Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Phase equilibrium data pertaining to melting of simplified carbonated peridotite in the systems CaO-MgO-SiO2-CO2 and CaO-MgO-Al2O3-SiO2-CO2 at pressures of 10-26 GPa, corresponding to similar to 300-750 km depths in the Earth, are presented. In both the studied systems, liquid compositions, with changing crystalline phase assemblage, are carbonatitic throughout the studied pressure range. In the system CMS-CO2, melting phase relations are isobarically invariant; liquid is in equilibrium with forsterite + clinoenstatite + clinopyroxene + magnesite, forsterite + majorite + clinopyroxene + magnesite, wadsleyite + majorite + clinopyroxene + magnesite, ringwoodite + majorite + calcium-silicate perovskite + magnesite, magnesium-silicate perovskite + periclase + calcium-silicate perovskite + magnesite at 12, 14, 16, 20, and 26 GPa, respectively. In the system CMAS-CO2, a phase assemblage consisting of forsterite + orthopyroxene + clinopyroxene + magnesite + garnet + melt from 10 to 14 GPa is isobarically invariant. However, owing to the disappearance of orthopyroxene at pressures greater than 14 GPa, from 16 and up to at least 26 GPa, the solidus of simplified carbonated peridotite spans a divariant surface in pressure-temperature space. The liquid coexists with wadsleyite + clinopyroxene + garnet + magnesite, ringwoodite + calcium-silicate perovskite + garnet + magnesite, and magnesium-silicate perovskite + periclase + calcium-silicate perovskite + magnesite at 16, 20, and 26 GPa, respectively. A curious, and as yet unexplained, feature of our study is an abrupt drop in the solidus temperature between 14 and 16 GPa that causes a small amount of melting of carbonated mantle in the Transition Zone of the Earth. In the systems CMS-CO2 and CMAS-CO2 liquid compositions at 16 and 20 GPa are highly calcic bona fide carbonatites; however, these liquids revert to being magnesiocarbonatites at 10-14 and 26 GPa. In the system CMS-CO2, at 16 GPa we locate an isobaric invariant point consisting of wadsleyite + clinopyroxene + anhydrous B + magnesite + melt. The presence of anhydrous B at 16 GPa and 1475 degrees C is interesting, as it lies outside the composition space of the mantle peridotite analog we have studied. However, despite the presence of two highly magnesian silicate crystalline phases, wadsleyite and anhydrous B, at 16 GPa and 1475 degrees C, the liquid composition remains calcic with molar Ca-number [Ca/(Ca + Mg) x 100] of about 63. The melting reactions at 16 and 20 GPa (with or without anhydrous B) show that lime-bearing crystalline silicates play a fairly large part in generating and controlling the composition of the liquids. At 16 GPa, in the system CMS-CO2, we also report an experimental run at 1575 degrees C, in which liquid coexists with only wadsleyite and majorite. The liquid composition is less calcic (Ca-number 54) than that for other runs at lower temperatures, but is still more calcic than liquids at 10-14 and 26 GPa in both the studied systems. At present, the likely cause for these changes in the reported phase relations is not known. For normally assumed mantle temperatures, melting in the Transition Zone of the Earth, owing to the presence of carbonate, is probably unavoidable. The depth range of the drop in the carbonated peridotite solidus closely matches that of commonly observed low seismic velocities at similar to 400-600 km depth in the Earth.
ISSN: 0022-3530

hal-00669945
https://hal.archives-ouvertes.fr/hal-00669945
DOI : 10.1093/petrology/egr048

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Jacupiranga Complex is one of several Meso-Cenozoic alkaline intrusive complexes along the margins of the intracratonic Paraná Basin in southern Brazil. The complex encompasses a wide range of rock-types, including dunites, wehrlites, clinopyroxenites, melteigites-ijolites, feldspar-bearing rocks (diorites, syenites, and monzonites), lamprophyres and apatite-rich carbonatites. While carbonatites have been extensively investigated over the last decades, little attention has been paid to the silicate rocks. This study presents new geochonological and geochemical data on the Jacupiranga Complex, with particular emphasis on the silicate lithotypes. 40Ar/39Ar ages for different lithotypes range from 133.7 ± 0.5 Ma to 131.4 ± 0.5 Ma, while monzonite zircon analyzed by SHRIMP yields a U-Pb concordia age of 134.9 ± 1.3 Ma. These ages indicate a narrow time frame for the Jacupiranga Complex emplacement, contemporaneous with the Paraná Magmatic Province. Most of the Jacupiranga rocks are SiO2-undersaturated, except for a quartz-normative monzonite. Based on geochemical compositions, the Jacupiranga silicate lithotypes may be separated into two magma-evolution trends: (1) a strongly silica-undersaturated series, comprising part of the clinopyroxenites and the ijolitic rocks, probably related to nephelinite melts and (2) a mildly silica-undersaturated series, related to basanite parental magmas and comprising the feldspar-bearing rocks, phonolites, lamprophyres, and part of the clinopyroxenites. Dunites and wehrlites are characterized by olivine compositionally restricted to the Fo83-84 interval and concentrations of CaO (0.13–0.54 wt%) and NiO (0.19–0.33 wt%) consistent with derivation by fractional crystallization, although it is not clear whether these rocks belong to the nephelinite or basanite series. Lamprophyre dikes within the complex are considered as good representatives of the basanite parental magma. Compositions of calculated melts in equilibrium with diopside cores from clinopyroxenites are quite similar to those of the lamprophyres, suggesting that at least a part of the clinopyroxenites is related to the basanite series. Some feldspar-bearing rocks (i.e. meladiorite and monzonite) show petrographic features and geochemical and isotope compositions indicative of crustal assimilation, although this may be relegated to a local process. Relatively high CaO/Al2O3 and La/Zr and low Ti/Eu ratios from the lamprophyres and calculated melts in equilibrium with cumulus clinopyroxene point to a lithospheric mantle metasomatized by CO2-rich fluids, suggesting vein-plus-wall-rock melting mechanisms. The chemical differences among those liquids are thought to reflect both variable contributions of melting resulting from veins and variable clinopyroxene/garnet proportions of the source.
ISSN: 0895-9811

hal-01583547
https://hal.archives-ouvertes.fr/hal-01583547
DOI : 10.1016/j.jsames.2017.05.009

Éditeur(s) : HAL CCSD Elsevier
Résumé : Carbon emission at volcanic centers requires a constant balance between output (mostly by volcanism, either at plate boundaries or intraplate) and input (mostly at trench settings) of carbon from and to the Earth's mantle. The form of carbon that resides in the mantle is controlled by depth (pressure) and oxygen fugacity, the latter in turn depending on the depth and the concentration of iron in the mantle. In the shallow, lithospheric mantle, carbon is likely to be present in the oxidized form of CO2 (except under cratons where carbon is reduced to graphite or diamond). Below approximately 90 km, in the asthenosphere, the oxidized form of carbon is carbonate, either mineral or melt, depending on the thermal regime. At depths greater than approximately 150 km, the asthenospheric mantle is too reducing for carbon to stay in its oxidized form and only diamond is present, unless there is sufficient hydrogen to form reduced C–H fluids. Hence, the region located in the depth range of 90 to 150 km deep is where carbonatitic melts can most likely be produced and impregnate the surrounding mantle through metasomatism. The upper bound of this region is called the carbonate ledge. This limit prevents carbonate (either solid or molten) from ascending because of degassing and CO2 liberation. The lower bound is a redox front where redox melting (that is, melting caused by oxidation) may take place in an ascending portion of carbon-containing mantle. Carbonatite eruptions and presence of carbonate mineral inclusions in deep-seated diamonds provide evidence that these boundaries can be trespassed in some cases.An analysis of the experimental data that has bearing on silicate melting in the presence of carbon further shows that the carbonate ledge is a melting curve with a negative or flat Clapeyron (dP/dT) slope. In the carbonated ultrabasic (peridotite) systems, the carbonate ledge is located between ~ 2–3 GPa. The ledge divides the pressure–temperature space into a region of low-pressure silicate melt production, and a high-pressure region where carbonatites can be produced. Carbonatitic melts in equilibrium with mantle peridotite have compositions close to dolomitic (approximately equal amounts of Ca and Mg) with a general trend of becoming markedly more magnesian with increasing pressure. Calcic carbonatites may be stable at pressures < 2 GPa if clinopyroxene is absent. At mantle transition zone pressure range, there seems to be a melting temperature decrease (negative fusion slope), which may be caused by the stabilization of majoritic garnet.The carbonated basic (broadly eclogitic) system is more complex than the peridotitic one, because of the strong control of bulk silicate composition on melting temperatures, and hence, on melt composition. In carbonated eclogite systems, we propose that the effect of bulk composition upon all observed features can perhaps be related to silica super-saturation, or lack thereof. In some cases, high calcium (> 80 mol% CaCO3) melts can be produced, making the melting of carbonated eclogites an appealing scenario for the genesis of calcio-carbonatites in the Earth's mantle. Comparison with modeled pressure–temperature paths of subducted oceanic lithosphere shows that fusion of carbonated eclogite at depths shallower than 200 km should be expected for hot (Cascadian-type) subduction thermal regimes. On the other hand, in the case of cooler thermal regimes (Honshu-type, for instance), subducted carbonates may be stable to greater depths in Earth at trench settings, depending on the bulk composition of the system.Furthermore, high-pressure experiments show evidence of a continuum among carbonatitic, kimberlitic, melilititic, and basaltic liquids, for increasing melting degree of carbonated peridotite. This continuum has not been documented in the case of fusion of carbonated eclogite. It may be present, however, when certain sediments are fused, although the silicate melts are granitic to rhyodacitic instead of being kimberlitic in composition. Additional high-pressure work on phase relations in the simple binary system CaCO3–MgCO3 and specific focus on oxide solubility in the vapor phase have the potential to further clarify phase relations on complex silicate–carbonate systems at mantle conditions.
ISSN: 0009-2541

hal-01277770
https://hal.archives-ouvertes.fr/hal-01277770
DOI : 10.1016/j.chemgeo.2015.05.018

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : International audience
Melting phase relations of model carbonated peridotite in the system CaO-MgO-Al2O3-SiO2-CO2 from 2 to 3 GPa are reported. Experimentally produced melts, which are model carbonatites, with approximately 36-40 wt % CaO, 12-17 wt % MgO, 0.2-1.5 wt % Al2O3, 1-4 wt % SiO2, and 40-42 wt % CO2 (carbon dioxide) are present at all pressures investigated. At 2.8 and 3 GPa, carbonatitic melts are seen experimentally at temperatures that are very close to the vapor-free (CO2) peridotite solidus and are found in equilibrium with forsterite, orthopyroxene, clinopyroxene, and garnet. Solidus phase relations with isobaric and pressure-temperature invariant points, defining the so-called carbonated peridotite solidus ledge, are also reported from 2.1 to 3 GPa. A divariant region exists from 2 to 2.6 GPa wherein two, compositionally different melts are present. In this region, these two melts, carbonatitic and silicate in composition, coexist with crystalline phase assemblage and free vapor. The silicate liquid has approximately 30-48 wt % SiO2 and approximately 6 to 20 wt % of dissolved CO2. The presence of carbonatitic and silicate liquids is interpreted to be due to liquid immiscibility. On the basis of melting phase relations reported here, we conclude that (a) the ledge is a feature along which model carbonatitic liquids are produced by reaction of silicates and CO2 vapor and (b) alkali-free carbonatites and silicate melts can form through melt unmixing at depths of ~60-80 km in the Earth's mantle.
ISSN: 0148-0227

hal-01053913
https://hal.archives-ouvertes.fr/hal-01053913
DOI : 10.1002/2013JB010913

Éditeur(s) : HAL CCSD Mineralogical Society of America
Résumé : International audience
Pressure-temperature divariant melting phase relations of model carbonated peridotite in the system CaO-MgO-Al2O3-SiO2-CO2 from 8 to 12 GPa are reported. From 8 to 12 GPa, melting temperatures on the studied pressure-temperature divariant surface rise quite rapidly. Liquids, in equilibrium with forsterite, orthopyroxene, clinopyroxene, and garnet, on the low-temperature side of the divariant surface are magnesiocarbonatitic in composition. With increasing temperature along an isobar on the pressure-temperature divariant surface, and with the same crystalline phase assemblage, liquids gradually become kimberlitic in their composition. Given the model system data reported here, Group IB kimberlites and perhaps some kimberlites from Greenland, Canada, and South Africa could be generated from direct melting of carbonated peridotite in the pressure range of approximately 6-8 GPa. Some kimberlites from Canada and Russia could have formed by partial melting of carbonated mantle peridotite at pressures of about 10-12 GPa. From 8 to 12 GPa, liquid compositions on the studied divariant surface show a limited compositional range, which implies that the divariant surface is essentially flat. The implied flatness of the divariant surface, and so long as the liquid is in equilibrium with the crystalline assemblage of forsterite + orthopyroxene + clinopyroxene + garnet on the divariant surface, indicate that kimberlites belonging to Group IA and those more magnesian than Group IA cannot have their origin in only being a melting product of carbonated mantle peridotite. The absence of topography of the studied pressure-temperature divariant surface in all likelihood limits the generation of kimberlites in the Earth's upper mantle only.
ISSN: 0003-004X

hal-01053915
https://hal.archives-ouvertes.fr/hal-01053915
DOI : 10.2138/am.2014.4826