Éditeur(s) : HAL CCSD E Schweizerbart Science Publishers
Résumé : International audience
We present an electron tomography study of dislocations in deformed olivine single crystals, at ca. 0.5 T m, along two distinct orientations. The easiest slip systems are [001](100) and [001]{110}. Disorientating a single crystal away from easy glide conditions leads to massive cross-slip, which generates three-dimensional dislocations, and thus contributes to hardening. Fast motion of curved non-screw dislocation in those planes leaves long straight screw dislocations which bear lattice friction and control plastic strain. We have identified several hardening mechanisms. Non-screw [001] dislocations interact elastically to form dipoles. Recovery mechanisms leading to dipole annihilation are observed, but they are slow at those temperatures and produce numerous sessile loops. These loops represent obstacles for gliding dislocations. Interactions between dislocations and sessile loops produce sessile segments (super jogs), which efficiently impede dislocation motions.
ISSN: 0935-1221

hal-01277821
https://hal.archives-ouvertes.fr/hal-01277821
DOI : 10.1127/ejm/2015/0027-2481

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In this paper, we determine dislocation core structures and Peierls stresses of wadsleyite, a high-pressure mineral present in the Earth mantle. We use a Peierls-Nabarro model combined with a finite-element method in which we introduce two-dimensional generalized stacking fault energies. Several potential slip planes of wadsleyite are considered. The results show that dislocations in this mineral can exhibit complex dislocation cores with linear or non-collinear dissociation and even three-dimensional dislocation cores. The calculation of the Peierls stresses gives information on the potential activity of slip systems governing the plasticity of wadsleyite. Our study confirms experimental observations that 1/2 < 1 1 1 >{1 0 1} is the easiest slip system in this structure at high-pressure and that [1 0 0](0 1 0) is the second easiest. Both these easily slip systems have dislocations that dissociate into collinear partial dislocations. In contrast [0 1 0] dislocations with very large Burgers vector (11.2 angstrom) are stabilized by complex dissociations involving four partial dislocations.
ISSN: 1359-6454

hal-00475548
https://hal.archives-ouvertes.fr/hal-00475548
DOI : 10.1016/j.actamat.2009.10.047

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Ocean island basalts (OIB) from the Comores archipelago (Indian Ocean) display mineralogical and geochemical features different from the other Indian OIB. We present here new geochronological data (40Ar/39Ar), major and trace element compositions and isotopic (Sr, Nd, Pb) ratios of silica-undersaturated alkaline rocks from Mayotte, the oldest island of the Comores. Two trends are defined using major element composition: (1) a highly silica-undersaturated trend which includes basanites, (melilite-bearing) nephelinites, intermediate lavas and phonolites from the southern part of the island and (2) a moderately silica-undersaturated trend which is mainly represented by alkali basalts, basanites, intermediate lavas and phonolites from the northern part of the island. Both trends could be explained, to some extent, by variable degrees of partial melting. Normative larnite-bearing olivine melilitites and nephelinites exhibit, in addition to their high silica-undersaturation, elevated concentrations in CaO (>12wt.%) and P2O5 (up to 1.35wt.%). These exceptional rocks would result from low degree deep partial melting of a CO2-metasomatized source in the presence of carbonate (probably dolomite) and apatite. Igneous rocks from southern and northwestern shield volcanoes are characterized by a radiogenic Pb composition, revealing the existence of a HIMU (high μ=238U/204Pb) component in their source. Its influence decreases from the main building stage (>10.6-~3.0Ma) to the post-shield stage for the benefit of a depleted MORB-mantle (DMM) component, especially in the north central rocks. This feature would reflect increasing melting degrees of the depleted dominant source, bearing small-scale HIMU heterogeneities progressively consumed with time. The HIMU signature might have been introduced in the Comorian lithospheric mantle by thermal erosion or delamination of a continental lithosphere during the Gondwana break-up. The other islands of the Comores archipelago (Moheli, Anjouan and "La Grille" type lavas from Grande Comore) display also a DMM-HIMU mixing trend. Only a few lavas from Grande Comore ("Karthala" type) and one sample from Mayotte show the clear EM1 contribution (87Sr/86Sr>0.7035) of the Comorian plume.
ISSN: 0024-4937

insu-01089376
https://hal-insu.archives-ouvertes.fr/insu-01089376
https://hal-insu.archives-ouvertes.fr/insu-01089376/document
https://hal-insu.archives-ouvertes.fr/insu-01089376/file/Pelleter%20et%20al%201.pdf
DOI : 10.1016/j.lithos.2014.09.012

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Transmission electron microscopy observations on olivine crystals deformed at moderate (≤1273 K) temperature evidenced dislocations interactions explaining the hardening observed in the experiments, but also recovery mechanisms by the absorption or emission of point defects. Thus we investigate the possibility that, at geological strain-rates, these recovery processes allow steady-state deformation by dislocation creep at low to moderate temperatures in the lithospheric mantle. We test this hypothesis using a 2.5-D dislocation dynamics (DD) model, which combines dislocation glide and recovery by climb. This model shows that diffusion-controlled recovery processes allow for steady-state deformation by dislocation creep in the lithospheric mantle at stresses <500 MPa. For stresses of 50–200 MPa, steady-state strain-rates of 10−15 s−110−15 s−1 may be attained at temperatures as low as 900 K. Fitting of the DD model produces a flow law, which represents a lower bound for the lithospheric mantle strength, since the models describe the deformation of an olivine single crystal in an easy slip orientation. Comparison of strain-rates and Moho temperatures inferred for different geodynamic environments and the predictions of this model-based flow law implies, nevertheless, that, except in incipient rifts, most of the observed deformation may be produced by stress levels ≤200 MPa, consistent with those inferred to be produced by convection. This convergence suggests that the present models, which explicitly calculate the time-dependent dislocation dynamics, may provide a correct first order estimate of the mechanical behaviour of the lithospheric mantle, which cannot be derived directly from any existing data.
ISSN: 0012-821X

hal-01277178
https://hal.archives-ouvertes.fr/hal-01277178
https://hal.archives-ouvertes.fr/hal-01277178/document
https://hal.archives-ouvertes.fr/hal-01277178/file/Boioli.pdf
DOI : 10.1016/j.epsl.2015.10.012

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We have performed tri-axial compression experiments on olivine aggregates at 900 °C and at a confining pressure of 300 MPa in a high-resolution gas-medium mechanical testing apparatus. Deformation at two different constant strain rates (1.1 × 10− 5 s− 1 and 3.4 × 10− 4 s− 1) yields continuous hardening, reaching maximal differential stresses of 930 and 1076 MPa, respectively, before sample failure at ca. 10% strain. The deformed samples were characterized by electron backscatter diffraction (EBSD) and transmission electron microscopy (TEM). Crystallographic preferred orientations (CPO) are weak but reveal an alignment of the [010] axes around the compression direction and some concentration of [001] and [100] axes normal to it. TEM observations confirm plastic deformation by dislocation glide, with both [001] and [100] Burgers vectors. Electron tomography, performed for the first time on deformed fined-grained olivine, shows that [001] dislocations glide extensively on {110} and {130} planes, in complement to the (010) and (100) glide planes often reported at high temperatures. [100] dislocations glide mostly on (010), but {011} and {041} planes are also activated. The experimental CPO and relative activity of slip systems are well reproduced by viscoplastic self-consistent simulations in which all [100] and [001] slip systems have similar strengths. They are also consistent with olivine CPO from natural samples deformed at low temperature. Comparison of the present mechanical results to those obtained for olivine single-crystals at similar conditions shows that at low temperature (below 1100 °C) and high stress (> 300 MPa) polycrystalline olivine has a more complex mechanical behavior than single crystals. However, both datasets advocate for a much weaker dry mantle lithosphere than previously thought.
ISSN: 0040-1951

hal-01053513
https://hal.archives-ouvertes.fr/hal-01053513
DOI : 10.1016/j.tecto.2014.03.022

Éditeur(s) : HAL CCSD National Institute of Environmental Health Sciences
Résumé : International audience
Safe drinking water is essential for well-being. Although microbiological contamination remains the largest cause of water-related morbidity and mortality globally, chemicals in water supplies may also cause disease, and evidence of the human health consequences is limited or lacking for many of them. We aimed to summarize the state of knowledge, identify gaps in understanding, and provide recommendations for epidemiological research relating to chemicals occurring in drinking water. Assessing exposure and the health consequences of chemicals in drinking water is challenging. Exposures are typically at low concentrations, measurements in water are frequently insufficient, chemicals are present in mixtures, exposure periods are usually long, multiple exposure routes may be involved, and valid biomarkers reflecting the relevant exposure period are scarce. In addition, the magnitude of the relative risks tends to be small. Research should include well-designed epidemiological studies covering regions with contrasting contaminant levels and sufficient sample size; comprehensive evaluation of contaminant occurrence in combination with bioassays integrating the effect of complex mixtures; sufficient numbers of measurements in water to evaluate geographical and temporal variability; detailed information on personal habits resulting in exposure (e.g., ingestion, showering, swimming, diet); collection of biological samples to measure relevant biomarkers; and advanced statistical models to estimate exposure and relative risks, considering methods to address measurement error. Last, the incorporation of molecular markers of early biological effects and genetic susceptibility is essential to understand the mechanisms of action. There is a particular knowledge gap and need to evaluate human exposure and the risks of a wide range of emerging contaminants.
ISSN: 0091-6765

hal-01118530
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01118530
PUBMED : 24380896
DOI : 10.1289/ehp.1206229
PUBMEDCENTRAL : PMC3948022

Éditeur(s) : HAL CCSD Springer
Résumé : International audience
Current Environmental Health Reports

hal-01118551
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01118551
PUBMED : 26231245
DOI : 10.1007/s40572-014-0032-x

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
A San Carlos olivine polycrystal has been deformed under uppermost mantle conditions, by compression at 900 °C, at a strain rate of 1.1 × 10−5 s−1, under a confining pressure of 300 MPa, using the Paterson press. Transmission electron tomography of dislocations has been performed by scanning transmission electron microscopy, by conventional transmission electron microscopy using the weak-beam dark-field technique, associated with precession or not, in order to determine the glide planes of [001] screw dislocations. This recent technique is the most suitable one since most [001] dislocations exhibit straight screw segments due to the high lattice friction on this character at low temperature. We find that [001] dislocations glide in (100), (010) and {110} as already reported, but also more unexpectedly in {120} and {130}. We show that at 900 °C, [001] {110} glide is dominant in polycrystals. We have, however, noted and characterized numerous cross-slip events in the specimen.
ISSN: 0342-1791

hal-01054330
https://hal.archives-ouvertes.fr/hal-01054330
DOI : 10.1007/s00269-014-0665-1

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : The core structures of dislocations in diopside have been calculated within the Peierls model, which assumes a planar core. 1/2 < 110 > dislocations can dissociate into two collinear partial dislocations. We show that [001] glide is very difficult in (010) and that a non-collinear dissociation of [001](100) (modelled within a Peierls-Nabarro-Galerkin approach) makes glide equally easy in (100) and {110}. A widely spread core structure corresponding to a low lattice friction has been found for [100](010) and [010](100) dislocations which is not supported by mechanical data and, together with TEM observations, suggests that another, probably non-planar core structure is possible for these dislocations.
ISSN: 0342-1791

hal-00558238
https://hal.archives-ouvertes.fr/hal-00558238
DOI : 10.1007/s00269-010-0370-7

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We performed torsional deformation experiments on pre-hydrated fine-grained olivine aggregates using an innovative experimental assembly to investigate water weakening in mantle rocks at high shear strains. San Carlos olivine powder was cold-pressed and then hot-pressed under hydrous conditions, producing aggregates with average grain sizes of 7 or 15 μm. Deformation experiments were performed in a high-resolution gas-medium apparatus equipped with a torsional actuator, under a confining pressure of 300 MPa, a temperature of 1200 °C, and constant shear strain rates ranging from 8 × 10−5 to 1.4 × 10−4 s−1. Maximum shear stresses range from 150 to 195 MPa. These values are 30% lower relative to those determined in previous torsion experiments on dry, fined-grained dunites under similar conditions. Textures and microstructures of the starting and deformed specimens were characterized by scanning and transmission electron microscopy. All deformed aggregates exhibit a shape-preferred orientation marking a foliation and lineation, as well as a reduction in mean grain size from 15 μm down to 3-4 μm due to dynamic recrystallization. Olivine crystallographic fabrics developed rapidly (γ < 0.1), but their strength, characterized by the J-index, is low compared to naturally deformed peridotites or to polycrystalline olivine deformed at similar finite shear strains under dry conditions. The crystallographic fabrics are consistent with deformation by a dislocation accommodated creep mechanism with activation of multiple {0 k l}[1 0 0] systems, among which the (0 1 0)[1 0 0] slip system is dominant, and minor participation of the (0 1 0)[0 0 1] slip system. Transmission electron microscopy confirmed the occurrence of dislocations with [1 0 0] and [0 0 1] Burgers vectors in most grains. Analysis of unpolarized infrared spectra indicates that hydrogen concentration in the olivine lattice is below the saturation level of 18 ppm wt H2O, which is similar to those typically observed in spinel-bearing peridotite xenoliths, and also provide evidence for water-rich inter-granular material trapped in pores and grain boundaries. Seismic properties computed from the CPO observations correspond to those most commonly observed in naturally deformed mantle peridotites with fast P-wave propagation and S-wave polarization subparallel to the shear direction. These torsion experiments on fine-grained olivine polycrystals under hydrous conditions indicate that water weakening under lithospheric conditions is linked to various defects with hydrogen in the olivine structure, as well as with water-derived species in grain boundaries or pores.
ISSN: 0031-9201

hal-00745170
https://hal.archives-ouvertes.fr/hal-00745170
DOI : 10.1016/j.pepi.2012.05.001

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Mantle noble gases record important and ancient isotopic heterogeneities, which fundamentally influence our understanding of mantle geodynamics, yet these heterogeneities are difficult to fully interpret without understanding the basic mechanisms of noble gas storage and transport in mantle minerals. A series of annealing experiments that mimic mantle conditions (i.e. sub-solidus with natural, polycrystalline, texturally equilibrated olivines at low noble gas partial pressures) show that intergranular interfaces (grain boundaries) are major hosts for noble gases in the mantle, and that interfaces can dramatically fractionate noble gases from their radio-parents (U + Th and K). Therefore, noble gas isotopic heterogeneities in the mantle could result from grain size variations. Fine-grained lithologies (mylonites and ultramylonites, for example) with more grain boundaries will have lower U/3He ratios (compared to a coarse grained equivalent), which, over time, will preserve higher 3He/4He ratios. As predicted by theory of points defect diffusivity, these results show that noble gas diffusion along interfaces is different from those in the grain lattice itself at low temperatures. However, for grain size relevant of the Earth's mantle, the resulting effective correlated activation energies (Ea)(Ea) and pre-exponential factors (Do/a2)(Do/a2) produce similar diffusivities at mantle temperatures for interface- and lattice-hosted helium. Therefore, grain boundaries do not significantly affect helium transport at mantle conditions and length scales.
ISSN: 0012-821X

hal-01236013
https://hal.archives-ouvertes.fr/hal-01236013
DOI : 10.1016/j.epsl.2015.08.024

Éditeur(s) : HAL CCSD Mineralogical Society of America
Résumé : International audience
To test if hydrogen incorporation by ionic diffusion can occur between a volatile-rich kimberlitic liquid and forsterite, results of high-pressure and high-temperature experiments using a piston-cylinder apparatus at 1200–1300 °C and 1 GPa for durations of 1 min, 5 h, and 23 h, are reported here. Kimberlitic liquid in the system CaO-MgO-Al2O3-SiO2-CO2-H2O and synthetic forsterite single crystals were chosen as a first simplification of the complex natural kimberlite composition. Unpolarized Fourier transform infrared spectroscopy was used to quantify the concentrations of OH in the crystallographically oriented forsterite. Scanning electron microscopy, electron backscattered diffraction, electron microprobe analyses, and transmission electron microscopy were performed to identify the run products. After 5 and 23 h, a forsterite overgrowth crystallized with the same orientation as the initial forsterite single crystal. The kimberlitic liquid has crystallized as micrometer-scale euhedral forsterite neocrystals with random crystallographic orientations, as well as a nanoscale aluminous phase and a calcic phase. Despite theoretical water-saturation of the system and long duration, none of the initial forsterite single crystals display signs of hydration such as hydrogen diffusion profile from the border toward the center of the crystal. Most likely, the presence of CO2 in the system has lowered the H2O fugacity to such an extent that there is no significant hydration of the starting forsterite single crystal or its overgrowth. Also, the presence of CO2 enhances rapid forsterite crystal growth. Forsterite growth rate is around 2 × 108 μm3/h at 1250 °C. These experimental results suggest a deep mantle origin of the high OH content found in natural mantle-derived xenoliths transported in kimberlites, as reported from the Kaapvaal craton. In agreement with previous studies, it also points out to the fact that significant hydration must take place in a CO2-poor environment.
ISSN: 0003-004X

hal-01217157
https://hal.archives-ouvertes.fr/hal-01217157
DOI : 10.2138/am-2015-5200

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
BACKGROUND: Mutations in the telomerase complex (TERT and TR) are associated with pulmonary fibrosis and frequent hematologic manifestations. The aim of this study was to characterize the prognosis of lung transplantation in patients with TERT or TR mutations. METHODS: Patients with documented TERT or TR mutations who received a lung transplant between 2007 and 2013 in France were identified via an exhaustive search of the lung transplantation network, one expert genetic laboratory, and the clinical research network on rare pulmonary diseases. RESULTS: There were 9 patients (7 men) with TERT (n = 6) or TR (n = 3) mutations who received a single (n = 8) or a double (n = 1) lung transplant for pulmonary fibrosis. Median age was 50 years (range, 35-61 years) at diagnosis and 52 years (range, 37-62 years) at the time of lung transplantation. Thrombocytopenia was present in 7 patients before lung transplantation. After lung transplantation, 6 patients developed myelodysplasia and/or bone marrow failure, directly contributing to death in 4 cases. Anemia was observed in 9 patients, and neutropenia was observed in 3 patients. The median survival after lung transplantation was 214 days (range, 59-1,709 days). CONCLUSIONS: Patients with mutations of the telomerase complex are at high risk of severe hematologic complications after lung transplantation, in particular, bone marrow failure. Specific recommendations should be developed for appropriate guidance regarding hematologic risk assessment before transplantation and management of the post-transplantation immunosuppressive regimen.
ISSN: 1053-2498

hal-01146848
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01146848
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01146848/document
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01146848/file/Severe%20hematological%20complications%20after%20lung%20transplantation_accepted.pdf
DOI : 10.1016/j.healun.2014.11.010

Éditeur(s) : HAL CCSD Taylor & Francis: STM, Behavioural Science and Public Health Titles
Résumé : International audience
The dislocation microstructures in a single crystal of olivine deformed experimentally in uniaxial compression at 1090 °C and under a confining pressure of 300 MPa, have been investigated by transmission electron tomography in order to better understand deformation mechanisms at the microscale relevant for lithospheric mantle deformations. Investigation by electron tomography reveals microstructures, which are more complex than previously described, composed of and dislocations commonly exhibiting 3D configurations. Numerous mechanisms such as climb, cross-slip, double cross-slip as well as interactions like junction formations and collinear annihilations are the source of this complexity. The diversity observed advocates for microscale deformation of olivine significantly less simple than classic dislocation creep reported in metals or ice close to melting temperature. Deciphering mechanism of hardening in olivine at temperatures where ionic diffusion is slow and is then expected to play very little role is crucial to better understand and thus model deformation at larger scale and at temperatures (900–1100 °C) highly relevant for the lithospheric mantle.
ISSN: 1478-6443

hal-01667146
https://hal.archives-ouvertes.fr/hal-01667146
DOI : 10.1080/14786435.2017.1367858

Éditeur(s) : HAL CCSD Nature Publishing Group
Résumé : International audience
Mantle flow involves large strains of polymineral aggregates. The strongly anisotropic plastic response of each individual grain in the aggregate results from the interactions between neighbouring grains and the continuity of material displacement across the grain boundaries. Orthorhombic olivine, which is the dominant mineral phase of the Earth's upper mantle, does not exhibit enough slip systems to accommodate a general deformation state by intracrystalline slip without inducing damage. Here we show that a more general description of the deformation process that includes the motion of rotational defects referred to as disclinations can solve the olivine deformation paradox. We use high-resolution electron backscattering diffraction (EBSD) maps of deformed olivine aggregates to resolve the disclinations. The disclinations are found to decorate grain boundaries in olivine samples deformed experimentally and in nature. We present a disclination-based model of a high-angle tilt boundary in olivine, which demonstrates that an applied shear induces grain-boundary migration through disclination motion. This new approach clarifies grain-boundary-mediated plasticity in polycrystalline aggregates. By providing the missing mechanism for describing plastic flow in olivine, this work will permit multiscale modelling of the rheology of the upper mantle, from the atomic scale to the scale of the flow.
ISSN: 0028-0836

hal-01054315
https://hal.archives-ouvertes.fr/hal-01054315
DOI : 10.1038/nature13043

Éditeur(s) : HAL CCSD Taylor & Francis: STM Behavioural Science and Public Health Titles Taylor & Francis: STM, Behavioural Science and Public Health Titles
Résumé : We have investigated by electron tomography, in a transmission electronic microscope, the interactions between dislocations in olivine single crystals and polycrystals deformed in axial compression at T < 1000 °C (T < 0.5Tm). Dislocations are mostly of the [0 0 1] type, except in the polycrystal where [1 0 0] and [0 0 1] dislocations have been activated. A few 〈1 0 1〉 junctions have been found and characterized. Many collinear interactions have been identified either involving direct interactions between crossing dislocations of opposite Burgers vectors or indirect interactions between dislocations gliding in parallel planes and sessile dislocation loops. We suggest that collinear interaction, already identified as the primary source of strain hardening in FCC metals, is the main dislocation interaction mechanism in olivine deformed at temperatures below 1000 °C.
ISSN: 1478-6443

hal-01174166
https://hal.archives-ouvertes.fr/hal-01174166
DOI : 10.1080/14786435.2014.1000996