Éditeur(s) : Gauthier-Villars
Résumé : The variability of ''yellow substance'' in waters of the Skagerrak and the Kattegat was studied during the international Skagex programme in 1990 and 1991. Data on attenuation of light and fluorescence of dissolved organic matter (DOM) in sea water were collected with a spectral transmissiometer and a submersible fluorometer within a depth range of 0-250 m at several stations. More than fifty-fold variations of fluorescence intensity over space and time were due to the combined action of different sources of DOM in the straits. The surface maximum of fluorescing DOM, related to river outflow, was spreading from Oslo fjord to the central Skagerrak in late spring. This maximum may be ecologically important because it diminishes shortwave PAR. In the autumn the brightest DOM fluorescence was found in the Kattegat and along the Norwegian coast in accordance with earlier studies. The local minima of DOM fluorescence are associated with the Jutland current. Both the instability of the current and a ten-fold difference in DOM content between deep layers of the Skagerrak and Kattegat resulted in strong synoptic variability of fluorescence in the transitional area between the straits. Seasonal and synoptic variabilities of ''yellow substance'' were minimal in the southern Kattegat. The vertical gradients of DOM fluorescence were mostly negative at the depth of the thermocline of the open Skagerrak in spring, reaching values of 40-50 % m-1. Fine structure and complex shape were inherent to fluorescence profiles from areas of intensive water mixing. DOM fluorescence closely covaried with attenuation of UV light: the correlation coefficient was + 0.9 for wavelength w <= 350 nm regardless of season. The inverse dependence between wavelength derivative and magnitude of UV attenuation in the straits did not change with season. DOM fluorescence and water salinity were negatively correlated at depths of 25-50 m but they varied independently in the upper 10 m. No significant correlation between fluorescence and nitrates has been found. Estimates of correlation with phosphates ranged from 0.7 to 0.8. In general, the changes of fluorescence were due to variations of DOM content in sea water but not to variability of DOM composition or state. The properties of DOM fluorescence in the Skagerrak-Kattegat area make it a useful natural tracer of water movements suitable for active remote sensing with airborne lidar.
Oceanologica Acta (0399-1784) (Gauthier-Villars), 1993 , Vol. 16 , N. 2 , P. 115-125

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/00099/21041/18667.pdf
http://archimer.ifremer.fr/doc/00099/21041/

Éditeur(s) : Gauthier-Villars
Résumé : An experimental techniques to estimate the influence of dissolved organic matter (DOM) on remote sensing of chlorophyll in water has been developed, based on the relationship between fluorescence and absorption of light by a substance. The profiles of fluorescence, chlorophyll content in sea water and estimates of light attenuation in water samples were used in the paper. These data have permitted to calculate the regressions linking fluorescence and light absorption at 450 nm by chlorophyll (ABC450) and by DOM (ABD450). The remote sensing needs no correction for DOM if M450 = 100* (ABC450/ABD450) much greater than 100. This technique has been applied to data collected during the international Skagex field experiment in the straits of Skagerrak and Kattegat in spring and autumn of 1990. It was found that M450 <= 100 everywhere in the subsurface layer. Unfavorable conditions for remote sensing of chlorophyll prevailed in the straits because of the uptake of DOM-rich water from the continent and the accumulation of phytoplankton in deeper layers. These and another processes can increase relative content of colored DOM even in waters of open ocean.
Oceanologica Acta (0399-1784) (Gauthier-Villars), 1992 , Vol. 15 , N. 3 , P. 255-259

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/00100/21159/18778.pdf
http://archimer.ifremer.fr/doc/00100/21159/

Éditeur(s) : Elsevier
Résumé : In biological modelling of the coastal phytoplankton dynamics, the light attenuation coefficient is often expressed as a function of the concentrations of chlorophyll and mineral suspended particulate matter (SPM). In order to estimate the relationship between these parameters over the continental shelf of the northern Bay of Biscay, a set of in situ data has been gathered for the period 1998-2003 when SeaWiFS imagery is available. These data comprise surface measurements of the concentrations of total SPM, chlorophyll, and irradiance profiles from which is derived the attenuation coefficient of the photosynthetically available radiation, K-PAR. The performance of the IFREMER look-up table used to retrieve the chlorophyll concentration from the SeaWiFS radiance is evaluated on this new set of data. The quality of the estimated chlorophyll concentration is assessed from a comparison of the variograms of the in situ and satellite-derived chlorophyll concentrations. Once the chlorophyll concentration is determined, the non living SPM, which is defined as the SPM not related to the dead or alive endogenous phytoplankton, is estimated from the radiance at 555 nm by inverting a semi-analytic model. This method provides realistic estimations of concentrations of chlorophyll and SPM over the continental shelf all over the year. Finally, a relationship, based on non living SPM and chlorophyll, is proposed to estimate K-PAR on the continental shelf of the Bay of Biscay. The same formula is applied to non living SPM and chlorophyll concentrations, observed in situ or derived from SeaWiFS radiance.
Remote Sensing of Environment (0034-4257) (Elsevier), 2005-03 , Vol. 95 , N. 1 , P. 29-46

Droits : 2004 Elsevier Inc. All rights reserved
http://archimer.ifremer.fr/doc/2005/publication-1172.pdf
DOI:10.1016/j.rse.2004.11.007
http://archimer.ifremer.fr/doc/00000/1172/

Éditeur(s) : HAL CCSD IOP Publishing
Résumé : The use of electron probe microanalysis (EPMA) at low voltage allows improvements in the lateral resolution and surface sensitivity of the technique down to the sub-micrometre scale, and it is also useful in minimizing X-ray absorption (for the analysis of ultra-light elements), charging effects and secondary fluorescence. However, EPMA at low voltage is accompanied by a number of problems which may affect the accuracy of quantitative results. A large number of these problems arise from the need of using low-energy X-ray lines such as L- and M-lines, which have low fluorescence yields, large uncertainties in the mass attenuation coefficients, and are affected by several spectroscopic difficulties (e.g., peak shifts and overlaps). Other factors that play an important role at low voltage are carbon contamination, surface oxidation, the quality of sample polishing, the influence of a conductive coating and the limitations of matrix correction procedures. In this paper, we illustrate the capabilities of EPMA at low voltage and we examine in detail the different sources of uncertainty that may affect the accuracy of quantitative results.
ISSN: 1757-8981

hal-00767564
https://hal.archives-ouvertes.fr/hal-00767564
DOI : 10.1088/1757-899X/32/1/012016