Éditeur(s) : HAL CCSD Springer Verlag (Germany) Springer Verlag
Résumé : International audience
Arenal volcano is nearly unique among arc volcanoes with its 42 year long (1968–2010) continuous, small-scale activity erupting compositionally monotonous basaltic andesites that also dominate the entire, ~7000 year long, eruptive history. Only mineral zoning records reveal that basaltic andesites are the result of complex, open-system processes deriving minerals from a variety of crystallization environments and including the episodic injections of basalt. The condition of the mafic input as well as the generation of crystal-rich basaltic andesites of the recent, 1968–2010, and earlier eruptions were addressed by an experimental study at 200 MPa, 900–1,050 °C, oxidizing and fluid-saturated conditions with various fluid compositions [H2O/(H2O + CO2) = 0.3–1]. Phase equilibria were determined using a phenocryst-poor (~3 vol%) Arenal-like basalt (50.5−wt% SiO2) from a nearby scoria cone containing olivine (Fo92), plagioclase (An86), clinopyroxene (Mg# = 82) and magnetite (Xulvö = 0.13). Experimental melts generally reproduce observed compositional trends among Arenal samples. Small differences between experimental melts and natural rocks can be explained by open-system processes. At low pressure (200 MPa), the mineral assemblage as well as the mineral compositions of the natural basalt were reproduced at 1,000 °C and high water activity. The residual melt at these conditions is basaltic andesitic (55 wt% SiO2) with 5 wt% H2O. The evolution to more evolved magmas observed at Arenal occurred under fluid-saturated conditions but variable fluid compositions. At 1,000 °C and 200 MPa, a decrease of water content by approximately 1 wt% induces significant changes of the mineral assemblage from olivine + clinopyroxene + plagioclase (5 wt% H2O in the melt) to clinopyroxene + plagioclase + orthopyroxene (4 wt% H2O in the melt). Both assemblages are observed in crystal-rich basalt (15 vol%) and basaltic andesites. Experimental data indicate that the lack of orthopyroxene and the presence of amphibole, also observed in basaltic andesitic tephra units, is due to crystallization at nearly water-saturated conditions and temperatures lower than 950 °C. The enigmatic two compositional groups previously known as low- and high-Al2O3 samples at Arenal volcano may be explained by low- and high-pressure crystallization, respectively. Using high-Al as signal of deeper crystallization, first magmas of the 1968–2010 eruption evolved deep in the crust and ascent was relatively fast leaving little time for significant compositional overprint by shallower level crystallization.
ISSN: 0010-7999

hal-01115717
https://hal.archives-ouvertes.fr/hal-01115717
DOI : 10.1007/s00410-014-1040-4

Éditeur(s) : HAL CCSD Ocean Drilling Programm
Résumé : This paper provides a summary of postcruise scientific results from Ocean Drilling Program (ODP) Leg 209 available to date, building upon shipboard observations and syntheses summarized in the Leg 209 Initial Results volume. During Leg 209, 19 holes were drilled at 8 sites along the Mid-Atlantic Ridge from 14°43´ to 15°44´N, mainly in residual mantle peridotite intruded by gabbroic rocks, in order to understand the tectonic and structural processes responsible for formation of oceanic lithosphere with abundant residual peridotite exposed on the seafloor coupled with a relatively low proportion of volcanic rocks. Based on proportions of recovered lithologies, the entire area may be underlain by mantle peridotite with ~20%–40% gabbroic intrusions and impregnations. Impregnated peridotites with olivine + two pyroxenes + plagioclase + spinel that apparently formed in equilibrium probably record crystallization from primitive mid-ocean-ridge basalt at pressures of 0.5–0.6 GPa. Metamorphic equilibria record isobaric cooling to ~1100°C at this pressure. Thus, the conductively cooled thermal boundary layer beneath the Mid-Atlantic Ridge in this region is >15 km thick. Combined crystallization and reaction with residual peridotite formed a series of impregnated peridotites recording increasing Na content at nearly constant Mg#; this process could explain some of the variation in fractionation-corrected Na (e.g., Na = 8.0) observed in mid-ocean-ridge basalts. Clinopyroxene textures and compositions record such impregnation processes, and they are particularly well documented for Site 1274. Other Leg 209 gabbroic rocks formed from extensive crystallization of highly evolved melts, indicating that a substantial proportion of melt entering the thermal boundary layer crystallizes entirely beneath the seafloor, with no volcanic equivalent. Alteration of peridotites occurred over a range of temperatures and is the result of three distinct processes: rock-dominated serpentinization with formation of brucite in olivine-rich lithologies, fluid-dominated serpentinization with formation of magnetite and no brucite, and fluid-dominated talc alteration with addition of SiO2 as well as H2O and oxygen. The latter two processes also exhibit detectable trace element metasomatism that is distinct in its character from the igneous impregnation described in the previous paragraph. Microstructures show that most residual peridotites were not ductilely deformed at temperatures less than ~1200°C. Structural and paleomagnetic data require tectonic rotations of relatively undeformed blocks; some rotations probably exceeded 60° around nearly horizontal axes parallel to the rift axis. Rotations occurred along several generations of high-temperature mylonitic shear zones extending deeper than 15 km depth and numerous faults at lower temperature. Early formed shear zones and faults were passively rotated around later features; such a process could have produced low-angle fault surfaces without slip on low-angle faults. This region provides end-member examples of processes that are common at many or most slow-spreading ridges. Osmium isotope ratios indicate an ancient history of depletion for residual peridotites from the 14°–16°N region along the Mid-Atlantic Ridge. Though depleted Os isotope ratios in peridotite have been reported elsewhere along the global ridge system, the values from this region are among the most depleted. In general, Os isotope ratios from mid-ocean-ridge basalts are systematically more radiogenic than Os isotope ratios from ridge peridotite samples, suggesting a polygenetic heterogeneous source for mid-ocean-ridge basalts. Geochemical studies of zircons from Leg 209 gabbroic rocks and impregnated peridotites, together with other ridge and arc-related zircons, indicate that ridge zircons have systematically lower fractionation-corrected U and Th concentrations compared to arc zircons. This observation provides a tool for interpreting the tectonic provenance of ancient detrital zircons and indicates an arclike provenance for Hadean detrital zircons. Geobiological studies and aerobiological studies were also undertaken during Leg 209. The geobiological work found no measurable microbial enhancement of olivine dissolution rate, possibly because the samples from Leg 209 were sterile. The aerobiological study determined that dust from North Africa, collected from the derrick of the JOIDES Resolution during Leg 209, contains a variety of abundant microorganisms.
Proceedings ODP, scientific results, 209

hal-00407966
https://hal.archives-ouvertes.fr/hal-00407966
DOI : 10.2973/odp.proc.sr.209.001.2007

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Cerro del Almirez massif (Nevado–Filábride Complex, Betic Cordillera, SE Spain) is composed of antigorite (Atg-) serpentinite and chlorite (Chl-) harzburgite separated by a thin reaction front formed in a palaeo-subduction setting. These ultramafic rocks preserve unique prograde structures related to the pre- and peak high-pressure event (1.6–1.9 GPa and 680–710 °C). The oldest subduction-related structures are preserved in Atg-serpentinites: a penetrative S1 foliation and associated L1 stretching lineation that formed in a non-coaxial regime with a top-to-the-W sense of shear. This planar–linear fabric is crosscut by olivine ± Ti-clinohumite veins, formed during the prograde breakdown of brucite and pre-metamorphic clinopyroxene, which form a system of veins decimetres long. They record embrittlement processes due to the release of 6 vol.% of H2O associated with brucite dehydration. The growth of prograde olivine and/or tremolite porphyroblasts is syn- to post-kinematic in relation to the S1 foliation. Further reactions at higher temperature related to the complete breakdown of the Atg (i.e. Atg-out) are post-kinematic to S1. Prograde Chl-harzburgite is crosscut by sets of conjugate zones associated with grain-size reduction of olivine grains. These grain-size reduction zones are interpreted as brittle structures generated by hydrofracturing due to overpressure fluids in a compressional setting at low-differential stresses.Structures related to the exhumation process are mainly preserved in the metasedimentary host rock, where an S2/L2 planar–linear fabric developed within a shear zone dominated by a non-coaxial regime with a top-to-the-W sense of movement in a transpressional regime. Peak metamorphic conditions deduced for the schists are similar in pressure (1.3–1.9 GPa) but lower in temperature (560–590 °C) compared to the ultramafic rocks in contact with them, suggesting a major shear zone at the base of the ultramafic massif during D2 deformation in a right-handed transpressional regime.
ISSN: 0040-1951

hal-01172303
https://hal.archives-ouvertes.fr/hal-01172303
DOI : 10.1016/j.tecto.2014.12.022

Éditeur(s) : HAL CCSD
Résumé : International audience
Metamorphic soles correspond to m to 500 m thick highly strained metamorphic rock units found beneath myloniticbanded peridotites at the base of large-scale ophiolites, as exemplified in Oman. Metamorphic soles aremainly composed of metabasalts deriving from the downgoing oceanic lithosphere and metamorphosed up togranulite-facies conditions by heat transfer from the mantle wedge. Pressure–temperature peak conditions areusually estimated at 1.00.2 GPa and 800100ºC. The absence of HP–LT metamorphism overprint implies thatmetamorphic soles have been formed and exhumed during subduction infancy. In this view, metamorphic soleswere strongly deformed during their accretion to the mantle wedge (corresponding, now, to the base of the ophiolite).Therefore, metamorphic soles and banded peridotites are direct witnesses of the dynamics of early subductionzones, in terms of thermal structure, fluid migration and rheology evolution across the nascent slab interface.Based on fieldwork and EBSD analyses, we present a detailed (micro–) structural study performed on samplescoming from the Sumeini window, the better-preserved cross-section of the metamorphic sole of Oman. Largedifferences are found in the deformation (CPO, grain size, aspect ratio) of clinopyroxene, amphibole and plagioclase,related to mineralogical changes linked with the distance to the peridotite contact (e.g., hardening due to theappearance of garnet and clinopyroxene).To model the incipient slab interface in laboratory, we carried out 5 hydrostatic annealing and simple-shear experimentson Griggs solid-medium apparatus. Deformation experiments were conducted at axial strain rates of 10-6s-1. Fine-grained amphibolite was synthetized by adding 1 wt.% water to a (Mid-Ocean Ridge) basalt powder asa proxy for the metamorphic sole (amphibole + plagioclase + clinopyroxene garnet assemblage). To synthetizegarnet, 2 experiments were carried out in hydrostatic conditions and with deformation at 800C with confiningpressure of 2 GPa. Another simple-shear experiment has been carried out at 800C and 1 GPa with fined-grainednatural garnet. With the aim of mimicking the early slab interface (between the metamorphic sole and bandedperidotites at the base of the ophiolite), 2 simple-shear deformation experiments with 2 layers have been carriedout at 800C and confining pressure of 1 GPa. The bottom layer was made of hydrated basalt powder and the toplayer was made of olivine.Fined-grained garnet-free amphibolite is significantly weaker than dunite but the appearance of harder mineralsin the amphibolite (garnet and clinopyroxene) has major implications on its rheological evolution. These resultsallow liking field observations of strain localization at the interface to the metamorphic sole formation
European Geosciences Union General Assembly 2016
Vienne, Austria

insu-01309394
https://hal-insu.archives-ouvertes.fr/insu-01309394

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The oxygen fugacity and therefore the iron redox state of a melt is known to have a strong influence on the liquid line of descent of magmas and thus on the composition of the coexisting melts and crystals. We present a new method to estimate this critical parameter from electron probe microanalyses of two of the most common minerals of basaltic series, plagioclase and clinopyroxene. This method is not based on stoichiometric calculations, but on the different partitioning behaviour of Fe3+ and Fe2+ between both minerals and a melt phase: plagioclase can incorporate more Fe3+ than Fe2+, while clinopyroxene can incorporate more Fe2+ than Fe3+. For example, the effect of oxidizing a partly molten basaltic system (Fe3+ is stabilized with respect to Fe2+) results in an increase of FeOtotal in plagioclase, but a decrease in the associated clinopyroxene. We propose an equation, based on published partition coefficients, that allows estimating the redox state of a melt from these considerations. An application to a set of experimental and natural data attests the validity of the proposed model. The associated error can be calculated and is on average <1 log unit of the prevailing oxygen fugacity.;In order to reduce the number of different variables influencing the Fe2+/Fe3+ mineral/melt equilibrium, our model is restricted to basaltic series with SiO2<60% that have crystallized at intermediate to low pressure (<0.5 GPa) and under relatively oxidizing conditions (Delta FMQ>0; where FMQ is the fayalite-magnetite-quartz oxygen buffer equilibrium), but it may be parameterized for other conditions. A spreadsheet is provided to assist the use of equations, and to perform the error propagation analysis.
ISSN: 0377-0273

hal-00475550
https://hal.archives-ouvertes.fr/hal-00475550
DOI : 10.1016/j.jvolgeores.2009.11.023

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Mid-ocean ridge basalt (MORB) is the most abundant magma on Earth, and provides a geochemical window into the mantle. Deriving mantle composition and melting processes from the erupted lavas requires correction to be made for their evolution as they pass through and generate the oceanic crust. This is typically done by assuming that modification of melts in crustal magma chambers occurs exclusively by fractional crystallisation. However, extensive mineral major- and trace element data from a full section of fast-spread lower crustal rocks exposed in Hess Deep (equatorial Pacific Ocean) demonstrate that their evolution is instead controlled by reactive porous flow. These reactions lead to a strong enrichment in, and fractionation of, incompatible trace elements in the melt (as recorded by clinopyroxene compositions), leading to melt compositions far outside of the compositional realm of MORB both in terms of trace element abundances and ratios. The reactive signature increases in strength up section, peaking in varitextured gabbros interpreted to represent the fossilised axial melt lens, indicating that reactive porous flow occurred on the scale of the entire lower crust. The enrichment of the melt is coupled with a strong trace element depletion of plagioclase, olivine, and, to a lesser extent, clinopyroxene cores, suggesting that these phases represent the residues of the reactions from which trace elements have been removed. The dominant role of reactive porous flow, and the resulting deviations from fractional crystallisation predictions, suggest that the lower oceanic crust plays a much more complex and significant role in modifying the compositions of MORB than previously expected, with consequent implications for models of mantle processes.
ISSN: 0012-821X

hal-00814075
https://hal.archives-ouvertes.fr/hal-00814075
DOI : 10.1016/j.epsl.2012.11.012

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The New Caledonia ophiolite (Peridotite Nappe) is dominated by mantle lithologies, composed of forearc-related refractory harzburgites and minor lherzolites in both the spinel and plagioclase facies.In this study, a comprehensive geochemical data set (major, trace elements and Sr–Nd isotopes) is used to constrain the mantle evolution of the lherzolites and their relationships with the basalts from the Poya Terrane, which tectonically underlies the mantle rocks. The majority of the lherzolites are low-strain porphyroclastic tectonites. They likely record an asthenospheric origin followed by re-equilibration at lithospheric conditions, as supported by geothermometric estimates (T = 1100–940 °C and 920–890 °C for porphyroclastic and neoblastic spinel-facies assemblages, respectively). Olivine composition (Fo = 88.5–90.0 mol%), spinel Cr# ([molar 100 • Cr/(Cr + Al)] = 13–17) and relatively high amounts (7–8 vol%) of Al2O3- and Na2O-rich clinopyroxene (up to 0.5 and 6.5 wt.%, respectively) indicate a moderately depleted geochemical signature for the spinel lherzolites. Bulk rock and clinopyroxene rare earth elements (REE) patterns display a typical abyssal-type signature, i.e. steeply plunging LREE accompanied by nearly flat HREE to MREE. Clinopyroxene REE compositions of the spinel lherzolites may be reproduced by small amounts of fractional melting of a garnet lherzolite precursor (~ 4%), followed by 4%–5% melting in the spinel peridotite field. The plagioclase lherzolites show melt impregnation microstructures, Cr- and Ti-rich spinels and incompatible trace element enrichments (REE, Ti, Y, and Zr) in bulk rocks and clinopyroxenes. Impregnation modelling for these elements suggests that the plagioclase lherzolites originated from residual spinel lherzolites by entrapment of highly depleted (non-aggregated) MORB melt fractions in the shallow oceanic lithosphere. Nd isotope compositions of the investigated peridotites are consistent with derivation from an asthenospheric mantle source that experienced a recent MORB-producing depletion event. This evolution was most likely accomplished in a spreading ridge. However, geochemical trace element modelling and Nd isotopes do not support a genetic mantle–crust link between the lherzolites and enriched-MOR-type basalts from the Poya Terrane.
ISSN: 0024-4937

hal-01412440
https://hal.archives-ouvertes.fr/hal-01412440
DOI : 10.1016/j.lithos.2016.04.030

Éditeur(s) : HAL CCSD Oxford University Press (OUP): Policy B - Oxford Open Option A Oxford University Press (OUP)
Résumé : International audience
Peridotite xenoliths exhumed by Quaternary alkaline magmatism in the Tahalgha district, southern Hoggar, represent fragments of the subcontinental lithospheric mantle beneath the boundary between the two major structural domains of the Tuareg Shield: the ‘Polycyclic Central Hoggar’ to the east and the ‘Western Hoggar’, or ‘Pharusian Belt’, to the west. Samples were collected from volcanic centres located on both sides of a major lithospheric shear zone at 4°35' separating these two domains. Although showing substantial variations in their deformation microstructures, equilibrium temperatures and modal and chemical compositions, the studied samples do not display any systematic changes of these features across the 4°35' fault. The observed variations rather record small-scale heterogeneities distributed throughout the study area and reflecting the widespread occurrence of vein conduits and metasomatized wall-rocks related to trans-lithospheric melt circulation during the Cenozoic. These features include partial annealing of pre-existing deformation microstructures, post-deformation metasomatic reactions, and trace-element enrichment, coupled with heating from 750–900°C (low-temperature lherzolites) to 900–1150°C (intermediate-T lherzolites and high-T harzburgites and wehrlites). Trace-element modelling confirms that the range of rare earth element (REE) variations observed in the Tahalgha clinopyroxenes may be accounted for by reactive porous flow involving a single stage of basaltic melt infiltration into a light REE (LREE)-depleted protolith. Whole-rock compositions record the final entrapment of disequilibrium metasomatic melts upon thermal relaxation of the veins–wall-rock system. The striking correlations between equilibrium temperatures and trace-element enrichment favor a scenario in which the high-temperature peridotites record advective heat transport along melt conduits, whereas the intermediate- and low-temperature lherzolites reflect conductive heating of the host Mechanical Boundary Layer. This indicates that the lithosphere did not reach thermal equilibrium, suggesting that the inferred heating event was transient and was rapidly erased by thermal relaxation down to the relatively low-temperature present-day geotherm. The low-T (<900°C) deformed lherzolites (porphyroclastic to equigranular) are characterized by only incipient annealing and LREE-depleted clinopyroxene compositions. They were only weakly affected by the Cenozoic events and could represent relatively well-preserved samples from rejuvenated Pan-African lithosphere. Extensive lithospheric rejuvenation occurred either regionally during the Pan-African orogeny, as a result of lithospheric delamination or thermomechanical erosion after thickening, or more locally along the meridional shear zones. The low-T Tahalgha lherzolites are comparable with lherzolites from Etang de Lherz, southern France, interpreted as lithospheric mantle rejuvenated by melt-induced refertilization during a late stage of the Variscan orogeny.
ISSN: 0022-3530

hal-01107410
https://hal.archives-ouvertes.fr/hal-01107410
DOI : 10.1093/petrology/egu056

Éditeur(s) : HAL CCSD Elsevier
Résumé : The Borborema Province, in the NE of Brazil, is a rather complex piece in the Brazil-Africa puzzle as it represents the junction of the Dahomeyide/Pharusian, Central African, Aracuai and Brasilia fold belts located between the West-African/Sao Luis, Congo/Sao Francisco and Amazonas craton. The correlation between the Dahomeyides from W-Africa (Ghana, Benin, Togo, and Mali) and the Borborema Province involves the Medio Coreau and Central Ceara domains. The inferred continuation of the main oceanic suture zone exposed in the Dahomeyides of W Africa is buried beneath the Phanerozoic Parnaiba Basin in Brazil (northwest of the Medio Coreau domain) where some high density gravity anomalies may represent hidden remnants of an oceanic suture. In addition to this major suture a narrow, nearly continuous strip composed of mainly mafic pods containing relics of eclogite-facies assemblages associated with partially migmatized granulite-facies metapelitic gneisses has been found further east in the NW Borborema Province. These high pressure mafic rocks, interpreted as retrograded eclogites, are located between the Transbrasiliano Lineament and the Santa Quiteria continental arc and comprise primitive to evolved arc-related rocks with either arc- or MORB-type imprints that can indicate either deep subduction of oceanic lithosphere or roots of continental and oceanic magmatic arcs. Average peak P-T conditions under eclogite-facies metamorphism (T=770 degrees C and P = 17.3 kbar) were estimated using garnet-clinopyroxene thermometry and Jd content in clinopyroxene. Transition to granulite-facies conditions, as well as later widespread re-equilibration under amphibolite facies, were registered both in the basic and the metapelitic rocks and suggest a clockwise P-T path characterized by an increase in temperature followed by strong decompression. A phenomenon possibly related to the exhumation of a highly thickened crust associated with the suturing of the Medio Coreau and Central Ceara domains, two distinct crustal blocks separated by the Transbrasiliano Lineament.
ISSN: 1342-937X

hal-00413584
https://hal.archives-ouvertes.fr/hal-00413584
DOI : 10.1016/j.gr.2009.01.003

Éditeur(s) : HAL CCSD Mineralogical Society of America
Résumé : International audience
Hydrogen distribution between nominally anhydrous minerals (NAMs) of a garnet-lherzolite under subsolidus conditions has been investigated. Separated NAMs from a garnet-peridotite from Patagonia (Chile) are annealed together (olivine, orthopyroxene, clinopyroxene, and garnet) using a piston-cylinder at 3 GPa and 1100 °C using talc-pyrex cell assembly for 10, 25, and 100 h. The talc-pyrex assembly provides enough hydrogen in the system to re-equilibrate the hydrogen concentrations at high pressure. The three coexisting nominally anhydrous minerals (NAMs, i.e., olivine, orthopyroxene, and clinopyroxene) were successfully analyzed using FTIR. The resulting hydrogen concentrations exceed significantly the initial hydrogen concentration by a factor of 13 for olivine and a factor of 3 for both pyroxenes. Once mineral-specific infrared calibrations are applied, the average concentrations in NAMs are 115 ± 12 ppm wt H2O for olivine, 635 ± 75 ppm wt H2O for orthopyroxene, and 1214 ± 137 ppm wt H2O for clinopyroxene, garnet grains are dry. Since local equilibrium seems achieved over time (for 100 h), the calculated concentration ratios are interpreted as mineral-to-mineral hydrogen partition coefficients (i.e., Nernst’s law) for a garnet-peridotite assemblage. It yields, based on mineral-specific infrared calibrations, DOpx/Ol = 5 ± 1, DCpx/Ol = 10 ± 2, and DCpx/Opx = 1.9 ± 0.4. While DCpx/Opx is in agreement (within error) with previous results from experimental studies and concentration ratios observed in mantle-derived peridotites, the DPx/Ol from this study are significantly lower than the values reported from mantle-derived xenoliths and also at odd with several previous experimental studies where melt and/or hydrous minerals co-exists with NAMs. The results confirm the sensitivity of hydrogen incorporation in olivine regarding the amount of water-derived species (H) in the system and/or the amount of water in the coexisting silicate melt. The results are in agreement with an important but incomplete dehydration of mantle-derived olivine occurring at depth, during transport by the host magma or during slow lava flow cooling at the surface. The rapid concentration modification in mantle pyroxenes also points out that pyroxenes might not be a hydrogen recorder as reliable as previously thought.
ISSN: 0003-004X

hal-01622132
https://hal.archives-ouvertes.fr/hal-01622132
DOI : 10.2138/am-2017-6089

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In the Oman ophiolite, the horizon where the melt lens pinched during drifting away from the ocean ridge axis has been identified. Starting in the Root Zone of the Sheeted Dike Complex (RZSDC) located above this horizon, 18 Sections down to the upper gabbros unit have been mapped in great detail, in selected areas of the southern massifs of this ophiolite. They are complemented by 133 sites, located throughout the entire ophiolite, where the transition from the RZSDC to the uppermost foliated gabbros is well exposed. Altogether, half the sites and 11 cross sections display, within a few tens of meters beneath the RZSDC, a magmatic foliation which is parallel to the overlying sheeted dikes. In the other sites and cross sections, the gabbro foliation is either flat-lying or steep but not parallel to the sheeted dikes. Compared to the RZSDC isotropic ophitic gabbros where clinopyroxene is interstitial between plagioclase laths, in the topmost steeply foliated gabbros, clinopyroxene is idiomorphic, becoming rapidly granular and tabular down section by recrystallization and peripheral alteration to hornblende. Moving down from these uppermost gabbros and over one hundred meters, the steep foliation becomes stronger and the poorly recovered top gabbros grade into the recrystallized, granular gabbros of the gabbro unit. These repeated observations indicate to ascribe these gabbros to subsidence of a compacting mush from the floor of the melt lens into the underlying, main magma chamber. The topmost gabbros beneath RZSDC, which were expelled from the melt lens by drifting very soon after settling on the melt lens floor, display in plagioclase a spectacular zoning pointing to a fast cooling. Moving downwards, stronger foliation, increased compaction and recovery-recrystallization are explained by the time spent by the subsiding mush inside the magma chamber increasing by one order of magnitude (similar to 50 to 500 yr) over this vertical distance. This field-based study brings compelling field evidence supporting the former models of subsidence which were based on the assumption that the mush that settled onto the floor of the melt lens is sucked downwards during drifting of the crust away from the ridge axis.
ISSN: 0012-821X

hal-00420903
https://hal.archives-ouvertes.fr/hal-00420903
DOI : 10.1016/j.epsl.2009.04.012

Éditeur(s) : HAL CCSD
Résumé : IODP Hole U1309D (IODP Exp. 304-305, 30°N) and ODP Site 1275 (ODP Lag 209, 15°45?N) sampled two oceanic core complexes, at the Mid-Atlantic Ridge. The recovered rocks are mostly gabbroic with some very primitive and olivine rich (Ol>70%). In Hole U1309D, trace element compositions of clinopyroxene and plagioclase poikiloblasts from olivine-rich rocks ndicate that they crystallized from the same melt in all lithologies. Olivine trace element compositions are in disequilibrium with the two other minerals. Olivine crystallographic preferred orientations are weak, with a relatively strong uncommon [001] concentration but consistent with deformation by dislocation creep with activation of the high temperature (010) [100] slip system, commonly described in asthenospheric mantle. The joint study of geochemical processes and microstructures in these rocks suggest a complex crystallization history in an open system with percolation of large volume of MORBtype melt and interaction with the depleted shallow mantle. Olivine-rich rocks are interpreted as the ultimate residue of these melt-mantle reaction processes. At Site 1275, the formation of the more evolved rocks of the gabbroic series is not related to the impregnation event creating olivine-rich rocks.
These rocks represent late magmatic injections, which are completely crystallized at depth as intrusivegabbroic bodies. The results presented in this thesis are consistent with the formation of oceanic core complexes associated with relatively strong magmatic activity, and with the crystallization of most of melt in the lithosphere without basaltic counterpart erupted on the seafloor.
Le puits IODP U1309D (Exp. IODP 304-305, 30°N) et le Site ODP 1275 (Leg ODP 209, 15°45'N) ont permis d'échantillonner deux core complexes océaniques de la dorsale Médio-Atlantique. Les roches récupérées sont principalement gabbroïques dont certaines très primitives et riches en olivine (ol >70%). Dans le puits U1309D, les compositions en éléments en trace des poeciloblastes de clinopyroxène et de plagioclase des roches riches en olivine indiquent qu'ils précipitent depuis le même magma dans toutes les lithologies. La composition en éléments en trace des olivines est en déséquilibre avec ces deux minéraux. Les fabriques cristallographiques de l'olivine sont faibles avec une concentration sur [001] inhabituelle, néanmoins compatibles avec une déformation plastique de haute température, avec l'activation du système de glissement (010) [100] communément décrit dans le manteau asthénosphérique. L'étude conjointe des caractéristiques géochimiques et microstructurales de ces roches met en lumière une histoire complexe de cristallisation dans un système ouvert où de larges volumes de magma de type MORB ont percolé et interagi avec le manteau appauvri superficiel. Ces roches riches en olivine représenteraient le résidu ultime de ces réactions liquide-manteau. Au site 1275, la formation des roches les plus évoluées de la série n'apparaît pas liée à l'événement d'imprégnation formant les roches riches en olivine. Ces roches correspondent à des injections tardives de magma qui ont entièrement cristallisé en profondeur sous forme de plutons intrusifs. Les résultats présentés dans ce mémoire sont compatibles avec une formation des core complexes océaniques associée à une activité magmatique relativement importante, et à une cristallisation complète de tout ou partie de ces magmas dans la lithosphère sans contre-partie volcanique en surface.
https://tel.archives-ouvertes.fr/tel-00354807

tel-00354807
https://tel.archives-ouvertes.fr/tel-00354807
https://tel.archives-ouvertes.fr/tel-00354807/document
https://tel.archives-ouvertes.fr/tel-00354807/file/these_MD.pdf

Éditeur(s) : HAL CCSD AGU and the Geochemical Society
Résumé : Mid-ocean ridges magmatism is, by and large, considered to be mostly dry. Nevertheless, numerous works in the last decade have shown that a hydrous component is likely to be involved in ocean ridges magmas genesis and/or evolution. The petrology and geochemistry of peculiar coarse grained gabbros sampled in the upper part of the gabbroic sequence from the northern Oman ophiolite (Wadi Rajmi) provide information on the origin and fate of hydrous melts in fast-spreading oceanic settings. Uncommon crystallization sequences for oceanic settings (clinopyroxene crystallizing before plagioclase), extreme mineral compositions (plagioclase An% up to 99, and clinopyroxene Mg # up to 96), and the presence of magmatic amphibole, imply the presence of a high water activity during crystallization. Various petrological and geochemical constraints point to hydration, resulting from the recycling of hydrothermal fluids. This recycling event may have occurred at the top of the axial magma chamber where assimilation of anatectic hydrous melts is recurrent along mid-ocean ridges or close to segments ends where fresh magma intrudes previously hydrothermally altered crust. In ophiolitic settings, hydration and remelting of hydrothermally altered rocks producing hydrous melts may also occur during the obduction process. Although dry magmatism dominates oceanic magmatism, the dynamic behavior of fast-spreading ocean ridge magma chambers has the potential to produce the observed hydrous melts (either in ophiolites or at spreading centers), which are thus part of the general mid-ocean ridges lineage.
ISSN: 1525-2027

hal-00939400
https://hal.archives-ouvertes.fr/hal-00939400
DOI : 10.1002/ggge.20137

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
A suite of eclogite xenoliths from the Roberts Victor kimberlite (South Africa) is remarkable for its high abundances of base metal sulfides (BMS; up to 2 modal %). However, while sulfides are nearly ubiquitous in Type I eclogites (garnet > 0.07% Na2O), Type II eclogites (garnet < 0.07% Na2O) systematically lack sulfides. Two different sulfide assemblages are recognised within the Type I xenolith suite. Both populations are polyphase Cu-Ni-Fe sulfides, one characterised by the pyrrhotite (Po) + pentlandite (Pn) + chalcopyrite (Cp) assemblage and the other by the smythite/violarite (Smy/Vi) + (Ni)pyrite (Py) + Cp assemblage. The latter is the most abundant assemblage and reflects the supergene alteration of the "primary" Po + Pn + Cp assemblage. This process overprints the original composition of the sulfides by remobilising elements such as S, Fe, Ni, Se and Te. In the Type I eclogites, BMS occur as inclusions within silicates (garnet and clinopyroxene) and as interstitial grains. No chemical differences were observed between enclosed and interstitial sulfides. However, their relative abundances are correlated, indicating a similar origin. The Po + Pn + Cp assemblage is identical to eclogitic sulfides previously described in some Roberts Victor diamonds. Silicate-enclosed sulfides could appear to be early phases, but they are restricted to the outer parts of the silicate grains, suggesting a late incorporation during partial recrystallisation of silicate phases, induced by fluid-rock percolation-reaction during a metasomatic event. Positive whole-rock correlations between Se and (La/Sm)N⁎ and between Cu and ΣLREEN⁎ indicate a direct link between sulfide content and the enrichment of Mg + incompatible elements in the Type I eclogites, further supporting a metasomatic origin of the sulfide component. Similarly, a negative correlation between ΣLREEN⁎ and Cucpx implies that the metasomatic agent was at least partially composed of S-rich fluid (e.g. H2S, SO2) that reacted with the rock and leached Cu out of the silicates. The coupling between sulfides and LREE in the Type I eclogites, as well as the absence of sulfides and metasomatic features (e.g. unequilibrated grain boundaries, melt pockets, fluid inclusions, phlogopite) in the Type II eclogites, demonstrate that Type II eclogites did not undergo such a metasomatic event and therefore may represent the less-modified protoliths of Type I eclogites.
ISSN: 0009-2541

hal-00903856
https://hal.archives-ouvertes.fr/hal-00903856
DOI : 10.1016/j.chemgeo.2013.06.015

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The ultramafic rocks of the Collo region in northeastern Algeria crop out as “stratified” masses that cut across older metamorphic formations of the Petite Kabylie basement. Based on petrological compositions and mineralogical observations, these rocks are mainly peridotites and serpentinites. The peridotites are identified as lherzolites, but dunites may occur rarely. The lherzolites are composed of olivine, orthopyroxene, clinopyroxene and chromian spinel. Their chemical composition shows high MgO (34.4–37.5 wt%), Cr (0.14–0.27 wt%), Ni (0.14–0.26 wt%) and Co (34–133 ppm) contents and low CaO and Al2O3 concentrations (0.02–2.2 wt% and 0.5 to 2.8 wt%, respectively). The chromite, which represents approximately 1–3% of the rock, is ubiquitous and shows two different generations: primary millimetric euhedral crystals and secondary fine xenomorphic grains and interstitial aggregates. The primary chromites are alumino-ferro-magnesian crystals that show high Al2O3 (25.77%–27.36%) and MgO (10.70%–13.36%). Cr# (100 × Cr/(Al + Cr)) ranges from 45 to 48, and Mg# (100 × Mg/(Mg + Fe2+)) from 49 to 59. The secondary interstitial grains are iron-rich chromites. They show low Al2O3 (4.67%–9.54%) and MgO (4.60%–4.65%). Cr# is relatively high (77–88), whereas Mg# shows relatively low values, ranging from 22 to 25. Primary chromite and whole-rock chemistry show that the Collo ultramafic rocks belong to Alpine-type peridotites that were emplaced within an orogenic setting. The oxygen isotopic composition of both peridotites and chromites is consistent with their derivation from a mantle source (δ18O ranges from +3.0 to +5.9‰). Low δ18O values (<+4.4‰) are recorded in serpentinites and are attributed to the effect of serpentinization processes through high-temperature metasomatic fluids. Magnesite-bearing serpentinites show the lowest δ18O values. These are interpreted as the result of surface water input.
ISSN: 0899-5362

hal-01468003
https://hal.archives-ouvertes.fr/hal-01468003
DOI : 10.1016/j.jafrearsci.2016.10.012

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Geochemical studies of primitive basalts have documented the presence of crustal-derived garnet pyroxenite in their mantle sources. The processes whereby melts with the signature of garnet pyroxenite are produced in the mantle are, however, poorly understood and somewhat controversial. Here we investigate a natural example of the interaction between melts of garnet pyroxenite derived from recycled plagioclase-rich crust and surrounding mantle in the Ronda peridotite massif. Melting of garnet pyroxenite at ∼1.5 GPa generated spinel websterite residues with MREE/HREE fractionation and preserved the positive Eu anomaly of their garnet pyroxenite precursor in whole-rock and clinopyroxene. Reaction of melts from garnet pyroxenite with depleted surrounding peridotite generated secondary fertile spinel lherzolite. These secondary lherzolites differ from common spinel lherzolite from Ronda and elsewhere by their lower-Mg# in clinopyroxene, orthopyroxene and olivine, lower-Cr# in spinel and higher whole-rock Al2O3, CaO, Sm/Yb and FeO⁎ at a given SiO2. Remarkably, secondary spinel lherzolite shows the geochemical signature of ghost plagioclase in the form of positive Eu and Sr anomalies in whole-rock and clinopyroxene, reflecting the transfer of a low-pressure crustal imprint from recycled pyroxenite to hybridized peridotite. Garnet pyroxenite melting and melt-peridotite interaction, as shown in the Ronda massif, may explain how the signature of subducted or delaminated crust is transferred to the mantle and how a garnet pyroxenite component is introduced into the source region of basalts. The efficiency of these processes in conveying the geochemical imprint of crustal-derived garnet pyroxenite to extruded lavas depends on the reactivity of pyroxenite melt with peridotite and the mantle permeability, which may be controlled by prior refertilization reactions similar to those documented in the Ronda massif. Highly fertile heterogeneities produced by pyroxenite-peridotite interaction, such as secondary spinel lherzolite in Ronda, may nucleate magmatic channels that remain chemically isolated from the ambient mantle and act as preferential pathways for melts with the signature of recycled crust.
ISSN: 0012-821X

hal-00814010
https://hal.archives-ouvertes.fr/hal-00814010
DOI : 10.1016/j.epsl.2012.11.047

Éditeur(s) : HAL CCSD Universidad de Barcelona
Résumé : Tens of Surtseyan tuff cones are exposed in the Rio Coichel valley, between Nireguao and Estancia Bano Nuevo (Southern Chilean Andes). The Early Cretaceous products of the submarine eruptions rest on, or are interbedded with, shallow marine sandstones of the Hauterivian-early Aptian Apeleg Formation. The Early Cretaceous rocks typically contain large amphibole phenocrysts, clinopyroxene and plagioclase, and have compositions that range from relatively primitive basalts to andesites. The basalts are slightly enriched in LREE and incompatible trace elements. They have low Ti-contents and negative anomalies in Nb and Ta, characteristic of subduction-related magmas. Centimetre-sized amphibole megacrysts and an amphibole-bearing clinopyroxenite xenolith have been found in one of the tuff cones located near Estancia Bano Nuevo. The amphibole megacrysts are pargasite (low Si and Ti, high Mg). The xenolith has diopsidic clinopyroxene with abundant inclusions, and pargasite veins enclosing smaller clinopyroxene neoblasts. Geochemical data show that the megacrysts and the xenolith have the same origin and correspond to underplated igneous bodies crystallized at high pressure.
ISSN: 1695-6133

hal-00512829
https://hal.archives-ouvertes.fr/hal-00512829
DOI : 10.1344/105.000001530

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
We report structural evidence of ductile strain localization in mantle pyroxenite from the spinel to plagioclase websterite transition in the Ronda Peridotite (southern Spain). Mapping shows that, in this domain, small-scale shear zones occurring at the base of the lithospheric section are systematically located within thin pyroxenite layers, suggesting that the pyroxenite was locally weaker than the host peridotite. Strain localization is associated with a sudden decrease of grain size and increasing volume fractions of plagioclase and amphibole as a result of a spinel to plagioclase phase transformation reaction during decompression. This reaction also fostered hydrogen extraction ('dehydroxylation') from clinopyroxene producing effective fluid saturation that catalyzed the synkinematic net-transfer reaction. This reaction produced fine-grained olivine and plagioclase, allowing the onset of grain-size sensitive creep and further strain localization in these pyroxenite bands. The strain localization in the pyroxenites is thus explained by their more fertile composition, which allowed earlier onset of the phase transition reactions. Geothermobarometry undertaken on compositionally zoned constituent minerals suggests that this positive feedback between reactions and deformation is associated with cooling from at least 1000°C to 700°C and decompression from 1*0 to 0*5 GPa.
ISSN: 0022-3530

hal-00941293
https://hal.archives-ouvertes.fr/hal-00941293
DOI : 10.1093/petrology/egt039

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
In ophiolites and in present-day oceanic crust formed at fast spreading ridges, oceanic plagiogranites are commonly observed at, or close to the base of the sheeted dike complex. They can be produced either by differentiation of mafic melts, or by hydrous partial melting of the hydrothermally altered sheeted dikes. In addition, the hydrothermally altered base of the sheeted dike complex, which is often infiltrated by plagiogranitic veins, is usually recrystallized into granoblastic dikes that are commonly interpreted as a result of prograde granulitic metamorphism. To test the anatectic origin of oceanic plagiogranites, we performed melting experiments on a natural hydrothermally altered dike, under conditions that match those prevailing at the base of the sheeted dike complex. All generated melts are water saturated, transitional between tholeiitic and calc-alkaline, and match the compositions of oceanic plagiogranites observed close to the base of the sheeted dike complex. Newly crystallized clinopyroxene and plagioclase have compositions that are characteristic of the same minerals in granoblastic dikes. Published silicic melt compositions obtained in classical MORB fractionation experiments also broadly match the compositions of oceanic plagiogranites; however, the compositions of the coexisting experimental minerals significantly deviate from those of the granoblastic dikes. Our results demonstrate that hydrous partial melting is a likely common process in the root zone of the sheeted dike complex, starting at temperatures exceeding 850A degrees C. The newly formed melt can either crystallize to form oceanic plagiogranites or may be recycled within the melt lens resulting in hybridized and contaminated MORB melts. It represents the main MORB crustal contamination process. The residue after the partial melting event is represented by the granoblastic dikes. Our results support a model with a dynamic melt lens that has the potential to trigger hydrous partial melting reactions in the previously hydrothermally altered sheeted dikes. A new thermometer using the Al content of clinopyroxene is also elaborated.
ISSN: 0010-7999

hal-00534058
https://hal.archives-ouvertes.fr/hal-00534058
DOI : 10.1007/s00410-010-0502-6

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
To understand the deep cycle of water, upper mantle water content and distribution between nominally anhydrous minerals (NAMs) and hydrous minerals (e.g., amphibole) must be constrained. We need then to understand H behaviour during mantle melting and metasomatism. Major, minor and trace element compositions including water contents were obtained on ten xenoliths of spinel-bearing peridotites from the Ray Pic locality, in the Southern part of the Massif Central (France). The sample suite investigated here is composed of rather fertile lherzolites (89.4 ≤ Fo ≤ 90.8%; 11.3 ≤ cr# in spinel ≤ 21.1%; 0.942 ≤ [Yb]cpx ≤ 1.90 ppm; cpx: clinopyroxene), which can be best explained by batch melting, with degree of melting between 3 and 10%. These xenoliths contain up to 8% modal amphibole. Three groups are defined as a function of the amphibole modal abundance (above or below 1%) and equilibrium temperature (above or below 1000 °C). Results show no clear positive correlation between modal metasomatism (amphibole) and incompatible element enrichment in cpx. Trace element compositions in cpx show strong enrichments of the most incompatible elements (e.g., (La/Sm)PM as high as 15.7; PM: normalised to primitive mantle values), but strong negative anomalies of the high field strength elements (e.g., (Th/Nb)PM as high as ~ 680). Such trace element fractionations are usually ascribed to the so-called carbonatitic metasomatism involving the percolation of small volume melts which are enriched in volatiles. The hydrogen concentrations in cpx range from 203 to 330 ppm wt. H2O, in orthopyroxene from 66 to 160 ppm wt. H2O and in olivine from 2 to 6 ppm wt. H2O. These values are within the common concentration range of other spinel-bearing peridotites. Amphiboles contain 1.9 ± 0.5 wt.% of H2O.The effect of metasomatism on water abundances in NAMs is not straightforward. Hydrous metasomatism (i.e., leading to the crystallisation of OH-bearing amphibole) has no effect on the water content of the co-existing NAMs. This suggests thus that the occurrence of hydrous minerals, such as amphibole, does not systematically imply that the coexisting NAMs are water-rich (saturated). Further, the percolation of volatile-rich small volume melts, which is fingerprinted by the strong enrichment of the incompatible elements, has also no clear effect on the water content of the NAMs. These data are thus difficult to reconcile with the admitted highly incompatible behaviour of H in upper mantle minerals.
ISSN: 0024-4937

hal-01278062
https://hal.archives-ouvertes.fr/hal-01278062
DOI : 10.1016/j.lithos.2015.08.013