Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We performed torsional deformation experiments on pre-hydrated fine-grained olivine aggregates using an innovative experimental assembly to investigate water weakening in mantle rocks at high shear strains. San Carlos olivine powder was cold-pressed and then hot-pressed under hydrous conditions, producing aggregates with average grain sizes of 7 or 15 μm. Deformation experiments were performed in a high-resolution gas-medium apparatus equipped with a torsional actuator, under a confining pressure of 300 MPa, a temperature of 1200 °C, and constant shear strain rates ranging from 8 × 10−5 to 1.4 × 10−4 s−1. Maximum shear stresses range from 150 to 195 MPa. These values are 30% lower relative to those determined in previous torsion experiments on dry, fined-grained dunites under similar conditions. Textures and microstructures of the starting and deformed specimens were characterized by scanning and transmission electron microscopy. All deformed aggregates exhibit a shape-preferred orientation marking a foliation and lineation, as well as a reduction in mean grain size from 15 μm down to 3-4 μm due to dynamic recrystallization. Olivine crystallographic fabrics developed rapidly (γ < 0.1), but their strength, characterized by the J-index, is low compared to naturally deformed peridotites or to polycrystalline olivine deformed at similar finite shear strains under dry conditions. The crystallographic fabrics are consistent with deformation by a dislocation accommodated creep mechanism with activation of multiple {0 k l}[1 0 0] systems, among which the (0 1 0)[1 0 0] slip system is dominant, and minor participation of the (0 1 0)[0 0 1] slip system. Transmission electron microscopy confirmed the occurrence of dislocations with [1 0 0] and [0 0 1] Burgers vectors in most grains. Analysis of unpolarized infrared spectra indicates that hydrogen concentration in the olivine lattice is below the saturation level of 18 ppm wt H2O, which is similar to those typically observed in spinel-bearing peridotite xenoliths, and also provide evidence for water-rich inter-granular material trapped in pores and grain boundaries. Seismic properties computed from the CPO observations correspond to those most commonly observed in naturally deformed mantle peridotites with fast P-wave propagation and S-wave polarization subparallel to the shear direction. These torsion experiments on fine-grained olivine polycrystals under hydrous conditions indicate that water weakening under lithospheric conditions is linked to various defects with hydrogen in the olivine structure, as well as with water-derived species in grain boundaries or pores.
ISSN: 0031-9201

hal-00745170
https://hal.archives-ouvertes.fr/hal-00745170
DOI : 10.1016/j.pepi.2012.05.001

Éditeur(s) : HAL CCSD Wiley
Résumé : International audience
Haplognathia ruberrima is a cosmopolitan gnathostomulid species found in sulfur bacterial mats in mangroves in Guadeloupe (French West Indies). Haplognathia ruberrima presents a d13C value lower than all measured meiofaunal grazers and lower than the available measured food sources of this environment. This low d13C value can not be due to specific ingestion of 13C-depleted methanogenic bacteria because abundances of those bacteria are reduced in surficial and deep sediments as revealed by d13C of bacterial fatty acid. According to scanning electron microscope observations, no bacterial ectosymbionts were observed at the surface of the gnathostomulids, and transmission electronmicroscope views revealed the absence of bacterial endosymbionts. Energy-dispersive X-ray spectroscopy analysis detected low levels of sulfur (0.32%+-0.8) in biological tissues of H. ruberrima, confirming the absence of thioautotrophic bacterial symbionts in these animals. Consequently, the low d13C value of H. ruberrima can not be due to the presence of sulfur-oxidizing symbionts but more probably to the selective and exclusive consumption of free-living, sulfuroxidizing bacteria
ISSN: 0173-9565

hal-01253239
https://hal.archives-ouvertes.fr/hal-01253239
DOI : 10.1111/maec.12296

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
A San Carlos olivine polycrystal has been deformed under uppermost mantle conditions, by compression at 900 °C, at a strain rate of 1.1 × 10−5 s−1, under a confining pressure of 300 MPa, using the Paterson press. Transmission electron tomography of dislocations has been performed by scanning transmission electron microscopy, by conventional transmission electron microscopy using the weak-beam dark-field technique, associated with precession or not, in order to determine the glide planes of [001] screw dislocations. This recent technique is the most suitable one since most [001] dislocations exhibit straight screw segments due to the high lattice friction on this character at low temperature. We find that [001] dislocations glide in (100), (010) and {110} as already reported, but also more unexpectedly in {120} and {130}. We show that at 900 °C, [001] {110} glide is dominant in polycrystals. We have, however, noted and characterized numerous cross-slip events in the specimen.
ISSN: 0342-1791

hal-01054330
https://hal.archives-ouvertes.fr/hal-01054330
DOI : 10.1007/s00269-014-0665-1

Éditeur(s) : HAL CCSD Mineralogical Society of America
Résumé : International audience
To test if hydrogen incorporation by ionic diffusion can occur between a volatile-rich kimberlitic liquid and forsterite, results of high-pressure and high-temperature experiments using a piston-cylinder apparatus at 1200–1300 °C and 1 GPa for durations of 1 min, 5 h, and 23 h, are reported here. Kimberlitic liquid in the system CaO-MgO-Al2O3-SiO2-CO2-H2O and synthetic forsterite single crystals were chosen as a first simplification of the complex natural kimberlite composition. Unpolarized Fourier transform infrared spectroscopy was used to quantify the concentrations of OH in the crystallographically oriented forsterite. Scanning electron microscopy, electron backscattered diffraction, electron microprobe analyses, and transmission electron microscopy were performed to identify the run products. After 5 and 23 h, a forsterite overgrowth crystallized with the same orientation as the initial forsterite single crystal. The kimberlitic liquid has crystallized as micrometer-scale euhedral forsterite neocrystals with random crystallographic orientations, as well as a nanoscale aluminous phase and a calcic phase. Despite theoretical water-saturation of the system and long duration, none of the initial forsterite single crystals display signs of hydration such as hydrogen diffusion profile from the border toward the center of the crystal. Most likely, the presence of CO2 in the system has lowered the H2O fugacity to such an extent that there is no significant hydration of the starting forsterite single crystal or its overgrowth. Also, the presence of CO2 enhances rapid forsterite crystal growth. Forsterite growth rate is around 2 × 108 μm3/h at 1250 °C. These experimental results suggest a deep mantle origin of the high OH content found in natural mantle-derived xenoliths transported in kimberlites, as reported from the Kaapvaal craton. In agreement with previous studies, it also points out to the fact that significant hydration must take place in a CO2-poor environment.
ISSN: 0003-004X

hal-01217157
https://hal.archives-ouvertes.fr/hal-01217157
DOI : 10.2138/am-2015-5200

Résumé : Les aciers inoxydables à haute teneur en molybdène présentent une excellente résistance à la corrosion et ont été récemment utilisés dans des applications marines. L'acier inoxydable de type 254 SMO contient du molybdène (6% Mo) et des quantités plus élevées en éléments d'alliages que les aciers inoxydables plus classiques tels que 304, 316 et 316L. Alors que Anees Uddin Malik et al. montrent que l’acier 254 SMO est moins sensible à la corrosion par piqûre en eau de mer du golfe persique, Abdulsalam et al. démontrent que bien que cet acier présente une bonne résistance à la corrosion, il reste encore sensible à une corrosion caverneuse (surtout en milieu à 16% en masse d’ion chlorure ou à plus de 30°C).La première partie de ce travail traite du comportement électrochimique de l’acier inoxydable 254 SMO immergé dans l’eau de mer naturelle en laboratoire. Ainsi deux sites de la Guyane ont été choisis pour effectuer des prélèvements d’eau. Des analyses physicochimiques de ces eaux sont réalisées et montrent que l’eau du site du Port Larivot contient une quantité en ions chlorures plus importante que celle de l’eau du site du Mahury. Une colonisation par des bactéries et crustacés (balanes) a été mise en évidence, à l’aide du microscope électronique à balayage environnemental. Les mesures électrochimiques, notamment la voltammétrie cyclique a montré l’existence d’une zone de passivation et l’augmentation du courant de passivation par un facteur de 10 en présence d’un biofilm pour l’acier inoxydable immergé en eau du Mahury durant 22 jours. La deuxième partie propose une étude approfondie du comportement de l’interface complexe métal/couche passive/biofilm. Trois différents coupons d’aciers inoxydables (brut, poli et grenaillé) ont été déposés sur site (in-situ) dans un premier temps. Dans une seconde étape, nous avons réalisé des expérimentations mixtes (incubation in-situ et croissance en laboratoire). L’évolution du potentiel d’abandon de ces aciers est très proche pour l’acier brut et l’acier poli. En revanche, celui de l’acier grenaillé, de par la présence des grains d’alumine à sa surface, affiche un comportement différent. Une étude comparative des deux expérimentations montre des différences concernant les paramètres électriques de l’interface complexe métal/couche passive/biofilm.
Stainless steels with high content in molybdenum present an excellent corrosion resistance and were recently used in marine applications. The stainless steel 254 SMO contains molybdenum (6 %) and higher amounts of alloying elements than conventional stainless steels such as 304, 316 and 316L. While Anees Uddin Malik et al. show that 254 SMO steel is less likely to be susceptible to pitting corrosion in Arabian Gulf sea water, Abdulsalam et al. demonstrate that although this steel has good resistance to corrosion, it remains still susceptible to crevice corrosion (especially in environment with 16 chloride percent weight or more than 30 ° C).The first part of this work deals with the electrochemical behaviour of stainless steel 254 SMO immersed in natural seawater at laboratory. Two sites in French Guyane were chosen to take samples of seawater. Physicochemical analyses of these waters are made and show than the in Port Larivot site seawater contains a higher quantity of chloride ion than to Mahury seawater. Colonization by bacteria and crustaceans (barnacles) was highlighted, using the environmental scanning electron microscope. The electrochemical measurements, including cyclic voltammetry showed the existence of a passivation region and increasing the passivation current by a factor of 10 in the presence of biofilm on stainless steel immersed in Mahury seawater during 22 days.The second part offers a detailed study of the behaviour of the interface metal/passive film/biofilm. Three different coupons of stainless steel (crude, polished and blasted) were deposited on the site (in-situ) in the first time. In a second step, we performed experiments mixed (in-situ incubation and growth in the laboratory). The evolution of the free potential of these steels is very close for crude steel and polished steel. Conversely, the blasted steel, by the presence of alumina grains on its surface, shows a different behaviour. A comparative study of those two experiments shows differences in the electrical parameters of the interface metal/passive film/biofilm.

http://www.theses.fr/2013AGUY0598/document

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The interplay between fault zone cataclasis and cementation is important since both processes can drastically reduce the permeability of faults in porous sandstones. Yet the prediction of fault cementation in high-porosity sandstone reservoirs remains elusive. Nevertheless, this process has rarely been investigated in shallowly buried faults (<2 km; T°<80 °C) where its sealing capacity could be acquired early in the geological history of a reservoir. In this paper, the macro- and microscopic analysis of a fault zone in the porous Cenomanian quartz arenite sands of Provence (France) shows that silica diagenesis occurs in the most intensely-deformed cataclastic parts of the fault zone. This fault zone shows 19–48% of its total thickness occupied by low-porosity quartz-cemented cataclastic shear bands whose porosities range from 0 – ca. 5%. The analysis of the weathering profile around the fault zone reveals the presence of groundwater silcretes in the form of tabular, tightly silicified concretions cross-cut by the fault. Detailed transmitted light, cold-cathodoluminescence and scanning electron microscopy analyses of the silica cements (from the fault and the silcrete) reveal that all the silica cements originate from groundwater diagenetic processes. This study therefore shows that silica cementation can occur specifically in fault zones and as groundwater silcrete in the shallow context of a groundwater system, generated at the vicinity of an erosional unconformity.
ISSN: 0191-8141

hal-01278286
https://hal.archives-ouvertes.fr/hal-01278286
DOI : 10.1016/j.jsg.2015.10.001

Éditeur(s) : HAL CCSD Magnolia Press
Résumé : International audience
Several diatoms in the family Achnanthaceae (Bacillariophyta), mainly from marine environments, have species with strongly apiculate, lemon-shaped valves. Some of them originally described under the genus Cocconeis (i.e., C. trachyderma or C. citronella), while others were first described as Stauroneis species [i.e. Stauroneis apiculata or S.(?) obesa]. Afterwards, Cocconeis citronella has been recombined within Achnanthes by Hustedt. The type material of C. citronella from Albert Mann’s collection, housed in the Smithsonian Institution (US), has been examined with light microscope; some ambiguities are pointed out and new details added to the original description. The intricate history of the latter taxon is redrawn and comparison with allied taxa are tentatively addressed. Cocconeis trachyderma is lectotypified and recombined as Achnanthes trachyderma comb. nov. Stauroneis apiculata and S.(?) obesa are recombined as Achnanthes apiculata comb. nov. and Achnanthes obesa comb. nov. respectively. The examination with light and scanning electron microscope of several marine samples from the Society Archipelago details the unique morphology of Achnanthes trachyderma which, until recently, has been often misidentified as Achnanthes citronella due to certain similarities between both taxa.
ISSN: 1179-3155

hal-01212892
https://hal-univ-perp.archives-ouvertes.fr/hal-01212892
DOI : 10.11646/phytotaxa.227.2.1

Éditeur(s) : HAL CCSD Czech Phycological Society
Résumé : International audience
As first observed on a group of taxa related to Cocconeis peltoides Hustedt, several other Cocconeis eHRenbeRG (Bacillariophyta) taxa possess a row of minute marginal pores on the external side of their sternum valve (SV) connected to small and simple internal portules, or processes. These processes are often located in continuity with the striae, but can also be slightly shifted or distant from the distal areola of the striae. The row of pores is often, but not always, externally separated from the stria by a crista marginalis. Within Cocconeis, and possibly all raphid diatoms, these processes seem unique and restricted to a few taxa. A list is presented of the taxa pertaining (or close) to Cocconeis that are actually known to share these micro–structures. In addition, the morphological variability of the processes is described in detail and a morphological comparison of the taxa is provided. The characteristic features of taxa showing a row of SV processes permit the tentative definition of several morphological groups. It is difficult to prove the taxonomic affiliation of these taxa and demonstrate or refute that these processes are ancestral characters. Some of these taxa are rare and restricted to low latitudes (e.g., tropical taxa) while others are frequent and ubiquitous. Abbreviations: (LM) light microscope, (SEM) scanning electron microscope, (RV) raphe valve, (SV) sternum valve, (RVVC) raphe valve valvocopula, (SVVC) sternum valve valvocopula
ISSN: 1802-5439

hal-01212883
https://hal-univ-perp.archives-ouvertes.fr/hal-01212883
https://hal-univ-perp.archives-ouvertes.fr/hal-01212883/document
https://hal-univ-perp.archives-ouvertes.fr/hal-01212883/file/fottea_fot-201502-0003.pdf
DOI : 10.5507/fot.2015.015

Éditeur(s) : HAL CCSD American Geophysical Union (AGU) American Geophysical Union
Résumé : International audience
Environmental magnetism of speleothems is still in its early stage of development. Here we report on our investigation of the environmental and paleomagnetic information that has been recorded in speleothems, and what are the factors that control its preservation and reliability. To address these issues, we used a multidisciplinary approach, including rock magnetism, petrography, scanning electron microscopy, stable carbon and oxygen isotope compositions, and major and trace element concentrations. We applied this to a set of samples from different stages of speleothem evolution: present-day dripwater (glass plates), a weathered stalactite, a fresh stalagmite, cave sediments, and terra rossa soils. These samples come from the Penico and Excentricas caves, located in two distinct aquifers of the Algarve region, South Portugal. Our results show that the main magnetic carriers of the speleothems under study are primary (detrital) and consist of maghemite (and magnetite?). Similarities in coercivity and temperature dependence of the studied set of samples suggest that iron oxides are inherited from the terra rossa soils that cap the cave and were transported to the speleothems by dripwater. Hence, they represent a regional environmental signature. Interestingly, a stable and probably detrital remanent magnetization could be isolated in the fresh stalagmite, whereas the weathered stalactite yielded chaotic magnetic directions and very low remanent intensities. We propose that these low intensities can be the result from (i) different remanence acquisition mechanisms between stalagmite and stalactite and/or (ii) iron dissolution by fungal activity. We also suggest that magnetic properties and color and the content in detrital elements in the fresh speleothem inform about environmental processes acting on the interface of rock (soil)-atmosphere, while oxygen isotope composition and alkaline-earth element concentrations inform about calcite-water interaction processes. These results provide a better understanding of how environmental information is recorded in speleothems and what the factors are that control the reliability of the paleomagnetic and paleo-environmental signal.
ISSN: 0148-0227

hal-01114953
https://hal.archives-ouvertes.fr/hal-01114953
DOI : 10.1002/2014JB011381

Éditeur(s) : HAL CCSD
Résumé : We present an experimental study of relations between hydraulic properties of clayey rocks and their deformation at bulk and micro scale. The experimentation is based on triaxial deformation of kaolinitic core samples, on permeability measurements, and on several methods of analysis of the microstructure. To produce the samples, remoulded kaolinite material is consolidated by axial loading up to 20 MPa in an oedometric cell. Then, in a triaxial cell, an undrained stress path is applied in order to induce shearing damage in the sample. The permeability of the sample is measured by fluid flow across the sample. Before and after these hydro-mechanical tests, the evolution and the homogeneity of the pore space and moreover the texture of the material are analysed by X-ray tomography, environmental scanning electron microscopy and thermic neutron diffraction. Contrary to expectations, the permeability at the sample scale does not vary significantly, although quite large deformation is reached. The final deformation is heterogeneous, with well-developed shear bands. It appears that the development of compacting and dilating zones generates a heterogeneous permeability field, which results in a negligible variation of the bulk permeability at the sample scale.
International Journal of Rock Mechanics and Mining Science

hal-00496407
https://hal.archives-ouvertes.fr/hal-00496407
DOI : 10.1016/j.ijrmms.2010.04.007

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The present study aims to apply the AMS method (Anisotropy of Magnetic Susceptibility) at a regional scale to track the fluid circulation direction that has produced an iron metasomatism within pre-existing dolomite host rock. The Urgonian formations hosting the Zn-Pb mineralizations in La Florida (Cantabria, northern Spain) have been taken as target for this purpose. Sampling was carried out, in addition to ferroan dolomite host rock enclosing the Zn-Pb mineralizations, in dolomite host rock and limestone to make the comparison possible between magnetic signals from mineralized rocks, where fluid circulation occurred, and their surrounding formations. AMS study was coupled with petrofabric analysis carried out by texture goniometry, Scanning Electron Microscopy (SEM) observations and also Shape Preferred Orientation (SPO) statistics. SEM observations of ferroan dolomite host rock illustrate both bright and dark grey ribbons corresponding respectively to Fe enriched and pure dolomites. SPO statistics applied on four images from ferroan dolomite host rock give a well defined orientation of ribbons related to the intermediate axis of magnetic susceptibility K2. For AMS data, two magnetic fabrics are observed. The first one is observed in ferroan dolomite host rock and characterised by a prolate ellipsoid of magnetic susceptibility with a vertical magnetic lineation. The magnetic susceptibility carrier is Fe-rich dolomite. These features are probably acquired during metasomatic fluid circulations. In Fe-rich dolomite host rock, ‹c› axes are vertical. As a rule, (0001) planes (i.e. planes perpendicular to ‹c› axes) are isotropic with respect to crystallographic properties. So, the magnetic anisotropy measured in this plane should reflect crystallographic modification due to fluid circulation. This is confirmed by the texture observed using the SEM. Consequently, AMS results show a dominant NE-SW elongation interpreted as the global circulation direction and a NW-SE secondary elongation that we have considered as sinuosities of the fluid trajectory. The second type of magnetic fabric is essentially observed in the limestone and characterised by an oblate form of the ellipsoid of magnetic susceptibility, a horizontal magnetic foliation and mixed magnetic susceptibility carriers. It is interpreted as a sedimentary fabric.
ISSN: 0012-821X

insu-00342499
https://hal-insu.archives-ouvertes.fr/insu-00342499
https://hal-insu.archives-ouvertes.fr/insu-00342499/document
https://hal-insu.archives-ouvertes.fr/insu-00342499/file/Essalhi-EPSL-2008.pdf
DOI : 10.1016/j.epsl.2008.11.011

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Carbonation of peridotite is a widespread process in nature, with emerging societal and environmental implications through geological storage of CO2. We studied the micro- and nano-scale structures associated with the carbonation of peridotite pervaded by a CO2-rich water and the induced changes of its hydrodynamic properties. Focused ion beam (FIB) nanotomography was coupled with scanning electron microscopy (SEM) and transmission electron microscopy (TEM) observations. An experimental sample of dunite core percolated by a CO2-rich fluid (pCO2 = 11 MPa) at 160 °C was compared with a naturally carbonated sample from the Atlantic Ridge (Exp. IODP 304). Results of the 8-days percolation experiment show continuous alteration of olivine into magnesite locally associated with a poorly crystalline serpentine-type mineral referred to as proto-serpentine. The experiment is also characterized by an overall decrease in rock porosity (from 7.7 to 6.4%) and permeability (from 8.5 × 10− 16 to 1.7 × 10− 16 m2). The primary inter-granular porosity (1 to 10 μm) is progressively filled with magnesite, leading to the overall decrease of permeability. At the same time, a secondary small-scale porosity (10 nm to 1 μm) is created at the tip of the dissolution features along the (010) cleavage planes of olivine grains. Carbonate crystals grow within these etch-pit structures behind the dissolution front. Dissolution and precipitation occur at a relative rate that maintains the secondary porosity over the timescale of the experiment (i.e. carbonate growth has to be the slowest one). This process is interpreted as an interface coupled dissolution-precipitation mechanism of olivine carbonation. Proto-serpentine is only formed in highly reduced flow areas, such as small olivine etch-pits (10 to 500 nm wide), which are more isolated from CO2 input. SEM-FIB analyses show the 3D preferential orientation of the dissolution-precipitation planes within a given olivine grain. It suggests the formation of lateral connections between the etch-pits (infra-micrometric “channels”) providing access to reactants and removing reaction products at the reaction sites. The experimental results show that olivine dissolution and magnesite precipitation converge to a quasi-steady state resulting in a constant carbonation rate controlled by reaction kinetics and not by mass transfer for this flow regime. The system self-regulates, independently of the porosity change at least during this incipient stage of olivine carbonation. Similar textures are observed in natural samples collected at 170 m-depth in the vicinity of veinlets driving late fluids down into the cooling oceanic lithosphere. This suggests that similar mechanisms are active in nature and can play an important role in the late, low temperature alteration stages of fractured peridotite. These results also highlight the critical role of nm-scale spatial arrangement of dissolution and precipitation features on mass transfers and on the sustainability of olivine carbonation through coupled dissolution-precipitation processes.
ISSN: 0009-2541

hal-01684733
https://hal.archives-ouvertes.fr/hal-01684733
DOI : 10.1016/j.chemgeo.2017.11.013

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The potential effects of the mineralogical composition of sediment on the degradation of oil buried on sandy beaches were investigated. Toward that purpose, a laboratory experiment was carried out with sandy sediment collected along NW Iberian Peninsula beaches, tar-balls from the Prestige oil spill (NW Spain) and seawater. The results indicate that the mineralogical composition is important for the physical appearance of the oil (tar-balls or oil coatings). This finding prompted a reassessment of the current sequence of degradation for buried oil based on compositional factors. Moreover, the halo development of the oil coatings might be enhanced by the carbonate concentration of the sand. These findings open new prospects for future monitoring and management programs for oiled sandy beaches.
ISSN: 0025-326X

hal-01122779
https://hal.archives-ouvertes.fr/hal-01122779
DOI : 10.1016/j.marpolbul.2014.06.040

Résumé : Ce travail porte sur l'inhibition de l'acier C38 en milieu acide HC1 1M par les extraits alcaloïdes issus de 2 plantes : aspidosperma album et geissospermum laeve. Biodégradables et respectueux de l'environnement, les alcaloïdes pourraient être utilisés temporairement pour prévenir la corrosion de l'acier C39 avec des taux d'inhibition supérieurs à ceux décrits dans la littérature. Dans la première partie du travail, l'influence de la concentration, du temps d'immersion et de la température sur le processus de corrosion de l'acier C38 en milieu HC1 1M en absence de polarisation et spectroscopie d'impédance électrochimique. Les analyses de surface effectuées par microscopie électronique a balayage montrent la présence d'une couche constituée d'un mélange d'oxyde de fer incorporant les alcaloïdes et qui conduit à la diminution de la vitesse de corrosion. La deuxième partie de ce travail a été consacrée à l'isolement des alcaloïdes des deux extraits afin de déterminer le ou les alcaloïdes responsables de l'activité inhibitrice et ainsi remonter aux mécanismes d’adsorption. Il a été montré que l'alcaloïde majoritaire des extraits est responsable de l'inhibition
This work is devoted to the corrosion inhibition of C38 steel in 1M HCL acid medium by alkaloids extracts from two plants : aspidosperma album and geissospermum laeve. Biodegradable and environmentally friendly, alkaloids could be used temporarily to prevent the corrosion of C38 steel with inhibition rates higher than those described in the literature. The first part of this work studies the influence of concentration, immersion time and temperature on the corrosion inhibitor by electrochemical measurements : polarization curves and electrochemical impedance spectroscopy. The surface analyses conducted by scanning electron microscopy showed the presence of a layer composed of an iron oxide mixture incorporating alkaloids extracts and which leads to the decrease of the corrosion rate. The second part of this work was devoted to the isolation of alkaloids of two extracts in order to determine the alkaloids responsible of the inhibitory activity and thus to determine the adsorption mechanisms. It was showed that the major alkaloids of two extracts is responsible of the inhibition activity

http://www.theses.fr/2013AGUY0578/document