Éditeur(s) : Springer Berlin / Heidelberg
Résumé : The role of particles in the fate and speciation of trace metals in macrotidal estuaries was studied using a surface complexation model (MOCO). Cadmium was selected as the target metal contaminant due to its reactivity in estuaries: cadmium behavior is mainly controlled by heterogeneous processes (sorption/desorption) related to salinity and suspended matter gradients. Various scenarios of suspended matter distribution according to salinity were simulated. The impact of surface properties (specific surface area, density of surface sites, acido-basic properties, and complexation constant) was evaluated using data collected on particles from the Gironde, Loire, and Seine estuaries. Our results show that particle surface properties, evaluated on the basis of various parameters, are instrumental in "non-conservative" contaminant speciation in the estuarine environment. Their evaluation enables us to understand and simulate, to a large extent, the fate of "Cd-type" contaminants (whose behavior is controlled by competition between sorption and desorption processes). The natural variations of these properties can be responsible for significant modifications of the Cd speciation in the macrotidal estuaries where salinity and SM gradients are very strong.
The Handbook of Environmental Chemistry (1433-6839) (Springer Berlin / Heidelberg), 2006 , Vol. 5H , P. 265-301

Droits : 2006 Springer
http://archimer.ifremer.fr/doc/2006/publication-2005.pdf
DOI:10.1007/b89479
http://archimer.ifremer.fr/doc/00000/2005/

Éditeur(s) : HAL CCSD Springer-Verlag Berlin Heidelberg
Résumé : International audience
The main biological function of reaction wood is to act as " muscle " for trees, enabling them to control their posture. The key property to achieve this function is the development of high mechanical stress during the formation of reaction wood cells, called " maturation strains ". Actually, reaction wood formation is basically the asymmetric formation of wood around the tree circumference, with higher maturation strains on the side where reaction wood is formed than on the opposite side. This asymmetry enables stems to bend upward or to compensate for the downward bending induced by gravity. At the cross section level, the performance in this biological function is linked not only to the magnitude of this asymmetry but also to an effect of the cross-sectional size (diameter) of the stem. Eccentric growth and variations in wood mechanical stiffness are second order effects that can modify this performance. Differences in maturation strains between reaction and non-reaction woods are related to their specific cell wall structure and composition. The swelling of the cell wall matrix during maturation and the effect of microfibril angle explain the differences in maturation strains between normal and compression wood. However, this mechanism fails in explaining the high maturation shrinkage of tension wood, and several hypotheses at the molecular levels are still under debate. How trees perceive their gravitational disequilibrium is also an open question for physiologists. Integrative biomechanical modelling (from the polymer level to the cell wall, cross section and whole tree levels) enables defining key variables that explain the performance of reaction wood as a system that insures the stem motricity. Maturation strains can be precisely measured only in recently formed wood at the tree surface, but their changes during the whole tree life can also be estimated by retrospective dendrochronological analysis through structural markers of reaction wood. Lastly, wood in living trees ensures general storage, defence, vascular and skeletal functions, that ask general questions about synergies and trade-offs as the structural characteristics of reaction wood can affect all these functions.
The Biology of Reaction Wood

ISBN : 978-3-642-10813-6
hal-01452085
https://hal.archives-ouvertes.fr/hal-01452085
https://hal.archives-ouvertes.fr/hal-01452085/document
https://hal.archives-ouvertes.fr/hal-01452085/file/Chap_Gril_al_Biomechanical_action_biological_functions_2014.pdf

Éditeur(s) : HAL CCSD Springer Berlin / Heidelberg
Résumé : International audience
In distributed collaborative systems, replicated objects, shared by users, are subject to concurrency constraints. All methods [4, 13, 18, 15, 16, 19, 22] proposed to serialize concurrent operations and achieve copies convergence of replicated objects are based on the use of Operational Transformations. In this context, giving the user the ability to undo an operation has been recognized as a difficult problem [1, 2, 3, 12, 14, 20, 21]. The few general propositions to solve the problem sometimes compromise copies convergence and/or users' intention, insofar as the Operational Transformations used are unsuitable for undo. This paper has a twofold objective. Firstly, it aims to highlight two general conditions (named C3 and C4) that need to be satisfied by any transformation adapted to undo. Secondly, it presents a general undo algorithm based on the definition of a generic undo-fitted transformation, which automatically verifies these conditions. The interest of the proposed method is that the undoing of an operation obeys to the same processing as the one used for regular operations in collaborative systems such as [15,19].
12th International Conference on Cooperative Informations Systems
Agia Napa, Cyprus

hal-00684656
https://hal.archives-ouvertes.fr/hal-00684656
DOI : 10.1007/978-3-540-30468-5_12

Éditeur(s) : HAL CCSD Springer-Verlag Berlin Heidelberg
Résumé : International audience
Reaction wood produces very peculiar maturation stresses at the tree periphery i.e. compressive stress or very high tensile stress, for compression and tension wood respectively, as compared to moderately high tensile stress for normal wood. This means that both its mechanical state and its mechanical and physical properties differ from normal wood. Compression wood shows big differences from normal wood in conifers, for all physical and mechanical properties: higher density and axial crushing strength (MOR) but lower modulus of elasticity (MOE), far higher axial (longitudinal) shrinkage but lower radial and tangential shrinkage, sometimes even lower than the axial shrinkage. For tension wood things are less simple and can vary a lot from hardwood species to species. Globally there are no systematic differences in density and transverse shrinkage, MOE tends to be a little higher while MOR is slightly lower. However, axial shrinkage is much higher for tension wood with a gelatinous layer (G layer) than normal wood due to the specific gel like organization of cellulose microfibrils in the G layer. For tension wood without a G layer(which is rather frequent) axial shrinkage in the first drying operation is around two times higher than in normal wood mainly because of a kind of hygro-thermal release of locked in maturation stress. Overall the very high tensile stress and stored elastic energy in tension wood lead to problemsin wood processing (end splitting and board warping), which is far less the case for compression wood. But due to the large difference in properties relative to normal wood, compression wood occurrence is always a big problem for the in service behaviour of timber, which is seldom the case for tension wood.
The biology of reaction wood

ISBN : 978-3-642-10813-6
hal-01135273
https://hal.archives-ouvertes.fr/hal-01135273