Éditeur(s) : HAL CCSD
Résumé : Volatile-rich, silica-undersaturated alkaline lavas record the important role of fluids during fluid-rock and magma-rock interactions in the mantle, which are key processes to understand the dynamics of the convective mantle and lithosphere-asthenosphere interactions in intracontinental settings. The aim of this thesis is to bring new constraints on the genesis of alkaline magmas by characterizing the crystallization conditions, the source and the partial melting processes taking part in the genesis of olivine nephelinites, pyroxene nephelinites and basanites from the Jbel Saghro volcanic field in the Moroccan Anti Atlas.The petrological and geochemical study of rocks and minerals coupled with the analysis of fluid inclusions constrains the pre-eruptive conditions of Saghro nephelinites to 1.7–2.2 GPa and ~1350 °C. Minerals show that nephelinitic magmas are rich in volatile elements (Cl, F, S), and fluid inclusions indicate that magmas were saturated with a CO2-rich fluid at pressures > 590 MPa. The various mineralogical assemblages and the presence of peridotite xenoliths suggest a rapid ascent for olivine nephelinites and more complex processes at depth for pyroxene nephelinites.Fractional crystallization and partial melting modelling of Saghro mafic lavas indicate that they are low-degree melts (0.6–2.5 %) of an amphibole-bearing carbonated peridotite enriched in incompatible elements, at the garnet-spinel transition (~80–85 km). Saghro nephelinites display a temporal evolution with a slight increase of the degree of melting and a decrease of the amount of residual amphibole from the oldest (olivine nephelinites, 9.6 Ma) to the most recent (pyroxene nephelinites, 2.9 Ma). Basanites form a system that is independent from nephelinites and are slightly higher-degree melts. Important variations in their chemical composition suggest variable amounts of fractional crystallization during ascent.The peculiar characteristics of Saghro nephelinites and basanites (enrichment in incompatible elements, negative anomalies in K, Zr, Hf and Ti, high Ca/Al and Zr/Hf ratios) indicate that their source was affected by carbonatitic metasomatism. The influence of this metasomatism is stronger for pyroxene nephelinites than for olivine nephelinites. These results suggest fluid-rock interactions beneath the Northwest African Craton, leading to the formation of a metasomatized mantle by CO2-rich carbonatitic components at the lithosphere-asthenosphere transition. The origin of the metasomatism inducing source enrichment and the formation of amphibole veins could be attributed to the melting of relict subducted oceanic lithosphere. The relatively low melting temperatures (< 1350 °C) suggest the absence of a thermal anomaly beneath the Jbel Saghro, and thus support a lithosphere delamination model as precursor of Saghro volca0,3nism. However, the increasing degree of partial melting over time, also observed in the Middle Atlas, together with the isotopic and geochemical similarities with Canary Islands alkaline lavas does not allow us to discard the influence of a deviation of the Canary mantle plume beneath northwest Africa.
Les laves alcalines sous-saturées riches en éléments volatils sont les marqueurs du rôle important des fluides dans le manteau et des interactions fluide-roche et magma-roche, processus clés pour comprendre la dynamique du manteau convectif et les interactions asthénosphère-lithosphère en domaine intracontinental. L’objectif de cette thèse est d’apporter de nouvelles contraintes sur la genèse des magmas alcalins en caractérisant les conditions de cristallisation, la source et les processus de fusion partielle à l’origine des néphélinites à olivine, des néphélinites à pyroxène et des basanites du champ volcanique du Jbel Saghro dans l’Anti-Atlas marocain.L’étude pétrologique et géochimique des roches et des minéraux, couplée à l’analyse des inclusions fluides a permis de contraindre les conditions pré-éruptives des néphélinites de Saghro à 1.7–2.2 GPa et ~1350 °C. Les minéraux montrent que les magmas néphélinitiques sont riches en éléments volatils (Cl, F, S), et les inclusions fluides indiquent que les magmas étaient saturés en fluide riche en CO2 à des pressions > 590 MPa. Les différents assemblages minéralogiques des néphélinites et la présence de xénolites péridotitiques suggèrent une ascension rapide des néphélinites à olivine et des processus plus complexes en profondeur pour les néphélinites à pyroxène.La modélisation des processus de cristallisation fractionnée et de fusion partielle des laves mafiques de Saghro a permis de déterminer qu’elles sont issues de faibles taux de fusion partielle (0.6–2.5 %) d’une péridotite carbonatée enrichie en éléments incompatibles, au niveau de la transition grenat–spinelle (~80–85 km) et en présence d’amphibole. Les néphélinites de Saghro montrent une évolution temporelle avec une légère augmentation du taux de fusion et une diminution de la quantité d’amphibole au résidu des plus anciennes (néphélinites à olivine, 9.6 Ma) aux plus récentes (néphélinites à pyroxène, 2.9 Ma). Les basanites forment un système indépendant des néphélinites et sont issues de taux de fusion plus élevés. Les fortes variations dans leur composition chimique suggèrent qu’elles ont subi de la cristallisation fractionnée lors de leur ascension.Les caractéristiques particulières des néphélinites et basanites de Saghro (enrichissement en éléments incompatibles, anomalies négatives en K, Zr, Hf et Ti, rapports Ca/Al et Zr/Hf élevés) indiquent que leur source a subi un métasomatisme principalement carbonatitique. L’influence de ce métasomatisme est plus forte pour les néphélinites à pyroxène que pour les néphélinites à olivine, impliquant une évolution temporelle de l’intensité du métasomatisme. Ces résultats suggèrent des interactions fluide-roche sous le craton Nord-Ouest Africain, entraînant la formation d'un manteau métasomatisé par des composants carbonatitiques riches en CO2 au niveau de la transition lithosphère-asthénosphère. L’origine du métasomatisme provoquant l’enrichissement de la source et la formation de veines d’amphibole pourrait être liée à la fusion de reliquats de croûte océanique subductée. Les températures de fusion relativement faibles (< 1350 °C) suggèrent l’absence d’anomalie thermique sous le Jbel Saghro, et favorisent donc un modèle de délamination de la lithosphère comme initiateur du volcanisme. Cependant, l’augmentation du taux de fusion partielle au cours du temps, également observée dans le Moyen Atlas, et les similitudes isotopiques et géochimiques avec les laves alcalines des îles Canaries ne permettent pas d’exclure une influence du panache des Canaries sur la source du volcanisme alcalin du Jbel Saghro.
https://tel.archives-ouvertes.fr/tel-01615888

NNT : 2015MONTS070
tel-01615888
https://tel.archives-ouvertes.fr/tel-01615888
https://tel.archives-ouvertes.fr/tel-01615888/document
https://tel.archives-ouvertes.fr/tel-01615888/file/53752_CHAMBOREDON_2015_archivage_cor.pdf

Éditeur(s) : HAL CCSD
Résumé : This thesis compiles two distinct studies that both document the control of microstructures on rock seismic properties. The first part deals with the development of crystallographic preferred orientations (CPO) in the uppermost mantle associated with melt/fluid-rock interactions, recorded in peridotites xenoliths from the Japan sea back-arc basin. The microstructural and geochemical characteristics of the studied samples reveal that active spreading is associated to uppermost mantle deformation similar to that observed in the Oman ophiolite. At the onset of back-arc spreading, there are no strong interactions between melt percolation and deformation in comparison to continental rift zones, probably due to the relatively small size and short duration of the spreading event. The second part presents a unique database of plagioclase CPO from variously deformed mafic rocks. CPO are grouped in three main types; their characteristics as a function of deformation regime (magmatic or crystal-plastic) are outlined and discussed. Calculated seismic properties of gabbroic rocks show that anisotropy tends to increase as a function of fabric strength, although it is generally weak, due to the competing effect of olivine/clinopyroxene and plagioclase.
Cette thèse regroupe deux études distinctes, qui documentent le contrôle des microstructures sur les propriétés sismiques des roches. La première partie traite du développement des orientations préférentielles cristallographiques (OPC) dans le manteau supérieur, associé aux interactions liquide/magma-roche, enregistré dans des xénolites de péridotites du bassin d'arrière-arc de la mer du Japon. Les caractéristiques microstucturales et géochimiques des échantillons étudiés montrent que l'ouverture arrière-arc active est associée à une déformation du manteau supérieure similaire à celle observée dans l'ophiolite d'Oman. L'initiation de l'extension d'arrière-arc n'est pas associée à de fortes interactions entre percolation magmatique et déformation, en comparaison avec les zones de rifting continentales, probablement en raison des taille et durée relativement petites de l'épisode d'ouverture. La seconde partie présente une base de données unique d'OPC de plagioclase de roches mafiques plus ou moins déformées. Les OPC sont classées en 3 types principaux; leurs caractéristiques en fonction du régime de déformation (magmatique ou plastique) sont présentées et discutées. Les propriétés sismiques calculées des roches gabbroiques montrent que l'anisotropie tend à croitre avec l'intensité des fabriques, bien qu'elle soit généralement faible, en raison des effets opposés des olivines/clinopyroxènes et du plagioclase.
https://tel.archives-ouvertes.fr/tel-00795505

tel-00795505
https://tel.archives-ouvertes.fr/tel-00795505
https://tel.archives-ouvertes.fr/tel-00795505/document
https://tel.archives-ouvertes.fr/tel-00795505/file/Satsukawa_thesis_UM2.pdf

Éditeur(s) : HAL CCSD Oxford University Press (OUP): Policy B - Oxford Open Option A Oxford University Press (OUP)
Résumé : International audience
Peridotites exhumed in the footwall of axial detachment faults at slow-spreading ridges are highly serpentinized. Most mid-ocean ridge detachment settings are magmatically active and hydrous fluid circulation in and near the fault has been shown to be influenced by the presence of melt or magmatic lithologies. Our working area along the Southwest Indian Ridge (62–65°E) is nearly amagmatic and represents an end-member to study the hydrous alteration of exhumed peridotites without these magmatic influences. We use an integrated petrological approach combining microstructural, mineralogical and chemical observations to unravel the sequence of serpentinization in 272 dredged samples of variably serpentinized peridotites and to document the circulation of serpentinizing fluids in and near the exhumation faults. We find that serpentine recrystallization and veins overprint the initial serpentinite mesh texture in ∼25% of the samples. Oxygen isotope data suggest that this sequence developed at relatively high temperatures (271–336°C) and under increasing fluid–rock ratios, from near stoichiometry for mesh texture formation to >10 during recrystallization. Increasing fluid supersaturation relative to serpentine favors the replacement of mesh texture lizardite by chrysotile and polygonal or polyhedral serpentine. We attribute local recrystallization into antigorite to moderate Si-metasomatism, possibly following pyroxene serpentinization. We do not observe the more pronounced Si-metasomatism leading to talc replacing serpentine that is reported for the more magmatically active Mid-Atlantic Ridge detachment settings and is attributed to prior leaching of magmatic rocks. Scales of preferential fluid pathways in our samples evolved from pervasive and close-spaced (<500 µm) microfractures during the formation of the initial serpentine mesh texture, to centimeter-thick planar domains of enhanced fluid flux, spaced at ∼10 cm intervals and probably grouped in corridors that may be up to ∼100 m across. Serpentine minerals are enriched in some fluid-mobile elements (Cl, B, U) relative to the peridotite protolith, and several elements (Al, Fe, Si, Cu, As, Sb, REE) are redistributed at the millimeter to decimeter scale. Serpentinizing fluids were seawater-derived, probably mildly alkaline (small to no europium anomalies), reducing and H2-enriched (formation of magnetite). These fluids may have been similar to, though warmer than, those venting at the ultramafic-hosted Lost City hydrothermal fluid (30°N, Mid-Atlantic Ridge).
ISSN: 0022-3530

hal-01174047
https://hal.archives-ouvertes.fr/hal-01174047
DOI : 10.1093/petrology/egv014

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
This study analyses the interactions between deformation and reactive fluid and melt percolation, and their effects on sub-arc mantle seismic properties based on microstructural observations on mantle xenoliths extracted by the Tubaf and Edison seamounts close to the Lihir Island, in the Papua New Guinea archipelago. These xenoliths sample an oceanic lithosphere, which has experienced high-temperature deformation in the presence of fluids or melts. This was followed by metasomatism under static conditions. Syn-kinematic percolation of reactive Si-rich melts or fluids in peridotites has produced pyroxene-enrichment, grain size reduction, and dispersion of olivine crystal preferred orientation (CPO). Fourier transform infrared spectroscopy analyses show that olivine has very low water contents (1-4 wt. ppm H2O), similar to spinel peridotites from other subduction zones. These low values may record both low water solubility in olivine at low pressure and dehydration during transport and exhumation. Water contents in pyroxenes are highly variable and likely result from spatially heterogeneous melt or fluid percolation. Analysis of olivine CPO indicates dominant activation of both (010)[100] and (001)[100] slip systems, which are characteristic of deformation under high temperature, low stress, low pressure and low to moderate hydrous conditions. Fast S-wave polarization and P- and Rayleigh propagation directions are thus parallel to the mantle flow direction. The pyroxene enrichment by melt-rock reactions is accompanied by dispersion of olivine CPO and induces a significant decrease of the maximum S-wave and P-wave anisotropy in the peridotites. The calculated seismic properties also show that the lowest Vp/Vs ratios (< 1.7) mapped in fore-arc mantle may only be explained by taking in consideration the CPO-induced elastic anisotropy of the peridotites.
ISSN: 0040-1951

hal-00950058
https://hal.archives-ouvertes.fr/hal-00950058
DOI : 10.1016/j.tecto.2013.09.024

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
The mantle above a subducting slab is the site of complex interactions between deformation, partial melting, fluid migration and magma transport. To constrain these interactions and their effects on olivine deformation, we analyze microstructures, crystal preferred orientations, and water contents of peridotite xenoliths entrained by andesites of the Avacha volcano, southern Kamchatka arc. These xenoliths are refractory spinel harzburgites that have coarse-grained microstructures with widely spaced subgrain boundaries and sinuous grain boundaries in olivine, consistent with deformation by dislocation creep under low deviatoric stress (< 13 MPa) and with a significant contribution from diffusional processes. Analysis of crystal preferred orientations (CPO) indicates dominant activation of high-temperature, low-stress {0kl}[100] slip systems in olivine and of(100)[001] in orthopyroxene. In most samples, coarse opx crystals, elongated parallel to the lineation, enclose small olivine grains in crystallographic continuity with neighbouring crystals, indicating crystallization of orthopyroxene at the expense of olivine as a result of reactive percolation of Si-rich fluids coeval with the high-temperature deformation. Secondary crystallization of interstitial orthopyroxene led locally to development of opx-rich lenses parallel to the foliation, characterized by a decrease in olivine grain size and dispersion of the olivine CPO without changing the dominant slip systems. Half of the samples also show acicular orthopyroxene aggregates with which is associated a fine-grained matrix composed of rounded strain-free olivine, orthopyroxene, spinel, and rare amphibole crystals. This matrix occurs pervasively along grain boundaries or forms millimeter-scale irregular lenses and anastomosing veinlets that crosscut the coarse crystals and their ductile deformation structures. Both acicular orthopyroxene and the fine-grained matrix are interpreted as resulting from reactive transport of H2O-rich fluids under static conditions, probably in the lithospheric mantle. Infrared analyses show that olivine contains 1-8 center dot 6 ppm by weight of water. These low water contents are similar to those observed in spinel peridotites from other subduction zones and probably record both the low solubility of water in olivine at low pressure and dehydration during exhumation of the xenoliths. Water contents in orthopyroxene are highly variable (25-506 ppm H2O), probably recording spatially heterogeneous interaction with fluids or melts and compositional disequilibrium in the studied samples. Change in the dominant percolation mechanism from porous flow to fracturing suggests cooling, consistent with the low temperatures estimated from pyroxene thermometry (< 800-900 degrees C). The Avacha xenoliths therefore record pervasive deformation of a region of the mantle under asthenospheric conditions, followed by its accretion to the base of the lithosphere, probably as a result of cooling of the mantle wedge. Percolation of Si-rich fluids or hydrous melts is recorded at all stages; this probably enhanced diffusion and lowered deviatoric stresses during ductile deformation, but did not change the dominant slip direction in olivine from [100] to [001].
ISSN: 0022-3530

hal-00456053
https://hal.archives-ouvertes.fr/hal-00456053
DOI : 10.1093/petrology/egp085

Éditeur(s) : HAL CCSD Elsevier
Résumé : The uppermost mantle in back arc regions is the site of complex interactions between partial melting, melt percolation, and fluid migration. To constrain these interactions and evaluate their consequences on geochemical cycles, we carried out an in situ trace element and water study of a suite of spinel peridotite xenoliths from two regions of the Japan back arc system, Ichinomegata (NE Japan) and Oki-Dogo (SW Japan), using LA-ICPMS and FTIR spectrometry, respectively. This study provides the first full dataset of trace element and hydrogen compositions in peridotites including analyses of all their main constitutive silicate minerals: olivine, orthopyroxene and clinopyroxene. The Ichinomegata peridotites sample a LREE-depleted refractory mantle (Mg# olivine = 0.90; Cr# spinel = 0.07–0.23; Yb clinopyroxene = 7.8–13.3 × C1-chondrite, and La/Yb clinopyroxene = 0.003–0.086 × C1-chondrite), characterized by Th-U positive anomalies and constant values of Nb/Ta. The composition of the studied Ichinomegata samples is consistent with that of an oceanic mantle lithosphere affected by cryptic metasomatic interactions with hydrous/aqueous fluids (crypto-hydrous metasomatism). In contrast, the Oki-Dogo peridotites have low Mg# olivine (0.86–0.93) and a broad range of compositions with clinopyroxene showing “spoon-shaped” to flat, and LREE-enriched patterns. They are also characterized by their homogeneous compositions in the most incompatible LILE (e.g., Rb clinopyroxene = 0.01–0.05 × primitive mantle) and HFSE (e.g., Nb clinopyroxene = 0.01–2.16 × primitive mantle). This characteristic is interpreted as resulting from various degrees of melting and extensive melt-rock interactions. FTIR spectroscopy shows that olivine in both Ichinomegata and Oki-Dogo samples has low water contents ranging from 2 to 7 ppm wt. H2O. In contrast, the water contents of pyroxenes from Ichinomegata peridotites (113–271 ppm wt. H2O for orthopyroxene, and 292–347 ppm wt. H2O for clinopyroxene) are significantly higher than in Oki-Dogo peridotites (9–35 ppm wt. H2O for orthopyroxene, and 15–98 ppm wt. H2O for clinopyroxene). This indicates a relationship between melt-rock interaction and water concentrations in pyroxenes. Our study suggests that the water content of the Japan mantle wedge is controlled by the late melt/fluid/rock interactions evidenced by trace element geochemistry: a mechanism triggered by magma-rock interactions may have acted as an efficient dehydrating process in the Oki-Dogo region while the Ichinomegata mantle water content is controlled by slab-derived crypto-hydrous metasomatism.
ISSN: 0016-7037

hal-01553105
https://hal.archives-ouvertes.fr/hal-01553105
DOI : 10.1016/j.gca.2017.03.042

Éditeur(s) : Oxford Univ Press
Résumé : In subduction zones, melting and dehydration of the subducted slab introduce material into the mantle wedge and modify its chemical and isotopic composition. As a consequence, island arc lavas differ significantly from mid-ocean ridge basalts and ocean island basalts. In some arcs, the composition of lavas is strongly influenced by the sedimentary material introduced with the slab; in others, magma composition is mainly affected by aqueous fluids released by the slab. The Lesser Antilles arc is known for its extreme continental-crust-like signature but for some Lesser Antilles lavas subducted sediments are barely involved and enrichment in fluid-mobile elements (Ba, U, Sr, Pb, etc.) is the dominant feature. Here we evaluate whether La/Sm is a quantitative proxy of sediment involvement in volcanic arcs, and we relate dehydration and melting processes to the temperature and pressure conditions of the slab. We use Martinique as a case study because in this island both dehydration and sediment melting fingerprints coexist. We measured major and trace elements for about 130 age-constrained samples, carefully chosen to cover all volcanic phases of Martinique (25 Ma to present). Using these results we demonstrate that: (1) weathering does not modify the La/Sm ratio; (2) fractional crystallization of amphibole and/or garnet does not increase La/Sm by more than 20%; (3) rare earth element transfer from wall-rock to magma during fractionation is not significant; (4) melting of the mantle source increases La/Sm by only about 20%. As a consequence, we show that the proportion of slab sediment incorporated in the mantle wedge controls the La/Sm ratio of the source. The observed correlations between La/Sm and Nd and Hf isotopic compositions indicate that the effect of sediment addition is the overwhelming factor: La/Sm is a good proxy for slab sediment proportion in Martinique. We observe a geographical gradient between slab dehydration and sediment melting on the island. Whereas lavas located on the western side of the island display a clear sedimentary input in their source, lavas located on the eastern side of the island, closer to the trench, are clearly influenced by dehydration of the subducted slab. In addition, the aqueous fluids clearly come from the subducted basalt and they did not interact with the overlying sediments. The influence of sediment added to the source of the magmas increases from the eastern part to the western part of the island. We relate this geographical change to the pressure and temperature conditions at the slab surface. Sediments probably cross their solidus under Martinique and hydrous melting is triggered. Finally, we show that under all volcanic arcs where the signature of sediments overwhelms the signature of fluids, the slab surface reaches P-T conditions that allow the subducted sediments to melt. Inversely, under most volcanic arcs where the signal of aqueous fluids dominates over sediment melts, the subducted slab is not hot enough for the sedimentary pile to melt.
Journal Of Petrology (0022-3530) (Oxford Univ Press), 2012-12 , Vol. 53 , N. 12 , P. 2441-2464

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/00113/22392/20234.pdf
DOI:10.1093/petrology/egs055
http://archimer.ifremer.fr/doc/00113/22392/

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Over the last decades, numerous studies have emphasized the role of serpentinites in the subduction zone geodynamics. Their presence and role in subduction environments are recognized through geophysical, geochemical and field observations of modern and ancient subduction zones and large amounts of geochemical database of serpentinites have been created. Here, we present a review of the geochemistry of serpentinites, based on the compilation of ~ 900 geochemical data of abyssal, mantle wedge and exhumed serpentinites after subduction. The aim was to better understand the geochemical evolution of these rocks during their subduction as well as their impact in the global geochemical cycle. When studying serpentinites, it is essential to determine their protoliths and their geological history before serpentinization. The geochemical data of serpentinites shows little mobility of compatible and rare earth elements (REE) at the scale of hand-specimen during their serpentinization. Thus, REE abundance can be used to identify the protolith for serpentinites, as well as magmatic processes such as melt/rock interactions before serpentinization. In the case of subducted serpentinites, the interpretation of trace element data is difficult due to the enrichments of light REE, independent of the nature of the protolith. We propose that enrichments are probably not related to serpentinization itself, but mostly due to (sedimentary-derived) fluid/rock interactions within the subduction channel after the serpentinization. It is also possible that the enrichment reflects the geochemical signature of the mantle protolith itself which could derive from the less refractory continental lithosphere exhumed at the ocean-continent transition. Additionally, during the last ten years, numerous analyses have been carried out, notably using in situ approaches, to better constrain the behavior of fluid-mobile elements (FME; e.g. B, Li, Cl, As, Sb, U, Th, Sr) incorporated in serpentine phases. The abundance of these elements provides information related to the fluid/rock interactions during serpentinization and the behavior of FME, from their incorporation to their gradual release during subduction. Serpentinites are considered as a reservoir of the FME in subduction zones and their role, notably on arc magma composition, is underestimated presently in the global geochemical cycle.
ISSN: 0024-4937

hal-00903601
https://hal.archives-ouvertes.fr/hal-00903601
DOI : 10.1016/j.lithos.2013.05.019

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Tectonic mixing of slab- and mantle-derived materials at the interface between converging plates highly enhances fluid-mediated mass transfer from the slab to the overlying mantle. Subduction mélanges can provide information about the interaction among different slices accreted at plate interface domains, with implications on the tectonic and geochemical evolution of the plate-interface itself. At Cima di Gagnone, pelitic schists and gneiss enclose chlorite harzburgite and garnet peridotite lenses, like in subduction mélanges located in-between downgoing slabs and overlying mantle. These peridotites host MORB-type eclogite and metarodingite, and derive from dehydration of serpentinized mantle protoliths. Their enrichment in fluid-mobile B, As, Sb, U, Th is the result of an early-stage oceanic serpentinization, followed by interaction with host metasediments during subduction burial. Here we define the element exchange process in the Gagnone mélange by means of the B, Sr and Pb isotope analysis of its main lithologies (ultramafic, mafic rocks and paragneiss). The 87Sr/86Sr and 206Pb/204Pb ratios of ultramafic rocks (0.7090–0.7124 and 18.292–18.837, respectively) show enrichments in radiogenic Sr and Pb after exchange with the host paraschist (up to 0.7287 87Sr/86Sr; 18.751 206Pb/204Pb). The δ11B values of peridotites (down to −10‰) point to a combined effect of (1) 11B release to deserpentinization fluids (serpentinized protoliths likely had positive δ11B and lower radiogenic Sr, Pb), and of (2) exchange with fluids from the surrounding metasediments. The whole Gagnone rock-suite is finally overprinted by retrograde fluids that essentially bring to an increase in radiogenic Pb (about 19.0 206Pb/204Pb) and to values of 0.710 87Sr/86Sr and of −10‰ δ11B. The recognition of different stages of interaction between mantle rocks and sedimentary/crustal reservoirs allows us to define the geochemical effects related to the early coupling of such rocks along the plate-interface. Our study shows that ultramafic rocks involved in subduction-zone metamorphism and serpentinization uptake radiogenic Pb and Sr released by associated sedimentary reservoirs. The exchange process envisioned here is not only representative of subduction mélanges: it can also be a proxy of mass transfer between slab and serpentinized supra-subduction mantle, as occurs in forearcs. Dehydration of the Gagnone-type serpentinized mantle releases crust-derived components to arcs, without direct involvement of metasediment dehydration and/or melting in subarc environments. The retention of appreciable amounts of fluid-mobile elements, radiogenic Pb and Sr in dehydrated Gagnone peridotites has implications on element recycling in the deep Earth’s mantle.
ISSN: 0016-7037

hal-01174137
https://hal.archives-ouvertes.fr/hal-01174137
DOI : 10.1016/j.gca.2015.04.024

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Sapat peridotite in Kohistan (NW Pakistan) is a 12x1 km sized body of meta-harzburgites, dunites, pyroxenites and meta-gabbros in the hanging wall of the Indus Suture Zone. Field relations, micro-textures, bulk and mineral chemistry document melt-rock reactions producing dunites at the expense of meta-harzburgites, and a consecutive olivine-clinopyroxenite formation from the same melt type. The association of mesa-gabbros, dunites, and pyroxenites is interpreted as a crust-mantle transition zone produced by the percolation of highly depleted primitive arc melt. The meta-harzburgites represent large portions of refractoty mantle that have suffered melt extraction and metasomatism prior to their interaction with the dunite-forming primitive arc melt and the establishment of the crust-mantle transition zone. Uncommon vein assemblages in the dunites that include Cr-clinochlore, calcite and olivine document a late percolation of slab-related, volatile-rich fluids. Taking into account the highly refractory composition of the Sapat mantle, its structural position, the evidence for interaction with highly depleted arc melts and the sub-solidus interaction with volatile-rich arc fluids, the Sapat ultramafic rocks are interpreted as being derived from the frontal Kohistan arc, representing a crust-mantle transition formed by arc magmatism.
ISSN: 0024-4937

hal-00424515
https://hal.archives-ouvertes.fr/hal-00424515
DOI : 10.1016/j.lithos.2008.07.004

Éditeur(s) : HAL CCSD Geological Society of America
Résumé : International audience
Fluid-rock interactions can control earthquake nucleation and the evolution of earthquake sequences. Experimental studies of fault frictional properties in the presence of fluid can provide unique insights into these interactions. We report the first results from experiments performed on cohesive silicate-bearing rocks (microgabbro) in the presence of pressurized pore fluids (H2O, drained conditions) at realistic seismic deformation conditions. The experimental data are compared with those recently obtained from carbonate-bearing rocks (Carrara marble). Contrary to theoretical arguments, and consistent with the interpretation of some field observations, we show that frictional melting of a microgabbro develops in the presence of water. In microgabbro, the initial weakening mechanism (flash melting of the asperities) is delayed in the presence of water; conversely, in calcite marble the weakening mechanism (brittle failure of the asperities) is favored. This opposite behavior highlights the importance of host-rock composition in controlling dynamic (frictional) weakening in the presence of water: cohesive carbonate-bearing rocks are more prone to slip in the presence of water, whereas the presence of water might delay or inhibit the rupture nucleation and propagation in cohesive silicate-bearing rocks.
ISSN: 0091-7613

hal-01054327
https://hal.archives-ouvertes.fr/hal-01054327
DOI : 10.1130/G34916.1

Éditeur(s) : HAL CCSD Elsevier
Résumé : Siberian cratonic mantle
International audience
The processes that control water distribution in nominally anhydrous minerals from peridotites are twofold. Melt depletion will remove water while metasomatism can potentially add water to these minerals. These processes can lead to a wide range of outcomes in water contents, which in turn could play a role in mantle rheology and long-term cratonic root stability. To examine these complexities, water concentrations in minerals from well-characterized peridotites from the Udachnaya kimberlite in the central Siberian craton were analyzed by FTIR. The peridotites span a complete top to bottom cross-section of typical cratonic lithospheric mantle (2-7 GPa and 700-1400 °C). Diffusion modeling of water content profiles across olivine grains shows that water loss during decompression is limited to the 100 μm rims of olivines; the cores preserved their mantle water contents. Water contents range from 6 to 323 ppm wt H2O in olivine, 28-301 ppm H2O in orthopyroxene (opx), 100-272 ppm H2O in clinopyroxene (cpx) and 0-23 ppm H2O in garnet. Melting modeling cannot reproduce the high water contents of cratonic mantle peridotites and any potential partial melting trend must have been erased by later events. The water contents of minerals, however, are correlated with modal abundances of clinopyroxene and garnet, bulk rock FeO, TiO2 and SiO2 as well as with light and middle rare earth elements in clinopyroxene and garnet. These relationships are best interpreted as interaction of residual, melt-depleted peridotites with silicate melt, which produced modal and cryptic metasomatism. Importantly, the water enrichment in the Siberian cratonic mantle took place prior to kimberlite magmatism and eruption. Water addition by metasomatism occurred from pressures >4 GPa all the way to the base of the cratonic root below central Siberia, but was limited to shallower levels (<5 GPa) in the Kaapvaal cratonic lithosphere. The difference in olivine water contents at the deepest levels of the Kaapvaal (<5 ppm H2O) and Siberian (6-323 ppm H2O) cratonic roots may be linked to oxygen fugacity and resulting fluid speciation or, alternatively, to reaction with different metasomatic agents. Calculated viscosities for the deepest Udachnaya samples are similar to those inferred for the asthenosphere. If these xenoliths are representative of the deep cratonic lithosphere, water is not as important a parameter as previously thought in the strength of cratonic lithosphere, otherwise the cratonic root beneath Udachnaya would have been delaminated. Alternatively, the metasomatic xenoliths may not be representative of the Siberian cratonic root and kimberlites preferentially sample cratonic mantle lithosphere material located near, and metasomatized by, melt conduits, which served as channels for upward migration of water-rich melts and fluids including kimberlites. In that case, the cratonic root overall still may have relatively low water contents, which in addition to its less metasomatized (more refractory) and thereby buoyant nature, still play a role in making it strong enough to resist delamination by the surrounding asthenosphere.
ISSN: 0016-7037

hal-01053920
https://hal.archives-ouvertes.fr/hal-01053920
DOI : 10.1016/j.gca.2014.04.011

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Spinel lherzolite xenoliths from Mont Briancon, French Massif Central, retain evidence for multiple episodes of melt depletion and melt/fluid infiltration (metasomatism). Evidence for primary melt depletion is still preserved in the co-variation of bulk-rock major elements (MgO 38.7-46.1 wt.%; CaO 0.9-3.6 wt.%), and many samples yield unradiogenic bulk-rock Os isotope ratios (Os-187/Os-188 = 0.11541-0.12626). However, many individual xenoliths contain interstitial glasses and melt inclusions that are not in equilibrium with the major primary minerals. Incompatible trace element mass balance calculations demonstrate that metasomatic components comprise a significant proportion of the bulk-rock budget for these elements in some rocks, ranging to as much as 25%, of Nd and 40% of Sr Critically, for Re-Os geochronology, melt/fluid infiltration is accompanied by the mobilisation of Sulfide. Consequently, bulk-rock isotope measurements, whether using lithophile (e.g. Rb-Sr, Sm-Nd) or siderophile (Re-Os) based isotope systems, may only yield a perturbed and/or homogenised average of these multiple events.;Osmium mass balance calculations demonstrate that bulk-rock Os in peridotite is dominated by contributions from two populations of sulfide grain: (i) interstitial, metasomatic Sulfide with low [Os] and radiogenic Os-187/Os-188, and (ii) primary sulfides with high [Os] and unradiogenic Os-187/Os-188, which have been preserved within host silicate grains and shielded from interaction with transient melts and fluid. The latter can account for >97% of bulk-rock Os and preserve geochronological information of the melt from which they originally precipitated as an immiscible liquid. The Re-depletion model ages of individual primary sulfide grains preserve evidence for melt depletion beneath the Massif Central from at least 1.8 Gyr ago despite the more recent metasomatic event(s). (C) 2009 Elsevier Ltd. All rights reserved.
ISSN: 0016-7037

hal-00454537
https://hal.archives-ouvertes.fr/hal-00454537
DOI : 10.1016/j.gca.2009.09.031

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Most peridotite massifs and mantle xenoliths show a wide range of isotopic variations, often involving significant decoupling between Hf, Nd and Sr isotopes. These variations are generally ascribed either to mingling of individual components of contrasted isotopic compositions or to time integration of parent-element enrichment by percolating melts/fluids, superimposed onto previous depletion event(s). However, strong isotopic decoupling may also arise during porous flow as a result of daughter-elements fractionation during solid-liquid interaction. Although porous flow is recognized as an important process in mantle rocks, its effects on mantle isotopic variability have been barely investigated so far. The peridotites of the Lherz massif (French Pyrenees) display a frozen melt percolation front separating highly refractory harzburgites from refertilized lherzolites. Isotopic signatures observed at the melt percolation front show a strong decoupling of Hf from Nd and Sr isotopes that cannot be accounted for by simple mixing involving the harzburgite protolith and the percolating melt. Using one dimensional percolation-diffusion and percolation-reaction modeling, we show that these signatures represent transient isotopic compositions generated by porous flow. These signatures are governed by a few critical parameters such as daughter element concentrations in melt and peridotite, element diffusivity, and efficiency of isotopic homogenization rather than by the chromatographic effect of melt transport and the refertilization reaction. Subtle variations in these parameters may generate significant inter-isotopic decoupling and wide isotopic variations in mantle rocks. (C) 2009 Elsevier B.V. All rights reserved.
ISSN: 0012-821X

hal-00413135
https://hal.archives-ouvertes.fr/hal-00413135
DOI : 10.1016/j.epsl.2008.12.033

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We report chlorine (Cl) and fluorine (F) abundances in minerals, interstitial glasses, and melt inclusions in 12 andesite-hosted, spinel harzburgite xenoliths and crosscutting pyroxenite veins exhumed from the sub-arc lithospheric mantle beneath Avacha volcano in the Kamchatka Arc (NE Russia). The data are used to calculate equilibrium mineral-melt partition coefficients (Dmineral/meltDmineral/melt) for Cl and F relevant to subduction-zone processes and unravel the history of volatile depletion and enrichment mechanisms in an arc setting.Chlorine is ∼100 times more incompatible in pyroxenes (View the MathML sourceDClmineral/melt = 0.005–0.008 [±0.002–0.003]) than F (View the MathML sourceDFmineral/melt = 0.50–0.57 [±0.21–0.24]), which indicates that partial melting of mantle sources leads to strong depletions in Cl relative to F in the residues. The data set in this study suggests a strong control of melt composition on View the MathML sourceDCl,Fpyroxene/melt, in particular H2O contents and Al/(Al + Si), which is in line with recent experiments. Fluorine is compatible in Ca-amphibole in the ‘wet’ sub-arc mantle (View the MathML sourceDFamphibole/melt = 3.5–3.7 [±1.5]) but not Cl (View the MathML sourceDClamphibole/melt = 0.03–0.05 [±0.01–0.03]), indicating that amphibole may fractionate F from Cl in the mantle wedge. The inter-mineral partition coefficients for Cl and F in this study are consistent amongst different harzburgite samples, whether they contain glass or not. In particular, disseminated amphibole hosts much of the Cl and F bulk rock budgets of spinel harzburgites (View the MathML sourceDClamphibole/pyroxene up to 14 and View the MathML sourceDFamphibole/pyroxene up to 40). Chlorine and fluorine are variably enriched (up to 1500 ppm Cl and 750 ppm F) in the parental arc picrite and boninite melts of primitive pyroxenite veins (and related melt inclusions) crosscutting spinel harzburgites.Based on the data in this study, the main inferences on the behaviour of Cl and F during melting and metasomatic processes in the sub-arc mantle are as follow:(i) Melting models show that most depleted mantle protoliths of intra-oceanic arc sources can have extremely low Cl/F (0.002–0.007) before being overprinted by subduction-derived components.(ii) Chlorine has a higher percolation distance in the mantle than F. Even for small fluid or melt volumes, Cl and F signatures of partial melting are overprinted by those of pervasive percolation, which increases Cl/F in percolating agents and bulk peridotites during chromatographic interaction and/or amphibole-forming metasomatic reactions. These processes ultimately control the bulk Cl and F compositions of the residual mantle lithosphere beneath arcs, and likely in other tectonic settings.(iii) Fluxed melting models suggest that Cl enrichment in arc picrite and boninite melts in this study, and in many arc melt inclusions reported in the literature, could be related to the infiltration of high Cl/F fluids derived from subducted serpentinite or altered crust in mantle wedge sources. However, these high Cl/F signatures should be re-evaluated with new models in light of the possible overprint of pervasive percolation effects in the mantle. The breakdown of amphibole (and/or mica) in the deep metasomatised mantle at higher pressure and temperature conditions than in the slab may explain, at least in part, the positive correlations between F abundances and Cl/F in primitive arc melt inclusions and slab depth.
ISSN: 0016-7037

hal-01553610
https://hal.archives-ouvertes.fr/hal-01553610
DOI : 10.1016/j.gca.2016.10.035

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Island arc picrites and boninites are magnesian magmatic rocks believed to be generated by high degrees of melting of depleted mantle sources fluxed by subduction-derived, volatile-rich components. These magmas can be probes of both the mantle wedge protoliths and subduction components, but are rare among other, usually more evolved, types of arc lavas. Furthermore, many arc picrites and boninites show evidence for late-stage differentiation prior to or during eruption, masking their primary, mantle-derived geochemical signatures. We report textural and chemical data on spinel-hosted melt inclusions of mantle origin in amphibole-bearing websterite veins cross-cutting spinel harzburgite xenoliths from the active andesitic Avacha volcano (south Kamchatka, Russia). The data are used to constrain the composition and origin of melts that formed the websterite veins in the sub-arc lithospheric mantle. The melt inclusions typically contain euhedral orthopyroxene and clinopyroxene and occasionally minor amphibole in silicate glass. The melt inclusions were homogenized using heating stages and gas-mixing furnaces. The homogenized glasses range from subalkaline primitive silica-rich picrite and high-Ca boninite (>15 wt % MgO, 48–54 wt % SiO2) to rhyolite. High-Ca boninite glasses have moderate volatile and low heavy rare earth element contents and elevated Cs, Rb, Ba, U, Sr, and Li abundances, with extremely high U/Th. In turn, the glasses display no negative spikes in the high field strength elements Nb, Ta, Zr, Hf, and Ti. We show that the silica-rich picrite and high-Ca boninite liquids in this study formed by high degrees of melting (>25%), at volatile under-saturation, of hybrid melt-depleted but silica-rich mantle sources at ≥1·5 GPa. The hybrid sources formed in two stages: first, by extraction of ∼15% melt from the convecting mantle to form a refractory protolith, which was subsequently enriched in silica via interaction with subduction-derived components prior to or during remelting in the mantle wedge. The subduction-derived components were enriched in fluid-mobile elements and probably oxidized. Overall, our results suggest that silica-rich picrites and high-Ca boninites can be primary melts in mature subduction zones and differentiate within the mantle wedge and the deep arc crust to form more evolved andesite magmas.
ISSN: 0022-3530

hal-01553676
https://hal.archives-ouvertes.fr/hal-01553676
DOI : 10.1093/petrology/egw066