Éditeur(s) : Copernicus Gesellschaft Mbh
Résumé : The distributions of the bio-essential trace element dissolved cobalt (DCo) and the apparent particulate Co (PCo) are presented along the GEOTRACES-A02 deep section from 64(o) N to 50(o) S in the western Atlantic Ocean (longest section of international GEOTRACES marine environment program). PCo was determined as the difference between total cobalt (TCo, unfiltered samples) and DCo. DCo concentrations ranged from 14.7 pM to 94.3 pM, and PCo concentrations from undetectable values to 18.8 pM. The lowest DCo concentrations were observed in the subtropical domains, and the highest in the low-oxygenated Atlantic Central Waters (ACW), which appears to be the major reservoir of DCo in the western Atlantic. In the Antarctic Bottom Waters, the enrichment in DCo with aging of the water mass can be related to suspension and redissolution of bottom sediments a well as diffusion of DCo from abyssal sediments. Mixing and dilution of deep water masses, rather than scavenging of DCo onto settling particles, generated the meridional decrease of DCo along the southward large-scale circulation in the deep western Atlantic. Furthermore, the apparent scavenged profile of DCo observed in the deep waters likely resulted from the persistence of relatively high concentrations in intermediate waters and low DCo concentrations in underlaying bottom waters. We suggest that the 2010 Icelandic volcanic eruption could have been a source of DCo that could have been transported into the core of the Northeast Atlantic Deep Waters. At intermediate depths, the high concentrations of DCo recorded in the ACW linearly correlated with the apparent utilization of oxygen (AOU), indicating that remineralization of DCo could be significant (representing up to 37% of the DCo present). Furthermore, the preferential remineralization of phosphate (P) compared to Co in these low-oxygenated waters suggests a decoupling between the deep cycles of P and Co. The vertical diffusion of DCo from the ACW appears to be a significant source of DCo into the surface waters of the equatorial domain. Summarizing, the dilution due to mixing processes rather than scavenging of DCo and the above-mentioned remineralization could be the two major pathways controlling the cycling of DCo into the intermediate and deep western Atlantic.
Biogeosciences (1726-4170) (Copernicus Gesellschaft Mbh), 2014 , Vol. 11 , N. 6 , P. 1561-1580

Droits : Author(s) 2014. CC Attribution 3.0 License.
http://archimer.ifremer.fr/doc/00241/35223/33727.pdf
DOI:10.5194/bg-11-1561-2014
http://archimer.ifremer.fr/doc/00241/35223/

Éditeur(s) : Yale University
Résumé : Data from a hydrographic section carried out in January-March 1994 offshore from the eastern coast of South America from 50S to 10N, are used to quantify the full-depth exchanges of water between the western boundary currents and the ocean interior. In the upper and intermediate layers, the westward transport associated with the southern branch of the South Equatorial Current was 49 Sv at the time of the cruise. The transports of the central and northern branches in the upper 200 m were 17 Sv and 12 Sv, respectively. After subtraction of the parts that recirculate in the subtropical, subequatorial, and equatorial domains, the fraction of the South Equatorial Current that effectively contributes to the warm water export to the North Atlantic is estimated at 18 Sv. The poleward boundary of the current southern branch is at 31S through the whole thickness of the subtropical gyre, but the latitude of the northern boundary varies from 7 degrees 30'S at the surface to 27S at 1400 m depth. The estimated latitude of its bifurcation into the Brazil Current and North Brazil Undercurrent also varies downward from about 14S at the surface to 28S at a depth of 600 m.In the North Atlantic Deep Water, eastward flows exceeding 10 Sv are observed at 3 degrees -4 degrees of latitude in both hemispheres, at 10S, and at 34S-30S. Between 4S and 17S, a net westward flow with an estimated transport of 19 Sv reinforces the southward deep western boundary current. Cyclonic circulations of Antarctic Bottom Water along the western boundaries of the Argentine and Brazil basins have amplitudes of 15 Sv and 13 Sv, respectively, exceeding those of the interbasin exchanges. The net alongshore transport of this water mass between the hydrographic section and the continental slope reverses to a southward direction from 13S to 27S, probably in relation with an eastward shift of the equatorward near-bottom boundary current at these latitudes.
Journal of Marine Research (0022-2402) (Yale University), 2000-11 , Vol. 58 , N. 6 , P. 1007-1039

Droits : 2000 Yale University
http://archimer.ifremer.fr/doc/2000/publication-803.pdf
DOI:10.1357/002224000763485782
http://archimer.ifremer.fr/doc/00000/803/

Éditeur(s) : Elsevier Science Bv
Résumé : For many trace elements, continental margins are the location of intense exchange processes between sediment and seawater, which control their distribution in the water column, but have yet to be fully understood. In this study, we have investigated the impact of fluid seepage at cold seeps on the marine cycle of neodymium. We determined dissolved and total dissolvable (TD) concentrations for REE and well-established tracers of fluid seepage (CH4, TDFe, TDMn), and Nd isotopic compositions in seawater samples collected above cold seeps and a reference site (i.e. away from any fluid venting area) from the Niger Delta margin. We also analyzed cold seep authigenic phases and various core-top sediment fractions (pore water, detrital component, easily leachable phases, uncleaned foraminifera) recovered near the hydrocast stations. Methane, TDFe and TDMn concentrations clearly indicate active fluid venting at the studied seeps, with plumes rising up to about 100 m above the seafloor. Depth profiles show pronounced REE enrichments in the non-filtered samples (TD concentrations) within plumes, whereas filtered samples (dissolved concentrations) exhibit slight REE depletion in plumes relative to the overlying water column and display typical seawater REE patterns. These results suggest that the net flux of REE emitted into seawater at cold seeps is controlled by the presence of particulate phases, most probably Fe-Mn oxyhydroxides associated to resuspended sediments. At the reference site, however, our data reveal significant enrichment for dissolved REE in bottom waters, that clearly relates to diffusive benthic fluxes from surface sediments. Neodymium isotopic ratios measured in the water column range from epsilon(Nd) similar to-15.7 to -10.4. Evidence that the epsilon(Nd) values for Antarctic Intermediate waters (AAIW) differed from those reported for the same water mass at open ocean settings shows that sediment/water interactions take place in the Gulf of Guinea. At each site, however, the bottom water epsilon(Nd) signature generally differs from that for cold seep minerals, easily leachable sediment phases, and detrital fractions from local sediments, ruling out the possibility that seepage of methane-rich fluids and sediment dissolution act as a substantial source of dissolved Nd to seawater in the Gulf of Guinea. Taken together, our data hence suggest that co-precipitation of Fe-Mn oxyhydroxide phases in sub-surface sediments leads to quantitative scavenging of dissolved REE at cold seeps, preventing their emission into bottom waters. Most probably, it is likely that diffusion from suboxic surface sediments dominates the exchange processes affecting the marine Nd cycle at the Niger Delta margin. (C) 2011 Elsevier B.V. All rights reserved.
Earth And Planetary Science Letters (0012-821X) (Elsevier Science Bv), 2011-12 , Vol. 312 , N. 3-4 , P. 443-452

Droits : 2011 Elsevier B.V. All rights reserved.
http://archimer.ifremer.fr/doc/00066/17754/15571.pdf
DOI:10.1016/j.epsl.2011.10.008
http://archimer.ifremer.fr/doc/00066/17754/

Éditeur(s) : Elsevier
Résumé : A comprehensive analysis of velocity data from subsurface floats in the northwestern tropical Atlantic at two depth layers is presented: one representing the Antarctic Intermediate Water (AAIW, pressure range 600-1050dbar), the other the upper North Atlantic Deep Water (uNADW, pressure range 1200-2050dbar). New data from three independent research programs are combined with previously available data to achieve blanket coverage in space for the AAIW layer, while coverage in the uNADW remains more intermittent. Results from the AAIW` mainly confirm previous studies on the mean flow, namely the equatorial zonal and the boundary currents, but clarify details on pathways, mostly by virtue of the spatial data coverage that sets float observations apart from e.g. shipborne or mooring observations. Mean transports in each of five zonal equatorial current bands is found to be between 2.7 and 4.5 Sv. Pathways carrying AAIW northward beyond the North Brazil Undercurrent are clearly visible in the mean velocity field, in particular a northward transport of 3.7Sv across 16 degrees N between the Antilles islands and the Mid-Atlantic Ridge. New maps of Lagrangian eddy kinetic energy and integral time scales are presented to quantify mesoscale activity. For the uNADW, mean flow and mesoscale properties are discussed as data availability allows. Trajectories in the uNADW east of the Lesser Antilles reveal interactions between the Deep Western Boundary Current (DWBC) and the basin interior, which can explain recent hydrographic observations of changes in composition of DWBC water along its southward flow. (C) 2009 Elsevier Ltd. All rights reserved.
Deep Sea Research Part I: Oceanographic Research Papers (0967-0637) (Elsevier), 2009-10 , Vol. 56 , N. 10 , P. 1615-1632

Droits : 2009 Elsevier Ltd All rights reserved.
http://archimer.ifremer.fr/doc/2009/publication-6815.pdf
DOI:10.1016/j.dsr.2009.06.002
http://archimer.ifremer.fr/doc/00000/6815/

Éditeur(s) : Gauthier-Villars
Résumé : Moored current measurements carried out from 31 March 1990 to 15 September 1991 in two stages at a point (near 6 degrees N) located over the mid-continental slope off French Guiana are presented. Six current meters were positioned between 200 and 2700 m depth. Upper level mean current data showed a northwestward flowing North Brazil Current (NBC) with mean velocity values decreasing from 10 cm/s in the range 200-250 m to almost zero at 800 m depth, the level of the Antarctic Intermediate Waters. In the range 500-800 m, the current reversed in spring in the presence of the southeastward Western Boundary Under Current (WBUC); the mean velocity from February to June 1991 is around 2 cm/s. Deep currents over the continental rise show a strong southeastward Deep Western Boundary Current extending from around 1000 m depth to the bottom (3000 m depth in this case) with mean core speeds of 20 cm/s at 2000-2070 m depth. Transport estimates based on these data and a few Pegasus sections for the mean vertical and lateral extensions of the DWBC yield a value of 21 x 10(6) m(3)/s at that location. Low-frequency current fluctuations were dominated by a well-defined 50- to 70-day period oscillation with peak-to-peak northwestward velocity amplitude of around 90 cm/s at the upper level. The mean vertical eddy kinetic energy distribution showed an abrupt decrease of the energy down to 800 m depth and a slight decrease below and down to the bottom.
Oceanologica Acta (0399-1784) (Gauthier-Villars), 1994 , Vol. 17 , N. 4 , P. 345-354

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/00098/20897/18510.pdf
http://archimer.ifremer.fr/doc/00098/20897/