Éditeur(s) : HAL CCSD Geological Society of America
Résumé : If the net flux to the island arc crust is primitive arc basalt, the evolved composition of most arc magmas entails the formation of complementary thick ultramafic keels at the root of the island arc crust. Dunite, wehrlite, and Cr-rich pyroxenite from the Jijal complex, constituting the Moho transition zone of the Kohistan paleo–island arc (northern Pakistan), are often mentioned as an example of high-pressure cumulates formed by intracrustal fractionation of mantle-derived melts, which were later extracted to form the overlying mafic crust. Here we show that calculated liquids for Jijal pyroxenites-wehrlites are strongly rare earth element (REE) depleted and display flat or convex-upward REE patterns. These patterns are typical of boninites and are therefore unlike those of the overlying mafic crust that have higher REE concentrations and are derived from light rare earth element (LREE)–enriched melts similar to island arc basalt. This observation, along with the lower 208Pb/204Pb and 206Pb/204Pb ratios of Jijal pyroxenites-wehrlites relative to gabbros, rejects the hypothesis that gabbros and ultramafic rocks derive from a common melt via crystal fractionation. In the 208Pb/204Pb versus 206Pb/204Pb diagram, ultramafic rocks and gabbros lie on the same positive correlation, suggesting that their sources share a common enriched mantle 2 (EM2) signature but with a major depleted component contribution for the ultramafic rocks. These data are consistent with a scenario whereby the Jijal ultramafic section represents a Moho transition zone formed via melt-rock reaction between subarc mantle and incoming melt isotopically akin to Jijal gabbroic rocks. The lack in the Kohistan arc of cogenetic ultramafic cumulates complementary to the evolved mafic plutonic rocks implies either (1) that a substantial volume of such ultramafic cumulates was delaminated or torn out by subcrustal mantle flow from the base of the arc crust in extraordinarily short time scales (0.10–0.35 cm/yr), or (2) that the net flux to the Kohistan arc crust was more evolved than primitive arc basalt.
ISSN: 0091-7613

hal-00406688
https://hal.archives-ouvertes.fr/hal-00406688
DOI : 10.1130/G23675A.1

Éditeur(s) : HAL CCSD Elsevier Masson
Résumé : The Beni Bousera peridotite contains a diversity of pyroxenite layers. Several studies have postulated that at least some of them represent elongated strips of oceanic lithosphere recycled in the convective mantle. Some pyroxenites were, however, ascribed to igneous crystal segregation or melt–rock reactions. To further constrain the origin of these rocks, we collected 171 samples throughout the massif and examined their variability in relation with the tectono-metamorphic domains. A major finding is that all facies showing clear evidence for a crustal origin are concentrated in a narrow corridor of mylonitized peridotites, along the contact with granulitic country rocks. These peculiar facies were most likely incorporated at the mantle–crust boundary during the orogenic events that culminated in the peridotite exhumation. The other pyroxenites derive from a distinct protolith that was ubiquitous in the massif before its exhumation. They were deeply modified by partial melting and melt–rock reactions associated with lithospheric thinning.
ISSN: 1631-0713

hal-01468018
https://hal.archives-ouvertes.fr/hal-01468018
https://hal.archives-ouvertes.fr/hal-01468018/document
https://hal.archives-ouvertes.fr/hal-01468018/file/chetouani.pdf
DOI : 10.1016/j.crte.2016.06.001

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
We report structural evidence of ductile strain localization in mantle pyroxenite from the spinel to plagioclase websterite transition in the Ronda Peridotite (southern Spain). Mapping shows that, in this domain, small-scale shear zones occurring at the base of the lithospheric section are systematically located within thin pyroxenite layers, suggesting that the pyroxenite was locally weaker than the host peridotite. Strain localization is associated with a sudden decrease of grain size and increasing volume fractions of plagioclase and amphibole as a result of a spinel to plagioclase phase transformation reaction during decompression. This reaction also fostered hydrogen extraction ('dehydroxylation') from clinopyroxene producing effective fluid saturation that catalyzed the synkinematic net-transfer reaction. This reaction produced fine-grained olivine and plagioclase, allowing the onset of grain-size sensitive creep and further strain localization in these pyroxenite bands. The strain localization in the pyroxenites is thus explained by their more fertile composition, which allowed earlier onset of the phase transition reactions. Geothermobarometry undertaken on compositionally zoned constituent minerals suggests that this positive feedback between reactions and deformation is associated with cooling from at least 1000°C to 700°C and decompression from 1*0 to 0*5 GPa.
ISSN: 0022-3530

hal-00941293
https://hal.archives-ouvertes.fr/hal-00941293
DOI : 10.1093/petrology/egt039

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We combined microstructural observations and high-resolution crystallographic preferred orientation (CPO) mapping to unravel the active deformation mechanisms in garnet clinopyroxenites, garnet-spinel websterites, and spinel websterites from the Beni Bousera peridotite massif. All pyroxenites display microstructures recording plastic deformation by dislocation creep. Pyroxene CPOs are consistent with dominant slip on [001]{110} in clinopyroxene and on [001](100) or [001](010) in orthopyroxene. Garnet clinopyroxenites have however high recrystallized fractions and finer grain sizes than spinel websterites. Recrystallization mechanisms also differ: subgrain rotation dominates in garnet clinopyroxenites, whereas in spinel websterites nucleation and growth also contribute. Elongated shapes and strong intracrystalline misorientations suggest plastic deformation of garnet, but CPOs are weak. Clinopyroxene porphyroclasts in spinel websterites show deformation twins underlined by orthopyroxene exsolutions. Thermodynamic calculations indicate that garnet clinopyroxenites deformed at 2.0 GPa and 950-1000 °C and spinel pyroxenites at 1.8 GPa and 1100-1150 °C. The lower temperatures may explain the faster work rates implied by the finer grained microstructures in garnet clinopyroxenites. Greater stresses may have also reduced the competence contrast between garnet and pyroxene in the garnet pyroxenites and, at the outcrop scale, lowered the competence contrast between pyroxenites and peridotites, favoring mechanical dispersion of pyroxenites in the cooler lithospheric mantle.
ISSN: 0191-8141

hal-00750322
https://hal.archives-ouvertes.fr/hal-00750322
DOI : 10.1016/j.jsg.2012.02.019

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Geochemical studies of primitive basalts have documented the presence of crustal-derived garnet pyroxenite in their mantle sources. The processes whereby melts with the signature of garnet pyroxenite are produced in the mantle are, however, poorly understood and somewhat controversial. Here we investigate a natural example of the interaction between melts of garnet pyroxenite derived from recycled plagioclase-rich crust and surrounding mantle in the Ronda peridotite massif. Melting of garnet pyroxenite at ∼1.5 GPa generated spinel websterite residues with MREE/HREE fractionation and preserved the positive Eu anomaly of their garnet pyroxenite precursor in whole-rock and clinopyroxene. Reaction of melts from garnet pyroxenite with depleted surrounding peridotite generated secondary fertile spinel lherzolite. These secondary lherzolites differ from common spinel lherzolite from Ronda and elsewhere by their lower-Mg# in clinopyroxene, orthopyroxene and olivine, lower-Cr# in spinel and higher whole-rock Al2O3, CaO, Sm/Yb and FeO⁎ at a given SiO2. Remarkably, secondary spinel lherzolite shows the geochemical signature of ghost plagioclase in the form of positive Eu and Sr anomalies in whole-rock and clinopyroxene, reflecting the transfer of a low-pressure crustal imprint from recycled pyroxenite to hybridized peridotite. Garnet pyroxenite melting and melt-peridotite interaction, as shown in the Ronda massif, may explain how the signature of subducted or delaminated crust is transferred to the mantle and how a garnet pyroxenite component is introduced into the source region of basalts. The efficiency of these processes in conveying the geochemical imprint of crustal-derived garnet pyroxenite to extruded lavas depends on the reactivity of pyroxenite melt with peridotite and the mantle permeability, which may be controlled by prior refertilization reactions similar to those documented in the Ronda massif. Highly fertile heterogeneities produced by pyroxenite-peridotite interaction, such as secondary spinel lherzolite in Ronda, may nucleate magmatic channels that remain chemically isolated from the ambient mantle and act as preferential pathways for melts with the signature of recycled crust.
ISSN: 0012-821X

hal-00814010
https://hal.archives-ouvertes.fr/hal-00814010
DOI : 10.1016/j.epsl.2012.11.047

Éditeur(s) : HAL CCSD American Geophysical Union (AGU) AGU and the Geochemical Society
Résumé : International audience
To study how an impacting plume modifies the mantle lithosphere, we analyzed the microstructures and crystal preferred orientations (CPO) of 29 peridotites and 37 pyroxenites that sample the mantle root of the Ontong Java Plateau (OJP) from 60 to 120 km depth. The peridotites show a strong compositional variability, but homogeneous coarse granular to tabular microstructures, except for those equilibrated at the shallowest and deepest depths, which are porphyroclastic. All peridotites have clear olivine CPO, with dominant fiber-[010] patterns. Low intragranular misorientations and straight grain boundaries in olivine suggest that, above 100 km depth, annealing often followed deformation. Calculated density and P wave velocities of the peridotites decrease weakly with depth. S wave velocities decrease faster, resulting in increasing Vp/Vs ratio with depth. Calculated densities and seismic velocity profiles are consistent with those estimated for normal mantle compositions under a cold oceanic geotherm. Enrichment in pyroxenites may further increase seismic velocities. The calculated seismic properties cannot therefore explain the low S waves velocities predicted by Rayleigh wave tomography and ScS data in the mantle beneath the OJP. Calculated P and S waves anisotropy is variable (2–12%). It is higher on average in the deeper section of the lithosphere. Because olivine has dominantly [010]-fiber CPO patterns, if foliations are horizontal, vertically propagating S waves and Rayleigh waves will sample very weak anisotropy in the OJP mantle lithosphere. Moreover, if the orientation of the lineation changes with depth, the anisotropy-induced contrast in seismic properties might produce an intralithospheric reflector marking the stratification of the OJP mantle root.
ISSN: 1525-2027

hal-01116428
https://hal.archives-ouvertes.fr/hal-01116428
DOI : 10.1002/2014GC005452

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
We show here that the Amalaoulaou complex, in the Pan-African belt of West Africa (Gourma, Mali), corresponds to the lower and middle sections of a Neoproterozoic intra-oceanic arc. This complex records a 90-130-Ma-long evolution of magmatic inputs and differentiation above a subducting oceanic slab. Early c. 793 Ma-old metagabbros crystallised at lower crustal or uppermost mantle depths (25-30 km) and have geochemical characteristic of high-alumina basalts extracted from a depleted mantle source slightly enriched by slab-derived sedimentary components ((La/Sm)(N) < 1; epsilon(Nd): +5.4-6.2; Sr-87/Sr-86: 0.7027-0.7029). In response to crustal thickening, these mafic rocks were recrystallised into garnet-granulites (850-1,000A degrees C; 10-12 kbar) and subject to local dehydration-melting reactions, forming trondhjemititic leucosomes with garnet-clinopyroxene-rutile residues. Slightly after the granulitic event, the arc root was subject to strong HT shearing during partial exhumation (detachment faults/rifting or thrusting), coeval with the emplacement of spinel- and garnet-pyroxenite dykes crystallised from a high-Mg andesitic parental magma. Quartz and hornblende-gabbros (700-660 Ma) with composition typical of hydrous volcanic rocks from mature arcs ((La/Sm)(N): 0.9-1.8; epsilon(Nd): +4.6 to +5.2; Sr-87/Sr-86: 0.7028-0.7031) were subsequently emplaced at mid-arc crust levels (similar to 15 km). Trace element and isotopic data indicate that magmas tapped a depleted mantle source significantly more enriched in oceanic sedimentary components (0.2%). Exhumation occurred either in two stages (700-660 and 623 Ma) or in one stage (623 Ma) with a final exhumation of the arc root along cold P-T path (550A degrees C, 6-9 kbar; epidote-amphibolite and greenschist facies conditions) during the main Pan-African collision event (620-580 Ma). The composition of magmas forming the Cryogenian Amalaoulaou arc and the processes leading to intra-arc differentiation are strikingly comparable to those observed in the deep section of exposed Mezosoic oceanic arcs, namely the Kohistan and Talkeetna complex. This evolution of the Amalaoulaou oceanic arc and its accretion towards the West African craton belong to the life and closure of the Pharusian Ocean that eventually led to the formation of the Greater Gondwana supercontinent, a similar story having occurred on the other side of the Sahara with the Mozambique Ocean.
ISSN: 0010-7999

hal-00639447
https://hal.archives-ouvertes.fr/hal-00639447
DOI : 10.1007/s00410-011-0624-5

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
The Ronda orogenic peridotite (southern Spain) contains a variety of pyroxene-rich rocks ranging from high-pressure garnet granulites and pyroxenites to low-pressure plagioclasespinel websterites. The 'asthenospherized' part of the Ronda peridotite contains abundant layered websterites ('group C' pyroxenites), without significant deformation, that occur as swarms of layers showing gradual modal transitions towards their host peridotites. Previous studies have suggested that these layered pyroxenites formed by the replacement of refractory spinel peridotites. Here, we present a major- and trace-element, and numerical modelling study of a layered outcrop of group C pyroxenite near the locality of Tolox aimed at constraining the origin of these pyroxenites after host peridotites by pervasive pyroxene-producing, refertilization meltrock reactions. Mg-number [=Mg/(Mg + Fe) cationic ratio] numerical modelling shows that decreasing Mg-number with increasing pyroxene proportion, characteristic of Ronda group C pyroxenites, can be accounted for by a melt-consuming reaction resulting in the formation of mildly evolved, relatively low Mg-number melts (similar to 0.65) provided that the melt fraction during reaction and the time-integrated melt/rock ratio are high enough (>0.1 and >1, respectively) to balance Mg-Fe buffering by peridotite minerals. This implies strong melt focusing caused by melt channelling in high-porosity domains resulting from compaction processes in a partial melted lithospheric domain below a solidus isotherm represented by the Ronda peridotite recrystallization front. The chondrite-normalized rare earth element (REE) patterns of group C whole-rocks and clinopyroxenes are convex-upward. Numerical modeling of REE variations in clinopyroxene produced by a pyroxene-forming, melt-consuming reaction results in curved trajectories in the (Ce/Nd)(N) vs (Sm/Yb)(N) diagram (where N indicates chondrite normalized). Based on (Ce/Nd)(N) values, two transient, enriched domains between the light REE (LREE)-depleted composition of the initial peridotite and that of the infiltrated melt may be distinguished in the reaction column: (1) a lower domain characterized by convex-upward REE patterns similar to those observed in Ronda group C pyroxeniteperidotite; (2) an upper domain characterized by melts with strongly LREE-enriched compositions. The latter are probably volatile-rich, small-volume melt fractions residual after the refertilization reactions that generated group C pyroxenites, which migrated throughout the massifincluding the unmelted lithospheric spinel-tectonite domain. The Ronda mantle domains affected by pyroxenite- and dunite- or harzburgite-forming reactions (the 'layered granular' subdomain and 'plagioclase-tectonite' domain) are on average more fertile than the residual, 'coarse granular' subdomain at the recrystallization front. This indicates that refertilization traces the moving boundaries of receding cooling of a thinned and partially melted subcontinental lithosphere. This refertilization process may be widespread during transient thinning and melting of depleted subcontinental lithospheric mantle above upwelling asthenospheric mantle.
ISSN: 0022-3530

hal-00412200
https://hal.archives-ouvertes.fr/hal-00412200
DOI : 10.1093/petrology/egn014

Éditeur(s) : HAL CCSD The Geochemical Society of Japan
Résumé : International audience
The Western Cordillera of Ecuador consists of Cretaceous crustal fragments of oceanic plateaux and superimposed insular arcs, which were accreted to the northwestern South American margin during the Late Cretaceous and Paleocene. Slices of high-grade metabasites, ultramafic rocks, gabbros and basalts, unmetamorphosed radiolarian cherts and scarce garnet-bearing metasediments were randomly exhumed along Miocene to Recent transcurrent faults crosscutting the Western Cordillera. The basalts show geochemical characteristics of oceanic plateau basalts (flat REE patterns, La/Nb = 0.85). The gabbros differ from the basalts in having lower REE levels, positive Eu anomalies, and negative Nb and Ta anomalies; they are interpreted as resulting from arc magmatism. The amphibolites and banded amphibolites have major and trace element chemistry similar to that of oceanic plateau basalts (flat REE patterns, La/Nb = 0.86) or to cumulate gabbros. The granulite shares with oceanic plateaus similar trace element chemistry (flat REE patterns, La/Nb < 1) and εNdi values (+7.6). Continent-derived metasediments are depleted in heavy REE (La/Y = 4.8) and have a negative Eu anomaly. Foliated lherzolites, melagabbronorites and pyroxenites consist of serpentinized olivine + cpx + opx ± Ca-plagioclase. Lherzolites, melagabbronorites and pyroxenites are LREE depleted with positive Eu anomalies, while the harzburgite displays a U-shaped REE pattern. The trace element abundances of the ultramafic rocks are very low (0.1 to 1 times the chondritic and primitive mantle values). The ultramafic rocks represent fragments of depleted mantle, deformed cpx-rich cumulate, and continental lithospheric mantle or mantle contaminated by subduction-fluid. Except the scarce quartz-rich metasediments, all these rocks likely represent remnants of accreted oceanic crustal fragments and associated depleted mantle. Since these samples were randomly sampled at depth by the fault, we propose that the Western Cordillera and its crustal root are mainly of oceanic nature.
ISSN: 0016-7002

insu-00679228
https://hal-insu.archives-ouvertes.fr/insu-00679228

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Correlations between major and minor transition elements in tectonically emplaced orogenic peridotites have been ascribed to variable degrees of melt extraction and melt–rock reaction processes, leading to depletion or refertilization. To elucidate how such processes are recorded in the subcontinental lithospheric mantle, we processed a large geochemical dataset for peridotites from the four tectono-metamorphic domains of the Beni Bousera orogenic massif (Rif Belt, northern Morocco). Our study reveals that variations in bulk-rock major and minor elements, Mg-number and modal mineralogy of lherzolites, as well as their clinopyroxene trace element compositions, are inconsistent with simple partial melting and mainly resulted from different reactions between melts and depleted peridotites. Up to 30% melting at < 3 GPa and cryptic metasomatism can account for the geochemical variations of most harzburgites. In Grt–Sp mylonites, melting and melt–rock reactions are masked by tectonic mixing with garnet pyroxenites and subsolidus re-equilibration. In the rest of the massif, lherzolites were mostly produced by refertilization of a refractory protolith (Mg-number ∼ 91, Ol ∼ 70%, Cpx/Opx = 0·4) via two distinct near-solidus, melt–rock reactions: (1) clinopyroxene and orthopyroxene precipitation and olivine consumption at melt/rock ratios <0·75 and variable mass ratio between crystallized minerals and infiltrated melt (R), which are recorded fairly homogeneously throughout the massif; (2) dissolution of orthopyroxene and precipitation of clinopyroxene and olivine at melt/rock ratios ≤1 and R = 0·2–0·3, which affected mainly the Ariègite–Seiland and Seiland domains. The distribution of secondary lherzolites in the massif suggests that the first refertilization reaction occurred prior to the differentiation of the Beni Bousera mantle section into petro-structural zones, whereas the second reaction was associated with the development of the tectono-metamorphic domains. Our data support a secondary, refertilization-related origin for most lherzolites in orogenic peridotite massifs.
ISSN: 0022-3530

hal-01526901
https://hal.archives-ouvertes.fr/hal-01526901
DOI : 10.1093/petrology/egx003

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We report chlorine (Cl) and fluorine (F) abundances in minerals, interstitial glasses, and melt inclusions in 12 andesite-hosted, spinel harzburgite xenoliths and crosscutting pyroxenite veins exhumed from the sub-arc lithospheric mantle beneath Avacha volcano in the Kamchatka Arc (NE Russia). The data are used to calculate equilibrium mineral-melt partition coefficients (Dmineral/meltDmineral/melt) for Cl and F relevant to subduction-zone processes and unravel the history of volatile depletion and enrichment mechanisms in an arc setting.Chlorine is ∼100 times more incompatible in pyroxenes (View the MathML sourceDClmineral/melt = 0.005–0.008 [±0.002–0.003]) than F (View the MathML sourceDFmineral/melt = 0.50–0.57 [±0.21–0.24]), which indicates that partial melting of mantle sources leads to strong depletions in Cl relative to F in the residues. The data set in this study suggests a strong control of melt composition on View the MathML sourceDCl,Fpyroxene/melt, in particular H2O contents and Al/(Al + Si), which is in line with recent experiments. Fluorine is compatible in Ca-amphibole in the ‘wet’ sub-arc mantle (View the MathML sourceDFamphibole/melt = 3.5–3.7 [±1.5]) but not Cl (View the MathML sourceDClamphibole/melt = 0.03–0.05 [±0.01–0.03]), indicating that amphibole may fractionate F from Cl in the mantle wedge. The inter-mineral partition coefficients for Cl and F in this study are consistent amongst different harzburgite samples, whether they contain glass or not. In particular, disseminated amphibole hosts much of the Cl and F bulk rock budgets of spinel harzburgites (View the MathML sourceDClamphibole/pyroxene up to 14 and View the MathML sourceDFamphibole/pyroxene up to 40). Chlorine and fluorine are variably enriched (up to 1500 ppm Cl and 750 ppm F) in the parental arc picrite and boninite melts of primitive pyroxenite veins (and related melt inclusions) crosscutting spinel harzburgites.Based on the data in this study, the main inferences on the behaviour of Cl and F during melting and metasomatic processes in the sub-arc mantle are as follow:(i) Melting models show that most depleted mantle protoliths of intra-oceanic arc sources can have extremely low Cl/F (0.002–0.007) before being overprinted by subduction-derived components.(ii) Chlorine has a higher percolation distance in the mantle than F. Even for small fluid or melt volumes, Cl and F signatures of partial melting are overprinted by those of pervasive percolation, which increases Cl/F in percolating agents and bulk peridotites during chromatographic interaction and/or amphibole-forming metasomatic reactions. These processes ultimately control the bulk Cl and F compositions of the residual mantle lithosphere beneath arcs, and likely in other tectonic settings.(iii) Fluxed melting models suggest that Cl enrichment in arc picrite and boninite melts in this study, and in many arc melt inclusions reported in the literature, could be related to the infiltration of high Cl/F fluids derived from subducted serpentinite or altered crust in mantle wedge sources. However, these high Cl/F signatures should be re-evaluated with new models in light of the possible overprint of pervasive percolation effects in the mantle. The breakdown of amphibole (and/or mica) in the deep metasomatised mantle at higher pressure and temperature conditions than in the slab may explain, at least in part, the positive correlations between F abundances and Cl/F in primitive arc melt inclusions and slab depth.
ISSN: 0016-7037

hal-01553610
https://hal.archives-ouvertes.fr/hal-01553610
DOI : 10.1016/j.gca.2016.10.035

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Sapat peridotite in Kohistan (NW Pakistan) is a 12x1 km sized body of meta-harzburgites, dunites, pyroxenites and meta-gabbros in the hanging wall of the Indus Suture Zone. Field relations, micro-textures, bulk and mineral chemistry document melt-rock reactions producing dunites at the expense of meta-harzburgites, and a consecutive olivine-clinopyroxenite formation from the same melt type. The association of mesa-gabbros, dunites, and pyroxenites is interpreted as a crust-mantle transition zone produced by the percolation of highly depleted primitive arc melt. The meta-harzburgites represent large portions of refractoty mantle that have suffered melt extraction and metasomatism prior to their interaction with the dunite-forming primitive arc melt and the establishment of the crust-mantle transition zone. Uncommon vein assemblages in the dunites that include Cr-clinochlore, calcite and olivine document a late percolation of slab-related, volatile-rich fluids. Taking into account the highly refractory composition of the Sapat mantle, its structural position, the evidence for interaction with highly depleted arc melts and the sub-solidus interaction with volatile-rich arc fluids, the Sapat ultramafic rocks are interpreted as being derived from the frontal Kohistan arc, representing a crust-mantle transition formed by arc magmatism.
ISSN: 0024-4937

hal-00424515
https://hal.archives-ouvertes.fr/hal-00424515
DOI : 10.1016/j.lithos.2008.07.004

Éditeur(s) : HAL CCSD
Résumé : The mantle deformation processes that control the thinning and break-up of continental lithosphere remain poorly understood. Our knowledge is restricted to either lithospheric scale thermo-mechanical models --that use experimentally derived flow laws--, geophysical imaging and/or rare xenoliths from active continental rifts, such as the East African Rift System. The originality of this work relies on the study of the two largest outcrops of diamond facies subcontinental lithospheric mantle in the world: the Beni Bousera and Ronda peridotite massifs in N Morocco and S Spain, respectively. The structures and petrologic and metamorphic zoning preserved in these massifs --implying a polybaric and polythermal evolution-- provides a unique opportunity to investigate the thermo-mechanical evolution of thick subcontinental lithospheric mantle in extensional settings. In this thesis we studied the deformation mechanisms in both peridotites and pyroxenites to constrain the modes of exhumation of subcontinental lithospheric mantle from garnet-, to spinel-, and finally, to plagioclase lherzolite facies conditions. We combined field mapping of tectonometamorphic domains and structural mapping of ductile structures, microstructural analysis, crystal preferred orientations (CPO) measurements and conventional thermobarometric calculations and thermodynamic modeling (Perple_X) to unravel the pressure and temperature conditions of deformation. We showed that exhumation from garnet- to spinel lherzolite facies conditions was accommodated by fast shearing --in thermal disequilibrium--along a lithospheric scale transtensional shear zone. In this context, the petrological zoning and the large temperature gradient (ca. 100ºC/km) preserved in the Beni Bousera massif represent the mechanical juxtaposition of progressively deeper and hotter lithospheric levels at depths of ca. 60 km in the latest Oligocene (ca. 25 Ma). Final exhumation from spinel- to plagioclase facies lherzolite and emplacement into the crust is best recorded in the Ronda massif where it occurred by inversion and lithospheric scale folding of the highly attenuated continental lithosphere in a back-arc region, probably in relation with southward slab rollback and subsequent collision with the palaeo-Maghrebien passive margin in the early Miocene (21-23 Ma).
Les processus de déformation contrôlant l'amincissement de la lithosphère continentale sont encore mal contraints. Nos connaissances sont principalement basées sur la modélisation thermomécanique d'extension à l'échelle de la lithosphère--utilisant des lois rhéologiques derivées expérimentalement, l'imagerie géophysique et l'analyse de xénolithes provenant de rift continentaux actifs à ce jour, tels que le Rift Est-Africain. L'originalité de ce travail reside dans l'étude des deux plus grands massifs de péridotites sous-continentales ayant enregistrées des conditions primaires du facies à diamant: les massifs de Beni Bousera au nord du Maroc et de Ronda au sud de l'Espagne, respectivement. Les structures et la zonation petrologique et métamorphique --impliquant une évolution polybarique et polythermique-- préservéees dans ces massifs offrent une opportunité unique pour étudier l'évolution thermo-mécanique du manteau sous-continental dans un contexte extensif. Dans ce travail, nous avons étudié les mécanismes de déformation des péridotites et des pyroxénites afin de contraindre les modes d'exhumation du manteau lithosphérique sous-continental, depuis des conditions du facies des lherzolites à grenat, jusqu'au facies à spinelle et enfin à plagioclase. Nous avons combiné la cartographie des faciès tectono-métamorphiques et des structures ductiles de déformation, l'analyse des microstructures, la mesure d'orientations préférentielles de réseau (OPR), et la géothermobarométrie conventionelle couplée à la modélisation thermodynamique (PerpleX) afin de contraindre les conditions de pression et température de la déformation. Nous avons montré que l'exhumation précoce du facies à grenat au facies à spinelle était accomodée par une faille transtensive affectant le manteau lithosphérique. Dans ce contexte, la zonation tectono-métamorphique et le gradient thermique important (ca. 100ºC/km) préservés à Beni Bousera résultent de la juxtaposition mécanique de domaines lithosphériques initialement équilibrés à différentes pressions et températures, fossilisée à une profondeur de ca. 60 km durant l'Oligocène supérieur (ca. 25 Ma). L'exhumation finale du facies de lherzolite à spinelle au facies à plagioclase et l'emplacement final dans la croûte, mieux enregistrés dans Ronda, se sont produits par inversion et plissement de la section lithosphérique fortement amincie dans un contexte arrière-arc, probablement lors du retrait vers le sud de la lithosphère subduite et la collision de l'arc avec les paléo-marges maghrébines au Miocène inférieur (21-23 Ma).
https://tel.archives-ouvertes.fr/tel-00767700

tel-00767700
https://tel.archives-ouvertes.fr/tel-00767700
https://tel.archives-ouvertes.fr/tel-00767700/document
https://tel.archives-ouvertes.fr/tel-00767700/file/THESE_Frets.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
This study reports petrostructural observations in the pargasite and phlogopite-bearing Finero peridotite massif (Italian Western Alps), which suggest that the pervasive foliation in this massif was formed by deformation concomitant with percolation of hydrous Si-rich melts: (1) diffuse contacts, but systematic parallelism between the pyroxenitic layers and the foliation of the peridotite (2) strong shape and crystal preferred orientations (SPO and CPO), but subhedral or interstitial shapes and weak intracrystalline deformation of the hydrous phases, (3) CPO, but interstitial shapes of the pyroxenes, (4) very coarse olivine grain sizes, which are correlated to the olivine abundance, and (5) elongated shapes, but weak intracrystalline deformation, and extremely weak and highly variable CPO of olivine. The pervasive deformation of the Finero peridotite occurred therefore under conditions that allowed coexistence of H2O–CO2-bearing melts, pargasite, and spinel, that is, temperatures of 980–1080 °C and pressures <2 GPa. The petrostructural observations suggest that the presence of hydrous melts results in accommodation of large amounts of deformation by stress-controlled dissolution–precipitation and advective transport of matter by the melts and in fast grain boundary migration in olivine. By consequence, it produces significant rheological weakening. Water contents in olivine are <4 ppm wt., implying limited contribution of hydration of olivine to weakening. In addition, the analysis of protomylonites composing the external domains of the shear zones that overprint the pervasive foliation indicates that the transition to melt-free conditions results in enhanced contribution of dislocation creep to the deformation. The associated increase of the peridotites' strength leads to onset of strain localization. The latter is not correlated to the local abundance in pargasite or phlogopite, implying that crystallization of amphiboles or phlogopite, even at concentrations of 25 vol.%, does not produce rheological weakening in the upper mantle.
ISSN: 0012-821X

hal-01667879
https://hal.archives-ouvertes.fr/hal-01667879
DOI : 10.1016/j.epsl.2017.08.015

Éditeur(s) : HAL CCSD University of Chicago Press
Résumé : International audience
Contrasting tectonic reconstructions of the westernmost Mediterranean have been proposed to explain the origin of the Alboran marine basin contemporaneously with Cenozoic convergence between the African and European plates. Cr-rich pyroxenites in the Ronda massif record the geochemical processes occurring in the subcontinental mantle of the Alboran domain in the Late Oligocene, thus constraining the geodynamic scenario of Cenozoic extension in the western Mediterranean lithosphere. Clinopyroxene in intrusive Cr-rich websterite dikes crosscutting the Ronda peridotite is strongly depleted in Nb-Ta and enriched in light rare earth elements, as typically observed in arc magmas, and is in trace element equilibrium with Neogene subduction-related lavas from the western and central Mediterranean. Sr-Nd-Pb radiogenic isotopes indicate that the mantle source of the Ronda pyroxenite dikes was contaminated by a subduction component released by detrital sediments likely deposited in passive continental margins. Rather than convective removal or delamination of the lithospheric root, our data strongly support Alboran geodynamic models that envisage slab rollback as the tectonic mechanism responsible for the Miocene lithospheric thinning. The Ronda Cr-rich pyroxenite dikes represent the earliest unambiguous manifestation of subduction-related magmatism in the western Mediterranean and testify to the involvement of terrigenous sediments in the primitive stages of subduction.
ISSN: 0022-1376

hal-00745853
https://hal.archives-ouvertes.fr/hal-00745853
DOI : 10.1086/663875

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Oman ophiolite includes both a fossil fast spreading axis, defined by five mantle diapirs, and an off-axis mantle diapir emplaced 30 km from the axis, providing a natural laboratory for the study of off-axis magmatic processes. We compare field and petrological observations coupled with geochemical and isotopic analyses of samples from the off-axis diapir with those of the nearest on-axis diapir, with a particular focus on the Moho Transition Zone (MTZ). Both diapirs are defined by the presence of steeply plunging lineations, but in the on-axis case, these lineations rotate gradually into parallelism with the horizontal magmatic lineations of the overlying crust, while in the off-axis case, a shear zone separates the steeply plunging lineations from the horizontal lineations of the surrounding mantle. In the on-axis diapir, the MTZ is 50 to 500 m thick and composed of dunite with layered gabbro lenses whereas in the off-axis diapir, the MTZ is thicker and composed of dunite with massive (∼20% of MTZ) clinopyroxenite lenses and a notable absence of plagioclase. Moreover, the off-axis diapir is associated with amphibole-bearing intrusions, consisting of Mg-rich gabbroic sills in the mantle peripheral to the diapir, and microgabbroic lenses of broadly basaltic composition in the overlying crust. The ε Nd values of the pyroxenites in the MTZ of the off-axis diapir fully overlap with those of the intrusions in the surrounding mantle and crust, suggesting that they are genetically related. Calculated rare earth element (REE) abundances of liquids in equilibrium with clinopyroxene imply that the magmas that traversed the MTZ of the off-axis diapir were more depleted in highly incompatible elements than their counterparts in the MTZ of the on-axis diapir. On the other hand, Nd isotopic compositions of the off-axis samples (εNd=6.2–7.9εNd=6.2–7.9 in 18 of 19 samples) indicate derivation of their parental magmas from a less depleted source than that which produced the magma associated with the on-axis gabbro (εNd=7.8–9.2εNd=7.8–9.2, 10 analyses).To explain these observations, we suggest that the earliest magmas in the uprising off-axis diapir formed from the partial melting of pyroxenite veins with less radiogenic Nd isotopic compositions than those of the ambient peridotite. As the diapir traversed the cool, hydrated lithosphere these early melts interacted with depleted harzburgites, lowering the incompatible element contents of the melt products while having little effect on their Nd isotopic compositions. The great abundance of clinopyroxene in the off-axis MTZ might be explained by the high pyroxene component in the original melt but perhaps also by the presence of water in the lithosphere, which would favor the crystallization of clinopyroxene while inhibiting that of plagioclase. The intrusions in the overlying crust could represent, to first order, the secondary melts produced by the melt–harzburgite reaction, while the sills in the surrounding mantle may be cumulates from such secondary melts.These results shed light on processes occurring during interaction between rising off-axis material and depleted, hydrated lithospheric mantle. Furthermore, if our interpretation is correct, the low εNd values of the off-axis samples contribute to the growing body of evidence for the presence of pyroxenite veins in the MORB mantle source.
ISSN: 0012-821X

hal-01306575
https://hal.archives-ouvertes.fr/hal-01306575
DOI : 10.1016/j.epsl.2015.12.005

Éditeur(s) : HAL CCSD Elsevier
Résumé : The ultramafic–mafic complexes located at the base of obducted paleo-island arcs are commonly interpreted as evidence for intra-crustal fractionation of primitive (high-Mg#) mantle melts. The present study, realized on the Jijal mafic–ultramafic basal section of the Cretaceous Kohistan oceanic arc (N Pakistan), discards a crystal fractionation model from a single parental magma to take into account the geochemical and isotope variations observed between the plutonic crust and the underlying ultramafic section. The basal ultramafic rocks, i.e. dunites, wehrlites and clinopyroxenites, show high Mg#, extremely depleted REE patterns, no marked HFSE anomalies and high LILE enrichment. Cpx and leached whole rocks from this unit yield restricted εNd values (+ 5.5 to + 6.8), a large εSr range (− 5.9 to + 8.8) and mainly radiogenic 207Pb/204Pb ratios. The overlying mafic section, i.e. gabbroic rocks, displays low Mg# (46 < Mg# < 54), enriched REE patterns and marked HFSE anomalies. These plutonic rocks have also very homogeneous Sr and Pb isotopic compositions defining a restricted domain, which does not overlap that of the ultramafic samples. Moreover, Cpx from the basal ultramafics yield an Sm–Nd isochron at 117 ± 7 Ma interpreted as dating crystallization of the ultramafic section. Together, these results indicate that the mafic rocks on one hand and the ultramafic rocks on the other hand, originate from separate sources with specific emplacement underneath the subduction zone. A lherzolite lens, collected from the top of the mafic section, plots on the early Cretaceous Sm–Nd isochron and therefore yields the same 143Nd/144Nd initial ratio. This suggests that the ultramafic part of the lower Kohistan arc complex sampled the initiation stages of the subduction with production of magmas with boninite-like features. At this stage, the mantle wedge has been already modified by percolation of the first slab-derived fluids. On such a scenario the lherzolite lens would correspond to the lithospheric mantle underneath the arc before its initiation. A multi-stage history is proposed for the evolution for the Kohistan arc through not, vert, similar 30 Ma. Stage #1 reflects the spontaneous initiation of subduction associated with extensive boninitic affinity magmatism, stages #2 and #3 are related to arc building by tholeiitic melts and, a fourth step (stage #4) corresponds to the intra-crustal differentiation.
ISSN: 0012-821X

hal-00407206
https://hal.archives-ouvertes.fr/hal-00407206
DOI : 10.1016/j.epsl.2007.06.026

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
We report new structural, microstructural, petrological, and major- and trace-element data on ultramafic rocks from the Kondyor zoned ultramafic complex in Far-East Russia. The ultramafic rocks are subdivided into three subconcentric lithologies, from core to rim: (1) a metasomatic domain where generally phlogopite-rich dykes pervasively intrude dunite; (2) a main dunite core; (3) a pyroxenite rim. The ultramafic rocks have nearly vertical contacts with the surrounding Archaean basement (gneisses, quartzites and marbles) and hornfelsed Riphean sediments. The hornfelsed sediments show a relatively steep ( 60), outward dipping layering, which rapidly flattens to horizontal away from the inner contact. Although the Riphean sediments define a dome-like structure, the inward, shallow dipping foliation of the dunites indicates a synformal structure. Detailed petro-structural investigations indicate that the Kondyor dunites were deformed by solid-state flow under asthenospheric mantle conditions. The outward textural change from coarse- to fine-grained equigranular dunite and the outward-increasing abundance of subgrains and recrystallized olivine grains suggest dynamic recrystallization while fluid circulation was channelized within the core metasomatic zone, with a decreasing melt fraction from core to rim, and also suggest that solid-state deformation induced grain-size reduction towards the cooling border of the Kondyor massif. Based on their geochemistry, the dunites are interpreted as mantle rocks strongly affected by reaction with melts similar to the JurassicCretaceous Aldan Shield lamproites. Rim pyroxenites were formed by a melt-consuming peritectic reaction, implying the existence of at least a small, conductive thermal gradient around the dunite body while the latter was still at near-solidus temperature conditions. This suggests that the zoned structure of Kondyor was initiated at mantle depths, most probably within the subcontinental lithosphere. Upon cooling, the lamproitic melts were progressively focused in the central part of the massif and drained into vein conduits where they reacted with the wall-rock dunite. Two-dimensional numerical modelling based on finite-differences with a marker-in-cell technique incorporates temperature-dependent rheologies for both molten and non-molten host rocks. The modelling consolidates the structural, petrological and geochemical interpretations, which show that the dunites represent the synformal, flat-lying apex of an asthenospheric mantle diapir, triggered by fluid pressure channelized in the core, which nearly reached the Earths surface. We conclude that translithospheric mantle diapirism is an important mode of mass transfer in the Earth.
ISSN: 0022-3530

hal-00424508
https://hal.archives-ouvertes.fr/hal-00424508
DOI : 10.1093/petrology/egn083

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Mantle-derived xenoliths hosted by melilitite lavas from In Teria (Ahaggar, SE Algeria) include garnet and spinel peridotites, pyroxenite and phlogopite megacrysts. The spinel and garnet peridotites record an early deformation event, which formed porphyroclastic microstructures and olivine crystal preferred orientations, followed by static infiltration of hydrous alkaline melts. This metasomatic stage (stage 1) is characterized by the crystallization of phlogopite in the garnet and spinel peridotites, amphibole in the spinel peridotites and clinopyroxene in the garnet peridotite, which record chemical equilibration with an alkaline silicate melt. These early events were largely overprinted by carbonatitic metasomatism (stage 2), which is observed only in the spinel peridotites. Spinel peridotite major and trace element compositions, as well as the compositions of newly formed minerals, are characteristic of interaction with carbonate melt, associated with strong enrichment in incompatible trace elements in clinopyroxene. This second stage was followed by crystallization of pyroxenites (stage 3) in vein conduits, probably segregated from alkaline melts. We propose a scenario in which the different metasomatic imprints record successive stages of interaction between lithospheric mantle and sublithospheric melts throughout the Cenozoic. In Sr–Nd isotope space, the host melilitites and several xenoliths are clustered and plot close to the HIMU mantle end-member. However, some peridotite xenoliths are shifted towards more radiogenic 87Sr/86Sr values. In 207Pb/204Pb–206Pb/204Pb and 208Pb/204Pb–06Pb/204Pb space the In Teria samples define a relatively large domain characterized by high 206Pb/204Pb and 208Pb/204Pb, consistent with a contribution of an HIMU component, considered to represent a sublithospheric signature. The highest 87Sr/86Sr values are comparable with those ascribed to the EM1 mantle end-member, representing the signature of the lower continental lithosphere, and are probably inherited from the pre-metasomatic lithospheric mantle beneath In Teria. Numerical modelling of porous percolation of melt of sublithospheric origin through an EM1-like lithospheric mantle protolith reproduces the In Teria peridotite compositions, using moderately sub-chondritic Sr/Nd values for the peridotite (e.g. In Teria garnet peridotite) and moderately super-chondritic Sr/Nd values in the melt (approximately ocean island basalt values). A few spinel peridotites require a component characterized by a 143Nd/144Nd signature higher than both the EM1 end-member and the local Ahaggar basalts; the 208Pb/204Pb compositions of several samples point to a component with a depleted mid-ocean ridge basalt (MORB) mantle (DMM) signature. Thus the lithospheric mantle beneath In Teria probably did not have a uniform EM1 signature before the onset of metasomatism; it included a DMM peridotite component as well as some peridotites with elevated 143Nd/144Nd values recording long-term LREE depletion.
ISSN: 0022-3530

hal-01356781
https://hal.archives-ouvertes.fr/hal-01356781
DOI : 10.1093/petrology/egw009

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Island arc picrites and boninites are magnesian magmatic rocks believed to be generated by high degrees of melting of depleted mantle sources fluxed by subduction-derived, volatile-rich components. These magmas can be probes of both the mantle wedge protoliths and subduction components, but are rare among other, usually more evolved, types of arc lavas. Furthermore, many arc picrites and boninites show evidence for late-stage differentiation prior to or during eruption, masking their primary, mantle-derived geochemical signatures. We report textural and chemical data on spinel-hosted melt inclusions of mantle origin in amphibole-bearing websterite veins cross-cutting spinel harzburgite xenoliths from the active andesitic Avacha volcano (south Kamchatka, Russia). The data are used to constrain the composition and origin of melts that formed the websterite veins in the sub-arc lithospheric mantle. The melt inclusions typically contain euhedral orthopyroxene and clinopyroxene and occasionally minor amphibole in silicate glass. The melt inclusions were homogenized using heating stages and gas-mixing furnaces. The homogenized glasses range from subalkaline primitive silica-rich picrite and high-Ca boninite (>15 wt % MgO, 48–54 wt % SiO2) to rhyolite. High-Ca boninite glasses have moderate volatile and low heavy rare earth element contents and elevated Cs, Rb, Ba, U, Sr, and Li abundances, with extremely high U/Th. In turn, the glasses display no negative spikes in the high field strength elements Nb, Ta, Zr, Hf, and Ti. We show that the silica-rich picrite and high-Ca boninite liquids in this study formed by high degrees of melting (>25%), at volatile under-saturation, of hybrid melt-depleted but silica-rich mantle sources at ≥1·5 GPa. The hybrid sources formed in two stages: first, by extraction of ∼15% melt from the convecting mantle to form a refractory protolith, which was subsequently enriched in silica via interaction with subduction-derived components prior to or during remelting in the mantle wedge. The subduction-derived components were enriched in fluid-mobile elements and probably oxidized. Overall, our results suggest that silica-rich picrites and high-Ca boninites can be primary melts in mature subduction zones and differentiate within the mantle wedge and the deep arc crust to form more evolved andesite magmas.
ISSN: 0022-3530

hal-01553676
https://hal.archives-ouvertes.fr/hal-01553676
DOI : 10.1093/petrology/egw066