Éditeur(s) : Elsevier Science Bv
Résumé : The biodynamic and saturation models offer promising lines of enquiry to predict the bioaccumulation of metals by aquatic organisms. However, in order to construct these models, the accumulation strategies have to be defined for each metal/organism couple in controlled conditions. This study aims at modelling the waterborne bioaccumulation of Ni and the influence of the water's geochemical properties on this process in a crustacean that is widely distributed in Europe, Gammarus pulex. In the laboratory, G. pulex was exposed to several Ni concentrations (from 0.001 to 100 mg L(-1)) in aquatic microcosms. Our results show that G. pulex is very tolerant to Ni (LC50(48 h) = 477 mg L(-1) Ni). Time course experiments enabled the construction of a biodynamic model by determining the uptake (k(u)) and elimination (k(e)) rate constants. When the exposure concentration exceeded 1 mg L(-1) Ni, the metal uptake reached a maximum due to a limited number of binding sites for Ni. Therefore, the organism's maximal capacity to accumulate the metal (B(max)) and the half-saturation constant (K) were determined to establish the saturation model. We showed that the two models are comparable for the lowest exposure concentrations (<1 mg L(-1) Ni), with k(u)/k(e) = B(max)/K. Then, the bioaccumulation of Ni was recorded in waters exhibiting various concentrations of three major ions (Na(+), Mg(2+) and Ca(2+)). Only Ca had an inhibitory effect on the Ni uptake. This study reports for the first time the bioaccumulation of Ni in G. pulex. Because of its high tolerance to Ni and its high capacity to accumulate this metal, this crustacean could be used as an indicator of Ni bioavailability in freshwaters. (C) 2011 Elsevier B.V. All rights reserved.
Aquatic Toxicology (0166-445X) (Elsevier Science Bv), 2011-08 , Vol. 104 , N. 3-4 , P. 161-167

Droits : 2011 Elsevier B.V. All rights reserved.
http://archimer.ifremer.fr/doc/00041/15217/18005.pdf
DOI:10.1016/j.aquatox.2011.04.011
http://archimer.ifremer.fr/doc/00041/15217/

Résumé : De type parabolique et soumis à l’action d’un couple de contrôles (h, k) où h et k jouent des rôles différents ; le contrôle k étant de type "contrôlabilité" et h de type "contrôle optimal".Il est alors naturel de considérer un problème d’optimisation multi-critères. Il existe plusieurs façons d’étudier de tels problèmes. Nous proposons, dans cette thèse, le contrôle de Stackelberg. Il s’agit d’une notion d’optimisation hiérarchique avec, ici, h qui est le "Leader" et k le "Follower".
In this thesis, we are interested in evolution problems governed by parabolic equations subjected to the action of a pair of controls (h, k) where h and k play different roles : the control k being of "controllability" type and h of "optimal control" type.It is then natural to consider a multi-criteria optimization problem. There are several ways to study such problems. We propose in this thesis, the Stackelberg control which is a notion of hierarchical optimization with here, h which is the "Leader" and k the "Follower".

http://www.theses.fr/2014AGUY0805/document

Extrait de : Candid and impartial considerations on the nature of the sugar trade ; the comparative importance of the British and French Islands in the West-Indies : with the value and consequence of St. Lucia and Granada, truly stated. Illustrated with copper-plates (Entre p. 178 et 179)
Résumé : A. Fort Royal. B. Battery upon Goat Point. C. The Town. D. The Church. E. Hospital Hill & Entrenchment. F. Redoubts. G. Morne Latoniere. H. Morne Moliere. I. Morne St Edoy. K. Entrenchments.

Permalien : http://www.manioc.org/images/SCH132550192i1
SCH132550192i1

Éditeur(s) : Archives départementales de la Martinique
2Fi745
Rivière Roxelane (Saint-Pierre)
Saint-Pierre

Droits : Reproduction soumise à autorisation
http://www.patrimoines-martinique.org/ark:/35569/a011273060198efMKYh

Éditeur(s) : Archives départementales de la Martinique
2Fi754
Saint-Pierre

Droits : Reproduction soumise à autorisation
http://www.patrimoines-martinique.org/ark:/35569/a011273060199wshZkb

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Predicting the impact of underground engineering on the environment requires the knowledge of natural media at different scales. In particular, understanding basic phenomena controlling the properties of rocks in the presence of complex fluids necessitates a detailed atomic description of the solid/fluid/solid contacts, the subject of Part I of the present study. First, building the solid interspace between two different crystals in a non-periodic situation is achieved using the ab initio and molecular mechanics code GenMol (TM). A description of the fluid confined within the interspace is then derived from the original genetic iterative multi-species (GIMS) algorithm implemented in the same code. This approach consists of equilibrating chemical potentials, cycle after cycle and species after species, between the confined fluid and the free natural fluid. An elementary iteration for a species k consists of different steps incrementing the number N-k of particles k, with other numbers N-k remaining constant. At each step, an optimum fluid composition is obtained by a genetic process distributing the fluid particles on a grid by stochastic shots, followed in fine by a refining process. The effectiveness of the GIMS approach is demonstrated in the case study of a fluid confined between two (0 0 1) kaolinite faces, with apertures h varying between 4 and 10 A. connected to a 9-species external solution [H2O, Cl-, Na+ CO2(aq), NaCl(aq), Ca2+, Mg2+, HCO3-, H3O+] where concentrations are ranging from 55 to 10(-4) mol/L. The results show a drastic variation in the solute/solvent and cations/ions ratios in the confined fluid when aperture h is lowered to less than 1 nm. These results obtained with a very rapid convergence of the iterative algorithm combined with a very competitive genetic optimizer are validated with high precision on a free solution. This description of contacts between crystals is original and unattainable by standard crystal interface approaches. It opens the way to understanding and/or predicting phenomena between crystals in a complex natural environment, such as adhesion or repulsion investigated in the Part II of this study.
ISSN: 0022-0248

hal-00544569
https://hal.archives-ouvertes.fr/hal-00544569
DOI : 10.1016/j.jcrysgro.2010.08.009

Éditeur(s) : Archives départementales de la Martinique
2Fi446
Montagne Pelée
Saint-Pierre

Droits : Reproduction soumise à autorisation
http://www.patrimoines-martinique.org/ark:/35569/a011273060196IVlYjL

Éditeur(s) : Archives départementales de la Martinique
2Fi433
Saint-Pierre

Droits : Reproduction soumise à autorisation
http://www.patrimoines-martinique.org/ark:/35569/a01127306019614C4Po

Éditeur(s) : Archives départementales de la Martinique
2Fi449
Rue Mont-au-Ciel (Saint-Pierre)
Fort (Saint-Pierre)
Saint-Pierre

Droits : Reproduction soumise à autorisation
http://www.patrimoines-martinique.org/ark:/35569/a011273060191qfDzXy

Éditeur(s) : Nature
Résumé : Mud volcanism is an important natural source of the greenhouse gas methane to the hydrosphere and atmosphere(1,2). Recent investigations show that the number of active submarine mud volcanoes might be much higher than anticipated ( for example, see refs 3 - 5), and that gas emitted from deep-sea seeps might reach the upper mixed ocean(6-8). Unfortunately, global methane emission from active submarine mud volcanoes cannot be quantified because their number and gas release are unknown(9). It is also unclear how efficiently methane-oxidizing microorganisms remove methane. Here we investigate the methane-emitting Haakon Mosby Mud Volcano (HMMV, Barents Sea, 72 degrees N, 14 degrees 44' E; 1,250 m water depth) to provide quantitative estimates of the in situ composition, distribution and activity of methanotrophs in relation to gas emission. The HMMV hosts three key communities: aerobic methanotrophic bacteria (Methylococcales), anaerobic methanotrophic archaea (ANME-2) thriving below siboglinid tubeworms, and a previously undescribed clade of archaea (ANME-3) associated with bacterial mats. We found that the upward flow of sulphate- and oxygen-free mud volcano fluids restricts the availability of these electron acceptors for methane oxidation, and hence the habitat range of methanotrophs. This mechanism limits the capacity of the microbial methane filter at active marine mud volcanoes to <40% of the total flux.
Nature (depuis 1997) (0028-0836) (Nature), 2006-10 , Vol. 443 , N. 7113 , P. 854-858

Droits : 2006 Nature Publishing Group
http://archimer.ifremer.fr/doc/2006/publication-4514.pdf
DOI:10.1038/nature05227
http://archimer.ifremer.fr/doc/00000/4514/

Éditeur(s) : Archives départementales de la Martinique
2Fi434
Saint-Pierre

Droits : Reproduction soumise à autorisation
http://www.patrimoines-martinique.org/ark:/35569/a0112730601995hTMlW

Éditeur(s) : Archives départementales de la Martinique
2Fi630
Mouillage (Saint-Pierre)
Saint-Pierre

Droits : Reproduction soumise à autorisation
http://www.patrimoines-martinique.org/ark:/35569/a011273060194jorQdo

Éditeur(s) : Archives départementales de la Martinique
2Fi1
Pont de pierre (Saint-Pierre)
Centre (Saint-Pierre)
Saint-Pierre
Fort (Saint-Pierre)

Droits : Reproduction soumise à autorisation
http://www.patrimoines-martinique.org/ark:/35569/a011273060184EYfemf

Éditeur(s) : Archives départementales de la Martinique
2Fi342
Place Bertin (Saint-Pierre)
Montagne Pelée
Mouillage (Saint-Pierre)
Saint-Pierre

Droits : Reproduction soumise à autorisation
http://www.patrimoines-martinique.org/ark:/35569/a011273060193QqnNON

Éditeur(s) : Archives départementales de la Martinique
2Fi19
Montagne Pelée
Mouillage (Saint-Pierre)
Saint-Pierre

Droits : Reproduction soumise à autorisation
http://www.patrimoines-martinique.org/ark:/35569/a0112730601944jKgdj

Éditeur(s) : Archives départementales de la Martinique
2Fi790
Fonds Coré (Saint-Pierre)
Saint-Pierre

Droits : Reproduction soumise à autorisation
http://www.patrimoines-martinique.org/ark:/35569/a011273060199IbJK24

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
IODP Site U1309 was drilled at Atlantis Massif, an oceanic core complex, at 30 degrees N on the Mid-Atlantic Ridge (MAR). We present the results of a bulk rock geochemical study (major and trace elements) carried out on 228 samples representative of the different lithologies sampled at this location. Over 96% of Hole U1309D is made up of gabbroic rocks. Diabases and basalts cross-cut the upper part of the section; they have depleted MORB compositions similar to basalts sampled at MAR 30 degrees N. Relics of mantle were recovered at shallow depth. Mantle peridotites show petrographic and geochemical evidence of extensive melt-rock interactions. Gabbroic rocks comprise: olivine-rich troctolites (>70% modal olivine) and troctolites having high Mg# (82-89), high Ni (up to 2300 ppm) and depleted trace element compositions (Yb 0.06-0.8 ppm); olivine gabbros and gabbros (including gabbronorites) with Mg# of 60-86 and low trace element contents (Yb 0.125-2.5 ppm); and oxide gabbros and leucocratic dykes with low Mg# (<50), low Ni (similar to 65 ppm) and high trace element contents (Yb up to 26 ppm). Troctolites and gabbros are amongst the most primitive and depleted oceanic gabbroic rocks. The main geochemical characteristics of Site U1309 gabbroic rocks are consistent with a formation as a cumulate sequence after a common parental MORB melt, although (lack of systematic) downhole variations indicate that the gabbroic series were built by multiple magma injections. In detail, textural and geochemical variations in olivine-rich troctolites and gabbronorites suggest chemical interaction (assimilation?) between the parental melt and the intruded lithosphere. Site U1309 gabbroic rocks do not represent the complementary magmatic product of 30 degrees N volcanics, although they sample the same mantle source. The bulk trace element composition of Site U1309 gabbroic rocks is similar to primitive MORB melt compositions; this implies that there was no large scale removal of melts from this gabbro section. The occurrence of such a large magmatic sequence implies that a high magmatic activity is associated with the formation of Atlantis Massif. Our results suggest that almost all melts feeding this magmatic system stays trapped into the intruded lithosphere.
ISSN: 0012-821X

hal-00413562
https://hal.archives-ouvertes.fr/hal-00413562
DOI : 10.1016/j.epsl.2008.12.034

Éditeur(s) : Archives départementales de la Martinique
2Fi432
Saint-Pierre

Droits : Reproduction soumise à autorisation
http://www.patrimoines-martinique.org/ark:/35569/a011273060199pQyWQY

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We report trace element concentrations of silicate phases in chondrules from LL3 ordinary chondrites Bishunpur and Semarkona. Results are similar to previously reported data for carbonaceous chondrites, with rare earth element (REE) concentrations increasing in the sequence olivine < pyroxene < mesostasis, and heavy REE (HREE) being enriched by 1–2 orders of magnitude (CI-normalized) relative to light REE (LREE) in ferromagnesian silicates, although no single olivine with very large LREE/HREE fractionation has been found. On average, olivine in type II chondrules is poorer in refractory lithophile incompatible elements (such as REE) than its type I counterpart by a factor of ∼2. This suggests that olivine in type I and II chondrules formed by batch and fractional crystallization, respectively, implying that type II chondrules formed under faster cooling rates (>∼10 K/h) than type I chondrules. Appreciable Na concentrations (3–221 ppm) are measured in olivine from both chondrule types; type II chondrules seem to have behaved as closed systems, which may require chondrule formation in the vicinity of protoplanets or planetesimals. At any rate, higher solid concentrations in type II chondrule forming regions may explain the higher oxygen fugacities they record compared to type I chondrules. Type I and type II chondrules formed in different environments and the correlation between high solid concentrations and/or oxygen fugacities with rapid cooling rates is a key constraint that chondrule formation models must account for.
ISSN: 0016-7037

hal-01174084
https://hal.archives-ouvertes.fr/hal-01174084
DOI : 10.1016/j.gca.2015.02.005

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : International audience
A CO2-rich brine core-flood experiment in calcite limestone for conditions representative of underground storage (P = 12 MPa and T = 100°C) was performed in order to explore the dissolution mechanisms arising at moderate CO2 partial pressure (0.3 MPa). An increase of the total porosity (φT) accompanied by a persistent permeability (k) decrease was measured. The mechanisms controlling this atypical anticorrelated k − φT relationship were investigated from the analysis of high-resolution X-ray microtomography images of the sample acquired before and after the experiment. All the evidences converge to the conclusion that the ubiquitous decrease of permeability measured during the 44 h of dissolution is due to the clogging of a fraction of the macroporosity by microporous material triggered by the rearrangement of the detached undissolved particles. This mechanism results in the development of low permeability zones bridging the macroporosity.
ISSN: 0094-8276

hal-00903585
https://hal.archives-ouvertes.fr/hal-00903585
DOI : 10.1002/grl.50595