Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
A suite of eclogite xenoliths from the Roberts Victor kimberlite (South Africa) is remarkable for its high abundances of base metal sulfides (BMS; up to 2 modal %). However, while sulfides are nearly ubiquitous in Type I eclogites (garnet > 0.07% Na2O), Type II eclogites (garnet < 0.07% Na2O) systematically lack sulfides. Two different sulfide assemblages are recognised within the Type I xenolith suite. Both populations are polyphase Cu-Ni-Fe sulfides, one characterised by the pyrrhotite (Po) + pentlandite (Pn) + chalcopyrite (Cp) assemblage and the other by the smythite/violarite (Smy/Vi) + (Ni)pyrite (Py) + Cp assemblage. The latter is the most abundant assemblage and reflects the supergene alteration of the "primary" Po + Pn + Cp assemblage. This process overprints the original composition of the sulfides by remobilising elements such as S, Fe, Ni, Se and Te. In the Type I eclogites, BMS occur as inclusions within silicates (garnet and clinopyroxene) and as interstitial grains. No chemical differences were observed between enclosed and interstitial sulfides. However, their relative abundances are correlated, indicating a similar origin. The Po + Pn + Cp assemblage is identical to eclogitic sulfides previously described in some Roberts Victor diamonds. Silicate-enclosed sulfides could appear to be early phases, but they are restricted to the outer parts of the silicate grains, suggesting a late incorporation during partial recrystallisation of silicate phases, induced by fluid-rock percolation-reaction during a metasomatic event. Positive whole-rock correlations between Se and (La/Sm)N⁎ and between Cu and ΣLREEN⁎ indicate a direct link between sulfide content and the enrichment of Mg + incompatible elements in the Type I eclogites, further supporting a metasomatic origin of the sulfide component. Similarly, a negative correlation between ΣLREEN⁎ and Cucpx implies that the metasomatic agent was at least partially composed of S-rich fluid (e.g. H2S, SO2) that reacted with the rock and leached Cu out of the silicates. The coupling between sulfides and LREE in the Type I eclogites, as well as the absence of sulfides and metasomatic features (e.g. unequilibrated grain boundaries, melt pockets, fluid inclusions, phlogopite) in the Type II eclogites, demonstrate that Type II eclogites did not undergo such a metasomatic event and therefore may represent the less-modified protoliths of Type I eclogites.
ISSN: 0009-2541

hal-00903856
https://hal.archives-ouvertes.fr/hal-00903856
DOI : 10.1016/j.chemgeo.2013.06.015

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Type I and Type II eclogite xenoliths from the Roberts Victor kimberlite (South Africa) show marked differences in terms of microstructures, mineralogy, major-and trace-element compositions and oxygen-isotope compositions. The unequilibrated microstructures of Type I eclogites, their typical accessory assemblages (phologopite, diamond, sulphides, fluid inclusions) and the ubiquitous presence of "melt pockets" in garnets provide strong evidence of metasomatism. Type II eclogites systematically lack such features and are microstructurally more equilibrated. Type I eclogites are more magnesium-rich than most Type II (mean Mg# = 0.56 vs. 0.46), while Type II eclogites are generally more Ca-rich (mean CaO = 9 vs. 12 wt%) and Fe-rich (mean FeO = 10 vs. 12 wt%). Type I eclogites are systematically enriched in LREE, Sr, Ba, alkali elements, HFSE, Th and U compared to the more depleted Type II eclogites. Calculated trace-element patterns of fluids in equilibrium with Type I eclogites are closely similar to those of volatile-rich small-volume mantle melts in the carbonatite-kimberlite spectrum commonly inferred to be responsible for mantle metasomatism. Although oxygen isotopes are often used to argue for a subduction origin of mantle eclogites, correlations between delta O-18 of garnet and typical metasomatic tracers suggest that the metasomatic process also has shifted the oxygen-isotope compositions of the Type I eclogites toward heavier values. Roberts Victor Type I eclogites thus carry the imprint of a metasomatic process that strongly modified their major-element, trace-element and isotopic compositions, while the more pristine Type II eclogites escaped this modification. Therefore, attempts to constrain the origin of Roberts Victor eclogites should not be based on the much more abundant Type I eclogites, which retain little geochemical memory of their protoliths. The most suitable materials for such investigations may be the less metasomatised, but more rare, Type II eclogites.
ISSN: 0016-7037

hal-00669867
https://hal.archives-ouvertes.fr/hal-00669867
DOI : 10.1016/j.gca.2011.08.035

Éditeur(s) : HAL CCSD Société Géologique de France
Résumé : Xenoliths brought up by kimberlite magmas are rare samples of otherwise inaccessible lithospheric mantle. Eclogite xenoliths are found in most cratons and commonly show a range of mineral and chemical compositions that can be used to better understand craton formation. This study focuses on five new kyanite-bearing eclogites from the Udachnaya kimberlite pipe (367±5 Ma). They are fine-to coarse-grained and consist mainly of “cloudy” clinopyroxene (cpx) and garnet (grt). The clinopyroxene is Al,Na-rich omphacite while the garnet is Ca-rich, by contrast to typical bi-mineral (cpx+grt) eclogites that contain Fe- and Mg-rich garnets. The Udachnaya kyanite eclogites are similar in modal and major element composition to those from other cratons (Dharwar, Kaapvaal, Slave, West African). The kyanite eclogites have lower REE concentrations than bi-mineral eclogites and typically contain omphacites with positive Eu and Sr anomalies, i.e. a “ghost plagioclase signature”. Because such a signature can only be preserved in nonmetasomatised samples, we infer that they were present in the protoliths of the eclogites. It follows that subducted oceanic crust is present at the base of the Siberian craton. Similar compositions and textures are also seen in kyanite eclogites from other cratons, which we view as evidence for an Archean, subduction-like formation mechanism related to craton accretion. Thus, contrary to previous work that classifies all kyanite eclogites as type I (IK), metasomatized by carbonatite/kimberlitic fluids, we argue that some of them, both from this work and those from other cratons, belong to the non-metasomatized type II (IIB). The pristine type IIB is the nearest in composition to protoliths of mantle eclogites because it contains no metasomatic enrichments.
ISSN: 0037-9409

hal-01622617
https://hal.archives-ouvertes.fr/hal-01622617
DOI : 10.1051/bsgf/2017008

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
Investigation of an eclogite xenolith, discovered in a Cretaceous granite from the Central Domain of the Dabieshan massif in eastern China, yields new petrological insights into the high to ultrahigh-pressure metamorphism, experienced by the Qinling-Dabie orogen. Prior to inclusion as a xenolith in the granite during the Early Cretaceous, this eclogite xenolith had recorded a complex metamorphic evolution that complies with subduction and exhumation processes experienced by the continental crust of the South China Block. Well-preserved mineral parageneses substantiate the prograde and retrograde stages revealed by inclusions in porphyroblastic garnet and zoned minerals such as garnet, comphacite and amphibole in the matrix. The relatively low P/T re-equilibration during a latemetamorphic stage was textually inferred by the presence of aluminous and calcic-subcalcic amphiboles such as katophorite, edenite, taramite and pargasite as main matrix phases. According to our U/Pb, Rb/Sr and new 40Ar/39Ar geochronological results, namely 109 ± 1 and 112 ± 2 Ma plateau ages for muscovite and amphiboles, respectively, two successive but distinct cooling stages account for the thermal history of the granite–migmatite gneiss dome that forms the Central Dabieshan Domain. We argue that prior to the Cretaceous doming, the Central Dabieshan Domain experienced a tectono-metamorphic evolution similar to that observed in the high-pressure to ultra high-pressure units developed in the Southern Dabieshan Domain and Hong'an massif.
ISSN: 1437-3254

hal-00104224
https://hal-insu.archives-ouvertes.fr/hal-00104224
https://hal-insu.archives-ouvertes.fr/hal-00104224/document
https://hal-insu.archives-ouvertes.fr/hal-00104224/file/Lin-IntJEarthSciences-2007.pdf
DOI : 10.1007/s00531-006-0129-z