Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We present an integrated study of geochemistry, petrofabrics and seismic properties of strongly sheared eclogites from the Chinese Continental Scientific Drilling (CCSD) project in the Sulu ultrahigh-pressure (UHP) metamorphic terrane, eastern China. First, geochemical data characterize diverse protoliths of the studied eclogites. The positive Eu- and Sr-anomalies, negative Nb anomaly and flat portion of heavy rare earth elements in coarse-grained rutile eclogites (samples B270 and B295) suggest a cumulate origin in the continental crust, whereas the negative Nb anomaly and enrichment of light rare earth elements in retrograde eclogites (samples B504, B15 and B19) imply an origin of continental basalts or island arc basalts. Second, P-wave velocities (V-p) of three typical eclogite samples were measured under confining pressures up to 500 MPa and temperatures to 700 degrees C. At 500 MPa and room temperature, the mean V-p reaches 8.50-8.53 km/s in samples B270 and B295 but drops to 7.86 km/s in sample B504, and the P-wave anisotropy changes from 1.7-2.7% to 5.5%, respectively. The pressure and temperature derivatives of V-p are larger in the retrograde eclogite than in fresh ones. Third, the electron backscatter diffraction (EBSD) measurements of the eclogites reveal random crystal preferred orientation (CPO) of garnet and pronounced CPO of omphacite, which is characterized by a strong concentration of [001]-axes sub-parallel to the lineation and of (010)-poles perpendicular to the foliation. The asymmetric CPO of omphacite in sample B270 recorded a top-to-the-south shear event during subduction of the Yangtze plate. The calculated fastest V-p is generally sub-parallel to the lineation, but a different deformation environment during exhumation could form second-order variations in omphacite CPO and affect the V-p distribution in eclogites (e.g., the fastest V-p is at similar to 35 degrees from the foliation in sample 13295). Comparison between measured and calculated seismic properties indicates that the CPO of omphacite controls the seismic anisotropy of eclogites at high pressure, and compositional layering and retrograde minerals will increase the anisotropy. Calculated P-wave velocities agree well with velocities measured at 500 MPa and room temperature for fresh eclogites, but much higher than those of retrograde eclogite. As a case study, the laboratory-derived V-p-P and V-p-T relationships were used to estimate P-wave velocities of eclogites and peridotites beneath the Western Superior Province, Canada. The results indicate that besides the fabric-induced anisotropy, the direction dependence of pressure and temperature derivatives of V-p can significantly increase seismic anisotropy of eclogites with depth, which results in eclogites being an important candidate for the seismic anisotropy in the upper mantle. Due to their very high density and velocity, garnet-rich eclogites within peridotite could be detected in seismic reflections in subduction zones.
ISSN: 0040-1951

hal-00463512
https://hal.archives-ouvertes.fr/hal-00463512
DOI : 10.1016/j.tecto.2008.09.027

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The late Carboniferous accretionary system of the South Tianshan orogen (North-Western China) underwent complex structural and polymetamorphic evolution. Combined petrological, geochronological and microstructural analysis of (ultra)high-pressure (UHP) metabasites (eclogites and blueschists) enclosed in metapelites show a relict coarse-grained eclogitic fabric S2 surrounded by a dominant fine-grained eclogite and blueschist facies retrograde fabric S2. The S2 fabric is reworked by upright folds F3 that are responsible for a major shortening of the whole accretionary system. For both the eclogite and blueschist, peak and retrograde P–T conditions have been thermodynamically constrained at 25–26 kbar and 425–500 °C and 10–13 kbar and 500−550 °C respectively, suggesting a shared exhumation history. The garnet-whole rock-amphibole isochron in the blueschist yielded Lu–Hf and Sm–Nd ages of 326.0 ± 2.9 Ma and 318.4 ± 3.9 Ma respectively, interpreted to date the prograde to peak metamorphic assemblage. The retrograde path of the eclogite is characterized by heterogeneous omphacite recrystallization into a mylonitic fine-grained matrix and crystallization of blue amphibole. Microstructures in both pristine porphyroclastic and recrystallized fine-grained domains in the eclogite indicate a gradual evolution from constriction-dominated (L>S-type) to flattening-dominated (S>L-type) type of deformation, increase of fabric intensity reflected by gradually growing M-indexes and the development of lattice preferred orientation (LPO) typical for dislocation creep under slightly hydrated conditions. Recrystallization of the matrix in the blueschist is homogeneous, which indicates a matrix dominated channel flow during exhumation. These LPOs evolutions suggest a significant mechanical coupling with the upper plate concomitant with oroclinal bending of the Kazakh orocline. Lock up of Kazakh orocline is responsible for further stress increase resulting in horizontal shortening of South Tianshan accretionary wedge and development of D3 upright folding and steepening of the whole sequence.
ISSN: 1342-937X

hal-01481263
https://hal.archives-ouvertes.fr/hal-01481263
DOI : 10.1016/j.gr.2016.07.007

Éditeur(s) : HAL CCSD Elsevier
Résumé : The Borborema Province, in the NE of Brazil, is a rather complex piece in the Brazil-Africa puzzle as it represents the junction of the Dahomeyide/Pharusian, Central African, Aracuai and Brasilia fold belts located between the West-African/Sao Luis, Congo/Sao Francisco and Amazonas craton. The correlation between the Dahomeyides from W-Africa (Ghana, Benin, Togo, and Mali) and the Borborema Province involves the Medio Coreau and Central Ceara domains. The inferred continuation of the main oceanic suture zone exposed in the Dahomeyides of W Africa is buried beneath the Phanerozoic Parnaiba Basin in Brazil (northwest of the Medio Coreau domain) where some high density gravity anomalies may represent hidden remnants of an oceanic suture. In addition to this major suture a narrow, nearly continuous strip composed of mainly mafic pods containing relics of eclogite-facies assemblages associated with partially migmatized granulite-facies metapelitic gneisses has been found further east in the NW Borborema Province. These high pressure mafic rocks, interpreted as retrograded eclogites, are located between the Transbrasiliano Lineament and the Santa Quiteria continental arc and comprise primitive to evolved arc-related rocks with either arc- or MORB-type imprints that can indicate either deep subduction of oceanic lithosphere or roots of continental and oceanic magmatic arcs. Average peak P-T conditions under eclogite-facies metamorphism (T=770 degrees C and P = 17.3 kbar) were estimated using garnet-clinopyroxene thermometry and Jd content in clinopyroxene. Transition to granulite-facies conditions, as well as later widespread re-equilibration under amphibolite facies, were registered both in the basic and the metapelitic rocks and suggest a clockwise P-T path characterized by an increase in temperature followed by strong decompression. A phenomenon possibly related to the exhumation of a highly thickened crust associated with the suturing of the Medio Coreau and Central Ceara domains, two distinct crustal blocks separated by the Transbrasiliano Lineament.
ISSN: 1342-937X

hal-00413584
https://hal.archives-ouvertes.fr/hal-00413584
DOI : 10.1016/j.gr.2009.01.003

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
The southwestern Tianshan (China) metamorphic belt records high-pressure (HP) to ultrahigh-pressure (UHP) conditions corresponding to a cold oceanic subduction-zone setting. Serpentinites enclosing retrogressed eclogite and rodingite occur as lenses within metapelites in the UHP unit, which also hosts coesite-bearing eclogites. Based on the petrology and petrography of these serpentinites, five events are recognized: (1) formation of a wehrlite–harzburgite–dunite association in the mantle; (2) retrograde metamorphism and partial hydration during exhumation of the mantle rocks close to the seafloor; (3) oceanic metamorphism leading to the first serpentinization and rodingitization; (4) UHP metamorphism during subduction; (5) retrograde metamorphism during exhumation together with a second serpentinization. The peak metamorphic mineral assemblage of the serpentinized wehrlite comprises Ti-chondrodite + olivine + antigorite + chlorite + magnetite + brucite. A computed pseudosection for this serpentinized wehrlite shows that the Al content in antigorite is mostly sensititive to temperature but can also be used to constrain pressure. The average XAl = 0·204 ± 0·026 of antigorite (XAl = Al (a.p.f.u.)/8, where Al is in atoms per formula unit for a structural formula M48T34O85(OH)62, and M and T are octahedral and tetrahedral sites, respectively) included in Ti-chondrodite and average XAl = 0·203 ± 0·019 of antigorite in the matrix result in a well-constrained peak metamorphic temperature of 510–530°C. Peak pressures are less precisely constrained at 37 ± 7 kbar. The Tianshan serpentinites thus record UHP metamorphic conditions and represent the deepest subducted serpentinites discovered so far. The retrograde evolution occurs within the stability field of brucite + antigorite + olivine + chlorite and formation of Ti-clinohumite at the expense of Ti-chondrodite has been observed, suggesting isothermal decompression. The resulting P–T path is in excellent agreement with the metamorphic evolution of country rocks, indicating that the UHP unit in Tianshan was subducted and exhumed as a coherent block. To refine the metamorphic path of the ultramafic rocks, we have investigated the stability fields of Ti-chondrodite and Ti-clinohumite using piston-cylinder experiments. A total of 11 experiments were conducted at 25–55 kbar and 600–750°C in a F-free natural system. Combined with previous experiments and information from natural rocks we constructed a petrogenetic grid for the stability of Ti-chondrodite and Ti-clinohumite in F-free peridotite compositions. The formation of Ti-chondrodite in serpentinites requires a minimum pressure of about 26 kbar, whereas in Ti-rich systems it can form at considerably lower pressures. A key finding is that at UHP conditions, F-free Ti-chondrodite or Ti-clinohumite breaks down in the presence of orthopyroxene between 700 and 750°C, at temperatures that are significantly lower than those of the terminal breakdown reactions of these humite minerals. These breakdown reactions are an additional source of fluid during prograde subduction of serpentinites.
ISSN: 0022-3530

hal-01243507
https://hal.archives-ouvertes.fr/hal-01243507
DOI : 10.1093/petrology/egv042

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
Investigation of an eclogite xenolith, discovered in a Cretaceous granite from the Central Domain of the Dabieshan massif in eastern China, yields new petrological insights into the high to ultrahigh-pressure metamorphism, experienced by the Qinling-Dabie orogen. Prior to inclusion as a xenolith in the granite during the Early Cretaceous, this eclogite xenolith had recorded a complex metamorphic evolution that complies with subduction and exhumation processes experienced by the continental crust of the South China Block. Well-preserved mineral parageneses substantiate the prograde and retrograde stages revealed by inclusions in porphyroblastic garnet and zoned minerals such as garnet, comphacite and amphibole in the matrix. The relatively low P/T re-equilibration during a latemetamorphic stage was textually inferred by the presence of aluminous and calcic-subcalcic amphiboles such as katophorite, edenite, taramite and pargasite as main matrix phases. According to our U/Pb, Rb/Sr and new 40Ar/39Ar geochronological results, namely 109 ± 1 and 112 ± 2 Ma plateau ages for muscovite and amphiboles, respectively, two successive but distinct cooling stages account for the thermal history of the granite–migmatite gneiss dome that forms the Central Dabieshan Domain. We argue that prior to the Cretaceous doming, the Central Dabieshan Domain experienced a tectono-metamorphic evolution similar to that observed in the high-pressure to ultra high-pressure units developed in the Southern Dabieshan Domain and Hong'an massif.
ISSN: 1437-3254

hal-00104224
https://hal-insu.archives-ouvertes.fr/hal-00104224
https://hal-insu.archives-ouvertes.fr/hal-00104224/document
https://hal-insu.archives-ouvertes.fr/hal-00104224/file/Lin-IntJEarthSciences-2007.pdf
DOI : 10.1007/s00531-006-0129-z

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Tectonic mixing of slab- and mantle-derived materials at the interface between converging plates highly enhances fluid-mediated mass transfer from the slab to the overlying mantle. Subduction mélanges can provide information about the interaction among different slices accreted at plate interface domains, with implications on the tectonic and geochemical evolution of the plate-interface itself. At Cima di Gagnone, pelitic schists and gneiss enclose chlorite harzburgite and garnet peridotite lenses, like in subduction mélanges located in-between downgoing slabs and overlying mantle. These peridotites host MORB-type eclogite and metarodingite, and derive from dehydration of serpentinized mantle protoliths. Their enrichment in fluid-mobile B, As, Sb, U, Th is the result of an early-stage oceanic serpentinization, followed by interaction with host metasediments during subduction burial. Here we define the element exchange process in the Gagnone mélange by means of the B, Sr and Pb isotope analysis of its main lithologies (ultramafic, mafic rocks and paragneiss). The 87Sr/86Sr and 206Pb/204Pb ratios of ultramafic rocks (0.7090–0.7124 and 18.292–18.837, respectively) show enrichments in radiogenic Sr and Pb after exchange with the host paraschist (up to 0.7287 87Sr/86Sr; 18.751 206Pb/204Pb). The δ11B values of peridotites (down to −10‰) point to a combined effect of (1) 11B release to deserpentinization fluids (serpentinized protoliths likely had positive δ11B and lower radiogenic Sr, Pb), and of (2) exchange with fluids from the surrounding metasediments. The whole Gagnone rock-suite is finally overprinted by retrograde fluids that essentially bring to an increase in radiogenic Pb (about 19.0 206Pb/204Pb) and to values of 0.710 87Sr/86Sr and of −10‰ δ11B. The recognition of different stages of interaction between mantle rocks and sedimentary/crustal reservoirs allows us to define the geochemical effects related to the early coupling of such rocks along the plate-interface. Our study shows that ultramafic rocks involved in subduction-zone metamorphism and serpentinization uptake radiogenic Pb and Sr released by associated sedimentary reservoirs. The exchange process envisioned here is not only representative of subduction mélanges: it can also be a proxy of mass transfer between slab and serpentinized supra-subduction mantle, as occurs in forearcs. Dehydration of the Gagnone-type serpentinized mantle releases crust-derived components to arcs, without direct involvement of metasediment dehydration and/or melting in subarc environments. The retention of appreciable amounts of fluid-mobile elements, radiogenic Pb and Sr in dehydrated Gagnone peridotites has implications on element recycling in the deep Earth’s mantle.
ISSN: 0016-7037

hal-01174137
https://hal.archives-ouvertes.fr/hal-01174137
DOI : 10.1016/j.gca.2015.04.024

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Hengshan–Wutaishan area forms part of the Trans-North-China Belt developed in response to the final amalgamation of the North China Craton. The Hengshan–Wutaishan domain and the adjacent Fuping massif constitute the largest and the most representative rock exposure of the belt. A structural study allows us to redefine the lithological and tectonic units that compose the architecture of the Hengshan–Wutaishan domain and to propose that the Trans-North-China Belt was built up through a polyphase tectonic evolution within the period 1900–1800 Ma. The first event (D1) corresponds to the emplacement of lower and upper nappes herein called the Orthogneiss and Volcanites Unit (OVU) and the Low Grade Mafic Unit (LGMU), respectively. The OVU mainly consists of rocks formed in an arc system and metamorphosed under amphibolite facies conditions whereas the LGMU represents oceanic crust rocks with an arc component that underwent greenschist facies metamorphism. The syn-metamorphic D1 deformation is characterized by a NW–SE stretching and mineral lineation with a top-to-the SE sense of shear that corresponds to the sense of nappe motion. U–Th–Pb EPM chemical dating on monazite from three metapelites of the OVU gives isochron ages of 1884 ± 11 Ma, 1886 ± 5 Ma and 1887 ± 4 Ma interpreted as the age of the prograde amphibolite facies metamorphism coeval with nappe stacking during the D1 event. The D2 event corresponds to a widespread crustal melting of the OVU and underlying basement rocks in Hengshan related to the exhumation of deep structures about 20–30 Ma after nappe emplacement. The migmatite contains blocks of retrograded eclogite or HP-granulitic restites, and is characterized by the development of a pervasive foliation and lineation. A late D2 event represents the folding stage of the migmatitic foliation during the completion of a dome. The Orthogneiss and Volcanics Unit and the Low Grade Mafic Unit are unconformably covered by weakly metamorphosed to unmetamorphosed sediments belonging to the Hutuo Supergroup. These rocks were deformed by a ductile D3 event, characterized by a NW–SE trending stretching lineation, south verging folds associated with an axial planar slaty cleavage and an E–W crenulation lineation. Lastly, a left-lateral wrenching along the Zhujiafang Shear Zone separates the northern and southern parts of Hengshan. Our structural study shows that there is no significant difference between the southern part of Hengshan and the lower part of Wutaishan, both areas belong to OVU and show a structural continuity. We suggest that this polyphase deformation developed in response to a north-westward subduction of an old ocean, named the Lüliang Ocean, beneath the Western Block, followed by collision with a micro-continent named the Fuping Block at not, vert, similar1890–1880 Ma.
ISSN: 0301-9268

insu-00151594
https://hal-insu.archives-ouvertes.fr/insu-00151594
https://hal-insu.archives-ouvertes.fr/insu-00151594/document
https://hal-insu.archives-ouvertes.fr/insu-00151594/file/Trap-PrecambrainResearch-2007.pdf
DOI : 10.1016/j.precamres.2007.03.001

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Serpentinites are one of the major components of the oceanic lithosphere and are stable in the slab and the mantle wedge up to 100-150 km depth in subduction zones. During oceanic mantle hydration and alteration, they trap trace and fluid mobile (FME: B, Li, As, Sb, Rb, Ba, Cs, Sr, U and Pb) elements that participate to elemental transfer occurring between the dehydrating slab and the mantle wedge in subduction context. The Lanzo massif is an eclogitized oceanic lithosphere that preserved its oceanic structure and recorded different steps of serpentinization/de-serpentinization from oceanic lizardite to prograde antigorite in subduction context, up to its dehydration and secondary olivine crystallization, and finally retrograde antigorite during massif exhumation. It constitutes a suitable place to study trace element behavior during serpentinization/de-serpentinization processes and associated chemical transfers between the different envelopes of the oceanic lithosphere and the mantle wedge. Geochemical analyses of serpentine and associated minerals show that the serpentinization/de-serpentinization of the Lanzo massif took place in a relatively closed system without significant trace element transfer between the different parts of the oceanic lithosphere. In the deeper part of the lithosphere, from the slightly serpentinized mantle peridotites (SSP, < 20% serpentinization) to the paleo-Moho, composed of massive serpentinites (MS, 80% serpentinization), the trace elements mobility is reduced. The chemical composition of lizardite and antigorite is homogenized with the local degree of serpentinization: in SSP, serpentine veins composition is inherited from the host mineral while, in MS, their composition is homogenous between destabilized phases at the scale of the outcrop (~ 5 m). In the shallowest part of the oceanic lithosphere, from the paleo-Moho to the oceanic paleo-seafloor, the serpentinites are foliated (FS, > 90% serpentinization). In that zone, the alpine deformation enhances the mobility of trace elements and permits their redistribution and the homogenization of antigorite composition at massif scale. Locally, in the SSP and MS, the crystallization of metamorphic veins of ~ 1-2 m corresponds to channelized fluid flows that allowed fluid transfers - and thereby trace elements - to longer distance. The successive crystallizations of antigorite and then olivine are accompanied by a diminution of some FME (B, Li, As, Sb, Ba, Rb) and Eu contents attesting that these elements are removed from slab to mantle wedge during subduction.
ISSN: 0009-2541

hal-00937661
https://hal.archives-ouvertes.fr/hal-00937661
DOI : 10.1016/j.chemgeo.2013.08.025