Éditeur(s) : HAL CCSD De Gruyter
Résumé : International audience
A comparative study of 9H-pyrido[3,4-b]indole (norharmane) and 1-methyl-9H-pyrido[3,4-b]indole (harmane) as inhibitors for C38 steel corrosion in 1 M HCl solution at 25 °C was carried out. Potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques were applied to study the metal corrosion behavior in the absence and presence of different concentrations of these inhibitors. The OCP as a function of time were also established. Cathodic and anodic polarization curves show that norharmane and harmane are a mixed-type inhibitors. Adsorption of indole derivatives on the C38 steel surface, in 1 M HCl solution, follows the Langmuir adsorption isotherm model. The ΔGads values were calculated and discussed. The potential of zero charge (PZC) of the C38 steel in inhibited solution was studied by the EIS method, and a mechanism for the adsorption process was proposed. Raman spectroscopy confirmed that indole molecules strongly adsorbed onto the steel surface. The electronic properties of indole derivates, obtained using the AM1 semi-empirical quantum chemical approach, were correlated with their experimental efficiencies using the linear resistance model (LR).
ISSN: 0018-3830

hal-01093227
https://hal-agroparistech.archives-ouvertes.fr/hal-01093227
DOI : 10.1515/HF.2010.034

Éditeur(s) : HAL CCSD
Résumé : International audience
In boundary lubrication regime, friction reduction and antiwear processes are associated to the presence of additives in the lubricating oils or greases. These processes are due to the formation of protective tribofilms resulting from chemical reactions between the additives and the sliding surfaces, in the physico-chemical conditions of the sliding contact. Conventional antiwear additives mainly consist of transition metal organo phosphate or thiophosphates which present a remarkable efficiency in the case of contacts between ferrous alloys. In the case of non reacting surfaces, these additives become inactive. Recently developped lubrication strategies consist in the use of dispersion in oils of nano additives able to build the protective tribofilm in the sliding contact without reaction with the surfaces. Carbon fluorinated phases, due to their lamellar structure and their high chemical stability even at relatively high temperature (400°C) represent interesting candidates as lubricant nano-additives subjected to present friction reduction, anti wear and anti corrosion actions. This work presents the tribologic behaviour of some carbon fluorinated derivatives such as graphite fluorides, fluorinated carbon nanofibers, fluorinated carbon nanodiscs and fluorinated carbon blacks. The influence, on the tribologic performances, of the structure of the initial carbon phases, of the fluorination rate (0
World Tribology Congress 2013
Torino, Italy

Droits : info:eu-repo/semantics/OpenAccess
hal-00926514
https://hal.archives-ouvertes.fr/hal-00926514
https://hal.archives-ouvertes.fr/hal-00926514/document
https://hal.archives-ouvertes.fr/hal-00926514/file/Delbe_9783.pdf
OATAO : 9783

Résumé : L'année 2004, année du vingtième anniversaire de sa création, aura été marquée, pour l'Ifremer, par une intense activité. 2004 a en effet été d'abord une année d'investissements et de résultats: de la biodiversité des massifs de coraux froids à la capacité des bactéries à produire des polymères biodégradables, de l'observation des effets de la crue centennale du Rhône sur les sédiments à la variabilité de l'hydrologie dans l'Atlantique Nord, de l'effet de la pluviométrie en hiver sur la mortalité estivale des huîtres à la sensibilisation environnementale des crevettes aux bactéries pathogènes, au lever par Lidar aéroporté de plus de 900 km² d'estrans de Bretagne, les résultats scientifiques ont été nombreux La technologie n'a pas été en reste avec les progrès de la protection contre la corrosion marine, les essais concluants de l'AUV, la mise à l'eau du Pourquoi pas?, ni les activités de surveillance du fait de l'augmentation des apparitions de toxines dans les coquillages. L'institut a en outre mené en 2004, avec ses ministères de tutelle, un important effort de réflexion sur ses missions et ses priorités, dont le contrat quadriennal 2005-2008, approuvéen conseil à' administration, finalisé en fin d'année et signé le 25 mai 2005 en présence de quatre ministres, trace désormais le cadre, en cohérence avec notre plan stratégique. [OCR NON CONTRÔLE]

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/2004/rapport-4830.PDF
http://archimer.ifremer.fr/doc/00000/4830/

Éditeur(s) : HAL CCSD
Résumé : The use of Xylopia frutescens extract as a C38 steel corrosion inhibitor in 1 M HCl solution was investigated by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) methods. Potentiodynamic polarization curves indicated that Xylopia frutescens extract behaves as mixed-type inhibitor. Graphical methods are illustrated by synthetic data to determine the parameter of CPE (α, Q). The adsorption of the extract constituents was further discussed in view of Langmuir adsorption isotherm. The effect of temperature on the inhibition efficiency was investigated using EIS and potentiodynamic polarization. SEM and EDX observations confirmed the existence of protective inhibitor film on metal surface.
ISSN: 1938-6737

hal-01304527
https://hal.archives-ouvertes.fr/hal-01304527
DOI : 10.1149/06426.0001ecst
PRODINRA : 351608