Éditeur(s) : HAL CCSD Société géologique de France
Résumé : International audience
Age constraints on the protoliths, deformation, metamorphism and melting events are key parameters when correlating different continental lithospheric remnants among each other and disentangling their evolution within large-scale orogens. In situ U-Th-Pb chemical dating on monazites using Electron Probe Micro-Analyser (EPMA) has been performed on eight samples throughout the Variscan Maures-Tanneron massif (SE France) in order to date the medium to high-tectonothermal events related to the Variscan orogeny.Results indicate a polyphased crustal evolution : (i) U-Th-Pb ages obtained in polygenetic monazite grain cores gave inherited Upper Ordovician (456 ± 11 Ma) age, highlighting the large scale occurrence of the Ordovician magmatic activity in the North Gondwanian margin. An Early Devonian (404 ± 10 Ma) age may date a protolith emplacement related to calc-alkaline supra-subduction magmatism or could be associated to an early medium-grade metamorphism, prior to collisional stage. (ii) The crustal thickening stage has been further recorded in prograde metamorphic monazites formed during the underthrusting and subsequent nappe stacking events, under amphibolite facies conditions. This stage is dated between 382 ± 11 (Middle Devonian) and 331 ± 5 Ma (Late Visean). (iii) An orogenic partial melting event took place during Middle Carboniferous and is accompanied by the crystallization of crustal peraluminous magmas (Plan-de-la-Tour granite, 329 ± 3 Ma).This contribution demonstrates the capacity of monazite to record the prograde path of rocks during increasing metamorphic conditions related to stages of crustal thickening, and the robustness of the U-Th-Pb chronometer in monazite despite the overprinting of high-grade thermal events, including partial melting. The age ranges of the different orogenic stages reported in this study are in good agreement with those reported in adjacent Variscan Corsica and Sardinia; while correlations with other nearest Variscan massifs like the Argentera massif in the southwestern Alps or the French Massif Central remain more hypothetic. The Internal Zone of the Maures-Tanneron massif, and more widely the Internal Zone of the Maures-Tanneron-Corsica-Sardinia segment, is part of the southern orogenic root system of the Variscan belt.
EISSN: 1777-5817

insu-01140973
https://hal-insu.archives-ouvertes.fr/insu-01140973
DOI : 10.2113/gssgfbull.186.2-3.145

Éditeur(s) : HAL CCSD E Schweizerbart Science Publishers
Résumé : Mafic microgranular enclaves produced by co-mingling between minette and syenite magmas are found in the Piquiri Syenite, southern Brazil. These enclaves were crystallized under upper mantle conditions. K-clinopyroxene and pyrope are among the early-crystallized phases, suggesting an initial pressure around 5GPa. The mineralogy of minettes comprises phenocrysts of magnesium biotite and diopside, occasionally apatite, in a groundmass formed by these minerals plus alkali feldspar. Two types of apatites are observed: (i) euhedral grains, as inclusions or groundmass constituents, and (ii) aciculate crystals formed during undercooling of mafic magma. Substitutional schemes suggested for these apatites are Si ⇆ P in the tetrahedral site, and Sr and LREE replacing Ca. La, Ce, Nd, and Sr concentrations reveal that these elements are extremely enriched in apatite. Partition coefficients between early-crystallized apatites and estimated melt compositions are DLa (11.8 - 30.6), DCe (16.1-33), DNd (12-31) and DSr (5.1-8.2). Apatite concentrates the LREE up to 200 times compared to clinopyroxene, even higher values were determined for ap/mica partitioning. The ap/cpx and ap/mica partition coefficients for undercooled minerals are close to the values determined for the near-liquidus phases, which indicates constant behavior of LREE and Sr between apatite-clinopyroxene-mica parageneses and minette liquids. Furthermore, these partitioning data preclude any chemical diffusion of these elements between minette and syenite magmas during co-mingling.
ISSN: 0935-1221

hal-00407602
https://hal.archives-ouvertes.fr/hal-00407602
DOI : 10.1127/0935-1221/2007/0019-0039

Éditeur(s) : HAL CCSD IOP Publishing
Résumé : The use of electron probe microanalysis (EPMA) at low voltage allows improvements in the lateral resolution and surface sensitivity of the technique down to the sub-micrometre scale, and it is also useful in minimizing X-ray absorption (for the analysis of ultra-light elements), charging effects and secondary fluorescence. However, EPMA at low voltage is accompanied by a number of problems which may affect the accuracy of quantitative results. A large number of these problems arise from the need of using low-energy X-ray lines such as L- and M-lines, which have low fluorescence yields, large uncertainties in the mass attenuation coefficients, and are affected by several spectroscopic difficulties (e.g., peak shifts and overlaps). Other factors that play an important role at low voltage are carbon contamination, surface oxidation, the quality of sample polishing, the influence of a conductive coating and the limitations of matrix correction procedures. In this paper, we illustrate the capabilities of EPMA at low voltage and we examine in detail the different sources of uncertainty that may affect the accuracy of quantitative results.
ISSN: 1757-8981

hal-00767564
https://hal.archives-ouvertes.fr/hal-00767564
DOI : 10.1088/1757-899X/32/1/012016

Éditeur(s) : HAL CCSD IOP Publishing
Résumé : We present the results of an inter-laboratory comparison of EPMA analysis at low voltage (5-6 kV) of three monophasic alloy steel samples. The aim of the work was to obtain an estimate of the present situation of low-voltage analysis of steel and identify needs for improvement. EPMA analyses of the samples were conducted by seven participant groups using electron microprobes and scanning electron microscopes of different kind, equipped with wavelength- and/or energy-dispersive X-ray spectrometers, and employing their own methodology of analysis. The results using WDS showed essentially an underestimation of the Cr contents, with relative deviations from the reference values ranging from -0.7 % to -17 %, and an overestimation of Fe and Ni, with relative deviations from the reference composition ranging from -4 % to +30 %, and from +14 % to +42 %, respectively. The relative deviations obtained by using EDS showed larger scatter, ranging from -16 % to +54 % for Cr, -0.4 % to +66 % for Fe and from +13 % to +90 % for Ni. Reasons for the differences observed and the scatter of results are discussed.
ISSN: 1757-8981

hal-00813999
https://hal.archives-ouvertes.fr/hal-00813999
DOI : 10.1088/1757-899X/32/1/012014

Éditeur(s) : HAL CCSD Cambridge University Press (CUP)
Résumé : International audience
ISSN: 1431-9276

hal-00411439
https://hal.archives-ouvertes.fr/hal-00411439

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Oisans Massif, located in the external zones of the western Alps, experienced significant shortening during the Alpine collision. While a series of major top-to-the west shear zones was recently described, the general low grade of the metamorphism has not attracted much petrological and geochronological studies. This paper provides combined temperature and age constraints on the evolution of the Oisans Massif. Temperature was estimated with the Raman Spectrometry of Carbonaceous Material (RSCM) method and chlorite geothermometry. Maximum temperature reached by the Mesozoic cover (Tmax) from Grenoble to the Galibier pass (E-W) and from Saint Jean de Maurienne to Embrun (N-S) yielded almost constant ca. 330 °C temperatures all through the Massif. Temperatures however strongly decrease either westward towards the top of the Vercors sedimentary sequence or eastward towards the Penninic Frontal Thrust. Age constraints were retrieved using 40Ar/39Ar in situ analyses performed on variously strained samples from Alpine shear zones. Over strain gradients, incipient Alpine recrystallizations progressively develop at the expense of former Variscan parageneses. A combined textural and EPMA approach permitted to identify newly formed chlorite and phengite that unequivocally grew in response to deformation or to low grade metamorphism. Chlorites recorded temperatures from ca. 350–150 °C during the activity of shear zones. In parallel, 40Ar/39Ar in situ experiments enabled dating deformation using both synkinematic phengites crystallized below the closure temperature of white-micas and former Variscan muscovite whose isotopic system have been, at least partially re-opened. Activity of top-to-the-west shear zones responsible for the shortening and thickening of the Oisans massif thus occurred between 34 and 33 and 25 Ma. Integrating these new age-constraints, Tmax estimates, and published geological data on the Oisans Massif and neighbouring areas allow proposing a new shortening scenario for the external zones. From ca. 34–33 Ma, the Oisans Massif was buried as a rigid block below more internal units and reached a temperature of ca. 330 °C. Shearing progressively localized along a series of top-to-the-W shear zones in the basement until 25 Ma. Deformation then localized along a major thrust at the base of the ECM massif and propagated along the basement-cover interface below the Vercors massif after 16 Ma.
ISSN: 0264-3707

Droits : info:eu-repo/semantics/OpenAccess
insu-01093878
https://hal-insu.archives-ouvertes.fr/insu-01093878
https://hal-insu.archives-ouvertes.fr/insu-01093878/document
https://hal-insu.archives-ouvertes.fr/insu-01093878/file/GEOD1326RA.pdf
DOI : 10.1016/j.jog.2014.09.004

Éditeur(s) : HAL CCSD Cambridge University Press (CUP)
Résumé : International audience
XFILM is a computer program for determining the thickness and composition of thin films on Substrates and multilayers by electron probe microanalysis. In this study, we describe the X-ray emission model implemented in the latest version of XFILM and assess its reliability by comparing measured and calculated k-ratios from thin-film samples available in the literature. We present and discuss examples of applications of XFILM that illustrate the capabilities of the program.
ISSN: 1431-9276

hal-00475542
https://hal.archives-ouvertes.fr/hal-00475542
DOI : 10.1017/S1431927609991218

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
A calibration method aimed at converting X-ray intensities into absolute units has been tested in different electron microprobes. The calibration requires measurement of the X-ray peak profile and measurement and calculation of the bremsstrahlung intensity emitted from a reference sample, at the energy of the X-ray line of interest. Specifically, measurements of the U M alpha and M beta lines emitted from UO2 and bremsstrahlung intensities emitted from an Al reference sample have been performed on five different instruments. The aim of the work is to determine to what accuracy X-ray intensities emitted from reference samples of actinide elements are transferable among different electron microprobes (virtual standard). The influence of the focussing geometry and different crystals and proportional counters used is analysed. Strategies to reduce the uncertainties affecting the absolute calibration of the studied lines are discussed.
ISSN: 0026-3672

hal-00411437
https://hal.archives-ouvertes.fr/hal-00411437
DOI : 10.1007/s00604-007-0856-2

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The oxygen fugacity and therefore the iron redox state of a melt is known to have a strong influence on the liquid line of descent of magmas and thus on the composition of the coexisting melts and crystals. We present a new method to estimate this critical parameter from electron probe microanalyses of two of the most common minerals of basaltic series, plagioclase and clinopyroxene. This method is not based on stoichiometric calculations, but on the different partitioning behaviour of Fe3+ and Fe2+ between both minerals and a melt phase: plagioclase can incorporate more Fe3+ than Fe2+, while clinopyroxene can incorporate more Fe2+ than Fe3+. For example, the effect of oxidizing a partly molten basaltic system (Fe3+ is stabilized with respect to Fe2+) results in an increase of FeOtotal in plagioclase, but a decrease in the associated clinopyroxene. We propose an equation, based on published partition coefficients, that allows estimating the redox state of a melt from these considerations. An application to a set of experimental and natural data attests the validity of the proposed model. The associated error can be calculated and is on average <1 log unit of the prevailing oxygen fugacity.;In order to reduce the number of different variables influencing the Fe2+/Fe3+ mineral/melt equilibrium, our model is restricted to basaltic series with SiO2<60% that have crystallized at intermediate to low pressure (<0.5 GPa) and under relatively oxidizing conditions (Delta FMQ>0; where FMQ is the fayalite-magnetite-quartz oxygen buffer equilibrium), but it may be parameterized for other conditions. A spreadsheet is provided to assist the use of equations, and to perform the error propagation analysis.
ISSN: 0377-0273

hal-00475550
https://hal.archives-ouvertes.fr/hal-00475550
DOI : 10.1016/j.jvolgeores.2009.11.023

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
This paper presents a reappraisal of the tectonic evolution of the Zanhuang Massif that lies at the eastern margin of the Trans-North China Orogen, a continent–continent collision belt that marked the amalgamation of the North China Craton in Late Paleoproterozoic. Detailed field work with focus on geometries of structures and kinematics was performed. This was completed with LA-ICP-MS U–Pb analyses on zircon, EPMA U–Th/Pb dating on monazite and 40Ar/39Ar dating on amphibole. These studies led us to propose a new three-fold litho-tectonic subdivision of the massif: The Western Zanhuang Domain (WZD) made of TTG, migmatite and pink anatectic granite is correlated to the Fuping Massif that crops out to the north-west. Both areas represent a continental block, called the Fuping Block, which acquired most of its architecture around 2100 Ma ago. The Eastern Zanhuang Domain (EZD) made of TTG and migmatite represents the western edge of an Eastern Neoarchean Block. In between, the Central Zanhuang Domain (CZD) is a NE–SW trending stack of supracrustal, gneiss and mafic magmatic rocks thrust sheets displaced toward the ESE upon the Eastern Block. The lithological features suggest that the CZD represents the remnant of an oceanic basin, called the Taihang Ocean that closed during the amalgamation of the Eastern Block and the Fuping Block around 1880–1850 Ma. In agreement with recent work done along the western margin of the belt, in the Lüliang Massif, this study documents the amalgamation of the North China Craton in response to the closure of two oceanic basins, namely the Lüliang Ocean and the Taihang Ocean. West-dipping subductions and collisions involving three distinct continental blocks, called the Western, the Fuping and the Eastern Blocks, took place around 1880–1850 Ma.
ISSN: 0301-9268

insu-00403871
https://hal-insu.archives-ouvertes.fr/insu-00403871
https://hal-insu.archives-ouvertes.fr/insu-00403871/document
https://hal-insu.archives-ouvertes.fr/insu-00403871/file/Trap-PrecambrianResearch-2009.pdf
DOI : 10.1016/j.precamres.2009.03.011

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Hengshan–Wutaishan area forms part of the Trans-North-China Belt developed in response to the final amalgamation of the North China Craton. The Hengshan–Wutaishan domain and the adjacent Fuping massif constitute the largest and the most representative rock exposure of the belt. A structural study allows us to redefine the lithological and tectonic units that compose the architecture of the Hengshan–Wutaishan domain and to propose that the Trans-North-China Belt was built up through a polyphase tectonic evolution within the period 1900–1800 Ma. The first event (D1) corresponds to the emplacement of lower and upper nappes herein called the Orthogneiss and Volcanites Unit (OVU) and the Low Grade Mafic Unit (LGMU), respectively. The OVU mainly consists of rocks formed in an arc system and metamorphosed under amphibolite facies conditions whereas the LGMU represents oceanic crust rocks with an arc component that underwent greenschist facies metamorphism. The syn-metamorphic D1 deformation is characterized by a NW–SE stretching and mineral lineation with a top-to-the SE sense of shear that corresponds to the sense of nappe motion. U–Th–Pb EPM chemical dating on monazite from three metapelites of the OVU gives isochron ages of 1884 ± 11 Ma, 1886 ± 5 Ma and 1887 ± 4 Ma interpreted as the age of the prograde amphibolite facies metamorphism coeval with nappe stacking during the D1 event. The D2 event corresponds to a widespread crustal melting of the OVU and underlying basement rocks in Hengshan related to the exhumation of deep structures about 20–30 Ma after nappe emplacement. The migmatite contains blocks of retrograded eclogite or HP-granulitic restites, and is characterized by the development of a pervasive foliation and lineation. A late D2 event represents the folding stage of the migmatitic foliation during the completion of a dome. The Orthogneiss and Volcanics Unit and the Low Grade Mafic Unit are unconformably covered by weakly metamorphosed to unmetamorphosed sediments belonging to the Hutuo Supergroup. These rocks were deformed by a ductile D3 event, characterized by a NW–SE trending stretching lineation, south verging folds associated with an axial planar slaty cleavage and an E–W crenulation lineation. Lastly, a left-lateral wrenching along the Zhujiafang Shear Zone separates the northern and southern parts of Hengshan. Our structural study shows that there is no significant difference between the southern part of Hengshan and the lower part of Wutaishan, both areas belong to OVU and show a structural continuity. We suggest that this polyphase deformation developed in response to a north-westward subduction of an old ocean, named the Lüliang Ocean, beneath the Western Block, followed by collision with a micro-continent named the Fuping Block at not, vert, similar1890–1880 Ma.
ISSN: 0301-9268

insu-00151594
https://hal-insu.archives-ouvertes.fr/insu-00151594
https://hal-insu.archives-ouvertes.fr/insu-00151594/document
https://hal-insu.archives-ouvertes.fr/insu-00151594/file/Trap-PrecambrainResearch-2007.pdf
DOI : 10.1016/j.precamres.2007.03.001