Éditeur(s) : HAL CCSD Elsevier
Résumé : Siberian cratonic mantle
International audience
The processes that control water distribution in nominally anhydrous minerals from peridotites are twofold. Melt depletion will remove water while metasomatism can potentially add water to these minerals. These processes can lead to a wide range of outcomes in water contents, which in turn could play a role in mantle rheology and long-term cratonic root stability. To examine these complexities, water concentrations in minerals from well-characterized peridotites from the Udachnaya kimberlite in the central Siberian craton were analyzed by FTIR. The peridotites span a complete top to bottom cross-section of typical cratonic lithospheric mantle (2-7 GPa and 700-1400 °C). Diffusion modeling of water content profiles across olivine grains shows that water loss during decompression is limited to the 100 μm rims of olivines; the cores preserved their mantle water contents. Water contents range from 6 to 323 ppm wt H2O in olivine, 28-301 ppm H2O in orthopyroxene (opx), 100-272 ppm H2O in clinopyroxene (cpx) and 0-23 ppm H2O in garnet. Melting modeling cannot reproduce the high water contents of cratonic mantle peridotites and any potential partial melting trend must have been erased by later events. The water contents of minerals, however, are correlated with modal abundances of clinopyroxene and garnet, bulk rock FeO, TiO2 and SiO2 as well as with light and middle rare earth elements in clinopyroxene and garnet. These relationships are best interpreted as interaction of residual, melt-depleted peridotites with silicate melt, which produced modal and cryptic metasomatism. Importantly, the water enrichment in the Siberian cratonic mantle took place prior to kimberlite magmatism and eruption. Water addition by metasomatism occurred from pressures >4 GPa all the way to the base of the cratonic root below central Siberia, but was limited to shallower levels (<5 GPa) in the Kaapvaal cratonic lithosphere. The difference in olivine water contents at the deepest levels of the Kaapvaal (<5 ppm H2O) and Siberian (6-323 ppm H2O) cratonic roots may be linked to oxygen fugacity and resulting fluid speciation or, alternatively, to reaction with different metasomatic agents. Calculated viscosities for the deepest Udachnaya samples are similar to those inferred for the asthenosphere. If these xenoliths are representative of the deep cratonic lithosphere, water is not as important a parameter as previously thought in the strength of cratonic lithosphere, otherwise the cratonic root beneath Udachnaya would have been delaminated. Alternatively, the metasomatic xenoliths may not be representative of the Siberian cratonic root and kimberlites preferentially sample cratonic mantle lithosphere material located near, and metasomatized by, melt conduits, which served as channels for upward migration of water-rich melts and fluids including kimberlites. In that case, the cratonic root overall still may have relatively low water contents, which in addition to its less metasomatized (more refractory) and thereby buoyant nature, still play a role in making it strong enough to resist delamination by the surrounding asthenosphere.
ISSN: 0016-7037

hal-01053920
https://hal.archives-ouvertes.fr/hal-01053920
DOI : 10.1016/j.gca.2014.04.011

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
EISSN: 1873-7803

hal-00530976
https://hal.archives-ouvertes.fr/hal-00530976
DOI : 10.1016/j.cageo.2010.01.001

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Excess gas phase in magmas erupting explosively is well known worldwide. However, the origin of this gas phase, in excess of what can be dissolved in the erupting magma at depth, and the rate of gas accumulation is less well defined. The 2010 mildly explosive eruption at Eyjafjallajökull, Iceland, produced mingled tephra of benmoreitic and trachytic composition whereas alkali basalt was emitted during preceding flank eruption. Tephra of the first explosive phase are composed of three glass types, alkaline rhyolite, mixed benmoreite, and basalt, which suggests that the basaltic magma intruded a pre-existing rhyolitic magma chamber, and ultimately triggered the eruption. The mixed benmoreitic tephra (erupted on 15 and 17 April 2010) had large 210Po in excess of 210Pb View the MathML source[(Po210/Pb210)0=1.88] at the time of eruption, and possibly a small 210Pb excess over its parent 226Ra. In contrast, the preceding flank eruption produced basalt with View the MathML source(Po210)0=0, upon eruption, and the final trachyte had lost most of its 210Po during open-system degassing. The 210Po excess in the first erupted benmoreites is interpreted to result from 210Po degassing of basaltic magma and the accumulation of 210Po-enriched gas, either in the upper part of the basaltic intrusion, below the rhyolite–basalt interface, or in the pre-existing residual rhyolitic magma chamber. From a simple model of radon and polonium accumulation in the rhyolitic reservoir, the ratio of the mass of basalt magma degassing over the mass of magma accumulating the excess gas decreased from 20 to 15 over 2 days, implying zoned magma reservoir, with the uppermost and gas-richest part erupting first. The duration of pre-eruptive gas accumulation in this model is approximately one year. This corresponds closely to the initiation of a seismic swarm beneath Eyjafjallajökull, early June 2009, which was the first pre-eruptive signal detected. The coincidence between initiation of gas accumulation at relatively shallow depth and deeper seismicity strongly suggests that the excess gas phase originated from a basalt magma batch intruded at depth, and that this gas phase reached the surface approximately a year later.
ISSN: 0012-821X

hal-01217142
https://hal.archives-ouvertes.fr/hal-01217142
DOI : 10.1016/j.epsl.2015.06.054

Éditeur(s) : HAL CCSD
Résumé : International audience
The geology of the North Pyrenean Zone in the central Pyrenees allows for the observation in the field of theentire section of the Pyrenean rift, from the mantle to the crust and the Mesozoic cover (pre, syn and post rift).The good knowledge we have of the pre-Alpine history of the Pyrenees allows us to properly constrain the Alpinegeological evolution of the pre-Triassic rocks which record both Variscan and Alpine orogenic cycles.The mantle outcrop as kilometric to centimetric fragments of peridotite dispersed within a carbonate metamorphicbreccia. The study of peridotite serpentinisation shows several events of low-temperature serpentinisation, incontact with seawater. In some locallities, we can observe a mixture of fragments of variously serpentinizedperidotites. This suggests a tectonic context where fragments of peridotites from different structural levels weresampled more or less synchronously.The granulitic basement is characterized by a Variscan syndeformational HT event (300-280 Ma). So farwe have not found any trace of a Cretaceous HT event (> 500C). On the other hand, the basement is affectedby a regional metasomatism that began during the Jurassic and became more spatially focused with time until itwas restricted to the Pyrenean rift during the Aptien, Albian and Cenomanian. The talc-chlorite metasomatism(120-95 Ma) shows an evolution from a static toward a syn-deformation hydrothermal event, under a more or lessnormal geothermal gradient. Extensional deformation is recorded by the reworking of several inherited low-angleVariscan tectonic contacts, but also by dispersed high-angle extensional shear zones formed under greenshistconditions.The metamorphic Mesozoic cover of the basement massifs, which constitute the so-called Internal MetamorphicZone, is an allochtonous unit made of lenses of Mesozoic rocks enclosed into the breccia, whichlocally contains peridotite and basement clasts. The Mesozoic metamorphic carbonates show a first phase ofsyn-metamorphic (450-600C, P < 2 kb) ductile deformation, and subsequent phases of folding and fracturing.The datation of neoformed minerals give a 108-85 Ma time span for the metamorphism. We interpret this brecciaas an abandonment breccia which marks the emergence of the main detachment. The basal contact of the Mesozoiccover has a complex 3D geometry traced by Triassic evaporites. It corresponds to a major pre- and synorogenicpolyphased tectonic contact.All these data show a geometrically complex hyper-extended rift where the crust was not stretched under ahigh geothermal gradient but thinned by the tectonic extraction of relatively thin lenses and perhaps cut by highangle low-grade shear zones. The 3D geometry, as well as the strain records and the breccia lithologies stronglysuggest a non-cylindricity for the exhumation process, probably within a transtentional system
Geophysical Research Abstracts
Vienne, Austria

insu-01510371
https://hal-insu.archives-ouvertes.fr/insu-01510371

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
ISSN: 0012-821X

hal-00380865
https://hal.archives-ouvertes.fr/hal-00380865
DOI : 10.1016/j.epsl.2008.04.020

Éditeur(s) : HAL CCSD AGU and the Geochemical Society
Résumé : International audience
Rainbow is a dome-shaped massif at the 36°14′N nontransform offset along the Mid-Atlantic Ridge. It hosts three ultramafic-hosted hydrothermal sites: Rainbow is active and high temperature; Clamstone and Ghost City are fossil and low temperature. The MoMARDREAM cruises (2007, 2008) presented here provided extensive rock sampling throughout the massif that constrains the geological setting of hydrothermal activity. The lithology is heterogeneous with abundant serpentinites surrounding gabbros, troctolites, chromitites, plagiogranites, and basalts. We propose that a W dipping detachment fault, now inactive, uplifted the massif and exhumed these deep-seated rocks. Present-day deformation is accommodated by SSW-NNE faults and fissures, consistent with oblique teleseismic focal mechanisms and stress rotation across the discontinuity. Faults localize fluid flow and control the location of fossil and active hydrothermal fields that appear to be ephemeral and lacking in spatiotemporal progression. Markers of high-temperature hydrothermal activity (∼350°C) are restricted to some samples from the active field while a more diffuse, lower temperature hydrothermal activity (<220°C) is inferred at various locations through anomalously high As, Sb, and Pb contents, attributed to element incorporation in serpentines or microscale-sulfide precipitation. Petrographic and geochemical analyses show that the dominant basement alteration is pervasive peridotite serpentinization at ∼160–260°C, attributed to fluids chemically similar to those venting at Rainbow, and controlled by concomitant alteration of mafic-ultramafic units at depth. Rainbow provides a model for fluid circulation, possibly applicable to hydrothermalism at oceanic detachments elsewhere, where both low-temperature serpentinization and magmatic-driven high-temperature outflow develop contemporaneously, channeled by faults in the footwall and not along the detachment fault.
ISSN: 1525-2027

hal-01115281
https://hal.archives-ouvertes.fr/hal-01115281
https://hal.archives-ouvertes.fr/hal-01115281/document
https://hal.archives-ouvertes.fr/hal-01115281/file/Andreani_et_al-2014-Geochemistry%2C_Geophysics%2C_Geosystems.pdf
DOI : 10.1002/2014GC005269

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Souttoufide belt is situated between the High-Atlas in the north, the Mauritanides in the south and the West African Craton as well as the Tindouf basin in the east. Thus, this belt is a part of the West African fold belt system which surrounds the West African Craton. Outcrops occur only in three areas, while the rest of the Souttoufide belt is covered by Meso- to Cenozoic sediments. These areas are, from the south to the north, the Adrar Souttouf Massif, the Smara Zemmour area, and the western part of the Anti-Atlas. Because of the continuing processing and numerous publications, the Anti-Atlas cannot be dealt with in detail. Fundamental geological work in both of the other areas was mainly done during the second third of the 20th century, followed by several decades of inactivity. Numerous studies were done in the Adrar Souttouf massif during the last decade, while the Smara-Zemmour area still remains poorly investigated. Most of them were focused on geochronological analyses and geochemistry. Accordingly, the obtained data led to a new interpretation. The Adrar Souttouf is interpreted as a Pan-African belt exhibiting a Neoproterozoic island arc reworked by the Variscan collision between the North American Craton (NAC) and the West African Craton (WAC). The Smara-Zemmour area is considered as the external part of this Variscan belt thrusted onto the Palaeozoic Tindouf basin. The western Anti-Atlas as considered as a Pan-African active margin reworked during the Variscan orogen. Together, these three areas, lead to the hypothesis of a Late Pan-African belt capped by the Early and Middle Palaeozoic covers and then affected by the Middle Carboniferous tectonic event (330 Ma) related to the Pangaean assembly. Correlations with adjacent belts (Mauritanides and Anti-Atlas) are considered.
ISSN: 0899-5362

hal-01382815
https://hal.archives-ouvertes.fr/hal-01382815
DOI : 10.1016/j.jafrearsci.2015.04.016

Éditeur(s) : HAL CCSD Mineralogical Society of America
Résumé : International audience
Wadsleyites with various iron contents were synthesized at ~12-14 GPa and 1400 °C under oxidizing and hydrous conditions in coexistence with enstatite. The samples were studied using micro-X-ray absorption near edge structure (XANES) and micro-Mössbauer spectroscopy to determine the ferric iron contents in polyphasic samples and secondary ion mass spectrometry (SIMS) to determine the water concentrations. XANES and Mössbauer analyses show that ferric iron content increases with increasing total iron content, and reaches a maximum of ~30% Fe3+/Fetotal. Two XANES results were cross-checked by Mössbauer analysis and both methods are in reasonable agreement. The use of Fourier transform infrared spectroscopy reveals a new protonation scheme in wadsleyite, with a significant proportion of protons associated with the high-frequency band at 3611 cm−1 and a new band located at 3500 cm−1. The intensity of these two bands is higher for Fe3+-rich wadsleyite. SIMS analyses show that water contents in wadsleyite vary from 4500 to 9400 ppm H2O by weight. Pyroxene water contents range from 790 to 1600 ppm wt H2O. The concentration of water in both phases decreases with increasing iron content. The partition coefficient of water between wadsleyite and pyroxene varies between 5 and 9 and increases with increasing Fe-number of wadsleyite [i.e., XFe/(XFe + XMg) × 100 ratio]. The divalent cation concentrations (i.e., Mg2+ + Fe2+), the Si as well as the H content in wadsleyite decrease with increasing Fe3+ content, indicating an incorporation mechanism via substitution into the metal (Me = Mg2+ and Fe2+) and Si sites with a ratio of 5/3 for (Fe3++H+):Me and of 5/1 for (Fe3++H+):Si, similarly as in the dry system. Thus, coupled substitution of Fe3+ and H+ does not affect the incorporation mechanism of Fe3+, but does affect the location of H+, which is partly incorporated at tetrahedral edges forming [FeSi′-(OH)o*]X neutral defects substituting for Si. In this model 25% of the ferric iron occupies the tetrahedral sites.
ISSN: 0003-004X

hal-00758071
https://hal.archives-ouvertes.fr/hal-00758071
DOI : 10.2138/am.2012.3869

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In northeastern Vietnam, the major tectonic episode responsible for nappes emplacement is Triassic. These allochtonous structures are intruded by granitic melts. Two post-tectonic massifs showing no sign of deformation have been dated by the LA-ICPMS zircon U-Pb techniques. Dating reveals a multiphase history with zircon cores showing evidence of Proterozoic magmatism. The emplacement of the Phia Bioc granite intrusive in allochtonous units is 248-245 Ma, an age which assesses a younger limit for the major nappes tectonic. This tectonic could be synchronous of the tectonometamorphic strike-slip faulting events (250-245 Ma) defined in the Truong Son Belt as the Indosinian orogen. The Phia Bioc intrusion is probably linked with the intra-plate magmatism of the Emeishan Large Igneous Province or with magma- tism associated with the Paleotethys closure. The age of the Phia Oac granite intrusion in displaced units is much younger, at 87.3 ± 1.2 Ma. This granite is probably linked to the magmatic activity produced dur- ing the Paleo-Pacific plate subduction under the SE Asia continental plate during the Mesozoic. Although the Cenozoic Red River fault system is close to these two plutons, this last thermotectonic episode has not been strong enough to disturb the U/Pb system. Zircons rims do not show any Tertiary magmatic or meta- morphic overprint.
ISSN: 0743-9547

hal-00681725
https://hal.archives-ouvertes.fr/hal-00681725
DOI : 10.1016/j.jseaes.2011.12.012

Éditeur(s) : HAL CCSD Springer Verlag (Germany) Springer Verlag
Résumé : International audience
The Cerro del Almirez massif (Spain) represents a unique fragment of serpentinized oceanic lithosphere that has been first equilibrated in the antigorite stability field (Atg-serpentinites) and then dehydrated into chlorite–olivine–orthopyroxene (Chl-harzburgites) at eclogite facies conditions during subduction. The massif preserves a dehydration front between Atg-serpentinites and Chl-harzburgites. It constitutes a suitable place to study redox changes in serpentinites and the nature of the released fluids during their dehydration. Relative to abyssal serpentinites, Atg-serpentinites display a low Fe3+/FeTotal(BR) (=0.55) and magnetite modal content (=2.8–4.3 wt%). Micro-X-ray absorption near-edge structure (μ-XANES) spectroscopy measurements of serpentines at the Fe–K edge show that antigorite has a lower Fe3+/FeTotal ratio (=0.48) than oceanic lizardite/chrysotile assemblages. The onset of Atg-serpentinites dehydration is marked by the crystallization of a Fe3+-rich antigorite (Fe3+/FeTotal = 0.6–0.75) in equilibrium with secondary olivine and by a decrease in magnetite amount (=1.6–2.2 wt%). This suggests a preferential partitioning of Fe3+ into serpentine rather than into olivine. The Atg-breakdown is marked by a decrease in Fe3+/FeTotal(BR) (=0.34–0.41), the crystallization of Fe2+-rich phases and the quasi-disappearance of magnetite (=0.6–1.4 wt.%). The observation of Fe3+-rich hematite and ilmenite intergrowths suggests that the O2 released by the crystallization of Fe2+-rich phases could promote hematite crystallization and a subsequent increase in fo2 inside the portion of the subducted mantle. Serpentinite dehydration could thus produce highly oxidized fluids in subduction zones and contribute to the oxidization of the sub-arc mantle wedge.
ISSN: 0010-7999

hal-01172310
https://hal.archives-ouvertes.fr/hal-01172310
DOI : 10.1007/s00410-015-1130-y

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We provide results of a detailed study of the first peridotite xenoliths of proven mantle origin reported from Bezymyanny volcano in the Klyuchevskoy Group, northern Kamchatka arc. The xenoliths are coarse spinel harzburgites made up mainly of Mg-rich olivine as well as subhedral orthopyroxene (opx) and Cr-rich spinel, and also contain fine-grained interstitial pyroxenes, amphibole and feldspar. The samples are unique in preserving the evidence for both initial arc mantle substrate produced by high-degree melt extraction and subsequent enrichment events. We show that the textures, modal and major oxide compositions of the Bezymyanny xenoliths are generally similar to those of spinel harzburgite xenoliths from Avacha volcano in southern Kamchatka. However, coarse opx from the Bezymyanny harzburgites has higher abundances of light and medium rare earth elements and other highly incompatible elements than coarse opx from the Avacha harzburgites. We infer that (1) the sub-arc lithospheric mantle beneath both Avacha and Bezymyanny (and possibly between these volcanoes) consists predominantly of harzburgitic melting residues, which experienced metasomatism by slab-related fluids or low-fraction, fluid-rich melts and (2) the degrees of metasomatism are higher beneath Bezymyanny. By contrast, xenolith suites from Shiveluch and Kharchinsky volcanoes 50-100 km north of the Klyuchevskoy Group include abundant cumulates and products of reaction of mantle rocks with silicate melts at high melt/rock ratios. The high melt flux through the lithospheric mantle beneath Shiveluch and Kharchinsky may be related to the asthenospheric flow around the northern edge of the sinking Pacific plate; lateral propagation of fluids in the mantle wedge south of the plate edge may contribute to metasomatism in the mantle lithosphere beneath the Klyuchevskoy Group volcanoes.
ISSN: 0377-0273

hal-00941258
https://hal.archives-ouvertes.fr/hal-00941258
DOI : 10.1016/j.jvolgeores.2012.12.022

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The eastern margin of the Tibetan Plateau is a key region to understand the formation and tectonic evolution of the plateau. Most studies concentrated on the Longmen Shan range that corresponds to the tectonically very active boundary between the Tibetan Plateau and the Sichuan Basin. This work addresses the deformation and exhumation pattern in the poorly understood metamorphic Danba dome situated at the conjunction between the southern Longmen Shan range and the major strike-slip Xian Shui He fault. The Early Mesozoic and Cenozoic evolution of the dome are then compared to the regional evolution of eastern Tibet. The about 830 Ma zircon U–Pb ages obtained on the Gezong and Gongcai gneiss as well as U–Pb ages on inherited zircons in the Early Mesozoic granites confirm the occurrence of Neo-Proterozoic magmatic episodes in the Danba basement at 800–900 Ma and 650–750 Ma. Following the closure of the Palaeotethys Ocean, granitoids were emplaced in the Danba metamorphic basement and Triassic cover from about 230 Ma to about 170 Ma. The western part of the Lian He Kau granitic massif, emplaced (between 210 and 200 Ma) within the Triassic cover sequence of the dome was only slightly affected by the Early Mesozoic deformation. However, in the eastern, deeper level compartment of the massif, ductile deformation occurred between 200 and 190 Ma, contemporaneous with the onset of the Barrovian-type metamorphism dated at 200–180 Ma. That deformation is compatible with the Early Mesozoic deformation observed in the Longmen Shan range and with the development of the large-scale décollement level in the Songpan Garzê area. Apatite fission track data then indicate that, following the Oligocene–Middle Eocene onset of eastward motion of the Songpan Garzê terrane, the Danba dome developed as a crustal-scale antiform during the Late Miocene–Early Pliocene (10–4 Ma). The exhumation was controlled by the Lian He Kau fault (a major transpressive structure parallel to the Xian Shui He fault) and the associated Manai thrust faults. Regionally, while the Oligocene–Middle Miocene exhumation phase seems to have been of regional extent, the Late Miocene to Present day phase is localised along the Longmen Shan range thrusts as well as along the back-thrusts formed by the Lian He Kau, Manai and associated faults.
ISSN: 0743-9547

insu-01117657
https://hal-insu.archives-ouvertes.fr/insu-01117657
DOI : 10.1016/j.jseaes.2015.02.009

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
ISSN: 0258-8900

hal-00682343
https://hal.archives-ouvertes.fr/hal-00682343
DOI : 10.1007/s00445-011-0554-0

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Piton des Neiges basaltic volcano (La Réunion) has been deeply dissected by erosion, exposing large volumes of debris avalanche deposits. To shed light on the factors that led to volcano flank destabilizations, we studied the structure, the crystallographic and magnetic fabrics of the substratum of a debris avalanche unit. This substratum is a complex of N50 seaward-dipping sills that has been exposed by the avalanche. Structural observations show that the sill plane in contact with the avalanche is one of the latest intrusions in the sill complex. In this uppermost sill, the anisotropy of magnetic susceptibility (AMS) is correlated to the crystallographic preferred orientation of magmatic silicate minerals, allowing us to use AMS as a proxy to infer the magmatic flow. The AMS fabric across the intrusion is strongly asymmetric, which reveals that the contact sill was emplaced with a normal shear displacement of its hanging wall. The shear displacement and the magma flow in the intrusion are both directed toward the NNE, i.e. toward the sea, which is also the direction of the slope and of the debris avalanche runout. Because all the sills in the intrusion complex have a similar dip and dip direction, it is likely that several of them also underwent a cointrusive slip toward the NNE. We conclude that this cointrusive normal slip, repeated over many intrusions of the sill complex, increased the flank instability of the volcano. This incre-mental instability may have ended up into the observed debris avalanche deposit. At Piton de la Fournaise, the active volcano of La Réunion, sill intrusion and cointrusive flank displacement have been inferred from geophys-ical studies for the April 2007 eruption. By providing direct evidence of sheared sills, our study substantiates the idea that repeated sill intrusions may eventually trigger flank destabilizations in basaltic volcanoes.
ISSN: 0040-1951

hal-01351758
http://hal.univ-reunion.fr/hal-01351758
http://hal.univ-reunion.fr/hal-01351758/document
http://hal.univ-reunion.fr/hal-01351758/file/2016-Tectonopgysics-Berthod.pdf
DOI : 10.1016/j.tecto.2016.02.017

Éditeur(s) : HAL CCSD Mineralogical Society of America
Résumé : International audience
To test if hydrogen incorporation by ionic diffusion can occur between a volatile-rich kimberlitic liquid and forsterite, results of high-pressure and high-temperature experiments using a piston-cylinder apparatus at 1200–1300 °C and 1 GPa for durations of 1 min, 5 h, and 23 h, are reported here. Kimberlitic liquid in the system CaO-MgO-Al2O3-SiO2-CO2-H2O and synthetic forsterite single crystals were chosen as a first simplification of the complex natural kimberlite composition. Unpolarized Fourier transform infrared spectroscopy was used to quantify the concentrations of OH in the crystallographically oriented forsterite. Scanning electron microscopy, electron backscattered diffraction, electron microprobe analyses, and transmission electron microscopy were performed to identify the run products. After 5 and 23 h, a forsterite overgrowth crystallized with the same orientation as the initial forsterite single crystal. The kimberlitic liquid has crystallized as micrometer-scale euhedral forsterite neocrystals with random crystallographic orientations, as well as a nanoscale aluminous phase and a calcic phase. Despite theoretical water-saturation of the system and long duration, none of the initial forsterite single crystals display signs of hydration such as hydrogen diffusion profile from the border toward the center of the crystal. Most likely, the presence of CO2 in the system has lowered the H2O fugacity to such an extent that there is no significant hydration of the starting forsterite single crystal or its overgrowth. Also, the presence of CO2 enhances rapid forsterite crystal growth. Forsterite growth rate is around 2 × 108 μm3/h at 1250 °C. These experimental results suggest a deep mantle origin of the high OH content found in natural mantle-derived xenoliths transported in kimberlites, as reported from the Kaapvaal craton. In agreement with previous studies, it also points out to the fact that significant hydration must take place in a CO2-poor environment.
ISSN: 0003-004X

hal-01217157
https://hal.archives-ouvertes.fr/hal-01217157
DOI : 10.2138/am-2015-5200

Éditeur(s) : HAL CCSD Elsevier
Résumé : Several nuclides of the ;238;U (;234;U, ;230;Th, ;226;Ra, ;210;Pb) and ;235;U (;231;Pa, ;227;Ac) decay series have been measured through gamma spectrometry in the U-bearing episyenites of the Bernardan mine (northwest Massif Central, France), in order to study recent mobilizations in the U-deposit and their time-scales. (;230;Th/;238;U) and (;231;Pa/;235;U) ratios show that U has been little affected during the last 350 ky, especially in the U-rich samples. In contrast, ;226;Ra was subjected to a general redistribution, with a clear tendency for Ra to be lost from the U-rich samples and added to U-poor samples. The highest Ra excesses are present in low-U samples, and are related to adsorption onto iron hydroxides. Ra appears to have been redistributed within the mineralised episyenitic bodies, which seem to remain in ;226;Ra–;238;U radioactive equilibrium, a result consistent with the earlier study of Leroy [1984. Episyénitisation dans le gisement d'uranium du Bernardan (Marche): Comparaison avec des gisements similaires du Nord-Ouest du Massif Central français. Miner. Depos. 19, 26–35]. As shown by the ;226;Ra and ;210;Pb data, the Ra redistribution was very active between 8 and 0.1 ky, and this might be a consequence of the hydrological changes in groundwater circulation accompanying the Holocene climate warming.
ISSN: 0009-2541

hal-00407600
https://hal.archives-ouvertes.fr/hal-00407600
DOI : 10.1016/j.chemgeo.2007.06.020

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The ultramafic rocks of the Collo region in northeastern Algeria crop out as “stratified” masses that cut across older metamorphic formations of the Petite Kabylie basement. Based on petrological compositions and mineralogical observations, these rocks are mainly peridotites and serpentinites. The peridotites are identified as lherzolites, but dunites may occur rarely. The lherzolites are composed of olivine, orthopyroxene, clinopyroxene and chromian spinel. Their chemical composition shows high MgO (34.4–37.5 wt%), Cr (0.14–0.27 wt%), Ni (0.14–0.26 wt%) and Co (34–133 ppm) contents and low CaO and Al2O3 concentrations (0.02–2.2 wt% and 0.5 to 2.8 wt%, respectively). The chromite, which represents approximately 1–3% of the rock, is ubiquitous and shows two different generations: primary millimetric euhedral crystals and secondary fine xenomorphic grains and interstitial aggregates. The primary chromites are alumino-ferro-magnesian crystals that show high Al2O3 (25.77%–27.36%) and MgO (10.70%–13.36%). Cr# (100 × Cr/(Al + Cr)) ranges from 45 to 48, and Mg# (100 × Mg/(Mg + Fe2+)) from 49 to 59. The secondary interstitial grains are iron-rich chromites. They show low Al2O3 (4.67%–9.54%) and MgO (4.60%–4.65%). Cr# is relatively high (77–88), whereas Mg# shows relatively low values, ranging from 22 to 25. Primary chromite and whole-rock chemistry show that the Collo ultramafic rocks belong to Alpine-type peridotites that were emplaced within an orogenic setting. The oxygen isotopic composition of both peridotites and chromites is consistent with their derivation from a mantle source (δ18O ranges from +3.0 to +5.9‰). Low δ18O values (<+4.4‰) are recorded in serpentinites and are attributed to the effect of serpentinization processes through high-temperature metasomatic fluids. Magnesite-bearing serpentinites show the lowest δ18O values. These are interpreted as the result of surface water input.
ISSN: 0899-5362

hal-01468003
https://hal.archives-ouvertes.fr/hal-01468003
DOI : 10.1016/j.jafrearsci.2016.10.012

Éditeur(s) : HAL CCSD American Geophysical Union (AGU)
Résumé : International audience
Deciphering Variscan versus Alpine history in the internal Rif system is a key to constraining the tectonic evolution of the Alboran domain and hence the geodynamics of the western Mediterranean system during the Cenozoic. This study focuses on the evolution of the metamorphic envelope of the Beni Bousera massif and its relation to the underlying peridotites. Combining structural geology, metamorphic petrology, and LA-ICP-MS U-Th-Pb dating of monazite, this study contributes to the understanding of the tectonic history of the western internal Rif. The regional foliation (S2) is characterized by LP/HT mineral assemblages and obliterates a former foliation (S1) developed along a barrovian (MP/MT) metamorphic gradient. The dating of some metamorphic monazite grains from a micaschist and a migmatitic gneiss demonstrates that the crustal envelope of the peridotite recorded two distinct tectonometamorphic episodes. Data from monazite inclusions in S1 garnet suggest that the first event, D1, is older than 250-170 Ma and likely related to the Variscan collision, in agreement with the barrovian type of the metamorphic gradient. The second event, D2, is Alpine in age (at circa 21 Ma) and corresponds to a strong lithosphere thinning allowing subsequent subcontinental mantle exhumation. Such a tectonic context provides an explanation for the LP/HT metamorphic gradient that is recorded in the regional foliation of the western Betic-Rif system. This extension is probably related to a subduction slab roll-back in the western end of the Mediterranean realm during the Oligo-Miocene times. No evidences for a Tertiary HP/LT metamorphism have been identified in the studied area
ISSN: 0278-7407

Droits : info:eu-repo/semantics/OpenAccess
insu-01152517
https://hal-insu.archives-ouvertes.fr/insu-01152517
https://hal-insu.archives-ouvertes.fr/insu-01152517/document
https://hal-insu.archives-ouvertes.fr/insu-01152517/file/gueydan-2015.pdf
DOI : 10.1002/2014TC003769

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The minerals constituting the Earth's upper mantle are nominally anhydrous silicates (NAMs). However they do contain hydrogen as a trace element, decorating point defects in their crystalline structure. Experimental petrology and mineralogy have quantified the maximum concentration under several compositional and thermodynamic conditions, but systematic studies on the hydrogen concentration in minerals from mantle-derived rocks have only recently been carried out. Here, we have compiled the distribution of hydrogen in upper mantle peridotite xenoliths, from which several conclusions can be drawn. NAMs from peridotite xenoliths contain a few ppm wt. H2O in their structure. From the current database, the hydrogen concentrations in olivine regularly increase with increasing depth. The amount of hydrogen in NAMs from peridotite xenoliths from subduction contexts is not higher than in other geological context for similar temperature and pressure conditions. The highest hydrogen concentrations is found in peridotitic olivines from cratonic mantle, and are likely due to the depth of origin. The increasing hydrogen concentration in olivine with increasing depth is likely controlled by the increase of H partitioning into olivine at the expense of orthopyroxene as imposed by a decrease in Al content in opx with depth. However, the sparse data could also indicate that the bulk hydrogen concentration slightly increases with depth > 150 km. In this case, it would suggest, locally (Udachnaya for example), a possible increase in water fugacity due to fluid saturation. Even if the most abundant mineral in mantle rocks is olivine, the bulk hydrogen concentration in peridotites is controlled by the amount of hydrogen stored in pyroxenes. However, hydrogen concentration in olivine remains crucial for consequences on physical properties such as rheology and electrical conductivity. Kinetics of hydrogen transport is reviewed and hydrous melt/fluid percolation appears necessary to homogenize the hydrogen distribution at km-scale. Sampling of natural rock specimens is currently biased (e.g., in favor of optically attractive samples) and needs improvement, which will be achieved by increasing sample diversity (all type of grain sizes, lithologies, geological settings) and size of rock samples, as well as advances in analytical techniques. Acquisition of high quality data will be achieved by studying the co-existing minerals in mantle specimens, exploring each sample by linear and mapping measurements, and using appropriate FTIR calibrations for polarized and unpolarized radiation.
ISSN: 0024-4937

hal-01306676
https://hal.archives-ouvertes.fr/hal-01306676
DOI : 10.1016/j.lithos.2015.11.012

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The decay of 187Re to 187Os provides a unique tracer of recycled lithosphere in the Earth's upper mantle, and the radiogenic Os isotope compositions of many mid-ocean ridge basalts (MORB) have been taken to indicate the presence of recycled oceanic crust in the mantle source. However, others have attributed the data to contamination by seawater or an age effect (due to 187Re decay following igneous crystallisation). This study presents new Re Os, U Th Ra and B isotope data for normal-MORB (N-MORB) glass (including 18 samples analysed previously). The scale of the variation in 187Os/188Os observed here in N-MORB glass ranges from 0.126 to 0.148, with a mean value of 0.133 ± 0.009 (2?). Previously published Os isotope data for MORB is shown to have been affected by an analytical artefact, and in particular the very radiogenic Os isotope compositions reported earlier are now shown not to exist. Nevertheless, some radiogenic Os isotope compositions are still seen in the data obtained here. Coupled Th and Ra excesses appear to rule out an age effect, at least, for those samples studied, however, ?11B covariations with 187Os/188Os are consistent with the assimilation of older oceanic crust (affected by seawater contamination). Individual sulphides (less likely to be affected by such contamination) are always less radiogenic than their glass host, with 187Os/188Os values ranging from 0.123 to 0.131. This indicates that sulphide precipitation occurred prior to contamination of the surrounding melt, but the data also suggest that low-Os sulphides have been affected by contamination through partial equilibration with that melt. Taken together, these indicate that dominant process responsible for the radiogenic Os isotope compositions of N-MORB glass is contamination by older oceanic crust. Although the influence of age effects and the presence of recycled material cannot be completely ruled out, Os-rich sulphides yield sub-chondritic Os isotope compositions which point rather to a long-term depletion in Re in the MORB source likely to have resulted from formation of the continental crust over much of Earth's history.
ISSN: 0012-821X

hal-00320075
https://hal.archives-ouvertes.fr/hal-00320075
DOI : 10.1016/J.EPSL.2007.05.014