Éditeur(s) : HAL CCSD Lavoisier
Résumé : International audience
Afin de réduire la consommation d'énergie électrique liée à l'utilisation intense de la climatisation dans les logements des régions tropicales de la Caraïbe, des matériaux composites fibres végétales/ciment ont été préparés en vue d'être utilisés dans le domaine de la construction. Les fibres de dictame (Maranta arundinacée), résidus de l'extraction de la farine de dictame, sont étudiées. Dans cet article, une première partie sera consacrée à la détermination des dimensions des particules et de la composition chimique des fibres de dictame brutes, à l'étude des évolutions structurales et de texture des fibres après leur pyrolyse (200 - 700°C). Puis le travail sur la prise des composites fibres de dictame/ciment sera mené. En particulier, l'influence de paramètres tels que la teneur en fibres, la teneur en eau et la température de pyrolyse des fibres de dictame sera abordée. Par ailleurs les chaleurs dégagées lors de la dégradation thermique des composites sont également déterminées.
ISSN: 1169-7954

hal-00809828
https://hal.univ-antilles.fr/hal-00809828
DOI : 10.3166/rcma.17.327-350

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Various bagasse fibre/cement composites have been prepared, the fibres having a random distribution in the composites. The influence of different parameters on the setting of the composite material has been studied: (1) botanical components of the fibre, (2) thermal or chemical treatment of the fibre, (3) bagasse fibre content and (4) added water percentage. This study shows a retarding effect of lignin on the setting of the composite, for small amount of heat-treated bagasse (200 °C) the behaviour of the composite is closely the same as the classical cement or cellulose/cement composite.
ISSN: 0958-9465

hal-00809715
https://hal.univ-antilles.fr/hal-00809715
DOI : 10.1016/S0958-9465(02)00003-3

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
ISSN: 0022-3697

hal-00808660
https://hal.univ-antilles.fr/hal-00808660

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Silane coating of fibers is a promising process for improving durability and adhesion of vegetable fibers used as reinforcement material in a cementitious matrix. The work presented in this paper gives an insight into the effect of combining pyrolysis treatment with silane treatment. Indeed, this study focuses on silane treatment of unpyrolyzed and pyrolyzed sugar cane bagasse fibers with an alkyltrialkoxysilane (RSi(OR′)3), S1 or a dialkyldialkoxysilane (R2Si(OR″)2), S2. The silane solutions used vary from 0.5% to 8% by volume. This paper describes the effect of two silane compounds on parameters such as the porosity, dimension, morphology and hygroscopic character of silane-coated sugar cane bagasse fibers. Preliminary studies on natural fiber reinforced composite setting time show the importance of the silane chemistry/structure, for fiber treatments with silane solution containing up to 6% (volume percent) silane. In the case of composites reinforced with unpyrolyzed bagasse fibers, setting time increases with silane coating. Combining pyrolysis and silane treatment improve the water resistance of the fibers, which become more hydrophobic.
ISSN: 1359-835X

hal-00809830
https://hal.univ-antilles.fr/hal-00809830
DOI : 10.1016/j.compositesa.2008.05.013

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
This paper examines the thermal properties of cement composites reinforced with vegetable bagasse fibres (1.5% and 3% wrtc). Thermal properties have been correlated to macroscopic density and porosity in order to estimate thermal conductivity of fibres using a calculation inspired from the Maxwell-Eucken modelling. Experimental investigations reveal that adding retified bagasse fibres reduces composites thermal conductivity and yields a weaker specific heat in comparison with composites made with alkaline bagasse fibres. Moreover, the more the fibres, the lighter the specimen; lower its thermal conductivity and lower its specific heat. Thermal conductivity of alkaline fibres is lower than retified fibres one.
ISSN: 1359-835X

hal-00809831
https://hal.univ-antilles.fr/hal-00809831
DOI : 10.1016/j.compositesa.2010.01.002

Éditeur(s) : HAL CCSD
Résumé : International audience
International Conference NOCMAT 2007
Maceio-Alagoas, Brazil

hal-00807968
https://hal.univ-antilles.fr/hal-00807968

Éditeur(s) : HAL CCSD Taylor & Francis
Résumé : International audience
This paper presents the effects of chemical and thermal treatments on the strength of vegetable fibers that were being considered as reinforcements in cementitious matrix composites for affordable housing. These include vegetable fibers extracted from banana trunks and sugar cane residues. The results suggested that pyrolysis increased the fiber strength, at least by a factor three. Acid attack generally degraded the strengths, while alkali attack had only a limited effect. Pyrolyzed banana leaves, coconut coir, and coconut sheaths fibers were also tested. The implications of the results were discussed for the development of strong cementitious matrix composites.
ISSN: 1042-6914

hal-00809827
https://hal.univ-antilles.fr/hal-00809827
DOI : 10.1080/10426910601063386

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
An empirical relation is proposed to analyze the broad band observed in the photoluminescence spectra of CuInSe2 (CIS) due to donor-acceptor pair recombinations. This permits, together with the knowledge of the majority carrier concentration and the compensation ratio, the determination of the activation energy ED of the donor and EA of the acceptor levels and the mean distance R between D-A pairs. Values of the dielectric constant ϵ, ED and EA for CIS obtained with this model agree with reported data.
ISSN: 0167-577X

hal-00808657
https://hal.univ-antilles.fr/hal-00808657
DOI : 10.1016/S0167-577X(96)00133-4

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Four fibers from banana-trees (leaf, trunk) and coconut-tree (husk, fabric) were examined before their incorporation in cementitious matrices, in order to prepare insulating material for construction. Their botanical compositions have been determined following a method described previously. Thermal degradation of these fibers were studied between 200 and 700 °C under nitrogen gas flow. Temperature of pyrolysis was the experimental parameter investigated. The solid residues obtained were analyzed by classical elemental analysis, Fourier Transform Infra Red (FTIR) spectroscopy and were observed by Scanning Electron Microscopy (SEM). This study has shown (1) the relation between botanical, chemical composition with both localization of fibers in the tree and type of tree; (2) the rapid and preferential decomposition of banana fibers with increasing temperature of pyrolysis and (3) the rough samples are made of hollow fibers.
ISSN: 0960-8524

hal-00809780
https://hal.univ-antilles.fr/hal-00809780
DOI : 10.1016/j.biortech.2005.11.030

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Thermogravimetric results on the thermal degradation of isolated components extracted from shells of tropical fruit stones and seeds allowed us to establish the dependence of the yield of char obtained by high-temperature pyrolysis (600-900 °C) of lignocellulosic raw materials on the content of components in precursors...
ISSN: 1387-1811

hal-00809743
https://hal.univ-antilles.fr/hal-00809743
DOI : 10.1016/S1387-1811(03)00288-9

Éditeur(s) : HAL CCSD Lavoisier
Résumé : International audience
Influence des constituants de la fibre de bagasse sur la prise du matériau composite bagasse/ciment
ISSN: 1169-7954

hal-00808663
https://hal.univ-antilles.fr/hal-00808663

Éditeur(s) : HAL CCSD Taylor & Francis
Résumé : International audience
This work evaluates the influence of three different intensities of refinement of sisal pulp and the effect of accelerated aging cycles on the behavior of composites. Fiber-cements were prepared by the slurry de-watering method and pressing as a crude simulation of the Hatschek process. Mechanical behavior of composites was evaluated by four-point bending test at 28 days, and after 50 and 100 wet/dry cycles. Refinement of pulp and aging have increased the strength and bulk density of composites and decreased the toughness and porosity. The best mechanical performance after aging was achieved for samples with highly refined fibers.
ISSN: 1042-6914

hal-00809817
https://hal.univ-antilles.fr/hal-00809817
DOI : 10.1080/10426910601062065

Éditeur(s) : HAL CCSD
Résumé : Composite materials incorporating vegetable fibres have known an increasingly interest during the past few decades. These environmental friendly materials are low-cost and offer advantages such as reduction of electrical consumption by air conditioning. Moreover, the use of vegetable fibres in replacement of synthetic fibre is interesting in developing countries where the availability of tropical plants and agricultural waste is important. This paper presents an initial investigation on the use of a construction material, composed of cement and pre-treated (heat or alkaline treatments) sugar cane bagasse fibres. The purpose of this study is to analyse the effect of fibre content and treatment on thermal conductivity, specific heat, flexural strength and density. The addition of retified fibres reduces composites thermal conductivity and yields a weaker specific heat in comparison with composites made with alkaline fibres. From mechanical point of view, composites made with alkaline fibres have a better flexural strength than others.
12th International Inorganic-bonded Fiber Composites Conference
Aalborg, Denmark

hal-00807543
https://hal.univ-antilles.fr/hal-00807543

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
A new method to grow large single crystals with stoichiometry close to 1:1:2 of CuInSe2, an important member of the I-III-VI2 family of chalcopyrite semiconductors for optoelectronic device applications, is described. This is called the horizontal varying gradient zone freeze technique and consists of the selenization in the liquid phase of stoichiometric Cu and In and later solidification under programmed varying gradient in a fully automated multiple zone horizontal furnace. All ingots obtained with Se pressure between 15 and 1760 mm of Hg were single phase having chalcopyrite structure and p-type conductivity. X-ray, DTA, optical and electrical characterizations of the samples taken from different parts of the ingots were made. From energy dispersive spectroscopy it is found that the samples of the ingot obtained with Se pressure at 836 mm of Hg were much closer to the ideal stoichiometry 1:1:2.
ISSN: 0022-0248

hal-00808624
https://hal.univ-antilles.fr/hal-00808624
DOI : 10.1016/0022-0248(95)00346-0

Éditeur(s) : HAL CCSD University of Minho
Résumé : International audience
13th International Congress on Polymers in Concrete
Madeira, Portugal

hal-00807961
https://hal.univ-antilles.fr/hal-00807961

Éditeur(s) : HAL CCSD
Résumé : International audience
The results of the Shubnikov-De Haas (SDH) oscillation measurements on CuInSe2-doped (CIS) crystals are presented for the first time. The measurements were performed in the temperature range from 1.9 to 40 K in pulsed magnetic fields up to 40 T. It was found that the Fermi surface of electrons consisted of one sphere. The values of the cyclotron effective mass at the bottom of the conduction band, the inter-band momentum matrix element and the g* factor were calculated.
Applied Physic Letters

hal-00808595
https://hal.univ-antilles.fr/hal-00808595
DOI : 10.1063/1.107741

Éditeur(s) : HAL CCSD ICE Publishing
Résumé : International audience
ISSN: 2049-1220

hal-01685775
https://hal.univ-antilles.fr/hal-01685775
DOI : 10.1680/jgrma.15.00012