Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
A detailed rock-magnetic and archeointensity study was carried out on materials baked by a western Mexican artisan following traditional techniques to produce faithful reproductions of archeological pieces of the Michoacan region (Western Mesoamerica). The field strength at the site (41.0 +/- 0.51 mu T) was measured with a fluxgate magnetometer and the temperature of the furnace during the baking process was monitored continually by means of a thermocouple placed in the middle of the baking cavity.;Rock-magnetic experiments performed on the raw material (clay and paste) and on in situ prepared baked ceramics and bricks included measurement of thermomagnetic curves (susceptibility and strong-field magnetization versus temperature), first-order reversal curves (FORC), anisotropy of magnetic susceptibility (AMS) and anisotropy of thermoremanent magnetization (A-TRM). Magnetite and probably hematite are present in the samples as carriers of the remanence. Hysteresis ratios suggest that the samples fall in the pseudo-single-domain grain size region, which may indicate a mixture of multidomain and a significant amount of single-domain grains.;Ceramic pieces and brick fragments were subjected to the Thellier-Coe archeointensity method and to an alternative paleointensity experiment, with a TRIAXE magnetometer, in order to check whether they are faithful recorders of the local geomagnetic field strength.;Mean raw-intensity of sample M1 (pottery) overestimates a 7% the expected site intensity, while those corresponding to the brick samples (LQ1 and LQ2) underestimate it 15%. Brick sample LNQ shows a slightly lower intensity (7%), but agrees with the expected site intensity within the experimental uncertainty. The intensity retrieved from the volcanic fragment also included closely reproduces the expected intensity. After A-TRM and cooling-rate corrections, all mean raw values move closer to the expected intensity.;Measurement of temperatures at different parts inside the kiln (bottom and upper parts of both central and peripheral parts) revealed the existence of significant thermal gradients, similar to those observed in ovens from other localities. Different cooling rates are then expected in a single oven.;The scatter in the intensity determinations observed in this study, retrieved from pieces elaborated together in the same oven, could arise from this differentiated cooling rate within the oven and thus, to an inappropriate cooling rate correction in the archeointensity protocol. As this situation was probably reproduced in the baking of ancient ceramic artifacts, a better knowledge of the temperature distribution inside these types of kiln would be desirable in order to choose the appropriate cooling rate correction.
ISSN: 0031-9201

hal-00644559
https://hal.archives-ouvertes.fr/hal-00644559
DOI : 10.1016/j.pepi.2011.06.007

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Synkinematic phyllosilicates in fault zones can be used to deduce the deformation mechanisms and the conditions of fault activity, as their chemical composition, crystal structure and texture can record the different stages of deformation and fluid-rock interactions. The Pic de Port Vieux, a second-order thrust related to the major Gavarnie thrust in the southern central part of the Pyrenees Axial Zone, juxtaposes Triassic pelites of the hanging wall and Cretaceous limestones of the footwall. In order to investigate the mineralogical and geochemical changes and constrain the deformation conditions of thrusting, characterization of phyllosilicates was performed along a transect in the fault hanging wall pelites. The Triassic pelites are mainly composed of quartz, calcite, phyllosilicates (chlorite and K-white mica) and ± hematite. The core fault zone thickness is estimated to be about one meter of intensively foliated green pelites, whereas the damage zone is composed of several meters of red pelites. XRD data demonstrated that the difference in color is related to hematite which is only present in the damage zone. Phyllosilicates of the damage zone are mainly inherited/diagenetic K-white mica and chlorite. In the core zone, newly formed chlorite is abundant and preferentially located in veins. It is enriched in Fe compared to the chlorite of the red pelites. The well-defined foliation in the core zone is overlaid by preferentially oriented muscovite grains which have homogeneous compositions, with less Na and relatively more Fe than mica from the red pelites. Newly formed chlorite and muscovite in the core zone are synkinematic to the fault activity. They are both related to deformation processes and fluid rock interactions. Kübler index measurements and chlorite thermometry show that synkinematic phyllosilicates have registered a temperature of 270°C ± 23°C for the damage zone and 285°C ± 28°C for the core zone which are corresponding to lower-anchizone/epizone grade conditions. Numerical modelling with the geochemical modelling program PhreeqC was performed to determine the favorable conditions for the mineralogical change between red and green pelites. It suggests that the main critical parameter favoring hematite dissolution and chlorite precipitation in the core zone, is the redox conditions. According to the model, the chemical changes in the core zone occurred due to interactions with highly reductive fluids. In addition, the hematite dissolution maybe the source of iron for newly formed phyllosilicates in the core zone that are more iron rich compared to those from the red pelites.
ISSN: 0169-1317

hal-01536006
https://hal.archives-ouvertes.fr/hal-01536006
DOI : 10.1016/j.clay.2017.05.008

Éditeur(s) : HAL CCSD Springer Verlag (Germany) Springer Verlag
Résumé : International audience
The Cerro del Almirez massif (Spain) represents a unique fragment of serpentinized oceanic lithosphere that has been first equilibrated in the antigorite stability field (Atg-serpentinites) and then dehydrated into chlorite–olivine–orthopyroxene (Chl-harzburgites) at eclogite facies conditions during subduction. The massif preserves a dehydration front between Atg-serpentinites and Chl-harzburgites. It constitutes a suitable place to study redox changes in serpentinites and the nature of the released fluids during their dehydration. Relative to abyssal serpentinites, Atg-serpentinites display a low Fe3+/FeTotal(BR) (=0.55) and magnetite modal content (=2.8–4.3 wt%). Micro-X-ray absorption near-edge structure (μ-XANES) spectroscopy measurements of serpentines at the Fe–K edge show that antigorite has a lower Fe3+/FeTotal ratio (=0.48) than oceanic lizardite/chrysotile assemblages. The onset of Atg-serpentinites dehydration is marked by the crystallization of a Fe3+-rich antigorite (Fe3+/FeTotal = 0.6–0.75) in equilibrium with secondary olivine and by a decrease in magnetite amount (=1.6–2.2 wt%). This suggests a preferential partitioning of Fe3+ into serpentine rather than into olivine. The Atg-breakdown is marked by a decrease in Fe3+/FeTotal(BR) (=0.34–0.41), the crystallization of Fe2+-rich phases and the quasi-disappearance of magnetite (=0.6–1.4 wt.%). The observation of Fe3+-rich hematite and ilmenite intergrowths suggests that the O2 released by the crystallization of Fe2+-rich phases could promote hematite crystallization and a subsequent increase in fo2 inside the portion of the subducted mantle. Serpentinite dehydration could thus produce highly oxidized fluids in subduction zones and contribute to the oxidization of the sub-arc mantle wedge.
ISSN: 0010-7999

hal-01172310
https://hal.archives-ouvertes.fr/hal-01172310
DOI : 10.1007/s00410-015-1130-y

Éditeur(s) : HAL CCSD Centre National de la Recherche Scientifique
Résumé : Une étude stratigraphique, sédimentologique et magnétique a été réalisée sur la partie supérieure d'une terrasse alluviale de l'oued Adaila, dansla plaine d'El Ma Labiod (nord-est de l'Algérie). Cette terrasse renferme un niveau très riche en matériel archéologique appartenant à la civilisation atérienne, dont l'âge dépasse 35 000 ans. Du point de vue sédimentologique, les sédiments sont dominés par la fraction limoneuse suivie par les sables fins et grossiers. Du point de vue stratigraphique, la succession de dépôts à éléments grossiers recouverts par des éléments fins correspond à des niveaux fluviatiles avec des mises en place à débit contrasté. Les courbes cumulatives ont un faciès dit " parabolique " et témoignent d'un sédiment immature et peu évolué. Les résultats de l'étude magnétique concordent avec les précédents. Ils révèlent une forte concentration en grains magnétiques dans la partie médiane de la coupe (foyer) et une faible concentration à la base (Unité L) contemporaine d'un climat sec. Les grains magnétiques, de taille variable (polydomaine, monodomaine et superparamagnétique), sont portés par la magnétite et la maghémite de faible champ coercitif, ainsi que par la goethite et l'hématite de fort champ coercitif. Les courbes de la susceptibilité magnétique en fonction de la température et les courbes de la décomposition de l'ARI (spectres de coercivité) confirment ces résultats.
ISSN: 1142-2904

hal-00750185
https://hal.archives-ouvertes.fr/hal-00750185

Éditeur(s) : HAL CCSD
Résumé : La grotte d'Angel, datée du Pléistocène moyen et de la base du Pléistocène supérieur, a livré un important matériel lithique et faunistique, et présente un intérêt exceptionnel dans la Péninsule Ibérique. Vu son importance, et dans le cadre d'un programme de recherche européen (N°IDPH/ER/05), une étude pluridisciplinaire a été réalisée sur le remplissage sédimentologique et les vestiges archéologiques. Nous présentons dans cet article les résultats de l'étude des propriétés magnétiques du remplissage de la grot- te. Cette approche a révélé la présence de deux unités magnétostratigraphiques. L'unité stratigraphique inférieure se caractérise par une forte concentration en grains magnétiques, parmi lesquels un fort pour- centage en grains superparamagnétiques (SP). Les minéraux magnétiques sont d'origine secondaire, de petite taille, de nature douce et dominés par la magnétite et la maghémite. Ces derniers ont subi une évo- lution géochimique post-dépositionnelle importante (forte pédogenèse). Au contraire, dans l'unité supé- rieure, les valeurs des différents paramètres magnétiques sont faibles et les minéraux magnétiques sont d'origine détritique et se caractérisent par une force coercitive élevée, conforme à la présence d'hématite. The Angel cave, dated between the middle to the base of the Upper Pleistocene, contains important lithic and faunal material, and is of exceptional interest in the Iberian Peninsula. Because of its importance, and in the framework of an European research project (N°IDPH/ER/05), a multidisciplinary study including palaeomagnetism, was undertaken on the sedimentary deposit and the archaeological material. The study of the magnetic properties of the cave sediments reveals the presence of two magnetostratigraphic units. The lower stratigraphic unit is characterized by an important concentration of magnetic grains with a con- siderable percentage of superparamagnetic grains (SP). The magnetic minerals are of secondary origin, fine grained, magnetically soft and dominated by magnetite and maghemite. The latter have undergone an important post-depositional geochemical evolution (marked pedogenesis). On the contrary, the upper unit is characterized by weaker magnetic parameters and the magnetic minerals are harder, of detrital origin, dominated by hematite
ESTUDIOS GEOLOGICOS-MADRID

hal-00903622
https://hal.archives-ouvertes.fr/hal-00903622
DOI : 10.3989/egeol.40946.222

Résumé : Les pathologies inflammatoires démyélinisantes primitives du système nerveux central (SNC) sont dominées par deux entités : la sclérose en plaques (SEP) et la neuromyélite optique (NMO). Ces deux pathologies se différencient par : 1. leur phénotype, la NMO se caractérisant par une myélite extensive dans le plan transversal et longitudinal et peu de lésions encéphaliques initiales ; 2. leur sévérité, le pronostic de la NMO étant moins bon que celui de la SEP ; 3. leur mécanisme immunologique, puisque l’immunité humorale domine nettement dans la NMO, cette pathologie répondant peu ou pas aux traitementshabituellement prescrits dans la SEP. Un anticorps sérique (IgG-NMO) a été retrouvé chez les patients atteints de NMO avec une sensibilité de 50-70% et une spécificité de 90-100%. Cet anticorps a pour cible le principal canal hydrique du SNC, l’aquaporine-4 (AQP4), qui se situe principalement sur les pieds astrocytaires jalonnant la barrière hémato-encéphalique. La SEP est relativement familière des neurologues car décrite sur le plan épidémiologique et dans son histoire naturelle depuis plus d’un siècle à travers de larges séries réalisées parfois en population générale. Son approche thérapeutique progresse suite à des essais contrôlés qui s’accumulent depuis maintenant près de 20 ans. Toutefois, la majorité des travaux ont été effectués chez les populations Caucasiennes en raison de sa plus grande fréquence dans ces populations. A l’inverse, la NMO garde encore un relatif mystère à cause de sa relative rareté, l’établissement très récent de critères diagnostiques et une physiopathologie très récemment éclaircie par la découverte de l’IgG-NMO qui a indiscutablement suscité un regain d’intérêt de cette affection. Ainsi, son incidence est quasiment inconnue de même que sa susceptibilité génétique. La progression du handicap de la NMO qu’il soit visuel ou moteur à l’évidence sévère, ne repose toujours pas sur des chiffres précis, la description des lésions neuroradiologiques reste encore très embryonnaire. Enfin, même s’il existe un consensus pour traiter énergiquement les poussées de NMO et les espacer, il n’existe quasiment aucune étude prospective.
Introduction: Aim of the study is to describe épidemiology, phenotype and treatment of demyelinating inflammatory diseases of the central nervous system (CNS) namely multiple sclerosis (MS) and neuromyelitis optica (NMO) in French West Indies.Epidemiology: MS emerged in the French West Indian (FWI) population with an incidence of 1.27/100 000 (CI 95%: 1.16-1.38) for the period 1992-2007 while incidence of NMO remained stable at 0.19/100,000 (CI 95%: 0.15–0.23). Both migration in Metropolitean France (MF) and decrease of sun exposure were risk factors for MS acquisition in FWI. Phenotype and treatment of NMO: NMO is a very rapidly disabling disease with median times to reach DSS 3, 6 and 8 of one year, 8 years and 22 years respectively. However, treatment by plasma exchanges were shown to reduce sequellae of NMO attacks ; mitoxantrone and rituximab reduced significantly annualized relapse rate (ARR) from 1.7 to 0.29 (p<10-4) and from 1,34 to 0,56 (p=0.0005) respectively, improving dramatically natural course of NMO.Phenotype and treatment of MS: Absence of Migration in MF in MS patients was found to be the strongest independent predictive factor of disability progression to DSS 6 (hazard ratio, 2.59; p=0.0002); beside short time to DSS3 (p=0.005), later age at onset (p=0.005), and multi-symptomatic onset (p=0.03). Treatment of MS by interferon beta-1 had a moderate impact in MS while natalizimab proved to be highly effective by reducing drastically ARR and inflammatory parameters on magnetic resonance imaging. Conclusion: Spectrum of demyelinating inflammatory disorders of CNS has reversed in French West Indies with overrepresentation of MS. Agressive therapy is needed to improve prognosis of NMO. Rapidly increasing of its incidence makes MS a new public health problem in French West Indies.

http://www.theses.fr/2012AGUY0511/document

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Three kilns and a collection of baked bricks from Italian archaeological sites have been studied for archaeointensity determination using the Thellier method as modified by Coe. All sites are dated based on archaeological information and their ages range from 500 to 800 AD and 1500 to 1700 AD. Rock magnetic studies identify magnetite, Ti- magnetite and hematite as the main magnetic minerals, and magnetic susceptibility versus temperature shows a good thermal stability of the samples. The intensity results have been corrected for anisotropy of the thermoremanent magnetization and cooling rate effects. The new data together with 136 previously published results are used to estimate the variation of the Earth's magnetic field over the past three millennia. The time distribution of the Italian absolute intensity data is irregular with the majority of determinations concentrated during the last four centuries, while older periods are very poorly covered. Most of the data come from volcanic rocks and show significant discrepancies. All data have been compared with archaeointensity results from Europe and regional and global models predictions. This work indicates the need to obtain more high quality archaeointensity results, in particular for the periods older than 200 BC and between 200 and 1000 AD, in order to determine a robust Italian intensity secular variation curve that, in combination with directional data, could be used for archaeomagnetic dating.
ISSN: 0956-540X

hal-00452451
https://hal.archives-ouvertes.fr/hal-00452451
DOI : 10.1111/j.1365-246X.2009.04455.x