Éditeur(s) : HAL CCSD Springer Verlag (Germany) Springer Verlag
Résumé : International audience
Separated olivine grains from a deeply subducted serpentinized wehrlite (Changawuzi in the western Tianshan ultrahigh-pressure belt, China) were analysed with unpolarized transmission FTIR and the Ti contents were determined using LA-ICP-MS. The major bands in the olivine spectra display striking similarities to Ti-clinohumite and are interpreted as OH in lamellae. The quantification of the water content in lamellae requires calibration of the IR-absorption for such bands. We have obtained a new absorption coefficient for Ti-clinohumite of 0.125+/−0.017 ppm cm2 based on polarized FTIR measurements on three orthogonal sections through a large single crystal of Ti-clinohumite from Val Malenco, which has a known water content of 1.53 wt%. The resulting water content in olivine using this calibration factor ranges from 440 to 2,600 ppm and correlates positively with the Ti content that ranges from 130 to 1,400 ppm. For the quantification of the water content in Ti-chondrodite and Ti-clinohumite that are associated with olivine, we developed a new method using attenuated total reflectance FTIR spectroscopy. Ti-chondrodite and Ti-clinohumite display similar IR bands at ~3,562, 3,525 and ~3,583–3,586 cm−1. As in olivine, the water content and Ti content correlate in both Ti-clinohumite and Ti-chondrodite, indicating an intergrowth of these minerals, which has been confirmed by TEM analyses. Our results confirm previous suggestions that there is a strong correlation between the Ti content of ultramafic rocks and their capacity to transport water to the deeper mantle in subduction zones beyond conditions where hydrous phases are stable.
ISSN: 0010-7999

hal-01172237
https://hal.archives-ouvertes.fr/hal-01172237
DOI : 10.1007/s00410-014-0992-8

Éditeur(s) : Amer Geophysical Union
Résumé : Large rivers are key hydrologic components in oceanography, particularly regarding air-sea and land-sea exchanges and biogeochemistry. We enter now in a new era of Sea Surface Salinity (SSS) observing system from Space with the recent launches of the ESA Soil Moisture and Ocean Salinity (SMOS) and the NASA Aquarius/Sac-D missions. With these new sensors, we are now in an excellent position to revisit SSS and ocean color investigations in the tropical northwest Atlantic using multi-year remote sensing time series and concurrent in situ observations. The Amazon is the world's largest river in terms of discharge. In its plume, SSS and upper water column optical properties such as the absorption coefficient of colored detrital matter (acdm) are strongly negatively correlated (<-0.7). Local quasi-linear relationships between SSS and acdm are derived for these plume waters over the period of 2010-2013 using new spaceborne SSS and ocean color measurements. Results allow unprecedented spatial and temporal resolution of this coupling. These relationships are then used to estimate SSS in the Amazon plume based on ocean color satellite data. This new product is validated against SMOS and in situ data and compared with previously developed SSS retrieval models. We demonstrate the potential to estimate tropical Atlantic SSS for the extended period from 1998 to 2010, prior to spaceborne SSS data collection.
Journal Of Geophysical Research-oceans (0148-0227) (Amer Geophysical Union), 2015-05 , Vol. 120 , N. 5 , P. 3177-3192

Droits : 2015. American Geophysical Union. All Rights Reserved.
http://archimer.ifremer.fr/doc/00255/36610/35742.pdf
DOI:10.1002/2014JC010109
http://archimer.ifremer.fr/doc/00255/36610/

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
Polarized emittance measurements were acquired for synthetic forsterite, the pure magnesium end member of the olivines group, on the whole infrared spectral range and up to the melting point by using CO2 laser heating. The experimental data, fitted with a semi-quantum dielectric function model, allowed the retrieval of the temperature dependence of the absorption coefficient of forsterite both in the opaque and semi-transparent regions. The analysis of the phonon parameters indicates that the lattice dynamics evolve drastically with increasing temperature. The normal modes involving motions of the magnesium cations located in site 1 are the more impacted, and some of them vanish around 1,200 K. The results confirm that the enhancement of the lattice anharmonicity and the increasing mobility of the magnesium cations are closely linked and are at the origin of the anomalies observed in the evolution of the thermophysical properties. This complete set of spectroscopic data may be a step toward a more precise evaluation of the impact of thermal radiation heat transfer inside systems involving forsterite and quantification of their heat budget.
ISSN: 0342-1791

hal-00817079
https://hal.archives-ouvertes.fr/hal-00817079
DOI : 10.1007/s00269-013-0570-z

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The indoor gas-phase concentrations of semi-volatile organic compounds (SVOCs) can be predicted from their respective concentrations in airborne particles by applying the particle/gas partitioning equilibrium. The temperature used for partitioning is often set to 25 °C. However, indoor temperatures frequently differ from this reference value. This assumption may result in errors in the predicted equilibrium gas-phase SVOC concentrations. To improve the prediction model, the temperature dependence of the particle/gas partition coefficient must be addressed. In this paper, a theoretical relationship between the particle/gas partition coefficient and temperature was developed based on the SVOC absorptive mechanism. The SVOC particle/gas partition coefficients predicted by employing the derived theoretical relationship agree well with the experimental data retrieved from the literature (R > 0.93). The influence of temperature on the equilibrium gas-phase SVOC concentration was quantified by a dimensionless analysis of the derived relationship between the SVOC particle/gas partition coefficient and temperature. The predicted equilibrium gas-phase SVOC concentration decreased by between 31% and 53% when the temperature was lowered by 6 °C, while it increased by up to 750% when the indoor temperature increased from 15 °C to 30 °C.
ISSN: 0048-9697

hal-01313749
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01313749
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01313749/document
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01313749/file/Temperature%20dependence%20of%20the%20particle%20gas%20partition%20coefficient_accepted.pdf
DOI : 10.1016/j.scitotenv.2016.04.106

Résumé : Les océans qui couvrent les deux tiers de la planète sont susceptibles d'offrir deux types d'énergie. D'une part des énergies utilisables à faible niveau de puissance et capables d'apporter une solution pratique à certains problèmes particuliers : ce sont essentiellement les énergies de la houle et du vent. D'autre part, une énergie qui ne se révèle intéressante qu'à partir d'un certain niveau de puissance: c'est l'énergie thermique des mers (E.T.M.) encore appelée énergie maréthermique (l'énergie marémotrice qui relève de ce dernier type est un cas assez particulier car elle ne concerne qu'un nombre de sites très restreint). Les énergies de la mer sont un sous produit direct de l'énergie solaire ; en effet, en raison de la valeur du flux d'énergie solaire, le globe terrestre intercepte une puissance équivalente à 200 milliards de mégawatts, mais en raison de la réflexion diffuse sur l'atmosphère, sur les nuages, sur la mer et sur la terre, près de la moitié de cette énergie incidente est renvoyée vers l'espace. La plus grande partie du rayonnement solaire converti en chaleur sert à chauffer la mer qui, du fait de son faible coefficient de réflexion, absorbe une quantité importante de lumière. Comme la chaleur spécifique de l'eau est très grande, et que le volume d'eau échauffée est important, les couches superficielles de l'océan vont jouer le rôle d'un immense réservoir de chaleur. On sait par ailleurs que les eaux profondes des océans. qui prennent naissance dans la région des pôles, s'écoulent lentement sur le fond des bassins océaniques et que leur température est voisine de 0°. Il est donc théoriquement possible. en utilisant les différences de température qui existent entre les eaux de surface et celles du fond. de concevoir une machine thermique capable de fournir de l'énergie mécanique transformée en énergie électrique. Il s'agit là d'une technologie douce qui constitue certainement un progrès par rapport aux technologies dures et brutales mises en œuvre jusqu'à présent.

Droits : 1978 Ifremer
http://archimer.ifremer.fr/doc/00039/14975/12302.pdf
http://archimer.ifremer.fr/doc/00039/14975/

Éditeur(s) : HAL CCSD Mineralogical Society of America
Résumé : International audience
Wadsleyites with various iron contents were synthesized at ~12-14 GPa and 1400 °C under oxidizing and hydrous conditions in coexistence with enstatite. The samples were studied using micro-X-ray absorption near edge structure (XANES) and micro-Mössbauer spectroscopy to determine the ferric iron contents in polyphasic samples and secondary ion mass spectrometry (SIMS) to determine the water concentrations. XANES and Mössbauer analyses show that ferric iron content increases with increasing total iron content, and reaches a maximum of ~30% Fe3+/Fetotal. Two XANES results were cross-checked by Mössbauer analysis and both methods are in reasonable agreement. The use of Fourier transform infrared spectroscopy reveals a new protonation scheme in wadsleyite, with a significant proportion of protons associated with the high-frequency band at 3611 cm−1 and a new band located at 3500 cm−1. The intensity of these two bands is higher for Fe3+-rich wadsleyite. SIMS analyses show that water contents in wadsleyite vary from 4500 to 9400 ppm H2O by weight. Pyroxene water contents range from 790 to 1600 ppm wt H2O. The concentration of water in both phases decreases with increasing iron content. The partition coefficient of water between wadsleyite and pyroxene varies between 5 and 9 and increases with increasing Fe-number of wadsleyite [i.e., XFe/(XFe + XMg) × 100 ratio]. The divalent cation concentrations (i.e., Mg2+ + Fe2+), the Si as well as the H content in wadsleyite decrease with increasing Fe3+ content, indicating an incorporation mechanism via substitution into the metal (Me = Mg2+ and Fe2+) and Si sites with a ratio of 5/3 for (Fe3++H+):Me and of 5/1 for (Fe3++H+):Si, similarly as in the dry system. Thus, coupled substitution of Fe3+ and H+ does not affect the incorporation mechanism of Fe3+, but does affect the location of H+, which is partly incorporated at tetrahedral edges forming [FeSi′-(OH)o*]X neutral defects substituting for Si. In this model 25% of the ferric iron occupies the tetrahedral sites.
ISSN: 0003-004X

hal-00758071
https://hal.archives-ouvertes.fr/hal-00758071
DOI : 10.2138/am.2012.3869