Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Heletz sandstone (Israel) reactivity is studied by means of CO2-rich brine percolation experiments and modeling. Experiments are performed at in situ temperature and pressure conditions with two distinctly different injection flow rates and for two different brine compositions: the genuine Heletz brine and a similar brine but in equilibrium with gypsum. The Heletz sandstone is composed of quartz, dolomite, ankerite, K-feldspar, clay minerals and minor amounts of gypsum and pyrite. The main reaction is the dissolution of the carbonates which is fastest for the highest flow rate injection and for the genuine Heletz brine. Permeability increases during the five percolation experiments, regardless of flow rate and brine type. This increase in permeability is associated to a decrease in porosity during the gypsum-equilibrated brine experiments due to gypsum precipitation. The precipitation of secondary minerals (kaolinite, muscovite and smectite) is mainly controlled by the dissolution of K-feldspar and largest at low flow rate injection, indicating that these precipitation processes are diffusion-controlled and localized in immobile zones where favorable chemical micro-environments exist. These processes are quantified by means of a reactive transport model. These results indicated that the CO2 injection at the Heletz site should trigger both permeability increase in interface between brine and CO2, which may extend over a large extension and where mixing processes are very active, especially near the well under intermittent injection conditions.
ISSN: 1750-5836

hal-01356329
https://hal.archives-ouvertes.fr/hal-01356329
DOI : 10.1016/j.ijggc.2015.10.023

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Saline aquifers in deep sedimentary formations are considered the primary candidates for geological storage of CO2, due to their large volumetric capacity that would be sufficient to meet the needs for CCS storage space in a global scale. In comparison to depleted oil and gas reservoirs the deep saline aquifers are, however, less investigated as there has previously been little economic interest in them. Effective methods for characterizing the storage aquifers are crucial for a successful implementation of any CCS project and therefore being developed and transferred from other applications in a various CCS projects.The objective of EU FP7 funded project MUSTANG project (A multiple space and time scale approach for the quantification of deep saline formations for CO2 storage, www.co2mustang.eu) has been to develop methods for characterizing saline aquifers and for understanding their properties. An essential part of this was establishment of a CO2 injection site at Heletz, Israel, where small-scale scientifically motivated injection experiments are planned to be carried out in presently ongoing continuation projects TRUST (http://trust-co2.org/) and CO2QUEST (www.co2quest.eu).While a large number of publications has been already produced based on the work in the MUSTANG project and its successors, and published in different journals, including this one, the objective of this Special Edition has been to gather some of the concluding work in the same journal issue. The focus has in particular been in summarizing the site characterization work carried out at the Heletz site, thereby providing readers an easy overview of the findings and characteristics of the site. In addition, some related work from some of the other sites investigated in MUSTANG project is also included, namely work from the sites Hontomin, Maguelone and a natural analog site in the North Sea. The results are intended to add to our understanding on relevant properties of geological formations as candidates for CO2 geological storage.
ISSN: 1750-5836

hal-01356326
https://hal.archives-ouvertes.fr/hal-01356326
DOI : 10.1016/j.ijggc.2016.02.007

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
To evaluate the performance of downhole and surface geophysical monitoring methods, a series of shallow gas injection-monitoring experiments has been performed in a coastal saline aquifer at Maguelone, France. The recorded data include pressure measurements with a Westbay multilevel completion and CO2 saturation at an observation well derived from electrical resistivity with a modified Waxman-Smits (MWS) model. In this work, the aim is to develop a simulation model capturing the gas transport behavior and consistent with field data. For this purpose, the simulation of the CO2 injection experiment is carried out with two conceptual models, a homogeneous model and a heterogeneous model treated with multiple realization Monte Carlo simulations. Numerical simulator TOUGH2 with the equation of state module EOS7C is used for the simulations. Comparison of the model results with field data suggests that the pressure responses are captured with relatively good accuracy. Similarly, the model also provides an overall reasonable agreement and correct order of magnitude for predicted gas saturation values. However, as the heterogeneity pattern in the field data remains largely unknown, the model predictions can only be used to capture the mean behavior as well as to provide insights into how heterogeneity can influence the system behavior, by means of sensitivity analyses of the influence of heterogeneities on individual realizations.
ISSN: 1750-5836

hal-01467240
https://hal.archives-ouvertes.fr/hal-01467240
DOI : 10.1016/j.ijggc.2016.09.006