Éditeur(s) : HAL CCSD
Résumé : Iran covers a large area limited in longitude by the meridians 44°E and 64°E and in latitude by the parallels 25°N and 40°N. Mapping a new gravity field over Iran is the first important data for geodetic, geophysicaland geodynamical considerations. In this thesis, the gravity measurements are used to determine the gravimetric geoid over Iran. This geoid is coupled with the GPS height and altitude (levelling) to realize an operational vertical surface at the territory of Iran. The contribution of the principal geodetic and gravimetric works realized in recent years are the establishment of: 1) the national absolute gravity network of Iran (NAGNI09), 2) the national gravity calibration line of Iran (NGCLI10) and 3) the multi-observations geodetic and gravimetric network of Iran (MPGGNI10). The absolute gravity network consists in 24 stations where the gravity measurement has been realized with the help of gravimeters FG5, with a precision better than 5μ Gal. The repetition of the observations at two stations between 2000 and 2007 makes obvious the inter-annual variations of gravity in relation of the amount of underground water changes and (or) tectonic deformation. The absolute gravity network has served the base stations for the realization of the MPGGNI10 geodetic and gravimetric network with a mesh of 55 km, at which the gravity is measured with the help of relative gravimeters CG-5 and CG-3/M, the GPS height and the altitude with a precision of 0.010 mGal, 0.03 m, and 3mm km respectively. The remove-restore technique coupled with the Helmert's condensation method is chousen to compute a new gravimetric geoid model, IRGeoid10, with a absolute and relative precision of the order of 0.26 m and 2.8 ppm respectively. The gravimetric geoid is adjusted at the GPS/levelling points to define new vertical reference surface over Iran
L'Iran couvre une grande superficie en longitude entre les méridiens 44°E et 64°E et en latitude entre les parallèles 25°N et 40°N. la cartographie de champ de pesanteur sur l'Iran est de premiére importance pour des considérations d'ordre géodésique, géophysique et geodynamique. Dans cette thèse, les mesures de pesanteur sont utilisées pour déterminer le géoïde gravimétrique sur l'Iran. Ce géoïde est couplé à la mesure de hauteur GPS et d'altitude (nivellement) pour réaliser une surface verticale opérationnelle sur le territoire Iranien. La contribution aux principaux travaux géodésiques et gravimétriques réalisés ces dernières années porte sur l'établissement: 1) du réseau national de gravimétrique absolu de l'Iran (NAGNI09), 2) de la ligne nationale d'étalonnage de gravimétrique de l'Iran (NGCLI10), 3) du réseau multi- observations géodésiques et gravimétriques de l'Iran (MPGGNI10). Le réseau gravimétrique absolu, comporte 24 stations où la mesure de la pesanteur a été réalisée à l'aide de gravimètres FG5, avec une précision meilleure que 5μ Gal. La répétition des observations sur deux sites entre 2000 et 2007 met en évidence des variations inter-annuelles de la pesanteur en relation avec l'évolution du contenu en eau du sous-sol et (ou) la déformation tectonique. Le réseau a servi de point d'appui pour la réalisation du réseau géodésique et gravimétrique MPGGNI10 de maille 55 km sur lequel a été mesuré la pesanteur à l'aide des gravimètres relatifs CG5 et CG-3/M, la hauteur de GPS et l'altitude avec une précision respectivement de 0.010 mGal, 0.03 m et 3mm km . La technique de retrait- restoration couplée à la méthode de condensation de Helmert a permis de calculer un nouveau modèle de géoïde gravimétrique, IRGeoid10, avec une précision absolue et relatif respectivement de l'ordre de 0.26m et 2.8 ppm. Ce géoïde est ajusté aux points GPS nivelés pour définir un nouveau référentiel des altitudes sur l'Iran.
https://tel.archives-ouvertes.fr/tel-00627614

tel-00627614
https://tel.archives-ouvertes.fr/tel-00627614
https://tel.archives-ouvertes.fr/tel-00627614/document
https://tel.archives-ouvertes.fr/tel-00627614/file/TheseYaghoubHatamDef.pdf

Éditeur(s) : HAL CCSD Royal Society of Chemistry
Résumé : International audience
Low-level water measurements of geological materials are fundamental in understanding the volatile inventories of the Earth from the mantle to crustal reservoirs. Here we describe the development of microanalytical techniques using the new SHRIMP SI ion microprobe to measure the abundances of OH− (as a proxy for water) in volcanic glass and nominally anhydrous minerals (NAMs). Samples were first analysed at the Carnegie Institute of Washington (CIW) on their Cameca ims-6f with calibrations based on previous FTIR and manometry analyses. SHRIMP SI is a large geometry ion microprobe and is currently mainly used for O and S isotope analyses. The analytical protocol used here incorporates multiple collection of 16O− and 16O1H− allowing rapid measurements. A single calibration line incorporating all glasses and NAMs for the SHRIMP SI allows calibration of 16O1H−/16O− to H2O over a wide range in concentration (50 to 15 000 ppm H2O). This calibration line has around a 10% uncertainty, which appears to be limited only by sample heterogeneity. The current background for SHRIMP analysis is between 20–40 ppm but this is expected to improve with improved pumping on the source chamber. A current limitation to water analysis of NAM samples, by any technique, is having a range of standard materials to enable OH− calibration to absolute H2O concentrations. Data are presented for 7 NAM samples (2 olivines, 2 orthopyroxenes and 3 clinopyroxenes) that appear to be promising as potential standards for international laboratory H2O measurements. These NAM samples have been analysed and characterised here by SHRIMP SI, FTIR, EMP and the Cameca ims-6f ion microprobe at CIW. Four of these samples have previously been measured by manometry to determine absolute H2O concentrations.
ISSN: 0267-9477

hal-01243514
https://hal.archives-ouvertes.fr/hal-01243514
DOI : 10.1039/c5ja00047e

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
A calibration method aimed at converting X-ray intensities into absolute units has been tested in different electron microprobes. The calibration requires measurement of the X-ray peak profile and measurement and calculation of the bremsstrahlung intensity emitted from a reference sample, at the energy of the X-ray line of interest. Specifically, measurements of the U M alpha and M beta lines emitted from UO2 and bremsstrahlung intensities emitted from an Al reference sample have been performed on five different instruments. The aim of the work is to determine to what accuracy X-ray intensities emitted from reference samples of actinide elements are transferable among different electron microprobes (virtual standard). The influence of the focussing geometry and different crystals and proportional counters used is analysed. Strategies to reduce the uncertainties affecting the absolute calibration of the studied lines are discussed.
ISSN: 0026-3672

hal-00411437
https://hal.archives-ouvertes.fr/hal-00411437
DOI : 10.1007/s00604-007-0856-2

Éditeur(s) : HAL CCSD American Chemical Society
Résumé : International audience
Chlordecone is an organochlorine pesticide that was extensively used in the French West Indies to fight weevils in banana plantations from 1973 to 1993. This has led to a persistent pollution of the environment and to the contamination of the local population for several decades with effects demonstrated on human health. Chlordecone accumulates mainly in the liver where it is known to potentiate the action of hepatotoxic agents. However, there is currently no information on its in situ localization in the liver. We have thus evaluated a matrix-assisted laser desorption ionization (MALDI) imaging quantification method based on labeled normalization for the in situ localization and quantification of chlordecone. After validating the linearity and the reproducibility of this method, quantitative MALDI imaging was used to study the accumulation of chlordecone in the mouse liver. Our results revealed that normalized intensities measured by MALDI imaging could be first converted in quantitative units. These quantities appeared to be different from absolute quantities of chlordecone determined by gas chromatography (GC), but they were perfectly correlated (R(2) = 0.995). The equation of the corresponding correlation curve was thus efficiently used to convert quantities measured by MALDI imaging into absolute quantities. Our method combining labeled normalization and calibration with an orthogonal technique allowed the in situ absolute quantification of chlordecone by MALDI imaging. Finally, our results obtained on the pathological mouse liver illustrate the advantages of quantitative MALDI imaging which preserves information on in situ localization without radioactive labeling and with a simple sample preparation.
ISSN: 0003-2700

hal-01118103
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01118103
PUBMED : 24837422
DOI : 10.1021/ac500313s

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : International audience
We examine absolute gravity (AG) and vertical Global Positioning System (GPS) time series between 1995 and 2010 at eight collocated sites in mid-continent North America. The comparison of AG and GPS rates aligned to ITRF2005 yields a gravity/uplift ratio of -0.17 +/- 0.01 mu Gal mm(-1) (1 mu Gal = 10 nm s(-2)) and an intercept of -0.1 +/- 0.5 mm yr(-1). In contrast, aligning the GPS velocities to ITRF2000 results in a gravity/uplift intercept of -1.3 +/- 0.5 mm yr(-1). The near-zero gravity/uplift offset for the ITRF2005 (or ITRF2008) results shows a good alignment of the GPS vertical velocities to Earth's center of mass, and confirms that GPS velocities in this reference frame can be compared to predictions of geodynamic processes such as glacial isostatic adjustment (GIA) or sea-level rise. The observed gravity/uplift ratio is consistent with GIA model predictions. The ratio remains constant in regions of fast and slow uplift, indicating that GIA is the primary driving process and that additional processes such as local hydrology have a limited impact on a decadal time-scale. Combining AG and GPS measurements can provide significant constraints for geodetic, geodynamic, and hydrological studies. Citation: Mazzotti, S., A. Lambert, J. Henton, T. S. James, and N. Courtier (2011), Absolute gravity calibration of GPS velocities and glacial isostatic adjustment in mid-continent North America, Geophys. Res. Lett., 38, L24311, doi:10.1029/2011GL049846.
ISSN: 0094-8276

hal-00689010
https://hal.archives-ouvertes.fr/hal-00689010
DOI : 10.1029/2011GL049846

Éditeur(s) : HAL CCSD Cambridge University Press (CUP)
Résumé : International audience
ISSN: 1431-9276

hal-00411439
https://hal.archives-ouvertes.fr/hal-00411439

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : In this paper we present the potential of a new compact superconducting gravimeter (GWR iGrav) designed for groundwater monitoring. At first, 3 yr of continuous gravity data are evaluated and the performance of the instrument is investigated. With repeated absolute gravity measurements using a Micro-g Lacoste FG5, the calibration factor (−894.8 nm s−2 V−1) and the long-term drift of this instrument (45 nm s−2 yr−1) are estimated for the first time with a high precision and found to be respectively constant and linear for this particular iGrav. The low noise level performance is found similar to those of previous superconducting gravimeters and leads to gravity residuals coherent with local hydrology. The iGrav is located in a fully instrumented hydrogeophysical observatory on the Durzon karstic basin (Larzac plateau, south of France). Rain gauges and a flux tower (evapo-transpiration measurements) are used to evaluate the groundwater mass balance at the local scale. Water mass balance demonstrates that the karst is only capacitive: all the rainwater is temporarily stored in the matrix and fast transfers to the spring through fractures are insignificant in this area. Moreover, the upper part of the karst around the observatory appears to be representative of slow transfer of the whole catchment. Indeed, slow transfer estimated on the site fully supports the low-flow discharge at the only spring which represents all groundwater outflows from the catchment. In the last part of the paper, reservoir models are used to characterize the water transfer and storage processes. Particular highlights are done on the advantages of continuous gravity data (compared to repeated campaigns) and on the importance of local accurate meteorological data to limit misinterpretation of the gravity observations. The results are complementary with previous studies at the basin scale and show a clear potential for continuous gravity time-series assimilation in hydrological simulations, even on heterogeneous karstic systems.
ISSN: 0956-540X

hal-01526965
https://hal.archives-ouvertes.fr/hal-01526965
https://hal.archives-ouvertes.fr/hal-01526965/document
https://hal.archives-ouvertes.fr/hal-01526965/file/fores2016.pdf
DOI : 10.1093/gji/ggw396