Éditeur(s) : Gauthier-Villars
Résumé : The distribution and behaviour of nutrients (nitrate, nitrite, ammonia, silicate and phosphate) have been examined over the course of a year in two major Scottish estuaries, the Forth and Tay. Maximum concentrations of nitrate and silicate in both estuaries occur in winter, when mixing is conservative. By contrast maximum phosphate, ammonia and nitrite concentrations (notably in the Forth) are observed in summer, these are related to lower oxygen concentrations both within the water column and sediments. Phosphate, ammonia and nitrite concentrations are high in the Forth relative to the Tay. Phosphate behaviour in plots for both estuaries show some common features including removal at low salinity, mid estuary inputs and simple dilution at high salinity. The results are interpreted on the basis of removal onto particles at low salinity followed by desorption at higher salinity together with an input from sediment porewaters. In the Forth the phosphate flux from sediments during the summer is estimated to be 1.98 +/- 1.25 mmol m-2 day-1. At this time the river input of phosphorus is only 10- 14 % of the mid estuary input. Under low river flow conditions in summer a large turbidity maximum (400-500 mg l-1 suspended solids) develops in the Forth estuary and this results in removal of phosphate. Removal is less dramatic in the Tay estuary as the turbidity is wind generated and therefore rarely exceeds 100 mg 1-1. Water quality in the Forth (as defined by the occurrence of low dissolved oxygen concentrations and the presence of species such as ammonia and nitrite) is inferior to that of the Tay. Relative to contaminated estuaries however concentrations in both estuaries are low. By virtue of its high fresh water discharge the Tay is a more significant source of nitrate to the North Sea during the winter than is the Forth. In the Forth bacterial mineralisation and nitrification of organic nitrogen occurs in the upper estuary, this results in an input of nitrate and consumption of dissolved oxygen. Further downstream broad mid estuarine peaks of nitrite and ammonia are observed indicative of a benthic source. Estimates of this source for ammonia and nitrite are 19-44 and 3.9-8.1 mmol m-2 day-1 respectively. In winter the main source of nitrogen to the Forth is from the river but in summer mid estuarine sources dominate. In the outer Tay a peak in dissolved ammonia is estimated to represent an input of 0.5-1.1 tonnes N day-1, this is attributed to sewer inputs from Dundee.
Oceanologica Acta (0399-1784) (Gauthier-Villars), 1992 , Vol. 15 , N. 3 , P. 261-277

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/00100/21160/18779.pdf
http://archimer.ifremer.fr/doc/00100/21160/

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
A new method was proposed to determine the nitrogen content of nitrocelluloses (NCs). It is based on the finding of a linear relationship between the nitrogen content and the molar ratio of nitrite-to-nitrate ions released after alkaline hydrolysis. Capillary electrophoresis was used to monitor the concentration of nitrite and nitrate ions. The influences of hydrolysis time and molar mass of NC on the molar ratio of nitrite-to-nitrate ions were investigated, and new insights into the understanding of the alkaline denitration mechanism of NCs, underlying this analytical strategy is provided. The method was then tested successfully with various explosive and non-explosive NC-containing samples such as various daily products and smokeless gunpowders. Inherently to its principle exploiting a concentration ratio, this method shows very good repeatability in the determination of nitrogen content in real samples with relative standard deviation (n=3) inferior to 1.5%, and also provides very significant advantages with respect to sample extraction, analysis time (1h for alkaline hydrolysis, 3min for electrophoretic separation), which was about 5 times shorter than for the classical Devarda's method, currently used in industry, and safety conditions (no need for preliminary drying NC samples, mild hydrolysis conditions with 1M sodium hydroxide for 1h at 60°C).
Journal of Hazardous Materials

hal-01103120
https://hal.archives-ouvertes.fr/hal-01103120
PUBMED : 25562808

Éditeur(s) : HAL CCSD IWA Publishing
Résumé : International audience
UV spectrophotometry is largely used for water and wastewater quality monitoring. The measurement/estimation of specific and aggregate parameters such as nitrate and dissolved organic carbon (DOC) is possible with UV spectra exploitation, from 2 to multi wavelengths calibration. However, if nitrate determination from UV absorbance is known, major optical interferences linked to the presence of suspended solids, colloids or dissolved organic matter limit the relevance of UV measurement for DOC assessment. A new method based on UV spectrophotometric measurement of raw samples (without filtration) coupling a dual pathlength for spectra acquisition and the second derivative exploitation of the signal is proposed in this work. The determination of nitrate concentration is carried out from the second derivative of the absorbance at 226 nm corresponding at the inflexion point of nitrate signal decrease. A short optical pathlength can be used considering the strong absorption of nitrate ion around 210 nm. For DOC concentration determination the second derivative absorbance at 295 nm is proposed after nitrate correction. Organic matter absorbing slightly in the 270-330 nm window, a long optical pathlength must be selected in order to increase the sensitivity. The method was tested on several hundred of samples from small rivers of two agricultural watersheds located in Brittany, France, taken during dry and wet periods. The comparison between the proposed method and the standardised procedures for nitrate and DOC measurement gave a good adjustment for both parameters for ranges of 2-100 mg/L NO3 and 1 30 mg/L DOC. (C) 2016 Elsevier Ltd. All rights reserved.
ISSN: 0043-1354

hal-01460742
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01460742
DOI : 10.1016/j.watres.2016.11.010
PUBMED : 27838025

Résumé : The hydrological (temperature, salinity, nitrate, nitrite, ammonium, phosphate and dissolved oxygen) and phytoplanktonic (biomass and cell abundances) results obtained on the points of Jobourg and Barneville during the nine 2006 cruises, do not enable the characterisation of an influence of non-active waste from the AREVA NC plant of La Hague on the environment.
Les résultats des paramètres hydrologiques (température, salinité, nitrate, nitrite, ammonium, phosphate et oxygène dissous) et phytoplanctoniques (biomasse et abondances cellulaires) obtenus sur les points Jobourg et Barneville lors des neuf campagnes annuelles de 2006, ne permettent pas de mettre en évidence une influence des rejets non actifs de l'usine AREVA NC de La Hague sur l'environnement.

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/2007/rapport-3835.pdf
http://archimer.ifremer.fr/doc/00000/3835/

Éditeur(s) : Edp Sciences S A
Résumé : A study on nitrogenous and phosphorous waste production in European seabass (Dicentrarchus labrax) was carried out in a flow-through land-based farm. The main objectives were (i) to calculate nitrogenous (N) and phosphorous (P) waste production (particulate and dissolved) from in situ measurements for different rearing ponds with specific fish biomasses, fish sizes and flow rates, (ii) to establish nitrogenous and phosphorous waste production budgets, ratios and equations, and (iii) to compare, for the whole farm, in situ measurements to estimate N and P waste production from waste equations. Waste production was manifest by an increase in concentrations of total ammonia nitrogen, total Kjeldhal nitrogen, particulate nitrogen, dissolved phosphorus and total phosphorus concentrations in the outlet water compared to the inlet water for both batches and whole farm. However, no production of nitrite or nitrate was observed. In our budgets, the N and P amounts from biomass gains and wastes were explained by the N and P derived from feed over the range 83.9-105.2 % and 66.5-104.6 % respectively, depending on the fish batch. Values were respectively 103.4 and 87.5 % for the same calculations in the farm. When the whole-farm waste production was calculated from previous equations derived from batches, and then compared with the measured data, the percentages of recovery (estimated by the ratio predicted data/measured data) were 88 and 94 % for total-N and total-P respectively.
L'étude de la production des déchets (azote et phosphore) d'une ferme de production de bars (Dicentrarchus labrax) est réalisée. Cette étude à pour objectif (i) de mesurer in situ la production des déchets azotés et phosphores sous forme particulaire et soluble, pour différents bassins d'élevage présentant des caractéristiques variables en terme de biomasse de poisson, de taille des poissons, de débit de l'eau de renouvellement, (ii) d'établir des équations de production de déchets à partir des données précédemment acquises, (iii) de comparer, pour l'ensemble des rejets au niveau de la ferme, les résultats obtenus par des mesures in situ, d'une part, et à l'aide des équations, d'autre part. La production de déchets se traduit par une augmentation des concentrations de l'azote particulaire, de l'azote ammoniacal, de l'azote organique dissous, ainsi que du phosphore particulaire et dissous. Aucune augmentation des nitrates et nitrites n'est observée. L'établissement des budgets d'azote et de phosphore permettent de rendre compte, selon les bassins, du devenir de 88,2 à 105,2 % de l'azote et de 66,2 à 104,6 % du phosphore introduits dans les bassins sous forme de nourriture en granulés. L'étude des budgets réalisée par les deux méthodes (mesures in situ et utilisation des équations) montre que les budgets établis à l'aide des équations rendent compte respectivement de 88 et 94 % de récupération de l'azote et du phosphore. Ces résultats sont respectivement de 103,4 et 87,5 % lorsqu'ils sont établis par des mesures in situ.
Aquatic Living Resources (0990-7440) (Edp Sciences S A), 1998-07 , Vol. 11 , N. 4 , P. 247-254

Droits : 1998 Published by Elsevier SAS
http://archimer.ifremer.fr/doc/1998/publication-872.pdf
DOI:10.1016/S0990-7440(98)89007-4
http://archimer.ifremer.fr/doc/00000/872/

Éditeur(s) : HAL CCSD Nature Publishing Group
Résumé : International audience
Seabirds concentrate nutrients from large marine areas on their nesting islands playing an important ecological role in nutrient transfer between marine and terrestrial ecosystems. Here we investigate the role of guano on corals reefs across scales by analyzing the stable nitrogen isotopic (delta N-15) values of the scleractinian coral Pocillopora damicornis on fringing reefs around two Pacific remote islets with large seabird colonies. Marine stations closest to the seabird colonies had higher nitrate + nitrite concentrations compared to more distant stations. Coral and zooxanthellae delta N-15 values were also higher at these sites, suggesting that guano-derived nitrogen is assimilated into corals and contributes to their nitrogen requirements. The spatial extent of guano influence was however restricted to a local scale. Our results demonstrate that seabird-derived nutrients not only spread across the terrestrial ecosystem, but also affect components of the adjacent marine ecosystem. Further studies are now needed to assess if this nutrient input has a positive or negative effect for corals. Such studies on remote islets also open fresh perspectives to understand how nutrients affect coral reefs isolated from other anthropogenic stressors.
ISSN: 2045-2322

hal-01681575
https://hal.archives-ouvertes.fr/hal-01681575
DOI : 10.1038/s41598-017-03781-y

Résumé : Dans le cadre de l'extension du RNO aux Antilles, un exercice d"intercomparaison des laboratoires pressentis pour effectuer les analyses du volet « hydrologie » a été organisé par l'IFREMER fin 2000-début 2001. L'exercice comportait l'analyse de cinq paramètres : salinité, nitrate, nitrite, ammonium et phosphate. Chacun des paramètres devait être analysé à deux niveaux de concentration. Les participants étaient au nombre de 3. Chaque laboratoire a reçu deux flacons de 250 ml pour la salinité et huit flacons de 150 ml pour les nutriments (un flacon par paramètre et par niveau). Les laboratoires étaient informés qu'ils devaient analyser les échantillons dans un délai de six semaines environ après réception, ce qui limitait les risques de dérive potentielle des concentrations pouvant provenir d'une instabilité accidentelle des échantillons. L'expédition a été effectuée au début décembre 2000, ce qui a permis une mise à disposition des échantillons dans les laboratoires pour la fin décembre. Ce rapport analyse les résultats de l'exercice et présente une interprétation de ceux-ci.

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/00018/12911/9866.pdf
http://archimer.ifremer.fr/doc/00018/12911/