Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Ultraslow spreading at mid-ocean ridges limits melting due to on-axis conductive cooling, leading to the prediction that peridotites from these ridges are relatively fertile. To test this, we examined abyssal peridotites from the Gakkel Ridge, the slowest spreading ridge in the global ocean ridge system. Major and trace element concentrations in pyroxene and olivine minerals are reported for 14 dredged abyssal peridotite samples from the Sparsely Magmatic (SMZ) and Eastern Volcanic (EVZ) Zones. We observe large compositional variations among peridotites from the same dredge and among dredges in close proximity to each other. Modeling of lherzolite trace element compositions indicates varying degrees of non-modal fractional mantle melting, whereas most harzburgite samples require open-system melting involving interaction with a percolating melt. All peridotite chemistry suggests significant melting that would generate a thick crust, which is inconsistent with geophysical observations at Gakkel Ridge. The refractory harzburgites and thin overlying oceanic crust are best explained by low present-day melting of a previously melted heterogeneous mantle. Observed peridotite compositional variations and evidence for melt infiltration demonstrates that fertile mantle components are present and co-existing with infertile mantle components. Melt generated in the Gakkel mantle becomes trapped on short length-scales, which produces selective enrichments in very incompatible rare earth elements. Melt migration and extraction may be significantly controlled by the thick lithosphere induced by cooling at such slow spreading rates. We propose the heterogeneous mantle that exists beneath Gakkel Ridge is the consequence of ancient melting, combined with subsequent melt percolation and entrapment.
ISSN: 0016-7037

hal-01307003
https://hal.archives-ouvertes.fr/hal-01307003
DOI : 10.1016/j.gca.2015.11.017

Éditeur(s) : HAL CCSD
Résumé : This study provides additional constraints on the relations between deformation, hydration and percolation of fluids and melts in the subcontinental lithospheric mantle beneath a craton and a rift, as well as their implication on its geodynamical behaviour. I have analysed the microstructures, the CPOs, and the hydrogen content of mantle xenoliths from the Kaapvaal craton, and two sets of xenoliths from different localities along the East African Rift (North Tanzanian Divergence and SE Ethiopia).The coarse-granular microstructures and the well-defined CPOs in Kaapvaal peridotites suggest a deformation followed by a long quiescence time. Orthorhombic olivine CPOs predominates, but axial-[100] and axial-[010] are also measured. Cratonic peridotites record multiple metasomatic episodes, leading to a significant compositional heterogeneity, which cannot be imaged by seismic studies. Olivine hydrogen contents are variable, but tend to increase until 150 km depth, reaching up to 50 ppm wt. H2O. The deeper samples are almost dry. Piston-cylinder experiments on hydrogen diffusion between a volatile-rich kimberlitic melt and forsterite suggest that the presence of CO2 in the system could significantly decrease water fugacity and thus forsterite hydration. These experimental results indicate that the hydrogen contents measured in olivine were acquired during a metasomatic event rather than during xenolith extraction by kimberlites. However, this metasomatism was not followed by remobilization of the cratonic root.In the North Tanzanian Divergence, localities within the rift axis and the volcanic transverse belt (Lashaine and Olmani) show significant differences in microstructures and olivine CPO patterns. In Lashaine, coarse-granular microstructures and orthorhombic to axial-[100] CPO patterns in olivine can be explained by transpressional deformation during the formation of the Mozambique belt, or by the occurrence of a remnant of a cratonic domain embedded within the Mozambique belt. Within the rift axis, porphyroclastic to mylonitic microstructures suggest a recent rift-related deformation accompanied by syn-kinematic melt-rock reactions, and followed by variable annealing. The strong heterogeneity in microstructures and olivine CPO suggests that this deformation was acquired during multiple tectonic events probably linked to episodic magma percolation, separated by quiescence episodes. The axial-[100] patterns in olivine and the oblique fast directions reported by SKS studies are coherent with transtensional deformation within the lithospheric mantle beneath the rift.The peridotites from SE Ethiopia are less recrystallized than the rift-axis Tanzanian peridotites, displaying coarse-porphyroclastic microstructures. Microstructures and orthorhombic CPOs in olivine suggest syn- to post-metasomatic deformation. S-waves polarization anisotropies calculated for these samples cannot explain alone the delay times reported by SKS studies in this part of the East-African Rift.
Les travaux réalisés durant cette thèse apportent de nouvelles contraintes sur les relations entre déformation, hydratation et percolation de fluides et/ou de magmas dans le manteau subcontinental sous un craton et sous un rift, et leurs implications sur son comportement rhéologique. Il repose sur l'analyse des microstructures, des OPRs et des teneurs en hydrogène de xénolites mantelliques du craton du Kaapvaal, et sur deux séries de xénolites provenant de différentes localités le long du rift Est-Africain (Divergence Nord Tanzanienne et SE de l'Ethiopie). Les microstructures granulaires à gros grains et les OPRs bien définies des péridotites du craton du Kaapvaal sont cohérentes avec un épisode de déformation suivi d'une longue période de quiescence. Les OPRs de l'olivine sont majoritairement à symétrie orthorhombique, mais des symétries axiale-[100] et axiale-[010] sont aussi mesurées. Les péridotites cratoniques enregistrent de multiples épisodes métasomatiques, ayant entraîné une hétérogénéité de compositions à petite échelle ne pouvant être détectée par les études sismiques. Les teneurs en hydrogène mesurées dans l'olivine sont variables, mais ont tendance à augmenter jusqu'à 150 km de profondeur, atteignant alors jusqu'à 50 ppm wt. H2O. En dessous de cette profondeur, les échantillons montrent des teneurs en hydrogène très faibles. Les expériences réalisées en piston-cylindre sur la diffusion de l'hydrogène issue d'un liquide kimberlitique vers de la forstérite suggèrent que la fugacité en eau pourrait fortement être diminuée par la présence de CO2, empêchant l'hydratation de l'olivine durant extraction des xénolites par les kimberlites. Ces résultats expérimentaux suggèrent que les teneurs en hydrogène dans l'olivine des péridotites du craton du Kaapvaal ont été acquises durant un épisode métasomatique en profondeur et non pendant leur extraction par les kimberlites. Ces teneurs n'ont toutefois pas à ce jour entraîné de remobilisation de la racine cratonique. Enfin, le calcul des propriétés sismiques des péridotites cratoniques révèle que les anisotropies générées par les OPRs de ces échantillons sont suffisantes pour expliquer les anisotropies mesurées par les ondes SKS et les ondes de surface.Les xénolites de la Divergence Nord-Tanzanienne, montrent des variations significatives de microstructures et d'OPR de l'olivine entre les péridotites des localités dans l'axe du rift et celles de la chaîne volcanique transverse (Lashaine et Olmani). A Lashaine, les microstructures granulaires à gros grains et les OPRs de type orthorhombique et axial-[010] peuvent être expliquée par une déformation en transpression liée à la formation de la chaîne Mozambique ou par la présence d'une relique d'un domaine cratonique à l'intérieur de la chaîne Mozambique. Dans l'axe du rift, les microstructures porphyroclastiques à mylonitiques suggèrent une déformation plus récente, accompagnée de réactions magma-roche sous des conditions proches du solidus, suivie d'un recuit variable. L'hétérogénéité des microstructures enregistrées par les échantillons du rift suggère de multiples épisodes de déformation localisée, probablement liés à l'injection percolation épisodique de magmas, espacés de périodes d'accalmie. Les OPRs de l'olivine de type axial-[100] et l'orientation des directions de polarisation des ondes SKS suggère que le rift s'est formé en régime de transtension Les péridotites du Sud-Est de l’Éthiopie présentent des microstructures porphyroclastiques à gros grains moins recristallisées qu'en Tanzanie. Les microstructures et les OPRs principalement de type orthorhombique suggèrent une déformation syn- à post-métasomatisme. Les anisotropies de polarisation des ondes S calculées pour ces échantillons sont insuffisantes pour expliquer à elles seules les déphasages des ondes SKS dans cette partie du rift.
https://tel.archives-ouvertes.fr/tel-01684759

Droits : info:eu-repo/semantics/OpenAccess
NNT : 2014MON20139
tel-01684759
https://tel.archives-ouvertes.fr/tel-01684759
https://tel.archives-ouvertes.fr/tel-01684759/document
https://tel.archives-ouvertes.fr/tel-01684759/file/43443_BAPTISTE_2014_archivage_cor.pdf

Éditeur(s) : HAL CCSD
Résumé : IODP Hole U1309D (IODP Exp. 304-305, 30°N) and ODP Site 1275 (ODP Lag 209, 15°45?N) sampled two oceanic core complexes, at the Mid-Atlantic Ridge. The recovered rocks are mostly gabbroic with some very primitive and olivine rich (Ol>70%). In Hole U1309D, trace element compositions of clinopyroxene and plagioclase poikiloblasts from olivine-rich rocks ndicate that they crystallized from the same melt in all lithologies. Olivine trace element compositions are in disequilibrium with the two other minerals. Olivine crystallographic preferred orientations are weak, with a relatively strong uncommon [001] concentration but consistent with deformation by dislocation creep with activation of the high temperature (010) [100] slip system, commonly described in asthenospheric mantle. The joint study of geochemical processes and microstructures in these rocks suggest a complex crystallization history in an open system with percolation of large volume of MORBtype melt and interaction with the depleted shallow mantle. Olivine-rich rocks are interpreted as the ultimate residue of these melt-mantle reaction processes. At Site 1275, the formation of the more evolved rocks of the gabbroic series is not related to the impregnation event creating olivine-rich rocks.
These rocks represent late magmatic injections, which are completely crystallized at depth as intrusivegabbroic bodies. The results presented in this thesis are consistent with the formation of oceanic core complexes associated with relatively strong magmatic activity, and with the crystallization of most of melt in the lithosphere without basaltic counterpart erupted on the seafloor.
Le puits IODP U1309D (Exp. IODP 304-305, 30°N) et le Site ODP 1275 (Leg ODP 209, 15°45'N) ont permis d'échantillonner deux core complexes océaniques de la dorsale Médio-Atlantique. Les roches récupérées sont principalement gabbroïques dont certaines très primitives et riches en olivine (ol >70%). Dans le puits U1309D, les compositions en éléments en trace des poeciloblastes de clinopyroxène et de plagioclase des roches riches en olivine indiquent qu'ils précipitent depuis le même magma dans toutes les lithologies. La composition en éléments en trace des olivines est en déséquilibre avec ces deux minéraux. Les fabriques cristallographiques de l'olivine sont faibles avec une concentration sur [001] inhabituelle, néanmoins compatibles avec une déformation plastique de haute température, avec l'activation du système de glissement (010) [100] communément décrit dans le manteau asthénosphérique. L'étude conjointe des caractéristiques géochimiques et microstructurales de ces roches met en lumière une histoire complexe de cristallisation dans un système ouvert où de larges volumes de magma de type MORB ont percolé et interagi avec le manteau appauvri superficiel. Ces roches riches en olivine représenteraient le résidu ultime de ces réactions liquide-manteau. Au site 1275, la formation des roches les plus évoluées de la série n'apparaît pas liée à l'événement d'imprégnation formant les roches riches en olivine. Ces roches correspondent à des injections tardives de magma qui ont entièrement cristallisé en profondeur sous forme de plutons intrusifs. Les résultats présentés dans ce mémoire sont compatibles avec une formation des core complexes océaniques associée à une activité magmatique relativement importante, et à une cristallisation complète de tout ou partie de ces magmas dans la lithosphère sans contre-partie volcanique en surface.
https://tel.archives-ouvertes.fr/tel-00354807

tel-00354807
https://tel.archives-ouvertes.fr/tel-00354807
https://tel.archives-ouvertes.fr/tel-00354807/document
https://tel.archives-ouvertes.fr/tel-00354807/file/these_MD.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Interactions between deformation and melt percolation yield important consequences for the evolution of the mantle lithosphere, controlling its composition and mechanical behavior. In the Lherz massif (Pyrenees, France), the analysis of structural relationships between harzburgites, lherzolites and pyroxenites and of the crystal-preferred orientations (CPO) of olivine and pyroxenes highlights a strong feedback between percolation of basaltic melts and deformation under near-solidus conditions at the lithosphere–asthenosphere boundary. Elongated harzburgite bodies up to tens of meters wide, which are the remnants of an old lithospheric mantle, preserve a constant foliation. This foliation is locally outlined by cm-scale flattened websteritic lenses. At the contact with the enclosing lherzolites, the harzburgite foliation is crosscut by the lherzolites foliation and by cm-wide websterite bands parallel to the contact. Strain intensity in the lherzolites increases with distance to the harzburgites. Based on these observations, we propose that reactive percolation was synchronous to the deformation and propose that variations in instantaneous melt fraction, due to pyroxenes and spinel crystallization during reactive melt transport, guided strain localization. Accordingly, the observed decrease in olivine CPO intensity and change in CPO patterns from harzburgites to distal lherzolites are interpreted as recording changes in the relative contribution of dislocation glide and diffusion processes, which is ruled by a balance between the instantaneous melt fraction and the local strain rate. We also propose that the pervasive websteritic layering in the refertilized lherzolites may result from deformation-assisted melt segregation in a system with decreasing permeability due to refertilization reactions. Finally, we discuss the possible timing and geodynamical context of the refertilization episode.
ISSN: 0012-821X

hal-00411724
https://hal.archives-ouvertes.fr/hal-00411724
DOI : 10.1016/j.epsl.2008.07.053

Éditeur(s) : HAL CCSD AGU and the Geochemical Society
Résumé : International audience
Peridotite xenoliths brought up to the surface by the volcanism of the Kerguelen Islands represent a mantle that has been affected by a high degree of partial melting followed by intense melt percolation above the Kerguelen plume. These xenoliths are therefore particularly suitable to investigate effects of melt-rock interaction on crystallographic fabrics (lattice-preferred orientation (LPO)) of peridotite minerals and on the LPO-induced seismic properties of peridotites above a mantle plume. We have studied a suite of 16 ultramafic samples representative of different degrees of partial melting and magma-rock interaction among which the protogranular harzburgites are the least metasomatised xenoliths and dunites are the ultimate stage of metasomatism. Olivine LPO is characterized by high concentration of [010] axes perpendicular to the foliation and [100] axes close to the lineation or distributed in the foliation plane in harzburgites, whereas the high concentration of [100] axes is parallel to the lineation and [010] axes is perpendicular to the assumed foliation in dunites. Olivine LPO in harzburgites is interpreted as being due to a deformation regime in axial compression or transpression. The fabric strength of olivine decreases progressively from protogranular to poikilitic harzburgites and finally to dunites, for which it remains nevertheless significant (J index 3.8). Seismic properties calculated from LPO of minerals indicate that metasomatism at higher melt/rock ratio lowers the P wave velocities. The most significant difference between harzburgites and dunites corresponds to the distribution of S wave anisotropy. Harzburgites display the maximum of anisotropy within the foliation plane and the minimum of anisotropy perpendicular to the foliation plane, whereas the lowest anisotropy is parallel to the lineation for dunites. These modifications of seismic properties as a result of metasomatic processes may induce seismic heterogeneities in the mantle above the Kerguelen plume. In addition, assuming a lithospheric mantle primarily harzburgitic and structured with a horizontal foliation, the seismic properties calculated for the Kerguelen xenoliths reconcile the rather high anisotropy evidenced by the horizontally propagating surface waves with the apparent isotropy revealed by the absence of splitting of vertically propagating teleseismic SKS waves recorded by the GEOSCOPE Kerguelen station.
ISSN: 1525-2027

hal-00366222
https://hal.archives-ouvertes.fr/hal-00366222
https://hal.archives-ouvertes.fr/hal-00366222/document
https://hal.archives-ouvertes.fr/hal-00366222/file/bascou_Kerguelen_2007GC001879_hal.pdf
DOI : 10.1029/2007GC001879

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The subcontinental lithospheric mantle evolves through time due to tectonic events and processes as static recrystallization and melt percolation. To constrain the extent of these processes in the South Patagonian subcontinental mantle lithosphere we performed a microstructural and Electron Backscattered Diffraction (EBSD) study of a suite of 35 peridotite xenoliths brought to the surface by Plio-Pleistocene alkaline volcanic rocks from Gobernador Gregores and Pali Aike. All samples show a well-developed olivine and pyroxene crystallographic preferred orientation (CPO), consistent with deformation by dislocation creep with dominant activation of [100]{0kl} in olivine. The coarse granular or tabular textures and the low density of intracrystalline deformation features indicate that deformation was followed by annealing under static conditions. The xenoliths also show microstructural evidence of multiple episodes of reactive melt percolation. Neither annealing nor melt percolation erased the olivine CPO, which has [010]-fiber, [100]-fiber and orthorhombic patterns in Pali Aike xenoliths and essentially [010]-fiber and orthorhombic patterns in Gobernador Gregores xenoliths. Seismic properties calculated based on the CPO and modal compositions are, however, rather homogeneous, with fast S-wave polarization and P-wave propagation parallel to the [100] olivine axis. The variation in the olivine CPO solely changes the minimum S-wave birefringence direction, which is normal to the foliation for axial-[010] olivine CPO. Average samples for the two localities, obtained by adding up the individual samples CPO data in a common reference frame, show, however, a 'normal' upper mantle anisotropy with a maximum S-wave birrenfringence of ca. 5% at high angle to the both the maximum [010] and [100] axes concentrations, that is in the foliation, but normal to the lineation, and a minimum birefringence at low angle to the [100] maximum, that is parallel to the lineation.
ISSN: 0040-1951

hal-01053500
https://hal.archives-ouvertes.fr/hal-01053500
DOI : 10.1016/j.tecto.2014.02.017

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
The western part of the Ronda peridotite massif (Southern Spain) consists mainly of highly foliated spinel-peridotite tectonites and undeformed granular peridotites that are separated by a recrystallization front. The spinel tectonites are interpreted as volumes of ancient subcontinental lithospheric mantle and the granular peridotites as a portion of subcontinental lithospheric mantle that underwent partial melting and pervasive percolation of basaltic melts induced by Cenozoic asthenospheric upwelling. The Re-Os isotopic signature of sulfides from the granular domain and the recrystallization front mostly coincides with that of grains in the spinel tectonites. This indicates that the Re-Os radiometric system in sulfides was highly resistant to partial melting and percolation of melts induced by Cenozoic lithospheric thermal erosion. The Re-Os isotopic systematics of sulfides in the Ronda peridotites thus mostly conserve the geochemical memory of ancient magmatic events in the subcontinental lithospheric mantle. Os model ages record two Proterozoic melting episodes at similar to 1.6 to 1.8 and 1.2-1.4 Ga, respectively. The emplacement of the massif into the subcontinental lithospheric mantle probably coincided with one of these depletion events. A later metasomatic episode caused the precipitation of a new generation of sulfides at similar to 0.7 to 0.9 Ga. These Proterozoic Os model ages are consistent with results obtained for several mantle suites in Central/Western Europe and Northern Africa as well as with the Nd model ages of the continental crust of these regions. This suggests that the events recorded in mantle sulfides of the Ronda peridotites reflect different stages of generation of the continental crust in the ancient Gondwana supercontinent.
ISSN: 0010-7999

hal-00564508
https://hal.archives-ouvertes.fr/hal-00564508
DOI : 10.1007/s00410-009-0429-y

Éditeur(s) : HAL CCSD American Geophysical Union (AGU)
Résumé : Mantle xenoliths in Pliocene alkali basalts of the eastern Betics (SE Iberia, Spain) are spinel ± plagioclase lherzolite, with minor harzburgite and wehrlite, displaying porphyroclastic or equigranular textures. Equigranular peridotites have olivine crystal preferred orientation (CPO) patterns similar to those of porphyroclastic xenoliths but slightly more dispersed. Olivine CPO shows [100]-fiber patterns characterized by strong alignment of [100]-axes subparallel to the stretching lineation and a girdle distribution of [010]-axes normal to it. This pattern is consistent with simple shear or transtensional deformation accommodated by dislocation creep. One xenolith provides evidence for synkinematic reactive percolation of subduction-related Si-rich melts/fluids that resulted in oriented crystallization of orthopyroxene. Despite a seemingly undeformed microstructure, the CPO in orthopyroxenite veins in composite xenoliths is identical to those of pyroxenes in the host peridotite, suggesting late-kinematic crystallization. Based on these observations, we propose that the annealing producing the equigranular microstructures was triggered by melt percolation in the shallow subcontinental lithospheric mantle coeval to the late Neogene formation of veins in composite xenoliths. Calculated seismic properties are characterized by fast propagation of P waves and polarization of fast S waves parallel to olivine [100]-axis (stretching lineation). These data are compatible with present-day seismic anisotropy observations in SE Iberia if the foliations in the lithospheric mantle are steeply dipping and lineations are subhorizontal with ENE strike, implying dominantly horizontal mantle flow in the ENE-WSW direction within vertical planes, that is, subparallel to the paleo-Iberian margin. The measured anisotropy could thus reflect a lithospheric fabric due to strike-slip deformation in the late Miocene in the context of WSW tearing of the subducted south Iberian margin lithosphere.
ISSN: 0278-7407

Droits : info:eu-repo/semantics/OpenAccess
hal-01685809
https://hal.archives-ouvertes.fr/hal-01685809
https://hal.archives-ouvertes.fr/hal-01685809/document
https://hal.archives-ouvertes.fr/hal-01685809/file/Hidas_et_al-2016-Tectonics.pdf
DOI : 10.1002/2016TC004165

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Despite a relatively 'uniform' fertile composition (Al2O3 = 2 center dot 19-4 center dot 47 wt %; Fo% = 89 center dot 2 +/- 0 center dot 3%; Cr#(Spl) = 8 center dot 9 +/- 1 center dot 5%), the Montferrier peridotite xenoliths show a wide range of S contents (22-590 ppm). Most sulphides are interstitial and show peculiar pyrrhotite-pentlandite intergrowths and low abundances of Cu-rich phases. Sulphide-rich samples are characterized by strong enrichment in the light rare earth elements and large ion lithophile elements without concomitant enrichment of the high field strength elements. Such trace-element fractionation is commonly ascribed to metasomatism by volatile-rich melts and/or carbonatitic melts. S and Se (11-67 ppb), as well as S/Se (up to approximate to 12 000), are correlated with La/Sm. Cu, however, remains broadly constant (30 +/- 5 ppm). These features strongly suggest that the percolation-reaction of such volatile-rich fluids has led to sulphide enrichment with an atypical signature marked by strong fractionation of the chalcophile elements (i.e. S vs Se and Cu). S-rich xenoliths are also characterized by high (Pd/Ir)(N) (1 center dot 2-1 center dot 9; where subscript N indicates normalized to chondrite), (Pd/Pt)(N) between 1 center dot 5 and 2 center dot 2, and (Os/Ir)(N) up to 1 center dot 85. Despite the relative uniform fertile composition of the xenoliths, Re/Os ranges between 0 center dot 02 and 0 center dot 18. Os-187/Os-188 is extremely variable even within a single sample and can be as high as 0 center dot 1756 for the most S-rich samples. Sulphides show highly fractionated and variable abundances of the highly siderophile elements (HSE) [0 center dot 03 (Pd/Ir)(N) < 1283] and Re-Os isotopic composition (0 center dot 115 < Os-187/Os-188 < 0 center dot 172). Such variation can be observed at the thin-section scale. Whole-rock and in situ sulphide data demonstrate that chalcophile and HSE systematics and the Os isotopic composition of the upper mantle could be significantly modified through metasomatism, even with volatile-rich fluids. These features highlight the complex behaviour of the HSE in fluid-rock percolation-reaction models and suggest a complex interplay between sulphide addition (crystallization or sulphidation) and partial equilibration of pre-existing sulphide. The specific fractionations observed in chemical proxies such as S and Se, Os and Ir, and Pd and Pt, as well as the low abundance of Cu-rich sulphides, suggest that sulphide addition may not have occurred via sulphide melts. Rather, we infer that S was present as a dissolved species in a (supercritical) oxidizing, volatile-rich fluid (C-O-H-S +/- Cl) along with other chalcophile and siderophile elements such as Os, Pd, Re and Au. The highly radiogenic Os composition of this fluid ( Os-187/ Os-188 > 0 center dot 17) would imply that such fluids are derived from an uncommon type of mantle source possibly related to carbonatite melts.
ISSN: 0022-3530

hal-00644524
https://hal.archives-ouvertes.fr/hal-00644524
DOI : 10.1093/petrology/egr038

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
A suite of eclogite xenoliths from the Roberts Victor kimberlite (South Africa) is remarkable for its high abundances of base metal sulfides (BMS; up to 2 modal %). However, while sulfides are nearly ubiquitous in Type I eclogites (garnet > 0.07% Na2O), Type II eclogites (garnet < 0.07% Na2O) systematically lack sulfides. Two different sulfide assemblages are recognised within the Type I xenolith suite. Both populations are polyphase Cu-Ni-Fe sulfides, one characterised by the pyrrhotite (Po) + pentlandite (Pn) + chalcopyrite (Cp) assemblage and the other by the smythite/violarite (Smy/Vi) + (Ni)pyrite (Py) + Cp assemblage. The latter is the most abundant assemblage and reflects the supergene alteration of the "primary" Po + Pn + Cp assemblage. This process overprints the original composition of the sulfides by remobilising elements such as S, Fe, Ni, Se and Te. In the Type I eclogites, BMS occur as inclusions within silicates (garnet and clinopyroxene) and as interstitial grains. No chemical differences were observed between enclosed and interstitial sulfides. However, their relative abundances are correlated, indicating a similar origin. The Po + Pn + Cp assemblage is identical to eclogitic sulfides previously described in some Roberts Victor diamonds. Silicate-enclosed sulfides could appear to be early phases, but they are restricted to the outer parts of the silicate grains, suggesting a late incorporation during partial recrystallisation of silicate phases, induced by fluid-rock percolation-reaction during a metasomatic event. Positive whole-rock correlations between Se and (La/Sm)N⁎ and between Cu and ΣLREEN⁎ indicate a direct link between sulfide content and the enrichment of Mg + incompatible elements in the Type I eclogites, further supporting a metasomatic origin of the sulfide component. Similarly, a negative correlation between ΣLREEN⁎ and Cucpx implies that the metasomatic agent was at least partially composed of S-rich fluid (e.g. H2S, SO2) that reacted with the rock and leached Cu out of the silicates. The coupling between sulfides and LREE in the Type I eclogites, as well as the absence of sulfides and metasomatic features (e.g. unequilibrated grain boundaries, melt pockets, fluid inclusions, phlogopite) in the Type II eclogites, demonstrate that Type II eclogites did not undergo such a metasomatic event and therefore may represent the less-modified protoliths of Type I eclogites.
ISSN: 0009-2541

hal-00903856
https://hal.archives-ouvertes.fr/hal-00903856
DOI : 10.1016/j.chemgeo.2013.06.015

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Mantle-derived xenoliths hosted by melilitite lavas from In Teria (Ahaggar, SE Algeria) include garnet and spinel peridotites, pyroxenite and phlogopite megacrysts. The spinel and garnet peridotites record an early deformation event, which formed porphyroclastic microstructures and olivine crystal preferred orientations, followed by static infiltration of hydrous alkaline melts. This metasomatic stage (stage 1) is characterized by the crystallization of phlogopite in the garnet and spinel peridotites, amphibole in the spinel peridotites and clinopyroxene in the garnet peridotite, which record chemical equilibration with an alkaline silicate melt. These early events were largely overprinted by carbonatitic metasomatism (stage 2), which is observed only in the spinel peridotites. Spinel peridotite major and trace element compositions, as well as the compositions of newly formed minerals, are characteristic of interaction with carbonate melt, associated with strong enrichment in incompatible trace elements in clinopyroxene. This second stage was followed by crystallization of pyroxenites (stage 3) in vein conduits, probably segregated from alkaline melts. We propose a scenario in which the different metasomatic imprints record successive stages of interaction between lithospheric mantle and sublithospheric melts throughout the Cenozoic. In Sr–Nd isotope space, the host melilitites and several xenoliths are clustered and plot close to the HIMU mantle end-member. However, some peridotite xenoliths are shifted towards more radiogenic 87Sr/86Sr values. In 207Pb/204Pb–206Pb/204Pb and 208Pb/204Pb–06Pb/204Pb space the In Teria samples define a relatively large domain characterized by high 206Pb/204Pb and 208Pb/204Pb, consistent with a contribution of an HIMU component, considered to represent a sublithospheric signature. The highest 87Sr/86Sr values are comparable with those ascribed to the EM1 mantle end-member, representing the signature of the lower continental lithosphere, and are probably inherited from the pre-metasomatic lithospheric mantle beneath In Teria. Numerical modelling of porous percolation of melt of sublithospheric origin through an EM1-like lithospheric mantle protolith reproduces the In Teria peridotite compositions, using moderately sub-chondritic Sr/Nd values for the peridotite (e.g. In Teria garnet peridotite) and moderately super-chondritic Sr/Nd values in the melt (approximately ocean island basalt values). A few spinel peridotites require a component characterized by a 143Nd/144Nd signature higher than both the EM1 end-member and the local Ahaggar basalts; the 208Pb/204Pb compositions of several samples point to a component with a depleted mid-ocean ridge basalt (MORB) mantle (DMM) signature. Thus the lithospheric mantle beneath In Teria probably did not have a uniform EM1 signature before the onset of metasomatism; it included a DMM peridotite component as well as some peridotites with elevated 143Nd/144Nd values recording long-term LREE depletion.
ISSN: 0022-3530

hal-01356781
https://hal.archives-ouvertes.fr/hal-01356781
DOI : 10.1093/petrology/egw009

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
During ODP Leg 209, a magma-starved area of the Mid-Atlantic Ridge (MAR) was drilled in the vicinity of the Fifteen-Twenty Fracture Zone (FZ) that offsets one of the slowest portions of the spreading ridge. We present here the results of a bulk rock multi-elemental study of 27 peridotites drilled at Sites 1272 and 1274 (to the south and the north of the FZ, respectively). The peridotites comprise mainly of harzburgites with minor dunites. Clinopyroxene (Cpx), which is interstitial and interpreted as secondary, is observed in Site 1274 peridotites. Sites 1272 and 1274 peridotites have low Al2O3 contents (<= 1 anhydrous wt.%), high Mg# (>91.5), and bulk rock trace elements compositions mostly below 0.1 x primitive mantle (PM). These peridotites, and in particular Site 1272 peridotites, represent the most depleted peridotites yet sampled at a slow spreading ridge. Their compositions indicate high degrees of partial melting and melt extraction. A single open-system melting event (melting plus percolation of melts produced within upwelling mantle) can explain their highly depleted yet linear chondrite-normalized REE patterns, characterized by a steady depletion from HREE to LREE. Late melt-rock reactions and precipitation of Cpx explains the slightly less depleted compositions of Site 1274 peridotites. Hence, the differences in composition between Sites 1272 and 1274 peridotites do not provide evidence for regional variations in the degrees of partial melting from the south to the north of the FZ. The occurrence of highly refractory peridotites in the Fifteen-Twenty area suggests we sampled a more actively convecting mantle than generally supposed below slow spreading centers.
ISSN: 0012-821X

hal-00412001
https://hal.archives-ouvertes.fr/hal-00412001
DOI : 10.1016/j.epsl.2007.11.058

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Most kimberlites contain abundant dunitic nodules. These are centimetre-sized, rounded and multi-grained assemblages of xenocrystic olivine with a wide range of compositions (Fo83 to Fo94). The absence of orthopyroxene and other mantle minerals and the range of olivine compositions have been attributed to reaction between mantle peridotite and (proto)kimberlitic fluid or melt, but the timing of the reaction is a subject of debate. In a kimberlite from the Kangamiut region of Greenland, nodule cores are surrounded by fine-grained outer margins with near-constant Fo contents (∼Fo88) but highly variable minor element contents (e.g. 500–2500 ppm Ni). These margins crystallized from the kimberlite melt and we show that their compositions can be explained by crystallization of olivine alone, if a high partition coefficient for Ni between melt and olivine (DNi > 20) is assumed. Orthopyroxene assimilation is not required, removing the constraint that its dissolution occurred during ascent of the kimberlite magma. Within some nodules, in addition to the usual core-to-margin gradients, we observe asymmetric compositional changes (variable Fo but near-constant minor element contents) across mobile grain boundaries. These changes document fluid percolation at the grain scale that occurred during dynamic recrystallization in the deforming lithospheric mantle. We note that chemical gradients associated with mobile grain boundaries are observed in olivines that cover the entire compositional range of the nodules, and propose that fluid-assisted dynamic recrystallization took place in dunite that was already compositionally heterogeneous. Reaction between peridotite and protokimberlitic melt or fluid and dissolution of orthopyroxene thus occurred within the lithospheric mantle, immediately (a few days) prior to the ascent of the kimberlite melt and the entrainment of the dunite nodules. We propose that the grain boundary zones probably mimic, at a fine scale, the fluid–peridotite interaction that caused, at a larger scale, orthopyroxene dissolution and formation of compositionally diverse olivine in kimberlites.
ISSN: 0022-3530

hal-01277963
https://hal.archives-ouvertes.fr/hal-01277963
DOI : 10.1093/petrology/egv054

Éditeur(s) : HAL CCSD Elsevier
Résumé : The ultramafic–mafic complexes located at the base of obducted paleo-island arcs are commonly interpreted as evidence for intra-crustal fractionation of primitive (high-Mg#) mantle melts. The present study, realized on the Jijal mafic–ultramafic basal section of the Cretaceous Kohistan oceanic arc (N Pakistan), discards a crystal fractionation model from a single parental magma to take into account the geochemical and isotope variations observed between the plutonic crust and the underlying ultramafic section. The basal ultramafic rocks, i.e. dunites, wehrlites and clinopyroxenites, show high Mg#, extremely depleted REE patterns, no marked HFSE anomalies and high LILE enrichment. Cpx and leached whole rocks from this unit yield restricted εNd values (+ 5.5 to + 6.8), a large εSr range (− 5.9 to + 8.8) and mainly radiogenic 207Pb/204Pb ratios. The overlying mafic section, i.e. gabbroic rocks, displays low Mg# (46 < Mg# < 54), enriched REE patterns and marked HFSE anomalies. These plutonic rocks have also very homogeneous Sr and Pb isotopic compositions defining a restricted domain, which does not overlap that of the ultramafic samples. Moreover, Cpx from the basal ultramafics yield an Sm–Nd isochron at 117 ± 7 Ma interpreted as dating crystallization of the ultramafic section. Together, these results indicate that the mafic rocks on one hand and the ultramafic rocks on the other hand, originate from separate sources with specific emplacement underneath the subduction zone. A lherzolite lens, collected from the top of the mafic section, plots on the early Cretaceous Sm–Nd isochron and therefore yields the same 143Nd/144Nd initial ratio. This suggests that the ultramafic part of the lower Kohistan arc complex sampled the initiation stages of the subduction with production of magmas with boninite-like features. At this stage, the mantle wedge has been already modified by percolation of the first slab-derived fluids. On such a scenario the lherzolite lens would correspond to the lithospheric mantle underneath the arc before its initiation. A multi-stage history is proposed for the evolution for the Kohistan arc through not, vert, similar 30 Ma. Stage #1 reflects the spontaneous initiation of subduction associated with extensive boninitic affinity magmatism, stages #2 and #3 are related to arc building by tholeiitic melts and, a fourth step (stage #4) corresponds to the intra-crustal differentiation.
ISSN: 0012-821X

hal-00407206
https://hal.archives-ouvertes.fr/hal-00407206
DOI : 10.1016/j.epsl.2007.06.026

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Despite decades of petrological and geochemical studies, the nature and setting of obducted ophiolites remain controversial: the influence of supra-subduction zone environments on pre-existing oceanic lithosphere is yet to assess, and the processes leading to subduction/obduction initiation are still poorly constrained. Our study documents successive influx of slab-derived fluids and progressive strain localization within the upper mantle in a supra-subduction environment during the first few My of the subduction history. We focus on strongly sheared mafic amphibolites intruding peridotites near the mantle–crust transition of the New Caledonia obducted ophiolite and ~ 50 to 100 m above the basal thrust contact of the ophiolite. These m- to hm-long and several m-thick shear bands are interpreted as inherited small-scale intrusions of mafic melts, probably dikes or sills, which were derived from a moderately refractory mantle source refertilized by supra-subduction zone fluids. 40Ar/39Ar age constraints on pargasite at ca. 90 Ma suggest that they could be inherited from the former Pacific west-dipping subduction.Secondary deformation of these mafic intrusions is intimately associated to three major stages of fluid infiltration: (1) the first stage of deformation and metasomatism is marked by syn-kinematic growth of Ca-amphibole (at 700–800 °C and 3–5 kbar) with a distinctive supra-subduction zone signature, and controlled later channelization of aqueous fluids. 40Ar/39Ar dating on magnesio-hornblende indicates that this deformation episode occurred at ca. 55 Ma, coincident with east-dipping subduction initiation; (2) the main metasomatic stage, characterized by the development of a phlogopite-rich matrix wrapping peridotites and amphibolite boudins, points to the percolation of alkali-rich aqueous fluids at still high temperature (650–750 °C); (3) the last, low temperature (< 600 °C) metasomatic stage results in the formation of deformed veinlets containing talc, chlorite and serpentine.
ISSN: 0024-4937

hal-01306664
https://hal.archives-ouvertes.fr/hal-01306664
https://hal.archives-ouvertes.fr/hal-01306664/document
https://hal.archives-ouvertes.fr/hal-01306664/file/Soret_2016_Strain_localization.pdf
DOI : 10.1016/j.lithos.2015.11.022

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Several recent studies have documented that reactions between melt and crystal mush in primitive gabbroic rocks (via reactive porous flow) have an important control in the formation of the lower oceanic crust and the evolution of MORBs. In this context, olivine-rich rocks can form either by fractional crystallization of primitive melts or by open system reactive percolation of pre-existing (possibly mantle-derived) olivine matrix. To address this question, we performed in-situ trace element analyses (by LA-ICP-MS) of olivine from the Erro-Tobbio ophiolite Unit (Ligurian Alps), where mantle peridotites show gradational contacts with an hectometer-scale body of troctolites and plagioclase wehrlites, and both are cut by later decameter-wide lenses and dykes of olivine gabbros. Previous studies inferred that troctolites and olivine gabbros represent variably differentiated crystallization products from primitive MORB-type melts. Olivines in the three rock types (mantle peridotites, troctolites, olivine gabbros) exhibit distinct geochemical signature and well-defined elemental correlations. As expected, compatible elements (e.g. Ni) show the highest concentrations in peridotites (2580–2730 ppm), intermediate in troctolites (2050–2230 ppm) and lowest in gabbros (1355–1420 ppm), whereas moderate incompatible elements (e.g. Mn, Zn) show the opposite behaviour. By contrast, highly incompatible elements like Zr, Hf, Ti, HREE are variably enriched in olivines of troctolites, and the enrichment in absolute concentrations is coupled to development of significant HFSE/REE fractionation (ZrN/NdN up to 80). AFC modelling shows that such large ZrN/NdN ratios in olivines are consistent with a process of olivine assimilation and plagioclase crystallization at decreasing melt mass, in agreement with textural observations. In-situ trace element geochemistry of olivine, combined with microstructural investigations, thus appears a powerful tool to investigate reactive percolation and the origin of olivine-rich rocks in the lower oceanic crust.
ISSN: 0016-7037

hal-01419938
https://hal.archives-ouvertes.fr/hal-01419938
DOI : 10.1016/j.gca.2016.06.029

Éditeur(s) : HAL CCSD Wiley-Blackwell
Résumé : International audience
Platinum-group element (PGE) abundances in mantle rocks are generally considered to result from a late meteorite addition to the early Earth, post-dating the core separation event. As such, PGEs are key tracers for the Earth accretion history. For decades, the PGEs systematics of undepleted mantle peridotites has been used to constrain the composition of meteorite impactors involved in the late veneer material. Despite multiple evidence of considerable modifications by partial melting, harzburgites from the Sumail ophiolite (Oman) display a mean PGE composition very akin to recently refined estimates for the Primitive Upper Mantle (PUM) of the Earth. These rocks document a resetting of the PUM signature by percolating basaltic melts, which precipitated Pd-enriched Cu-Ni sulphides within a strongly Pd-depleted residual harzburgitic protolith. Such a resetting casts doubt on both the reliability of any PUM estimates and relevance of the PUM concept itself, at least for PGEs.
ISSN: 0954-4879

hal-00413122
https://hal.archives-ouvertes.fr/hal-00413122
DOI : 10.1111/j.1365-3121.2008.00850.x

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The N-S Languedoc volcanic province between the French Massif Central and the Mediterranean Sea is characterized by sporadic scattered low volume (similar to 2 km(3)) and geochemically homogeneous alkali basaltic activity spanning from 161 to 05 Ma The existence of magmatic activity of such a long duration within such a small area (similar to 140 km long and similar to 60 km wide) in spite of the extensive shift to the East of the European plate (about 2500 km during the last 160 Ma) is problematic Trace-element abundances in lavas suggest low degrees of melting (1-5%) in the spinet-garnet transition zone of an enriched Iherzolitic source The lavas display rather large ranges in Sr isotopic ratios (0 70307-0 70436) The Nd-143/Nd-144 ratio variations are smaller (0 51268-0 51300) and these of Pb-206/Pb-204 Pb-208/Pb-204 and Pb-207/Pb-204 are 18 745-19 515 38 53239 228 and 15 567-15 680 respectively The Languedoc lithospheric mantle as sampled by xenoliths is globally similar to the Pyrenees lithosphere The xenoliths show also rather large Sr Nd and Pb isotopic variations (Sr-87/Sr-86 0 70287-0 70578 Nd-143/Nd-144 0 51256-0 51414 Pb-208/Pb-204 37772-39 041 Pb-206/Pb-204 17 901-19 353) except for Pb-207/Pb-204 (15 570-15 620) The Pb-206/Pb-204 and La/Sm ratios are positively correlated both in xenoliths and lavas The increase of the Pb-206/Pb-204 (which could be interpreted as participation of the European Asthenospheric Reservoir EAR) is probably related to volatile-rich (carbonated?) fluid percolation This is corroborated by LILE and HFSE patterns observed in several xenoliths Therefore our data on lavas and xenoliths suggest a lithospheric origin for this long lived magmatism We propose (1) that the role of the asthenosphere in the Languedoc volcanism was restricted to volatile-rich fluid supplying and (2) that the fluid injection within the lithosphere may be related to the arrival of the Central Atlantic Plume head beneath Western Europe about 70 Ma ago In this model the isotopic signature of the oldest lavas (>70 Ma) would be that of the mantle lithosphere inherited from Hercynian processes The signatures of the subsequent lavas would be driven by the metasomatic component stored within the lithosphere and preferentially mobilized during incipient melting This metasomatised lower lithosphere was close to its solidus and small changes in P (or T) triggered incipient melting leading to basaltic volcanism Successive local re adjustments of the lithospheric blocks which accompanied the Meso-Cenozoic evolution of the Thetys Ligurian margin towards the present Mediterranean margin are the probable cause of these changes and so the sporadic volcanic activity in Languedoc is unrelated to deep asthenospheric processes
ISSN: 0024-4937

hal-00558884
https://hal.archives-ouvertes.fr/hal-00558884
DOI : 10.1016/j.lithos.2010.04.009

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
North Tanzanian Divergence is the first stage of continental break-up of East African Rift (<6 Ma) and is one of the most concentrated areas of carbonatite magmatism on Earth, with singular Oldoinyo Lengai and Kerimasi volcanoes. Hanang volcano is the southernmost volcano in the North Tanzanian Divergence and the earliest stage of rift initiation. Hanang volcano erupted silica-undersaturated alkaline lavas with zoned clinopyroxene, nepheline, andradite-schorlomite, titanite, apatite, and pyrrhotite. Lavas are low MgO-nephelinite with low Mg# and high silica content (Mg# = 22.4–35.2, SiO2 = 44.2–46.7 wt%, respectively), high incompatible element concentrations (e.g. REE, Ba, Sr) and display Nb–Ta fractionation (Nb/Ta = 36–61). Major elements of whole rock are consistent with magmatic differentiation by fractional crystallization from a parental melt with melilititic composition. Although fractional crystallization occurred at 9–12 km and can be considered as an important process leading to nephelinite magma, the complex zonation of cpx (e.g. abrupt change of Mg#, Nb/Ta, and H2O) and trace element patterns of nephelinites recorded magmatic differentiation involving open system with carbonate–silicate immiscibility and primary melilititic melt replenishment. The low water content of clinopyroxene (3–25 ppm wt. H2O) indicates that at least 0.3 wt% H2O was present at depth during carbonate-rich nephelinite crystallization at 340–640 MPa and 1050–1100 °C. Mg-poor nephelinites from Hanang represent an early stage of the evolution path towards carbonatitic magmatism as observed in Oldoinyo Lengai. Paragenesis and geochemistry of Hanang nephelinites require the presence of CO2-rich melilititic liquid in the southern part of North Tanzanian Divergence and carbonate-rich melt percolations after deep partial melting of CO2-rich oxidized mantle source.
ISSN: 0010-7999

hal-01467390
https://hal.archives-ouvertes.fr/hal-01467390
DOI : 10.1007/s00410-016-1273-5

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The lithospheric mantle is intrinsically heterogeneous and anisotropic. These two properties govern the repartition of deformation, controlling intraplate strain localization and development of new plate boundaries. Geophysical and geological observations provide clues on the types, ranges, and characteristic length scales of heterogeneity and anisotropy in the lithospheric mantle. Seismic tomography points to variations in geothermal gradient and hence in rheological behavior at scales of hundreds of km. Seismic anisotropy data substantiate anisotropic physical properties consistent at scales of tens to hundreds of km. Receiver functions imply lateral and vertical heterogeneity at scales < 10 km, which might record gradients in composition or anisotropy. Observations on naturally deformed peridotites establish that compositional heterogeneity and Crystal Preferred Orientations (CPOs) are ubiquitous from the mm to the km scales. These data allow discussing the processes that produce/destroy heterogeneity and anisotropy and constraining the time scales over which they are active. This analysis highlights: (i) the role of deformation and reactive percolation of melts and fluids in producing compositional and structural heterogeneity and the feedbacks between these processes, (ii) the weak mechanical effect of mineralogical variations, and (iii) the low volumes of fine-grained microstructures and difficulty to preserve them. In contrast, olivine CPO and the resulting anisotropy of mechanical and thermal properties are only modified by deformation. Based on this analysis, we propose that strain localization at the plate scale is, at first order, controlled by large-scale variations in thermal structure and in CPO-induced anisotropy. In cold parts of the lithospheric mantle , grain size reduction may contribute to strain localization, but the low volume of fine-grained domains limits this effect.
ISSN: 0040-1951

hal-01277174
https://hal.archives-ouvertes.fr/hal-01277174
DOI : 10.1016/j.tecto.2015.07.026