Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Chalkidiki block is a major domain in the North Aegean that, contrary to other domains in the region, largely escaped thermal perturbations during Tertiary extension. As a result, the Chalkidiki block is an ideal candidate to glean information related to the timing of Mesozoic thermal events using appropriate geochronological techniques. We have undertaken a laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) study (U-Th-Pb on monazites and U-Pb on zircons) coupled with 40Ar/39Ar dating on nine samples from various structural levels within the thrust system of the Chalkidiki block. The eastern, and structurally lower part of the system revealed a complete isotopic reset of Carboniferous – Early Triassic monazites coeval with partial monazite destruction, REE-mobilisation and formation of apatite-allanite-epidote coronas at ~ 132 Ma, a reaction that is commonly observed in amphibolite-facies rocks. These coronas formed after crystallisation of garnet (i.e., at T > 580 °C) and, in all probability, either close to the peak-temperature conditions (~ 620 °C) on a prograde path or during retrogression between the peak-temperature and the low-temperature boundary of the amphibolite facies. Cooling of these rocks and arrival at mid-crustal levels occurred at 95–100 Ma. By contrast, the western, and structurally uppermost part of the system went through the same event by 120–125 Ma. Further structural considerations with respect to medium-temperature geochronology data imply that syn-metamorphic thrusting must have ceased by early Late Cretaceous. We emphasize that, with the sole exception of the Chalkidiki block, no pre-45 Ma medium-temperature geochronology data are preserved in other North Aegean domains, a feature that is clearly related to the extension-induced thermal perturbation of the region during the Tertiary.
ISSN: 0040-1951

insu-01329472
https://hal-insu.archives-ouvertes.fr/insu-01329472
https://hal-insu.archives-ouvertes.fr/insu-01329472/document
https://hal-insu.archives-ouvertes.fr/insu-01329472/file/kydonakis-tectono-2016.pdf
DOI : 10.1016/j.tecto.2016.06.006

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
High-grade migmatitic and mylonitic gneisses from the Day Nui Con Voi massif in northern Vietnam record temperatures of 760-810 °C at pressures of 6-10 kbars. High temperature conditions have resulted in the development of major element diffusional profiles in garnet. Laser ablation ICP-MS analyses of trace elements indicate that REE and Hf closely followed Rayleigh-like fractionation trends but underwent significant post-crystallization modification. Light REE and to a lesser extent, HREE rim-to-rim zonation profiles show progressive flattening with the decreasing garnet size. Nd and Sm are completely homogenized in the crystals smaller than 1.5 mm, while Lu always preserves variable degrees of core-to-rim concentration gradient. The observed REE patterns are interpreted as resulting from the combination of protracted garnet growth of progressively smaller crystals and intracrystalline diffusion. This had profound influence on Sm-Nd geochronology and resulted in isochron ages ranging from 50 to 32 Ma. The youngest age was obtained for a sample, where all garnet crystals are smaller than 2 mm in which light REE profiles are completely or nearly completely homogenized. Thus, only the youngest age represents geologically meaningful event, and 31.7 ± 0.9 Ma age is interpreted as the best estimate of the resetting episode due to high temperature diffusional homogenization of light REE during early Oligocene metamorphism. Older Sm-Nd ages reflect mixed analyses of variably reset individual garnet crystals. Lu-Hf isotopic analyses of bulk garnet fractions, despite yielding high parent/daughter isotopic ratios appeared very scattered and did not allow defining isochron ages. Instead, apparent ages defined by whole rock and individual garnet fractions range from c. 80 to 160 Ma. Very old apparent ages are interpreted as being the consequence of intracrystalline Lu diffusion and preservation of the original Hf distribution, which leads to lower 176Lu/177Hf ratios, and thus steeper (older) isochrons. Back diffusion of Lu during commonly observed resorption played a subordinate role in modifying isotope systematics.
ISSN: 0009-2541

hal-00813949
https://hal.archives-ouvertes.fr/hal-00813949
DOI : 10.1016/j.chemgeo.2012.04.024

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
Cobalt-bearing pyrite (0.5-2.0 wt.% Co) is abnormally abundant (up to 35 vol.% of the total volume of the sulfide phase) in some eastern Pyrenean peridotite massifs, compared to pieces of subcontinental mantle studied so far for sulfides. Pyrite occurs as vermicular intergrowths inside pentlandite and/or chalcopyrite or as coarser, blocky grains in the intergranular pores of host peridotites. Those different pyrites are characterized by different platinum-group element systematics (measured by laser ablation microprobe and ICP-MS). Vermicular pyrite intergrown with pentlandite displays Os-, Ir-, Ru- and Rh-enriched chondrite normalized PGE patterns of Monosulfide solid solution (Mss). In contrast, coarse-grained intergranular ("blocky") pyrites, are PGE-poor. Chalcophile trace elements (i.e. Zn, Pb, Ag, Au) that are not usually concentrated in mantle-derived sulfides were commonly detected. By contrast, selenium contents are generally low, yielding thus pyrite with high S/Se ratio (> 10(5)), consistent with a sedimentary sulfur source. Pyrite microtextures and chalcophile trace element contents support a process of assimilation of crustal sulfur from the metamorphosed sedimentary country rocks. These latter generated highly reactive CO2-S fluids, which were injected into structural discontinuities of the lherzolitic bodies. Sulfur has reacted at T = 300-550A degrees C with pre-existing, mantle-derived, metal-rich sulfide assemblages (pentlandite-chalcopyrite). Addition of crustal sulfur did produce Mss which, on cooling, exsolved the Os-rich pyrite in addition to pentlandite. The coarse-grained pyrite types have crystallized directly from S-rich fluids.
ISSN: 0010-7999

hal-00617425
https://hal.archives-ouvertes.fr/hal-00617425
DOI : 10.1007/s00710-010-0138-2

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
For the first time, an albite orthogneiss has been recognised and dated within the HP-LT blueschist facies metabasites and metapelites of the Ile de Groix. It is characterised by a peraluminous composition, high LILE, Th and U contents, MORB-like HREE abundances and moderate Nb and Y values. A U-Pb age of 480.8 ± 4.8 Ma was obtained by LA-ICP-MS dating of zircon and titanite. It is interpreted as the age of the magmatic emplacement during the Early Ordovician. Morphologically different zircon grains yield late Neoproterozoic ages of 546.6-647.4 Ma. Zircon and titanite U-Pb ages indicate that the felsic magmatism from the Ile de Groix is contemporaneous with the acid, pre-orogenic magmatism widely recognised in the internal zones of the Variscan belt, related to the Cambro-Ordovician continental rifting. The magmatic protolith probably inherited a specific chemical composition from a combination of orogenic, back-arc and anorogenic signatures because of partial melting of the Cadomian basement during magma emplacement. Besides, the late Devonian U-Pb age of 366 ± 33 Ma obtained for titanite from a blueschist facies metapelite corresponds to the age of the HP-LT peak metamorphism.
ISSN: 1437-3254

insu-00714570
https://hal-insu.archives-ouvertes.fr/insu-00714570
DOI : 10.1007/s00531-011-0732-5

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Detrital zircons in metasedimentary rocks attributed to three different complexes in the Central and Pernambuco-Alagoas domains of the Borborema Province, northeastern Brazil, were dated by LA-ICP-MS. Two samples from each of the following complexes were analyzed: Sertania and Surubim, in the Central Domain, and Rio Una, in the Pernambuco-Alagoas Domain. One sample of the Sertania Complex yielded only Paleoproterozoic zircons, whereas Neoproterozoic zircons predominate in the other, with the youngest zircon indicating deposition after 642 Ma. One of the samples of the Surubim Complex yielded, again, only Paleoproterozoic concordant zircon ages. In the other sample, although Paleoproterozoic zircons predominate, ages vary from the Mesoarchean to the Neoproterozoic. The age of the youngest zircon in this latter sample indicates deposition after 850 Ma and an overgrowth on an Archean grain yielded an age of 623 +/- 6 Ma (2 sigma), interpreted as the age of peak metamorphism. The two samples of the Rio Una Complex yielded predominantly detrital zircons with ages in the ranges 2.2-2.1 Ga and 1.7-1.6 Ga. In this complex, the youngest detrital zircon suggests deposition after 917 Ma and metamorphic zircons indicate peak metamorphic conditions between 600 Ma and 617 Ma.;The results of this study, together with available data from the literature, allow the following conclusions: (a) The Sertania Complex is a Neoproterozoic sequence, and not Paleoproterozoic, as previously thought; (b) The similarity in lithological associations, detrital zircon populations and C isotope signature between the Sertania and Surubim complexes suggest that they belong to the same lithostratigraphic unit; (c) Although the Rio Una Complex can be older than the Sertania/Surubim Complex, the lack of zircons younger than 900 Ma can also result from insufficient sampling or absence of young rocks alongside the drainage system that collected detritus to this complex: (d) The regional metamorphism related to the Brasiliano Orogeny attained its climax at 630-600 Ma; (e) The age spectra of detrital zircons require their derivation from erosion of rocks formed not only during known geological events in the Borborema Province and in the nearby Sao Francisco/Congo Craton, but also from the Amazonian Craton, suggesting accumulation in an intracratonic setting within a preexisting large continent: (f) The short timespan between deposition and orogenic deformation may explain the overall medium- to high-temperature metamorphism due to maintenance, in the subsequent compressional event, of the elevated geothermal gradients produced during broad-scale lithosphere extension.
ISSN: 0301-9268

hal-00443856
https://hal.archives-ouvertes.fr/hal-00443856
DOI : 10.1016/j.precamres.2009.09.009

Éditeur(s) : HAL CCSD Cambridge University Press (CUP)
Résumé : In NW Turkey, the medium-grade Kemer micaschists of the Biga Peninsula record NE-directed extension related to ductile to brittle–ductile shearing during the Palaeogene period: a lower limit for their exhumation is given by the Late Maastrichtian age of the HP–LT metamorphism of a similar nearby area (Çamlica micaschists); an upper limit is given by the Early Eocene intrusion age of the post-kinematic Karabiga granitoid, dated as 52.7 ± 1.9 Ma using the U–Pb LA–ICP–MS method on xenotime. Correlations with the northeasterly Rhodope region and integration into the geodynamic regional frame indicate that the Kemer micaschists experienced an extensional deformation connected to a collisional context in latest Cretaceous–early Tertiary times. The Kemer micaschists therefore represent a new area (the first in Turkey), which suffered synorogenic extension in the north Aegean domain at the very beginning of Tertiary times.
ISSN: 0016-7568

hal-00407955
https://hal.archives-ouvertes.fr/hal-00407955
DOI : 10.1017/S001675680700310X

Éditeur(s) : HAL CCSD Royal Society of Chemistry
Résumé : International audience
LA-ICP-MS analysis of the chemical composition of biogenic carbonate has many applications in the environmental sciences but the characteristics of the material produced by the ablation process are largely unknown. To fill this gap, we have undertaken a study of the chemical and physical nature of particles produced by laser ablation of biogenic carbonates. SEM imaging suggests that laser ablation produces two distinct particle populations, one consisting of microsize particles and the other of nanosize particles. A 213 nm laser gives rise to a higher proportion of microsize particles than a 193 nm laser, probably because the 213 nm laser couples less completely with carbonate material. The microsize particles appear to form by photomechanical fracturing along lines of cleavage or weakness, rather than by hydrodynamic sputtering (as is generally observed for silicates). Chemical analysis of the carbonate particles suggests that little chemical fractionation of biogenic carbonates occurs during the ablation process or during transport to the plasma. This is supported by the constancy of the fractionation factor ([X/Ca](measured)/[X/Ca] true) during the course of an ablation of a carbonate standard. In contrast, changes in the fractionation factor during the first few seconds of ablation of the NIST 612 are observed for some elements. This difference in fractionation is likely to result from the different formation mechanisms of the microsize particles.
ISSN: 0267-9477

hal-00411933
https://hal.archives-ouvertes.fr/hal-00411933
DOI : 10.1039/b706727e

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Generation and emplacement of felsic magmas in the Paleoproterozoic Baoulé-Mossi domain, West African Craton does not match the apparent peaks of global crust generation identified between ca. 2900–2600, 1900–1600 and 1200–900 Ma. In contrast, across the Baoulé-Mossi domain, the emplacement of felsic intrusions ranges from ca. 2300 to 2000 Ma. It has proven difficult to place this magmatism within a robust geodynamic framework due to the lack of accurate geochronological data from across the West African Craton. The present study addresses this issue by presenting eighty-four new felsic intrusions zircon ion microprobe and LA-ICP-MS U-Pb ages from areas that up until now have not been targeted for geochronology. The new dataset, when fully integrated with existing age data, reveals a craton-wide diachronous geochronological pattern characterized by a magmatic front that migrated westward. This migration proceeded at a rate of 35 km per million years, with an apparent offset of the initiation and cessation of felsic magmatic activity between the east and west of approximately 50 million years. The new data also show that although the entire Baoulé-Mossi domain was subject to continuous magmatic activity for at least 150 million years, this magmatic activity displays a rather different record in the eastern and western portions of the domain. The differences are expressed as a westward migration of the magmatic activity, cessation of activity around ca. 2100 Ma (easternmost portion) and ca. 2050 Ma (westernmost portion) and a higher incidence of inherited ages in the westernmost portion when compared to the easternmost region. In addition, the new U-Pb data identify some of the oldest felsic intrusions in the region, including a granite from Burkina Faso (2265 ± 17 Ma) and a diorite porphyry (2216 ± 5 Ma) in southern Mali. This study also reveals inherited Archean zircon cores from across southern Mali. The combination of the new data presented here, along with previously published data, suggests that the Baoulé-Mossi domain formed from the accretion of two major crustal blocks. The Archean inherited ages open a window for further investigation of the interaction between the Archean Kénéma-Man and the Paleoproterozoic Baoulé-Mossi domains.
ISSN: 0301-9268

hal-01623272
https://hal.archives-ouvertes.fr/hal-01623272
DOI : 10.1016/j.precamres.2017.07.036

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Serpentinites from subduction environments represent an important sink for fluid-mobile elements. In order to constrain geochemical behavior of fluid-mobile elements hosted by serpentine phases during subduction processes, we carried out a geochemical study (trace elements and Pb isotopes) of a series of serpentinites and cumulates from the accretionary wedge of Greater Caribbean (Cuba and Dominican Republic). The trace element compositions of the primary and alteration-related phases were analyzed in situ using LA-HR-ICP-MS techniques. The studied samples represent parts of the subducted proto-Atlantic oceanic lithosphere, which has experienced low to high grade metamorphism (greenschist to eclogite facies), before being exhumed; a subset of these samples were derived from the mantle wedge. This sampling provides the opportunity to trace the chemical mobility of fluid-mobile elements during prograde metamorphism along a cold geotherm in an oceanic subduction setting.
ISSN: 0009-2541

hal-00720895
https://hal.archives-ouvertes.fr/hal-00720895
DOI : 10.1016/j.chemgeo.2012.04.009

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
New U–Pb monazite, zircon, and xenotime ages date the Late Carboniferous crystallization of the anatectic Vialais granite in the Montagne Noire Axial Zone and the high-temperature deformation and metamorphism of the augen gneiss (Ordovician granite protolith) from which the granite was likely derived. The U–Pb monazite ages obtained from the augen gneiss (308 ± 3 Ma), late kinematic Vialais granite (303 ± 4 Ma), and post-kinematic leucogranite (298 ± 2 Ma), bracket the high-temperature deformation and metamorphism at ~ 310–300 Ma, clearly postdating regional contraction and nappe emplacement (> 320 Ma). The planar–linear and locally linear fabrics in the augen gneiss outline a regional-scale double dome structure (Caroux and Espinouse sub-domes) containing smaller (km-scale) upright folds. Compared to the Caroux sub-dome, the larger, migmatitic Espinouse sub-dome contains abundant leucosome, leucogranite bodies and late-kinematic intrusions (Vialais granite). The Vialais granite displays a weak magmatic foliation that defines the main layering of the Espinouse migmatite. Ellipsoidal quartz–sillimanite nodules concentrated above the roof of the granite recorded an increment of strain (vertical shortening, E–NE elongation) during granite emplacement and crystallization, consistent with the extension event that exhumed the domes. These new geochronological and structural data suggest that the Montagne Noire double dome formed in a pull-apart structure within a dextral strike–slip system. Upright folding in the sub-domes has been traditionally assigned to a regional contraction event; alternatively, we propose that local contraction is associated with the convergence of low-viscosity crust beneath the upper crust pull-apart. Dynamic models of extension of hot crust indicate that contraction at depth is generated by flow of low-viscosity orogenic crust converging and rising to fill the gap created by upper crust extension. This interpretation solves the long-standing problem of apparent coeval contraction and extension in the Montagne Noire double dome and establishes migmatite dome emplacement in strike–slip corridors as a style of late Variscan tectonics.
ISSN: 0040-1951

insu-01112009
https://hal-insu.archives-ouvertes.fr/insu-01112009
DOI : 10.1016/j.tecto.2014.12.002

Éditeur(s) : HAL CCSD Ecological Society of America
Résumé : Reliable assessment of fish origin is of critical importance for exploited species, since nursery areas must be identified and protected to maintain recruitment to the adult stock. During the last two decades, otolith chemical signatures (or "fingerprints") have been increasingly used as tools to discriminate between coastal habitats. However, correct assessment of fish origin from otolith fingerprints depends on various environmental and methodological parameters, including the choice of the statistical method used to assign fish to unknown origin. Among the available methods of classification, Linear Discriminant Analysis (LDA) is the most frequently used, although it assumes data are multivariate normal with homogeneous within-group dispersions, conditions that are not always met by otolith chemical data, even after transformation. Other less constrained classification methods are available, but there is a current lack of comparative analysis in applications to otolith microchemistry. Here, we assessed stock identification accuracy for four classification methods (LDA, Quadratic Discriminant Analysis [QDA], Random Forests [RF], and Artificial Neural Networks [ANN]), through the use of three distinct data sets. In each case, all possible combinations of chemical elements were examined to identify the elements to be used for optimal accuracy in fish assignment to their actual origin. Our study shows that accuracy differs according to the model and the number of elements considered. Best combinations did not include all the elements measured, and it was not possible to define an ad hoc multielement combination for accurate site discrimination. Among all the models tested, RF and ANN performed best, especially for complex data sets (e. g., with numerous fish species and/or chemical elements involved). However, for these data, RF was less time-consuming and more interpretable than ANN, and far more efficient and less demanding in terms of assumptions than LDA or QDA. Therefore, when LDA and QDA assumptions cannot be reached, the use of machine learning methods, such as RF, should be preferred for stock assessment and nursery identification based on otolith microchemistry, especially when data set include multispecific otolith signatures and/or many chemical elements.
ISSN: 1051-0761

hal-00644549
https://hal.archives-ouvertes.fr/hal-00644549
DOI : 10.1890/09-1887.1

Éditeur(s) : HAL CCSD Wiley
Résumé : International audience
We report trace element analyses by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) of metal grains from nine different CR chondrites, distinguishing grains from chondrule interior ("interior grains"), chondrule surficial shells ("margin grains"), and the matrix ("isolated grains"). Save for a few anomalous grains, Ninormalized trace element patterns are similar for all three petrographic settings, with largely unfractionated refractory siderophile elements and depleted volatile Au, Cu, Ag, S. All three types of grains are interpreted to derive from a common precursor approximated by the least-melted, fine-grained objects in CR chondrites. This also excludes recondensation of metal vapor as the origin of the bulk of margin grains. The metal precursors were presumably formed by incomplete condensation, with evidence for high-temperature isolation of refractory platinum-group-element (PGE)-rich condensates before mixing with lower temperature PGE-depleted condensates. The rounded shape of the Ni-rich, interior grains shows that they were molten and that they equilibrated with silicates upon slow cooling (1-100 K h 1), largely by oxidation/evaporation of Fe, hence their high Pd content, for example. We propose that Ni-poorer, amoeboid margin grains, often included in the pyroxene-rich periphery common to type I chondrules, result from less intense processing of a rim accreted onto the chondrule subsequent to the melting event recorded by the interior grains. This means either that there were two separate heating events, which formed olivine/ interior grains and pyroxene/margin grains, respectively, between which dust was accreted around the chondrule, or that there was a single high-temperature event, of which the chondrule margin records a late "quenching phase," in which case dust accreted onto chondrules while they were molten. In the latter case, high dust concentrations in the chondrule-forming region (at least three orders of magnitude above minimum mass solar nebula models) are indicated.
ISSN: 1086-9379

hal-01003975
https://hal.archives-ouvertes.fr/hal-01003975
DOI : 10.1111/maps.12212

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
IODP Hole U1309D (Atlantis Massif, Mid-Atlantic Ridge 30 degrees N) is the second deepest hole drilled into slow spread gabbroic lithosphere. It comprises 5.4% of olivine-rich troctolites (->70% olivine), possibly the most primitive gabbroic rocks ever drilled at mid-ocean ridges. We present the result of an in situ trace element study carried out on a series of olivine-rich troctolites, and neighbouring troctolites and gabbros, from olivine-rich intervals in Hole U1309D. Olivine-rich troctolites display poilkilitic textures; coarse-grained subhedral to medium-grained rounded olivine crystals are included into large undeformed clinopyroxene and plagioclase poikiloblasts. In contrast, gabbros and troctolites have irregularly seriate textures, with highly variable grain sizes, and locally poikilitic clinopyroxene oikocrysts in troctolites. Clinopyroxene is high Mg# augite (Mg# 87 in olivine-rich troctolites to 82 in gabbros), and plagioclase has anorthite contents ranging from 77 in olivine-rich troctolites to 68 in gabbros. Olivine has high forsterite contents (82-88 in olivine-rich troctolites, to 78-83 in gabbros) and is in Mg-Fe equilibrium with clinopyroxene. Clinopyroxene cores and plagioclase are depleted in trace elements (e.g., Yb-cpx similar to 5-11 x Chondrite), they are in equilibrium with the same MORB-type melt in all studied rock-types. These compositions are not consistent with the progressively more trace element enriched (evolved) compositions expected from olivine rich primitive products to gabbros in a MORB cumulate sequence. They indicate that clinopyroxene and plagioclase crystallized concurrently, after melts having the same trace element composition, consistent with crystallization in an open system with a buffered magma composition. The slight trace element enrichments and lower Cr contents observed in clinopyroxene rims and interstitial grains results from crystallization of late-stage differentiated melts, probably indicating the closure of the magmatic system. In contrast to clinopyroxene and plagioclase, olivine is not in equilibrium with MORB, but with a highly fractionated depleted melt, similar to that in equilibrium with refractory oceanic peridotites, thus possibly indicating a mantle origin. In addition, textural relationships suggest that olivine was in part assimilated by the basaltic melts after which clinopyroxene and plagioclase crystallized (impregnation). These observations suggest a complex crystallization history in an open system involving impregnation by MORB-type melt(s) of an olivine-rich rock or mush. The documented magmatic processes suggest that olivine-rich troctolites were formed in a zone with large magmatic transfer and accumulation, similar to the mantle-crust transition zone documented in ophiolites and at fast spreading ridges.
ISSN: 0009-2541

hal-00420916
https://hal.archives-ouvertes.fr/hal-00420916
DOI : 10.1016/j.chemgeo.2009.02.013

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Borborema Province of northeastern Brazil is divided into three main domains: northern, central, and southern. Several U-Pb zircon ages of plutons and orthogneisses became available in the recent years in the central and northern domains, but similar results are scarce in the southern domain. This study reports U-Pb dates for single zircon grains from one orthogneiss (Jupi orthogneiss) and two plutons (Cachoeirinha syenitic pluton and Cabanas granite) south of the East Pernambuco shear zone system (EPSZ). The results provide geochronological constraints on the timing of deformation and magmatism in this part of the southern domain and allow correlations with the central domain. The Jupi orthogneiss was emplaced and deformed during development of the regional flat-lying foliation. A Pb-206/U-238 weighted apparent mean age of 606 +/- 8 Ma is interpreted as the crystallization age of the protolith of the orthogneiss and consequently the age of high-grade Brasiliano metamorphism. The NNE-trending Cachoeirinha pluton is only locally affected by strike-slip deformation, whereas the ENE-trending Cabanas granite is intensely affected by deformation related to the EPSZ. The 587 8 Ma and 573 4 Ma ages of the Cachoeirinha pluton and Cabanas granite, respectively, bracket the main period of activity of the EPSZ. Tectonomagmatic activity in the study area is similar to the age of Brasiliano events in the central domain, north of the EPSZ. In addition, xenocrystic zircons in the Jupi orthogneiss and Cabanas granite are interpreted as inherited from Paleoproterozoic source rocks, suggesting the presence of widespread reworked old crust in the southern domain, similar to the central domain. These results support the idea that the central and southern domains belonged to the same crustal block before the onset of the Brasiliano orogeny.
ISSN: 0895-9811

hal-00411394
https://hal.archives-ouvertes.fr/hal-00411394
DOI : 10.1016/j.jsames.2007.06.003

Éditeur(s) : HAL CCSD BioMed Central
Résumé : International audience
ABSTRACT: BACKGROUND: The amount of lead in the environment has decreased significantly in recent years, and so did exposure. However, there is no known safe exposure level and, therefore, the exposure of children to lead, although low, remains a major public health issue. With the lower levels of exposure, it is becoming more difficult to identify lead sources and new approaches may be required for preventive action. This study assessed the usefulness of lead isotope ratios for identifying sources of lead using data from a nationwide sample of French children aged from six months to six years with blood lead levels (B-Pb) [greater than or equal to] 25 ug/L. METHODS: Blood samples were taken from 125 children, representing about 600,000 French children; environmental samples were taken from their homes and personal information was collected. Lead isotope ratios were determined using quadrupole ICP-MS (inductively coupled plasma - mass spectrometry) and the isotopic signatures of potential sources of exposure were matched with those of blood in order to identify the most likely sources. RESULTS: In addition to the interpretation of lead concentrations, lead isotope ratios were potentially of use for 57% of children aged from six months to six years with blood lead level [greater than or equal to] 25 ug/L (7% of overall children in France, about 332,000 children), with at least one potential source of lead and sufficiently well discriminated lead isotope ratios. Lead isotope ratios revealed a single suspected source of exposure for 32% of the subjects and were able to eliminate at least one unlikely source of exposure for 30% of the children. CONCLUSIONS: In France, lead isotope ratios could provide valuable additional information in about a third of routine environmental investigations.
ISSN: 1476-069X

inserm-00624817
http://www.hal.inserm.fr/inserm-00624817
http://www.hal.inserm.fr/inserm-00624817/document
http://www.hal.inserm.fr/inserm-00624817/file/1476-069X-10-75.pdf
DOI : 10.1186/1476-069X-10-75

Éditeur(s) : HAL CCSD
Résumé : National audience
Le standard d’eau de rivière naturelle SLRS-5 (NRC-CNRC) est uneréférence de contrôle qualité en analyse d’eau de routine pour la communautéinternationale. Dix laboratoires français étudiant les élémentsmajeurs et en trace dans les solutions naturelles (groupe de travail del’atelier du CNRS « Isotrace ») valident leurs mesures avec les 19 élémentscertifiés par le producteur. Or, d’autres éléments non certifiés sontrégulièrement analysés par ces laboratoires qui ont comparé et compilé2 années de leurs mesures sur ce standard d’eau. La plupart desmesures sont réalisées par ICP-MS (Inductively Coupled Plasma Mass-Spectrometry).Dans un premier temps, il a été vérifié que les résultats obtenus étaientcohérents pour les éléments certifiés par le producteur. Ainsi Ba présenteune valeur compilée de 14,2 1,4 g/l (330 mesures issues de 9laboratoires participants) en accord avec la valeur certifiée de 14 0,5g/l.Ensuite, des valeurs moyennes et leurs incertitudes associées sont proposéespour des éléments non certifiés par NRC-CNRC tels que le siliciumet 35 éléments en trace (terres rares, Ag, B, Bi, Cs, Ga, Ge, Li, Nb,P, Rb, Rh, Re, S, Sc, Sn, Th, Ti, Tl,W, Y et Zr). Le rapport isotopique deSr est aussi proposé à partir de mesures par TIMS (Thermo IonisationMass Spectrometry).Il apparaît que les mesures individuelles et compilées varient dequelques ng/l à 2400 g/l avec des incertitudes associées comprisesentre 2 et 240%. Les fortes incertitudes associées ne sont pas proportionnellesaux concentrations puisque certaines mesures s’accordent mêmeà de faibles teneurs tels que Bi (0,9 0,3 ng/l valeur compilée). Danscertains cas, un ou deux laboratoires ont caractérisé l’élément impliquantmoins de mesures et une incertitude associée plus élevée quelleque soit la concentration en l’élément. C’est le cas, par exemple, de Ge(0,015 0,014 g/l valeur compilée) caracterisé par seulement 2 laboratoires(34 mesures) et de P (8,19 3,40 g/l) issu de 8 mesuresd’un seul laboratoire. Les terres rares et onze autres éléments (B, Bi,Cs, Li, Rb, Si, Th, Ti, Tl, Y et Zr) ont été déterminés par au moins 3laboratoires différents et apportent des informations complémentairesessentielles à l’utilisation
24 ème Réunion des sciences de la Terre 2014
Pau, France

insu-01080879
https://hal-insu.archives-ouvertes.fr/insu-01080879

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Geochronological studies of samples from continuous crustal sections of fossil intra-oceanic arcs are paramount for determining the precise timing of major processes that took place during the building of an oceanic island-arc crust. In this study, laser ablation ICP-MS U-Pb zircon (and conventional Rb-Sr) analyses pinpoint the timing of major events responsible for crustal growth of the Kohistan paleo-island arc (Northern Pakistan). Inheritance in magmatic rocks is evidence for recycling of intra-arc material and indicates that the Kohistan arc may have formed as early as 135 +/- 4 Ma. One older inherited grain indicates that the arc developed on a young oceanic lithosphere whose remnants include a c. 175 Ma old component. An interesting consequence is that intra-oceanic arc magmas can yield inherited zircons, which can be much older than the arc system itself without requiring recycling back into the mantle by subduction processes. In the case of the Kohistan arc, ante-arc Neotethys oceanic lithosphere was tapped by arc magmas during their way upward into the arc crust. The oldest magmatic ages measured in this study fall in the range 101-102 Ma (100.9 +/- 0.6 and 102.1 +/- 0.4 Ma). This period corresponds to arc build-up and thickening of the arc crust. Leucogranitic melts dated at 89.9 +/- 0.4 Ma and 90.9 +/- 1.0 Ma are considered as produced by dehydration/melting reaction accompanying granulitisation of the thickened lower arc crust. A maximum age for this event is 97.7 +/- 0.7 Ma, the age of emplacement of a garnet meta-tonalite affected by granulite facies metamorphism. Magmatic activity was still ongoing during and after the granulitisation as testified by emplacement of a diorite and a gabbro dated at 89.1 +/- 0.6 and 88.2 +/- 0.9 Ma respectively. The upper part of the metaplutonic sequence contains diorite samples dated at 84.6 +/- 0.5 Ma and 84.3 +/- 0.5 Ma and as young as 81.1 +/- 0.7 Ma. During this period, and based on the present day outcropping sequences, the mean crustal growth rate varied from 32 to 65 km(3)/km/Ma (volume per unit width along the strike of the arc) which is comparable to the range for present day arcs of the Western Pacific region. The correspondence of crustal growth rates observed for present-day island arcs and the good preservation of the crustal section in the Kohistan arc, make this area an exceptional natural laboratory to study arc related processes and to check models of continental crust formation by arc accretion.
ISSN: 0012-821X

hal-00644555
https://hal.archives-ouvertes.fr/hal-00644555
DOI : 10.1016/j.epsl.2011.07.016

Éditeur(s) : HAL CCSD Elsevier
Résumé : Integrated field, LA-MC-ICP-MS geochronology and geochemical data from the Novo Oriente Group have been investigated in order to determine their provenance and possible tectonic setting. This group in the southwestern portion of the Ceara Central Domain, is a well-preserved metavolcanosedimentary sequence, in part exhalative, composed of two distinct formations. The proximal coastal Bonsucesso Formation comprises mainly quartzite and minor basic metavolcanic rocks and is in gradational contact with the distal Caranbas Formation which constitutes a metapelitic-volcanic-carbonate sequence, including metabasic rocks with pillow structure and sheared serpentinized ultrabasic rocks. The youngest detrital zircon found in the quartzite of the Bonsucesso Formation yielded an age of ca. 2.1 Ga and well-defined peaks around 2.2.2.3-2.4 and 2.5 Ga. In addition, zircons from a related metabasalt yielded an upper intercept age of 2083 +/- 28 Ma. We interpret the zircons found in this metabasalt as inherited from the host quartzite. This fact is supported by depleted-mantle Nd model ages (T-DM age) from correlated metabasic and metaultrabasic rocks from other places in the Novo Oriente sequence, which have yielded ages between 1.36 and 1.69 Ga, that is younger than the zircon age obtained in the metabasalt extruded over the Bonsucesso quartzite. Geochemical data of the metasedimentary rocks from the Caraubas Formation indicates a provenance composed of a mixture of felsic and intermediate sources typical of old stable cratons and older continental roots of active tectonic settings. The rocks of the Crania (Medio Coreau Domain) and Bacaja Complexes (southeastern Amazonian Craton) exposed to the west of the Novo Oriente Group, and largely covered by the Phanerozoic Parnaiba intracratonic basin, are the most likely source rocks. Since the precise age of the Novo Oriente Group is not yet well constrained, two distinct settings may be proposed: (1) it may represent a more evolved basin developed from extensional processes during the Mesoproterozoic (ca. 1.5-1.3 Ga); and (2) it could constitute part of the passive margin systems developed during the break-up of the Rodinia crown copyright supercontinent (ca. 0.95-0.8 Ga), associated with a pre-Brasiliano/Pan-African ocean (e.g. Pharusian Ocean). Crown.
ISSN: 1342-937X

hal-00512825
https://hal.archives-ouvertes.fr/hal-00512825
DOI : 10.1016/j.gr.2010.02.001

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Eastern Hoggar is by far the least well known part of the Tuareg Shield. It is composed, from west to east, of the Aouzegueur, Edembo and Djanet Terranes. The Djanet Terrane is the easternmost Hoggar terrane and comprises a greenschist-facies clastic sedimentary sequence, the Djanet Group, intruded by granitoids. Laser ablation (LA-) ICP-MS U-Pb zircon ages of detrital zircons from these sediments yield a large range of ages similar to ages known in Central and Western Hoggar; the youngest is 590 +/- 10 Ma (2 sigma), which is the maximum age of deposition of the Djanet Croup. The Djanet Group is intruded by the Djanet Batholith (571 +/- 16 Ma), by high-level subcircular plutons such as the Tin Bedjane Pluton (568 +/- 5 Ma) and finally by the felsic Tin Amali Dyke Swarm (558 +/- 5 Ma), all ages being SHRIMP U-Pb zircon. The deposition and metamorphism of the Djanet Group thus occurred between 590 Ma (the age of the youngest detrital zircons analyzed in the Djanet Group) and c. 570 Ma (the age of intrusive granitoids). Nd T-DM two-stage model ages (1.30-2.03 Ga), initial Sr-87/Sr-86 ratios (0.7035-0.7095) and epsilon(Nd) (-3 to -11) of the three intrusive suites, all being high-K calc-alkaline in composition, indicate mainly an old, Rb-depleted continental source. Migmatization in the adjacent Edembo Terrane is dated at 568 +/- 4 Ma (U-Pb zircon SHRIMP age), contemporaneous with the intrusion of the Djanet plutons. Rocks and events in the Edembo and Djanet Terranes are all intracontinental. We propose that the Djanet Terrane lies on the boundary of a craton located to the north-east, that we defined here as the Murzuq craton. The existence of the Murzuq craton is supported by sedimentary and geophysical data. We suggest that the deformation of Eastern Hoggar occurred 575-555 Ma, due to the indentation of the Murzuq craton and has no link with the older convergence with the West African craton as was the case for the central and western parts of the Tuareg Shield. This determines a late Ediacaran intracontinental Murzukian event that probably also occurred to the east in the Tibesti area.
ISSN: 0301-9268

hal-00512833
https://hal.archives-ouvertes.fr/hal-00512833
DOI : 10.1016/j.precamres.2010.05.011

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In pre-drift reconstructions, the central and southern parts of the Borborema Province, northeastern Brazil, belong to a large Brasiliano-Pan-African orogenic realm situated to the north of the São Francisco-Congo Craton. In order to better understand the timing and geodynamic setting under which this orogenic system developed, a structural, geochemical and geochronological study was conducted across the east Pernambuco shear zone (EPSZ) system, which separates the Pernambuco-Alagoas Domain (PEAL) from the Central Domain. A sample of the Pinhões orthogneiss (GE-1), in the Central Domain, one sample of a syenitic orthogneiss (CA-34) wrapped by the EPSZ, and one sample of orthogneiss named Altinho (CA-40), in the northern portion of the PEAL, were dated by LA-ICP-MS. The Pinhões orthogneiss yielded an age of 869 ± 9 Ma, interpreted as the emplacement age of the protolith during a late Tonian magmatic episode. Samples CA-40 and CA-34 yielded 206Pb/238U weighted mean ages of 652 ± 6 Ma and 636 ± 3 Ma, respectively, which are interpreted as dating emplacement and crystallization of the magmatic protoliths. However, it is also possible that these rocks were formed during the same magmatic event in view of the identical ages of 646 ± 13 Ma and 646 ± 11 Ma, respectively, given by the less precise upper intercept of the discordia lines. The metaluminous and magnesian nature of the Altinho orthogneiss is akin to the calc-alkalic suite. However, some samples plot in the intraplate field in tectonic discrimination diagrams and the Nd TDM model age of 1.36 Ga is unlike that of juvenile magmas in convergent settings. The Altinho orthogneiss is quite similar in terms of trace elements geochemistry to the syenitic orthogneiss, which has a clearer intraplate affinity, and the dated samples have identical initial Sr isotope ratios (0.7047). Therefore, emplacement in an extensional setting is preferred over a convergent one. Two samples of paragneisses (SB-1 and BB-9) from the PEAL were also dated. The ages of the youngest zircon grains in sample BB-9 (655–642 Ma) overlap the crystallization age of the Altinho orthogneiss, implying that sedimentation is younger than or, at best, synchronous with magmatism. The age of low Th/U grains in samples CA-34 (615 ± 8 Ma) and SB-1 (587 ± 12 Ma) are related to a subsequent metamorphic overprint, which is loosely constrained between 580 and 620 Ma. These observations, combined with evidence provided by previous studies, suggest that the change from an extensional to a contracional setting occurred at ca. 640–630 Ma. In contrast with most collisional orogens, where a long period of oceanic subduction precedes collision, the inferred tectonic evolution suggests that the Brasiliano Orogeny resulted from inversion of continental and/or proto oceanic rifts.
ISSN: 0895-9811

hal-01174177
https://hal.archives-ouvertes.fr/hal-01174177
DOI : 10.1016/j.jsames.2014.09.007