Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Whole-rock concentrations of Se and Te were determined in 53 peridotite samples collected in orogenic bodies from the Eastern Pyrenees, including the Lherz massif (33 samples), the type-locality of Iherzolite. Orogenic Iherzolites tectonically emplaced into the continental crust escaped devolatilisation that may strongly alter concentrations of those volatile trace elements in basalt-hosted peridotite xenoliths. The Se and Te concentration ranges (<3.5-100.7 ppb; <1-11 ppb) are consistent with the few analyses of mantle samples yet available, yet extending to higher Se concentrations. In-situ analyses performed by LAM-ICPMS on base metal sulfides indicate that the Se budget is controlled by sulfides whereas a large fraction of Te (50 +/- 30%) does not reside in sulfides. The missing fraction is accounted for by fractional crystallization of Pt-Pd tellurides from Cu-Ni sulfide melts. A maximum of one third of the S budget of Eastern Pyrenean peridotites was added by assimilation of crustal sulfides, which crystallized as pyrite. Disregarding those contaminated samples, some features of the Se and Te systematics (e.g. bivariate plots vs. fertility index) cannot be explained by partial melting processes. The best fit for 33 peridotites (mostly from Lherz) yields higher than chondritic S/Se (3.1213 +/- 500; r(2) = 0.96) for near chondritic Se/Te (8.6 +/- 2; r(2) = 0.9). Our study suggest that such superchondritic S/Se ratios are better explained by petrogenetic processes involving refertilization of harzburgitic lithosphere by metal (Cu,Ni)-rich sulfide melts precipitated along with clinopyroxene and Al-spinel from silicate melts en-route to the surface.
ISSN: 0009-2541

hal-00544577
https://hal.archives-ouvertes.fr/hal-00544577
DOI : 10.1016/j.chemgeo.2010.09.007

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
Cobalt-bearing pyrite (0.5-2.0 wt.% Co) is abnormally abundant (up to 35 vol.% of the total volume of the sulfide phase) in some eastern Pyrenean peridotite massifs, compared to pieces of subcontinental mantle studied so far for sulfides. Pyrite occurs as vermicular intergrowths inside pentlandite and/or chalcopyrite or as coarser, blocky grains in the intergranular pores of host peridotites. Those different pyrites are characterized by different platinum-group element systematics (measured by laser ablation microprobe and ICP-MS). Vermicular pyrite intergrown with pentlandite displays Os-, Ir-, Ru- and Rh-enriched chondrite normalized PGE patterns of Monosulfide solid solution (Mss). In contrast, coarse-grained intergranular ("blocky") pyrites, are PGE-poor. Chalcophile trace elements (i.e. Zn, Pb, Ag, Au) that are not usually concentrated in mantle-derived sulfides were commonly detected. By contrast, selenium contents are generally low, yielding thus pyrite with high S/Se ratio (> 10(5)), consistent with a sedimentary sulfur source. Pyrite microtextures and chalcophile trace element contents support a process of assimilation of crustal sulfur from the metamorphosed sedimentary country rocks. These latter generated highly reactive CO2-S fluids, which were injected into structural discontinuities of the lherzolitic bodies. Sulfur has reacted at T = 300-550A degrees C with pre-existing, mantle-derived, metal-rich sulfide assemblages (pentlandite-chalcopyrite). Addition of crustal sulfur did produce Mss which, on cooling, exsolved the Os-rich pyrite in addition to pentlandite. The coarse-grained pyrite types have crystallized directly from S-rich fluids.
ISSN: 0010-7999

hal-00617425
https://hal.archives-ouvertes.fr/hal-00617425
DOI : 10.1007/s00710-010-0138-2

Éditeur(s) : HAL CCSD
Résumé : National audience
Dans la région de Bestiac, en haute-Ariège, une coupe nord-sud d’àpeine plus d’un kilomètre de long centrée sur la zone nord-pyrénéennemétamorphique montre les relations entre le socle anté-alpin (gneissgranulitiques et série paléozoïque) du massif nord-pyrénéen du St Barthélémyet de la zone axiale, et la série mésozoïque constituée principalementde marbres et de brèches carbonatées à éléments de lherzolite,mais aussi du flysch crétacé supérieur.A partir de nouvelles données cartographiques, structurales, métamorphiqueset géochronologiques, nous montrons les modalités de l’extensiondans le socle varisque (comment ’escamoter’ la croûte sans ’trop’l’étirer ?), et comment celle-ci a précédé la mise à la surface du manteauet la formation du complexe bréchique. Ces données nous permettentde caractériser l’importance de l’héritage varisque dans la structurationalpine, mais aussi de poser la question de l’impact des déformations alpinesdans ce qui est considéré comme varisque. Enfin, la restaurationde la coupe nous permet d’aborder la question de la géométrie 3D dusystème au Crétacé, et des rôles respectifs des composantes extensiveset décrochantes.
24 ème Réunion des sciences de la Terre 2014
Pau, France

insu-01080833
https://hal-insu.archives-ouvertes.fr/insu-01080833

Éditeur(s) : HAL CCSD Wiley-Blackwell
Résumé : International audience
In the Pyrenees, the lherzolites nowhere occur as continuous units. Rather, they always outcrop as restricted bodies, never more than 3 km wide, scattered across Mesozoic sedimentary units along the North Pyrenean Fault. We report the results of a detailed analysis of the geological setting of the Lherz massif (central Pyrenees), the type-locality of lherzolites and one of the most studied occurrences of mantle rocks worldwide. The Lherz body is only 1.5 km long and belongs to a series of ultramafic bodies of restricted size (a few metres to some hundreds of metres), occurring within sedimentary formations composed mostly of carbonate breccias originating from the reworking of Mesozoic platform limestones and dolomites. The clastic formations also include numerous layers of polymictic breccias reworking lherzolitic clasts. These layers are found far from any lherzolitic body, implying that lherzolitic clasts cannot derive from the in situ fragmentation of an ultramafic body alone, but might also have been transported far away from their sources by sedimentary processes. A detailed analysis of the contacts between the Lherz ultramafic body and the surrounding limestones confirms that there is no fault contact and that sediments composed of ultramafic material have been emplaced into fissures within the brecciated carapace of the peridotites. These observations bear important constraints for the mode of emplacement of the lherzolite bodies. We infer that mantle exhumation may have occurred during Albian strike-slip deformation linked to the rotation of Iberia along the proto-North Pyrenean Fault.
ISSN: 0954-4879

hal-00412602
https://hal.archives-ouvertes.fr/hal-00412602