Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Understanding long-term variability in the frequency of intense storm activity is important for assessing whether changes are controlled by climate evolution. Understanding this variability is also important for predicting present and future community vulnerability and economic loss. Our ability to make these assessments has been limited by the short (less than 50 years) instrument record of storm activity. Storm-induced deposits preserved in the sediments of coastal lagoons offer the opportunity to study the links between climatic conditions and storm activity on longer timescales. In this study, we present a record of these extreme climatic events that have occurred in the French Mediterrannean coast over the past 1500 years. The identification of these extreme events is based on the analysis of sediment cores from Gulf of Aigues-Mortes lagoons that contain a specific sedimentary and geochemical signature associated with intense storms.;Overwash deposits do not show any evidence of intense storm landfalls in the region for several hundred years prior to the late 17th century A.D. The apparent increase in intense storms around 250 years ago occurs during the latter half of the Little Ice Age, a time of lower continental surface temperatures. Comparison of the sediment record with palaeoclimate records indicates that this variability was probably modulated by atmospheric dynamics. The apparent increase of the superstorm activity during the latter half of the Little Ice Age was probably due to the thermal gradient increase leading to enhanced lower tropospheric baroclinicity over a large Central Atlantic/European domain and leading to a modification of the occurrence of extreme wind events along the French Mediterranean coast. A complete understanding of the relationship between climate fluctuations, storm activity, and the coastal response will be crucial to predicting the impacts of future climate change.
ISSN: 0031-0182

hal-00617525
https://hal.archives-ouvertes.fr/hal-00617525
DOI : 10.1016/j.palaeo.2010.11.009

Éditeur(s) : HAL CCSD Société géologique de France
Résumé : In the eastern Pyrenees, the lherzolites always outcrop as restricted bodies scattered across Mesozoic sedimentary units along the North Pyrenean fault. In this article, we focus on the sedimentary processes associated with the tectonic exhumation of the mantle rocks during the Lower Cretaceous and we provide a new detailed analysis of the ultramafic-bearing sedimentary sequences associated with the Lherz body. The Lherz body, 1.5 km long only, belongs to a series of ultramafic bodies of restricted size (a few m to some hundred of m), occurring within sedimentary formations composed mostly of carbonate breccias originating from the reworking of Mesozoic platform limestones and dolomites. The carbonate clasts include marbles displaying different evolutions in relation with the Cretaceous thermal metamorphic event. The clastic formations also include numerous layers of polymictic breccias reworking ultramafic clasts. These layers are found far from any peridotitic body, implying that ultramafic clasts have been transported far away from their sources by sedimentary processes after their disaggregation on the seafloor. In addition, clasts of ultramafic-rich breccias and sandstones are also observed which indicates rapid sedimentation and diagenesis within a tectonically active environment. We discuss the significance of these deposits and their bearing on our understanding of the tectono-sedimentary processes associated with mantle exhumation in a context of development of narrow intracontinental basins suffering extreme crustal thinning.
EISSN: 1777-5817

hal-00766884
https://hal.archives-ouvertes.fr/hal-00766884
DOI : 10.2113/gssgfbull.183.5.443

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Deposit feeders are able to process a considerable volume of sediment, containing large 9 quantities of associated bacteria. However, conclusions concerning the trophic role played by 10 benthic bacteria in marine sediments are still not fully elucidated. This study deals with 11 bacterivory by the gastropod Hydrobia ulvae, one of the most abundant deposit-feeding 12 species in intertidal mudflats in Western Europe. Ingestion rates of bacteria were determined 13 during grazing experiments using 15 N pre-enriched bacteria. Grazing experiments were 14 performed in order to measure effects of abiotic (temperature, salinity and luminosity) and 15 biotic (bacterial and algal abundances) factors on ingestion rates of bacteria by H. ulvae of an 16 intertidal mudflat (Brouage, Marennes-Oléron, France). The mean ingestion rate of bacteria 17 by H. ulvae was 1149 ngC ind-1 h-1. The general trend showed a temperature effect with an 18 optimum around 30°C, and the assimilation rate was significantly lower at 5°C. Bacterial 19 assimilation did not significantly differ between salinity 18 and salinity 31. Ingestion was the 20 same in light and in dark conditions. Results were compared with those of other grazing 21 experiments conducted simultaneously in similar conditions with two other grazers with 22 different size and feeding modes: the foraminifera Ammonia tepida and a nematode 23 community from the superficial sediment of the Brouage mudflat. Hydrobia ulvae and 24 nematodes presented a feeding behavior less influenced by environmental changes than A. tepida. Hydrobia ulvae ingested bacteria at a higher rate than smaller meiofaunal grazers and seemed to have a lower ability to selectively ingest diatoms than meiofaunal grazers.
ISSN: 1385-1101

hal-01248039
https://hal.archives-ouvertes.fr/hal-01248039
https://hal.archives-ouvertes.fr/hal-01248039/document
https://hal.archives-ouvertes.fr/hal-01248039/file/Pascal%20et%20al%202008.pdf
DOI : 10.1016/j.seares.2008.05.003

Éditeur(s) : HAL CCSD Société géologique de France
Résumé : A study combining very high resolution seismic and sediment core data has been carried out on the Thau lagoon (Mediterranean coast, microtidal setting, SE France) in order to understand more clearly the dynamics and Holocene chronology of its closure through the different stages of its filling. One main seismic unit (U2) has been defined into the infill, above the rocky basement (U0) and a composite unit U1, which is interpreted as remnants of Pleistocene fluvial terraces or/and to early marine Holocene deposits. Unit U2, that reaches locally 9 m in thickness, rests conformably on U1 in the central part of the lagoon and onlaps U0 or U1 close to the edge of the lagoon. It is divided in two sub-units, U2-1 and U2-2. U2-2 rests paraconformably on U2-1 in the central part of the lagoon where the infill is the thickest, while a marked erosional unconformity is observed between U2-1 and U2-2 on topographic highs of the basement and on the seaward edge of the lagoon. A total of seven elementary sequences have been observed in U2-1 and U2-2.;According to core data, U2 consists in a series of mud-dominated sequences, with shell fragments dispersed at the base. The vertical distribution of the fauna into U2-1 and U2-2 reveals a lagoonal environment. However in U2-1, marine species are more abundant in the south of the lagoon. C-14 AMS dating provides three ages: similar to 6000 cal yr B.P. in the lower part of U2-1 on CAL1, 5400 cal yr B.P. just above the boundary between U2-1 and U2-2 on CAL4, similar to 3000 cal yr B.P. in the middle of U2-2 on CAL4.;A scenario to explain the lagoon infill stratigraphy and geometry is proposed. The beginning of the lagoon infill occurred with the initiation of the barrier construction, as soon as the sea-level rise slowed down significantly, i.e. between 7000-6000 yr B.P. The sediment-fill began into the back-barrier system, with a high rate of sedimentation for U2-1, according to the radiocarbon data. At 5400 yr B.P., the barrier is assumed to be totally closed leading to the deposition of the fully lagoonal U2-2 succession. The unconformity between U2-1 and U2-2 is interpreted as the result of a rapid landward retreat of the barrier. This severe retreat could be related to climate forcing and/or brutal change in sediment discharge driven by the Rhone River, which is the main sediment source of the longshore drift. In this scenario, the last sub-unit, U2-2, represents most of the late Holocene infill. In this framework, the elementary sequences observed in U2-2 could be related to high frequency climate changes of about 1000-1500 years periodicity according to C-14 dates.
EISSN: 1777-5817

hal-00486386
https://hal.archives-ouvertes.fr/hal-00486386
DOI : 10.2113/gssgfbull.181.2.197

Éditeur(s) : HAL CCSD Wiley-Blackwell
Résumé : International audience
Associations between marine invertebrates and chemoautotrophic bacteria constitute a wide field for the study of symbiotic associations. In these interactions, symbiont transmission must represent the cornerstone allowing the persistence of the association throughout generations. Within Bivalvia, in families such as Solemyidae or Vesicomyidae, symbiont transmission is undoubtedly vertical. However, in Lucinidae, symbiont transmission is described in the literature as 'environmental', symbionts being acquired from the environment by the new host generations. Hence, if there is transmission, symbionts should be transmitted from adults to juveniles via the environment. Consequently, we should observe a release of the symbiont by adults. We attempted to detect such a release within two Lucinidae species of the genus Codakia. We sampled 10 Codakia orbicularis and 20 Codakia orbiculata distributed in 10 crystallizing dishes containing filtered seawater. During 1 month of investigation, we analyzed water of the dishes in order to detect any release of a symbiont using catalyzed report deposition-FISH techniques. For 140 observations realized during this period, we did not observe any release of symbionts. This suggests that the idea of host-to-host passage in Lucinidae is inaccurate. We could therefore consider that the transmission mode from generation to generation does not occur within Lucinidae, symbiosis appearing to be advantageous in this case only for the host, and constitutes an evolutionary dead-end for the bacteria.
ISSN: 0168-6496

hal-00751560
https://hal.univ-antilles.fr/hal-00751560
DOI : 10.1111/j.1574-6941.2008.00626.x

Éditeur(s) : HAL CCSD Taylor & Francis
Résumé : International audience
The Jurassic Mirdita ophiolite crops out in the western branch of the Hellenide-Dinaride ophiolite belt in the Balkan Peninsula; it represents a remnant of the Tethyan oceanic lithosphere developed between the Apulian and Pelagonian microcontinents. Emplaced during the Cretaceous on the western margin of Pelagonia, the Mirdita ophiolite was involved in southwestward thrusting of the Hellenide-Dinaride tectonic units during the Eocene alpine tectonics. It was little affected, however, by these alpine events as marked by nearly horizontal Cretaceous limestone deposits overlying the ophiolite. A continuous section of Middle Jurassic oceanic crust, including thin gabbros, a N-S-trending sheeted dike complex, and extrusive rocks, is exposed in the central part of the ophiolite and thickens eastward within a regional, N-S-trending synform. Peridotite massifs exposed along the western and eastern edges of this synform show major structural and petrological differences. The eastern ultramafic domain has a harzburgitic mantle exhibiting a high-temperature asthenospheric foliation dipping steeply to moderately to the west. Major chromite deposits are restricted to these eastern ultramafic massifs. The western ultramafic domain has a zoned mantle, with asthenospheric harzburgite exposed at its western margin, progressively replaced eastward by plagioclase-peridotites that were highly strained at low temperatures, and that are bounded by amphibole-peridotites along with crustal rocks. The occurrence of plagioclase is ascribed to melt impregnation processes that occurred immediately before or during intense lithospheric deformation. The gabbros in the eastern massifs are thicker (1-2 km and layered, whereas they are highly thin and discontinuous in the western massifs. Mantle peridotites of the western massifs locally are in direct contact with the overlying diabase and volcanic rocks along ductile shear zones. Development of epidote-amphibolite facies metamorphism in upper-crustal rocks was produced by hydrothermal alteration in the oceanic realm, and was intense and widespread in the western domain. The Mirdita ophiolite likely originated in a short-lived, narrow ocean basin, which was closed during the Middle Jurassic by eastward overthrusting of the western domain, and westward subduction of the eastern domain. This constrictional phase was followed by dextral oblique convergence between the Pelagonian and Apulian microcontinents. This model implies a parautochtonous origin of the Mirdita ophiolite between these two microcontinents.
ISSN: 0020-6814

hal-00456063
https://hal.archives-ouvertes.fr/hal-00456063
DOI : 10.1080/00206810902823982

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Eastern Hoggar is by far the least well known part of the Tuareg Shield. It is composed, from west to east, of the Aouzegueur, Edembo and Djanet Terranes. The Djanet Terrane is the easternmost Hoggar terrane and comprises a greenschist-facies clastic sedimentary sequence, the Djanet Group, intruded by granitoids. Laser ablation (LA-) ICP-MS U-Pb zircon ages of detrital zircons from these sediments yield a large range of ages similar to ages known in Central and Western Hoggar; the youngest is 590 +/- 10 Ma (2 sigma), which is the maximum age of deposition of the Djanet Croup. The Djanet Group is intruded by the Djanet Batholith (571 +/- 16 Ma), by high-level subcircular plutons such as the Tin Bedjane Pluton (568 +/- 5 Ma) and finally by the felsic Tin Amali Dyke Swarm (558 +/- 5 Ma), all ages being SHRIMP U-Pb zircon. The deposition and metamorphism of the Djanet Group thus occurred between 590 Ma (the age of the youngest detrital zircons analyzed in the Djanet Group) and c. 570 Ma (the age of intrusive granitoids). Nd T-DM two-stage model ages (1.30-2.03 Ga), initial Sr-87/Sr-86 ratios (0.7035-0.7095) and epsilon(Nd) (-3 to -11) of the three intrusive suites, all being high-K calc-alkaline in composition, indicate mainly an old, Rb-depleted continental source. Migmatization in the adjacent Edembo Terrane is dated at 568 +/- 4 Ma (U-Pb zircon SHRIMP age), contemporaneous with the intrusion of the Djanet plutons. Rocks and events in the Edembo and Djanet Terranes are all intracontinental. We propose that the Djanet Terrane lies on the boundary of a craton located to the north-east, that we defined here as the Murzuq craton. The existence of the Murzuq craton is supported by sedimentary and geophysical data. We suggest that the deformation of Eastern Hoggar occurred 575-555 Ma, due to the indentation of the Murzuq craton and has no link with the older convergence with the West African craton as was the case for the central and western parts of the Tuareg Shield. This determines a late Ediacaran intracontinental Murzukian event that probably also occurred to the east in the Tibesti area.
ISSN: 0301-9268

hal-00512833
https://hal.archives-ouvertes.fr/hal-00512833
DOI : 10.1016/j.precamres.2010.05.011

Éditeur(s) : HAL CCSD Taylor & Francis
Résumé : The Latest Cretaceous/Paleocene paleokarsts from Bas-Languedoc (South of France) are characterized by : 1) exokarstic paleosurfaces (sink holes, pinnacles, canyons) which are mostly superimposed onto the Late Jurassic limestones and partly filled up with breccias and sandy clays containing Paleocene planktonic foraminifera; 2) endokarstic cavities filled up by sandy pelites and laminated mudstones with similar micropaleontological assemblage. All these cavities constitute three cut-and-filled paleokarstic systems. A general model of formation for this polyphase system is proposed. These paleosurfaces are generated by a Latest Cretaceous tectonic phase and Paleocene movements associated with eustatic rises inducing rapid floodings. During Upper Danian-Lower Selandian times three successive base levels drops, whose cumulated duration could be as long as 3 Ma, have induced several hundred metres of incisions within the exposed Jurassic carbonate series. A paleogeographic reconstruction shows three main marine gulfs which extend towards NE the EW Pyrenean thrust belt ("Pyrenean Paleocene Trough", PPT) located on the axis of the future Pyrenees. The similarity of the facies and micropaleontological content in the two domains suggests connexions between the marine Paleocene deposits of Bas-Languedoc and the PPT. It could thus explain the succession of the same tectono-eustatic events. We propose, as an hypothesis, that the rapid sea-level changes, as recorded by the imbricated karstic paleomorphologies, could be induced by the closing and the opening of a strait in the Eastern part of the PPT acting as a sill. This would be controlled by tectonic movements along the active orogenic axis of the Pyrenean Range and eustatic variations of the Paleocene World Ocean. The karstic systems developed during these low-stand episodes may have been later reactivated after the Early Selandian and more specifically during the Messinian desiccation event. This late evolution may have generated deep flooded karsts, now situated below the present sea level. Such karsts, partly inherited from Paleocene, could be important aquifers of economic interest.
ISSN: 0985-3111

hal-00407601
https://hal.archives-ouvertes.fr/hal-00407601
DOI : 10.3166/ga.20.301-326

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
This paper focuses on the analyses of the clastic sedimentary infill of the Coastal Plain of Eastern Mexico, which initiated synchronously with the Laramide orogeny in the vicinity of the Golden Lane. Results of these analyses are used as boundary conditions for calibrating/interpreting seismic profiles across more distal depocenters in the offshore of the Gulf of Mexico, from the sea shore and continental slope in the west to the abyssal plain in the east. The objective of the study is to better predict the reservoir distribution in the Deep offshore Basin of the Gulf of Mexico (DBGM), in order to explore for petroleum. The Coastal Plain is underlain by three morpho-tectonic domains: the tectonic front of the Sierra Madre Orientale (SMO), the Chicontepec deep water flexural basin, and the Tuxpan Platform (also known as the Golden Lane). Each domain is characterized by a distinct, dominantly siliciclastic Cenozoic lithostratigraphy. After a Jurassic rifting episode, followed by thermal subsidence, the oceanic basin and its western passive margin were deformed during the Upper Cretaceous and Paleogene, by far field stresses associated with the Cordilleran-Laramide Orogeny. Starting in the Late Cretaceous-Early Paleogene and during the Early Eocene, the tectonic load associated with the Laramide Orogen (Sierra Madre Oriental, SMO) caused flexural subsidence of the foreland located under the Coastal Plain. During this period, a massive transfer of siliciclastic sediments occurred from the Laramide foothills into the adjacent foreland. Sediments were eroded of the Sierra Madre tectonic wedge. Loading by these sediments pushed source units associated with the former passive margin down ward. The first syn-tectonic sediments of the Laramide orogeny were turbiditic silt layers in submarine fans which record also numerous collapse episodes and gravity slides. During the Late Eocene and Oligocene, the flexural subsidence stopped in the hinterland, whereas the subsidence of the passive margin resumed. This resulted in a change in the overall sedimentary architecture of the basin. Paleo-highs and reefs facies of the Golden Lane were flooded. Clastics by-passed the reefs and progradational clastic stratification formed as sediment moved towards the DBGM in the east. The final depositional environment of the continental platform/Coastal Plain became deltaic, marked by a succession of sand bars, levees and channels systems. From Miocene times onward, a system of gravitational listric faults developed near the platform to slope transition, resulting in a coeval compressional system at the transition between the slope and the abyssal plain. This system is driven by sediments charge. Because the sedimentation rate is larger than the subsidence, a large amount of clastics and slumped sediments are deposited in hangingwall basins.
ISSN: 0264-8172

hal-00424586
https://hal.archives-ouvertes.fr/hal-00424586
DOI : 10.1016/j.marpetgeo.2008.03.009

Éditeur(s) : HAL CCSD Société géologique de France
Résumé : International audience
The Messinian salinity crisis (MSC) is characterized by gigantic erosion that remodels the margins while a thick, essentially evaporitic and detrital, sedimentary sequence forms in the deep basins. Based on recent (MAURESC, 2003) and earlier (MESEA 1, 1990; MAGIRAA, 1996; GEOBREST, 2002) seismic reflection data, this work brings to light the record of the MSC on the Provençal margin, which has until now been rarely explored from this perspective. Beyond its strictly regional interest, this study fits into a larger synthesis of MSC seismic markers in the Mediterranean and Black Sea marine domain [Lofi et al., 2011] and employs the new nomenclature established on this occasion. The results obtained reveal a Messinian detrital body (CU unit) of 625 metres maximum thickness at the foot of the margin, accumulating at the mouths of the principal canyons. Its form, facies and extension assimilate it to clastic fans, fed by subaerial erosion linked to the MSC. The relative geometry of CU and the Messinian units MU and UU deposited in the deep basin give indications to their chronostratigraphic relations. The deposition of the CU unit is posterior to the basal part of the mobile unit consisting of halite (MU), but contemporary to its top. These results agree with the recent scenarii, which propose that the precipitation of MU in the basin began early, during the lowering of the sea level, and ended at a low level during the MSC [Blanc, 2000; Martin et al., 2001; Sage et al., 2005; Ryan, 2009]. The UU unit surmounts MU and is subdivided into two sub-units with perceptibly different seismic facies : UU1 at the base and UU2 at the summit. UU1 could correspond to a unit containing more halite and/or more clastic material than UU2. The UU1 sub-unit could be partially contemporary to the CU unit. Concerning salt tectonics and its markers, three structural provinces have been evidenced in the sector of study, respectively : an upslope domain in extension (normal faults), an intermediary domain in translation (tabular MU) and a downslope domain in contraction (salt diapirs). These domains are directly linked to the gravity spreading and/or gliding of the brittle sedimentary cover formed by the CU, UU and Plio-Quatenary units and of the mobile level, MU. In the study area, a close relation between the distribution and thickness of CU and salt tectonics has additionally been evidenced at the mouths of the large Messinian canyons, being best expressed where CU is thick.
EISSN: 1777-5817

hal-00498286
https://hal.archives-ouvertes.fr/hal-00498286

Éditeur(s) : HAL CCSD
Résumé : The Firouzkuh Fault in most of its extension is located at the southern side of Firouzkuh Valley in west of the Central Alborz. It is a SW - NE prominent structure with a 70 km long on a sinistral -normal fault. It has been known as a south-dipping reverse fault.Paleoseismic analysis and C14 dating along the Firouzkuh left -lateral strike-slip fault indicate that Central Alborz has been shaken by large earthquakes during the Holocene. Here we present the data carried out of one of the two excavated trenches with 15 m long, 2m wide, ~ 4m deep in the east of Firouzkuh, where we found some evidence for last paleoearthquake associated to seismic re-activity on Firouzkuh Fault in the second trench (F2) that dug across a gauge zone. The last event is evidenced by cutting young superficial deposit where this faulted unit stratigrafically covered alluvium deposits yielded dated human bones fragments. The bones found in 60-70cm-deep of trench which a C14 age of 1159 ± 28 BP. Regarding to estimated slips per event on paleoseismological log of eastern wall of trench F1, event magnitudes for each paleoearthquakes are M≈7.
Geosciences Scientific Quarterly Journal

hal-00800375
https://hal.archives-ouvertes.fr/hal-00800375

Éditeur(s) : HAL CCSD Société géologique de France
Résumé : New radiolarian assemblages of Late Jurassic age were extracted from seven chert localities of the basement comp ex of La Desirade Island (Guadeloupe), the oldest geological unit of the Lesser Antilles arc and the eastern Caribbean region. These fauna range in age from Kimmeridgian or early Tithonian to early or early late Tithonian, showing that La Desirade cherts are not all coeval, contrary to what was established by previous studies. Furthermore, the close spatial association of cherts and volcanic elements composed of basaltic flows and volcaniclastics suggests a mixed setting of hydrothermal siliceous deposits and biogenous sedimentation consistent with an arc-related oceanic setting rather than an ophiolite-type oceanic crust. As the Youngest age is obtained to the northwest of the basement complex where as older data are found to the southeast, it also Suggests that La Desirade basement complex may have undergone some structural stacking consistent with an accretion-type geodynamic getting. Our biochronological data provide a preliminury try tectonic model of an eastward subduction zone for Lesser Antilles arc basement emplacement during the Mesozois.
EISSN: 1777-5817

hal-00445252
https://hal.archives-ouvertes.fr/hal-00445252
DOI : 10.2113/gssgfbull.180.5.399

Éditeur(s) : HAL CCSD Public Library of Science
Résumé : International audience
Among persisting questions on bone calcification, a major one is the link between protein expression and mineral deposition. A cell culture system is here proposed opening new integrative studies on biomineralization, improving our knowledge on the role played by non-collagenous proteins in bone. This experimental in vitro model consisted in human primary osteoblasts cultured for 60 days at the surface of a 3D collagen scaffold mimicking an osteoid matrix. Various techniques were used to analyze the results at the cellular and molecular level (adhesion and viability tests, histology and electron microscopy, RT-and qPCR) and to characterize the mineral phase (histological staining, EDX, ATG, SAED and RMN). On long term cultures human bone cells seeded on the osteoid-like matrix displayed a clear osteoblast phenotype as revealed by the osteoblast-like morphology, expression of specific protein such as alkaline phosphatase and expression of eight genes classically considered as osteoblast markers, including BGLAP, COL1A1, and BMP2. Von Kossa and alizarine red allowed us to identify divalent calcium ions at the surface of the matrix, EDX revealed the correct Ca/P ratio, and SAED showed the apatite crystal diffraction pattern. In addition RMN led to the conclusion that contaminant phases were absent and that the hydration state of the mineral was similar to fresh bone. A temporal correlation was established between quantified gene expression of DMP1 and IBSP, and the presence of hydroxyapatite, confirming the contribution of these proteins to the mineralization process. In parallel a difference was observed in the expression pattern of SPP1 and BGLAP, which questioned their attributed role in the literature. The present model opens new experimental possibilities to study spatio-temporal relations between bone cells, dense collagen scaffolds, NCPs and hydroxyapatite mineral deposition. It also emphasizes the importance of high collagen density environment in bone cell physiology.
ISSN: 1932-6203

hal-01142641
http://hal.upmc.fr/hal-01142641
http://hal.upmc.fr/hal-01142641/document
http://hal.upmc.fr/hal-01142641/file/Silvent_2013_Collagen.pdf
DOI : 10.1371/journal.pone.0057344

Résumé : Les aciers inoxydables à haute teneur en molybdène présentent une excellente résistance à la corrosion et ont été récemment utilisés dans des applications marines. L'acier inoxydable de type 254 SMO contient du molybdène (6% Mo) et des quantités plus élevées en éléments d'alliages que les aciers inoxydables plus classiques tels que 304, 316 et 316L. Alors que Anees Uddin Malik et al. montrent que l’acier 254 SMO est moins sensible à la corrosion par piqûre en eau de mer du golfe persique, Abdulsalam et al. démontrent que bien que cet acier présente une bonne résistance à la corrosion, il reste encore sensible à une corrosion caverneuse (surtout en milieu à 16% en masse d’ion chlorure ou à plus de 30°C).La première partie de ce travail traite du comportement électrochimique de l’acier inoxydable 254 SMO immergé dans l’eau de mer naturelle en laboratoire. Ainsi deux sites de la Guyane ont été choisis pour effectuer des prélèvements d’eau. Des analyses physicochimiques de ces eaux sont réalisées et montrent que l’eau du site du Port Larivot contient une quantité en ions chlorures plus importante que celle de l’eau du site du Mahury. Une colonisation par des bactéries et crustacés (balanes) a été mise en évidence, à l’aide du microscope électronique à balayage environnemental. Les mesures électrochimiques, notamment la voltammétrie cyclique a montré l’existence d’une zone de passivation et l’augmentation du courant de passivation par un facteur de 10 en présence d’un biofilm pour l’acier inoxydable immergé en eau du Mahury durant 22 jours. La deuxième partie propose une étude approfondie du comportement de l’interface complexe métal/couche passive/biofilm. Trois différents coupons d’aciers inoxydables (brut, poli et grenaillé) ont été déposés sur site (in-situ) dans un premier temps. Dans une seconde étape, nous avons réalisé des expérimentations mixtes (incubation in-situ et croissance en laboratoire). L’évolution du potentiel d’abandon de ces aciers est très proche pour l’acier brut et l’acier poli. En revanche, celui de l’acier grenaillé, de par la présence des grains d’alumine à sa surface, affiche un comportement différent. Une étude comparative des deux expérimentations montre des différences concernant les paramètres électriques de l’interface complexe métal/couche passive/biofilm.
Stainless steels with high content in molybdenum present an excellent corrosion resistance and were recently used in marine applications. The stainless steel 254 SMO contains molybdenum (6 %) and higher amounts of alloying elements than conventional stainless steels such as 304, 316 and 316L. While Anees Uddin Malik et al. show that 254 SMO steel is less likely to be susceptible to pitting corrosion in Arabian Gulf sea water, Abdulsalam et al. demonstrate that although this steel has good resistance to corrosion, it remains still susceptible to crevice corrosion (especially in environment with 16 chloride percent weight or more than 30 ° C).The first part of this work deals with the electrochemical behaviour of stainless steel 254 SMO immersed in natural seawater at laboratory. Two sites in French Guyane were chosen to take samples of seawater. Physicochemical analyses of these waters are made and show than the in Port Larivot site seawater contains a higher quantity of chloride ion than to Mahury seawater. Colonization by bacteria and crustaceans (barnacles) was highlighted, using the environmental scanning electron microscope. The electrochemical measurements, including cyclic voltammetry showed the existence of a passivation region and increasing the passivation current by a factor of 10 in the presence of biofilm on stainless steel immersed in Mahury seawater during 22 days.The second part offers a detailed study of the behaviour of the interface metal/passive film/biofilm. Three different coupons of stainless steel (crude, polished and blasted) were deposited on the site (in-situ) in the first time. In a second step, we performed experiments mixed (in-situ incubation and growth in the laboratory). The evolution of the free potential of these steels is very close for crude steel and polished steel. Conversely, the blasted steel, by the presence of alumina grains on its surface, shows a different behaviour. A comparative study of those two experiments shows differences in the electrical parameters of the interface metal/passive film/biofilm.

http://www.theses.fr/2013AGUY0598/document

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The ∼55 km-long Firouzkuh fault is located in the Central Alborz Mountains of Iran. It is a left-lateral fault, which dips to the south, and possesses a small dip-slip component of motion that we interpret to result from extension. The ratio of horizontal to vertical displacement across the fault, calculated from the cumulative displacement of landscape features, is 7.6. We provide constraints on the timing of the last earthquake on the Firouzkuh fault from two trenches (T1 and T2) across the fault zone, excavated in 2004, and located east of Firouzkuh city. The trenches expose faulted sedimentary deposits. Two optically-stimulated luminescence (OSL) ages from sediments in the lower part of trench T1 date from the late Pleistocene (15.9 ± 0.9 ka and 27.1 ± 1.7 ka). The younger of the two dated units in T1 is displaced vertically across the fault by 2.2–4.4 m, from which we estimate a strike-slip displacement of 18.2–33.4 m, and hence a average horizontal slip-rate of 1.1–2.2 mm/yr. The sediments exposed in T1 do not yield constraints on the most recent earthquake history. In trench T2, however, human skeletal remains of a middle aged male, which yield a radiocarbon age of 1159 ± 28 BP (corresponding to a mean calendar age of 791 AD), were found within a faulted alluvial layer at a depth of 60–70 cm from the surface. The existence of these medieval human places shows that a surface-rupturing earthquake occurred at some time after 1159 ± 28 BP. The amount of slip in each earthquake on the Firouzkuh fault is difficult to estimate, but assuming the entire ∼55 km fault length ruptures in each event, they will have had a maximum magnitude of 7.1. At our estimated late Quaternary slip-rate of ∼1.1–2.2 mm/yr magnitude 7.1 earthquakes, involving ∼1.2 m average displacement, would be expected to occur every ∼1100–540 years. As the last earthquake on the Firouzkuh fault may be up to ∼700 years in age we suggest that the Firouzkuh fault is a major hazard for earthquakes in the near future.
ISSN: 0743-9547

hal-01122835
https://hal.archives-ouvertes.fr/hal-01122835
DOI : 10.1016/j.jseaes.2013.12.018

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
This study presents the geochemical composition of superficial sediment under oxic and suboxic bottom water conditions along the Chilean continental margin (SE Pacific), where evidence for benthic chemosynthetic activity associated with diffuse seeping of chemically reduced fluids has been reported. The exploration was carried out at: (1) the Chilean Triple Junction (CTJ), at a water depth of ∼2900 m, with the additional indication of hydrothermal activity near a methane-rich cold-seep area (46°S) (German et al., 2010); and (2) the El Quisco methane seep site (EQSS), at ∼340 m water depth (33°S) (Melo et al., 2007; Krylova et al., 2014). While the deeper CTJ is located within an oxic environment (dissolved oxygen in the bottom waters: 164 μM), the shallower EQSS lies within a suboxic environment (dissolved oxygen in bottom water: 23 μM), located within the lower limit of the SE Pacific oxygen minimum zone (OMZ).Pore water from short cores was analyzed for dissolved major, minor, and trace elements (Cl, Na, Mg, K, Ca, Sr, Si, B, P, Ba, Pb, Mn, Fe, Cd, U, and Mo), δ13DIC, sulfide, sulfate, and methane. The solid sediment fraction was likewise analyzed for total organic carbon (TOC), metals, and redox potential. Elevated sediment temperatures were found in superficial sediments (5–13 °C) at the CTJ site, which could be due to warm fluids associated with the proximity of the ridge, where hydrothermal vents may occur. Reduced fluids were also present here, indicated by higher Mn fluxes toward the water column even in oxidized sediments (RPD > 8 cm), which contrasted with the lower fluxes in reduced sediments of the EQSS site (RPD ∼ 2 cm). 13C-depleted DIC, anomalously low pore water Cl (∼15 ppb), and low concentrations of other major elements may be the result of dilution by fluid seeping and precipitation of major elements, producing authigenic enrichment (Ca, Mg, Sr). The fluid could also: (a) be diluted by pure water produced during methane hydrate dissociation, as observed in other cold-seep areas; and (b) correspond to clay mineral dehydration, as reported in plate subduction systems. The reducing conditions established at the CTJ conduct the Cd enrichment at a similar magnitude of that seen at the shallower suboxic site (EQSS). Evidence of chimney or vent fauna was not observed. At the EQSS, higher TOC and total sulfide contents were consistent with enhanced deposition of organic matter and reducing conditions developed in the OMZ, favoring the authigenic enrichment of Cd, U and Pb. The geochemical evidence, based only on methane concentrations and δ13DIC, is insufficient to establish the presence of methane seeps, as previously reported.
ISSN: 0079-6611

hal-01412700
https://hal.archives-ouvertes.fr/hal-01412700
DOI : 10.1016/j.pocean.2016.09.002

Éditeur(s) : HAL CCSD Springer/Terra Scientific Publishing Company
Résumé : International audience
This study of the Cajati deposit provides evidence that the ore was neither purely hydrothermal, nor volcanic in origin, as previous workers have proposed. The ores were formed from magnetite-rich magmas, hydrothermally altered and intruded at an indicated crustal depth in excess of 500 m. The mineralogical and textural association between magnetite and magnesioferrite in the carbonatite, and between the titanomagnetite and magnesioferrite-Ti mineralization in the pyroxenite of hedenbergite, seems to be analog mineralizations strongly related to the ionic substitution of Fe2+ by Mg. Relatively high Q ratios (>= 5) for Jacupirangite-pyroxenite may indicate a thermo remanent magnetization (TRM) by the ore during post-metamorphic cooling, however it call also be developed from chemical remanent magnetization (CRM). Vector plots for the pyroxenite samples show reasonably linear and stable magnetic components. The intensity decay Curves show that only two components of magnetizations are likely present. Continuous susceptibility measurements with increasing temperature show that the main magnetic phase seems to be magnetite. Maghemite is probably produced during the cooling process. Susceptibility recorded from low temperature (liquid nitrogen (- 196 degrees C)) to room temperature produces typical Curves. indicating Verwey transition of magnetite. Hysteresis parameters point Out that nearly all values fill in a novel region of the Day plot, parallel to but below magnetite SD + MD mixing curves.
ISSN: 1343-8832

hal-00420922
https://hal.archives-ouvertes.fr/hal-00420922

Éditeur(s) : HAL CCSD Elsevier
Résumé : This study deals with the preliminary data of rare earth elements (REE) obtained on northeastern Algerian phosphorites from the Tébessa region. These phosphorites are located in two different basins: the northern basin represented by Dj. El Kouif, Dj. Dyr and Tazbant showings and the southern basin with the giant Dj. Onk phosphate deposit. The host sedimentary formation is Late Paleocene to Early Eocene. Twenty-six (26) samples from the four (4) localities were collected and analyzed for their REE contents using the ICP-MS technique. Phosphates from the southern basin (Dj. Onk deposit) show ∑REE contents ranging from 174.41 and 906.39 ppm (average ∑REE = 623.01 ppm), while the northern phosphorites have lower ∑REE contents (from 125.45 to 472.44 ppm; average = 265.57 ppm). PAAS-normalized REE patterns and binary Box plot of (Sm/Pr)N vs (Sm/Yb)N show HREE enrichments for samples from the northern localities while most samples from the southern basin are HREE depleted. Normalized (La/Yb)N vs (La/Sm)N plot shows that (La/Sm)N ratios of all samples are similar to those of modern seawater (from 0.83 to 1.55). However, the (La/Yb)N ratios of the two basins are significantly higher (from 0.67 to 1.18), which indicates an early diagenesis. The Ce/Ce* vs Pr/Pr* diagram shows that the observed Ce anomaly was not affected by diagenesis and more likely represents a proxy for redox conditions. The obtained results substantiate that the northern phosphorites were formed in more oxic environment with more pronounced negative Ce anomalies, whereas the southern phosphorites have lower Ce anomalies. Northern phosphorites are different from those from the south probably because the northern basin was more connected to an open sea as did the Sra Ouartan basin in northern Tunisia. These results have also been confirmed by statistical method studies, such as factorial discriminate analysis.
ISSN: 1877-7058

hal-01412572
https://hal.archives-ouvertes.fr/hal-01412572
https://hal.archives-ouvertes.fr/hal-01412572/document
https://hal.archives-ouvertes.fr/hal-01412572/file/kechided2016.pdf
DOI : 10.1016/j.proeng.2016.02.048

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The barrier reef tract of New Caledonia is the second largest in the world enclosing lagoons of variable width. The Late Quaternary evolution of these barrier reefs and lagoons is poorly known. A recent high resolution seismic and multibeam bathymetry survey was carried out in the south-western lagoon from shoreline to open ocean across the barrier reef pass systems to perform sequence stratigraphy and to better understand the Quaternary evolution of the lagoon. Two depositional sequences bounded by type-1 erosional surfaces can be identified. The bounding surfaces delineate the bottom of two generations of incised valleys. System tracts comprising a complete succession of regressive, lowstand, transgressive and highstand tracts were observed only in the upper sequence. Chronostratigraphic and sedimentological interpretations of the seismic data are based on correlations with the chronology defined in the nearby cores drilled through the reefs and in the gravity cores previously recovered in the inner lagoon. Interpretation of seismic data is also carried out on the basis of correlation with multibeam bathymetric data. Our results indicate that the history of the New Caledonian lagoon probably does not exceed 200ka marked by two or three brief episodes each of immersion of about ten thousand years. The bathymetric data reveal that during successive low sea level stands, the lagoon was dependent upon erosional fluvial networks. The deep fluvial valleys were connected to the continental slope through the passes. Seismic records reveal that upstream palaeo-channels are not connected to the modern coastal rivers. In contrast, many aggrading deposits, including numerous stacking channels, and extending across the proximal part of the outer lagoon, can be identified. Examination of drainage network morphology suggests a progressive tilt of the outer lagoon. Such evolution reveals that the Nouméa lagoon which is one of the widest in the world is an exceptional modern example of a rimmed shelf providing data to analyze the past counterparts.
ISSN: 0031-0182

insu-00338953
https://hal-insu.archives-ouvertes.fr/insu-00338953
DOI : 10.1016/j.palaeo.2008.08.012

Éditeur(s) : HAL CCSD American Geophysical Union (AGU)
Résumé : International audience
The Pyrenean peridotites (lherzolites) form numerous small bodies of subcontinental mantle, a few meters to 3 km across, exposed within the narrow north Pyrenean zone (NPZ) of Mesozoic sediments paralleling the north Pyrenean Fault. Recent studies have shown that mantle exhumation occurred along the future NPZ during the formation of the Albian-Cenomanian Pyrenean basins in relation with detachment tectonics. This paper reviews the geological setting of the Pyrenean lherzolite bodies and reports new detailed field data from key outcrops in the Bearn region. Only two types of geological settings have to be distinguished among the Pyrenean ultramafic bodies. In the first type (sedimented type or S type), the lherzolites occur as clasts of various sizes, ranging from millimetric grains to hectometric olistoliths, within monogenic or polymictic debris flow deposits of Cretaceous age, reworking Mesozoic sediments in dominant proportions as observed around the Lherz body. In the second type (tectonic type or T type), the mantle rocks form hectometric to kilometric slices associated with crustal tectonic lenses. Both crustal and mantle tectonic lenses are in turn systematically associated with large volumes of strongly deformed Triassic rocks and have fault contacts with units of deformed Jurassic and Lower Cretaceous sediments belonging to the cover of the NPZ. These deformed Mesozoic formations are not older that the Aptian-early Albian. They are unconformably overlain by the Albian-Cenomanian flysch formations and have experienced high temperature-low pressure mid-Cretaceous metamorphism at variable grades. Such a tectonic setting characterizes most of the lherzolite bodies exposed in the western Pyrenees. These geological data first provide evidence of detachment tectonics leading to manle exhumation and second emphasize the role of gravity sliding of the Mesozoic cover in the preorogenic evolution of the Pyrenean realm. In the light of such evidence, a simple model of basin development can be inferred, involving extreme thinning of the crust, and mantle uprising along a major detachment fault. We demonstrate coeval development of a crust-mantle detachment fault and generalized gravitational sliding of the Mesozoic cover along low-angle faults involving Triassic salt deposits as a tectonic sole. This model accounts for the basic characteristics of the precollisional rift evolution in the Pyrenean realm.
ISSN: 0278-7407

hal-00512818
https://hal.archives-ouvertes.fr/hal-00512818
DOI : 10.1029/2009TC002588