Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Introduction Evidence has accumulated that exposure to ambient air pollution during pregnancy may influence preterm birth (PTB) in urban settings. Conversely, this relation has barely been investigated in rural areas where individual characteristics (demographic, socioeconomic, and psychosocial factors) and environmental co-exposures may differ. Objective We examined the association between prenatal exposure to traffic-related air pollution and PTB among pregnant women from the PELAGIE mother–child cohort (Brittany, France, 2002–2006) living in urban (n=1550) and rural (n=959) settings. Methods Women’s residences were classified as either urban or rural according to the French census bureau rural–urban definitions. Nitrogen dioxide (NO2) concentrations at home addresses were estimated from adjusted land-use regression models as a marker of traffic-related pollution. Associations between NO2 concentrations and PTB were assessed with logistic regression models. Results Prevalence of PTB was similar among women living in urban (3.2%) and in rural (3.5%) settings. More positive socioeconomic characteristics and health behaviors but more single-parent families were observed among urban women. NO2 exposure averaged 20.8±6.6 µg m−3 for women residing in urban areas and 18.8±5.6 µg m−3 for their rural counterparts. A statistically significant increased risk of PTB was observed among women exposed to NO2 concentrations ≥16.4 µg m−3 and residing in urban areas but not among their rural counterparts. Discussion The results of this study, conducted in a region with interspersed urban–rural areas, are in line with previous findings suggesting an increased risk of PTB associated with higher NO2 concentrations for women living in urban areas. The absence of association among their rural counterparts for whom exposure levels were similar suggests that environmental mixtures and psychosocial inequalities might play a role in this heterogeneity
ISSN: 0013-9351

hal-01165108
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01165108
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01165108/document
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01165108/file/Air%20pollution%20%26%20preterm%20birth%20PELAGIE_HAL-accepted.pdf
PUBMED : 26092808

Éditeur(s) : Elsevier
Résumé : The distribution and speciation of mercury (Hg) in air, rain, and surface waters from the artificial tropical lake of Petit-Saut in French Guiana were investigated during the 2003/04 period. In the air, total gaseous mercury (TGM) at the dam station averaged 12 +/- 2 pmol m(-3) of which > 98% was gaseous elemental mercury (GEM). GEM distribution depicted a day-night cycling with high concentrations (up to 15 pmol m(-3)) at dawn and low concentrations (down to 5 pmol m(-3)) at nightfall. Reactive gaseous mercury (RGM) represented < 1% of the GEM with a mean concentration of 4 3 fmol m(-3). Diel RGM variations were negatively related to GEM. In the rain, the sum of all Hg species in the unfiltered (HgTUNF) averaged 16 +/- 112 pmol L-1. Temporal distribution of HgTUNF exhibited a pattern of high concentrations during the late dry seasons (up to 57.5 pmol L-1) and low concentrations (down to 2.7 pmol L-1) in the course of the wet seasons. Unfiltered reactive (HgRUNF), dissolved gaseous (DGM) and monomethyl (MMHgUNF.) Hg constituted 20, 5 and 5% of HgTUNF, respectively. All measured Hg species were positively related and displayed negative relationships with the pH of the rain. In the reservoir surface waters, dissolved total mercury (HgTD) averaged 3.4 +/- 1.2 pmol L-1 of which 10% consisted of DGM. DGM showed a trend of high concentrations during the dry seasons (480 +/- 270 finol L-1 and lower (230 +/- 130 finol L-1) in the course of the wet seasons. Diel variations included diurnal photo-induced DGM production (of about 60 firiol L-1 h(-1)) coupled to minute to hour oxidation/ reduction cycles (of > 100 firiol L-1 amplitude). Finally, calculated atmospheric Hg inputs to the Petit-Saut reservoir represented 14 mot yr(-1) whereas DGM evasion reached 23 mol yr(-1). Apportionment among forms of Hg deposition indicated that up to 75% of the total Hg invasive flux follows the rainfall pathway. (C) 2007 Elsevier B.V. All rights reserved.
Science of The Total Environment (0048-9697) (Elsevier), 2007-10 , Vol. 385 , N. 1-3 , P. 132-145

Droits : 2007 Elsevier B.V. All rights reserved
http://archimer.ifremer.fr/doc/2007/publication-3329.pdf
DOI:10.1016/j.scitotenv.2007.06.013
http://archimer.ifremer.fr/doc/00000/3329/

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Whole-rock concentrations of Se and Te were determined in 53 peridotite samples collected in orogenic bodies from the Eastern Pyrenees, including the Lherz massif (33 samples), the type-locality of Iherzolite. Orogenic Iherzolites tectonically emplaced into the continental crust escaped devolatilisation that may strongly alter concentrations of those volatile trace elements in basalt-hosted peridotite xenoliths. The Se and Te concentration ranges (<3.5-100.7 ppb; <1-11 ppb) are consistent with the few analyses of mantle samples yet available, yet extending to higher Se concentrations. In-situ analyses performed by LAM-ICPMS on base metal sulfides indicate that the Se budget is controlled by sulfides whereas a large fraction of Te (50 +/- 30%) does not reside in sulfides. The missing fraction is accounted for by fractional crystallization of Pt-Pd tellurides from Cu-Ni sulfide melts. A maximum of one third of the S budget of Eastern Pyrenean peridotites was added by assimilation of crustal sulfides, which crystallized as pyrite. Disregarding those contaminated samples, some features of the Se and Te systematics (e.g. bivariate plots vs. fertility index) cannot be explained by partial melting processes. The best fit for 33 peridotites (mostly from Lherz) yields higher than chondritic S/Se (3.1213 +/- 500; r(2) = 0.96) for near chondritic Se/Te (8.6 +/- 2; r(2) = 0.9). Our study suggest that such superchondritic S/Se ratios are better explained by petrogenetic processes involving refertilization of harzburgitic lithosphere by metal (Cu,Ni)-rich sulfide melts precipitated along with clinopyroxene and Al-spinel from silicate melts en-route to the surface.
ISSN: 0009-2541

hal-00544577
https://hal.archives-ouvertes.fr/hal-00544577
DOI : 10.1016/j.chemgeo.2010.09.007

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We report concentrations of hydrogen (H) in upper mantle minerals of peridotites (olivine and pyroxenes) transported by alnöitic lavas, which erupted on the southwestern border of the Ontong Java Plateau (Malaita, Solomon Islands, West Pacific). Unpolarized FTIR analyses show that olivine, orthopyroxene, and diopside contain 2–32 ppm, 162–362 ppm and 159–459 ppm wt H2O, respectively. In the studied lherzolites, garnets are anhydrous. The concentration of hydrogen within individual olivine and pyroxene grains is almost homogeneous, indicating no evidence of dehydration or hydration by ionic diffusion. In the lherzolite, the concentration of hydrogen in olivine tends to increase weakly with depth (based on geothermobarometry), consistent with the increase of water solubility with increasing water fugacity as a function of pressure, but concentrations remain well below water-saturation values determined experimentally. The highest concentration of H in olivine (32 ppm wt H2O) is, however, found in refractory spinel harzburgites, which equilibrated at depths of 85 km., while deeper specimens as the high-temperature spinel harzburgites, and some of the garnet lherzolites, contain less hydrogen in olivine. Olivines from pyroxene- or pargasite-rich peridotites have also lower hydrogen concentrations. We interpret the high hydrogen concentrations in olivine from the refractory spinel harzburgites as due to (1) simultaneous hydration and metasomatism of the lithospheric mantle by a water-rich silicate melt/fluid, during which hydrogen follows MREE and where spinel harzburgite have experienced ‘stealth’ metasomatism, and/or (2) to a late ‘fleeting’ hydrogen metasomatism, which would hydrate the rock after this first ‘stealth’ metasomatism event. In the second case, the composition of the ‘fleeting’ percolating fluid (small volume fraction of very evolved fluids, with high volatiles concentration and transient properties) is likely to be linked to the decrease of the plume activity and resulting in the downwelling of the lithosphere asthenosphere boundary. The difference in hydrogen concentration between harzburgites and lherzolites could be linked to variation in trace elements in olivine induced by the first ‘stealth’ metasomatism alone or associated to the late ‘fleeting’ hydrogen metasomatism, triggered by the lack of secondary crystallization of clinopyroxenes in the harzburgite. To conclude, H concentrations in upper mantle minerals may thus be correlated to metasomatic events, with the later yielding variation of the mineral assemblage and trace element composition that constitute the peridotites.
ISSN: 0024-4937

hal-01143385
https://hal.archives-ouvertes.fr/hal-01143385
DOI : 10.1016/j.lithos.2014.11.005

Éditeur(s) : Elsevier
Résumé : Phosphorus forms with respect to sediment characteristics, such as grain-size, and major chemical elements, were studied in French coastal marine areas (the Bay of Seine and the Loire and Gironde Estuaries).In the three areas, Fe/Al-bound phosphate (Fe/Al-P) and exchangeable phosphate (exch-P) were significantly related to the proportion of fine fraction (< 63 mum). The special association of these forms with fine particles, as well as the relationships between exch-P, Fe/Al-P and Fe showed that adsorption processes on Fe oxides had taken place. However, for similar Fe concentrations, Bay of Seine sediments showed Fe/Al-P concentrations which were four to five times higher than those found in the Loire and Gironde Estuaries. This was attributed to differences in sediment nature and processes in these two types of areas. Indeed, the Loire and Gironde Estuaries frequently show hypoxia.Calcium-bound phosphate (Ca-P) was found in all grain size classes with comparable concentrations in the Bay of Seine where there was no correlation between Ca-P and Ca. This corresponded to the calcium's marine origin (shells) in the Bay of Seine. In contrast, the correlation of Ca-P with Ca and the fine fraction of the sediment in the Loire and Gironde Estuaries was characteristic of the predominant metamorphic origin of Ca-P in these areas.Useful information for interpretation of P-forms can be obtained from major sediment characteristics. Thus, for areas where specific relationships have previously been established good estimates of P-forms could be predicted from sediment properties.
Estuarine, Coastal and Shelf Science (0272-7714) (Elsevier), 2001-05 , Vol. 52 , N. 5 , P. 617-629

Droits : 2001 Academic Press. All rights reserved
http://archimer.ifremer.fr/doc/2001/publication-469.pdf
DOI:10.1006/ecss.2001.0766
http://archimer.ifremer.fr/doc/00000/469/

Éditeur(s) : National Shellfisheries Association
Résumé : The subcellular fractionation of the digestive gland cells of the common cuttlefish Sepia officinalis was performed to investigate the distribution of metals between organelles and cytosol and the different cytosolic fractions separated by gel-filtration chromatography. Total metal concentrations vary over 3 orders of magnitude, ranging from dwt for Pb to dwt for Zn. With the exception of Cd, Co, and Cu, metals were mostly bound to the organelles. Whereas no specific organelle compartment was found for Mn, Ph, and Zn, Fe was mainly associated with nucleus, brown body, and "boule" fraction (i.e., 52%) and 44% of the total Ag was contained in the lysosomal and mitochondria enriched fraction. The link of metals with hydrosoluble proteins in the cytosolic fraction was investigated at 254 and 280 not. Direct relationship between cytosolic metal and metallothioneins could only be established for Ag and Cu, whereas Cd and Zn seem to mainly bind high (> 70 kDa) and low (< 4 kDa) molecular weight proteins.
The Journal of Shellfish Research (0730-8000) (National Shellfisheries Association), 2006-12 , Vol. 25 , N. 3 , P. 987-993

Droits : 2006 NSA
http://archimer.ifremer.fr/doc/2006/publication-2532.pdf
http://archimer.ifremer.fr/doc/00000/2532/

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Orogenic lherzolites exhibit a specific (although reproducible) platinum-group element signature characterized by slight positive deviations of Pd/Ir, Rh/Ir and Ru/Ir ratios from the canonical chondritic model. Such a signature was alternatively considered to be a compositional feature of the primitive upper mantle or resulting from sulfide melt addition by refertilisation reactions in the continental lithosphere. To shed additional light on this conundrum, the distribution of PGE in FON B 93, an unserpentinized, fertile (3.24% Al2O3) orogenic lherzolite (French Pyrenees) used as in-house standard by our group, has been studied to different scales, from the bulk rock to trace minerals. In addition to new ICPMS analyses after separation into Nis and Te coprecipitation, its whole-rock PGE concentrations were redetermined by three different laboratories using very precise ID-ICP-MS methods after digestion of the sample in Carius tube at T=250 degrees C and 320 degrees C or in high-pressure asher (HPA-S). The four methods produce reproducible Ru, Rh and Pd contents (7.1 +/- 0.18 ppb; 1.43 +/- 0.05 ppb; 7.1 +/- 0.30 ppb) whereas the non-ID NiS-fire assay method underestimates the Os and Ir concentrations by c.a. 10 and 15% compared to ID-ICP-MS analyses (4.40 +/- 0.07 and 4.00 +/- 0.17 ppb, respectively). Platinum was the most difficult to analyse. If performed on powder aliquots smaller than 3 g, the ID-ICP-MS analyses generate strong nugget effects while the non-ID NiS-fire assay method yields statistically lower (but highly reproducible) Pt concentrations (6.92 +/- 0.26 ppb). These features reflect the strong partitioning of Pt into trace phases that SEM and laser ablation-ICP-MS analyses on thin sections identify as both high-temperature Pt-Ir-Os alloys and Pt-(Pd) tellurides of likely subsolidus origin; ten to fifteen grains ranging in maximum dimension from a few micrometres to a few hundreds of nanometers, were identified by standard polished thin section. LA-ICP-MS data on base metal sulfides (25 grains analysed), coupled with the whole-rock S concentration (277 +/- 10 ppm) and modal composition of the BMS (90% pentlandite+accessory pyrite and secondary pyrrhotite + 10% chalcopyrite) allowed the contribution of the BMS phase to the PGE budget of FON B 93 to be estimated. Except Pt that exhibits a 95% deficit in the BMS phase, the PGE concentrations measured by ID-ICP-MS can be balanced by BMS while Al-spinel is a negligible contributor, accounting for less than 0.5% of the Ru budget. The occurrence of Pt in trace phases may bias the whole-rock Pt concentrations because 1) mechanical collection of Pt-rich trace phases remains problematic with the Nis button, and 2) Pt-Ir-Os alloys may be prone to digestion problems in conventional Carius tube procedures. Since they could be stable at mantle depth, such refractory alloys that contain Os and Ir may also have enhanced the heavy PGEs/light PGEs fractionation. Our observations likely pertain to orogenic lherzolites as a whole because BMS assemblages in these mantle rocks record evolution at low sulfur fugacity, which prevents Pt-Ir-Os alloy from entering the Mss in the mantle; moreover, at subsolidus temperature, pentlandite, the major BMS, cannot accommodate 0 valence state Pt.
ISSN: 0009-2541

hal-00411486
https://hal.archives-ouvertes.fr/hal-00411486
DOI : 10.1016/j.chemgeo.2007.06.030

Éditeur(s) : ACH : Association of Caribbean Historians
Extrait de : 46e colloque de l'Association des historiens de la Caraïbe, du 11 au 15 mai 2014.
Description : Les cubaines noires ont utilisé une variété de stratégies dans leur quête de réforme, de stabilité financière et sociale et d'égalité politique pendant l'ère républicaine (1902-1958). Cette communication étudie le militantisme politique des femmes noires, en se concentrant sur la façon dont la dynamique de classe façonnent leurs stratégies de résistance.
Siècle(s) traité(s) : 20
Droits : CC-BY-NC-ND - Attribution - Pas d'utilisation commerciale - Pas de modification
Permalien : http://www.manioc.org/fichiers/V15008
V15008

Éditeur(s) : HAL CCSD MDPI AG, Basel, Switzerland
Résumé : International audience
Abstract View references (46)This work shows the preparation of silica membranes by a two-step sol-gel method using tetraethyl orthosilicate in ethanolic solution by employing nitric acid and ammonia as co-catalysts. The sols prepared in pH 6 resulted in the lowest concentration of silanol (Si-OH) species to improve hydrostability and the optimized conditions for film coating. The membrane was tested to desalinate 0.3-15 wt % synthetic sodium chloride (NaCl) solutions at a feed temperature of 22 °C followed by long term membrane performance of up to 250 h in 3.5 wt % NaCl solution. Results show that the water flux (and salt rejection) decrease with increasing salt concentration delivering an average value of 9.5 kg m-2 h-1 (99.6%) and 1.55 kg m-2 h-1 (89.2%) from the 0.3 and 15 wt % saline feed solutions, respectively. Furthermore, the permeate salt concentration was measured to be less than 600 ppm for testing conditions up to 5 wt % saline feed solutions, achieving below the recommended standard for potable water. Long term stability shows that the membrane performance in water flux was stable for up to 150 h, and slightly reduced from thereon, possibly due to the blockage of large hydrated ions in the micropore constrictions of the silica matrix. However, the integrity of the silica matrix was not affected by the long term testing as excellent salt rejection of >99% was maintained for over 250 h. © 2013 by the authors; licensee MDPI, Basel, Switzerland.
ISSN: 2077-0375

hal-01683203
https://hal.univ-antilles.fr/hal-01683203
DOI : 10.3390/membranes3030136

Éditeur(s) : HAL CCSD
Résumé : International audience
BACKGROUND: Several studies suggest that exposure to organophosphate insecticides (OP) during pregnancy impairs neurodevelopment in children. OBJECTIVES: We evaluated associations between biomarkers of prenatal and postnatal OP exposure and cognitive function of 6-year-olds in a French longitudinal birth cohort. METHODS: In 2002-2006, the PELAGIE mother-child cohort enrolled pregnant women from Brittany. For a random subcohort, we measured nonspecific dialkylphosphate metabolites (DAP) of OP in one maternal urine sample, collected before 19 weeks' gestation, and in one urine sample collected from their 6-year-old children. Six subtests of the Wechsler Intelligence Scale for Children-4th edition (WISC-IV) was administered at 6 years to evaluate cognitive function (n=231). Linear regression models controlling for factors including maternal intelligence and the Home Observation for Measurement of the Environment score were used. RESULTS: WISC-IV scores were not significantly associated with prenatal or childhood total DAP metabolites. WISC verbal comprehension score was significantly higher in association with the highest maternal urinary concentrations of diethylphosphate metabolites (DE) (5.5; 95% CI: 0.8, 10.3 for extgreater 13.2 nmol/L versus extlessLOQ), while WISC working memory score was significantly lower in association with the highest urinary concentrations of DE metabolites at age 6 years (-3.6; 95% CI: -7.8, -0.6 for extgreater 11.1 nmol/L versus extlessLOD). CONCLUSION: This study found no evidence that prenatal OP exposure adversely affected cognitive function in 6-year-olds, perhaps because of the higher population's socioeconomic status than in previous studies though other causal and non-causal explanations are also possible. The negative association between WISC score and concurrent DE urinary concentrations requires replication by longitudinal studies investigating childhood OP exposure
Environmental Health Perspectives

hal-01207282
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01207282
DOI : 10.1289/ehp.1409472
PUBMED : 26394442

Éditeur(s) : Université des Antilles. Service commun de la documentation University of Virgin Islands, USA
Extrait de : 52e congrès annuel de la Société caribéenne des plantes alimentaires / 52nd annual meeting of the Caribbean food crops society (CFCS), du 10 au 16 juillet 2016. INRA, CFCS
Description : Limited work has focused on the nutritionally beneficial purple-fleshed sweetpotato in the Caribbean. Purple-fleshed sweetpotatoes are an excellent source of bioflavonoids and antioxidants. Cultivars of purple-fleshed sweetpotato are common in Asia but seldom grown in the west. These Asian cultivars set tuberous roots along the stem length where they root. The objective of this work was to introgress the purple-fleshed characteristic into highly productive early bearing (90-105 days) lines. The purple-fleshed line 'VIP' was used in reciprocal crosses with ?Bonita?, ?Liberty?, ?Mojave? and ?Ruddy?. From hand pollination of these hexaploid plants, 179 seedlings were obtained with a skin color ranging from white to deep burgundy. After the first field trial, 60 were selected for further evaluation based on early tuberous root shape and set, weevil tolerance and soluble sugar content. Continued evaluation will reduce selection down to 20 which further scrutiny to narrow selection to the top five. Le travail limité s'est concentré sur le sweetpotato pourpre-étoffé nutritionnellement salutaire dans les Caraïbe. Les sweetpotatoes Pourpre-étoffés sont une excellente source des bioflavonoïdes et des antioxydants. Les cultivateurs du sweetpotato pourpre-étoffé sont communs en Asie mais sont rarement développés dans l'ouest. Ces cultivateurs asiatiques placent les racines tubéreuses sur la longueur de tige où ils s'enracinent. L'objectif de ce travail était aux introgress que la caractéristique pourpre-étoffée dans la première incidence fortement productive (90-105 jours). La ligne pourpre-étoffée 'VIP' a été employée dans les croix réciproques avec « Bonita », « liberté », « Mojave » et « vermeil ». De la pollinisation de main de ces usines hexaploïdes, 179 jeunes plantes ont été obtenues avec une couleur de la peau s'étendant de blanc à Bourgogne profond. Après le premier essai pratique, 60 ont été sélectionnés pour davantage d'évaluation basée sur la forme tôt et l'ensemble de racine tubéreuse, la tolérance de charançon et le contenu soluble de sucre. L'évaluation continue ramènera la sélection pour avaler à 20 qui promeuvent l'examen minutieux pour rétrécir la sélection aux cinq principaux.
Siècle(s) traité(s) : 21
Droits : CC-BY-NC-ND - Attribution - Pas d'utilisation commerciale - Pas de modification
Permalien : http://www.manioc.org/fichiers/V16265
V16265

Éditeur(s) : Gauthier-Villars
Résumé : The seasonal variations of total dissolved copper were surveyed during one year (1983/1984) in the Aulne estuary (Western Brittany, France), an ecosystem with a high rate of water renewal. Copper in filtered water samples (after and without acidification) was determined after preconcentration on Chelex 100, and the eluates were analyzed by graphite furnace atomic absorption spectroscopy. The concentrations of free and complexed copper were then plotted versus chlorosity. Globally, the total dissolved copper concentrations tend to decrease with salinity. The role of physicochemical parameters such as pH and suspended matter (adsorption-desorption mechanisms) on dissolved copper content is shown to be significant. With a variable intensity, desorption (release) takes place in summer and in autumn, while adsorption is observed at very low chlorosity in winter. The dissolved copper concentrations in the Aulne estuary (0.26 to 2.52-mu-g.l-1, with the highest values in autumn) are similar to most estuarine copper values. The proportion of complexed species ranges from 4 to 69% (average of 27%).
Les variations saisonnières des concentrations en cuivre dissous dans l'estuaire de l'Aulne (Bretagne occidentale) ont été mesurées au cours d'un cycle annuel (1983/1984). Les concentrations en cuivre libre et celles en cuivre complexé ont été suivies séparément en fonction de la chlorosité, un paramètre conservatif. Les profils obtenus pour le cuivre total dissous montrent généralement une décroissance des teneurs en métal des eaux douces aux eaux marines, tout en restant supérieures à celles de la droite théorique de mélange. On montre le rôle fondamental de la variation du pH concomitante de celle de la matière en suspension (mécanisme d'adsorption-désorption) dans l'évolution des teneurs en cuivre dissous. Ce processus agit plus ou moins intensément dans le sens de la désorption (été, automne) ou de l'adsorption (hiver aux faibles chlorosités). Dans l'ensemble, les teneurs en cuivre total dissous (de 0,26 à 2,52 J.lg.l- 1 , les valeurs automnales étant les plus élevées) sont comparables à celles de nombreux autres écosystèmes estuariens, avec un taux de complexation compris entre 4 et 69% (moyenne de 27% ).
Oceanologica Acta (0399-1784) (Gauthier-Villars), 1991 , Vol. 14 , N. 5 , P. 445-457

Droits : Gauthier-Villars
http://archimer.ifremer.fr/doc/00103/21377/18977.pdf
http://archimer.ifremer.fr/doc/00103/21377/43066.pdf
http://archimer.ifremer.fr/doc/00103/21377/

Éditeur(s) : Yale University
Résumé : Sea-surface temperature images of the coastal upwelling regions off Northwest Africa show that the core of upwelling is sometimes located far from the coast. This has been documented in three regions that share a common feature, namely a wide and shallow continental shelf. This upwelling feature plays a key role in the ecology of the Canary Current System. It creates an innerfront which provides retention for biological material, e.g. fish eggs and larvae, in the highly productive nearshore environment. An analytical model has been developed based on a two dimensional extension of Ekman's solution. The linear and steady response of a homogeneous ocean forced by an upwelling-favorable wind provides a mechanism for the upwelling separation from the coast. The merging of the surface and bottom Ekman layers induces a very weak cross-shore circulation and a "kinematic barrier" for the Ekman transport divergence. In the case of an alongshore wind, the barrier is located near the isobath h ≈ 0.4D, where D is the thickness of Ekman layers. This yields an upwelling cell which is essentially concentrated in the region 0.5D < h < 1.25D, with upwelling occurring preferentially near the isobath h ≈ 0.6D. It turns out that the cross-shore width of upwelling scales with D/S, the ratio of Ekman depth to bottom topographic slope. The application of this solution to real bathymetric profiles rationalizes, not only the offshore upwelling observations in Northwest Africa, but also the influence of topography on the cross-shelf structure of a wind-driven coastal upwelling. The model also quantifies the effect of the cross-shore wind component showing how it drives the nearshore pressure gradient adjustment and how it affects the upwelling. A linear numerical experiment reproduces the theoretical steady solution, thereby allowing investigation of the transient regime. Relaxation of the hypothesis in the numerical model validates the linear assumption of the theory and then allows investigation of the sensitivity to friction parameterizations and the influence of stratification. The latter leads to an "oscillation" of the upwelling cell with seaward migration driven by outcropping and homogeneization of the water column, and, coastal incursion driven by a "boundary layers splitting" process caused by shoreward advection of the isopycnal dome and stratification of the inner shelf.
Journal of Marine Research (Yale University), 2008-09 , Vol. 66 , N. 5 , P. 589-616

Droits : 2008 Yale University
http://archimer.ifremer.fr/doc/2008/publication-6334.pdf
DOI:10.1357/002224008787536790
http://archimer.ifremer.fr/doc/00000/6334/

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Different household insecticide applications via two electric vaporizers emitting transfluthrin were realized in a full-scale experimental room under controlled air exchange rate conditions. On-line high-time resolved measurements of the gas-phase concentrations of the active substance during and immediately after the spreading periods were performed with a High Sensitivity Proton-Transfer-Reaction Mass Spectrometer (HS-PTR-MS). Experimental and modelled data from the ConsExpo 4.0 software were also compared to evaluate the sources of differences. Different application scenarios were also compared. Averaged inhaled concentrations over 1h, 1week, and 5months were estimated to be 8.3, 1.8, and 1.8μg.m(-3), respectively. Corresponding margins of exposures range from 1000 to 10,000, claiming for the absence of effect. Dermal and dust ingestion pathways, although roughly estimated, seems being non-negligible. This claims for a more in-depth integrated risk assessment.
ISSN: 0160-4120

hal-00875320
https://hal-univ-rennes1.archives-ouvertes.fr/hal-00875320
https://hal-univ-rennes1.archives-ouvertes.fr/hal-00875320/document
https://hal-univ-rennes1.archives-ouvertes.fr/hal-00875320/file/Transfluthrin-indoor-accepted.pdf
DOI : 10.1016/j.envint.2013.07.011

Éditeur(s) : Université des Antilles Études caribéennes
Résumé : Le secteur du tourisme et des services s’est imposé comme le véritable moteur des économies insulaires de la Caraïbe depuis la fin des années 1980, décennie. Dans ces territoires confrontés à la crise des traditionnelles économies de plantations, le tourisme a pris une importance considérable (19,2 milliards de dollars US pour une croissance moyenne annuelle de 7 % depuis 1990). Cependant les modalités du développement touristique actuelles ne sont pas sans poser certains problèmes d’ordre économique (faiblesses des retombées locales) et environnemental (concentration des flux). Les territoires de la Caraïbe insulaire développent de nouvelles stratégies touristiques autour de l’écotourisme
Tourism has become the driving force of the island economies of the Caribbean basin since the latter part of the 1980s. Within this island realm, the traditional plantation economies have gone through an economic crisis while tourism. On the other hand, has taken on considerable importance (19.2 billion dollars and a 7% annual growth rate since 1990. Nevertheless this growth has not been without its economic problems (a low level of local linkages) and environmental (concentration of tourist flows). Caribbean island tourism is now concentrating its efforts on developing new strategies based on ecotourism perspectives. Tourism, ecotourism and development strategies in the Caribbean.
Caraïbes

Droits : info:eu-repo/semantics/openAccess
urn:doi:10.4000/etudescaribeennes.3383
http://journals.openedition.org/etudescaribeennes/3383

Éditeur(s) : HAL CCSD
Résumé : International audience
Previous studies have reported respiratory, cardiac and muscle changes at rest in triathletes 24 h after completion of the event. To examine the effects of these changes on metabolic and cardioventilatory variables during exercise, eight male triathletes of mean age 21.1 (SD 2.5) years (range 17-26 years) performed an incremental cycle exercise test (IET) before (pre) and the day after (post) an official classic triathlon (1.5-km swimming, 40-km cycling and 10-km running). The IET was performed using an electromagnetic cycle ergometer. Ventilatory data were collected every minute using a breath-by-breath automated system and included minute ventilation (V(E)), oxygen uptake (VO2), carbon dioxide production (VCO2), respiratory exchange ratio, ventilatory equivalent for oxygen (V(E)/VO2) and for carbon dioxide (V(E)/VCO2), breathing frequency and tidal volume. Heart rate (HR) was monitored using an electrocardiogram. The oxygen pulse was calculated as VO2/HR. Arterialized blood was collected every 2 min throughout IET and the recovery period, and lactate concentration was measured using an enzymatic method. Maximal oxygen uptake (VO2max) was determined using conventional criteria. Ventilatory threshold (VT) was determined using the V-slope method formulated earlier. Cardioventilatory variables were studied during the test, at the point when the subject felt exhausted and during recovery. Results indicated no significant differences (P > 0.05) in VO2max [62.6 (SD 5.9) vs 64.6 (SD 4.8) ml x kg(-1) x min(-1)], VT [2368 (SD 258) vs 2477 (SD 352) ml x min(-1)] and time courses of VO2 between the pre- versus post-triathlon sessions. In contrast, the time courses of HR and blood lactate concentration reached significantly higher values (P < 0.05) in the pre-triathlon session. We concluded that these triathletes when tested 24 h after a classic triathlon displayed their pre-event aerobic exercise capacity, bud did not recover pretriathlon time courses in HR or blood lactate concentration.
EUROPEAN JOURNAL OF APPLIED PHYSIOLOGY

hal-00720432
https://hal.univ-antilles.fr/hal-00720432
https://hal.univ-antilles.fr/hal-00720432/document
https://hal.univ-antilles.fr/hal-00720432/file/Article_2.pdf

Éditeur(s) : HAL CCSD
Résumé :   Diplôme : DEA
il s'agit d'un type de produit dont les métadonnées ne correspondent pas aux métadonnées attendues dans les autres types de produit : DISSERTATION
Links between architectural stages of development (ASD), photosynthetic capacities and leaf characteristics in Tachigali melinonii (Caesalpiniaceae) were investigated in the tropical forest of French Guiana. Three ASD were sampled under three light conditions to elucidate the impact of ASD- and light-related changes on photosynthetic functional traits. Photosynthetic parameters (maximum rate in RubisCO carboxylation (Vcmax) and maximum rate of electron transport (Jmax) were estimated by adjusting a biochemical model (Farquhar et al., 1980) to response curves of CO2 assimilation rate to intercellular CO2 concentration, under saturated light. In addition, N and C foliar concentrations were analysed and N allocations to the carboxylation and bioenergetic processus of photosynthesis were calculated using the model of Niinemets and Tenhunen (1997). The variations in ecophysiological parameters observed were due to leaf anatomical and structural changes instead of changes in photosynthetic components, suggesting adjustments to light conditions. Tachigali melinonii thus appears to display morphological and anatomical plasticity at different ASDs and under different light conditions.
Une espèce forestière de Guyane Française, Tachigali melinonii (Caesalipiniaceae), a été choisie afin de regarder la variation des traits fonctionnels relatifs à la photosynthèse en fonction de la disponibilité en lumière et en fonction de son stade de développement architectural. Du fait du tempérament de l'espèce vis-à-vis de la lumière de type «struggling gambler» (ombrage nécessaire aux jeunes stades puis développement en pleine lumière), trois stades clefs de développement parmi la séquence de différenciation de l'espèce ainsi que trois environnements lumineux ont été choisis. Les capacités photosynthétiques foliaires ont été estimées à partir de l'ajustement de paramètres du modèle biochimique de photosynthèse foliaire (Farquhar et al. 1980) sur des courbes de réponses de l'assimilation de CO² (A) à des concentrations intracellulaires en CO² (Ci) croissantes, en condition de lumière saturante. La vitesse maximale de carboxylation Vcmax et le flux maximal d'électrons photosynthétiques Jmax ont ainsi été estimés et ensuite reliés aux caractéristiques structurales foliaires, notamment la concentration en azote, en carbone ainsi qu'avec la densité et l’épaisseur. Les fractions d'azote allouées aux processus photosynthétiques de carboxylation et de bioénergétique ont été calculées. Des variations, dues à un effet du stade de développement sur les paramètres étudiés ainsi qu’à un effet de la quantité de lumière disponible, ont été constatées. Ces variations sont surtout liées à des ajustements anatomiques et structuraux foliaires et non à des modifications de l’appareil photosynthétique. Tachigali melinonii semble donc modifier ses caractéristiques structurales foliaires en fonction de son stade de développement, ce qui suppose un contrôle ontogénique partiel, et en fonction de la disponibilité en lumière.
https://hal.archives-ouvertes.fr/hal-01189520

hal-01189520
https://hal.archives-ouvertes.fr/hal-01189520
PRODINRA : 44951

Éditeur(s) : Elsevier
Résumé : We studied the effects of a lactic acid bacterium, Pediococcus acidilactici (strain MA 18/5M, CNCM), as a dietary probiotic on growth performance and some nutritional and microbiological aspects of the shrimp Litopenaeus stylirostris. Experimental shrimp culture was carried out over 10 weeks, using floating cages of 14 m(2) each set in earthen ponds, in a New Caledonia farm affected by "Summer syndrome", a septicaemic vibriosis caused by Vibrio nigripulchritudo. The experiment design testing probiotic-coated pellets against control was replicated in two earthen ponds. High mortalities, characteristic of Summer syndrome, were observed during the first 2 weeks of the trial. The probiotic improved production in the treated cages from both ponds with increases in the survival rate (7% and 15% respectively) and final biomass (8% and 12% respectively). No differences were recorded among treatments on growth performances, but significant lower food conversion ratios were obtained with probiotic treatment. After 5 weeks of rearing, the Hepatosomatic Index and the adjusted dry weight of the digestive gland were significantly increased by 10% and by 9% respectively in shrimps treated with probiotic. In the meantime, the specific activities of alpha amylase and trypsin in the digestive gland showed a significant effect of the probiotic treatment with respective increases by 35% and 55%. The rise in total trypsin activity following morning feeding was also enhanced by the probiotic treatment (P < 0.001). The highest concentration of probiotic (between 10(4)-10(5) CFU g(-1) of fresh gut) in the shrimp gut was obtained 2 h after feeding. The concentration remained high for 4 h after feeding before decreasing until the next meal. Total bacterial counts on Marine agar and TCBS in the gut were significantly lowered by the probiotic treatment over the 10 weeks of the experiment. Additionally, during the first 2 weeks, prevalence and load of V nigripulchritudo strains in haemolymph was lower in animals fed with the probiotic diet. This study demonstrated, under pond conditions, that feeding shrimp with live terrestrial lactic acid bacteria can be an effective treatment for improving shrimp culture affected by vibriosis. (c) 2008 Elsevier B.V. All rights reserved.
Aquaculture (0044-8486) (Elsevier), 2008-03 , Vol. 275 , N. 1-4 , P. 182-193

Droits : 2008 Elsevier B.V. All rights reserved.
http://archimer.ifremer.fr/doc/2008/publication-4079.pdf
DOI:10.1016/j.aquaculture.2008.01.011
http://archimer.ifremer.fr/doc/00000/4079/

Éditeur(s) : HAL CCSD
Résumé : During the course of their life cycle organisms are exposed to natural environment variations capable of inducing physiological, morphological and behaviour changes, thus a phenotypic plasticity. Phenotypic plasticity is the ability of a genotype to generate a new phenotype following exogeneous or endogeneous stress. Here, we investigated the phenotypic plasticity of the non-calcifying symbiotic cnidarian Anemonia viridis at multiple levels of structural complexity, in vivo and in vitro. In vivo, we determined the mechanisms behind the phenotypic plasticity under expected future climate change (i.e. ocean acidification and ocean warming). Our results show physiological changes in the inorganic carbon use of the sea anemone A. viridis exposed to high pCO2 during a long-term stress in natura or a short-term stress in controlled conditions. We then observed an equivalent decrease in carbonic anhydrase activity, a key enzyme of cnidarian carbon concentrating mechanisms. Also, we demonstrated that an increase in seawater temperature modified the response observed during a high pCO2 scenario. In vitro, we established a viable primary cell culture from regenerating tentacles of A. viridis. We determined the gastrodermal tissue origin of the cultivated cells and validated the use of this new tool to the in vitro study of stress response at the cellular level. The set-up of this powerful in vitro tool will open a multitude of perspectives for the study of cellular responses to exogeneous stress (as global change perturbations) and to endogeneous stress (as the symbiosis constraints experienced by symbiotic cnidarians)
Durant leur cycle de vie, les organismes sont exposés à des variations environnementales capables d'induire des changements physiologiques, morphologiques et comportementaux, résultant d’une plasticité phénotypique. La plasticité phénotypique est la capacité d'un génotype à générer un nouveau phénotype suite à un stress. Ici, nous avons étudié la plasticité phénotypique d’un Cnidaire symbiotique et non-calcifiant, l’anémone de mer Anemonia viridis, à de multiples niveaux de complexité structurale, in vivo et in vitro. In vivo, nous avons identifié les mécanismes sous-jacents de la plasticité phénotypique potentiellement induits par les futurs changements climatiques (acidification et réchauffement des océans). Nos résultats montrent des modifications dans l'utilisation du carbone inorganique par A. viridis exposée à une forte pCO2 lors d’un stress chronique in natura ou lors d’un stress court en conditions contrôlées. Nous avons ainsi observé une diminution des activités anhydrase carbonique, une enzyme clé des mécanismes de concentration du carbone chez les Cnidaires. Nous avons aussi démontré que l'augmentation concomittante de la température modifie la réponse observée lors d'une élévation seule de la pCO2. In vitro, nous avons établi une culture de cellules primaires viables issue de tentacules d’A. viridis en régénération. Nous avons déterminé l'origine gastrodermale des cellules cultivées et validé l'utilisation de ce nouvel outil pour l'étude de la réponse au stress au niveau cellulaire. Ce nouvel outil ouvre une multitude de perspectives pour l'étude des réponses cellulaires aux stress exogènes (changement climatique) et endogènes (contraintes dues à la symbiose)
https://tel.archives-ouvertes.fr/tel-01674220

Droits : info:eu-repo/semantics/OpenAccess
NNT : 2016AZUR4136
tel-01674220
https://tel.archives-ouvertes.fr/tel-01674220
https://tel.archives-ouvertes.fr/tel-01674220/document
https://tel.archives-ouvertes.fr/tel-01674220/file/2016AZUR4136.pdf

Éditeur(s) : HAL CCSD American Physiological Society
Résumé : Full text: http://jn.physiology.org/content/88/3/1475
International audience
The contribution of voltage-gated calcium channels (VGCC) to the development of cultured embryonic cockroach brain neurons was assessed using pharmacological agents. VGCC currents were recorded using the patch-clamp technique and were found to be blocked dose-dependently by micromolar concentrations of mibefradil. The activation and inactivation properties of the calcium channels enable a sizeable calcium current to flow at rest (about -30 and -20 mV in high-potassium culture media). As expected, the cytoplasmic-free calcium concentration was found to rise when the extracellular potassium concentration was raised from 3 to 15 and 30 mM. The effects of VGCC blockers and calcium chelators were different in fresh and in mature cultures in which the neurons were connected to each other to form a defined network. In fresh cultures, the two non-selective VGCC blockers (verapamil and mibefradil) induced a dose-dependent cell death that was proportional to their blocking effect on I(Ba). This effect could not be prevented by addition of fetal calf serum to the culture medium. A similar effect was obtained using intra- or extracellular calcium chelating agents (10 microM BAPTA-AM or 10 mM EGTA). Quite unexpectedly, blockade of the P/Q-like (omega-Aga WA-sensitive) component of the calcium current by 500 nM of omega-AgaTx IVA had no lethal effect, suggesting that the corresponding channels are not involved in the survival mechanism. As expected from their lack of effect on I(Ba), isradipine, nifedipine, and omega-CgTx GVIA did not induce cell death. When the neurons started growing neurites, their sensitivity to calcium channel blockade by mibefradil decreased, indicating a correlation between neurite outgrowth and resistance to calcium depletion. In mature cultures, the neurons became resistant to mibefradil, verapamil, and BAPTA-AM. However, these agents, as well as omega-AgaTx IVA, had a significant inhibitory effect on the increase in diameter of the connectives that linked adjacent clusters of neurons. This effect has been shown to result, in the case of mibefradil, from an inhibition of neurite outgrowth characterized by a significant reduction of the number of primary neurites and secondary branchings but not to a significant modification of the diameter of individual neurites. These results support the view that, as in vertebrates, calcium influx through VGCC plays an important role in survival and neurite outgrowth of cultured embryonic insect neurons. The differential contribution of the P/Q-like and R-like (omega-Aga WA-sensitive) calcium channels in these processes is discussed.
ISSN: 0022-3077

hal-00982287
https://hal.archives-ouvertes.fr/hal-00982287
DOI : 10.1152/jn.00749.2001
PUBMED : 12205168