Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
Purpose: Marine mangrove sediments in the Manche-à-Eau lagoon (Guadeloupe, Caribbean Sea) harbor locally extensive, white microbial mats. These mats cover the surface of reduced sediments near the roots of red mangrove trees, Rhizophora mangle, and are mainly composed of sulfur-oxidizing bacteria belonging to the Beggiatoaceae family, with some filamentous cyanobacteria. The goal of this study was to investigatethe possible influence of sediment characteristics on the presence of these microbial mats. Materials and methods: Four push cores were collected in April 2013, two from zones with microbial mats and two from zones without mats. Sediment characteristics (grain-size distribution, mineralogy, total organic carbon (TOC) and total nitrogen (TN) contents, atomic TOC/TN ratios, and organic matter (OM) δ13C values) were compared for all four cores.Results and discussion: Significant differences were observed between sediments below microbial mats and those without mats. Sediments with microbial mats contained greater amounts of clay, and higher TOC, TN, and TOC/TN ratios, with lower total carbonate content andδ13C values. The higher clay content most likely results from lower fluid flow velocity near to mangrove roots, while higher TOC/TN ratiosand lower δ13C values indicate higher inputs of OM from mangrove trees. These results are consistent with the fact that microbial mats were observed near the roots of mangrove trees, which trap OM from terrestrial vegetation and fine sediments.Conclusions: The grain-size distribution of sediment particles, the total carbonate content, and the δ13C values are the main parameters discriminating between zones with microbial mats and those without mats. Variations in total carbonate content, which is mainly of biogenic origin, result from conditions that are more favorable for benthic organisms in zones without microbial mats. Variations of the TOC/TN ratios are controlled by the presence of a non-negligible amount of inorganic nitrogen bound to surface clay mineral particles and/or by microbial processes.
ISSN: 1439-0108

hal-01682110
https://hal.univ-antilles.fr/hal-01682110
DOI : 10.1007/s11368-016-1555-6

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The thermal evolution of sediments in the shallowest part of sedimentary basins is challenging to investigate as most of the geothermometers are at their application limits. This is typically the case of the Callovian-Oxfordian claystones at the eastern border of the Paris Basin. A recent 2000 m deep well penetrated the entire Jurassic and Triassic sedimentary series and permitted coring of sediments never reached by previous drilling in this part of the basin. Thanks to the use of several independent geothermometers (apatite fission track thermochronology, fluid inclusion microthermometry, clay mineralogy and sedimentary organic matter evolution) the burial history of the Mesozoic series has been reconstructed, modeled and calibrated using kinetic algorithms relevant to the various paleothermometers used. In addition to these conventional methods, an innovative approach was developed using the temperature-dependence of the magnetic mineral assemblage within clay-rich sediments ("MagEval"). Thermal modeling indicates that the Callovian-Oxfordian and the Lower Triassic experienced maximum burial temperatures of 50 +/- 5 C-circle and 90 +/- 10 C-circle respectively, i.e., about 25 C higher than present-day. This temperature offset implies the erosion of several hundred meters of sediments which, depending on the thermal flux and conductivity considered, most likely constituted Upper Cretaceous chalk deposits. Falling sea level resulted in the exposure and subsequent dismantling of the chalk cover at the beginning of Cenozoic times. The eastern border of the basin was then subjected to slow erosion and discrete tectonic deformation.
ISSN: 0264-8172

hal-01313142
https://hal.archives-ouvertes.fr/hal-01313142
DOI : 10.1016/j.marpetgeo.2013.08.019

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
This study presents the geochemical composition of superficial sediment under oxic and suboxic bottom water conditions along the Chilean continental margin (SE Pacific), where evidence for benthic chemosynthetic activity associated with diffuse seeping of chemically reduced fluids has been reported. The exploration was carried out at: (1) the Chilean Triple Junction (CTJ), at a water depth of ∼2900 m, with the additional indication of hydrothermal activity near a methane-rich cold-seep area (46°S) (German et al., 2010); and (2) the El Quisco methane seep site (EQSS), at ∼340 m water depth (33°S) (Melo et al., 2007; Krylova et al., 2014). While the deeper CTJ is located within an oxic environment (dissolved oxygen in the bottom waters: 164 μM), the shallower EQSS lies within a suboxic environment (dissolved oxygen in bottom water: 23 μM), located within the lower limit of the SE Pacific oxygen minimum zone (OMZ).Pore water from short cores was analyzed for dissolved major, minor, and trace elements (Cl, Na, Mg, K, Ca, Sr, Si, B, P, Ba, Pb, Mn, Fe, Cd, U, and Mo), δ13DIC, sulfide, sulfate, and methane. The solid sediment fraction was likewise analyzed for total organic carbon (TOC), metals, and redox potential. Elevated sediment temperatures were found in superficial sediments (5–13 °C) at the CTJ site, which could be due to warm fluids associated with the proximity of the ridge, where hydrothermal vents may occur. Reduced fluids were also present here, indicated by higher Mn fluxes toward the water column even in oxidized sediments (RPD > 8 cm), which contrasted with the lower fluxes in reduced sediments of the EQSS site (RPD ∼ 2 cm). 13C-depleted DIC, anomalously low pore water Cl (∼15 ppb), and low concentrations of other major elements may be the result of dilution by fluid seeping and precipitation of major elements, producing authigenic enrichment (Ca, Mg, Sr). The fluid could also: (a) be diluted by pure water produced during methane hydrate dissociation, as observed in other cold-seep areas; and (b) correspond to clay mineral dehydration, as reported in plate subduction systems. The reducing conditions established at the CTJ conduct the Cd enrichment at a similar magnitude of that seen at the shallower suboxic site (EQSS). Evidence of chimney or vent fauna was not observed. At the EQSS, higher TOC and total sulfide contents were consistent with enhanced deposition of organic matter and reducing conditions developed in the OMZ, favoring the authigenic enrichment of Cd, U and Pb. The geochemical evidence, based only on methane concentrations and δ13DIC, is insufficient to establish the presence of methane seeps, as previously reported.
ISSN: 0079-6611

hal-01412700
https://hal.archives-ouvertes.fr/hal-01412700
DOI : 10.1016/j.pocean.2016.09.002

Éditeur(s) : Elsevier
Résumé : The ecological quality status (EcoQ) of intertidal mudflats constrained by Pacific oyster farming was assessed by single (H', AMBI, BENTIX and BOPA) and multimetric (M-AMBI and average score) index approaches in the Pertuis Charentais (SW France). Fifteen sampling stations were monitored seasonally for sedimentological features and macrozoobenthos in 2004. Sediments affected by oyster biodeposits showed organic matter enrichment, and sediments from off-bottom culture sites had higher organic matter contents and lower redox potentials than sediments from on-bottom culture sites. Biotic indices consistently registered responses of macrozoobenthos to organic enrichment but there was only partial agreement between single index-derived EcoQs. The average score was better than M-AMBI and single indices for determining EcoQs. Accordingly, oyster farming alters intertidal macrozoobenthic assemblages moderately, and off-bottom cultures cause more disturbance than on-bottom cultures. Hydrodynamics and seasons may interact with culture practices in smothering/strengthening biodeposition-mediated effects through dispersal/accumulation of biodeposits.
Marine Pollution Bulletin (0025-326X) (Elsevier), 2008-11 , Vol. 56 , N. 11 , P. 1898-1912

Droits : 2008 Elsevier Ltd All rights reserved.
http://archimer.ifremer.fr/doc/2008/publication-4650.pdf
DOI:10.1016/j.marpolbul.2008.07.010
http://archimer.ifremer.fr/doc/00000/4650/

Éditeur(s) : Elsevier Sci Ltd
Résumé : The quantity and the source of organic matter preserved in the Recent turbiditic channel-levees systems around 4000 m-depth off the Congo River were determined using bulk geochemical approaches (Rock-Eval, elemental and isotopic analyses) as well as molecular and optical analyses on selected samples. These mud-rich sediments contain high amount of organic matter (3% Corg on average), the origin of which is a mixture of terrestrial higher-plant debris and deeply oxidized phytoplanktonic material. Although the relative contribution of continental source versus marine source of the organic matter cannot be precisely quantified, the continental fraction appears significant (at least 70-80%) especially for such depths and distances from the coast. The organic matter distribution appears very homogeneous at different scales, from the single turbiditic event to the entire levee, and changes in accumulation rates have a little impact on the quantity and quality of preserved organic matter. With a petroleum potential around 4.5 kg HC per t rock, the fine-grained turbiditic sediments in the Congo deep-sea system could be regarded as an analog of gas-prone source rocks for the deep offshore of the Atlantic margins. Finally, the Congo deep-sea turbiditic system is a major conveyor of organic carbon to the deep ocean. Further studies are needed to evaluate the efficiency of such systems for the storage of continental organic matter into the deep ocean in relation to sea-level and climatic changes. (C) 2010 Elsevier Ltd. All rights reserved.
Marine And Petroleum Geology (0264-8172) (Elsevier Sci Ltd), 2010-05 , Vol. 27 , N. 5 , P. 995-1010

Droits : 2010 Elsevier Ltd All rights reserved.
http://archimer.ifremer.fr/doc/00006/11700/9285.pdf
DOI:10.1016/j.marpetgeo.2010.02.006
http://archimer.ifremer.fr/doc/00006/11700/

Éditeur(s) : HAL CCSD SAGE Publications
Résumé : International audience
A multiproxy analysis of lacustrine sediments cored in Grand-Case Pond at Saint-Martin, north of the Lesser Antilles archipelago, reveals three distinct climatic periods for the last 3700 years. From 3700 to ~2500 yr cal. BP and from 1150 yr cal. BP to the present, carbonate mud deposition occurred in connection with pond lowstands. These periods were also punctuated by severe drought events, marked by gypsum laminae, and hurricane landfalls, leading to marine sand inputs into the pond. The intermediate time interval, from 2500 to 1150 yr cal. BP, is typified by black organic mud deposition, suggesting that hypoxic to anoxic conditions prevailed at the pond bottom. These were probably linked with a perennial pond highstand and reflect more uniform and wetter climatic conditions than today. The carbon isotopic composition of the ostracod Perissocytheridea bisulcata shows that the lowest δ13C values are recorded during the hypoxic periods, as a consequence of bacterial recycling of isotopically depleted organic matter. Such a climatic history agrees closely with that documented from other records in the Caribbean area, such as the Cariaco Basin, central coast of Belize or Barbados. By constrast, discrepancies seem to emerge from the comparison between hurricane activity recorded at Saint-Martin on the one hand and Vieques (Puerto Rico) on the other hand. We explain this apparent contradiction by a balance between two distinct storm paths in response to latitudinal shifts of the Intertropical Convergence Zone (ITCZ). Stronger storm activity over the Gulf coast and the inner Caribbean Sea is favoured by a southern position of the ITCZ in connection with dry climatic conditions. Plausible links with the North Atlantic Oscillation (NAO) are also suggested.
ISSN: 0959-6836

halshs-00758748
https://halshs.archives-ouvertes.fr/halshs-00758748
https://halshs.archives-ouvertes.fr/halshs-00758748/document
https://halshs.archives-ouvertes.fr/halshs-00758748/file/Malaize_et_al._2011_cor.pdf
DOI : 10.1177/0959683611400198

Éditeur(s) : Elsevier
Résumé : Sediment cores acquired in 2004 off the Rhone prodelta show consistent anomalous methane concentrations of up to 87,440 ppm. Methane compositional and isotopic data support a biogenic origin, although there are a few sites that show strongly depleted delta C-13 values (-53%o PDB) suggesting a mixed source for the gas (biogenic and thermogenic). Anomalous methane concentrations (samples with more than 90 ppm) are discussed and integrated with organic carbon data, sedimentary rates and ADCP profiles. Highest gas concentrations were found directly off the river mouth (20-40 m water depth) and where the IFREMER models point to the thickest accumulation (> 2 m) in response to the Rhone flood event. In areas unaffected by the high flux of organic matter and rapid/thick flood deposition, or in between flood events, the conditions for methanogenesis and gas accumulation have not been met; in these areas, the physical and biological reworking of the surficial sediment may effectively oxidize and mineralize organic matter and limit bacterial methanogenesis in the sub-surface. We propose that in the Rhone prodelta flood deposits deliver significant amounts of terrigenous organic matter that can be rapidly buried, effectively removing this organic matter from aerobic oxidation and biological uptake and leading to the potential for methanogenesis with burial.
Marine Geology (0025-3227) (Elsevier), 2006-12 , Vol. 234 , N. 1-4 , P. 215-231

Droits : 2006 Elsevier B.V. All rights reserved
http://archimer.ifremer.fr/doc/2006/publication-2396.pdf
DOI:10.1016/j.margeo.2006.09.005
http://archimer.ifremer.fr/doc/00000/2396/

Éditeur(s) : HAL CCSD Elsevier
Résumé : This study analyzes the records of several trace metals sensitive to redox conditions in continental shelf sediments off Concepcion, Chile (36 degrees S). The continental margin off Concepcion (36 S; 73 W) lies beneath an important upwelling center characterized by high primary production rates and, consequently, high fluxes of organic matter. In spring and summer, this material settles to the seafloor where it decays, producing periods of very low oxygen content in bottom waters (<1 mL L-1). In addition, an oxygen minimum zone develops at similar to 100-400 m water depth, where dissolved oxygen levels are <0.5 mL L-1. This situation changes during strong El Nino events, when dissolved oxygen at the bottom increases drastically (>1 mL L-1).;The goals of this study were to determine the input of trace metals to the sediment and to decipher how this information can be used to reveal variations in primary productivity or bottom oxygenation. Gravity cores collected at two stations - VG06-2 over the mid-shelf station (88 m water depth, upper boundary of the oxygen minimum zone) and VG06-3 over the outer shelf (120 m water depth, within the oxygen minimum zone) - were sampled for high resolution profiles (1 cm) of trace metals, biogenic opal, stable isotopes, and total organic carbon. The results suggest that the variability in the trace metal distribution on the continental shelf off Concepcion is determined by redox conditions and the organic carbon flux to the bottom. Some sections of the sediment cores from the outer shelf showed appreciable authigenic enrichment of U, Cd, and Mo (EF: 5-10, 2-5, and 10-16 respectively) along with heavier values of delta N-15, suggesting periods of suboxic conditions. During these periods, fluxes of organic material to the bottom were higher, as indicated by elevated TOC and opal contents. Alternating periods of higher and lower trace metal contents were not observed mid-shelf as they were on the outer shelf. Rather, the mid-shelf samples showed authigenic enrichment of U, Cd, and Mo (EF: 1-6, 4-5, and 10-20, respectively) throughout the core except in a 10-cm-thick gray layer. In general, authigenic enrichment of U. Mo, and Cd occurred at both sites, coincident with olive green layers in the cores. These layers were associated with periods of elevated primary productivity and suboxic conditions. Such periods did not seem to last as long as the oxygenated periods, which had higher inputs of refractive detrital material, coincident with the occurrence of distinct gray sediment layers.
ISSN: 0079-6611

hal-00682159
https://hal.archives-ouvertes.fr/hal-00682159
DOI : 10.1016/j.pocean.2011.07.010

Éditeur(s) : Elsevier
Résumé : To elucidate the origin of the silicic acid (DSi) anomaly observed along the 4000 isobath on the Congo margin, we have established a benthic Si mass balance and performed direct measurements of biogenic silica (bSiO(2)) dissolution in the deep waters and in the sediments. Results strongly suggest that the anomaly originates from the sediments; the intensity of DSi recycling is consistent with the degradation of organic matter, as observed from Si:O-2 ratios in the benthic fluxes compared to that ratio observed in the anomalies. Strong imbalances, observed in both the Si and C mass balances, suggest that the biogenic matter that degrades and dissolves in these sediments near 4000 m does not come from pelagic sedimentation. It is probably not coming also from the deep channel, because observations were similar in the deep channel vicinity (site D) and further south, far from its influence (site C). The composition of the sediments, with an Si:C ratio close to that observed on continental shelves, suggests that this matter is coming from downslope transport. A first estimate of the magnitude of this flux at global scale, close to 12 T mol Si yr(-1), suggests that it may be an important path for transferring Si from land to ocean.
Deep Sea Research Part II: Topical Studies in Oceanography (0967-0645) (Elsevier), 2009-11 , Vol. 56 , N. 23 , P. 2197-2207

Droits : 2009 Elsevier Ltd All rights reserved.
http://archimer.ifremer.fr/doc/2009/publication-7410.pdf
DOI:10.1016/j.dsr2.2009.04.003
http://archimer.ifremer.fr/doc/00000/7410/

Éditeur(s) : Gauthier-Villars
Résumé : The biogeological organization of Thau lagoon was investigated through the granulometric analysis of surficial sediments and study of the qualitative and the quantitative distribution of benthic macrofauna and meiofauna. These show clearly that the lagoonal system is organized according to confinement as conceived by Guelorget and Perthuisot (1983 a; 1992), which depends upon the rate of exchanges with the open sea and the hydrodynamic pattern of the basin. The latter appears to be composed of a pair of lagoonal subsystems separated by a hydrodynamically unstable barrier. The northern subsystem displays the classical concentric organization of Mediterranean lagoons with a clearly defined hydraulic umbilicus. The southern subsystem displays a transverse original organization due to a large zone of exchanges with the sea through the sand bar. The basin is globally subject to only slight confinement, but displays signs of organic matter accumulation due to the intensification of shellfish culture.
Oceanologica Acta (0399-1784) (Gauthier-Villars), 1994 , Vol. 17 , N. 1 , P. 105-114

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/00098/20880/18494.pdf
http://archimer.ifremer.fr/doc/00098/20880/

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
The New Jersey continental shelf extends 150 km off the shoreline. During IODP Expedition 313, siliciclastic deposits of late Eocene to late Pleistocene age were drilled down to 631, 669 and 755 m below seafloor at sites 27A, 28A and 29A respectively in very shallow waters (33.5 to 36 m depth). Pore water salinities display multilayered brackish-salty-brine units 10 to 170 m thick, where low-salinity water is preferentially stored in fine-grained sediments. The sharp boundaries of these buried aquifers are often marked by cemented layers a few centimetres thick. The mineralogy and scanning electron microscope observations of these layers show two phases of cementation by authigenic minerals: (1) the early carbonate cement is frequently associated with pyrite, and (2) the late silicate cement infills the residual porosity. The isotopic compositions of the carbonate cements vary widely: −2.4 < δ¹⁸O ‰ VPDB < +2.8; −15.1 < δ¹³C ‰ VPDB < +15.6. The δ¹⁸O values indicate that the carbonate cements precipitated with pore waters comprising variable mixtures of seawater and ¹⁸O-depleted fresh water originating from submarine groundwater discharge. The δ¹³C values of the carbonate cements are related to organic matter diagenesis, providing ¹³C-depleted dissolved inorganic carbon during bacterial sulphate reduction and anaerobic oxidation of methane, and ¹³C-rich dissolved inorganic carbon during methanogenesis. The diagenetic cementation processes included chemical weathering of reactive silicate minerals by the CO²-rich pore waters issued from organic matter diagenesis that released bicarbonate, cations and dissolved silica, which were further precipitated as carbonate and silicate cements. The estimated range of temperature (18±4 °C) during carbonate precipitation is consistent with carbonate cementation at moderate burial depths; however, silicate cementation occurred later during diagenesis at deeper burial depths.
ISSN: 0276-0460

hal-01559985
https://hal.archives-ouvertes.fr/hal-01559985
DOI : 10.1007/s00367-017-0506-6

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Roussillon sedimentary Basin (South France) is a complex multi-layered aquifer, close to the Mediterranean Sea facing seasonally increases of water abstraction and salinization issues. We report geochemical and isotopic vertical variability in this aquifer using groundwater sampled with a Westbay System® at two coastal monitoring sites: Barcarès and Canet. The Westbay sampling allows pointing out and explaining the variation of water quality along vertical profiles, both in productive layers and in the less permeable ones where most of the chemical processes are susceptible to take place.The aquifer layers are not equally impacted by salinization, with electrical conductivity ranging from 460 to 43,000 μS·cm− 1. The δ2H–δ18O signatures show mixing between seawater and freshwater components with long water residence time as evidenced by the lack of contribution from modern water using 3H, 14C and CFCs/SF6. S(SO4) isotopes also evidence seawater contribution but some signatures can be related to oxidation of pyrite and/or organically bounded S. In the upper layers 87Sr/86Sr ratios are close to that of seawater and then increase with depth, reflecting water–rock interaction with argillaceous formations while punctual low values reflect interaction with carbonate. Boron isotopes highlight secondary processes such as adsorption/desorption onto clays in addition to mixings. At the Barcarès site (120 m deep), the high salinity in some layers appear to be related neither to present day seawater intrusion, nor to Salses-Leucate lagoonwater intrusion. Groundwater chemical composition thus highlights binary mixing between fresh groundwater and inherited salty water together with cation exchange processes, water–rock interactions and, locally, sedimentary organic matter mineralisation probably enhanced by pyrite oxidation.Finally, combining the results of this study and those of Caballero and Ladouche (2015), we discuss the possible future evolution of this aquifer system under global change, as well as the potential management strategies needed to preserve quantitatively and qualitatively this water resource.
ISSN: 0048-9697

hal-01685219
https://hal-brgm.archives-ouvertes.fr/hal-01685219
DOI : 10.1016/j.scitotenv.2016.05.016

Éditeur(s) : Amer Soc Limnology Oceanography
Résumé : A new benthic station equipped with oxygen microelectrodes and environmental sensors was developed by Laboratoire des Sciences du Climat et de L’Environnement (LSCE) and Division Technique of the Institut National des Sciences de L’Univers (DT-INSU) to perform in situ time series monitoring of sediment oxygen demand, linked to the mineralization of organic matter. The time series typically cover periods of 2-3 months, with a base frequency of 1 set of oxygen profiles per day. The profiling head assessed the lateral heterogeneity of the sediment oxygen demand at the beginning of the time series over a 0.8-m long rectangle to discriminate spatial and temporal variability. A continuous recalibration is performed using a moored oxygen optode anchored to the benthic station together with a set of environmental sensors. These sensors (turbidity, temperature, salinity, and oxygen) can trigger a high-frequency profiling mode to investigate the fate of particulate organic matter delivered during floods, resuspension, and deposition events. Deployments of the benthic station were performed in the Rhone River subaqueous delta (Mediterranean Sea). We show that “stable” periods (when neither floods nor storms occur) were characterized by a stable oxygen demand. In the case of resuspension events, an increase of the sediment oxygen demand by a factor of 2-3 with a relaxation time of 1 day was observed, indicating that the new benthic station can adequately capture the impact of resuspension events on the oxygen demand in deltaic sediments.
Limnology And Oceanography-methods (1541-5856) (Amer Soc Limnology Oceanography), 2014-11 , Vol. 12 , P. 729-741

Droits : 2014, by the American Society of Limnology and Oceanography, Inc.
http://archimer.ifremer.fr/doc/00230/34126/32597.pdf
http://archimer.ifremer.fr/doc/00230/34126/36349.pdf
DOI:10.4319/lom.2014.12.729
http://archimer.ifremer.fr/doc/00230/34126/

Éditeur(s) : Pergamon-elsevier Science Ltd
Résumé : We tested the applicability of the BIT (branched and isoprenoid tetraether) index as a proxy for palaeoflood events in the river-dominated continental margin of the Gulf of Lions (NW Mediterranean). We compared the concentrations of branched glycerol dialkyl glycerol tetraethers (br GDGTs) and crenarchaeol in suspended particulate matter (SPM) collected downstream in the Rhône River, as well as in surface sediments and a ca. 8m piston core from the Rhône prodelta. The core covered the last 400 yr, with four distinct intervals recording the river influence under natural and man-induced shifts in four main channels of the river mouth (Bras de Fer, Grand Rhône, Pégoulier,and Roustan). The results indicate that there are mixed sources of br GDGTs and crenarchaeol in the prodelta, complicating applicationof the BIT index as an indicator of continental organic carbon input and thus as a palaeoflood proxy. However, the sedimentary BIT record for the period when continental material was delivered by the river more directly to the core site (Roustan phase;1892 to present) mimics the historical palaeoflood record. This shows the potential of the BIT index as a palaeoflood proxy, provided that the delivery route of the continental material by rivers to the core sites remains constant over time. The study also highlights the idea that shifts in river channels should be taken into account for the use of the BIT index as a palaeoflood proxy.
Organic Geochemistry (0146-6380) (Pergamon-elsevier Science Ltd), 2014-10 , Vol. 75 , P. 99-108

Droits : 2014 Elsevier Ltd. All rights reserved.
http://archimer.ifremer.fr/doc/00198/30969/29345.pdf
DOI:10.1016/j.orggeochem.2014.06.011
http://archimer.ifremer.fr/doc/00198/30969/

Éditeur(s) : Gauthier-Villars
Résumé : During RV Gaveshani cruise No. 235 (August-September, 1993), particulate matter was collected from euphotic and deeper waters in the Bay of Bengal and analysed for biogenic silica (BSi), lithogenic silica (LSi) and particulate organic carbon (POC). Mean depth profiles of BSi showed a minimum in the surface waters and a maximum in the middle depths of the euphotic zone. The deepening of BSi maxima from north to south coincides with the deepening of the thermocline and thickening of the surface layer. In coastal waters, the contribution of BSi to total particulate silica was high (> 80 %); in offshore waters it was 60-70 %. BSi/POC (0.086) and LSi/POC (0.023) ratios show that particulate matter consists mostly of biogenic material, while the BSi/LSi (1.61) ratio revealed the dominance of siliceous phytoplankton in the euphotic zone. High concentrations of BSi (0.49 mu mol l(-1)) and LSi (1.89 mu mol l(-1)) in deeper waters are due to a high sedimentation rate, the resuspension of bottom sediments and the flow of large amounts of riverine siliceous material.
Oceanologica Acta (0399-1784) (Gauthier-Villars), 1997 , Vol. 20 , N. 3 , P. 493-500

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/00093/20459/18131.pdf
http://archimer.ifremer.fr/doc/00093/20459/

Résumé : Kepone contamination of French West Indies marine environments is scarcely known. Contaminated soils particles are carried by rivers from terrestrial zones to the coastal marine sediments where they settle. Thus coastal sediments potential function as a sink for them, but also as a source of contamination for the marine biota. Therefore, they can be of major importance both in relation with the origin of the catchment area contamination and with the potential impact of this contamination on the benthic ecosystems. The objectives of this study are to characterize the marine deposits in order to define the spatial extent of the contamination and to determine the temporal stages of this contamination in the superficial sedimentary column (about one half-meter deep). Two neighbouring bays were chosen along the south-atlantic coasts of the Martinique Island, the Robert Bay, where different previous studies have been already performed, and the Galion Bay, which also present important environmental concerns. The results (i) confirm the general low rate of kepone contamination in the Robert Bay superficial sediments, while the influence of the river is more pronounced in the Galion Bay for which sediment samples from the proximity of the river outfall are more contaminated, (ii) relativize the role of organic matter associated to the finer particle in the little contaminated marine sediments (iii) and at last, differentiate strongly the contamination of the two bays due to specific characteristic parameters. So, it apparears that the sedimentary dynamics and mineralogical cohorts undoubtedly should explain the discrepancies in the contamination of the sediments between the two bays, also characterized by very different humus-clayed compounds in the soils of each catchment basin.
La connaissance de la contamination des milieux marins antillais par la chlordécone est fragmentaire. Or, la fonction potentielle de ‘puits’, mais également de ‘source’, qu’assurent les sédiments littoraux suite au transfert de la molécule des sols terrestres jusqu’aux fonds marins devrait leur confèrer un rôle majeur dans leur relation avec les écosystèmes benthiques comme dans leur connexion avec les bassins versants correspondants. Du fait de la méconnaissance sédimentologique de ces milieux, le double objectif de la présente étude était de caractériser ces fonds afin de cerner l’extension spatiale de la contamination en chlordécone et de déterminer les phases temporelles de cette dernière dans la colonne sédimentaire superficielle (environ quarante premiers centimètres). Les zones d’étude choisies sont deux baies sud-atlantiques martiniquaises adjacentes, le havre du Robert, déjà retenu comme zone-atelier pour des études antérieures sur la dynamique du bassin versant, et la baie du Galion faisant l’objet de préoccupations environnementales et de travaux scientifiques prévus sur le bassin versant attenant. Les résultats obtenus conduisent à : (i) confirmer le faible taux de contamination générale des sédiments du havre du Robert, alors que l’influence de la rivière à débit significatif de la baie du Galion marque en ce sens les sédiments proches de son exutoire ; (ii) relativiser le rôle de la matière organique liée aux particules les plus fines dans cette faible contamination marine des sédiments et enfin (iii) différencier fortement la contamination des deux baies à partir de paramètres caractéristiques. Les dynamiques sédimentaires et les cortèges minéralogiques constituent sans aucun doute des pistes explicatives aux différences de contamination des sédiments entre les deux baies dont les bassins versants sont également caractérisés par des sols présentant des composés argilo-humiques très différents.

Droits : 2012 Ifremer
http://archimer.ifremer.fr/doc/00071/18247/15810.pdf
http://archimer.ifremer.fr/doc/00071/18247/

Éditeur(s) : EDP Sciences
Résumé : We present results obtained from a pristine site of French Guiana (South America), at the Pic Matecho, a region far from gold mining activity. This area contains a small permanent lake, a rare situation in French Guiana. Tree canopy, soils and Lake Matecho sediments were analysed in total Hg and Pb-210. The annual deposit of litterfall is estimated at 40 mug (Hg)/m(2)/y. The top sediment content of 0.2 mug (Hg)/g indicates a large contribution of the atmospheric deposit. In sediment, the decrease of total Hg with depth is neither due to local human influence, nor to increase of atmospheric background during this century. It is attributed to remineralization of organic matter in the upper part of the sediment : the majority of the total Hg deposited at the water/sediment interface is not permanently trapped in the sediment but remobilized in water. Interpretation of the historical sediment profile suggests a constant deposit rate over the last millennium.
Journal De Physique Iv (1155-4339) (EDP Sciences), 2003-05 , Vol. 107 , P. 859-862

Droits : 2003 EDP Sciences
http://archimer.ifremer.fr/doc/00000/10630/9348.pdf
DOI:10.1051/jp4:20030433
http://archimer.ifremer.fr/doc/00000/10630/

Éditeur(s) : HAL CCSD Mineralogical Society
Résumé : The diagenetic evolution of the magnetic minerals during burial in sedimentary basins has been recently proposed. In this study, we provide new data from the Grès d’Annot basin, SE France. We analyze fine-grained clastic rocks that suffered a burial temperature from ~60 to >250 °C, i.e., covering oil and gas windows. Low temperature magnetic measurements (10–300 K), coupled with vitrinite reflectance data, aim at defining the magnetic mineral evolution through the burial history. Magnetite is documented throughout the entire studied transect. Goethite, probably occurring as nanoparticles, is found for a burial temperature <80 °C. Micron-sized pyrrhotite is highlighted for a burial temperature >200 °C below the Alpine nappes and the Penninic Front. A model of the evolution of the magnetic assemblage from 60 to >250 °C is proposed for clastic rocks, containing iron sulfides (pyrite) and organic matter. This work provides the grounds for a better understanding of the magnetic properties of petroleum plays.
ISSN: 0009-8558

hal-01122812
https://hal.archives-ouvertes.fr/hal-01122812
DOI : 10.3390/min4030667

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Xenoestrogens may persist in the environment by binding to sediments or suspended particulate matter serving as long-term reservoir and source of exposure, particularly for organisms living in or in contact with sediments. In this study, we present for the first time an effect-directed analysis (EDA) for identifying estrogenic compounds in a sediment sample using embryos of a transgenic reporter fish strain. In the tg(cyp19a1b-GFP) transgenic zebrafish strain, the expression of GFP (green fluorescent protein) in the brain is driven by an oestrogen responsive element in the promoter of the cyp19a1b (aromatase) gene. The selected sediment sample of the Czech river Bilina had already been analysed in a previous EDA using the yeast oestrogen screening assay and had revealed fractions containing estrogenic compounds. When normal phase HPLC (high performance liquid chromatography) fractionation was used for the separation of the sediment sample, the biotest with transgenic fish embryos revealed two estrogenic fractions. Chemical analysis of candidate compounds in these sediment fractions suggested alkylphenols and estrone as candidate compounds responsible for the observed estrogenic effect. Alkylphenol concentrations could partially explain the estrogenicity of the fractions. However, xenoestrogens below the analytical detection limit or non-targeted estrogenic compounds have probably also contributed to the sample's estrogenic potency. The results indicated the suitability of the tg(cyp19a1b-GFP) fish embryo for an integrated chemical-biological analysis of estrogenic effects.
ISSN: 0166-445X

hal-01072210
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01072210
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01072210/document
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01072210/file/Effect-directed_analysis_for_estrogenic_compounds-final.pdf
DOI : 10.1016/j.aquatox.2014.05.016

Éditeur(s) : Gauthier-Villars
Résumé : The mangroves of Senegal are limited to the inlet of the Casamance - a river with very low discharge - and to the Sine-Saloum. The mineralogical and geochemical analysis of sediments (derived from 30 deep bore-holes) shows the thickness of the mangrove substrate, which overlies the continental terminal formation. Kaolinite and smectite account for over 90% of the clay fraction. The former is derived from the continental terminal whereas the latter is of marine origin. The chemical composition of the mangrove sediments is remarkably stable and clays play an overwhelming role in the preservation of organic matter and pyrite. Since 1968, a drought in Senegal has caused an important increase in the salinity levels of streams and water-tables; a considerable modification of vegetation zones in the Casamance, especially manifest in the extension of bare flats locally known as "tannes" at the expense of mangroves and marked changes in the morphology and geochemistry of mangrove soils. Compared to most mangrove areas in the humid tropics, mangroves in Senegal are characterized by a very fragile equilibrium.
Oceanologica Acta, Special issue (0399-1784) (Gauthier-Villars), 1982

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/00246/35744/34252.pdf
http://archimer.ifremer.fr/doc/00246/35744/