Éditeur(s) : HAL CCSD Elsevier Masson
Résumé : International audience
When fish larvae recruit back to a reef, chemical cues are often used to find suitable habitat or to find juvenile or adult conspecifics. We tested if the chemical information used by larvae was intentionally produced by juvenile and adult conspecifics already on the reef (communication process) or whether the cues used result from normal biochemical processes with no active involvement by conspecifics (“spying” behavior by larvae). Conspecific chemical cues attracted the majority of larvae (four out of the seven species tested); although while some species were equally attracted to cues from adults and juveniles (Chromis viridis, Apogon novemfasciatus), two exhibited greater sensitivity to adult cues (Pomacentrus pavo, Dascyllus aruanus). Our results indicate also that spying cues are those most commonly used by settling fishes (C. viridis, P. pavo, A. novemfasciatus). Only one species (D. aruanus) preferred the odour of conspecifics that had had visual contact with larvae (communication).
ISSN: 1631-0691

hal-01212899
https://hal-univ-perp.archives-ouvertes.fr/hal-01212899
DOI : 10.1016/j.crvi.2015.05.004

Éditeur(s) : HAL CCSD Springer
Résumé : The analysis of three different regions of the South- Pyrenean fold-and-thrust belt reveals that during the Tertiary compression the hydrological system was compartmentalised in time and space. During the early-middle Eocene, when the thrust front affected marine soft-sediments in the Ainsa basin, the thrust fault zones were dominated by formation fluids derived from Eocene marine waters trapped in the underlying Eocene marls, although influences of meteoric waters were also present. During the middle-late Eocene, when the thrust front emplaced marine rocks over continental redbeds in the eastern Catalan basin (L'Escala thrust), the thrust fault zones were dominated by meteoric fluids. These fluids flowed preferentially along these faults, draining laterally the meteoric fluids and acting as barriers hindering their flowing towards more external parts of the belt. During the Oligocene, the most external part of the fold-and-thrust belt in the eastern Catalan basin developed on top of a salt detachment horizon. The thrust front affected continental materials of late Eocene-Oligocene age. At this moment, the thrusts were conduits for meteoric fluids arriving from the surface and also for evolved meteoric fluids migrating over short distance upwards after being in contact with the underlying evaporitic beds. Most of the fractures show a similar sequence of microfractures. Microfractures of stage 1 formed when the sediment was poorly lithified. Microfractures of stage 2 represent the main episode of vein formation which developed when a progressive induration of the host sediment occurred. During microfracture stage 3, formed in an extensional regime, the host sediment was more indurated. The repetition of this sequence of microfractures in different fracture generations of the same outcrop indicates that the sediment induration was restricted to the vicinity of the vein. Away from the veins, the sediment remained poorly lithified during the entire deformation cycle. Calcite cement within the host rock precipitated later than the syn-compressive veins, when the sediment was more indurated. Elemental geochemistry and stable isotopes of the calcite veins indicates that early generation of microfractures is infilled by local fluids (either marine or meteoric), whereas external fluids (meteoric or evolved meteoric) infilled the main compressive stage of microfractures. The hot temperature of these fluids (157°C to 183°C in the Atiart-Arro example) indicates their circulation through deep parts of the thrust belt. The progressive increase of the 87Sr/86Sr ratio through time is due to the progressive uplift, exposure and erosion of the internal Pyrenean Axial Zone.
Thrust belts and foreland basins, from fold kinematics to hydrocarbon systems

hal-00408001
https://hal.archives-ouvertes.fr/hal-00408001
DOI : 10.1007/978-3-540-69426-7_5

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The identification of the structures and deformation patterns in magma-poor continental rifted margins is essential to characterize the processes of continental lithosphere necking. Brittle faults, often termed mantle detachments, are believed to play an essential role in the rifting processes that lead to mantle exhumation. However, ductile shear zones in the deep crust and mantle are rarely identified and their mechanical role remains to be established. The western Betics (Southern Spain) provides an exceptional exposure of a strongly thinned continental lithosphere, formed in a supra-subduction setting during Oligocene-Lower Miocene. A full section of the entire crust and the upper part of the mantle is investigated. Variations in crustal thickness are used to quantify crustal stretching that may reach values larger than 2000% where the ductile crust almost disappear, defining a stage of hyper-stretching. Opposite senses of shear top-to-W and top-to-E are observed in two extensional shear zones located close to the crust-mantle boundary and along the brittle-ductile transition in the crust, respectively. At locations where the ductile crust almost disappears, concordant top-to-E-NE senses of shear are observed in both upper crust and serpentinized mantle. Late high-angle normal faults with ages of ca. 21 Ma or older (40Ar/39Ar on white mica) crosscut the previously hyper-stretched domain, involving both crust and mantle in tilted blocks. The western Betics exemplifies, probably better than any previous field example, the changes in deformation processes that accommodate the progressive necking of a continental lithosphere. Three successive steps can be identified: i/a mid-crustal shear zone and a crust-mantle shear zone, acting synchronously but with opposite senses of shear, accommodate ductile crust thinning and ascent of subcontinental mantle; ii/hyper-stretching localizes in the neck, leading to an almost disappearance of the ductile crust and bringing the upper crust in contact with the subcontinental mantle, each of them with their already acquired opposite senses of shear; and iii/high-angle normal faulting, cutting through the Moho, with related block tilting, ends the full exhumation of the mantle in the zone of localized stretching. The presence of a high strength sub-Moho mantle is responsible for the change in sense of shear with depth. Whereas mantle exhumation in the western Betics occurred in a backarc setting, this deformation pattern controlled by a high-strength layer at the top of the lithosphere mantle makes it directly comparable to most passive margins whose formation lead to mantle exhumation. This unique field analogue has therefore a strong potential for the seismic interpretation of the so-called “hyper-extended margins”.
ISSN: 0264-8172

insu-01310895
https://hal-insu.archives-ouvertes.fr/insu-01310895
https://hal-insu.archives-ouvertes.fr/insu-01310895/document
https://hal-insu.archives-ouvertes.fr/insu-01310895/file/Frasca-MarPetGeol-2016.pdf
DOI : 10.1016/j.marpetgeo.2016.04.020

Éditeur(s) : HAL CCSD
Résumé : Semi-volatile organic compounds (SVOCs) refer to a broad spectrum of molecules from different chemical families that have numerous properties. They can be used as pesticides, plasticizers, flame retardants, surfactants, lubricants, etc. Consequently, they are introduced in numerous applications in buildings or used daily by the entire population. Once emitted through evaporation or abrasion in the indoor environment or introduced from the outdoors, their chemical or biological degradation is limited, and they persist indoors. This persistence also explains why some SVOCs that were banned a few years ago are still detected in the air and dust inside buildings. In indoor environments, SVOCs are divided between the gas phase, airborne particles, and dust settled on floors and surfaces. SVOCs are of concern due to their established or suspected health effects and their widespread exposure through different environmental media and pathways. The objective of the thesis was to study the concentrations of 66 SVOCs on airborne particles (PM10) and 48 SVOCs in settled dust in two samples of dwellings randomly selected across France. PM10 were sampled during the nationwide housing survey carried out by the French Observatory of indoor air quality in 2003-2005. The dust samples were collected from vacuum cleaner bags during a nationwide survey carried out in French dwellings where at least one child aged 6 months to 6 years lived (2008-2009). The SVOCs to be analyzed had prior been selected using a ranking method based on their toxicity and indoor concentrations. The data analysis focused in particular on the identification of French specificities in terms of detected molecules and measured concentrations. It highlighted some determinants of exposure, e.g., influence of particle size, type of dust collected, dust bioaccessibility, which are not always considered and limit the comparability of results. The measured concentrations were also used to assess the health ranking implemented prior to this work and to confirm its relevance. The concentrations measured both in the air and in settled dust were compared to study the similarities in terms of concentrations and SVOC mixtures. Finally, the exposure doses to SVOCs were calculated for both a child and an adult to assess the respective contributions of inhalation and ingestion to these compounds in particulate phase in dwellings.
Les composés organiques semi-volatils (COSV) font l’objet d’une attention croissante depuis une dizaine d’années. Utilisés dans de nombreux produits et matériaux du quotidien, ils sont émis dans les bâtiments par dispersion lors de l’usage, par évaporation ou abrasion. Du fait de leurs caractéristiques physico-chimiques, ces composés se répartissent à la fois dans l’air, en phases gazeuse et particulaire, et dans les poussières déposées au sol, sur le mobilier et les objets. Compte tenu du temps passé par la population dans les bâtiments, en particulier par les populations sensibles comme les enfants, les femmes enceintes et les personnes âgées, l’exposition à ces substances mérite d’être documentée, tenant compte des voies d’exposition en jeu : inhalation, ingestion et contact cutané. La thèse a porté sur les COSV présents en phase particulaire dans les logements. L’objectif de la thèse visait à exploiter les mesures de 66 COSV dans les particules en suspension de diamètre inférieur à 10 µm (PM10) et de 48 COSV dans les poussières au sol de taille inférieure à 100 µm considérées comme étant celles adhérant à la peau. Ces mesures ont été réalisées dans le cadre de deux campagnes nationales : la campagne « Logements » de l’Observatoire de la qualité de l’air intérieur conduite en 2003-2005 et l’enquête Plomb-Habitat dont les prélèvements ont eu lieu en 2008-2009. Une hiérarchisation des molécules jugées prioritaires au regard de leur impact sanitaire potentiel avait permis au préalable d’établir la liste des COSV à mesurer. L’exploitation de ces données de contamination a notamment porté sur l’identification d’éventuelles spécificités françaises au regard des molécules en présence et/ou des concentrations mesurées. Elle a permis de mettre en lumière un ensemble de facteurs déterminants de l’exposition (influence de la taille des particules, du type de poussières collectées, de leur bioaccessibilité), qui ne sont pas toujours considérés et qui limitent par ailleurs la comparabilité des résultats. Les concentrations mesurées ont aussi permis d’évaluer rétrospectivement la hiérarchisation sanitaire et d’en confirmer la pertinence. Les concentrations des COSV quantifiés à la fois dans l’air et au sol ont été mises en perspective afin d’examiner dans quelle mesure les particules en suspension et les poussières déposées sont similaires en termes de concentrations et de mélanges de COSV en présence. Enfin, l‘estimation des doses d’exposition aux COSV à partir d’équations simples, de variables humaines d’exposition et des données de contamination a permis une première évaluation des contributions respectives de l’inhalation et de l’ingestion aux expositions domestiques des enfants et adultes à ces composés en phase particulaire.
https://tel.archives-ouvertes.fr/tel-01308524

NNT : 2015REN1B033
tel-01308524
https://tel.archives-ouvertes.fr/tel-01308524
https://tel.archives-ouvertes.fr/tel-01308524/document
https://tel.archives-ouvertes.fr/tel-01308524/file/MANDINCorinne.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Pyrethroid insecticides are widely used in agriculture and in homes. Despite the neurotoxicity of these insecticides at high doses, few studies have examined whether lower-level exposures could adversely affect children's neurodevelopment. The PELAGIE cohort included 3421 pregnant women from Brittany, France between 2002 and 2006. When their children reached their sixth birthday, 428 mothers from the cohort were randomly selected, successfully contacted and found eligible. A total of 287 (67%) mothers agreed to participate with their children in the neuropsychological follow-up. Two cognitive domains were assessed by the Wechsler Intelligence Scale for Children: verbal comprehension and working memory. Five pyrethroid and two organophosphate insecticide metabolites were measured in maternal and child first-void urine samples collected between 6 and 19 gestational weeks and at 6 years of age, respectively. Linear regression models were used to estimate associations between cognitive scores and urinary pyrethroid metabolite concentrations, adjusting for organophosphate metabolite concentrations and potential confounders. Maternal prenatal pyrethroid metabolite concentrations were not consistently associated with any children's cognitive scores. By contrast, childhood 3-PBA and cis-DBCA concentrations were both negatively associated with verbal comprehension scores (P-trend = 0.04 and P-trend < 0.01, respectively) and with working memory scores (P-trend = 0.05 and P-trend < 0.01, respectively). No associations were observed for the three other childhood pyrethroid metabolite concentrations (4-F-3-PBA, cis-DCCA, and trans-DCCA). Low-level childhood exposures to deltamethrin (as cis-DBCA is its principal and selective metabolite), in particular, and to pyrethroid insecticides, in general (as reflected in levels of the 3-PBA metabolite) may negatively affect neurocognitive development by 6 years of age. Whatever their etiology, these cognitive deficits may be of importance educationally, because cognitive impairments in children interfere with learning and social development. Potential causes that can be prevented are of paramount public health importance
ISSN: 0160-4120

hal-01162374
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01162374
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01162374/document
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01162374/file/Pyrethroid%20insecticide%20exposure.pdf
DOI : 10.1016/j.envint.2015.05.009

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Several recent studies have documented that reactions between melt and crystal mush in primitive gabbroic rocks (via reactive porous flow) have an important control in the formation of the lower oceanic crust and the evolution of MORBs. In this context, olivine-rich rocks can form either by fractional crystallization of primitive melts or by open system reactive percolation of pre-existing (possibly mantle-derived) olivine matrix. To address this question, we performed in-situ trace element analyses (by LA-ICP-MS) of olivine from the Erro-Tobbio ophiolite Unit (Ligurian Alps), where mantle peridotites show gradational contacts with an hectometer-scale body of troctolites and plagioclase wehrlites, and both are cut by later decameter-wide lenses and dykes of olivine gabbros. Previous studies inferred that troctolites and olivine gabbros represent variably differentiated crystallization products from primitive MORB-type melts. Olivines in the three rock types (mantle peridotites, troctolites, olivine gabbros) exhibit distinct geochemical signature and well-defined elemental correlations. As expected, compatible elements (e.g. Ni) show the highest concentrations in peridotites (2580–2730 ppm), intermediate in troctolites (2050–2230 ppm) and lowest in gabbros (1355–1420 ppm), whereas moderate incompatible elements (e.g. Mn, Zn) show the opposite behaviour. By contrast, highly incompatible elements like Zr, Hf, Ti, HREE are variably enriched in olivines of troctolites, and the enrichment in absolute concentrations is coupled to development of significant HFSE/REE fractionation (ZrN/NdN up to 80). AFC modelling shows that such large ZrN/NdN ratios in olivines are consistent with a process of olivine assimilation and plagioclase crystallization at decreasing melt mass, in agreement with textural observations. In-situ trace element geochemistry of olivine, combined with microstructural investigations, thus appears a powerful tool to investigate reactive percolation and the origin of olivine-rich rocks in the lower oceanic crust.
ISSN: 0016-7037

hal-01419938
https://hal.archives-ouvertes.fr/hal-01419938
DOI : 10.1016/j.gca.2016.06.029

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : International audience
We present Contact Dynamics discrete element simulations of the earthquake-triggered Jiufengershan avalanche, which mobilized a 60 m thick, 1.5 km long sedimentary layer, dipping similar to 22 degrees SE toward a valley. The dynamic behavior of the avalanche is simulated under different assumptions about rock behavior, water table height, and boundary shear strength. Additionally, seismic shaking is introduced using strong motion records from nearby stations. We assume that seismic shaking generates shearing and frictional heating along the surface of rupture, which, in turn, may induce dynamic weakening and avalanche triggering; a simple "slip-weakening'' criterion was adopted to simulate shear strength drop along the rupture surface. We investigate the mechanical processes occurring during triggering and propagation of an avalanche mobilizing shallowly dipping layers. Incipient deformation forms a pop-up structure at the toe of the dip slope. As the avalanche propagates, the pop-up deforms into an overturned fold, which overrides the surface of separation along a decollement. Simultaneously, uphill layers slide at high velocity (125 km/h) and are folded and disrupted as they reach the toe of the dip slope. The avalanche foot forms a wedge that is pushed forward as deformed rocks accrete at its rear. We simulated five cross sections across the Jiufengershan avalanche, which differ in the geometry of the surface of separation. Topographic and simulated surface profiles are similar. The friction coefficient at the surface of separation determined from back analysis is abnormally low (mu(SS) = 0.2), possibly due to lubrication by liquefied soils. The granular deposits of simulated earthquake- and rain-triggered avalanches are similar.
ISSN: 0148-0227

hal-00420882
https://hal.archives-ouvertes.fr/hal-00420882
DOI : 10.1029/2008JF001075

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : Some major challenges for geophysicists and structural geologists using three-dimensional boundary element method codes (3D-BEM) are: (1) reducing the amount of memory required to solve large and dense systems and (2) incorporation of inequality constraints such as traction inequality constraints (TIC) and displacement inequality constraints (DIC). The latter serves two purposes. First, for example, inequality constraints can be used to simulate frictional slip (using TIC). Second, these constraints can prevent element interpenetration while allowing opening mode (using DIC). We have developed a method that simultaneously incorporates both types of functionality of the inequality constraints. We show that the use of an appropriate iterative solver not only avoids the allocation of significant memory for solving the system (allowing very large model computation and simplifying parallelization on multi-core processors), but also admits interesting features such as natural incorporation of TICs and DICs. Compared to other techniques of contact management (e.g., Lagrange multipliers, penalty method, or complementarity problem), this new simple methodology, which does not use any incremental trial-and-error procedures, brings more flexibility, while making the system more stable and less subject to round-off errors without any computational overhead. We provide validations and comparisons of the inequality constraints implementation using 2D analytical and numerical solutions.
ISSN: 1420-0597

hal-00561035
https://hal.archives-ouvertes.fr/hal-00561035
DOI : 10.1007/s10596-009-9170-x

Éditeur(s) : HAL CCSD Wiley
Résumé : International audience
The embryonic development in Chione cancellata, from fertilization to straighthinge D-stage veliger larva, occurs in 24 h at 251C. Transmission (TEM) and scanning (SEM) electron microscopy show that morphogenetic processes result in a gastrula with two depressions, 4 h after fertilization (T014 h). Two hours later, one depression, located at the animal pole, develops into an open cave, the floor of which becomes the shell field, characterized by scarce microvilli, located below the lower face of the prototrochal pad. The invagination located at the vegetal pole is characterized by regular microvilli and constitutes the digestive tract. At T018 h, the late gastrula differentiates into a typical motile trochophore, possessing a well-developed prototroch delimiting anterior and posterior embryonic regions. At T019h, the shell field, located between the prototroch and the telotroch, appears as a saddle-shaped region with a wrinkled surface extending on both sides of the embryo, establishing bilateral symmetry. From TEM observations, the apical surface of the underlying cells possesses a modified glycocalyx featuring a dense pellicle overlapping the cells of the shell field. At T0112 h, the prototroch is displaced toward the anterior region by outgrowth of the shell material. TEM views show that the wrinkled surface observed with SEM corresponds to the periostracum, attached dorsally to the hinge and ventrally to the cells of the future mantle edge. At T0115 h, an alveolar matrix of proteinaceous material, which could contain calcite crystals, appears between the periostracum and the mantle. At T0124 h, prodissoconch I formation is completed and the D-stage larvae possess a calcified shell. At this stage of development, only one mantle fold is present, representing the outer fold. The periostracumsecreting cells are in contact with the marginal cells of the velum. This functional velum is composed of four bands of cilia. Our TEMobservations confirm previous descriptions of the velum ciliary bands obtained only from SEM analyses, such as described in other bivalves. The apical sense organ and the digestive tract are poorly developed. From observations at the ultrastructural level of shell differentiation in C. cancellata, we propose a new interpretation of shell differentiation, including hinge and ligament for bivalves as opposed to that described for gastropods.
ISSN: 1077-8306

hal-00755283
https://hal.univ-antilles.fr/hal-00755283
DOI : 10.1111/j.1744-7410.2006.00036.x

Résumé : Mondialisation et cultures populaires à Barbade et Trinidad (musique, Carnaval et danse) La culture caribéenne subit de plus en plus les assauts de la mondialisation. Et la question qui se pose concerne l'impact de la mondialisation sur la culture dans la région, c'est-à- dire le passage de la culture ethnique à la mondialisation. Au cours des siècles, le Caribéen, ce métis culturel, cet individu s'est façonné au contact d'influences diverses . Il faut attendre les années 1970 pour que la Barbade et Trinidad se forgent une nouvelle identité sous l'influence du Black Power venu des Etats - Unis et du mouvement Rastafari issu de la Jamaïque. Par ailleurs, l'influence de la télévision et de la musique américaine combinée aux migrations et aux effets de la mondialisation constitue des éléments majeurs à la formation de cette nouvelle identité. Aujourd 'hui après plus de cinquante ans d'indépendance, il y a une timide appréciation de la culture locale. Timide , parce qu'à radio, on entend plus de la musique internationale (américaine, anglais) que de musique locale (calypso, soca) saufpendant le Carnaval de Trinidad et le Crop Over de Barbade. Ce que regrettent les calypsoniens qui reprochent aux radios locales de ne diffuser cette musique que pendant cette période. De la musique caribéenne, les . jeunes de Barbade et de Trinidad plébiscitentures le reggae, la dancehall, le raggasoca, la musique soca. En fait, le calypso correspond à un moment de la vie. A Trinidad, la musique indienne joue un rôle important qui correspond à la population du pays. La musique de Rihanna, l'icône du moment n'a rien de caribéen. Mais son succès phénoménal à Barbade et ailleurs permet de mieux appréhender les facettes de l'identité caribéenne, en général et en particulier, celle de Barbadien et du Trinidadien. De nos jours, les nouvelles technologies accentuent les effets de la mondialisation et contribuent à l'émergence d'une « décréolisation » pour reprendre les termes de G. Létang et d'une nouvelle identité..
Globalization and popular cultures in Barbados and Trinidad Caribbean culture is under the influence ofglobalization. The question is here the impact ofglobalization on the culture in the region . Through centuries the Caribbean man has been made through different cultures. We must wait for the years 1970 to see Barbados and Trinidad which have been made a new identity under the influence of Black Power and the Rastafari movement coming from Jamaica. After more than 50 years ofindependence, there is a shy appreciation oflocal culture . There is more international music than calypso. In Trinidad the Indian music plays an important role corresponding ta the population of the country The new technologies increase the effect of the globalization. It constitutes the rise of the "decreolisation movement".

http://www.theses.fr/2013AGUY0681/document

Éditeur(s) : HAL CCSD BioMed Central
Résumé : [b]Background[/b]: [i]Amblyomma variegatum[/i] and [i]A. hebraeum[/i] are two ticks of veterinary and human health importance in south-east Africa. In Zimbabwe they occupy parapatric (marginally overlapping and juxtaposed) distributions. Understanding the mechanisms behind this parapatry is essential for predicting the spatio-temporal dynamics of Amblyomma spp. and the impacts of associated diseases. It has been hypothesized that exclusive competition between these species results from competition at the levels of male signal reception (attraction-aggregation-attachment pheromones) or sexual competition for mates. This hypothesis predicts that the parapatry described in Zimbabwe could also be present in other countries in the region. [br/][b]Methods[/b]: To explore this competitive exclusion hypothesis we conducted field surveys at the two species' range limits in Mozambique to identify areas of sympatry (overlapping areas) and to study potential interactions (communicative and reproductive interference effects) in those areas. At sympatric sites, hetero-specific mating pairs were collected and inter-specific attractiveness/repellent effects acting at long and short distances were assessed by analyzing species co-occurrences on co-infested herds and co-infested hosts.[br/] [b]Results[/b]: Co-occurrences of both species at sampling sites were infrequent and localized in areas where both tick and host densities were low. At sympatric sites, high percentages of individuals of both species shared attachment sites on hosts and inter-specific mating rates were high. Although cross-mating rates were not significantly different for[i] A. variegatum[/i] and [i]A. hebraeum[/i] females, attraction towards hetero-specific males was greater for [i]A. hebraeum[/i] females than for A. variegatum females and we observed small asymmetrical repellent effects between males at attachment sites.[br/][b]Conclusions[/b]: Our observations suggest near-symmetrical reproductive interference between [i]A. variegatum[/i] and [i]A. hebraeum[/i], despite between-species differences in the strength of reproductive isolation barriers acting at the aggregation, fixation and partner contact levels. Theoretical models predict that sexual competition coupled with hybrid inviability, greatly reduces the probability of one species becoming established in an otherwise suitable location when the other species is already established. This mechanism can explain why the parapatric boundary in Mozambique has formed within an area of low tick densities and relatively infrequent host-mediated dispersal events.
ISSN: 1756-3305

hal-01220744
https://hal.archives-ouvertes.fr/hal-01220744
https://hal.archives-ouvertes.fr/hal-01220744/document
https://hal.archives-ouvertes.fr/hal-01220744/file/2015%20Bournez%20Parasites%20%26%20Vectors_%7B365AAFF5-7041-480B-9B77-9CD0485A9B72%7D.pdf
DOI : 10.1186/s13071-015-1116-7

Résumé : La tribologie est définie comme la science qui étudie les phénomènes de frottement, d’usure et de lubrification. Elle intervient à chaque fois que deux surfaces sont en mouvement relatif l’une par rapport à l’autre. On la rencontre donc principalement dans les moteurs, les instruments de coupe, les assemblages mécaniques etc. Le frottement et l’usure sont les causes principales des pertes de performances et de durabilité des systèmes. L’usure coute 3 % du PIB en France et on estime que 10 % à 30 % de l’énergie produite dans le monde est consommée par frottement, c’est dire l’importance que porte le monde industriel à cette science.C'est la lubrification qui a pour rôle de minimiser le frottement et de protéger les surfaces de l'usure. Il existe différents régimes de lubrification, cependant les travaux effectués au cours de cette thèse de doctorat s’intéressent exclusivement au régime de lubrification limite. Dans ce régime de lubrification, l’épaisseur du film de lubrifiant est du même ordre de grandeur que la hauteur des aspérités des surfaces en contact et le frottement et l'usure des surfaces peuvent être très sévères. La stratégie mise en place pour lutter contre ces phénomènes consiste à ajouter des additifs à l'huile lubrifiante, qui formeront au cours du frottement un film protecteur (le tribofilm). Il apparait donc primordial de bien caractériser ces tribofilms afin de mieux comprendre les mécanismes de réduction de frottement et de l’usure, qui restent encore à ce jour mal connus.Les nanotechnologies permettent aujourd'hui d'apporter un nouvel éclairage sur cette problématique et nous les avons mises à profit pour étudier le comportement mécanique des tribofilms à l’échelle nanométrique.L’objectif de ce travail est de comprendre les processus de réduction de frottement observés à l’échelle macroscopique lorsque des particules de composés lamellaires sont associées à un liquide de faible viscosité. Les tribofilms étudiés sont formés à partir de trois composés lamellaires différents, le graphite, le thiophosphate de nickel NiPS3 et le bisulfure de molybdène MoS2. Pour ces trois composés, deux types de tribofilms ont été étudiés : ceux formés à partir des particules seules (les tribofilms secs) et ceux formés en présence de liquide (les tribofilms éther).L’analyse des propriétés tribologiques mesurées à macro et nano échelle, nous ont permis de mieux comprendre la contribution des effets individuels et collectifs sur les mécanismes réducteurs de frottement. Ces expériences ont permis de mettre en évidence que la réduction du coefficient de frottement observée à macro-échelle n'est pas due à la nanostructuration des tribofilms ni à une baisse des interactions entre les feuillets mais plutôt à un effet collectif des particules et du liquide.
Tribology is the science of friction phenomena, wear and lubrication. It takes part every time two surfaces are in relative motion. It performs meanly in engine and mechanical systems. Friction and wear are the mean reasons of loose of performance and durability of mechanical systems. Wear costs 3% of the GDP in France and about 10% to 30% of the produced energy in the world is consumed by friction.The aim of lubrication is to reduce friction and protect the surface against wear. There are four different types of lubrication regimes but this study is focused on the boundary regime. In this regime, lubricant thickness is of the same order of the magnitude of the sliding surfaces roughness, leading to a high-level of friction and wear. Additives are added to the lubricating base oil, in order to build a protecting tribofilm. Characterization of the tribofilms appears essential to better understand the friction and wear reduction mechanisms.Nanotechnology allows to bring a new insight on this issue through the study of the mechanical behavior of the tribofilms at nanoscale.The aim of this work is to better understand the process of the friction reduction observed at macroscale when lamellar particles are associated to a low viscosity liquid. The tribofilms are formed from three different lamellar compounds, graphite, nickel thiophosphate NiPS3 and molybdenum disulfide MoS2. Two different kinds of tribofilms are studied: those formed with the solids particles only (dry tribofilms) and those formed in presence of liquid (wet tribofilms).The analyses of the tribological properties measured at nanoscale allow us to better understand the contribution of the individual and collective effects on friction reduction mechanims. We show that the reduction of the friction coefficient observed at macroscale is not related to the surface nanostructuration of the tribofilms neither to the decrease of the interaction energy between the sliding surfaces, but rather to collective effects of the liquid and the particles in the contact.

http://www.theses.fr/2014AGUY0706/document

Éditeur(s) : HAL CCSD Sidestone Press
Résumé : International audience
Les habitations-plantations constituent le creuset historique et symbolique où fut fondu l'alliage original que sont les cultures antillaises. Elles sont le berceau des sociétés créoles contemporaines qui y ont puisé tant leur forte parenté que leur diversité. Leur étude a été précocement le terrain de prédilection des historiens. Les archéologues antillanistes se consacraient alors plus volontiers à l'étude des sociétés précolombiennes. Ainsi, en dehors des travaux pionniers de J. Handler et F. Lange à la Barbade, c'est surtout depuis la fin des années 1980 qu'un véritable développement de l'archéologie des habitations-plantations antillaises a pu être observé. Les questions pouvant être traitées par l'archéologie des habitations-plantations sont extrêmement riches et multiples et ne sauraient être épuisées par la publication d'un unique ouvrage. Les différents chapitres qui composent ce livre dirigé par K. Kelly et B. Bérard n'ont pas vocation à tendre à l'exhaustivité. Ils nous semblent, par contre, être représentatifs, par la variété des questions abordée et la diversité des angles d'approche, de la dynamique actuelle de ce champ de la recherche. Cette diversité est évidemment liée à celle des espaces concernés: les habitations-plantations de cinq îles des Petites Antilles : Antigua, la Guadeloupe, la Dominique, la Martinique et la Barbade sont ici étudiées. Elle est aussi, au sein d'un même espace, due à la cohabitation de différentes pratiques universitaires. Nous espérons que cet ouvrage, tout en diffusant une information jusqu'à présent trop dispersée, sera le point de départ de nouveaux travaux. Ce développement de la recherche est une nécessité scientifique mais aussi sociale pour les populations antillaises. L'archéologie historique est une voie d'accès privilégiée aux interstices de l'histoire coloniale (contact précoloniaux, commerce interlope, marronnage physique et moral, nécessaires concessions fruits de la négociation permanente entre la norme coloniale et réalité quotidienne, etc.). En fouillant la terre antillaise, les archéologues ne peuvent que conter la quotidienneté de la vie au sein de l'archipel. Or c'est aussi (beaucoup ?) de ces interstices, s'inscrivant le plus souvent dans des échelles micro-locales, locales ou régionales, qu'ont émergé les cultures antillaises.
https://hal.univ-antilles.fr/hal-00973942

ISBN : 9789088901942
hal-00973942
https://hal.univ-antilles.fr/hal-00973942

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Recent research has demonstrated the importance of dermal exposure for some semivolatile organic compounds (SVOCs) present in the gas phase of indoor air. Though models for estimating dermal intake from gaseous SVOCs exist, their predictions can be subject to variations in input parameters, which can lead to large variation in exposure estimations. In this sensitivity analysis for a steady state model, we aimed to assess these variations and their determinants using probabilistic Monte Carlo sampling for 8 SVOCs from different chemical families: phthalates, bisphenols, polycyclic aromatic hydrocarbons (PAHs), organophosphorus (OPs), organochlorines (OCs), synthetic musks, polychlorinated biphenyls (PCBs) and polybromodiphenylethers (PBDEs). Indoor SVOC concentrations were found to be the most influential parameters. Both Henry's law constant (H) and octanol/water partition coefficient (Kow) uncertainty also had significant influence. While exposure media properties such as volume fraction of organic matter in the particle phase (fom-part), particle density (ρpart), concentration ([TSP]) and transport coefficient (ɣd) had a slight influence for some compounds, human parameters such as body weight (W), body surface area (A) and daily exposure (t) make a marginal or null contribution to the variance of dermal intake for a given age group. Inclusion of a parameter sensitivity analysis appears essential to reporting uncertainties in dermal exposure assessment.
ISSN: 0160-4120

hal-01526430
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01526430
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01526430/file/Dermal%20absorption%20of%20semivolatile%20organic%20compounds_accepted.pdf
DOI : 10.1016/j.envint.2017.02.005
PUBMED : 28249739

Éditeur(s) : HAL CCSD AGU and the Geochemical Society
Résumé : International audience
The ODP/IODP multileg campaign at ODP Site 1256 (Cocos plate, eastern equatorial Pacific) provides the first continuous in situ sampling of fast spreading ocean crust from the extrusive lavas, through the sheeted dikes and down into the uppermost gabbros. This paper focuses on a detailed petrographic and microanalytical investigation of the gabbro section drilled during IODP Expedition 312. The marked patchy and spotty features that can be observed in many Hole 1256D gabbros is mostly due to a close association of two different lithological domains in variable amounts: (1) subophitic domains and (2) a granular matrix. Major and trace element mineral compositions, geothermometry, and petrological modeling suggest that subophitic and granular domains follow one single magma evolution trend formed by in situ fractionation. The subophitic domains correspond to the relative primitive, high-temperature end-member, compositionally similar to the basalts and dikes from the extrusive unit upsection, while the granular domains fit with a magma evolution by crystal fractionation to lower temperatures, up to a degree of crystallization of similar to 80%. Our results support the following scenario for the fossilization of the axial melt lens at ODP Site 1256: relatively primitive MORB melts under near-liquidus conditions fill the melt lens and feed the upper, extrusive crust. Near the melt lens-sheeted dike boundary at lower temperatures, crystallization starts with first plagioclase before clinopyroxene in a mushy zone forming the subophitic domains. At decreasing temperatures, the subophitic domains continue to crystallize, finally forming a well-connected framework. Evolved, residual melt is finally trapped within the subophitic network, crystallizing at near-solidus conditions to the granular matrix. Another important textural feature in Hole 1256D gabbros is the presence of microgranular domains which are interpreted as relics of stoped/assimilated sheeted dikes (transformed to "granoblastic dikes" by contact metamorphism). All these different domains can be observed in close association, often at the thin section scale, demonstrating the extremely complex petrological record of combined crystallization/assimilation processes ongoing in the axial melt lens. Very similar gabbros with a marked spotty/patchy appearance, and bearing the same close association of lithological domains as observed at Site 1256, are known in the so-called "varitextured gabbro" unit from the Oman Ophiolite located at the same structural level, between cumulate gabbros and granoblastic dikes. The close petrological similarity of the gabbro/dike transition between both IODP Hole 1256D and the Oman ophiolite suggests that in situ fractionation and dike assimilation/contamination are major magmatic processes controlling the dynamics and fossilization of the axial melt lens at fast spreading oceanic ridges.
ISSN: 1525-2027

hal-00644798
https://hal.archives-ouvertes.fr/hal-00644798
DOI : 10.1029/2011GC003655