Éditeur(s) : Pergamon-elsevier Science Ltd
Résumé : We report rare earth element (REE) and neodymium (Nd) isotope data for the organic fraction of sediments collected from various depositional environments, i.e. rivers (n=25), estuaries (n=18), open-ocean settings (n=15), and cold seeps (n=12). Sedimentary Organic Matter (SOM) was extracted using a mixed hydrogen peroxide/nitric acid solution (20%-H2O2 – 0.02M-HNO3), after removal of carbonate and oxy-hydroxide phases with dilute hydrochloric acid (0.25M-HCl). A series of experimental tests indicate that extraction of sedimentary organic compounds using H202 may be complicated occasionally by partial dissolution of sulphide minerals and residual carbonates. However, this contamination is expected to be minor for REE because measured concentrations in H2O2 leachates are about two-orders of magnitude higher than in the above mentioned phases. The mean REE concentrations determined in the H2O2 leachates for samples from rivers, estuaries, coastal seas and open-ocean settings yield relatively similar levels, with ΣREE = 109 ± 86 ppm (mean ± s; n=58). The organic fractions leached from cold seep sediments display even higher concentration levels (285 ± 150 ppm; mean ± s; n=12). The H2O2 leachates for most sediments exhibit remarkably similar shale-normalized REE patterns, all characterized by a mid-REE enrichment compared to the other REE. This suggests that the distribution of REE in leached sedimentary organic phases is controlled primarily by biogeochemical processes, rather than by the composition of the source from which they derive (e.g. pore, river or sea- water). The Nd isotopic compositions for organic phases leached from river sediments are very similar to those for the corresponding detrital fractions. In contrast, the SOM extracted from marine sediments display εNd values that typically range between the εNd signatures for terrestrial organic matter (inferred from the analysis of the sedimentary detrital fractions) and marine organic matter (inferred from the analysis of local surface seawater). A notable exception is the case of organic matter (OM) fractions leached from cold seep sediment samples, which sometimes exhibit εNd values markedly different from both terrigenous and surface seawater signatures. This suggests that a significant fraction of organic compounds in these sediments may be derived from chemosynthetic processes, recycling pore water REE characterized by a distinct isotopic composition. Overall, our results confirm that organic matter probably plays an important role in the oceanic REE budget, through direct scavenging and remineralization within the water column. Both the high REE abundances and the shape of shale-normalized patterns for leached SOM also suggest that OM degradation in sub-surface marine sediments during early diagenesis could control, to a large extent, the distribution of REE in pore waters. Benthic fluxes of organic-bound REE could hence substantially contribute to the exchange processes between particulates and seawater that take place at ocean margins. Neodymium isotopes could provide useful information for tracing the origin (terrestrial versus marine) and geographical provenance of organic matter, with potential applications in paleoceanography. In particular, future studies should further investigate the potential of Nd isotopes in organic compounds preserved in sedimentary records for reconstructing past variations of surface ocean circulation.
Geochimica Et Cosmochimica Acta (0016-7037) (Pergamon-elsevier Science Ltd), 2014-09 , Vol. 140 , P. 177-198

Droits : 2014 Elsevier Ltd. All rights reserved.
http://archimer.ifremer.fr/doc/00191/30250/28682.pdf
DOI:10.1016/j.gca.2014.05.016
http://archimer.ifremer.fr/doc/00191/30250/

Éditeur(s) : HAL CCSD Cambridge University Press (CUP)
Résumé : International audience
Upper Triassic volcanic and sedimentary rocks of the Mamonia Complex in southwestern Cyprus are exposed in erosional windows through the post-Cretaceous cover, where the Mamonia Complex is tectonically imbricated with the Troodos and Akamas ophiolitic suites. Most of these Upper Triassic volcanic rocks have been considered to represent remnants of Triassic oceanic crust and its associated seamounts. New Nd and Pb isotopic data show that the whole Mamonia volcanic suite exhibits features of oceanic island basalts (OIB). Four rock types have been distinguished on the basis of the petrology and chemistry of the rocks. Volcanism began with the eruption of depleted olivine tholeiites (Type 1) and oceanic island tholeiites (Type 2) associated with deep basin siliceous and/or calcareous sediments. The tholeiites were followed by highly phyric alkali basalts (Type 3) interbedded with pelagic Halobia-bearing limestones or white reefal limestones. Strongly LREE-enriched trachytes (Type 4) were emplaced during the final stage of volcanic activity. Nd and Pb isotopic ratios suggest that tholeiites and mildly alkali basalts derived from partial melting of heterogeneous enriched mantle sources. Fractional crystallization alone cannot account for the derivation of trachytes from alkaline basalts. The trachytes could have been derived from the partial melting at depth of mafic material which shares with the alkali basalts similar trace element and isotopic compositions. This is corroborated by the rather similar isotopic compositions of the alkali basalts and trachytes. The correlations observed between incompatible elements (Nb, Th) and {varepsilon}Nd and Pb isotopic initial ratios suggest that the Mamonia suite was derived from the mixing of a depleted mantle (DMM) and an enriched component of High µ (µ = 238U/204Pb, HIMU) type. Models using both Nd and Pb isotopic initial ratios suggest that the depleted tholeiites (Type 1) derived from a DMM source contaminated by an Enriched Mantle Type 2 component (EM2), and that the oceanic tholeiites (Type 2), alkali basalts (Type 3) and trachytes (Type 4) were derived from the mixing of the enriched mantle source of the depleted tholeiites with a HIMU component. None of the Mamonia volcanic rocks show evidence of crustal contamination. The Upper Triassic within-plate volcanism likely erupted in a small southerly Neotethyan basin, located north of the Eratosthenes seamount and likely floored by oceanic crust.
ISSN: 0016-7568

insu-00353657
https://hal-insu.archives-ouvertes.fr/insu-00353657
DOI : 10.1017/S0016756806002937

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We present new Sr-Nd-Pb isotope data of the western Alpujárride metamorphic basement and the pre-Miocene Flysch sediments of the Betic Cordillera (southern Spain). Nd model ages are consistent with an increasing detrital input from the Alborán domain to the Flysch Trough in the western Mediterranean during the late Oligocene. The Alpujárride metamorphic crustal rocks derived from Archean-Paleoproterozoic terranes located along the northern margin of Gondwana in the Neoproterozoic. The heterogeneous isotopic signatures of the Alpujárride units indicate that they have different sedimentary protoliths and underwent contrasted Variscan and pre-Variscan tectono-magmatic evolutions. Melts/fluids derived from the western Alpujárride gneisses contaminated the mantle source of the Ronda high-Mg pyroxenite dykes, implying that the Alpujárride lower crust underthrusted the subcontinental lithospheric mantle of the Alborán domain generating subduction-like magmatism in the late Oligocene. The western Alpujárride upper crust is involved in the Neogene volcanism of the Alborán Sea basin, but only contaminated some LREE-enriched calc-alkaline lavas erupted along the continental margins. On the other hand, tholeiitic lavas in the center of the basin show no isotopic evidence of crustal assimilation. This indicates that most of the crust in the central Alborán Sea accreted by Miocene tholeiitic magmatism and that Alpujárride lower crust is absent and likely foundered close to the continental margins of the basin.
ISSN: 0024-4937

hal-01526912
https://hal.archives-ouvertes.fr/hal-01526912
DOI : 10.1016/j.lithos.2016.10.003

Éditeur(s) : Elsevier
Résumé : The combined use of Lu-Hf and Sm-Nd isotope systems potentially offers a unique perspective for investigating continental erosion, but little is known about whether, and to what extent, the Hf-Nd isotope composition of sediments is related to silicate weathering intensity. In this study, Hf and Nd elemental and isotope data are reported for marine muds, leached Fe-oxide fractions and zircon-rich turbidite sands collected off the Congo River mouth, and from other parts of the SE Atlantic Ocean. All studied samples from the Congo fan (muds, Fe-hydroxides, sands) exhibit indistinguishable Nd isotopic composition (epsilon(Nd)similar to - 16), indicating that Fe-hydroxides leached from these sediments correspond to continental oxides precipitated within the Congo basin. In marked contrast, Hf isotope compositions for the same samples exhibit significant variations. Leached Fe-hydroxide fractions are characterized by epsilon(Hf) values (from -1.1 to +13) far more radiogenic than associated sediments (from -7.1 to -12.0) and turbidite sands (from -27.2 to -31.6). epsilon(Hf) values for Congo fan sediments correlate very well with Al/K (i.e. a well-known index for the intensity of chemical weathering in Central Africa). Taken together, these results indicate that (1) silicate weathering on continents leads to erosion products having very distinctive Hf isotope signatures, and (2) a direct relationship exists between epsilon(Hf) of secondary clay minerals and chemical weathering intensity. These results combined with data from the literature have global implications for understanding the Hf-Nd isotope variability in marine precipitates and sediments. Leached Fe-hydroxides from Congo fan sediments plot remarkably well on an extension of the 'seawater array' (i.e. the correlation defined by deep-sea Fe-Mn precipitates), providing additional support to the suggestion that the ocean Hf budget is dominated by continental inputs. Fine-grained sediments define a diffuse trend, between that for igneous rocks and the,seawater array', which we refer to as the 'zircon-free sediment array' (epsilon(Hf)=0-91 epsilon(Nd)+3.10). Finally, we show that the Hf-Nd arrays for seawater, unweathered igneous rocks, zircon-free and zircon-bearing sediments (epsilon(Hf)= 1.80 epsilon(Nd)+2.35) can all be reconciled, using Monte Carlo simulations, with a simple weathering model of the continental crust. (C) 2008 Elsevier B.V. All rights reserved.
Earth and Planetary Science Letters (0012-821X) (Elsevier), 2009 , Vol. 277 , N. 3-4 , P. 318-326

Droits : 2009 Elsevier B.V. All rights reserved.
http://archimer.ifremer.fr/doc/2009/publication-6451.pdf
DOI:10.1016/j.epsl.2008.10.028
http://archimer.ifremer.fr/doc/00000/6451/

Éditeur(s) : HAL CCSD Société géologique de France
Résumé : National audience
The late Lower to Middle Permian Panjal Traps (NW Himalaya, India-Pakistan) represent the greatest magmatic province erupted on the northern Indian platform during the Neotethys opening. New geochemical and isotopic analyses were performed on basalts from the eastern borders of the traps (SE Zanskar-NW Spiti area) in order to characterize this volcanism, to discuss its compositional variations in comparison to Panjal counterparts and its relationships with the opening of Neotethys. Lavas show features of tholeiitic low-Ti (< 1.6%) continental flood basalts with LREE, Th enrichments and Nb-Ta negative anomalies. Trace element ratios combined with {varepsilon}Ndi values (–3.6 to +0.9) and high Pb isotopic ratios suggest that these tholeiitic basalts were derived from an OIB-like mantle contaminated at various degrees by a continental crust component. Previous geochemical features are broadly similar to those of the coeval Panjal volcanic sequences identified westwards (Ladakh, Kashmir and Pakistan). Present geochemical constraints obtained for the Panjal Traps basalts suggest they originated from rapid effusion of tholeiitic melts during opening of the Neotethys Ocean. Similar magmatism implying an OIB-type reservoir is contemporaneously recognized on and along the adjacent Arabian platform. Both Indian and Arabian Permian volcanics were emplaced during coeval syn-rift to post rift transition. These Lower to Middle Permian south Neotethyan continental flood magmatism are regarded as associated to a passive rifting. In this scheme, OIB-type isotopic signature would be related either to a melting episode of syn-rift up-welling mantle plumes or to a melting of a regional abnormally hot and enriched mantle.
EISSN: 1777-5817

insu-00338862
https://hal-insu.archives-ouvertes.fr/insu-00338862
DOI : 10.2113/gssgfbull.179.4.383

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The New Caledonia ophiolite (Peridotite Nappe) is dominated by mantle lithologies, composed of forearc-related refractory harzburgites and minor lherzolites in both the spinel and plagioclase facies.In this study, a comprehensive geochemical data set (major, trace elements and Sr–Nd isotopes) is used to constrain the mantle evolution of the lherzolites and their relationships with the basalts from the Poya Terrane, which tectonically underlies the mantle rocks. The majority of the lherzolites are low-strain porphyroclastic tectonites. They likely record an asthenospheric origin followed by re-equilibration at lithospheric conditions, as supported by geothermometric estimates (T = 1100–940 °C and 920–890 °C for porphyroclastic and neoblastic spinel-facies assemblages, respectively). Olivine composition (Fo = 88.5–90.0 mol%), spinel Cr# ([molar 100 • Cr/(Cr + Al)] = 13–17) and relatively high amounts (7–8 vol%) of Al2O3- and Na2O-rich clinopyroxene (up to 0.5 and 6.5 wt.%, respectively) indicate a moderately depleted geochemical signature for the spinel lherzolites. Bulk rock and clinopyroxene rare earth elements (REE) patterns display a typical abyssal-type signature, i.e. steeply plunging LREE accompanied by nearly flat HREE to MREE. Clinopyroxene REE compositions of the spinel lherzolites may be reproduced by small amounts of fractional melting of a garnet lherzolite precursor (~ 4%), followed by 4%–5% melting in the spinel peridotite field. The plagioclase lherzolites show melt impregnation microstructures, Cr- and Ti-rich spinels and incompatible trace element enrichments (REE, Ti, Y, and Zr) in bulk rocks and clinopyroxenes. Impregnation modelling for these elements suggests that the plagioclase lherzolites originated from residual spinel lherzolites by entrapment of highly depleted (non-aggregated) MORB melt fractions in the shallow oceanic lithosphere. Nd isotope compositions of the investigated peridotites are consistent with derivation from an asthenospheric mantle source that experienced a recent MORB-producing depletion event. This evolution was most likely accomplished in a spreading ridge. However, geochemical trace element modelling and Nd isotopes do not support a genetic mantle–crust link between the lherzolites and enriched-MOR-type basalts from the Poya Terrane.
ISSN: 0024-4937

hal-01412440
https://hal.archives-ouvertes.fr/hal-01412440
DOI : 10.1016/j.lithos.2016.04.030

Éditeur(s) : HAL CCSD Annual Reviews
Résumé : International audience
The record of the continental lithosphere is patchy and incomplete; no known rock is older than 4.02 Ga, and less than 5% of the rocks preserved are older than 3 Ga. In addition, there is no recognizable mantle lithosphere from before 3 Ga. We infer that there was lithosphere before 3 Ga and that ∼3 Ga marks the stabilization of blocks of continental lithosphere that have since survived. This was linked to plate tectonics emerging as the dominant tectonic regime in response to thermal cooling, the development of a more rigid lithosphere, and the recycling of water, which may in turn have facilitated plate tectonics. A number of models, using different approaches, suggest that at 3 Ga the volume of continental crust was ∼70% of its present-day volume and that this may be a minimum value. The continental crust before 3 Ga was on average more mafic than that generated subsequently, and this pre-3 Ga mafic new crust had fractionated Lu/Hf and Sm/Nd ratios as inferred for the sources of tonalite-trondhjemite-granodiorite and later granites. The more intermediate composition of new crust generated since 3 Ga is indicated by its higher Rb/Sr ratios. This change in composition was associated with an increase in crustal thickness, which resulted in more emergent crust available for weathering and erosion. This in turn led to an increase in the Sr isotope ratios of seawater and in the drawdown of CO2. Since 3 Ga, the preserved record of the continental crust is marked by global cycles of peaks and troughs of U-Pb crystallization ages, with the peaks of ages appearing to match periods of supercontinent assembly. There is increasing evidence that the peaks of ages represent enhanced preservation of magmatic rocks in periods leading up to and including continental collision in the assembly of supercontinents. These are times of increased crustal growth because more of the crust that is generated is retained within the crust. The rates of generation of continental crust and mantle lithosphere may have remained relatively constant at least since 3 Ga, yet the rates of destruction of continental crust have changed with time. Only relatively small volumes of rock are preserved from before 3 Ga, and so it remains difficult to establish which of these are representative of global processes and the extent to which the rock record before 3 Ga is distorted by particular biases.
ISSN: 0084-6597

hal-01622692
https://hal.archives-ouvertes.fr/hal-01622692
DOI : 10.1146/annurev-earth-063016-020525

Éditeur(s) : HAL CCSD Elsevier
Résumé : The ultramafic–mafic complexes located at the base of obducted paleo-island arcs are commonly interpreted as evidence for intra-crustal fractionation of primitive (high-Mg#) mantle melts. The present study, realized on the Jijal mafic–ultramafic basal section of the Cretaceous Kohistan oceanic arc (N Pakistan), discards a crystal fractionation model from a single parental magma to take into account the geochemical and isotope variations observed between the plutonic crust and the underlying ultramafic section. The basal ultramafic rocks, i.e. dunites, wehrlites and clinopyroxenites, show high Mg#, extremely depleted REE patterns, no marked HFSE anomalies and high LILE enrichment. Cpx and leached whole rocks from this unit yield restricted εNd values (+ 5.5 to + 6.8), a large εSr range (− 5.9 to + 8.8) and mainly radiogenic 207Pb/204Pb ratios. The overlying mafic section, i.e. gabbroic rocks, displays low Mg# (46 < Mg# < 54), enriched REE patterns and marked HFSE anomalies. These plutonic rocks have also very homogeneous Sr and Pb isotopic compositions defining a restricted domain, which does not overlap that of the ultramafic samples. Moreover, Cpx from the basal ultramafics yield an Sm–Nd isochron at 117 ± 7 Ma interpreted as dating crystallization of the ultramafic section. Together, these results indicate that the mafic rocks on one hand and the ultramafic rocks on the other hand, originate from separate sources with specific emplacement underneath the subduction zone. A lherzolite lens, collected from the top of the mafic section, plots on the early Cretaceous Sm–Nd isochron and therefore yields the same 143Nd/144Nd initial ratio. This suggests that the ultramafic part of the lower Kohistan arc complex sampled the initiation stages of the subduction with production of magmas with boninite-like features. At this stage, the mantle wedge has been already modified by percolation of the first slab-derived fluids. On such a scenario the lherzolite lens would correspond to the lithospheric mantle underneath the arc before its initiation. A multi-stage history is proposed for the evolution for the Kohistan arc through not, vert, similar 30 Ma. Stage #1 reflects the spontaneous initiation of subduction associated with extensive boninitic affinity magmatism, stages #2 and #3 are related to arc building by tholeiitic melts and, a fourth step (stage #4) corresponds to the intra-crustal differentiation.
ISSN: 0012-821X

hal-00407206
https://hal.archives-ouvertes.fr/hal-00407206
DOI : 10.1016/j.epsl.2007.06.026

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Oman ophiolite includes both a fossil fast spreading axis, defined by five mantle diapirs, and an off-axis mantle diapir emplaced 30 km from the axis, providing a natural laboratory for the study of off-axis magmatic processes. We compare field and petrological observations coupled with geochemical and isotopic analyses of samples from the off-axis diapir with those of the nearest on-axis diapir, with a particular focus on the Moho Transition Zone (MTZ). Both diapirs are defined by the presence of steeply plunging lineations, but in the on-axis case, these lineations rotate gradually into parallelism with the horizontal magmatic lineations of the overlying crust, while in the off-axis case, a shear zone separates the steeply plunging lineations from the horizontal lineations of the surrounding mantle. In the on-axis diapir, the MTZ is 50 to 500 m thick and composed of dunite with layered gabbro lenses whereas in the off-axis diapir, the MTZ is thicker and composed of dunite with massive (∼20% of MTZ) clinopyroxenite lenses and a notable absence of plagioclase. Moreover, the off-axis diapir is associated with amphibole-bearing intrusions, consisting of Mg-rich gabbroic sills in the mantle peripheral to the diapir, and microgabbroic lenses of broadly basaltic composition in the overlying crust. The ε Nd values of the pyroxenites in the MTZ of the off-axis diapir fully overlap with those of the intrusions in the surrounding mantle and crust, suggesting that they are genetically related. Calculated rare earth element (REE) abundances of liquids in equilibrium with clinopyroxene imply that the magmas that traversed the MTZ of the off-axis diapir were more depleted in highly incompatible elements than their counterparts in the MTZ of the on-axis diapir. On the other hand, Nd isotopic compositions of the off-axis samples (εNd=6.2–7.9εNd=6.2–7.9 in 18 of 19 samples) indicate derivation of their parental magmas from a less depleted source than that which produced the magma associated with the on-axis gabbro (εNd=7.8–9.2εNd=7.8–9.2, 10 analyses).To explain these observations, we suggest that the earliest magmas in the uprising off-axis diapir formed from the partial melting of pyroxenite veins with less radiogenic Nd isotopic compositions than those of the ambient peridotite. As the diapir traversed the cool, hydrated lithosphere these early melts interacted with depleted harzburgites, lowering the incompatible element contents of the melt products while having little effect on their Nd isotopic compositions. The great abundance of clinopyroxene in the off-axis MTZ might be explained by the high pyroxene component in the original melt but perhaps also by the presence of water in the lithosphere, which would favor the crystallization of clinopyroxene while inhibiting that of plagioclase. The intrusions in the overlying crust could represent, to first order, the secondary melts produced by the melt–harzburgite reaction, while the sills in the surrounding mantle may be cumulates from such secondary melts.These results shed light on processes occurring during interaction between rising off-axis material and depleted, hydrated lithospheric mantle. Furthermore, if our interpretation is correct, the low εNd values of the off-axis samples contribute to the growing body of evidence for the presence of pyroxenite veins in the MORB mantle source.
ISSN: 0012-821X

hal-01306575
https://hal.archives-ouvertes.fr/hal-01306575
DOI : 10.1016/j.epsl.2015.12.005

Éditeur(s) : HAL CCSD Elsevier
Résumé : Kyanite and zoisite eclogites from the Limousin area in the Variscan French Massif Central (FMC) have been formed by deep subduction to 100 km depth at peak pressure-temperature conditions around 660 degrees C and 2.9 GPa. They belong to a thin tectonic unit comprising ophiolitic bodies devoid of HP-UHP markers and forming a transported suture zone now separating the two main lithotectonic units of the FMC with contrasted tectono-metamorphic features (namely the lower and upper allochthons). Composition of kyanite-eclogites is similar to supra-subduction-zone basalts found in back-arc basins or island arcs (LREE depleted, negative Nb-Ta anomalies, epsilon Nd: +6 to + 9). Zoisite eclogites have the major-element fingerprint of ultrabasic iron-rich plagioclase cumulates common in continental intrusions or forming Fe-Ti oceanic gabbros. The distribution of immobile trace-elements is however more comparable to alkaline Si-undersaturated rocks, but the Sr-Nd isotopic composition (Sr-87/Sr-86: 0.706; epsilon Nd: -3 to -5) suggests the intervention of an old radiogenic crustal component during their petrogenesis. The chemical composition of hydrous zoisite eclogites does not correspond closely to a common magmatic precursor. It is thus suggested that, by analogy with well exposed worldwide HP-UHP terranes, at least a part of the trace-element signature and the isotopic compositions are controlled by channelled fluid-rock interaction at UHP conditions, leading to localised segregation of zoisite that hosts nearly all Sr and LREE budgets of the bulk eclogite. Sr-Nd isotopic composition of these samples is thus controlled by zoisite and probably represents the isotopic composition of the fluid phase present during UHP recrystallisation. Zircons extracted from a zoisite eclogite were dated in-situ by LA-ICP-MS. Crystallisation of the magmatic precursor is bracketed between 489 and 475 Ma and the UHP event is dated at 412 +/- 10 Ma, in agreement with published ages for the Eo-Variscan HP stage in the FMC. A late resetting of the U-Pb isotopic system at 382 +/- 7 Ma is related to an anatectic high pressure-medium pressure event, well known in the Limousin area. The oceanic eclogites dated in this study are tentatively linked to the Galicia-South Brittany Lower Paleozoic Ocean; they show evidence of the existence of an intra-oceanic subduction zone at the Lower Ordovician and of partial closure of this oceanic domain by ocean-continent subduction during Early Devonian.
ISSN: 0024-4937

hal-00512835
https://hal.archives-ouvertes.fr/hal-00512835
DOI : 10.1016/j.lithos.2010.05.013

Éditeur(s) : HAL CCSD
Résumé : Differentiation of the lithospheric mantle occurred principally through partial melting and extraction of melts. Harzburgites are generally considered as melting residues whereas lherzolites are regarded as pristine mantle weakly affected by melting. However, some orogenic peridotites show evidence of igneous refertilization. In this context, this work re-investigates the nature of the Lherz lherzolites (Pyrenees), type-locality of lherzolites, described as a piece of preserved fertile mantle. Structural and geochemical data show that these lherzolites are not pristine but formed through a refertilization reaction between MORB-like melts and refractory lithosphere. Moreover, the Lherz peridotites were partly used to infer the composition of the primitive upper mantle and these results may have important implications for the nature of the late veneer. Additionally, crystal-preferred orientations of minerals (CPO) highlight a strong feedback between melt percolation and finite strain in the percolated rocks. CPO variations are ruled by a subtle balance between instantaneous melt fraction and local strain rate. This work also investigated the effect of melt percolation on Hf, Nd and Sr isotopes. Isotope systematics in Lherz shows that strong isotopic decoupling may arise in a percolation front. The modelling suggests that decoupled isotopic signatures are generated during porous flow and governed by the melt/matrix elements concentrations, chemical diffusivities or efficiency of isotopic homogenization. Melt-rock interactions can generate “intraplate-like” isotopic signatures. This suggests that a part of isotopic signatures of mantle-related rocks could be generated by diffusional processes associated with melt transport.
La différenciation du manteau lithosphérique s'est principalement effectuée par fusion partielle et extraction de magmas. Les harzburgites sont généralement considérées comme des résidus de fusion tandis que les lherzolites représentent un manteau originel peu affecté par la fusion. Cependant, certaines péridotites orogéniques montrent des évidences de refertilisation magmatique. Dans ce contexte, ce travail remet en cause la nature primitive des lherzolites de Lherz (Pyrénées), lithotype de la lherzolite. Les données structurales et géochimiques montrent que ces lherzolites ne représentent pas du manteau préservé mais qu'elles se sont formées par une réaction de refertilisation entre un liquide de type MORB et une lithosphère réfractaire. De plus, les orientations préférentielles de réseau (OPR) des minéraux montrent une forte interdépendance entre la percolation magmatique et la déformation finie observée dans les roches percolées. Les variations d'OPR semblent contrôlées par un équilibre subtil entre fraction de liquide instantanée et taux de déformation local. Ce travail a également abordé les effets de la percolation magmatique sur la variabilité isotopique des roches mantelliques. Les résultats montrent qu'un fort découplage isotopique peut s'observer dans un front de percolation. Les modèles suggèrent que le découplage des signatures isotopiques se produit pendant la percolation, gouverné par le rapport des concentrations en éléments (magma/matrice), la diffusivité et le processus d'homogénéisation isotopique. Les réactions magma/roche peuvent générer des signatures isotopiques de type intraplaque. Ceci suggère qu'une part des signatures isotopiques des roches ou laves dérivées du manteau pourrait être produite par des processus diffusionnels associés à du transport de magma.
https://tel.archives-ouvertes.fr/tel-00431325

tel-00431325
https://tel.archives-ouvertes.fr/tel-00431325
https://tel.archives-ouvertes.fr/tel-00431325/document
https://tel.archives-ouvertes.fr/tel-00431325/file/theseleroux08.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Maghrebides, Betics and some parts of the Calabrian, NE Sicilian and Tuscan allochtons constitute dismembered fragments of the Alpine belt that resulted from the Cenozoic collision between Africa and Eurasia and the opening of the Western Mediterranean basin. Mineral and whole-rock geochemical analyses have been performed on three distinct outcrops of mantle material from the Edough Massif of NE Algeria, namely the Bou Maiza (BM) gabbros, the La Voile Noire (LVN) amphibolites and the Sidi Mohamed (SM) peridotites. In all samples, Sr isotopes are largely affected by seawater alteration (87Sr/86Sract. > 0.70384 and up to 0.70888) and cannot be used to evaluate the nature of the source reservoirs. SM peridotites display variable depleted mantle Nd isotopic signatures (εNdact. from + 7.0 to + 12.2) and geochemical features suggesting no significant chemical depletion as a result of partial melting and melt extraction (Mg# < 90; slightly LREE-depleted patterns with La/YbN = 0.33-0.39). These rocks are interpreted as parts of the subcontinental lithospheric mantle incorporated into the crustal units of the Edough Massif during the early stages of opening of the Algerian basin. BM gabbros and LVN amphibolites show geochemical signatures indicating derivation from a common Depleted Mantle reservoir (εNd > + 7.9) and are likely cogenetic, but without filiation with the SM peridotites. Pb isotopes indicate a contribution of sediments in the source reservoir, which is attributed to contamination solely by hydrous fluids released from a sedimentary component. This observation, together with a LILE-enrichment, suggests a back-arc basin environment. These results indicate that BM and LVN units were obducted onto the North African margin and subsequently fragmented, probably during doming and exhumation of the lower continental crust of the Edough massif. Doming resulted in opposite movements of the overlying oceanic units, southward for the BM units and northward for LVN amphibolites.
ISSN: 0040-1951

hal-01122777
https://hal.archives-ouvertes.fr/hal-01122777
DOI : 10.1016/j.tecto.2014.03.031

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Ocean island basalts (OIB) from the Comores archipelago (Indian Ocean) display mineralogical and geochemical features different from the other Indian OIB. We present here new geochronological data (40Ar/39Ar), major and trace element compositions and isotopic (Sr, Nd, Pb) ratios of silica-undersaturated alkaline rocks from Mayotte, the oldest island of the Comores. Two trends are defined using major element composition: (1) a highly silica-undersaturated trend which includes basanites, (melilite-bearing) nephelinites, intermediate lavas and phonolites from the southern part of the island and (2) a moderately silica-undersaturated trend which is mainly represented by alkali basalts, basanites, intermediate lavas and phonolites from the northern part of the island. Both trends could be explained, to some extent, by variable degrees of partial melting. Normative larnite-bearing olivine melilitites and nephelinites exhibit, in addition to their high silica-undersaturation, elevated concentrations in CaO (>12wt.%) and P2O5 (up to 1.35wt.%). These exceptional rocks would result from low degree deep partial melting of a CO2-metasomatized source in the presence of carbonate (probably dolomite) and apatite. Igneous rocks from southern and northwestern shield volcanoes are characterized by a radiogenic Pb composition, revealing the existence of a HIMU (high μ=238U/204Pb) component in their source. Its influence decreases from the main building stage (>10.6-~3.0Ma) to the post-shield stage for the benefit of a depleted MORB-mantle (DMM) component, especially in the north central rocks. This feature would reflect increasing melting degrees of the depleted dominant source, bearing small-scale HIMU heterogeneities progressively consumed with time. The HIMU signature might have been introduced in the Comorian lithospheric mantle by thermal erosion or delamination of a continental lithosphere during the Gondwana break-up. The other islands of the Comores archipelago (Moheli, Anjouan and "La Grille" type lavas from Grande Comore) display also a DMM-HIMU mixing trend. Only a few lavas from Grande Comore ("Karthala" type) and one sample from Mayotte show the clear EM1 contribution (87Sr/86Sr>0.7035) of the Comorian plume.
ISSN: 0024-4937

insu-01089376
https://hal-insu.archives-ouvertes.fr/insu-01089376
https://hal-insu.archives-ouvertes.fr/insu-01089376/document
https://hal-insu.archives-ouvertes.fr/insu-01089376/file/Pelleter%20et%20al%201.pdf
DOI : 10.1016/j.lithos.2014.09.012

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Multiproxy analyses were performed on core MS27PT recovered in hemipelagic sediments deposited on the Nile margin in order to reconstruct Nile River palaeohydrological fluctuations during the last 100,000 years. The strontium and neodymium isotope composition of the terrigenous fraction and the major element distribution reveal large and abrupt changes in source, oscillating between a dominant aeolian Saharan contribution during arid periods and a dominant Nile River contribution during pluvial periods. Iron content shows a strong correlation with strontium and neodymium isotopes. This allows the use of a high-resolution continuous Fe record as a proxy of Blue Nile sediment input over the last 100,000 years. The detailed Fe record, with approximately 10 years resolution during pluvial periods, is consistent with subtropical African records of well-dated lake level fluctuations and thus constitutes a first continuous high resolution record of the East African monsoon regime intensity over Ethiopia.;The detailed Fe record shows the two main known pluvial periods attributed to strengthening of the African monsoon over Ethiopia, the Nabtian period from 14 to 8 ka cal BP and the Saharan period from 98 to 72 ka BR For the first time, the last glacial period (Marine Isotope Stage (MIS) 2,3 and 4) is documented with a continuous record showing large oscillations between high and low East African palaeo-monsoon regimes.;The end of the Nabtian period occurred at 8 ka in core MS27PT, i.e. much earlier than on the East Equatorial African region where it ended around 5.5 ka. We interpret this as evidence that the southward shift of the rain belt occurred 3000 years earlier over the Eastern Ethiopian Highland and propose that the gradual southward migration of the rain belt was associated with highly variable intensity and longer rainy seasons from 8 to 5 ka. During the last glacial period, two wet periods are present around 60-50 ka BP and 38-30 ka BP. These two humid periods are in phase with the rise of atmospheric CH4 concentrations suggesting that wetland tropical African area was one of the sources of the atmospheric CH4 during the MIS 3. During the Last Glacial Maximum and MIS 4, high Saharan aeolian influxes in phase with records of aeolian dust deposited in East Antarctica are documented. This study highlights the importance of reconstructions of monsoon rainfall fluctuation at high temporal resolution to better understand the link between low- and high-latitude climate variability at millennial timescales.
ISSN: 0277-3791

hal-00496481
https://hal.archives-ouvertes.fr/hal-00496481
DOI : 10.1016/j.quascirev.2010.02.006

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Mantle-derived xenoliths hosted by melilitite lavas from In Teria (Ahaggar, SE Algeria) include garnet and spinel peridotites, pyroxenite and phlogopite megacrysts. The spinel and garnet peridotites record an early deformation event, which formed porphyroclastic microstructures and olivine crystal preferred orientations, followed by static infiltration of hydrous alkaline melts. This metasomatic stage (stage 1) is characterized by the crystallization of phlogopite in the garnet and spinel peridotites, amphibole in the spinel peridotites and clinopyroxene in the garnet peridotite, which record chemical equilibration with an alkaline silicate melt. These early events were largely overprinted by carbonatitic metasomatism (stage 2), which is observed only in the spinel peridotites. Spinel peridotite major and trace element compositions, as well as the compositions of newly formed minerals, are characteristic of interaction with carbonate melt, associated with strong enrichment in incompatible trace elements in clinopyroxene. This second stage was followed by crystallization of pyroxenites (stage 3) in vein conduits, probably segregated from alkaline melts. We propose a scenario in which the different metasomatic imprints record successive stages of interaction between lithospheric mantle and sublithospheric melts throughout the Cenozoic. In Sr–Nd isotope space, the host melilitites and several xenoliths are clustered and plot close to the HIMU mantle end-member. However, some peridotite xenoliths are shifted towards more radiogenic 87Sr/86Sr values. In 207Pb/204Pb–206Pb/204Pb and 208Pb/204Pb–06Pb/204Pb space the In Teria samples define a relatively large domain characterized by high 206Pb/204Pb and 208Pb/204Pb, consistent with a contribution of an HIMU component, considered to represent a sublithospheric signature. The highest 87Sr/86Sr values are comparable with those ascribed to the EM1 mantle end-member, representing the signature of the lower continental lithosphere, and are probably inherited from the pre-metasomatic lithospheric mantle beneath In Teria. Numerical modelling of porous percolation of melt of sublithospheric origin through an EM1-like lithospheric mantle protolith reproduces the In Teria peridotite compositions, using moderately sub-chondritic Sr/Nd values for the peridotite (e.g. In Teria garnet peridotite) and moderately super-chondritic Sr/Nd values in the melt (approximately ocean island basalt values). A few spinel peridotites require a component characterized by a 143Nd/144Nd signature higher than both the EM1 end-member and the local Ahaggar basalts; the 208Pb/204Pb compositions of several samples point to a component with a depleted mid-ocean ridge basalt (MORB) mantle (DMM) signature. Thus the lithospheric mantle beneath In Teria probably did not have a uniform EM1 signature before the onset of metasomatism; it included a DMM peridotite component as well as some peridotites with elevated 143Nd/144Nd values recording long-term LREE depletion.
ISSN: 0022-3530

hal-01356781
https://hal.archives-ouvertes.fr/hal-01356781
DOI : 10.1093/petrology/egw009

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The eastern part of the Cordillera Occidental of Ecuador comprises thick buoyant oceanic plateaus associated with island-arc tholeiites and subduction-related calc-alkaline series, accreted to the Ecuadorian Continental Margin from Late Cretaceous to Eocene times. One of these plateau sequences, the Guaranda Oceanic Plateau is considered as remnant of the Caribbean–Colombian Oceanic Province (CCOP) accreted to the Ecuadorian Margin in the Maastrichtien. Samples studied in this paper were taken from four cross-sections through two arc-sequences in the northern part of the Cordillera Occidental of Ecuador, dated as (Río Cala) or ascribed to (Macuchi) the Late Cretaceous and one arc-like sequence in the Chogòn-Colonche Cordillera (Las Orquídeas). These three island-arcs can clearly be identified and rest conformably on the CCOP. In all four localities, basalts with abundant large clinopyroxene phenocrysts can be found, mimicking a picritic or ankaramitic facies. This mineralogical particularity, although not uncommon in island arc lavas, hints at a contribution of the CCOP in the genesis of these island arc rocks. The complete petrological and geochemical study of these rocks reveals that some have a primitive island-arc nature (MgO values range from 6 to 11 wt.%). Studied samples display marked Nb, Ta and Ti negative anomalies relative to the adjacent elements in the spidergrams characteristic of subduction-related magmatism. These rocks are LREE-enriched and their clinopyroxenes show a tholeiitic affinity (FeOT–TiO2 enrichment and CaO depletion from core to rim within a single crystal). The four sampled cross-sections through the island-arc sequences display homogeneous initial Nd, and Pb isotope ratios that suggest a unique mantellic source for these rocks resulting from the mixing of three components: an East-Pacific MORB end-member, an enriched pelagic sediment component, and a HIMU component carried by the CCOP. Indeed, the ankaramite and Mg-basalt sequences that form part of the Caribbean-Colombian Oceanic Plateau are radiogenically enriched in 206Pb/204Pb and 207Pb/204Pb and contain a HIMU component similar to that observed in the Gorgona basalts and Galápagos lavas. The subduction zone that generated the Late Cretaceous arcs occurred far from the continental margin, in an oceanic environment. This implies that no terrigenous detrital sediments interacted with the source at this period. Thus, the enriched component can only result from the melting of subducted pelagic sediments. We have thus defined the East-Pacific MORB, enriched (cherts, pelagic sediments) and HIMU components in an attempt to constrain and model the genesis of the studied island-arc magmatism, using a compilation of carefully selected isotopic data from literature according to rock age and paleogeographic location at the time of arc edification. Tripolar mixing models reveal that proportions of 12–15 wt.% of the HIMU component, 7–15 wt.% of the pelagic sediment end-member and 70–75 wt.% of an East-pacific MORB end-member are needed to explain the measured isotope ratios. These surprisingly high proportions of the HIMU/CCOP component could be explained by the young age of the oceanic plateau (5–15 Ma) during the Late Cretaceous arc emplacement. The CCOP, basement of these arc sequences, was probably still hot and easily assimilated at the island-arc lava source.
ISSN: 0895-9811

insu-00353692
https://hal-insu.archives-ouvertes.fr/insu-00353692
DOI : 10.1016/j.jsames.2008.06.003

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Almost all Red Sea deeps contain metal-rich sediments covered by brine pools. It is generally agreed that these metal-rich deposits precipitated from overlying metal-rich brines that originated from migrating hydrothermal fluids. No brine pool has ever been reported in Thetis Deep, inciting us to evaluate if such a brine layer ever occurred in the deep during the past. In order to address that questioning, a study combining mineralogical, geochemical (major-, minor-, rare-earth elements) and isotopic (Sr. Nd. Pb) approaches was completed on cored sediments and extracted interstitial waters from inside and outside the deep.;The sediments have an overall hydrothermal origin, as shown by the REE concentrations and patterns, metal contents, and Pb-Nd isotopic data, all pointing to a mantle signature. The intensity of the hydrothermal activity varied with time in the deep; the most intense episode resulting in an almost pure Fe-oxi-hydroxide layer. Varied chemical arguments, especially the Zr and REE data of the sediments, favor the fact that the whole sedimentation in Thetis Deep occurred in the absence of a stable, salt-rich and mineralized brine pool, and that no brine layer ever existed. This conclusion is supported by the constant Sr isotope composition of the sediment and its interstitial waters that are almost identical to that of the Red Sea seawater. The study also suggests that hydrothermal activity monitored fluid supplies that interacted differently with seawater in the different Red Sea deeps, resulting in an overall formation of metal-rich sediments, but along varied local conditions. (C) 2009 Elsevier B.V. All rights reserved.
ISSN: 0375-6742

hal-00475646
https://hal.archives-ouvertes.fr/hal-00475646
DOI : 10.1016/j.gexplo.2009.10.001

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Eastern Hoggar is by far the least well known part of the Tuareg Shield. It is composed, from west to east, of the Aouzegueur, Edembo and Djanet Terranes. The Djanet Terrane is the easternmost Hoggar terrane and comprises a greenschist-facies clastic sedimentary sequence, the Djanet Group, intruded by granitoids. Laser ablation (LA-) ICP-MS U-Pb zircon ages of detrital zircons from these sediments yield a large range of ages similar to ages known in Central and Western Hoggar; the youngest is 590 +/- 10 Ma (2 sigma), which is the maximum age of deposition of the Djanet Croup. The Djanet Group is intruded by the Djanet Batholith (571 +/- 16 Ma), by high-level subcircular plutons such as the Tin Bedjane Pluton (568 +/- 5 Ma) and finally by the felsic Tin Amali Dyke Swarm (558 +/- 5 Ma), all ages being SHRIMP U-Pb zircon. The deposition and metamorphism of the Djanet Group thus occurred between 590 Ma (the age of the youngest detrital zircons analyzed in the Djanet Group) and c. 570 Ma (the age of intrusive granitoids). Nd T-DM two-stage model ages (1.30-2.03 Ga), initial Sr-87/Sr-86 ratios (0.7035-0.7095) and epsilon(Nd) (-3 to -11) of the three intrusive suites, all being high-K calc-alkaline in composition, indicate mainly an old, Rb-depleted continental source. Migmatization in the adjacent Edembo Terrane is dated at 568 +/- 4 Ma (U-Pb zircon SHRIMP age), contemporaneous with the intrusion of the Djanet plutons. Rocks and events in the Edembo and Djanet Terranes are all intracontinental. We propose that the Djanet Terrane lies on the boundary of a craton located to the north-east, that we defined here as the Murzuq craton. The existence of the Murzuq craton is supported by sedimentary and geophysical data. We suggest that the deformation of Eastern Hoggar occurred 575-555 Ma, due to the indentation of the Murzuq craton and has no link with the older convergence with the West African craton as was the case for the central and western parts of the Tuareg Shield. This determines a late Ediacaran intracontinental Murzukian event that probably also occurred to the east in the Tibesti area.
ISSN: 0301-9268

hal-00512833
https://hal.archives-ouvertes.fr/hal-00512833
DOI : 10.1016/j.precamres.2010.05.011

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Spinel lherzolite xenoliths from Mont Briancon, French Massif Central, retain evidence for multiple episodes of melt depletion and melt/fluid infiltration (metasomatism). Evidence for primary melt depletion is still preserved in the co-variation of bulk-rock major elements (MgO 38.7-46.1 wt.%; CaO 0.9-3.6 wt.%), and many samples yield unradiogenic bulk-rock Os isotope ratios (Os-187/Os-188 = 0.11541-0.12626). However, many individual xenoliths contain interstitial glasses and melt inclusions that are not in equilibrium with the major primary minerals. Incompatible trace element mass balance calculations demonstrate that metasomatic components comprise a significant proportion of the bulk-rock budget for these elements in some rocks, ranging to as much as 25%, of Nd and 40% of Sr Critically, for Re-Os geochronology, melt/fluid infiltration is accompanied by the mobilisation of Sulfide. Consequently, bulk-rock isotope measurements, whether using lithophile (e.g. Rb-Sr, Sm-Nd) or siderophile (Re-Os) based isotope systems, may only yield a perturbed and/or homogenised average of these multiple events.;Osmium mass balance calculations demonstrate that bulk-rock Os in peridotite is dominated by contributions from two populations of sulfide grain: (i) interstitial, metasomatic Sulfide with low [Os] and radiogenic Os-187/Os-188, and (ii) primary sulfides with high [Os] and unradiogenic Os-187/Os-188, which have been preserved within host silicate grains and shielded from interaction with transient melts and fluid. The latter can account for >97% of bulk-rock Os and preserve geochronological information of the melt from which they originally precipitated as an immiscible liquid. The Re-depletion model ages of individual primary sulfide grains preserve evidence for melt depletion beneath the Massif Central from at least 1.8 Gyr ago despite the more recent metasomatic event(s). (C) 2009 Elsevier Ltd. All rights reserved.
ISSN: 0016-7037

hal-00454537
https://hal.archives-ouvertes.fr/hal-00454537
DOI : 10.1016/j.gca.2009.09.031

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Middle to Late Triassic lavas were sampled within three tectonostratigraphic groups of the Hawasina Nappes in the Oman Mountains. They are predominantly alkali basalts and trachybasalts, associated with minor sub-alkaline basalts, trachyandesites, trachytes and rhyolites. Their major, trace elements and Nd-Pb isotopic compositions are very similar to those of the Permian plume-related high-Ti basalts which also occur in the Hawasina Nappes. The Triassic lavas derive from low-degree melting of an enriched OIB-type mantle source, characterized by εNdi = 0.3-5.3 and (206Pb/204Pb)i = 16.96-19.31 (for t = 230 My). With time, melting depths decreased from the garnet + spinel to the spinel lherzolite facies and the degree of melting increased. The oldest are distinguished from the others by unradiogenic Nd and Pb signatures, with εNdi = − 4.5 to − 1.2 and (206Pb/204Pb)i = 16.35-17.08, which we attribute to their contamination by Arabo-Nubian lower crust. The lavas likely derived from the Oman lithospheric mantle, the original DMM-HIMU signature of which was overprinted during its pervasive metasomatism by the Permian plume-related melts. We suggest that these lavas were emplaced during post-breakup decompression-triggered melting in the Middle Triassic during global kinematic reorganization of the Tethyan realm.
ISSN: 0024-4937

insu-00559080
https://hal-insu.archives-ouvertes.fr/insu-00559080
https://hal-insu.archives-ouvertes.fr/insu-00559080/document
https://hal-insu.archives-ouvertes.fr/insu-00559080/file/FC_TriasOman.pdf
DOI : 10.1016/j.lithos.2010.12.006