Éditeur(s) : HAL CCSD
Résumé : International audience
The corrosion rates in the presence of some indole derivates, namely, 9H-pyrido[3,4-b]indole (norharmane) and 1-methyl-9H-pyrido[3,4-b]indole (harmane), as inhibitors of C38 steel corrosion inhibitor in 1 M HCl solution, were measured by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques, in the range of temperatures from 25 to 55∘C. Results obtained revealed that the organic compounds investigated have inhibiting properties for all temperatures. The inhibition was assumed to occur via adsorption of the indole molecules on the metal surface. Adsorption of indole derivates was found to follow the Langmuir isotherm. The apparent activation energies, enthalpies, and entropies of the dissolution process and the free energies and enthalpies for the adsorption process were determined by potentiodynamic polarization and electrochemical impedance. The fundamental thermodynamic functions were used to collect important information about indole inhibitory behaviour.
international Journal of Corrosion

hal-01683120
https://hal.univ-antilles.fr/hal-01683120
DOI : 10.1155/2013/139798

Éditeur(s) : HAL CCSD
Résumé : International audience
ECS Trans.

hal-01239240
https://hal.archives-ouvertes.fr/hal-01239240

Éditeur(s) : HAL CCSD
Résumé : International audience
Field trip Guidebook, CorseAlp 2011 Meeting of Geology

hal-00604006
https://hal.archives-ouvertes.fr/hal-00604006

Éditeur(s) : HAL CCSD Electrochemical Society, Inc.
Résumé : International audience
ISSN: 1938-5862

hal-01683130
https://hal.univ-antilles.fr/hal-01683130
DOI : 10.1149/06426.0001ecst

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In this paper, we propose a benchmarking of supervised machine learning techniques (neural networks, Gaussian processes and support vector machines) in order to forecast the Global Horizontal solar Irradiance (GHI). We also include in this benchmark a simple linear autoregressive (AR) model as well as two naive models based on persistence of the GHI and persistence of the clear sky index (denoted herein scaled persistence model). The models are calibrated and validated with data from three French islands: Corsica (41.91°N; 8.73°E), Guadeloupe (16.26°N; 61.51°W) and Reunion (21.34°S ; 55.49°E). The main findings of this work are, that for hour ahead solar forecasting, the machine learning techniques slightly improve the performances exhibited by the linear AR and the scaled persistence model. However, the improvement appears to be more pronounced in case of unstable sky conditions. These nonlinear techniques start to outperform their simple counterparts for forecasting horizons greater than one hour.
ISSN: 0038-092X

Droits : info:eu-repo/semantics/OpenAccess
hal-01101564
https://hal.archives-ouvertes.fr/hal-01101564
https://hal.archives-ouvertes.fr/hal-01101564/document
https://hal.archives-ouvertes.fr/hal-01101564/file/Manuscript_Lauretetal_Rev_unmarked.pdf
DOI : 10.1016/j.solener.2014.12.014

Éditeur(s) : HAL CCSD
Résumé : International audience
The relationships between Philodendron solimoesense and the larvae of two chalcid wasp species, inhabiting up to 88% of the infructescences, were studied in French Guiana. Exurus sp. (Chalcidoidea, Eulophidae, Tetrastichinae), is a gall maker and its larvae develop at the expense of seeds which are transformed into galls. We estimate that two seeds are necessary for the development of one eulophid. Their impact on plant reproductive success appears to be important, since parasitized fruits produce 60% fewer seeds than nonparasitized fruits and could explain the reduced seed set observed (53%). The larvae of a Sycophila sp. (Chalcidoidea, Eurytomidae, Eurytominae) are also present in the fruits of P. solimoesense occupied by eulophid larvae. The eurytomid larvae apparently develop at the expense of about one eulophid and are responsible for the death of 39% of them by direct predation or indirectly by consuming the gall tissues. Eulophids are far more abundant than eurytomids, since parasitized fruits contain an average of 11 eulophids but only one eurytomid. As chalcid wasp emergence takes place in a closed cavity and sex ratios are strongly biased in a given gall, local mate competition may occur as observed for fig wasps within figs.
International Journal of Plant Sciences

hal-01202708
https://hal.archives-ouvertes.fr/hal-01202708

Éditeur(s) : HAL CCSD
Résumé : International audience
The pollination of Philodendron solimoesense (subgenus Meconostigma) was studied in four populations of French Guiana. Flowering is asynchronous within each population during July, and the flowering cycle is a 2-d process. Numerous insects visit Philodendron inflorescences, but the main pollinator seems to be Cyclocephala colasi (Scarabaeidae, Dynastinae). The pollination process displays aspects typical of beetle pollination: the production of heat and of a strong odor, the presence of a food reward (stigmatic secretion and sterile male flowers), and the presence of a copulation chamber. Flower heat production is important (ca. 117C above the ambient air) and may help to volatilize the fragrance. Attraction and choice-test experiments showed that C. colasi is not likely to depend on chemical information (such as pheromone) to localize conspecifics but may rely instead on stimuli produced by the inflorescences in order to meet mating partners
International Journal of Plant Sciences

hal-01202475
https://hal.archives-ouvertes.fr/hal-01202475

Éditeur(s) : HAL CCSD National Research Council Canada
Résumé : International audience
Spadix temperature was measured in three species of Philodendron: P. acutatum, P. pedatum and P.solimoesense. These species showed two different patterns of spadix temperature during their flowering cycle.In P. acutatum and P. pedatum (subgenus Philodendron), the spadix warmed up twice during the beginning ofeach flowering night with a temperature not significantly different from that of ambient air between the twopeaks. In P. solimoesense (subgenus Meconostigma), the spadix temperature rose up to 14oC above that ofambient air during the first night, then it progressively cooled down but remained 3-6oC above ambient airtemperature. We propose that the heat production and the spadix temperature patterns observed may reflectdifferent physiological processes and have a taxonomic significance in the genus Philodendron.
ISSN: 0008-4026

hal-01202714
https://hal.archives-ouvertes.fr/hal-01202714

Éditeur(s) : HAL CCSD Museum Nationale d'Histoire Naturelle Paris
Résumé : International audience
Comparative study of heat production in some Araceae. The thermogenetic cycle of the inflorescences is compared in the genera Anubias, Cercestis, Dieffenbachia, Homalomena and Philodendron. The genera Philodendron, Anubias and Homalomena have a thermogenetic cycle characterized by the production of two peaks of heat. In Dieffenbachia and Cercestis the cycle is characterized by the presence of a single peak appearing during the first day of the floral cycle. Differences between these two thermogenetic patternsare linked with pollination mecanisms.
Comparaison du cycle thermogénétique des inflorescences dans les genres Anubias, Cercestis, Dieffenbachia, Homalomena et Philodendron. Les genres Philodendron, Anubias et Homalomena ont un cycle thermogénétique caractérisé par la présence de deux pics de chaleur sans différence de temperature entre les deux événements. Dans les genres Dieffenbachia et Cercestis le cycle thermogénétique est caractérisé par la présence d’un seul pic de chaleur qui apparaît le premier jour du cycle floral. Les différences entre les deux types de cycles thermogénétiques sont liées aux mécanismes de pollinisation.
ISSN: 1280-8571

hal-01202740
https://hal.archives-ouvertes.fr/hal-01202740

Éditeur(s) : HAL CCSD International Association for Energy Economics
Résumé : International audience
In this paper we propose to determinate and to test a set ofstatistical parameters (20)to estimate the predictability of the global horizontal irradiation time series and thereby propose a new prospective tool indicating the expected error regardlessthe forecasting methodsa modeller can possibly implement. The mean absolute log return, which is a tool usually used in econometry, proves to be a very good estimator. Some examples of the use of this tool are exposed, showing the interest of this statistical parameter in concrete cases of predictions or optimizations.
ISSN: 0195-6574

hal-01180041
https://hal.archives-ouvertes.fr/hal-01180041
https://hal.archives-ouvertes.fr/hal-01180041/document
https://hal.archives-ouvertes.fr/hal-01180041/file/discriminent_param.pdf

Éditeur(s) : HAL CCSD
Résumé : International audience
Modèle 3D Terre-Mer et nouvelles données chronostratigraphiques sur le bassin Oligo-Miocène de Castelsardo, Sardaigne

hal-00604012
https://hal.archives-ouvertes.fr/hal-00604012

Éditeur(s) : HAL CCSD National Research Council Canada
Résumé : International audience
In French Guiana, inflorescences of Philodendron squamiferum Poepp. (Araceae) were regularly visited by the scarab beetle Cyclocephala simulatrix Hölne and (Scarabaeidae, Coleoptera) occasionally by Cyclocephala tylifera Hölne. The flowering cycle lasted 2 days, and the protogynous inflorescence exhibited features typical of beetle pollination (floral chamber, food rewards, flower heating). The spadix temperature was measured during the entire flowering cycle in French Guiana and at the Montreal Botanical Garden. Both sets of measurements gave a similar temperature pattern. The spadix warmed up twice at the beginning of each evening with no notable heat production between the two peaks. These two temperature peaks were well synchronized with the arrival and departure of beetles
ISSN: 0008-4026

hal-01202724
https://hal.archives-ouvertes.fr/hal-01202724

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
Trophobiotic associations between Caternaultiella rugosa (Heteroptera; Plataspidae) and two ant species, Camponotus brutus (Formicidae) and Myrmicaria opaciventris (Myrmicinae), were recorded at the base of the trunks of Bridelia micrantha (Euphorbiaceae). The bug colonies were generally sheltered in pavilions built by the ants, but during periods of proliferation, part of the colonies developed outside the pavilions. We examined the protective activity of the two associated ant species against an encyrtid parasitoid wasp that parasitized egg masses of the bug. Egg masses situated outside the pavilions were significantly less parasitized on trees occupied by either ant species than on experimental trees where ants were excluded by a sticky barrier. Egg masses were significantly less parasitized on trees occupied by C. brutus than on those occupied by M. opaciventris, both inside and outside the pavilions. Moreover, they were less parasitized inside than outside the pavilions when protected by C. brutus. Inside the pavilions, parental care of the egg masses and first-instar nymphs was abandoned to the ants. In contrast, outside the pavilions, the females of C. rugosa guarded egg masses and clusters of first-instar nymphs. Furthermore, adults and last-instar nymphs grouped around and above first-instar nymphs, forming a protective shield. These groups formed and disintegrated daily, according to the attending ant's rhythm of activity
ISSN: 0029-8549

hal-01202757
https://hal.archives-ouvertes.fr/hal-01202757
DOI : 10.1007/s004420000479

Éditeur(s) : HAL CCSD
Résumé : CorseAlp 2011 was held in April 2011. A link to the website is here: CorseAlp 2011. The CorseAlp field trips were designed to introduce the participants to the general features of the geology of Alpine Corsica and to recent specific discoveries. The three-day post-workshop field trip (Field trip 2) focused on the general architecture of Alpine Corsica in an EW transect between the Balagne region and Bastia. First day: The internal zones of Alpine Corsica: from Bastia to Saint Florent. Intinerary: Saint Florent, Serra di Pigno, Cima Malaspina, Patrimonio, Saint Florent. Second day: The Tenda massif and its eastern margin. Intinerary: Saint Florent, Casta, Fontana Porragghia, Rue de Morello, Fontana a Murello quarry; Fornali. Third day: The external zones of Alpine Corsica in the Balagne region. Intineray: Saint Florent, Colle di U'Vezzu, Ostriconi, Belgodere, San Sebastiano Chapel, San Colombano, Ponte Leccia, Francardo, Bastia.
Journal of the Virtual Explorer

hal-00688971
https://hal.archives-ouvertes.fr/hal-00688971

Éditeur(s) : HAL CCSD Ecoscience
Résumé : International audience
Hymenoptera pollinators and figs (ripe or unripe) of Ficus vallis-choudae are protected from the predatory activity of myrmicine ants (Atopomyrmex mocquerisi; Crematogaster clariventris; Cremato gaster sp.) by other ants (Camponotus acvapimensis and Camponotus brutus; Formicinae) who attack neither unripe figs nor the pollinator. On trees occupied by Atopomyrmex and Crematogaster, and on trees invaded by columns of workers after recruitment by scouts, the predatory activity begins when the fig wasps emerge. Then, the ants attack unripe figs (asynchronization in ripeness), destroying whole figs of certain trees. The male function of the trees through pollen dispersal by fig wasps is, therefore, severely reduced, while the female function (seed dispersal) is affected only on unripe figs before fig wasp emergence. We recorded 13 ant species on the 73 Ficus vallis-choudae of the Batchenga savanna (Cameroon) studied, but only the five previously cited species were able to occupy an entire fig tree. The three Myrmicinae which have a status of dominant (large colony size; strong territoriality vis-à-vis other dominant species; can tolerate non-dominant species) tended scale insects. Both Camponotus species (and the eight other ant species) are non-dominant (small colony size), but are able to occupy a whole tree under certain conditions (here, when they tend the tettigometrid Hilda undata) and to be territorial. Their status corresponds, therefore, to that of sub-dominant. Tests of aggressiveness showed that each ant species is aggressive towards alien conspecifics. C. brutus individuals were tolerated on fig trees occupied by Atopomyrmex mocquerisi or by Crematogaster clariventris, while workers of both latter species, who do not tolerate one another, were not tolerated on fig trees occupied by C. brutus. In this situation, the cost-benefit for the trees depends on the ant species that occupies their foliage; C. brutus, when tending tettigometrids, is advantageous. There is, therefore, an indirect influence of the tettigometrids on the production of fig pollinating wasps and seeds. Chez Ficus vallis-choudae, les figues, matures ou non, et leurs hyménoptères pollinisateurs sont protégés de l'activité prédatice de la part de trois espèces de fourmis Myrmicinae (Atopomyrmex mocquerisi; Crematogaster clariventris; Crematogaster sp.) par d'autres fourmis (Camponotus acvapimensis et Camponotus brutus; Formicinae) qui, elles, ne s'attaquent ni aux figues non matures, ni aux pollinisateurs. L'action prédatrice des Atopomyrmex et des Crematogaster débute à l'émergence des pollinisateurs et sétend sur des figuiers qu'elles n'occupent pas grâce à la formation de colonnes recrutées par des ouvrières éclaireuses. Ensuite, elles attaquent les figues moins mûres (asynchronie dans la maturation), toutes les figues d'un arbre pouvant être détruites. La fonction mâle de l'arbre est donc sévèrement réduite via la prédation des pollinisateurs. La fonction femelle est moins affectée, les figues, au moment de l'émergence des pollinisateurs ayant des graines matures. Nous avons recensé 13 espèces de fourmis sur les 73 Ficus vallis-choudae étudiés dans la savane de Batchenga (Cameroun), mais uniquement les cinq espèces citées ci-haut peuvent occuper un figuier entier. Les trois Myrmicinae sont des « dominantes » (grosses colonies; forte territorialité contre les autres dominantes; peuvent tolérer des « non-dominantes » ) qui exploitent des cochenilles. Les deux Camponotus (ainsi que les huit autres espèces) appartiennent au lot des « non-dominantes » (petites colonies), mais dans certaines situations (ici, lorsqu'elles exploitent le Tettigometridae Hilda undata) elles peuvent aussi occuper un arbre entier et en défendre l'accès. On les qualifie alors de « sub-dominantes » . Des tests d'agressivité ont permis de montrer que chaque espèce est agressive vis-à-vis d'ouvrières étrangères conspécifiques, que les ouvrières de Camponotus brutus sont tolérées sur les figuiers occupés par Atopomyr ex mocquerisi ou par Crematogaster clariventris, alors que les ouvrières de ces deux espèces, qui ne se tolèrent pas entre elles, ne sont pas tolérées sur les figuiers occupés par Camponotus brutus. Dans ces conditions, le rapport coût/bénéfice pour l'arbre dépend de l'espèce de fourmi qui l'occupe, Camponotus brutus étant l'espèce avantageuse, grâce à l'exploitation des tettigomètres. En conséquence, il y a une influence indirecte du tettitogomètre sur la production d'insectes pollinasiteurs et de graines.
ISSN: 1195-6860

hal-01214443
https://hal.archives-ouvertes.fr/hal-01214443
DOI : 10.2307/42902390

Éditeur(s) : HAL CCSD
Résumé : International audience
In this work, we have led an analysis of the error of different global solar radiation prediction models according to the global solar radiation variability. Different predictions models where performed such as machine learning techniques (Neural Networks, Gaussian processes and support vector machines) in order to forecast the Global Horizontal solar Irradiance (GHI). We also include in this study a simple linear autoregressive (AR) model as well as two naive models based on persistence of the GHI and persistence of the clear sky index (denoted herein scaled persistence model). The models are calibrated and tested with data from three 3 French islands: Corsica (42.15°N ; 9.08°E), Guadeloupe (16.25°N ; 61.58°W) and Reunion (21.15°S ; 55.5°E). Guadeloupe and Reunion are located in a subtropical climatic zone whereas Corsica is in a tempered climatic zone. Hence the global solar radiation variation differs significantly. The output error of the different models was quantified by the nRSME. In order to quantify the influence of the global solar radiation variability on the forecasting models error we performed a classification of typical days according to different typical days. Each class of typical day is defined by a variation of global solar radiation rate. For each class and for each location, the selected forecasting models where performed and the error was quantified. With this analysis a global solar radiation forecasting models can be selected according to the location, the global solar radiation fluctuations and hence the meteorological conditions. INTRODUCTION Large and frequent variations of solar radiation can be observed in tropical climates with amplitudes reaching 800 W/m² and occurring within a short time interval, from few seconds to few minutes, according to the geographical location. Such fluctuations can be due for example to the dynamic of clouds which can be very complex and depend on cloud type, size, speed and spatial distribution and, more generally, due to some specific local meteorological conditions. Thus, the solar energy forecasting, a process used to predict the amount of solar energy available in the current and near terms, might be a difficult task. Some of the best predictors found in literature are Autoregressive and moving average (ARMA) [5,7,8], Bayesian inferences [9,10], Markov chains [11], k-Nearest-Neighbors predictors [12] or artificial intelligence techniques as the Artificial Neural Network (ANN) [9-11]. Although these methodologies are potentially good in many areas, we observed in our previous studies on global radiation prediction [9,13,14] that the simple model based on the persistence of the clear sky index gives often very good results with acceptable errors [15] for short term forecasting time horizon (<= 1 hour). The goal of this paper is to determinate the influence of solar radiation variability regarding different classes of days on the expected error provided by different forecasting methods that the modeller can possibly implement. The paper is organized as follow: Section 2 describes the data we have used. Section 3 exposes the classification methodology and the results obtained for the three studied locations. In the two following sections, the forecasting methods are exposed and then 3 the errors on the forecasting results for each location and for each class are exposed.
The Third Southern African Solar Energy Conference (SASEC2015)
Kruger National Park, South Africa

Droits : info:eu-repo/semantics/OpenAccess
hal-01099487
https://hal.archives-ouvertes.fr/hal-01099487
https://hal.archives-ouvertes.fr/hal-01099487/document
https://hal.archives-ouvertes.fr/hal-01099487/file/article%20SASEC.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In this paper, we propose a benchmarking of supervised machine learning techniques (neural networks, Gaussian processes and support vector machines) in order to forecast the Global Horizontal solar Irradiance (GHI). We also include in this benchmark a simple linear autoregressive (AR) model as well as two naive models based on persistence of the GHI and persistence of the clear sky index (denoted herein scaled persistence model). The models are calibrated and validatedwith data from three French islands: Corsica (41.91°N; 8.73°E), Guadeloupe (16.26°N; 61.51°W) and Reunion (21.34°S ; 55.49°E). The main findings of this work are, that for hour ahead solar forecasting,the machine learning techniques slightly improve the performances exhibited by the linear AR and the scaled persistence model. However, the improvement appears to be more pronounced in case of unstable sky conditions.These nonlinear techniques start to outperform their simple counterparts for forecasting horizons greater than one hour.
ISSN: 0038-092X

Droits : info:eu-repo/semantics/OpenAccess
hal-01099211
https://hal.archives-ouvertes.fr/hal-01099211
https://hal.archives-ouvertes.fr/hal-01099211/document
https://hal.archives-ouvertes.fr/hal-01099211/file/Manuscript_Lauretetal_Rev_unmarked.pdf

Éditeur(s) : HAL CCSD National Research Council Canada
Résumé : International audience
The spadix of Arum italicum Miller consists of two main parts: a clavate sterile portion (appendix) and a cylindroid fertile portion. In the fertile portion with both male and female zones, there are two zones of sterile flowers (bristles). The basal portion of bristles is surrounded by a verrucose structure consisting of a mass of tissular excrescences. During early stages of development, there is no free space between the different zones of the inflorescence. The elongation of the inflorescence axis is what eventually separates the different zones from each other. There are no atypical flowers that are morphologically intermediate between male and female flowers as is the case in other genera of Aroideae (e.g., Cercestis, Philodendron, Schismatoglottis). The structure of the bristles in the inflorescences of Arum does not correspond to any type of atypical flower (unisexual or bisexual) that has been analysed previously in the Araceae. From a developmental point of view, it is not possible to determine if the bristles correspond to aborted or modified female or male flowers. In the early stages of development, the stamens, staminodes, and appendix are covered by globular masses of extracellular calcium oxalate crystals.
Le spadice de l’Arum italicum comporte deux parties principales : une portion claviforme stérile (appendice) et une portion cylindroïde fertile. Dans la portion fertile avec zones mâles et femelles, il y a deux zones de fleurs stériles (soies). La portion basales des soies est entourée par une structure verruqueuse, constituée d’une masse d’excroissances tissulaires. Aux premiers stades du développement, il n’y a pas d’espace libre entre les différentes zones de l’inflorescence. L’élongation de l’axe de l’inflorescence est ce qui sépare éventuellement les différentes zones l’une de l’autre. Il n’y pas de fleurs atypiques intermédiaires entre des fleurs mâles et des fleurs femelles, comme c’est le cas dans d’autres genres d’Aroideae (p. ex. Cercestis, Philodendron, Schismataglottis). La structure des soies chez les inflorescences de l’Arum ne correspond à aucune des fleurs atypiques (unisexuées ou bisexuées) qui ont précédemment été analysées chez les Araceae. Considérant le développement, il n’est pas possible de déterminer si les soies correspondent à des modifications de fleurs femelles ou mâles avortées. Aux premiers stades du développement, les étamines, les staminodes et les appendices sont couverts de masses globuleuses constituées de cristaux extracellulaires d’oxalate de calcium.
ISSN: 0008-4026

hal-01206194
https://hal.archives-ouvertes.fr/hal-01206194