Éditeur(s) : HAL CCSD Elsevier
Résumé : Siberian cratonic mantle
International audience
The processes that control water distribution in nominally anhydrous minerals from peridotites are twofold. Melt depletion will remove water while metasomatism can potentially add water to these minerals. These processes can lead to a wide range of outcomes in water contents, which in turn could play a role in mantle rheology and long-term cratonic root stability. To examine these complexities, water concentrations in minerals from well-characterized peridotites from the Udachnaya kimberlite in the central Siberian craton were analyzed by FTIR. The peridotites span a complete top to bottom cross-section of typical cratonic lithospheric mantle (2-7 GPa and 700-1400 °C). Diffusion modeling of water content profiles across olivine grains shows that water loss during decompression is limited to the 100 μm rims of olivines; the cores preserved their mantle water contents. Water contents range from 6 to 323 ppm wt H2O in olivine, 28-301 ppm H2O in orthopyroxene (opx), 100-272 ppm H2O in clinopyroxene (cpx) and 0-23 ppm H2O in garnet. Melting modeling cannot reproduce the high water contents of cratonic mantle peridotites and any potential partial melting trend must have been erased by later events. The water contents of minerals, however, are correlated with modal abundances of clinopyroxene and garnet, bulk rock FeO, TiO2 and SiO2 as well as with light and middle rare earth elements in clinopyroxene and garnet. These relationships are best interpreted as interaction of residual, melt-depleted peridotites with silicate melt, which produced modal and cryptic metasomatism. Importantly, the water enrichment in the Siberian cratonic mantle took place prior to kimberlite magmatism and eruption. Water addition by metasomatism occurred from pressures >4 GPa all the way to the base of the cratonic root below central Siberia, but was limited to shallower levels (<5 GPa) in the Kaapvaal cratonic lithosphere. The difference in olivine water contents at the deepest levels of the Kaapvaal (<5 ppm H2O) and Siberian (6-323 ppm H2O) cratonic roots may be linked to oxygen fugacity and resulting fluid speciation or, alternatively, to reaction with different metasomatic agents. Calculated viscosities for the deepest Udachnaya samples are similar to those inferred for the asthenosphere. If these xenoliths are representative of the deep cratonic lithosphere, water is not as important a parameter as previously thought in the strength of cratonic lithosphere, otherwise the cratonic root beneath Udachnaya would have been delaminated. Alternatively, the metasomatic xenoliths may not be representative of the Siberian cratonic root and kimberlites preferentially sample cratonic mantle lithosphere material located near, and metasomatized by, melt conduits, which served as channels for upward migration of water-rich melts and fluids including kimberlites. In that case, the cratonic root overall still may have relatively low water contents, which in addition to its less metasomatized (more refractory) and thereby buoyant nature, still play a role in making it strong enough to resist delamination by the surrounding asthenosphere.
ISSN: 0016-7037

hal-01053920
https://hal.archives-ouvertes.fr/hal-01053920
DOI : 10.1016/j.gca.2014.04.011

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
The mantle above a subducting slab is the site of complex interactions between deformation, partial melting, fluid migration and magma transport. To constrain these interactions and their effects on olivine deformation, we analyze microstructures, crystal preferred orientations, and water contents of peridotite xenoliths entrained by andesites of the Avacha volcano, southern Kamchatka arc. These xenoliths are refractory spinel harzburgites that have coarse-grained microstructures with widely spaced subgrain boundaries and sinuous grain boundaries in olivine, consistent with deformation by dislocation creep under low deviatoric stress (< 13 MPa) and with a significant contribution from diffusional processes. Analysis of crystal preferred orientations (CPO) indicates dominant activation of high-temperature, low-stress {0kl}[100] slip systems in olivine and of(100)[001] in orthopyroxene. In most samples, coarse opx crystals, elongated parallel to the lineation, enclose small olivine grains in crystallographic continuity with neighbouring crystals, indicating crystallization of orthopyroxene at the expense of olivine as a result of reactive percolation of Si-rich fluids coeval with the high-temperature deformation. Secondary crystallization of interstitial orthopyroxene led locally to development of opx-rich lenses parallel to the foliation, characterized by a decrease in olivine grain size and dispersion of the olivine CPO without changing the dominant slip systems. Half of the samples also show acicular orthopyroxene aggregates with which is associated a fine-grained matrix composed of rounded strain-free olivine, orthopyroxene, spinel, and rare amphibole crystals. This matrix occurs pervasively along grain boundaries or forms millimeter-scale irregular lenses and anastomosing veinlets that crosscut the coarse crystals and their ductile deformation structures. Both acicular orthopyroxene and the fine-grained matrix are interpreted as resulting from reactive transport of H2O-rich fluids under static conditions, probably in the lithospheric mantle. Infrared analyses show that olivine contains 1-8 center dot 6 ppm by weight of water. These low water contents are similar to those observed in spinel peridotites from other subduction zones and probably record both the low solubility of water in olivine at low pressure and dehydration during exhumation of the xenoliths. Water contents in orthopyroxene are highly variable (25-506 ppm H2O), probably recording spatially heterogeneous interaction with fluids or melts and compositional disequilibrium in the studied samples. Change in the dominant percolation mechanism from porous flow to fracturing suggests cooling, consistent with the low temperatures estimated from pyroxene thermometry (< 800-900 degrees C). The Avacha xenoliths therefore record pervasive deformation of a region of the mantle under asthenospheric conditions, followed by its accretion to the base of the lithosphere, probably as a result of cooling of the mantle wedge. Percolation of Si-rich fluids or hydrous melts is recorded at all stages; this probably enhanced diffusion and lowered deviatoric stresses during ductile deformation, but did not change the dominant slip direction in olivine from [100] to [001].
ISSN: 0022-3530

hal-00456053
https://hal.archives-ouvertes.fr/hal-00456053
DOI : 10.1093/petrology/egp085

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
This study analyses the interactions between deformation and reactive fluid and melt percolation, and their effects on sub-arc mantle seismic properties based on microstructural observations on mantle xenoliths extracted by the Tubaf and Edison seamounts close to the Lihir Island, in the Papua New Guinea archipelago. These xenoliths sample an oceanic lithosphere, which has experienced high-temperature deformation in the presence of fluids or melts. This was followed by metasomatism under static conditions. Syn-kinematic percolation of reactive Si-rich melts or fluids in peridotites has produced pyroxene-enrichment, grain size reduction, and dispersion of olivine crystal preferred orientation (CPO). Fourier transform infrared spectroscopy analyses show that olivine has very low water contents (1-4 wt. ppm H2O), similar to spinel peridotites from other subduction zones. These low values may record both low water solubility in olivine at low pressure and dehydration during transport and exhumation. Water contents in pyroxenes are highly variable and likely result from spatially heterogeneous melt or fluid percolation. Analysis of olivine CPO indicates dominant activation of both (010)[100] and (001)[100] slip systems, which are characteristic of deformation under high temperature, low stress, low pressure and low to moderate hydrous conditions. Fast S-wave polarization and P- and Rayleigh propagation directions are thus parallel to the mantle flow direction. The pyroxene enrichment by melt-rock reactions is accompanied by dispersion of olivine CPO and induces a significant decrease of the maximum S-wave and P-wave anisotropy in the peridotites. The calculated seismic properties also show that the lowest Vp/Vs ratios (< 1.7) mapped in fore-arc mantle may only be explained by taking in consideration the CPO-induced elastic anisotropy of the peridotites.
ISSN: 0040-1951

hal-00950058
https://hal.archives-ouvertes.fr/hal-00950058
DOI : 10.1016/j.tecto.2013.09.024

Éditeur(s) : HAL CCSD Elsevier
Résumé : The uppermost mantle in back arc regions is the site of complex interactions between partial melting, melt percolation, and fluid migration. To constrain these interactions and evaluate their consequences on geochemical cycles, we carried out an in situ trace element and water study of a suite of spinel peridotite xenoliths from two regions of the Japan back arc system, Ichinomegata (NE Japan) and Oki-Dogo (SW Japan), using LA-ICPMS and FTIR spectrometry, respectively. This study provides the first full dataset of trace element and hydrogen compositions in peridotites including analyses of all their main constitutive silicate minerals: olivine, orthopyroxene and clinopyroxene. The Ichinomegata peridotites sample a LREE-depleted refractory mantle (Mg# olivine = 0.90; Cr# spinel = 0.07–0.23; Yb clinopyroxene = 7.8–13.3 × C1-chondrite, and La/Yb clinopyroxene = 0.003–0.086 × C1-chondrite), characterized by Th-U positive anomalies and constant values of Nb/Ta. The composition of the studied Ichinomegata samples is consistent with that of an oceanic mantle lithosphere affected by cryptic metasomatic interactions with hydrous/aqueous fluids (crypto-hydrous metasomatism). In contrast, the Oki-Dogo peridotites have low Mg# olivine (0.86–0.93) and a broad range of compositions with clinopyroxene showing “spoon-shaped” to flat, and LREE-enriched patterns. They are also characterized by their homogeneous compositions in the most incompatible LILE (e.g., Rb clinopyroxene = 0.01–0.05 × primitive mantle) and HFSE (e.g., Nb clinopyroxene = 0.01–2.16 × primitive mantle). This characteristic is interpreted as resulting from various degrees of melting and extensive melt-rock interactions. FTIR spectroscopy shows that olivine in both Ichinomegata and Oki-Dogo samples has low water contents ranging from 2 to 7 ppm wt. H2O. In contrast, the water contents of pyroxenes from Ichinomegata peridotites (113–271 ppm wt. H2O for orthopyroxene, and 292–347 ppm wt. H2O for clinopyroxene) are significantly higher than in Oki-Dogo peridotites (9–35 ppm wt. H2O for orthopyroxene, and 15–98 ppm wt. H2O for clinopyroxene). This indicates a relationship between melt-rock interaction and water concentrations in pyroxenes. Our study suggests that the water content of the Japan mantle wedge is controlled by the late melt/fluid/rock interactions evidenced by trace element geochemistry: a mechanism triggered by magma-rock interactions may have acted as an efficient dehydrating process in the Oki-Dogo region while the Ichinomegata mantle water content is controlled by slab-derived crypto-hydrous metasomatism.
ISSN: 0016-7037

hal-01553105
https://hal.archives-ouvertes.fr/hal-01553105
DOI : 10.1016/j.gca.2017.03.042

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Diffusion parameters for HTO, 36Cl−, and 125I− were determined on Upper Toarcian argillite samples from the Tournemire Underground Research Laboratory (Aveyron, France) using the through diffusion technique. The direction of diffusion was parallel to the bedding plane. The purpose of the present study was 3-fold; it was intended (i) to confirm the I− interaction with Upper Toarcian argillite and to verify the effects of initial I− concentration on this affinity, as previously observed by means of radial diffusion experiments, (ii) to highlight any discrepancy between Cl− and I− diffusivity, and (iii) to investigate the effect of an increase of the ionic strength of the solution on the anionic tracers' diffusive behaviour. The results show that the effective diffusion coefficient (De) and diffusion accessible porosity (εa) values obtained with an ionic strength (I.S.) synthetic pore water of 0.01 eq L−1 are: De = 2.35-2.50 × 10−11 m2 s−1 and εa = 12.0-15.0% for HTO, and De = 14.5-15.5 × 10−13 m2 s−1 and εa = 2.5-2.9% for 36Cl−. Because of anionic exclusion effects, anions diffuse slower and exhibit smaller diffusion accessible porosities than HTO, taken as a water tracer. The associated effective diffusion coefficient (De) and rock capacity factor (α) obtained for 125I are: De = 7.00-8.60 × 10−13 m2 s−1 and α = 4.3-7.2%. Such values make it possible to calculate low 125I distribution ratios (0.0057 < RD < 0.0192 mL g−1) which confirm the trend indicating that the 125I rock capacity factor increases with the decrease of the initial I− concentration. Additional through-diffusion experiments were carried out with a higher ionic strength synthetic pore water (I.S. = 0.11 eq L−1). No evolution of HTO diffusion parameters was observed. The anionic tracers' effective diffusion coefficient increased by a factor of two but no clear evolution of their accessible porosity was observed. Such a paradox could be related to the particularly small mean pore size of the Upper Toarcian argillite of Tournemire. The most significant finding of this study is the large discrepancy (factor of two) between the values of the effective diffusion coefficient for 125I and 36Cl. Whatever the ionic strength of the synthetic solution used, 125I exhibited De values two times lower than those of 36Cl. A detailed explanation for this difference cannot be given at present even if a hypothesis based on ion-pairing or on steric-exclusion cannot be excluded. This makes questionable the assumption usually made for quantifying 125I sorption and postulating that 36Cl and 125I would diffuse in the same porosity. In other terms, at Tournemire, 125I sorption could be more pronounced than previously indicated.
ISSN: 0883-2927

hal-00757749
https://hal.archives-ouvertes.fr/hal-00757749
DOI : 10.1016/j.apgeochem.2011.12.017

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Roussillon sedimentary Basin (South France) is a complex multi-layered aquifer, close to the Mediterranean Sea facing seasonally increases of water abstraction and salinization issues. We report geochemical and isotopic vertical variability in this aquifer using groundwater sampled with a Westbay System® at two coastal monitoring sites: Barcarès and Canet. The Westbay sampling allows pointing out and explaining the variation of water quality along vertical profiles, both in productive layers and in the less permeable ones where most of the chemical processes are susceptible to take place.The aquifer layers are not equally impacted by salinization, with electrical conductivity ranging from 460 to 43,000 μS·cm− 1. The δ2H–δ18O signatures show mixing between seawater and freshwater components with long water residence time as evidenced by the lack of contribution from modern water using 3H, 14C and CFCs/SF6. S(SO4) isotopes also evidence seawater contribution but some signatures can be related to oxidation of pyrite and/or organically bounded S. In the upper layers 87Sr/86Sr ratios are close to that of seawater and then increase with depth, reflecting water–rock interaction with argillaceous formations while punctual low values reflect interaction with carbonate. Boron isotopes highlight secondary processes such as adsorption/desorption onto clays in addition to mixings. At the Barcarès site (120 m deep), the high salinity in some layers appear to be related neither to present day seawater intrusion, nor to Salses-Leucate lagoonwater intrusion. Groundwater chemical composition thus highlights binary mixing between fresh groundwater and inherited salty water together with cation exchange processes, water–rock interactions and, locally, sedimentary organic matter mineralisation probably enhanced by pyrite oxidation.Finally, combining the results of this study and those of Caballero and Ladouche (2015), we discuss the possible future evolution of this aquifer system under global change, as well as the potential management strategies needed to preserve quantitatively and qualitatively this water resource.
ISSN: 0048-9697

hal-01685219
https://hal-brgm.archives-ouvertes.fr/hal-01685219
DOI : 10.1016/j.scitotenv.2016.05.016

Éditeur(s) : HAL CCSD Geological Society of America
Résumé : International audience
Fluid-rock interactions can control earthquake nucleation and the evolution of earthquake sequences. Experimental studies of fault frictional properties in the presence of fluid can provide unique insights into these interactions. We report the first results from experiments performed on cohesive silicate-bearing rocks (microgabbro) in the presence of pressurized pore fluids (H2O, drained conditions) at realistic seismic deformation conditions. The experimental data are compared with those recently obtained from carbonate-bearing rocks (Carrara marble). Contrary to theoretical arguments, and consistent with the interpretation of some field observations, we show that frictional melting of a microgabbro develops in the presence of water. In microgabbro, the initial weakening mechanism (flash melting of the asperities) is delayed in the presence of water; conversely, in calcite marble the weakening mechanism (brittle failure of the asperities) is favored. This opposite behavior highlights the importance of host-rock composition in controlling dynamic (frictional) weakening in the presence of water: cohesive carbonate-bearing rocks are more prone to slip in the presence of water, whereas the presence of water might delay or inhibit the rupture nucleation and propagation in cohesive silicate-bearing rocks.
ISSN: 0091-7613

hal-01054327
https://hal.archives-ouvertes.fr/hal-01054327
DOI : 10.1130/G34916.1

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
During compressive events, deformation in sedimentary basins is mainly accommodated by thrust faulting and related fold growth. Thrust faults are generally rooted in the basement and may act as conduits or barriers for crustal fluid flow. Most of recent studies suggest that fluid flow through such discontinuities is not apparent and depends on the structural levels of the thrust within the fold-and-thrust belt. In order to constrain the paleofluid flow through the Jaca thrust-sheet-top basin (Paleogene southwest-Pyrenean fold-and-thrust belt) this study compares on different thrust faults located at different structural levels. The microstructures in the different fault zones studied are similar and consist of pervasive cleavage, calcite shear veins (SV1), extension veins (EV1) and late dilatation veins (EV3). In order to constrain the nature and the source of fluids involved in fluid-rock interactions within fault zones, a geochemical approach, based on oxygen and carbon stable isotope and trace element compositions of calcite from different vein generations and host rocks was adopted. The results suggest a high complexity in the paleohydrological behaviors of thrust faults providing evidence for a fluid-flow compartmentalization within the basin. Previous studies in the southern part of the Axial Zone (North of the Jaca basin) indicates a circulation of deep metamorphic water, probably derived from the Paleozoic basement, along fault zones related to the major basement Gavarnie thrust. In contrast, in northern part of the Jaca basin, the Monte Perdido thrust fault is affected by a closed hydrological fluid system involving formation water during its activity. The Jaca and Cotiella thrust faults, in turn, both located more to the south in the basin, are characterized by a composite fluid flow system. Indeed, stable isotope and trace element compositions of the first generations of calcite veins suggest a relatively closed paleohydrological system, whereas the late calcite vein generations, which are probably associated with the late tectonic activity of the basin, support a contribution of both meteoric and marine waters. Based on these results, a schematic fluid-flow model is presented. This model allows visualization of three main fluid flow compartments along a N-S transect.
ISSN: 0264-8172

hal-00963606
https://hal.archives-ouvertes.fr/hal-00963606
DOI : 10.1016/j.marpetgeo.2013.09.005

Éditeur(s) : HAL CCSD
Résumé : In coastal carbonate aquifers submitted to a saline intrusion, water - rock interactions processes at the interface between freshwater and saltwater are a cause for heterogeneities development within the porous media. The dissolutions and precipitations induced by the mixing zone play a major role in the transport properties of the reservoir and so in the long term evolution of the saltwater intrusion. The characterization and the in situ observation of a current saline intrusion in the Llucmajor carbonate platform at the experimental site of Ses Sitjoles (South-Easth of Mallorca Island, Spain), allowed to study the temporal evolution of the saltwater intrusion and the biogeochemical processes active in the mixing zone. The influence of microstructure, characterized using X-Ray microtomography, on the petrophysical and flow properties was investigated in laboratory and flow-through experiments were also conducted to study the modifications of the microstructures when submitted to water - rock interactions processes. The mixing zone at the Ses Sitjoles site appears as quite thick and not very sensitive to climate and anthropic stress and is proved to be the locus of active microbiological activity. Laboratory studies highlight a strong control of the microporosity on transport processes and of pCO2 on water - rock interactions. The percolation experiments of slightly reactive waters reveal calcite dissolution together with a decrease in permeability due to a rearrangement of micro-grains within the microporous network.
Les processus d'interactions fluide-roche à l'interface eau douce-eau salée, dans les aquifères carbonatés côtiers soumis à une intrusion saline, sont une des causes du développement d'hétérogénéités dans la structure du milieu poreux. Les dissolutions et/ou précipitations engendrées par la présence de cette zone de mélange jouent un rôle déterminant pour les propriétés de transport du réservoir et donc l'évolution à long terme de l'intrusion d'eau salée. En prenant l'exemple de la plateforme carbonatée de Llucmajor au niveau du site expérimental de Ses Sitjoles (Sud-Est de Majorque, Espagne), un travail de caractérisation et d'observation in situ à moyen terme de l'intrusion saline actuelle de ce réservoir permet de décrire son évolution temporelle et les processus biogéochimiques actifs dans la zone de mélange. L'influence de la microstructure du milieu poreux, caractérisée par microtomographie RX, sur les propriétés pétrophysiques et hydrodynamiques est étudiée en laboratoire et des expériences de percolations d'eaux réactives (mélanges eau douce - eau salée et eau pure chargée en CO2) sont réalisées afin d'étudier les modifications de ces microstructures lorsqu'elles sont soumises à des interactions eau - roche. La zone de mélange eau douce - eau salée rencontrée au niveau du site de Ses Sitjoles est large et peu sensible aux contraintes extérieures (climatologiques et anthropiques) et constitue un lieu d'activité microbiologique particulièrement actif. En laboratoire, on observe un fort contrôle des phénomènes de transport par la microporosité et des processus d'interactions eau - roche par la pCO2. Dans le cas d'une percolation de fluides moyennement réactifs, les expériences mettent en évidence une dissolution de calcite accompagnée par une diminution de la perméabilité, liée à un réarrangement des micro-grains à l'intérieur du réseau microporeux.
https://tel.archives-ouvertes.fr/tel-00767152

tel-00767152
https://tel.archives-ouvertes.fr/tel-00767152
https://tel.archives-ouvertes.fr/tel-00767152/document
https://tel.archives-ouvertes.fr/tel-00767152/file/thesegaring.pdf

Éditeur(s) : HAL CCSD
Résumé : Fault zones are major discontinuities in sedimentary basins. Understanding their role on fluid migrations is an essential issue to (i) characterize the mechanisms and kinematics of deformation and (ii) to determine the parameters which control the distribution of energetic or mineral resources. This work applies to faulting under a temperature range of 200-250°C, corresponding to that of deeply buried reservoirs as well as potentially seismogenic fault zones. The studied faults are normal faults affecting the “Grès d’Annot” Formation, a Priabonian-Rupelian siliclastic turbidite succession of the Alpine foreland basin. They are located in two distinct areas: the Moutière-Restefond area in the eastern part of the basin and the Estrop area in the western part. Vitrinite reflectance outside fault zones indicates maximal temperatures of 240-260°C at Moutière-Restefond and 170-200°C at Estrop, i.e. burial depths around 8 km and 6 km, respectively, assuming a mean geothermal gradient of 30°C/km. Burial was due to underthrusting below the Embrunais-Ubaye Alpine nappes, the difference in burial between the two areas traducing the westward taper of the nappe front.The studied faults affect alternating arkosic sandstone beds and pelite layers with offsets from centimeters to decameters. Two types of core zones are recognized: (1) the foliated core zones of the Moutière-Restefond area, where deformation dominated by pressure solution and synkinematic phyllosilicate neoformation resulted in a foliated fabric, and (2) the core zones of the Estrop area, characterized by dilatant quartz-mineralized veins and breccia. Fault and host rock petrophysical properties were measured on drill plugs, using the water porosity technique and nitrogen permeability technique under 2 Mpa of confining pressure. In the Moutière-Restefond fault zones, plug axes were oriented in three orthogonal directions corresponding to the main deformation axes (X, Y, Z) of the foliated arkose to characterize the effect of structural anisotropy. In the Estrop fault zones, where deformation does not show equivalent anisotropy, the plug axes were oriented according to the main fault plane orientation (i.e., parallel to azimuth, parallel to dip and normal). In each fault zone, the porosity of fault rocks is equivalent to that of host rocks. In the Moutière-Restefond fault zones, the plugs parallel to the X and Z axes of deformation have a permeability similar to that of the host rocks, whereas permeability parallel to the Y axis (i.e. parallel to the foliation and the main fault plane) is one order of magnitude higher. By contrast, the permeability values in the Estrop fault zones are isotropic and equivalent to the host rock values. This study highlights the importance of various types of deformation mechanisms and related fluid-rock interactions in determining different fault rock types within a similar protolith, ultimately controlling distinct petrophysical properties of fault zones.
Les zones de failles constituent des discontinuités majeures dans la croûte supérieure. Ce mémoire s’intéresse aux failles actives à des profondeurs de 5-8 km, i.e. dans des conditions pouvant jouer un rôle important (i) sur le comportement mécanique de de la croûte, en particulier sur son potentiel sismogénique et (ii) sur la compartimentation des réservoirs géologiques profondément enfouis.Les failles étudiées sont des failles normales (rejet jusqu’à 50 mètres) affectant des alternances de bancs de grès arkosiques et de pélites dans les Grès d’Annot, une formation turbiditique d’âge priabonien-rupélien du bassin d’avant-chaine alpin. Les Grès d’Annot ont été enfouis sous les nappes de l’Embrunais-Ubaye peu de temps après leur dépôt et exhumés au Miocène moyen-supérieur. L’étude a été réalisée dans deux secteurs des Alpes de Haute-Provence, (1) le secteur de l’Estrop (chaine des Trois Evéchés, dans la partie occidentale du bassin) et (2) le secteur de Point Vert-Restefond (alentours du col de la Bonette, dans la partie orientale du bassin). La réflectance de la vitrinite dans les Grès d’Annot indique des températures maximales de 160-190°C dans le secteur (1) et de 240-260 °C dans le secteur (2) , soit des profondeurs d’enfouissement de 5-6 km et 8-10 km, respectivement, dans l’hypothèse d’un gradient géothermique moyen de 25-30°C/km. A partir des observations microstructurales, de données d’inclusions de fluides, de modélisations thermodynamiques sur chlorites syncinématiques et des indices de cristallinité de l’illite, on a établi que les failles du secteur (1) ont fonctionné à une température d’environ 200°C pour une pression de 0.6Kbar et celles du secteur (2) dans une gamme de température de 200-220°C et de pression comprise entre 0.6 et 1.1 Kba. L’activité de la faille de Point-Vert a été datée par la méthode 40Ar/39Ar au Miocène inférieur (21 Ma). Ces failles sont interprétées comme associées aux premiers stades du soulèvement résultant de l’activité des chevauchements dans le socle sous-jacent.Deux types principaux de roches de failles caractérisent les failles étudiées. Les brèches dilatantes sont majoritaires dans les zones de failles du secteur (1) alors que les arkoses foliées sont majoritaires dans les zones de failles du secteur (2). Les brèches dilatantes témoignent de mécanismes de déformation dominés par la fracturation transgranulaire et la pression-solution des silicates. Ce dernier mécanisme se manifeste principalement par d’abondantes précipitations cycliques de quartz, les stylolites restant peu développés. Les géométries structurales sont associées à l’activation de plans T de Riedel déterminant l’ouverture de relais extensifs et un régime localement dilatant. Nous associons ce type de roche de faille à une faible pression effective au cours de la déformation.La déformation cisaillante exprimée dans les arkoses foliées témoigne de mécanismes de déformation dominés par (i) la fracturation intragranulaire et transgranulaire, (ii) la pressionsolution/ précipitation des silicates, principalement le quartz, (iii) la néoformation de micas blancs liée à l’altération des feldspaths et (iv) la précipitation de chlorite. Ce travail montre également que les transformations minéralogiques liées aux interactions fluide-roche dans la zone de faille (forte augmentation de la proportion des phyllosilicates au dépend des feldspaths) changent radicalementla composition minéralogique de la roche. Nous associons ce type de roche de faille à une forte pression effective au cours de la déformation.La pétrophysique montre que les brèches de failles (secteur 1) ont une perméabilité isotrope et équivalente à celle du protolithe (10-3mD sous 2 MPa de confinement) tandis que les roches foliées (secteur 2) montrent une augmentation de perméabilité (10-2mD) selon l’axe Y de la déformation, d’un ordre de grandeur supérieure aux perméabilités suivant les axes X et Z et dans la roche hôte (10-3mD). Ce drain préférentiel potentiel est associé à l’orientation des phyllosilicates dans la foliation.
https://hal.archives-ouvertes.fr/tel-01310382

tel-01310382
https://hal.archives-ouvertes.fr/tel-01310382
https://hal.archives-ouvertes.fr/tel-01310382/document
https://hal.archives-ouvertes.fr/tel-01310382/file/Th%C3%A8seCAVAILHES2012.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The present study reports data on CO2-rich geothermal waters and their associated carbonate deposits from the SW part of the Permian Lodève Basin (South of France). Both waters and carbonates are enriched in 226Ra, with activities up to 2.2 Bq/L and 3.5 Bq/g respectively. A series of carbonate samples precipitated around the studied wells since 1990 were dated through the 226Ra-210Pb and 228Ra-228Th methods, and the results are discussed in a new Concordia diagram. While both methods give comparable dates for many samples, Ra-Pb ages are sometimes much older than Ra-Th ages. We propose that these discrepancies result from the adsorption of 222Rn daughter nuclides in such a Rn-rich environment. The (228Ra/226Ra)0 activity ratios calculated at the time of deposition are remarkably constant for about 12 years, suggesting the presence of a steady-state aquifer. The low (228Ra/226Ra)0 ratios (0.348 ± 0.008) are best explained if most of the Ra derives from the Cambrian carbonate series (mainly dolostone) underlying the Permian Basin, which have low Th/U and similar (228Ra/226Ra) ratios. This study suggests that Ra and other alkaline-earth elements do not necessarily originate from the rocks surrounding the deep geothermal reservoir, but rather may be introduced into the CO2-rich water during its transfer towards the surface and interaction with carbonate rocks.
ISSN: 0009-2541

hal-01053715
https://hal.archives-ouvertes.fr/hal-01053715
DOI : 10.1016/j.chemgeo.2014.02.008

Éditeur(s) : HAL CCSD
Résumé : International audience
In the context of climate change, this study presents the ability of major/trace elements together with strontiumisotopes to trace back water paths at small scale and to deconvolve the geochemical signal of a small watershedsubject to intense flash floods episodes (Peyne, Hérault, France). Two small sub-basins draining distinct lithologiesin their heads (Plio-Villafranchian conglomerate versus Triassic gypsum-rich marls and dolomites) and the sameMiocene lithology downstream are investigated.Major elements and Ca/Na vs. Mg/Na ratios classically applied at large scale to distinguish carbonate from silicateweathering, allow here discriminating the three main lithologies from the two sub-basins. Trace elements Rband Sr coupled to calcium, also allow this lithological discrimination but in addition the Ca/Rb vs. Sr/Rb tracersappear to be much more discriminant for the various hydrological conditions. Thus, in combination with detailedlithological descriptions, they allow identifying the different facies that imprint the water signature through water-rock interaction according to the hydrological conditions.Strontium isotopes and Rb/Sr ratio, discriminate more precisely the drained lithologies of the 2 sub-basins. Firstly,the 87Sr/86Sr ratios allow identifying the nature of the lithologies and their main component(s) contributing to theSr budget in water and thus imprint the isotopic signature. Secondly, Sr isotopes evidenced two distinct Miocenefacies: the detritric faction (sandy marls), and the marine carbonates.The geochemical signatures of the brook samples draining both compartments were compared to the signatureof the Peyne River outlet just before the confluence into the Hérault River. It appears that the signature of thePeyne River, integrating all the water draining the basin, is relatively stable whatever the hydrological conditionsand mainly marked by the Miocene formations. Sr isotopes further highlight that this signature seems to resultfrom the mixing of both Miocene facies present in the lower part of the Peyne watershed, i.e. the sandy marls andthe carbonates. The typical signatures of the Plio-Villafanchian conglomerates and Triassic gypsiferous marls anddolomites of the headwaters of each sub-basin are completely hidden by the Miocene signatures. This should berelated to the large drainage area of the Miocene compared to other lithologies, despite the high solubility of thegypsum formations releasing large quantities of dissolved elements in solution.Understanding water paths at small scale is even more efficient when the geochemical approach is coupled with adetailed geological description. Indeed, the geochemical tracers are extremely dependent on the facies sequences(morphology) and of the soil nature (mineralogical composition), this is particularly sensitive at small scale.In the context of climate change increasing the intensity of rain events in the Mediterranean region, and resultingin catastrophic floods events (flash floods), tracing the origin of water contributing to the runoff is of primaryimportance and this must be investigated at small scale. Geochemical and isotopic fingerprinting thus constituteexcellent tools which can help to define the area of interest to be monitored in the framework of flood forecast andwarning networks
EGU General Assembly 2015
Vienne, Austria

hal-01118622
https://hal-brgm.archives-ouvertes.fr/hal-01118622

Éditeur(s) : HAL CCSD Inter-Research
Résumé : International audience
Ecological connectivity is important for effective marine planning and biodiversity conservation. Our aim was to identify factors important in influencing variation in benthic community structure on shallow rocky reefs in 2 regions of the Mediterranean Sea with contrasting oceanographic regimes. We assessed beta (β) diversity at 146 sites in the littoral and shallow sub-littoral from the Adriatic/Ionian Seas (eastern region) and Ligurian/Tyrrhenian Seas (western region) using a null modelling approach to account for variation in species richness. The distance decay relationship between species turnover within each region and geographic distance by sea was determined using generalised linear models. Mantel tests were used to examine correlations between β diversity and connectivity by ocean currents, estimated from Lagrangian dispersal simulations. Variation in β diversity between sites was partitioned according to environmental and spatial components using a distance-based redundancy approach. Species turnover along a gradient of geographic distance was greater by a factor of 3 to 5 in the western region than the eastern region, suggesting lower con-nectivity between sites. β diversity was correlated with connectivity by ocean currents at both depths in the eastern region but not in the western region. The influence of spatial and environmental predictors of β diversity varied considerably between regions, but was similar between depths. Our results highlight the interaction of oceanographic, spatial and environmental processes influencing benthic marine β diversity. Persistent currents in the eastern region may be responsible for lower observed β diversity compared to the western region, where patterns of water circulation are more variable.
Marine Ecology Progress Series

Droits : http://creativecommons.org/licenses/by/
hal-01357935
https://hal-univ-perp.archives-ouvertes.fr/hal-01357935
https://hal-univ-perp.archives-ouvertes.fr/hal-01357935/document
https://hal-univ-perp.archives-ouvertes.fr/hal-01357935/file/m553p001.pdf
DOI : 10.3354/meps11783

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
Electrical resistivity soundings are used by geophysicists to determine the structure and composition of the Earth's crust and mantle and to explore natural resources (ore, oil, gas, water). Their interpretations in terms of composition and in-situ physical conditions depend mainly on laboratory measurements of electrical conductivity of rocks at simulated crustal conditions of temperature, pressure, saturation and pore pressures. These measurements present a numbers of limitations, in particular, in the case where conductive pore fluids are present, as in the case of deep reservoir conditions, where temperature exceeds 250 A degrees C. Here, we present a new cell capable of measuring electrical conductivity of large saturated samples at confining pressure up to 200 MPa, pore pressure up to 50 MPa, and temperature up to 500 A degrees C. The measurement cell has been developed in a commercial, internally heated, gas pressure apparatus (Paterson press). It is based on the concept of "guard ring" electrode, which is adapted to samples that are jacketed by a very conductive, metallic material. Numerical modeling of the current flow in the electrical cell allowed defining the optimal cell geometry. Calibration tests have been performed on Fontainebleau sandstones saturated with electrolytes of different conductivities, up to 350 A degrees C. The resulting electrical formation factor and temperature dependence of electrical conductivity are in very good agreement with previous studies. This new cell will improve the exploration and exploitation of deep fluid reservoirs, as in unconventional, high enthalpy geothermal fields. In particular, the investigations address possible effects of fluid-rock interactions on electrical resistivity of a reservoir host rock.
ISSN: 0169-3913

hal-00681997
https://hal.archives-ouvertes.fr/hal-00681997
DOI : 10.1007/s11242-011-9846-2

Éditeur(s) : HAL CCSD American Geophysical Union (AGU) American Geophysical Union
Résumé : International audience
Environmental magnetism of speleothems is still in its early stage of development. Here we report on our investigation of the environmental and paleomagnetic information that has been recorded in speleothems, and what are the factors that control its preservation and reliability. To address these issues, we used a multidisciplinary approach, including rock magnetism, petrography, scanning electron microscopy, stable carbon and oxygen isotope compositions, and major and trace element concentrations. We applied this to a set of samples from different stages of speleothem evolution: present-day dripwater (glass plates), a weathered stalactite, a fresh stalagmite, cave sediments, and terra rossa soils. These samples come from the Penico and Excentricas caves, located in two distinct aquifers of the Algarve region, South Portugal. Our results show that the main magnetic carriers of the speleothems under study are primary (detrital) and consist of maghemite (and magnetite?). Similarities in coercivity and temperature dependence of the studied set of samples suggest that iron oxides are inherited from the terra rossa soils that cap the cave and were transported to the speleothems by dripwater. Hence, they represent a regional environmental signature. Interestingly, a stable and probably detrital remanent magnetization could be isolated in the fresh stalagmite, whereas the weathered stalactite yielded chaotic magnetic directions and very low remanent intensities. We propose that these low intensities can be the result from (i) different remanence acquisition mechanisms between stalagmite and stalactite and/or (ii) iron dissolution by fungal activity. We also suggest that magnetic properties and color and the content in detrital elements in the fresh speleothem inform about environmental processes acting on the interface of rock (soil)-atmosphere, while oxygen isotope composition and alkaline-earth element concentrations inform about calcite-water interaction processes. These results provide a better understanding of how environmental information is recorded in speleothems and what the factors are that control the reliability of the paleomagnetic and paleo-environmental signal.
ISSN: 0148-0227

hal-01114953
https://hal.archives-ouvertes.fr/hal-01114953
DOI : 10.1002/2014JB011381

Éditeur(s) : HAL CCSD
Résumé : International audience
The giant Imiter silver mine located at the northern edge of the West African craton in Morocco is assumed to be a late Neoproterozoic epithermal deposit mainly characterized by a hypogene paragenesis of Agrich sulphides and sulfosalts, and Ag-Hg alloys occuring preferentially in quartz-rich veins. The secondary enrichment zone at Imiter reaches a thickness of 50 to 150 m below ground surface. The upper levels, famous because of giant native silver crystals, grade up to 300 kg/t. Metallographic observations, SEM-EDS and XRD analyses reveal the presence of a quite complex secondary paragenesis made of acanthite, cinnabar, imiterite, perroudite, cerussite, mimetite, iron oxyhydroxides, synchisite and coronadite. Supergene alteration processes of the giant Imiter silver mine deposit consist of the remobilisation of the primary hypogene paragenesis by (i) deep and old basinal brines and (ii) downward infiltrations of surficial waters becoming progressively more reduced and F-enriched in response to fluid-rock interactions. Development of such a supergene mineralization strongly suggests prevalence of arid to semiarid conditions.
Let's talk ore deposits, proceeding of the eleventh biennial sga meeting
Antofagasta, Chile

hal-00601984
https://hal-brgm.archives-ouvertes.fr/hal-00601984
https://hal-brgm.archives-ouvertes.fr/hal-00601984/document
https://hal-brgm.archives-ouvertes.fr/hal-00601984/file/SGA2011_0234.pdf

Éditeur(s) : HAL CCSD CRC Press Taylor & Francis Group
Résumé : aucun
Water-Rock Interaction XIII

hal-00857370
https://hal.archives-ouvertes.fr/hal-00857370

Éditeur(s) : HAL CCSD CRC Press Taylor & Francis Group
Résumé : In the chapter : Role of water-rock-gas interaction in sequestration of CO2
Water-Rock Interaction XIII

ISBN : 978-0415604260
hal-00855782
https://hal.archives-ouvertes.fr/hal-00855782