Résumé : This report synthesises the knowledge on the biogeochemical cycle, bioconcentration processes and ecotoxicity of lead in the marine environment. Man induced changes on the lead cycle, especially along the French coasts are reviewed. Concentration levels, mechanisms and fluxes between geochemical reservoirs are assessed. Emphasis is given on sublethal effects and toxicity mechanisms. Quality standards used in European Community countries are listed. Conclusions and recommendations for environmental management and research are given.
Le présent document constitue une synthèse des connaissances sur le cycle biogéochimique, la bioconcentration et l'écotoxicité du plomb en milieu marin. Il fait état des perturbations du cycle du plomb par l'action de l'homme, en particulier dans le milieu littoral français. Les niveaux de concentration et les quantités échangées entre les réservoirs géochimiques sont évalués. L'accent est mis sur les effets sublétaux et les mécanismes de toxicité vis-à-vis du biotope marin. Les réglementations relatives en milieu marin actuellement en vigueur dans les pays de la Communauté européenne sont répertoriées. Avec les conclusions quelques recommandations en matière de gestion et de recherche sont faites.

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/1993/rapport-1449.pdf
http://archimer.ifremer.fr/doc/00000/1449/

Éditeur(s) : HAL CCSD SAGE Publications
Résumé : International audience
The distribution of redox-sensitive elements (V, U, Mo, Mn) was studied in a sedimentary archive of the Pierre-Blanche lagoon encompassing 3500 years of sedimentation. Between 240 and 255 cm (i.e. between 0 and 350 cal. ad) in the core, there was a dark layer with no mollusc shells. Enrichments of V, U and Mo and depletion of Mn were observed in this layer compared with overlying and underlying sediments. This was attributed to the occurrence of anoxia in bottom water or at the sediment/water interface during the Roman period. This episode was concomitant with the formation of a sandy barrier, which now isolates the lagoon from the sea. Our results suggest that the isolation of the lagoon, which was deeper in the period concerned than at present, favoured stagnation of the water. Combined with the excess nutrient inputs because of human activities in Lattara harbour, stagnation may have caused anoxia in bottom water at least in some parts of the Palavasian lagoon system. Bottom conditions nevertheless remained sufficiently reducing for the accumulation of U and Mo to persist until around 800 cal. ad. Although the lagoon has been hyper-eutrophic since at least the middle of the 20th century and although anoxia occurs frequently in summer, redox proxies show no evidence for their occurrence. The shallow water and associated resuspension and reoxidation events explain the lack of V, Mo and U enrichment in recent sediments.
ISSN: 0959-6836

hal-01062151
https://hal.archives-ouvertes.fr/hal-01062151

Éditeur(s) : HAL CCSD American Chemical Society
Résumé : International audience
A sediment core encompassing 3500 years of continuous sedimentation has been collected from a coastal lagoon located on the southwestern French Mediterranean coast. Lead concentrations and stable isotopes show that the sediments have recorded the three major periods of Pb pollution: the Etruscan-Greek-Roman period (650 BC to AD 50), the medieval period (AD 650 to AD 1450), and the modern period (from around AD 1850 to the present). These periods were separated by low pollution periods during the Dark Ages (between AD 50 and 650) and during the 16th century. From the end of the 19th century to the 1960s, Pb pollution increased exponentially. Coal combustion was the major source of Pb in the lagoon in the second half of the 20th century. Both the decrease in coal consumption and the ban on leaded gasoline resulted in a decrease in Pb pollution by a factor of 1.5 between 1973 and 1995. From 1991, sewage treatment plants and incinerators could be the major source of Pb. The average baseline Hg concentration from 1525 BC to AD 900 was 0.017 ± 0.003 μg g(-1) (n = 54). The Hg concentrations profile shows three major peaks: in AD 1150, AD 1660, and AD 1969, with the concentrations being respectively 8, 5, and 34 times higher than the baseline levels. The medieval peak (AD 1150) is attributed the medical use of Hg in the town of Montpellier and/or the burning of soil and vegetation. Noticeable Hg pollution was also detected during the 17th century in relation to gold and silver amalgamation in Europe. From the end of the 19th century, Hg concentrations increased exponentially until 1969. This modern pollution is attributed to the burning of coal.
ISSN: 0013-936X

halsde-00639280
https://hal.archives-ouvertes.fr/halsde-00639280

Éditeur(s) : HAL CCSD Elsevier
Résumé : In this study, we assessed past and present influence of ancient mining activity on metal(loid) enrichment in sediments of a former mining watershed (Gardon River, SE France), that is now industrialized and urbanized. A sedimentary archive and current sediments were characterized combining geochemical analyses, zinc isotopic analyses and sequential extractions. The archive was used to establish local geochemical background and recorded (i) increasing enrichment factors (EFs) for Pb, Zn, Cd, Tl, Hg, As and Sb throughout the industrial era, (ii) a contamination peak in 1976 attributed to a tailings dam failure, and (iii) current levels in 2002 and 2011 similar to those of 1969, except for Sb and Hg, reflecting a persisting contamination pattern. Inter-element relationships and spatial distribution of EF values of current sediments throughout the watershed suggested that both ancient and current contamination had a common origin for Pb, Zn, Cd, Tl and As related to the exploitation of Pb/Zn mineralization while old Sb mines and coal extraction area were the main sources for Sb and Hg respectively. This prevailing mining origin was reflected for Zn by a relatively uniform isotopic composition at δ66Zn = 0.23 ± 0.03‰, although slight decrease from 0.23‰ to 0.18‰ was recorded from upstream to downstream sites along the river course in relation with the contribution of the lighter δ66Zn signature (~ 0.08‰) of acid mine drainage impacted tributaries. Results from sequential extractions revealed that the potential mobility of the studied metal(loid)s varied in the order Sb < Tl ≈ As < Zn < Pb < Cd, with an increase of the mobile pool for Cd, Pb, Zn and to a lesser extent for As and Tl associated to increased enrichment. Altogether, these results tend to demonstrate that ancient mining activity still contributes to metal enrichment in the sediments of the Gardon River and that some of these metals may be mobilized toward the water compartment.
ISSN: 0048-9697

hal-01054163
https://hal.archives-ouvertes.fr/hal-01054163
DOI : 10.1016/j.scitotenv.2014.02.078