Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In this work we perform a statistical analysis of global solar radiation measured at two sites, 38 km distant from, in Guadeloupe, French West Indies. We have established a correlation model based on the coefficient of variation assuming a time scale separation. The coefficient of variation is calculated on minutes interval with data measured at 1 Hz. This analysis highlight the dynamic correlation that can occur between measurements from two different sites with a time step of one second. From this results, knowing the coefficient of variation on a site we have established a new correlation model on this parameter for another site. A diagram linking the standard deviation on both sites, for a given coefficient of variation is proposed for correlated and non-correlated cases. More over this analysis put in evidence the existence of a threshold time under which there is no significant correlation. This model can be useful in choosing new sites of production not only for establishing correlation from on site to another, but also in optimizing the geographical distribution of the solar farms within the territory.
ISSN: 0960-1481

Droits : http://hal.archives-ouvertes.fr/licences/copyright/
hal-01099045
https://hal.archives-ouvertes.fr/hal-01099045
https://hal.archives-ouvertes.fr/hal-01099045/document
https://hal.archives-ouvertes.fr/hal-01099045/file/Article%20Foison_2014.pdf

Éditeur(s) : HAL CCSD
Résumé : EGU2012-6377- Geophysical Research Abstracts vol. 14
The hot geothermal fluid produced by the wells of the Bouillante power station, in Guadeloupe, contains various dissolved species such as silica or some metals (Zn, Pb, etc). During the exploitation, the geothermal fluid is flashing and cooling (from 260 to 160°C for the high-pressure steam-liquid separation and down to 110°C for the low-pressure phase separation of a part of the separated liquid at 160°C). Consequently, the dissolved species can form scale deposits such as amorphous silica or poly-metallic sulphides, according to the exploitation conditions, and cause serious scaling problems on the production and the surface installations. These minerals could also precipitate during the partial underground re-injection of the production fluids which is being set up in the Bouillante power station. In this study, in order to predict and prevent the possible silica precipitation at temperature lower than 160°C, during the partial underground reinjection of the production fluids of Bouillante or their thermal valorization down to 110°C temperatures, we propose to investigate on site the kinetics of silica precipitation as a function of temperature and pH. The experiments presented here were carried out on site on samples of separated waters collected after the steam-water separator at 160°C, containing about 600 ppm of SiO2, at four cooling temperatures: 22, 50, 75 and 90°C, and for pH ranging from 4 to 9. These experiments showed that the silica deposition was always initiated by a polymerization mechanism characterized by an order 2 kinetic law and the formation of a white colloidal gel, which slowed down the silica precipitation under solid form. This latter was observed much later, after the polymerization stage, and only in particular conditions (long time of atmospheric exposure, water stagnation,. . . ). The results also confirmed that the silica precipitation kinetics is strongly dependent on pH. In acidic solution, a transition period is observed before the beginning to the silica polymerization. At neutral-basic pH, there is no transition period and the rate of polymerization is maximal for pH close to 8. The undergoing modeling of these experimental data and specific surface area measurements on the colloidal gel will allow us to determinate the kinetics parameters useful for the prediction and prevention of silica precipitation under the specific exploitation conditions of Bouillante power station. This work is financially supported by ADEME (French Agency for Energy and Environment), BRGM and UAG.
EGU General Assembly 2012
Vienne, Austria

hal-00697627
https://hal-brgm.archives-ouvertes.fr/hal-00697627

Éditeur(s) : HAL CCSD AGU and the Geochemical Society
Résumé : Geochemistry, Geophysics, Geosystems, v. 9, p. Q12001, 2008. http://dx.doi.org/10.1029/2008GC002098
International audience
Rb/Sr, 40Ar/39Ar, and Sm/Nd isotopic data are reported in Caledonian eclogites from the Lindås Nappe, Bergen Arcs, Norway, in order to investigate processes controlling isotopic equilibrium at mineral scale in polymetamorphic rocks. The Bergen Arcs exposes Sveconorwegian ∼950–930 Ma granulites, partially overprinted by Caledonian eclogite-facies metamorphism at ∼425 Ma and amphibolite-facies metamorphism at ∼410 Ma. Geochemical and Rb-Sr data from more than 10 phengite fractions separated from one sample reflect the composition of the microdomain (a few hundred microns in size) in which phengite crystallized. Phengite crystallized after garnet or plagioclase by dissolution-precipitation processes yield apparent age between 700 and 600 Ma. At the time of their crystallization, these phengites inherited the isotopic composition of their precursor minerals, at a microdomain scale. Phengite from quartz veins, which crystallized from elements mobilized by the circulating fluid, yield an age closer to the eclogite-facies metamorphic age. The closed system evolution of the eclogitizing fluid, the segregation of textural and reactional microdomains, the high Sr content of the studied phengite, and the short duration of the recrystallization processes (<1Ma) are interpreted as the main factors responsible for the lack of a Rb/Sr isotopic equilibrium, at the scale of hand samples. Such equilibrium is nevertheless reached in quartz veins where the crystallization of minerals implies that the fluid circulation acted as a factor of isotopic homogenization. The in situ single mineral Ar/Ar datings revealed that both eclogite- and amphibolite-facies minerals are characterized by an excess of radiogenic argon (ages between 425 and 520 Ma). The excess of argon has been inherited from the previous granulite and has been only partially evacuated from the system by the circulating fluid. The apparent Sm/Nd ages from garnets inherited from the granulite-facies metamorphism (c. 930 Ma) are in agreement with previous estimates. This result confirms that the diffusion of Nd in garnet does not occur at temperatures lower than 700°C. This study highlights the complexity of radiochronometer behavior during HP metamorphism and demonstrates that coupling different radiochronometers, such as Ar/Ar and Rb/Sr, does not always guarantee the validity of the geochronological results.
ISSN: 1525-2027

hal-00407885
https://hal.archives-ouvertes.fr/hal-00407885
DOI : 10.1029/2008GC002098

Éditeur(s) : HAL CCSD BioMed Central
Résumé : International audience
BACKGROUND: Environmental exposures, including dietary contaminants, may influence the developing immune system. This study assesses the association between maternal pre-parturition consumption of seafood and wheeze, eczema, and food allergy in preschool children. Fish and shellfish were studied separately as they differ according to their levels of omega-3 polyunsaturated fatty acids (which have anti-allergic properties) and their levels of contaminants. METHODS: The PELAGIE cohort included 3421 women recruited at the beginning of pregnancy. Maternal fish and shellfish intake was measured at inclusion by a food frequency questionnaire. Wheeze, eczema, and food allergy were evaluated by a questionnaire completed by the mother when the child was 2 years old (n = 1500). Examination of the associations between seafood intake and outcomes took major confounders into account. Complementary sensitivity analyses with multiple imputation enabled us to handle missing data, due mostly to attrition. RESULTS: Moderate maternal pre-parturition fish intake (1 to 4 times a month) was, at borderline significance, associated with a lower risk of wheeze (adjusted OR = 0.69 (0.45-1.05)) before age 2, compared with low intake (< once/month). This result was not, however, consistent: after multiple imputation, the adjusted OR was 0.86 (0.63-1.17). Shellfish intake at least once a month was associated with a higher risk of food allergy before age 2 (adjusted OR = 1.62 (1.11-2.37)) compared to low or no intake (< once/month). Multiple imputation confirmed this association (adjusted OR = 1.52 (1.05-2.21)). CONCLUSIONS: This study suggests that maternal pre-parturition shellfish consumption may increase the risk of food allergy. Further large-scale epidemiologic studies are needed to corroborate these results, identify the contaminants or components of shellfish responsible for the effects observed, determine the persistence of the associations seen at age 2, and investigate potential associations with health effects observable at later ages, such as allergic asthma.
ISSN: 1476-069X

Droits : info:eu-repo/semantics/OpenAccess
inserm-00926282
http://www.hal.inserm.fr/inserm-00926282
http://www.hal.inserm.fr/inserm-00926282/document
http://www.hal.inserm.fr/inserm-00926282/file/1476-069X-12-102.pdf
DOI : 10.1186/1476-069X-12-102

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Despite many studies, our understanding of silica precipitation from natural waters remains limited, in particular for geothermal waters. Here we present a detailed study on the kinetics of silica polymerization as a function of fluid temperature and pH using high-temperature (250-260 °C) seawater-derived geothermal fluids as those discharged from the Bouillante geothermal site.We monitored the on-site decrease in monomeric silica concentration(initial SiO2 concentration of about 600 mg/l)with time using the molybdenum blue spectrophotometric method on samples of separated water collected from the high-pressure separator at 167 °C and cooled to 25, 50, 75, and 90 °C and for pH values ranging from 5 to 8. During all these experiments, only silica polymerization was observed, with the formation of colloidal particles in suspension in the solutions. No scaling of amorphous silica was formed. The collected data were after modeled in order to determine the useful kinetic parameters for predicting and preventing amorphous silica precipitation in the production wells during fluid exploitation in the specific context of Bouillante. Results under the investigated experimental conditions show that the kinetics of silica precipitation is affected more strongly by pH than by temperature change. The reaction in the acidic Bouillante solution begins with a transition period that significantly decreases the kinetics of silica polymerization. Modeling the experimental data indicates that the silica polymerization up to the state of equilibrium is characterized by a 2nd-order kinetic law relative to dissolved silica; this could indicate that the polymerization is controlled mainly by the formation of dimers. However, the first hour of the experiments is better characterized by a 4th-order kinetic law, suggesting more complex polymerization reactions in the initial stage with the formation of nanocolloidal particles containing 3 to 4 monomers. In both cases, the corresponding kinetics rate constant k is linearly dependent on pH for pH between 5 and 7. The activation energy Ea for the overall reaction, calculated using the Arrhenius equation under the considered pH and temperature conditions, ranges between 41±9.8 and 54±9.6 kJ/mol. To complete this work, the colloid particles formed at the end of the kinetics experiments were extracted and analyzed by SEM and TEM microscopy, X-ray Diffraction and the BET method. Results show that the size of the colloids increase and their specific surface decrease with increasing pH and are thus dependent on pH. Globally, our work provides a reliable database for understanding silica polymerization kinetics in natural geothermal brines or geologic waters characterized by a near neutral pH and moderate dissolved silica concentrations.
ISSN: 0009-2541

hal-01403092
https://hal-brgm.archives-ouvertes.fr/hal-01403092
DOI : 10.1016/j.chemgeo.2016.08.031

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The formation age of the Siberian cratonic mantle is not well established as yet. Re–Os data on various mantle-derived materials have shown that it contains Archaean components, but the reported Re-depletion ages show a broad variation range (3.4 to 1 Ga) and are commonly ≤ 2 Ga for peridotite xenoliths. We report Hf and Nd isotope data for cpx and garnet separated from nine refractory spinel and garnet peridotite xenoliths from the Udachnaya kimberlite. The cpx from low-opx spinel harzburgites show extremely high εHf values, from + 607 to + 2084, which testify to long-term evolution of these rocks with high Lu/Hf ratios, consistent with their residual origin and near absence of post-melting enrichments in the Lu–Hf system. Such high εHf values are unusual for cpx from other cratonic peridotites and are higher than those reported for depleted cpx in off-cratonic peridotites. The clinopyroxenes from low-opx spinel harzburgites yield Hf model ages from 1.9 to 1.7 Ga while the cpx from high-opx spinel harzburgites yield Hf model ages from 3.0 to 1.9 Ga. When plotted together, they define a Lu/Hf isochron with an age of 1.80 Ga, which we consider as a robust estimate of the formation age (melt extraction event) because it is obtained on residual rocks that show no evidence for HREE and Hf enrichments and because the model ages for three out of four individual samples are similar to each other. The cpx have high εNd of + 94 to + 123, which are inconsistent with their low Sm/NdPM of < 1 and yield no meaningful age estimates. The consistently high, positive εNd in these cpxs can be interpreted in terms of long-term evolution of refractory peridotites with high Sm/Nd, followed by relatively recent LREE enrichments.We infer that a significant part of the lithospheric mantle in the central Siberian craton may have been formed during a major event (or a series of events) at around 1.8 Ga. Older ages reported for the central Siberian craton may refer to less common materials from cratonic or other domains formed in the Archaean that were later incorporated into the cratonic roots. The transition from the “Archaean” to “modern” tectonic regimes in Siberia and possibly elsewhere may have taken place at 1.8–1.9 Ga rather than at ~ 2.5 Ga, i.e. in the second half of the Paleoproterozoic rather than at the Archaean–Proterozoic boundary, at which time the asthenospheric mantle became generally too cold to experience high-degree melting on a large scale. The ~ 1.8 Ga formation age of the Siberian cratonic mantle is coeval with that for a major part of the ancient continental crust in the central Siberian craton. The temporal crust–mantle links may be explained either by the generation of the initial source materials for continental crust in the same melting event that formed the residual peridotites or, alternatively, by subduction and melting of pre-existing proto-lithosphere destabilized by a major mantle upwelling that formed the residual mantle.
ISSN: 0009-2541

hal-01115519
https://hal.archives-ouvertes.fr/hal-01115519
DOI : 10.1016/j.chemgeo.2014.10.018

Éditeur(s) : HAL CCSD Elsevier
Résumé : The Gulf of Aigues-Mortes (NW Mediterranean Sea) is a midshelf zone whose scale is an intermediate between the nearshore scale (0–10 m depth) and the coastal scale (including the whole continental shelf). Its hydrodynamics is investigated for the first time. ADCP, CTD and thermosalinograph data were collected during three short cruises (HYGAM; March 6–7, 20–21, April 5–6, 2005). They were scheduled approximately every 15 days to sample the gulf circulation under different weather conditions. Moreover, the cruise data were used to validate the Symphonie model, a 3D primitive equations circulation model. The circulation features displayed by in situ data were well reproduced by Symphonie. A downscaling modelling approach was implemented, the largest scale being obtained by the replay of the MFSTEP regional model of the North-Western Mediterranean Sea. The analysis, closely coupling in situ measurements and model results, provides information that would not have been obtained using data separately. The great variability of the oceanic circulation at this scale is well evidenced. Winds are the main forces, not only locally but also at a larger scale. North winds generate coherent structures interacting with the general Mediterranean circulation. The explanation of the induced currents is then not straightforward, some of them being, for example, northward. South and southeast winds reinforce the sloping surface, the latter allowing the geostrophic equilibrium with longshore currents. This study, focused on the end of winter 2004–2005, also enhances the heat fluxes from offshore to nearshore, as well as the initiation of shelf dense waters. The knowledge of the midshelf oceanic circulation is then applied to run a numerical experiment which describes both the dispersion of a fictive contaminant from a point S (at the centre of the GAM), and evaluates the risk of contamination of the beaches along the GAM shores.
ISSN: 0278-4343

hal-00196620
https://hal.archives-ouvertes.fr/hal-00196620
DOI : 10.1016/j.csr.2007.06.006

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Reef positions record the interaction between eustasy and tectonics, and have been used worldwide to characterize vertical deformations of upper-plates at different time-scales and constrain the seismic behavior of megathrusts. Along the Lesser Antilles volcanic arc, high-resolution marine geophysical data were collected on the 2–20 km wide eastern Martinique reef platform to reconstruct its stratigraphic and morphologic history, and understand the influence of local normal faulting, volcanism and plate-scale subduction processes on Holocene and Late Pleistocene reef development. The subsiding Martinique platform's stratigraphy is composed of multiple superimposed sea-level highstand deposits separated by subaerial exposure surfaces of sea-level low stands. The carbonate platform consists of two laterally-extensive carbonate units (unit U2 overlying unit U3) that extend to the platform edge to a depth of − 95 m MSL (mean sea level), and form two morphologic terraces, M2 and M3 respectively. The landward portion of unit U2 is partially overlain between 0 and − 60 m MSL by the living reef tract U1. The current reef is composed of a landward fringing reef, a lagoon and a seaward barrier reef, the latter forming a double-bank barrier around the Caravelle Peninsula. In near-shore multi-channel seismic profiles, a distinct reflector at ~− 35 m MSL, probably a subaerial exposure surface E1, separates the reef sequence formed during the last transgression from a Pleistocene fossil reef tract forming unit U2. Offshore of Mount Pelée volcano (Late Pleistocene), the Holocene reef did not develop above unit U2, whose upper surface is incised by channels and apparent sinkholes. During the Holocene transgression, the possibility of excessive turbidity due to volcanic activity may have inhibited reef development in this area. The un-dated unit U2 probably developed 120–130 ka ago during the last interglacial (MIS 5.5) + 6 m MSL highstand as thick, extensive reefs deposited all along the Lesser Antilles arc. Due to subsidence, MIS 5.5 reefs are not represented by onshore facies, except along the southern Sainte Anne Peninsula where normal faulting and uplift balances island-scale subsidence. Based on unit U2's present elevation and assuming an MIS 5.5 age and + 6 m MSL sea level, Martinique has subsided at maximum 0.3 m/ky, likely due to subduction processes that question the coupling state of the megathrust.
ISSN: 0025-3227

hal-01307036
https://hal.archives-ouvertes.fr/hal-01307036
DOI : 10.1016/j.margeo.2015.08.001

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
A laser ablation ICP-MS U-Pb age of 17.84 +/- 0.12 Ma (late Burdigalian) was obtained from monazites separated from a leucocratic diatexite collected in close proximity to a small peridotite massif incorporated into the lower crustal sequence of the Edough Massif (north-eastern Algeria), a southern segment of the peri-Mediterranean Alpine Belt. Monazites extracted from a neighbouring deformed leucogranite intruding early Paleozoic phyllites yield a consistent age of 17.4 +/- 1.3 Ma. Zircons occurring in the same leucogranite, with magmatic characteristics, have an age of 308 +/- 7 Ma interpreted as dating magmatic crystallisation of the leucogranite and reflecting partial melting during the Hercynian orogeny. Low Th/U domains (Th/U<0.10) from the same grains substantiate recrystallisation during a younger metamorphic event whose upper age limit is 286 +/- 11 Ma. These results emphasize the polycyclic evolution of basement rocks preserved in the crystalline units of the western Mediterranean and indicate that part of their metamorphic features were inherited from older, Hercynian, events. Taken together with published Ar-Ar dates, the late Burdigalian age of monazites indicates a rapid cooling rate of c. 370 degrees C/Ma and is regarded as closely approximating the emplacement of the peridotites into the Hercynian basement. The monazite ages are significantly younger than those recorded for orogenic peridotites from the Betic-Rif oroctine and for the timing of lithospheric extension forming the Alboran sea. It is also younger than rifting and back-arc extension opening the Liguro-Provencal basin. The late Burdigalian age is interpreted as dating the incipient rifting event that opened the Algerian basin, which is consequently not a continuation of the Liguro-Provencal basin. At the scale of the western Mediterranean, these observations concur with current models supporting slab roll-back and an eastwards migration of extension in the western Mediterranean, but suggest that the Algerian basin opened as a result of torsion and stretching of the Thethyan slab due to its steepening under the Alboran microplate.
ISSN: 0009-2541

hal-00424511
https://hal.archives-ouvertes.fr/hal-00424511
DOI : 10.1016/j.chemgeo.2008.11.016

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Coastal aquifers often display seawater intrusion resulting in the formation of a salty water wedge progressing inland. This study investigates the mass transfers in the mixing zone at the freshwater-seawater interface where the water is out of equilibrium with the rock-forming carbonates. Investigations were conducted in two boreholes, separated by 5 m, at the Ses Sitjoles test site (Mallorca Island, Spain) where repeated electrical conductivity logs of the formation and the saturating fluid, as well as regular pore-water sampling and permanent downhole multi-parameter monitoring of the water were performed over a period of 9 a. In the mixing zone, the significant acidification, the calcite saturation index profile and the Ca concentration profile cannot be explained by conservative mixing nor by dissolution-precipitation reactions only. Conversely, the analysis of organic C content and of the distinctly different time-resolved pH profiles measured in the two boreholes suggests the development of perennial biomass that triggers calcite dissolution. Moreover, the presence of biomass seems to be correlated with the permeability and vertical connectivity at the meter-scale. It is speculated that the mechanism could be self-activated because the microbiological activity induces calcite dissolution and tends to increase porosity and permeability that favors biomass development.
ISSN: 0883-2927

hal-00937665
https://hal.archives-ouvertes.fr/hal-00937665
DOI : 10.1016/j.apgeochem.2013.09.011

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In this work we perform a statistical analysis of global solar radiation measured at two sites, Petit Canal and Pointe a Pitre, 38 km distant from, Guadeloupe, French West Indies. We have established a correlation model based on the coefficient of variation assuming a time scale separation. The coefficient of variation is calculated on 10 min interval with data measured at 1 Hz. This analysis highlights the dynamic correlation that can occur between measurements from two different sites with a time step of 1 s. From these results, knowing the coefficient of variation on a site, we have established a new correlation model on this parameter for another site. A diagram linking the standard deviation for the studied sites, for a given coefficient of variation is proposed for correlated and non-correlated cases. Moreover this analysis evidences the existence of a threshold time under which there is no significant correlation. The methodology and the model can be applied to any other sites to establish diagrams of the coefficient of variation.This model can be useful in choosing new sites of PV production in establishing correlation from on site to another
ISSN: 0960-1481

hal-01528078
https://hal.archives-ouvertes.fr/hal-01528078
DOI : 10.1016/j.renene.2015.10.049

Éditeur(s) : HAL CCSD Public Library of Science
Résumé : International audience
The Black Rat (Rattus rattus) spread out of Asia to become one of the world's worst agricultural and urban pests, and a reservoir or vector of numerous zoonotic diseases, including the devastating plague. Despite the global scale and inestimable cost of their impacts on both human livelihoods and natural ecosystems, little is known of the global genetic diversity of Black Rats, the timing and directions of their historical dispersals, and the risks associated with contemporary movements. We surveyed mitochondrial DNA of Black Rats collected across their global range as a first step towards obtaining an historical genetic perspective on this socioeconomically important group of rodents. We found a strong phylogeographic pattern with well-differentiated lineages of Black Rats native to South Asia, the Himalayan region, southern Indochina, and northern Indochina to East Asia, and a diversification that probably commenced in the early Middle Pleistocene. We also identified two other currently recognised species of Rattus as potential derivatives of a paraphyletic R.rattus. Three of the four phylogenetic lineage units within R. rattus show clear genetic signatures of major population expansion in prehistoric times, and the distribution of particular haplogroups mirrors archaeologically and historically documented patterns of human dispersal and trade. Commensalism clearly arose multiple times in R. Rattus and in widely separated geographic regions, and this may account for apparent regionalism in their associated pathogens. Our findings represent an important step towards deeper understanding the complex and influential relationship that has developed between Black Rats and humans, and invite a thorough re-examination of host-pathogen associations among Black Rats.
PLoS ONE

ird-00714383
http://hal.ird.fr/ird-00714383
http://hal.ird.fr/ird-00714383/document
DOI : 10.1371/journal.pone.0026357
IRD : fdi:010055548

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : International audience
Both flow field heterogeneity and mass transfer between mobile and immobile domains have been studied separately for explaining observed anomalous transport. Here we investigate non-Fickian transport using high-resolution 3-D X-ray microtomographic images of Berea sandstone containing microporous cement with pore size below the setup resolution. Transport is computed for a set of representative elementary volumes and results from advection and diffusion in the resolved macroporosity (mobile domain) and diffusion in the microporous phase (immobile domain) where the effective diffusion coefficient is calculated from the measured local porosity using a phenomenological model that includes a porosity threshold ( inline image) below which diffusion is null and the exponent n that characterizes tortuosity-porosity power-law relationship. We show that both flow field heterogeneity and microporosity trigger anomalous transport. Breakthrough curve (BTC) tailing is positively correlated to microporosity volume and mobile-immobile interface area. The sensitivity analysis showed that the BTC tailing increases with the value of inline image, due to the increase of the diffusion path tortuosity until the volume of the microporosity becomes negligible. Furthermore, increasing the value of n leads to an increase in the standard deviation of the distribution of effective diffusion coefficients, which in turn results in an increase of the BTC tailing. Finally, we propose a continuous time random walk upscaled model where the transition time is the sum of independently distributed random variables characterized by specific distributions. It allows modeling a 1-D equivalent macroscopic transport honoring both the control of the flow field heterogeneity and the multirate mass transfer between mobile and immobile domains.
ISSN: 0043-1397

hal-01278285
https://hal.archives-ouvertes.fr/hal-01278285
DOI : 10.1002/2015WR017645

Éditeur(s) : HAL CCSD AGU and the Geochemical Society
Résumé : International audience
Analysis of the microstructures in the km-scale mantle shear zone that separates the northern and the central parts of the Lanzo peridotite massif provides evidence of an evolution in time and space of deformation processes accommodating shearing in the shallow mantle within an extensional setting. This shear zone displays an asymmetric distribution of deformation facies. From south to north, gradual reorientation of the foliation of coarse porphyroclastic plagioclase-bearing peridotites is followed by development of protomylonites, mylonites, and mm-scale ultramylonite bands. A sharp grain size gradient marks the northern boundary. Early deformation under near-solidus conditions in the south is recorded by preservation of weakly deformed interstitial plagioclase and almost random clinopyroxene and plagioclase crystal orientations. Feedback between deformation and melt transport probably led to melt focusing and strain weakening in the shear zone. Overprint of melt-rock reaction microstructures by solid-state deformation and decrease in recrystallized grain size in the protomylonites and mylonites indicate continued deformation under decreasing temperature. Less enriched peridotite compositions and absence of ultramafic dykes or widespread melt-impregnation microstructures north of the shear zone and clinopyroxene and amphibole enrichment in the mylonites and ultramylonites suggest that the shear zone acted as both a thermal barrier and a high-permeability channel for late crystallizing fluids. These observations, together with chemical data indicating faster cooling of central Lanzo relative to the northern body, corroborate that this shear zone is a mantle detachment fault. All deformation facies have crystal preferred orientations consistent with deformation by dislocation creep with dominant activation of the (010)[100] and (100)[001] systems in olivine and orthopyroxene, respectively. Dynamic recrystallization produces dispersion of olivine CPO but not a change of dominant deformation mechanism. Evidence for activation of grain boundary sliding is limited to mm-scale ultramylonite bands, where solid-state reactions produced very fine grained polymineralic aggregates. Except for these latest stages of deformation, strain localization does not result from the microstructural evolution; the grain size decrease is a consequence of the need to deform a rock volume whose strength continuously increases because of decreasing temperature conditions. Strain localization in the intermediate levels thus essentially results from the more localizing behavior of both the deep, partially molten, and shallow parts of this extensional shear zone distribution.
ISSN: 1525-2027

hal-00644844
https://hal.archives-ouvertes.fr/hal-00644844
DOI : 10.1029/2011GC003627

Éditeur(s) : HAL CCSD
Résumé : National audience
Crustal-scale models for the Pyrenees based on ECORS reflection profileshave around 20 years now. In recent years, new understandingswere gained on the reconstruction to the preorogenic times, namelya scenario of extreme crustal attenuation and mantle exhumation ; inturn, this has implications on the interpretation of the present-day structure,as new models for the chain must consider feedbacks between themid-Cretaceous hyperextension and the Pyrenean inversion. On the WcentralPyrenean traverse, the southern part comprises 3 S-vergent basementthrust units, the Lakora, Gavarnie and Guarga units, flanked by thedetached cover of the Jaca piggyback basin and the Ebro basin, wherethe Mesozoic is thin and Late Cretaceous-Tertiary synorogenic carbonateand detrital sequences record a southward depocenter migration.To the N, the Chaînons Béarnais belt (CB) is a system of Jurassic to LowerCretaceous carbonate anticline ridges separated by synclines withthick Albian-Cenomanian flysch, covered to the north by Upper Cretaceousflysch sequences. The CB is thrust southwards together with theLakora thrust unit and northwards onto the Aquitaine basin. CB foldinglargely results from the rising and squeezing of diapirs initiated duringthe Jurassic-Early Cretaceous extension. Pieces of crust and mantle liftedin the diapirs attest that the CB derive from a Cretaceous domainof hyperextended continental crust and exhumed mantle. Moho reflectionsin the ECORS-Arzaq profile constrain the present deep structure.Restoration leads to a Mesozoic cover detachment over the N-Iberianand S-European margins. Inversion began by subduction of the exhumedmantle and folding and pop-up thrusting of the CB cover onto themargins. From the mid-late Eocene onwards, continental collision wasaccommodated by wedging and thrust stacking in the Iberian crust, involvingthe piggyback formation of S-vergent basement thrusts in theupper crust, and the northward subduction of the lower crust.
24 ème Réunion des sciences de la Terre 2014
Pau, France

insu-01080831
https://hal-insu.archives-ouvertes.fr/insu-01080831

Éditeur(s) : HAL CCSD Elsevier
Résumé : The correct characterization of the effective reactive transport dynamics is an important issue for modeling reactive transport on the Darcy scale, specifically in situations in which reactions are localized, that is when different reactions occur in different portions of the porous medium. Under such conditions the conventional approach of homogenizing only the porous medium chemistry is not appropriate. We consider here reactive transport in a porous medium that is characterized by mass transfer between a mobile and a distribution of immobile regions. Chemical and physical heterogeneities are reflected by distributions of kinetic reaction rate constants and residence times in the immobile zones. We derive an effective reactive transport equation for the mobile solute that is characterized by non-local physical mass transfer and reaction terms. Specifically, chemical heterogeneity is upscaled in terms of a reactive memory function that integrates both chemical and physical heterogeneity. Mass transfer limitations due to physical heterogeneity yield effective kinetic rate coefficients that can be much smaller than the volumetric average of the local scale coefficients. These results help to explain and quantify the often reported discrepancy between observed field reaction rate constants and the ones obtained under well mixed laboratory conditions. Furthermore, these results indicate that transport under physical and chemical heterogeneity cannot be upscaled separately.
ISSN: 0169-7722

hal-00617674
https://hal.archives-ouvertes.fr/hal-00617674
DOI : 10.1016/j.jconhyd.2010.06.002

Éditeur(s) : HAL CCSD
Résumé : International audience
The Transbaikal region extends over several hundreds of kilometres east of the Baikal Rift System. It is characterized by a number of sub-parallel Mesozoic grabens or half grabens generally filled with late Jurassic to Early Cretaceous clastic sediments interbedded with coal layers (1). Similar basins occur on an even larger area spanning from the Transbaikal region down to Korea implying a large-scale extensional process affecting most of the Amuria plate during the Mesozoic. In the Transbaikal region, the normal faults controlling the edges of the Mesozoic basins are generally superimposed to Palaeozoic ductile shear zones implying a strong localisation of the extensional deformation on inherited structures. Recent studies, associated to our own fieldwork demonstrated that some of the faults were again activated (2), still as extensional faults, during the Tertiary or Quaternary, and that some of them are presently active. The closure of the Mongol-Okhotsk ocean separating the Siberian plate from the Amurian block during the Mesozoic corresponds to a major event in the growth process of the East Asian continent. The oceanic suture zone is situated on the southern edge of the Transbaikal region and its roughly SW-NE direction is parallel to the basins (3). The timing of the closure of the Mongol-Okhotsk ocean is still highly debated: while sedimentological and tectonic data suggest that the oceanic closure and the following collision occurred in early Middle Jurassic (4), paleomagnetic studies advocate for a Early Cretaceous collision (5). Furthermore, several other questions remain on the localization, the size and the fate of the relief that most probably formed during the collision between the Amuria block and the Siberian craton. In order to answer those questions we used low temperature thermochronology data associated to tectonic, sedimentology and palinology to investigate the evolution of the Transbaikal grabens from Mesozoic to Present. Tectonic and thermochronology data provide evidences of exhumation and erosion along the eastern edge of the Siberian craton during the Middle Jurassic as well as a potential continuum of deformation between the Mesozoic extension and the initiation of the Baikal Rift System (6). Sedimentology and palinology reveals that the sediments deposited in the Transbaikal basin did not registered large-scale compressive deformation during or after their Late Jurassic - Early Cretaceous deposition and that they do not correspond to the dismantling of a strong compressive relief.
Geophysical Research Abstracts
Vienne, Austria

insu-00810487
https://hal-insu.archives-ouvertes.fr/insu-00810487

Éditeur(s) : HAL CCSD Springer Verlag (Germany)
Résumé : International audience
The Michaelis-Menten enzymatic reaction is sufficient to perceive many subtleties of network modeling, including the concentration and time scales separations, the formal equivalence between bulk phase and single-molecule approaches, or the relationships between single-cycle transient probabilities and steady state rates. Twelve methods proposed by different authors and yielding the same famous Michaelis-Menten equation, are selected here to illustrate the kinetic and probabilistic use of rate constants and to review basic techniques for handling them. Finally, the general rate of an ordered multistep reaction, of which the Michaelis-Menten reaction is a particular case, is deduced from a Markovian approach.
ISSN: 0259-9791

hal-00920806
https://hal-univ-rennes1.archives-ouvertes.fr/hal-00920806
https://hal-univ-rennes1.archives-ouvertes.fr/hal-00920806v2/document
https://hal-univ-rennes1.archives-ouvertes.fr/hal-00920806/file/12MM.pdf
ARXIV : 1312.5468

Éditeur(s) : HAL CCSD
Résumé : 1 p.
International audience
The 12th May 2008 Wenchuan earthquake in the Longmen Shan occurred on a large thrust fault largely inherited from an Indosinian structure itself probably controlled by an older structural heritage of the South China block continental margin. Within the whole northeast Tibet region, such a structural inheritance has had a major impact on the Tertiary deformation. It appears of primary importance to assess the pre-Tertiary tectonic evolution of the main blocks involved to understand the actual deformation in the eastern edge of Tibet. Over the past decades, the Proterozoic to Cenozoic tectonic, metamorphic and geochronologic history of the Longmen Shan and Songpan Garzê area have been largely studied. We present a synthesis of the tectonic evolution of the Songpan Garzê fold and thrust belt from Triassic to present. The Songpan-Garzê belt was formed during closure of a wide oceanic basin ?lled with a thick (5 to 15 km) sequence of Triassic ?yschoid sediments. Closure of the basin due to Triassic subduction involved strong shortening, intense folding and faulting of the Triassic series. A large-scale décollement, that presently outcrops along the eastern boundary of the belt (Danba area), allowed the growth of a wide and thick accretionary wedge. It develops in the Paleozoic and Triassic series and separates the accretionary prism from an autochthonous crystalline basement which shares many similarities with the basement of the Yangtze Craton (0.7-0.9 Ga). To the north and northwest, below the thickened Triassic series of the belt, the composition (oceanic or continental) of the basement remains unknown. During the Indosinian orogeny the emplacement of orogenic granites (220 - 150 Ma) was associated to crustal thickening. The isotopic composition of granitoids shows that their magma source were predominantly derived from melting of the proterozoic basement with varying degrees of sedimentary material and negligible mantle source contribution. In the Danba area, the décollement outcrops in a large tertiary antiform with a NNW-SSE axis. It has been exhumed too in the hanging wall of the NE-SW faults of the Tertiary Longmen-Shan belt that marks the present day transition from the Tibetan plateau to the Sichuan basin. These faults have episodically absorbed signi?cant shortening since the Late Triassic. The amount and precise timing of post-triassic deformation are dif?cult to constrain especially because of the dif?culty to isolate the tertiary thermochronological signal from the protracted late Triassic - Cretaceous thermal history. Nonetheless it is generally accepted that Jurassic - Cretaceous tectonism did not modi?ed the general Triassic architecture of eastern Tibet contrarily to the Tertiary deformation. The long-term cooling histories obtained on Mesozoic granites and on the metamorphic series of the Danba dome are very similar showing a very slow and regular cooling during Jurassic andCretaceous, con?rming the absence of major tectonic event between c.a. 150 and 30 Ma. Low temperature thermochronology data indicate that ?nal exhumation and cooling occurred in theTertiary with an acceleration between 10 and 5 Ma along the major tectonic structures. Within the Longmen Shan range, a total denudation of 7 to 10 km is estimated for the late Cenozoic period. Similar amounts of late Tertiary denudation have been estimated along an east-west section across the Xianshuihe fault
Asian climate and tectonics seminar
Utrecht, Netherlands

insu-00610298
https://hal-insu.archives-ouvertes.fr/insu-00610298
DOI : 10.1016/j.jseaes.2010.03.008

Éditeur(s) : HAL CCSD Springer Verlag (Germany)
Résumé : International audience
The Michaelis-Menten enzymatic reaction is sufficient to perceive many subtleties of network modeling, including the concentration and time scales separations, the formal equivalence between bulk phase and single-molecule approaches, or the relationships between single-cycle transient probabilities and steady state rates. Seven methods proposed by different authors and yielding the same famous Michaelis-Menten equation, are selected here to illustrate the kinetic and probabilistic use of rate constants and to review basic techniques for handling them. Finally, the general rate of an ordered multistep reaction, of which the Michaelis-Menten reaction is a particular case, is deduced from a Markovian approach.
Journal of Mathematical Chemistry

hal-00920806
https://hal-univ-rennes1.archives-ouvertes.fr/hal-00920806
https://hal-univ-rennes1.archives-ouvertes.fr/hal-00920806/document
ARXIV : 1312.5468
DOI : 10.1007/s10910-013-0237-5