanography (0967-0645) (Elsevier), 2009-11 , Vol. 56 , N. 23 , P. 2197-2207

Droits : 2009 Elsevier Ltd All rights reserved.
http://archimer.ifremer.fr/doc/2009/publication-7410.pdf
DOI:10.1016/j.dsr2.2009.04.003
http://archimer.ifremer.fr/doc/00000/7410/

Éditeur(s) : HAL CCSD Royal Society of Chemistry
Résumé : International audience
LA-ICP-MS analysis of the chemical composition of biogenic carbonate has many applications in the environmental sciences but the characteristics of the material produced by the ablation process are largely unknown. To fill this gap, we have undertaken a study of the chemical and physical nature of particles produced by laser ablation of biogenic carbonates. SEM imaging suggests that laser ablation produces two distinct particle populations, one consisting of microsize particles and the other of nanosize particles. A 213 nm laser gives rise to a higher proportion of microsize particles than a 193 nm laser, probably because the 213 nm laser couples less completely with carbonate material. The microsize particles appear to form by photomechanical fracturing along lines of cleavage or weakness, rather than by hydrodynamic sputtering (as is generally observed for silicates). Chemical analysis of the carbonate particles suggests that little chemical fractionation of biogenic carbonates occurs during the ablation process or during transport to the plasma. This is supported by the constancy of the fractionation factor ([X/Ca](measured)/[X/Ca] true) during the course of an ablation of a carbonate standard. In contrast, changes in the fractionation factor during the first few seconds of ablation of the NIST 612 are observed for some elements. This difference in fractionation is likely to result from the different formation mechanisms of the microsize particles.
ISSN: 0267-9477

hal-00411933
https://hal.archives-ouvertes.fr/hal-00411933
DOI : 10.1039/b706727e

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We present reconstructions of late Holocene changes in the source of organic matter and siliceous export production in the Relocanví Fjord (41°S, 72°W), Northern Chilean Patagonia, based on organic carbon content, δ13Corg, N/C ratio, diatom assemblages and biogenic silica contents from three sediment cores. The age models are based on a combination of 210Pb profiles, AMS 14C dating, and on the first occurrence of the diatom Rhizosolenia setigera f. pungens, as a stratigraphic marker in the fjords. The cores span the last 300 to 700 yr. Diatoms dominate the siliceous assemblages in the three cores (98% on average). Our results suggest that precipitation seasonality in the region of Reloncaví was high in CE 1300–1400 and CE 1700–1850, with a clear decreasing trend since CE 1850. The latter trend is in agreement with instrumental records and tree-ring reconstructions. These fluctuations seem to be associated with the Southern Annular Mode (SAM).
ISSN: 0033-5894

hal-01217176
https://hal.archives-ouvertes.fr/hal-01217176
DOI : 10.1016/j.yqres.2015.05.006

Éditeur(s) : HAL CCSD Société géologique de France
Résumé : New radiolarian assemblages of Late Jurassic age were extracted from seven chert localities of the basement comp ex of La Desirade Island (Guadeloupe), the oldest geological unit of the Lesser Antilles arc and the eastern Caribbean region. These fauna range in age from Kimmeridgian or early Tithonian to early or early late Tithonian, showing that La Desirade cherts are not all coeval, contrary to what was established by previous studies. Furthermore, the close spatial association of cherts and volcanic elements composed of basaltic flows and volcaniclastics suggests a mixed setting of hydrothermal siliceous deposits and biogenous sedimentation consistent with an arc-related oceanic setting rather than an ophiolite-type oceanic crust. As the Youngest age is obtained to the northwest of the basement complex where as older data are found to the southeast, it also Suggests that La Desirade basement complex may have undergone some structural stacking consistent with an accretion-type geodynamic getting. Our biochronological data provide a preliminury try tectonic model of an eastward subduction zone for Lesser Antilles arc basement emplacement during the Mesozois.
EISSN: 1777-5817

hal-00445252
https://hal.archives-ouvertes.fr/hal-00445252
DOI : 10.2113/gssgfbull.180.5.399