Éditeur(s) : HAL CCSD Mineralogical Society
Résumé : International audience
Almost all magmas contain sulfide- or sulfate-bearing phases. In most natural samples the sulfur-bearing phase is a sulfide, which typically is pyrrhotite (Fe1−xS) or pyrite (FeS2) although chalcopyrite (CuFeS2), pentlandite ((Fe,Ni)9S8), sphalerite (ZnS) or molybdenite (MoS2) may be present as well. Sulfate minerals are rare at magmatic conditions, and anhydrite (CaSO4) is the most common. Other magmatic SO4-bearing minerals include the sodalite group minerals (haüyne simplified formula: (Na,Ca)4-8(Al6Si6(O,S)24)(SO4,Cl)1-2), scapolite minerals (silvialite: (Ca,Na)4Al6Si6O24(SO4,CO3)), and S-bearing apatite (Ca5(PO4)3(F, Cl, OH)). Barite (BaSO4) has been mentioned in rare cases (Marchev 1991). Sulfur-bearing minerals usually constitute a negligible fraction of the mineral assemblage in magmatic rocks and thus can be classified as accessory minerals. The crystallization of sulfide, sulfate, and S-bearing minerals strongly depends on melt composition, temperature and pressure, and the S speciation in melt which, in turn, is strongly dependent on the prevailing oxygen fugacity (Baker and Moretti 2011, this volume; Wilke et al. 2011, this volume). Irrespectively of the low abundance of S-bearing minerals, the evolution of sulfur in magmas may be evaluated from the occurrence of sulfides and sulfates. These minerals are critical for estimating the activity of various sulfur-bearing species in magmas and can be used to constrain the oxygen fugacity and the S concentration in the melt (e.g., pre-eruptive sulfur concentration in melts). The presence of either sulfide or sulfate in silicate melt indicates that the predominant dissolved sulfur species in the melt are S2− or S6+, respectively. Typically one of these species is dominant, but there are conditions where S2− ...
ISSN: 1529-6466

hal-00644580
https://hal.archives-ouvertes.fr/hal-00644580
DOI : 10.2138/rmg.2011.73.10

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
The processes active in the deep crust above an oceanic subduction zone during its evolution have been constrained through a detailed geochemical study (major and trace elements and Sr, Nd and Pb isotopes) of representative samples through an 30 km thick exhumed crustal section of the Cretaceous Kohistan oceanic island arc (Northern Pakistan). The use of both trace elements and radiogenic isotopes reveals two distinct geochemical suites (suites A and B) within the JijalPatanKiruKamila (JPKK) complex. Suite A is characterized by a progressive enrichment in Pb-207 and a decrease in Nd-143/Nd-144 with increasing La-N/Sm-N. Suite B has higher Pb-207/Pb-204 and lower Nd-143/Nd-144 ratios with approximately constant La-N/Sm-N. By combining trace elements with different partitioning behaviour it is demonstrated that there is an increasing contribution of the subduction component in the magmas with time. It is also possible to distinguish a slab component imprint carried by aqueous fluids from one corresponding to sediment melts. Intrusive granites are abundant in the upper levels of the JPKK section. All were generated at the arc root level (Jijal crustal section) during dehydration-melting of hornblende-rich plutonic rocks. A three-stage geodynamic model is proposed for the evolution of the arc over a period of 30 Myr. The first stage (117105 Ma) starts with the onset of subduction, which was followed by the building of the volcanic arc. The second stage (10599 Ma to 9691 Ma) corresponds to a major igneous event, which was characterized by abundant magma underplating and granulite-facies metamorphism at the arc base. Recycling of the residualcumulative lower crust into the convective asthenospheric mantle was efficient during this stage, and was probably related to thermo-mechanical erosion of the base of the crust. The last stage (9585 Ma) corresponds to a period of low magmatic activity, which marked the end of the intra-oceanic subduction. This is related to the formation of a cold blanket above the slab surface as a result of thermo-mechanical erosion of the cold walls of the subduction zone (i.e. the upper part of the slab and the base of the overriding plate), and corner flow dragging the cold material into the zone of melt generation. Ultimately, a voluminous magmatic pulse occurred around 85 Ma (forming the Chilas complex), before arccontinent collision.
ISSN: 0022-3530

hal-00420068
https://hal.archives-ouvertes.fr/hal-00420068
DOI : 10.1093/petrology/egp010

Éditeur(s) : HAL CCSD Société géologique de France
Résumé : International audience
Age constraints on the protoliths, deformation, metamorphism and melting events are key parameters when correlating different continental lithospheric remnants among each other and disentangling their evolution within large-scale orogens. In situ U-Th-Pb chemical dating on monazites using Electron Probe Micro-Analyser (EPMA) has been performed on eight samples throughout the Variscan Maures-Tanneron massif (SE France) in order to date the medium to high-tectonothermal events related to the Variscan orogeny.Results indicate a polyphased crustal evolution : (i) U-Th-Pb ages obtained in polygenetic monazite grain cores gave inherited Upper Ordovician (456 ± 11 Ma) age, highlighting the large scale occurrence of the Ordovician magmatic activity in the North Gondwanian margin. An Early Devonian (404 ± 10 Ma) age may date a protolith emplacement related to calc-alkaline supra-subduction magmatism or could be associated to an early medium-grade metamorphism, prior to collisional stage. (ii) The crustal thickening stage has been further recorded in prograde metamorphic monazites formed during the underthrusting and subsequent nappe stacking events, under amphibolite facies conditions. This stage is dated between 382 ± 11 (Middle Devonian) and 331 ± 5 Ma (Late Visean). (iii) An orogenic partial melting event took place during Middle Carboniferous and is accompanied by the crystallization of crustal peraluminous magmas (Plan-de-la-Tour granite, 329 ± 3 Ma).This contribution demonstrates the capacity of monazite to record the prograde path of rocks during increasing metamorphic conditions related to stages of crustal thickening, and the robustness of the U-Th-Pb chronometer in monazite despite the overprinting of high-grade thermal events, including partial melting. The age ranges of the different orogenic stages reported in this study are in good agreement with those reported in adjacent Variscan Corsica and Sardinia; while correlations with other nearest Variscan massifs like the Argentera massif in the southwestern Alps or the French Massif Central remain more hypothetic. The Internal Zone of the Maures-Tanneron massif, and more widely the Internal Zone of the Maures-Tanneron-Corsica-Sardinia segment, is part of the southern orogenic root system of the Variscan belt.
EISSN: 1777-5817

insu-01140973
https://hal-insu.archives-ouvertes.fr/insu-01140973
DOI : 10.2113/gssgfbull.186.2-3.145

Éditeur(s) : HAL CCSD American Geophysical Union (AGU)
Résumé : International audience
[1] Zircons and monazites from 6 samples of the North Ayilari dextral shear zone (NAsz), part of the Karakorum fault zone (KFZ), have been dated with the U-Th-Pb method, using both ID-TIMS and SIMS techniques. The ages reveal (1) inheritance from several events spanning a long period between the late Archean and the Jurassic; (2) an Eocene-Oligocene magmatic event (similar to 35-32 Ma); (3) an Oligo-Miocene magmatic event (similar to 25-22 Ma), at least partly synkinematic to the right-lateral deformation; and (4) a period of metamorphism metasomatism (similar to 22-14 Ma) interpreted as thermal and fluid advection in the shear zone. The Labhar Kangri granite located similar to 375 km farther Southeast along the KFZ is dated at 21.1 +/- 0.3 Ma. Such occurrence of several Oligo-Miocene granites along the KFZ, some of which show evidence for synkinematic emplacement, suggests that the fault zone played an important role in the genesis and /or collection of crustal melts. We discuss several scenarios for the onset and propagation of the KFZ, and offset estimates based on the main sutures zones. Our preferred scenario is an Oligo-Miocene initiation of the fault close to the NA range, and propagation along most of its length prior to similar to 19 Ma. In its southern half, the averaged long-term fault-rate of the KFZ is greater than 8 to 10 mm/a, in good agreement with some shorter-term estimates based on the Indus river course, or Quaternary moraines and geodesy. Our results show the KFZ cannot be considered as a small transient fault but played a major role in the collision history.
ISSN: 0278-7407

hal-00412570
https://hal.archives-ouvertes.fr/hal-00412570
DOI : 10.1029/2007TC002184

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
A laser ablation ICP-MS U-Pb age of 17.84 +/- 0.12 Ma (late Burdigalian) was obtained from monazites separated from a leucocratic diatexite collected in close proximity to a small peridotite massif incorporated into the lower crustal sequence of the Edough Massif (north-eastern Algeria), a southern segment of the peri-Mediterranean Alpine Belt. Monazites extracted from a neighbouring deformed leucogranite intruding early Paleozoic phyllites yield a consistent age of 17.4 +/- 1.3 Ma. Zircons occurring in the same leucogranite, with magmatic characteristics, have an age of 308 +/- 7 Ma interpreted as dating magmatic crystallisation of the leucogranite and reflecting partial melting during the Hercynian orogeny. Low Th/U domains (Th/U<0.10) from the same grains substantiate recrystallisation during a younger metamorphic event whose upper age limit is 286 +/- 11 Ma. These results emphasize the polycyclic evolution of basement rocks preserved in the crystalline units of the western Mediterranean and indicate that part of their metamorphic features were inherited from older, Hercynian, events. Taken together with published Ar-Ar dates, the late Burdigalian age of monazites indicates a rapid cooling rate of c. 370 degrees C/Ma and is regarded as closely approximating the emplacement of the peridotites into the Hercynian basement. The monazite ages are significantly younger than those recorded for orogenic peridotites from the Betic-Rif oroctine and for the timing of lithospheric extension forming the Alboran sea. It is also younger than rifting and back-arc extension opening the Liguro-Provencal basin. The late Burdigalian age is interpreted as dating the incipient rifting event that opened the Algerian basin, which is consequently not a continuation of the Liguro-Provencal basin. At the scale of the western Mediterranean, these observations concur with current models supporting slab roll-back and an eastwards migration of extension in the western Mediterranean, but suggest that the Algerian basin opened as a result of torsion and stretching of the Thethyan slab due to its steepening under the Alboran microplate.
ISSN: 0009-2541

hal-00424511
https://hal.archives-ouvertes.fr/hal-00424511
DOI : 10.1016/j.chemgeo.2008.11.016

Éditeur(s) : HAL CCSD Geological Society of America
Résumé : International audience
his study describes the structural setting, petrogenesis, and geochronology of a suite of acidic magmatic rocks that are intruded in the metamorphic core of the Tertiary ophiolitic suture zone of the Sabzevar Range, NE central Iran. These intrusive bodies show tabular geometries with solid-state fabrics documenting syntectonic emplacement during crustal shortening. In the total alkalis-silica (TAS) diagram, their compositions define a medium-K calc-alkaline suite, spanning from basaltic andesite to the dacite and rhyolite fields. They show characteristic low MgO (0.15–0.60 wt%) and Ni (<20 ppm), high Sr contents, a negligible Eu anomaly, and extremely fractionated rare earth element (REEs), with high La/Yb and Sr/Y (up to 900) ratios, but very low Yb and Y contents. They also show zircon Hf isotope compositions compatible with a mid-ocean-ridge basalt (MORB)–type oceanic crust. Inverse and forward thermobarometry constrains conditions of magma crystallization in the upper-pressure field of the amphibolite facies (ca. 1.2–1.5 GPa and 750 °C). Integrated U-Pb zircon and 40Ar/39Ar white mica and amphibole geochronology constrains the Sabzevar magmatism to the late Paleocene (at ca. 58 Ma). Genesis of the Sabzevar magmatic suite is interpreted in terms of prograde, wet amphibolite melting during oceanic subduction, within a pressure-temperature range between a plagioclase-out and a hornblende-out boundary. Magma differentiation and high-pressure amphibole fractionation of pristine slab melts are proposed as the dominant factors that imparted the adakite signature in the Sabzevar structural zone. Implications in terms of the regional tectonic scenario are discussed and framed within the advancing and retreating evolution of the Neotethyan subduction during the Mesozoic–Tertiary time span.
ISSN: 0016-7606

hal-01122824
https://hal.archives-ouvertes.fr/hal-01122824
DOI : 10.1130/B30913.1

Éditeur(s) : HAL CCSD
Résumé : International audience
The geology of the North Pyrenean Zone in the central Pyrenees allows for the observation in the field of theentire section of the Pyrenean rift, from the mantle to the crust and the Mesozoic cover (pre, syn and post rift).The good knowledge we have of the pre-Alpine history of the Pyrenees allows us to properly constrain the Alpinegeological evolution of the pre-Triassic rocks which record both Variscan and Alpine orogenic cycles.The mantle outcrop as kilometric to centimetric fragments of peridotite dispersed within a carbonate metamorphicbreccia. The study of peridotite serpentinisation shows several events of low-temperature serpentinisation, incontact with seawater. In some locallities, we can observe a mixture of fragments of variously serpentinizedperidotites. This suggests a tectonic context where fragments of peridotites from different structural levels weresampled more or less synchronously.The granulitic basement is characterized by a Variscan syndeformational HT event (300-280 Ma). So farwe have not found any trace of a Cretaceous HT event (> 500C). On the other hand, the basement is affectedby a regional metasomatism that began during the Jurassic and became more spatially focused with time until itwas restricted to the Pyrenean rift during the Aptien, Albian and Cenomanian. The talc-chlorite metasomatism(120-95 Ma) shows an evolution from a static toward a syn-deformation hydrothermal event, under a more or lessnormal geothermal gradient. Extensional deformation is recorded by the reworking of several inherited low-angleVariscan tectonic contacts, but also by dispersed high-angle extensional shear zones formed under greenshistconditions.The metamorphic Mesozoic cover of the basement massifs, which constitute the so-called Internal MetamorphicZone, is an allochtonous unit made of lenses of Mesozoic rocks enclosed into the breccia, whichlocally contains peridotite and basement clasts. The Mesozoic metamorphic carbonates show a first phase ofsyn-metamorphic (450-600C, P < 2 kb) ductile deformation, and subsequent phases of folding and fracturing.The datation of neoformed minerals give a 108-85 Ma time span for the metamorphism. We interpret this brecciaas an abandonment breccia which marks the emergence of the main detachment. The basal contact of the Mesozoiccover has a complex 3D geometry traced by Triassic evaporites. It corresponds to a major pre- and synorogenicpolyphased tectonic contact.All these data show a geometrically complex hyper-extended rift where the crust was not stretched under ahigh geothermal gradient but thinned by the tectonic extraction of relatively thin lenses and perhaps cut by highangle low-grade shear zones. The 3D geometry, as well as the strain records and the breccia lithologies stronglysuggest a non-cylindricity for the exhumation process, probably within a transtentional system
Geophysical Research Abstracts
Vienne, Austria

insu-01510371
https://hal-insu.archives-ouvertes.fr/insu-01510371

Éditeur(s) : HAL CCSD Elsevier
Résumé : The Erro-Tobbio peridotites (Voltri Massif, Ligurian Alps) represent subcontinental lithospheric mantle tectonically exhumed during Permo-Mesozoic extension of the Europe-Adria lithosphere. Previous studies have shown that exhumation started during Permian times, and occurred along kilometer-scale lithospheric shear zones which enhanced progressive deformation and recrystallization from spinel- to plagioclase-facies conditions. Ongoing field and petrologic investigations have revealed that the peridotites experienced, during uplift, a composite history of diffuse melt migration and multiple episodes of ultramafic-mafic intrusions. In this paper we present the results of field, structural and petrologic-geochemical investigations into a sector of the Erro-Tobbio peridotite unit that preserves well this multiple intrusion history. Melt impregnation in the peridotites is evidenced by significant plagioclase enrichment and crystallization of unstrained orthopyroxene replacing kinked mantle olivine and clinopyroxene; impregnating melts were thus opx-saturated. Melt-rock interaction caused chemical changes in mantle minerals (e.g. Al decrease and REE increase in cpx; Ti and Cr# enrichment in spinel). Nevertheless, clinopyroxenes still exhibit LREE depletion (Ce;N;/Sm;N; = 0.006-0.011), indicating a depleted signature for the percolating melts. Melt impregnation was thus related to diffuse porous flow migration of depleted MORB-type melt fractions that modified their compositions towards opx saturation by mantle-melt interaction during ascent. The impregnated peridotites are intruded by a hectometer-scale stratified cumulate body, mostly consisting of troctolites and plagioclase wehrlites, showing gradational, interfingered contacts with the host mantle rocks. Subsequent intrusion events are revealed by the occurrence of olivine gabbros as decameter-wide lenses, variably thick (centimeter- to meter-scale) dykes and thin dykelets, which crosscut both the peridotite foliation and the magmatic layering in the cumulates. Overall, major and trace element compositions of minerals in the intrusives indicate that they represent variably differentiated cumulus products crystallized from rather primitive N-MORB-type aggregated melts. Slightly more evolved compositions are shown by olivine gabbros, relative to the troctolites and plagioclase wehrlites of the cumulate body. Mineral chemistry features (e.g. the Fo-An correlation and high Na, Ti, Mg# in cpx) indicate that the studied intrusive rocks crystallized at moderate pressure conditions (3-5 kbar, i.e. 9-15 km depth). Our study thus points to a progressive transition from porous flow melt migration to emplacement of magmas in fractures, presumably related to progressive change of lithospheric mantle rheology during extension-related uplift and cooling.
ISSN: 0024-4937

hal-00407669
https://hal.archives-ouvertes.fr/hal-00407669
DOI : 10.1016/j.lithos.2006.06.014

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
The composition of S-rich apatite, of volatile-rich glass inclusions in apatite, and of interstitial glasses in alkaline xenoliths from the 1949 basanite eruption in La Palma has been investigated to constrain the partitioning of volatiles between apatite and alkali-rich melts. The xenoliths are interpreted as cumulates from alkaline La Palma magmas. Apatite contains up to 0.89 wt% SO3 (3560 ppm S), 0.31 wt% Cl, and 0.66 wt% Ce2O3. Sulfur is incorporated in apatite via several independent exchange reactions involving (P5+, Ca2+) vs. (S6+, Si4+, Na+, and Ce3+). The concentration of halogens in phonolitic to trachytic glasses ranges from 0.15 to 0.44 wt% for Cl and from < 0.07 to 0.65 wt% for F. The sulfur concentration in the glasses ranges from 0.06 to 0.23 wt% SO3 (sulfate-saturated systems). The chlorine partition coefficients (D (Cl) (apatite/glass) ) range from 0.4 to 1.3 (average D (Cl) (apatite/glass) = 0.8), in good agreement with the results of experimental data in mafic and rhyolitic system with low Cl concentrations. With increasing F in glass inclusions D (F) (apatite/glass) decreases from 35 to 3. However, most of our data display a high partition coefficient (similar to 30) close to D (F) (apatite/glass) determined experimentally in felsic rock. D (S) (apatite/glass) decreases from 9.1 to 2.9 with increasing SO3 in glass inclusions. The combination of natural and experimental data reveals that the S partition coefficient tends toward a value of 2 for high S content in the glass (> 0.2 wt% SO3). D (S) (apatite/glass) is only slightly dependent on the melt composition and can be expressed as: SO3 apatite (wt%) = 0.157 * ln SO3 glass (wt%) + 0.9834. The phonolitic compositions of glass inclusions in amphibole and hauyne are very similar to evolved melts erupted on La Palma. The lower sulfur content and the higher Cl content in the phonolitic melt compared to basaltic magmas erupted in La Palma suggest that during magma evolution the crystallization of hauyne and pyrrhotite probably buffered the sulfur content of the melt, whereas the evolution of Cl concentration reflects an incompatible behavior. Trachytic compositions similar to those of the (water-rich) glass inclusions analyzed in apatite and clinopyroxene are not found as erupted products. These compositions are interpreted to be formed by the reaction between water-rich phonolitic melt and peridotite wall-rock.
ISSN: 0010-7999

hal-00644803
https://hal.archives-ouvertes.fr/hal-00644803
DOI : 10.1007/s00410-011-0606-7

Éditeur(s) : HAL CCSD Elsevier
Résumé : The ultramafic–mafic complexes located at the base of obducted paleo-island arcs are commonly interpreted as evidence for intra-crustal fractionation of primitive (high-Mg#) mantle melts. The present study, realized on the Jijal mafic–ultramafic basal section of the Cretaceous Kohistan oceanic arc (N Pakistan), discards a crystal fractionation model from a single parental magma to take into account the geochemical and isotope variations observed between the plutonic crust and the underlying ultramafic section. The basal ultramafic rocks, i.e. dunites, wehrlites and clinopyroxenites, show high Mg#, extremely depleted REE patterns, no marked HFSE anomalies and high LILE enrichment. Cpx and leached whole rocks from this unit yield restricted εNd values (+ 5.5 to + 6.8), a large εSr range (− 5.9 to + 8.8) and mainly radiogenic 207Pb/204Pb ratios. The overlying mafic section, i.e. gabbroic rocks, displays low Mg# (46 < Mg# < 54), enriched REE patterns and marked HFSE anomalies. These plutonic rocks have also very homogeneous Sr and Pb isotopic compositions defining a restricted domain, which does not overlap that of the ultramafic samples. Moreover, Cpx from the basal ultramafics yield an Sm–Nd isochron at 117 ± 7 Ma interpreted as dating crystallization of the ultramafic section. Together, these results indicate that the mafic rocks on one hand and the ultramafic rocks on the other hand, originate from separate sources with specific emplacement underneath the subduction zone. A lherzolite lens, collected from the top of the mafic section, plots on the early Cretaceous Sm–Nd isochron and therefore yields the same 143Nd/144Nd initial ratio. This suggests that the ultramafic part of the lower Kohistan arc complex sampled the initiation stages of the subduction with production of magmas with boninite-like features. At this stage, the mantle wedge has been already modified by percolation of the first slab-derived fluids. On such a scenario the lherzolite lens would correspond to the lithospheric mantle underneath the arc before its initiation. A multi-stage history is proposed for the evolution for the Kohistan arc through not, vert, similar 30 Ma. Stage #1 reflects the spontaneous initiation of subduction associated with extensive boninitic affinity magmatism, stages #2 and #3 are related to arc building by tholeiitic melts and, a fourth step (stage #4) corresponds to the intra-crustal differentiation.
ISSN: 0012-821X

hal-00407206
https://hal.archives-ouvertes.fr/hal-00407206
DOI : 10.1016/j.epsl.2007.06.026

Éditeur(s) : HAL CCSD AGU and the Geochemical Society
Résumé : International audience
Microbathymetry data, in situ observations, and sampling along the 13°20′N and 13°20′N oceanic core complexes (OCCs) reveal mechanisms of detachment fault denudation at the seafloor, links between tectonic extension and mass wasting, and expose the nature of corrugations, ubiquitous at OCCs. In the initial stages of detachment faulting and high-angle fault, scarps show extensive mass wasting that reduces their slope. Flexural rotation further lowers scarp slope, hinders mass wasting, resulting in morphologically complex chaotic terrain between the breakaway and the denuded corrugated surface. Extension and drag along the fault plane uplifts a wedge of hangingwall material (apron). The detachment surface emerges along a continuous moat that sheds rocks and covers it with unconsolidated rubble, while local slumping emplaces rubble ridges overlying corrugations. The detachment fault zone is a set of anostomosed slip planes, elongated in the along-extension direction. Slip planes bind fault rock bodies defining the corrugations observed in microbathymetry and sonar. Fault planes with extension-parallel stria are exposed along corrugation flanks, where the rubble cover is shed. Detachment fault rocks are primarily basalt fault breccia at 13°20′N OCC, and gabbro and peridotite at 13°30′N, demonstrating that brittle strain localization in shallow lithosphere form corrugations, regardless of lithologies in the detachment zone. Finally, faulting and volcanism dismember the 13°30′N OCC, with widespread present and past hydrothermal activity (Semenov fields), while the Irinovskoe hydrothermal field at the 13°20′N core complex suggests a magmatic source within the footwall. These results confirm the ubiquitous relationship between hydrothermal activity and oceanic detachment formation and evolution.
ISSN: 1525-2027

hal-01571973
https://hal.archives-ouvertes.fr/hal-01571973
https://hal.archives-ouvertes.fr/hal-01571973v2/document
https://hal.archives-ouvertes.fr/hal-01571973/file/Escart-n_et_al-2017-Geochemistry%2C_Geophysics%2C_Geosystems.pdf
DOI : 10.1002/2016GC006775

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The N-S oriented Raghane shear zone (8 degrees 30') delineates the western boundary of the Saharan metacraton and is, with the 4 degrees 50' shear zone, the most important shear zone in the Tuareg shield. It can be followed on 1000 km in the basement from southern Air, Niger to NE Hoggar, Algeria. Large subhorizontal movements have occurred during the Pan-African orogeny and several groups of granitoids intruded during the Neoproterozoic. We report U-Pb zircon datings (laser ICP-MS) showing that three magmatic suites of granitoids emplaced close to the Raghane shear zone at c. 790 Ma, c. 590 and c. 550 Ma. A comprehensive and detailed (158 sites, more than 1000 cores) magnetic fabric study was performed on 8 plutons belonging to the three magmatic suites and distributed on 200 km along the Raghane shear zone. The main minerals in all the target plutons do not show visible preferential magmatic orientation except in narrow shear zones. The AMS study shows that all plutons have a magnetic lineation and foliation compatible with the deformed zones that are zones deformed lately in post-solidus conditions. These structures are related to the nearby mega-shear zones, the Raghane shear zone for most of them. The old c. 793 Ma Touffok granite preserved locally its original structures. The magnetic structures of the c. 593 Ma Ohergehem pluton, intruded in the Aouzegueur terrane, are related to thrust structures generated by the Raghane shear zone while it is not the case of the contemporaneous plutons in the Assode-Issalane terrane whose structures are only related to the subvertical shear zones. Finally, the c. 550 Ma granite group has magnetic structure related to the N-S oriented Raghane shear zone and its associated NNE-SSW structures when close to them, but NW-SE oriented when further. These NW-SE oriented structures appear to be characteristic of the late Neoproterozoic evolution of the Saharan metacraton and are in relation to the convergence with the Murzuq craton. This evolution reflects the rheological contrast existing along the Raghane shear zone marking the western boundary of the Saharan metacraton.
ISSN: 0040-1951

hal-00429354
https://hal.archives-ouvertes.fr/hal-00429354
DOI : 10.1016/j.tecto.2009.04.022

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Mid-ocean ridge basalt (MORB) is the most abundant magma on Earth, and provides a geochemical window into the mantle. Deriving mantle composition and melting processes from the erupted lavas requires correction to be made for their evolution as they pass through and generate the oceanic crust. This is typically done by assuming that modification of melts in crustal magma chambers occurs exclusively by fractional crystallisation. However, extensive mineral major- and trace element data from a full section of fast-spread lower crustal rocks exposed in Hess Deep (equatorial Pacific Ocean) demonstrate that their evolution is instead controlled by reactive porous flow. These reactions lead to a strong enrichment in, and fractionation of, incompatible trace elements in the melt (as recorded by clinopyroxene compositions), leading to melt compositions far outside of the compositional realm of MORB both in terms of trace element abundances and ratios. The reactive signature increases in strength up section, peaking in varitextured gabbros interpreted to represent the fossilised axial melt lens, indicating that reactive porous flow occurred on the scale of the entire lower crust. The enrichment of the melt is coupled with a strong trace element depletion of plagioclase, olivine, and, to a lesser extent, clinopyroxene cores, suggesting that these phases represent the residues of the reactions from which trace elements have been removed. The dominant role of reactive porous flow, and the resulting deviations from fractional crystallisation predictions, suggest that the lower oceanic crust plays a much more complex and significant role in modifying the compositions of MORB than previously expected, with consequent implications for models of mantle processes.
ISSN: 0012-821X

hal-00814075
https://hal.archives-ouvertes.fr/hal-00814075
DOI : 10.1016/j.epsl.2012.11.012

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
IODP Hole U1309D (Atlantis Massif, Mid-Atlantic Ridge 30 degrees N) is the second deepest hole drilled into slow spread gabbroic lithosphere. It comprises 5.4% of olivine-rich troctolites (->70% olivine), possibly the most primitive gabbroic rocks ever drilled at mid-ocean ridges. We present the result of an in situ trace element study carried out on a series of olivine-rich troctolites, and neighbouring troctolites and gabbros, from olivine-rich intervals in Hole U1309D. Olivine-rich troctolites display poilkilitic textures; coarse-grained subhedral to medium-grained rounded olivine crystals are included into large undeformed clinopyroxene and plagioclase poikiloblasts. In contrast, gabbros and troctolites have irregularly seriate textures, with highly variable grain sizes, and locally poikilitic clinopyroxene oikocrysts in troctolites. Clinopyroxene is high Mg# augite (Mg# 87 in olivine-rich troctolites to 82 in gabbros), and plagioclase has anorthite contents ranging from 77 in olivine-rich troctolites to 68 in gabbros. Olivine has high forsterite contents (82-88 in olivine-rich troctolites, to 78-83 in gabbros) and is in Mg-Fe equilibrium with clinopyroxene. Clinopyroxene cores and plagioclase are depleted in trace elements (e.g., Yb-cpx similar to 5-11 x Chondrite), they are in equilibrium with the same MORB-type melt in all studied rock-types. These compositions are not consistent with the progressively more trace element enriched (evolved) compositions expected from olivine rich primitive products to gabbros in a MORB cumulate sequence. They indicate that clinopyroxene and plagioclase crystallized concurrently, after melts having the same trace element composition, consistent with crystallization in an open system with a buffered magma composition. The slight trace element enrichments and lower Cr contents observed in clinopyroxene rims and interstitial grains results from crystallization of late-stage differentiated melts, probably indicating the closure of the magmatic system. In contrast to clinopyroxene and plagioclase, olivine is not in equilibrium with MORB, but with a highly fractionated depleted melt, similar to that in equilibrium with refractory oceanic peridotites, thus possibly indicating a mantle origin. In addition, textural relationships suggest that olivine was in part assimilated by the basaltic melts after which clinopyroxene and plagioclase crystallized (impregnation). These observations suggest a complex crystallization history in an open system involving impregnation by MORB-type melt(s) of an olivine-rich rock or mush. The documented magmatic processes suggest that olivine-rich troctolites were formed in a zone with large magmatic transfer and accumulation, similar to the mantle-crust transition zone documented in ophiolites and at fast spreading ridges.
ISSN: 0009-2541

hal-00420916
https://hal.archives-ouvertes.fr/hal-00420916
DOI : 10.1016/j.chemgeo.2009.02.013

Éditeur(s) : HAL CCSD Springer
Résumé : International audience
We present here a synthesis of the evolution of rifted continental margin systems in the Gulf of Aden. These margins are volcanic to the west of the Gulf of Aden, where they are influenced by the Afar hotspot, and non-volcanic east of longitude 46° E. The combined use of magnetics, gravity, seismic reflection, field observations (tectonic, stratigraphic and sedimentological) and oil well data allowed us to obtain better constraints on the timing of continental rifting and seafloor spreading. From the Permo-Triassic to the Oligocene, the Arabian-African plate was subject to distributed extension, probably due, at least from the Cretaceous, to tensile stresses related to the subduction of the Tethysian slab in the north. In Late Eocene-Early Oligocene, 34-33 Ma ago, rifting started to localise along the future area of continental breakup. Initially guided by the inherited basins, continental rifting then occurred synchronously over the entire gulf before becoming localised on the northern and southern borders of the inherited grabens, in the direction of the Afar hotspot. In the areas with non-volcanic margins (in the east), the faults marking the end of rifting trend parallel to the inherited grabens. Only the transfer faults cross-cut the inherited grabens, and some of these faults later developed into transform faults. The most important of these transform faults follow a Precambrian trend. Volcanic margins were formed in the west of the Gulf, up to the Guban graben in the southeast and as far as the southern boundary of the Bahlaf graben in the northeast. Seaward dipping reflectors can be observed on many oil industry seismic profiles. The influence of the hotspot during rifting was concentrated on the western part of the gulf. Therefore, it seems that the western domain was uplifted and eroded at the onset of rifting, while the eastern domain was characterised by more continuous sedimentation. The phase of distributed deformation was followed by a phase of strain localisation during the final rifting stage, just before formation of the Ocean-Continent Transition (OCT), in the most distal graben (DIM graben). About 20 Ma ago, at the time of the continental break-up, the emplacement of the OCT started in the east with exhumation of the subcontinental mantle. Farther west, the system was heated up by the strong influence of the Afar hotspot, which led to breakup with much less extension. In the Gulf of Aden (s.str), up to the Shukra El Sheik fracture zone, oceanic spreading started 17.6 Ma ago. West of this fracture zone, oceanic accretion started 10 Ma ago, and 2 Ma ago in the Gulf of Tadjoura. Post-rift deformation of the eastern margins of the Gulf of Aden can be seen in the distal and proximal domains. Indeed, the substantial post-rift uplift of these margins could be associated with either the continental break-up, or activity of the Afar hotspot and related volcanic/magmatic activity. Uplift of the northern proximal margin was still active (e.g. stepped beach rocks exposed at 60 m of 2 Ma; 30 m of 35,200 years; 10 and 2 m) and active volcanoes can be inferred at depths of between 70 and 200 km beneath the margin (at 5-10 km distance from the coast). On the distal margin, heat flow measurements show a high value that is associated with post-rift volcanic activity and the development of a volcano (with flows and sills) shortly after the formation of the OCT. The Afar hotspot is therefore important for several reasons. It allows the localisation of deformation along the Red Sea/Aden system and the rapid opening of the Gulf after the continental break-up; its influence also seems to persist during the post-rift period.
ISSN: 1866-7411

hal-01053089
https://hal.archives-ouvertes.fr/hal-01053089
DOI : 10.1007/s12517-011-0475-4

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The platinum-group element (PGE) systematics of continental mantle peridotites show large variability, reflecting petrogenetic processing of the upper mantle during partial melting and melt/fluid percolation inside the lithosphere. By removing Pd-Cu-Ni rich sulfides, partial melting events that have stabilized the sub-continental mantle lithosphere fractionated PPGEs (Palladium-group PGE; Pt, Pd) relative to IPGEs (Iridium-group PGE; Os, Ir, Ru, Rh). Residual base-metal sulfides (BMS) survive as enclosed IPGE-enriched Monosulfide Solid Solutions (Mss), which otherwise decompose into Ru-Os-Ir-rich refractory platinum-group minerals (PGMs) once the partial melts become S-undersaturated. The small-scale heterogeneous distribution of these microphases may cause extreme nugget effects, as seen in the huge variations in absolute PGE concentrations documented in cratonic peridotites. Magmas fluxing through the lithospheric mantle may change the initial PGE budgets inherited from the melting events, resulting in the great diversity of PGE systematics seen in peridotites from the sub-continental lithosphere. For instance, melt-rock reactions at increasing melt/rock ratios operate as open-system melting processes removing residual BMS/PGMs. Highly percolated peridotites are characterized by extreme PGE depletion, coupled with PGE patterns and Os-isotope compositions that gradually evolve toward that of the percolating melt. Reactions at decreasing melt-rock ratios (usually referred to as "mantle metasomatism") precipitate PPGE-enriched BMS that yield suprachondritic Pd/Ir and occasionally affect Pt/Ir and Rh/Ir ratios as well. Moreover, volatile-rich, small volume melts fractionate Os relative to Ir and S relative to Se, thereby producing rocks with supra-chondritic Os/Ir and S/Se coupled with supra-chondritic Pd/Ir and Pt/Ir. Major magmatic inputs at the lithosphere-asthenosphere boundary may rejuvenate the PGE systematics of the depleted mantle. Integrated studies of "refertilized" peridotites with worldwide provenance provide evidence for mixing between old PGM-rich harzburgitic protoliths and newly-precipitated BMS. Long-lived PGMs carry the Os-isotope compositions of ancient melt‐depletion events into seemingly undepleted fertile lherzolites. Another diagnostic feature of major refertilization processes is the increasing modal abundance of Pt-Pd-Te-Bi or Pt-As-S microphases. Due to regional-scale refertilization processes, sizeable (> 100 km) domains of the upper lithospheric mantle are now significantly enriched in Pd, Au, Cu, Se, and other incompatible chalcophile elements that are of considerable importance in PGE-ore forming events.
ISSN: 0024-4937

hal-00828626
https://hal.archives-ouvertes.fr/hal-00828626
DOI : 10.1016/j.lithos.2012.08.017

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Chenaillet Ophiolite in the Franco-Italian Alps represents a well-exposed ocean-floor sequence that was only weakly overprinted by Alpine metamorphism during its emplacement in the Alpine nappe stack. Pillow lavas showing a Mid Ocean Ridge Basalt (MORB) signature overlie tectonically exhumed gabbros and serpentinized mantle rocks similar to oceanic core complexes (OCC) described from present-day slow- to ultraslow-spreading ridges. Based on detailed mapping it can be shown that: 1) syn-magmatic high-temperature shear zones are truncated by oceanic detachment faults; 2) sediments consisting exclusively of clasts derived from the footwall of the detachment are overlain by voluminous lavas, and 3) emplacement of lavas is linked with high-angle faulting that overprint the oceanic detachment fault. Based on stratigraphic and cross cutting relationships we conclude that: 1) a complex relation between high- and low-temperature shear zones exists, 2) oceanic detachment faults may be obliterated by later emplaced of MOR basalts, and 3) high-angle faults may serve at shallow levels as feeder channels for the overlying pillow basalts. These observations raise questions about the relative relations in time and space between magmatic, hydrothermal and tectonic processes at spreading systems. We propose that the observed change from exhumation along an oceanic detachment fault to high-angle faulting associated with extrusion of volcanic rocks may represent an evolution within a life cycle of a spreading system that may be comparable to present-day slow- to ultraslow-spreading ridges.
ISSN: 0024-4937

hal-00617678
https://hal.archives-ouvertes.fr/hal-00617678
DOI : 10.1016/j.lithos.2010.10.017

Éditeur(s) : Elsevier Science Bv
Résumé : In the South Gabon Basin, deep multi-channel seismic reflection and gravity modeling analysis have shed light on key features of the structure of the margin. The thinned continental crust beneath the Gabon Margin appears to be composed of two distinct layers, separated by a clear, strong and more or less continuous reflector running in the 7–10 s TWT window. The lower crust is characterized by a higher density, intermediate between the lower values of the upper crust and the denser values of the mantle. The lower crust is irregularly shaped and presents lateral thickness variations along the direction of thinning and along the coast. In the offshore thinned continental domain, the lower and upper crust form a 20–25 km thick body. Crustal thicknesses point to a relatively sharp and narrow transition, along a few tens of kilometers, between the unthinned and the thinned continental crust. The high density layer identified offshore Gabon presents similar characteristics in density, geometry and spatial distribution, as the underplated magmatic bodies observed along volcanic margins, e.g. along the South Atlantic Namibia Margin or the North Atlantic Vøring Margin. Although this lower crustal body could possibly represent ultra mafic serpentinized rocks or high grade metamorphic crustal rocks, we suggest that it could be composed of mafic rocks. Magmas resulting from partial melting during rifting may underplate the crust and/or be intruded in the lower crust through a system of dykes and sills. In this view, the present-day crustal thicknesses along rifted margins, characterized by magmatic underplating and/or intrusion, are not representative of the thinning that the crust experienced during rifting. Results of this study point to relatively shallow sedimentary basins along the South Gabon Margin. The deepest offshore depocenters located under the westernmost side of the continental platform appear to be associated with the deepest syn-rift basins These basins seem to extend along 20 to 40 km in the ~ NE–SW direction with a present-day average thickness of 7.3 km. Offshore Gabon, whereas the crustal thinning appears significant, the syn-rift deposit are not thick. We suggest that the area was anomalously uplifted during the rifting phase, due to an elevated thermal lithospheric gradient. The conclusions derived from our seismic and gravity analysis are consistent with the implications such a thermal anomaly would have on the tectonic evolution of a rifted margin with 1) an underplated high density lower crustal layer, 2) shallow depth syn-rift basins associated with a relatively thin crust and subsequently 3) elevated recorded subsidence rates in the initial post-rift stages. Research Highlights ► The Gabon Margin appears characterized by an underplated high density lower crustal layer. ► Shallow depth syn-rift basins are associated with a relatively thin crust. ► Seismic and gravity analysis points to an anomalous uplift of the Gabon Margin during the rifting phase. ► Crustal structure, syn-rift infill and post-rift subsidence are consistent an uplift of the Gabon Margin during the rifting phase. ► The uplift of the Gabon Margin is possibly due to an elevated thermal lithospheric gradient.
Tectonophysics (0040-1951) (Elsevier Science Bv), 2011-06 , Vol. 506 , N. 1-4 , P. 31-45

Droits : 2011 Elsevier B.V. All rights reserved.
http://archimer.ifremer.fr/doc/00039/15020/12347.pdf
DOI:10.1016/j.tecto.2011.04.009
http://archimer.ifremer.fr/doc/00039/15020/

Éditeur(s) : HAL CCSD AGU and the Geochemical Society
Résumé : International audience
Continental rifts and passive continental margins show fundamental along-axis segmentation patterns that have been attributed to one or a number of different processes: extensional fault geometry, variable stretching along strike, preexisting lithospheric compositional and structural heterogeneities, oblique rifting, and the presence or absence of eruptive volcanic centers. The length and width scales of the rift stage fault-bounded basin systems change during the late evolution of the new plate boundary, and the role of magmatism may increase as rifting progresses to continental rupture. Along obliquely spreading ridges, first-order mid-ocean ridge geometries originate during the synrift stage, indicating an intimate relationship between magma production and transform fault spacing and location. The Gulf of Aden rift is a young ocean basin in which the earliest synrift to breakup structures are well exposed onshore and covered by thin sediment layers offshore. This obliquely spreading rift is considered magma-poor and has several large-offset transforms that originated during late stage rifting and control the first-order axial segmentation of the spreading ridge. Widely spaced geophysical transects of passive margins that produce only isolated 2-D images of crust and uppermost mantle structure are inadequate for evaluation of competing rift evolution models. Using closely spaced new geophysical and geological observations from the Gulf of Aden we show that rift sectors between transforms have a large internal variability over short distances (∼10 km): the ocean-continent transition (OCT) evolves from a narrow magmatic transition to wider zones where continental mantle is probably exhumed. We suggest that this small-scale variability may be explained (1) by the distribution of volcanism and (2) by the along-strike differences in time-averaged extension rate of the oblique rift system. The volcanism may be associated with (1) the long-offset Alula-Fartak Fracture Zone, which may enhance magma production on its younger side, or (2) channeled flow from the Afar plume material along the newly formed OCT and the spreading ridge. Oblique extension and/or hot spot interactions may thereby have a significant control on the styles of rifting and continental breakup and on the evolution of many magma-poor margins.
ISSN: 1525-2027

hal-00504866
https://hal.archives-ouvertes.fr/hal-00504866
https://hal.archives-ouvertes.fr/hal-00504866/document
https://hal.archives-ouvertes.fr/hal-00504866/file/G3-Leroy_al-2010.pdf
DOI : 10.1029/2009GC002963

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In pre-drift reconstructions, the central and southern parts of the Borborema Province, northeastern Brazil, belong to a large Brasiliano-Pan-African orogenic realm situated to the north of the São Francisco-Congo Craton. In order to better understand the timing and geodynamic setting under which this orogenic system developed, a structural, geochemical and geochronological study was conducted across the east Pernambuco shear zone (EPSZ) system, which separates the Pernambuco-Alagoas Domain (PEAL) from the Central Domain. A sample of the Pinhões orthogneiss (GE-1), in the Central Domain, one sample of a syenitic orthogneiss (CA-34) wrapped by the EPSZ, and one sample of orthogneiss named Altinho (CA-40), in the northern portion of the PEAL, were dated by LA-ICP-MS. The Pinhões orthogneiss yielded an age of 869 ± 9 Ma, interpreted as the emplacement age of the protolith during a late Tonian magmatic episode. Samples CA-40 and CA-34 yielded 206Pb/238U weighted mean ages of 652 ± 6 Ma and 636 ± 3 Ma, respectively, which are interpreted as dating emplacement and crystallization of the magmatic protoliths. However, it is also possible that these rocks were formed during the same magmatic event in view of the identical ages of 646 ± 13 Ma and 646 ± 11 Ma, respectively, given by the less precise upper intercept of the discordia lines. The metaluminous and magnesian nature of the Altinho orthogneiss is akin to the calc-alkalic suite. However, some samples plot in the intraplate field in tectonic discrimination diagrams and the Nd TDM model age of 1.36 Ga is unlike that of juvenile magmas in convergent settings. The Altinho orthogneiss is quite similar in terms of trace elements geochemistry to the syenitic orthogneiss, which has a clearer intraplate affinity, and the dated samples have identical initial Sr isotope ratios (0.7047). Therefore, emplacement in an extensional setting is preferred over a convergent one. Two samples of paragneisses (SB-1 and BB-9) from the PEAL were also dated. The ages of the youngest zircon grains in sample BB-9 (655–642 Ma) overlap the crystallization age of the Altinho orthogneiss, implying that sedimentation is younger than or, at best, synchronous with magmatism. The age of low Th/U grains in samples CA-34 (615 ± 8 Ma) and SB-1 (587 ± 12 Ma) are related to a subsequent metamorphic overprint, which is loosely constrained between 580 and 620 Ma. These observations, combined with evidence provided by previous studies, suggest that the change from an extensional to a contracional setting occurred at ca. 640–630 Ma. In contrast with most collisional orogens, where a long period of oceanic subduction precedes collision, the inferred tectonic evolution suggests that the Brasiliano Orogeny resulted from inversion of continental and/or proto oceanic rifts.
ISSN: 0895-9811

hal-01174182
https://hal.archives-ouvertes.fr/hal-01174182
DOI : 10.1016/j.jsames.2014.06.004