Éditeur(s) : HAL CCSD
Résumé : This thesis has been conducted on a fractured crystalline basement located in Ploemeur (South of Brittany, France). The detailed study of this basement requires a good understanding of their internal structures, namely their intrinsic properties, flow mode, density and fractures distribution. This work is focused on the petrophysical characterization of the granitic formations. Physical properties were determined from downhole geophysical measurements and images, and petrophysical measurements with thin sections made for each mini-core in the laboratory. Fresh-altered schist and fresh-altered granite separated by a normal angle fault are the main lithology of the Ploemeur crystalline basement. The results showed that the petrophysical properties were function of both porosity variation and degree of alteration and that the pore-space topology was found to be porositydependent. This thesis introduces a new formula between electrical resistivity and porosity. In addition, the laboratory measurements of Ploemeur revealed that seismic wave velocity was a function not only of porosity, but also of the predominant pore type. In general, the pore aspect ratio inverted from velocity measurements were classified roughly into crack shape. In the Ploemeur crystalline basement, the downhole geophysical measurements and images were used to measure changes in physical and chemical properties in the borehole fluid and the bedrock surrounding the boreholes. The effective integration of different geophysical methods, hydrogeological tests and lithological description was the best way to characterize the fractures in the crystalline basement, and is critical for a suitable estimation of fluid circulation.
Le socle cristallin fracturé, situé à Ploemeur (Bretagne sud, France) est l'objet de ce travail de thèse. L'étude détaillée du socle nécessite une bonne compréhension de la structure interne, à savoir les propriétés intrinsèques, le mode d'écoulement, la densité et la distribution des fractures. Ce travail de thèse est consacré à la caractérisation pétrophysique des formations granitiques. Les propriétés physiques ont été déterminées à partir de l'interprétation des données de mesures de géophysique en forage, des images de paroi du puits et des mesures pétrophysiques réalisées sur carottes en laboratoire. Afin de replacer les mesures dans leur contexte lithologique, une lame mince a été analysée pour chaque mini-carotte. Les formations lithologiques rencontrées dans le socle cristallin de Ploemeur sont des schistes et granites sains et altérés, ces deux lithologies étant séparées par une zone de faille. Les résultats ont montré que les propriétés pétrophysiques des roches étaient fonction à la fois de la variation de la porosité et du degré d'altération des roches et que la topologie de l'espace poreux était fortement dépendante de la porosité. Cette thèse introduit une nouvelle formule entre la résistivité électrique et la porosité. De plus, les mesures en laboratoire sur les échantillons de Ploemeur révèlent que les vitesses sismiques ne sont pas seulement fonction de la quantité de porosité, mais aussi fonction de facteur de forme. Ce dernier a été calculé sur les échantillons du socle de Ploemeur à partir des vitesses acoustiques. Les résultats ont montré que la porosité est de forme fissurale. L'intégration des données issues des images optiques et acoustiques, des mesures de géophysique en forage, et de la description des carottes a permis d'étudier de façon détaillée la géologie et l'hydrodynamique du socle de Ploemeur. L'intégration effective de ces différentes méthodes avec les tests hydrogéologiques ressort comme la meilleure façon de caractériser les fractures et les circulations en eau dans le socle.
https://tel.archives-ouvertes.fr/tel-00444175

Droits : info:eu-repo/semantics/OpenAccess
tel-00444175
https://tel.archives-ouvertes.fr/tel-00444175
https://tel.archives-ouvertes.fr/tel-00444175/document
https://tel.archives-ouvertes.fr/tel-00444175/file/thesebelghoul.pdf

Éditeur(s) : HAL CCSD
Résumé : International audience
This paper presents the background for the calculation of anisotropic piezoelectric properties of single crystals and the graphical display of the results in two or three dimensions, and the calculation of the aggregate properties from constituent crystals and the texture of the aggregate in a coherent manner. The texture data can be obtained from a wide range of sources, including pole figure diffraction and single orientation measurements (electron backscattered diffraction, electron channelling pattern, Laue Pattern, optical microscope universal-stage). We consider the elastic wave propagation in piezoelectric crystals as an example of the interaction of electrical (2nd rank tensor), piezoelectric (3rd rank tensor) and elastic properties (4th rank tensor). In particular, we give explicit formulae for the calculation of the Voigt averaged tensor from individual orientations or from an orientation distribution function. For the latter we consider numerical integration and an approach based on the expansion into spherical harmonics. We illustrate the methods using single crystals, polycrystalline quartz measured using electron channelling patterns and ideal Curie limiting groups applied to quartz aggregates. This paper also serves as a reference paper for the mathematical tensor capabilities of the texture analysis software MTEX
Geological Society Special Publication, 409

hal-01277789
https://hal.archives-ouvertes.fr/hal-01277789
DOI : 10.1144/SP409.2

Éditeur(s) : HAL CCSD
Résumé : International audience
The purpose of our study is to model a geothermal reservoir. When geothermal reservoir are assumed to be composed of pure water, the transfer of mass and energy is classically described by two balance equations: mass balance equation and the energy balance equation. In addition to those equations, fluid velocity ist classically given by the Darcy law while thermodynamic properties, inferred from theoretical or empirical equations of state, are used to close the mathematical system. Once this system is closed, there exist different solutions. The first one is to solve for pressure and temperature with a variable switch to saturation in the two-phase region (e.g. TOUGH2). The second one is to solve for pressure and enthalpy to increase stability of phase transition between single and two-phase states (e.g. Hydrotherm). We adopted the second option and chose te use a splitting method to get rid of the complexity of coupling equations and a finite volume method for the spatial discretization. Selecting object-oriented languages, we developed a multi-language framework, combining Python, Fortran and a C++ implementation of IAPWS (from the freesteam project) including the supercritical equations, in porous media velocity is given by Darcy law and to close the system physical properties are determined by the IAPWS-IF97 thermodynamic formulation. We resolve the equations in pressure and enthalpy instead of pressure and temperature in order to increase stability and to handle easier the passage from a single-phase to a two-phase system. We solve the system by using a splitting method - to get rid of the complexity of coupling equations - and a finite volume method. We offer some freedom to users thanks to the implementation of several methods like explicit or implicit Euler, Runge-Kutta or BDF2 for time solvers or GMRES and BICGSTAB for the linear solver. We can handle several boundary conditions like no-flow - describing a boundary which can not exchange matter with the exterior - or like a mixed-therm condition - a Dirichlet condition to the pressure and a Dirichlet or an outflow condition to the temperature in order to describe a recharge or a discharge zone - ... We're developing a multi-language framework, combining Python, Fortran and the C++ implementation of IAPWS (from the freesteam project). All these languages are object-oriented. We've applied this simulation model to the dogger in Paris, France, to several one-dimensional systems and a two-dimensional one made by Coumou with the CSMP++ platform. The dogger is a reservoir exploited to produce heat by pumping water at 70 and reinjecting it in the reservoir at 40. In the one-dimensional systems we wanted to observe the process of heat transfer from a higher temperature boundary to a smaller one in a high-energy domain. The last simulation shows the natural convection of water in a fault. For every simulation we compared the solutions we found with an other code (TOUGH2 or CSMP++) and they agreed. The next step will be to model the geothermal plant in Guadeloupe, West Indies. It's the only place in France - and in the West Indies so far - producing electricity with the earth power. The temperature can reach up to 1000 and the pressure range is around a few hundreds MPa. In some surface zones we can see two-phase water at atmospheric pressure. In the 1980s Bouillante was a laboratory for France. Since 1995 Bouillante has given 30GWh electricity a year to the Guadeloupeans.
PROCEEDINGS, Thirty-Ninth Workshop on Geothermal Reservoir Engineering
Stanford, United States

Droits : info:eu-repo/semantics/OpenAccess
hal-00944133
https://hal-brgm.archives-ouvertes.fr/hal-00944133
https://hal-brgm.archives-ouvertes.fr/hal-00944133/document
https://hal-brgm.archives-ouvertes.fr/hal-00944133/file/Copol.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
A good knowledge of the intermittency of global solar radiation is crucial for selecting the location of a solar power plant and predicting the generation of electricity. This paper presents a multifractal analysis study of 367 daily global solar radiation sequences measured with a sampling rate of 1 Hz over one year at Guadeloupean Archipelago (French West Indies) located at 16 150N latitude and 60 300W longitude. The mean power spectrum computed follows a power law behavior close to the Kolmogorov spectrum. The intermittent and multifractal properties of global solar radiation data are investigated using several methods. Under this basis, a characterization for each day using three multifractal parameters is proposed.
ISSN: 0038-092X

hal-00903410
https://hal.archives-ouvertes.fr/hal-00903410
DOI : 10.1016/j.solener.2013.09.018

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The minerals constituting the Earth's upper mantle are nominally anhydrous silicates (NAMs). However they do contain hydrogen as a trace element, decorating point defects in their crystalline structure. Experimental petrology and mineralogy have quantified the maximum concentration under several compositional and thermodynamic conditions, but systematic studies on the hydrogen concentration in minerals from mantle-derived rocks have only recently been carried out. Here, we have compiled the distribution of hydrogen in upper mantle peridotite xenoliths, from which several conclusions can be drawn. NAMs from peridotite xenoliths contain a few ppm wt. H2O in their structure. From the current database, the hydrogen concentrations in olivine regularly increase with increasing depth. The amount of hydrogen in NAMs from peridotite xenoliths from subduction contexts is not higher than in other geological context for similar temperature and pressure conditions. The highest hydrogen concentrations is found in peridotitic olivines from cratonic mantle, and are likely due to the depth of origin. The increasing hydrogen concentration in olivine with increasing depth is likely controlled by the increase of H partitioning into olivine at the expense of orthopyroxene as imposed by a decrease in Al content in opx with depth. However, the sparse data could also indicate that the bulk hydrogen concentration slightly increases with depth > 150 km. In this case, it would suggest, locally (Udachnaya for example), a possible increase in water fugacity due to fluid saturation. Even if the most abundant mineral in mantle rocks is olivine, the bulk hydrogen concentration in peridotites is controlled by the amount of hydrogen stored in pyroxenes. However, hydrogen concentration in olivine remains crucial for consequences on physical properties such as rheology and electrical conductivity. Kinetics of hydrogen transport is reviewed and hydrous melt/fluid percolation appears necessary to homogenize the hydrogen distribution at km-scale. Sampling of natural rock specimens is currently biased (e.g., in favor of optically attractive samples) and needs improvement, which will be achieved by increasing sample diversity (all type of grain sizes, lithologies, geological settings) and size of rock samples, as well as advances in analytical techniques. Acquisition of high quality data will be achieved by studying the co-existing minerals in mantle specimens, exploring each sample by linear and mapping measurements, and using appropriate FTIR calibrations for polarized and unpolarized radiation.
ISSN: 0024-4937

hal-01306676
https://hal.archives-ouvertes.fr/hal-01306676
DOI : 10.1016/j.lithos.2015.11.012

Éditeur(s) : HAL CCSD
Résumé : Composite materials incorporating vegetable fibres have known an increasingly interest during the past few decades. These environmental friendly materials are low-cost and offer advantages such as reduction of electrical consumption by air conditioning. Moreover, the use of vegetable fibres in replacement of synthetic fibre is interesting in developing countries where the availability of tropical plants and agricultural waste is important. This paper presents an initial investigation on the use of a construction material, composed of cement and pre-treated (heat or alkaline treatments) sugar cane bagasse fibres. The purpose of this study is to analyse the effect of fibre content and treatment on thermal conductivity, specific heat, flexural strength and density. The addition of retified fibres reduces composites thermal conductivity and yields a weaker specific heat in comparison with composites made with alkaline fibres. From mechanical point of view, composites made with alkaline fibres have a better flexural strength than others.
12th International Inorganic-bonded Fiber Composites Conference
Aalborg, Denmark

hal-00807543
https://hal.univ-antilles.fr/hal-00807543

Résumé : Le fluide chaud produit par les forages de la centrale géothermique de Bouillante (Guadeloupe) est enrichi en espèces dissoutes telles que la silice qui peuvent précipiter sous forme de dépôts solides lors de son refroidissement et gêner fortement la production électrique. L’un des principaux objectifs de ce travail de thèse a donc été d’améliorer l’état des connaissances sur les conditions physiques, chimiques et cinétiques de la précipitation de la silice amorphe à Bouillante. Après une étude des caractéristiques physico-chimiques des fluides et des dépôts associés au champ de Bouillante, des expériences sur la cinétique de précipitation de la silice, sur site, pour une large gamme de température (25 - 90°C) et de pH (4 - 12) ont été menées et analysées en détail.Pour l’ensemble de ces expériences, seule la polymérisation (réversible) de la silice dissoute, sous forme de suspensions colloïdales très stables en solution, a été observée. La modélisation des données expérimentales de cinétique montre que la vitesse de polymérisation de la silice suit une loi d’ordre 2 vis-à-vis de la silice dissoute jusqu’à l’équilibre en accord avec une dimérisation de la silice. Par contre, durant l’étape initiale de la réaction, une loi d’ordre 4 semble mieux adaptée, suggérant des réactions de polymérisation plus complexes avec formation de tétramères. La température a un effet limité sur la cinétique de polymérisation de la silice comparé à l’effet du pH qui est beaucoup plus important. L’énergie d’activation de la réaction globale est de 41 - 54 kJ pour des pH compris entre 5 et 8.La caractérisation de la silice précipitée a mis en évidence des différences notables entre la structure poreuse de la silice solide prélevée sur les installations de surface et celle de la silice colloïdale obtenue par polymérisation lors des expériences de cinétique, ce qui semble indiquer que des mécanismes différents interviennent dans ces deux contextes de précipitation de la silice dissoute.Le deuxième objectif de cette thèse était d’évaluer la possibilité de valoriser la silice extraite de l’eau géothermale de Bouillante dans un procédé de traitement des eaux naturelles par adsorption. Pour cela, les propriétés d’adsorption de la silice géothermale brute et fonctionnalisée par le poly(ethylèneimine) (ou PEI) ont été étudiées pour deux polluants : un colorant, le bleu de méthylène et un métal lourd, le plomb. Les résultats obtenus montrent que la silice brute possède une grande capacité d’adsorption vis-à-vis du bleu de méthylène. En outre, la fonctionnalisation de la silice par le PEI permet d’améliorer sa capacité d’adsorption vis-à-vis du plomb en solution, en accord avec un modèle cinétique du pseudo-second ordre suggérant une chimisorption. Le modèle d’isotherme de Redlich-Peterson est également en très bon accord avec les données expérimentales.
The hot geothermal fluid produced by the geothermal power plant of Bouillante (Guadeloupe) contains various dissolved components such as silica that can precipitate as solid deposits during their cooling and cause serious problems on the electricity generation. One of the aim of this study is to improve the understanding on the physical, chemical and kinetics conditions of the amorphous silica precipitation in the Bouillante geothermal field. After a study on the physical and chemical characteristics of the Bouillante fluids and deposits which can form during their exploitation, experiments on the kinetics of silica precipitation, on site, under a large range of temperature (25 – 90°C) and pH (4 – 12) have been carried out and analyzed in detail.During on site kinetics experimentations only dissolved silica polymerization (reversible) as colloidal gel, very stable in solution, was observed. Modeling of the experimental data showed that the kinetics polymerization is characterized by a 2-order kinetic law relative to dissolved silica until the equilibrium that is consistent with silica dimerization. On the other side, the initial stage of the reaction is better characterized by a 4-order kinetic law that suggested more complex polymerization reactions with tetramers formation.Temperature has a little effect on the polymerization kinetics compared with the pH which has an effect more important. The activation energy of silica precipitation calculated between 25 and 90°C, is about 41 - 54 kJ for pH ranging to 5 - 8.The characterization of the silica precipitate reveals significant differences in the porous structure of the silica collected on the surface installations and the one obtained from kinetic experiments that suggests different precipitation mechanisms. The second objective of this thesis was to evaluate the possibility to promote geothermal silica for the treatment of natural waters containing contaminants by adsorption. Adsorption properties of the untreated and functionalized by poly(ethylèneimine) (ou PEI) geothermal silica have been investigated for two pollutants: a colorant, the methylene blue and a heavy metal, the lead.Results showed that untreated silica has a great adsorption capacity concerning the methylene blue. Besides, silica functionalization by the PEI allows improving the adsorption capacity for lead in solution. The adsorption kinetics curves followed a pseudo-second order model consistent with a chimisorption. The isotherm model of Redlich-Peterson fitted well the experimental data.

http://www.theses.fr/2014AGUY0698/document

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
A good knowledge of the intermittency of global solar radiation is crucial for selecting the location of a solar power plant and predicting the generation of electricity. This paper presents a multifractal analysis study of 367 daily global solar radiation sequences measured with a sampling rate of 1 Hz over one year at Guadeloupean Archipelago (French West Indies) located at 16°15'N latitude and 60°30'W longitude. The mean power spectrum computed follows a power law behaviour close to the Kolmogorov spectrum. The intermittent and multifractal properties of global solar radiation data are investigated using several methods. Under this basis, a characterization for each day using three multifractal parameters is proposed
ISSN: 0038-092X

hal-01527892
https://hal.archives-ouvertes.fr/hal-01527892
DOI : 10.1016/j.solener.2013.09.018