Éditeur(s) : HAL CCSD Mineralogical Society of America
Résumé : International audience
The effect of trace concentrations of Ti on the rate and mechanism of hydrogen diffusion in pure forsterite was investigated experimentally. Forsterite doped with 350–400 ppm Ti (predominantly octahedral Ti3+, minor tetrahedral Ti4+) was prepared by diffusing Ti into pure synthetic forsterite at high temperature (1500 °C), very low oxygen fugacity (~QFM-5) at atmospheric pressure. The Ti-doped forsterite was then diffusively hydroxylated in a piston-cylinder apparatus at much lower temperatures (650–1000 °C) and higher oxygen fugacities, at 1.5–2.5 GPa, with chemical activities buffered by forsterite-enstatite or forsterite-periclase and partial pressure of H2O equal to total pressure. This produced hydrogen concentration-distance profiles of several hundred micrometers in length. Diffusion of hydrogen through the Ti-doped forsterite, even at very high Embedded Image , does not lead to redox re-equilibration of the high Ti3+/ΣTi ratio set during the synthesis of the starting material at extremely reducing conditions—the metastable point defects are partially preserved.Three main hydroxylated point defects are observed; hydroxyl is associated with Ti4+ (titano-clinohumite point defects), Ti3+ (and possibly other trivalent cations), and M-site vacancies. Concentration-distance profiles represent an interplay between diffusion and reaction (i.e., site rearrangement) to form the observed point defects. In all experiments, the concentration-distance profiles of the hydroxylated Ti defects coincide with the concentration-distance profiles of the M-site vacancy substitution, with the same crystallographic anisotropy. This suggests that the macroscopic movement of hydrogen through the crystal is due to one diffusion mechanism (the diffusion of hydroxylated M-site vacancies). The net H diffusion coefficient [logD(ΣH)], between 650–1000 °C, is Embedded Image where the values of logD0(ΣH) parallel to [100] and [001] directions are −3.0 ± 0.4 and −2.2 ± 0.4, respectively; diffusion is therefore around one order of magnitude faster along the c axis than along the a axis. The diffusion of hydrogen is slightly faster in Ti-doped forsterite than in pure forsterite. There is no effect of chemical activity or oxygen fugacity on the rate of diffusion. Hydrogen diffusion profiles represent a complex interplay between the movement of H through the crystal lattice and point-defect reactions to maintain charge balance.
ISSN: 0003-004X

hal-01467402
https://hal.archives-ouvertes.fr/hal-01467402
DOI : 10.2138/am-2016-55681571

Éditeur(s) : HAL CCSD
Résumé : The mantle deformation processes that control the thinning and break-up of continental lithosphere remain poorly understood. Our knowledge is restricted to either lithospheric scale thermo-mechanical models --that use experimentally derived flow laws--, geophysical imaging and/or rare xenoliths from active continental rifts, such as the East African Rift System. The originality of this work relies on the study of the two largest outcrops of diamond facies subcontinental lithospheric mantle in the world: the Beni Bousera and Ronda peridotite massifs in N Morocco and S Spain, respectively. The structures and petrologic and metamorphic zoning preserved in these massifs --implying a polybaric and polythermal evolution-- provides a unique opportunity to investigate the thermo-mechanical evolution of thick subcontinental lithospheric mantle in extensional settings. In this thesis we studied the deformation mechanisms in both peridotites and pyroxenites to constrain the modes of exhumation of subcontinental lithospheric mantle from garnet-, to spinel-, and finally, to plagioclase lherzolite facies conditions. We combined field mapping of tectonometamorphic domains and structural mapping of ductile structures, microstructural analysis, crystal preferred orientations (CPO) measurements and conventional thermobarometric calculations and thermodynamic modeling (Perple_X) to unravel the pressure and temperature conditions of deformation. We showed that exhumation from garnet- to spinel lherzolite facies conditions was accommodated by fast shearing --in thermal disequilibrium--along a lithospheric scale transtensional shear zone. In this context, the petrological zoning and the large temperature gradient (ca. 100ºC/km) preserved in the Beni Bousera massif represent the mechanical juxtaposition of progressively deeper and hotter lithospheric levels at depths of ca. 60 km in the latest Oligocene (ca. 25 Ma). Final exhumation from spinel- to plagioclase facies lherzolite and emplacement into the crust is best recorded in the Ronda massif where it occurred by inversion and lithospheric scale folding of the highly attenuated continental lithosphere in a back-arc region, probably in relation with southward slab rollback and subsequent collision with the palaeo-Maghrebien passive margin in the early Miocene (21-23 Ma).
Les processus de déformation contrôlant l'amincissement de la lithosphère continentale sont encore mal contraints. Nos connaissances sont principalement basées sur la modélisation thermomécanique d'extension à l'échelle de la lithosphère--utilisant des lois rhéologiques derivées expérimentalement, l'imagerie géophysique et l'analyse de xénolithes provenant de rift continentaux actifs à ce jour, tels que le Rift Est-Africain. L'originalité de ce travail reside dans l'étude des deux plus grands massifs de péridotites sous-continentales ayant enregistrées des conditions primaires du facies à diamant: les massifs de Beni Bousera au nord du Maroc et de Ronda au sud de l'Espagne, respectivement. Les structures et la zonation petrologique et métamorphique --impliquant une évolution polybarique et polythermique-- préservéees dans ces massifs offrent une opportunité unique pour étudier l'évolution thermo-mécanique du manteau sous-continental dans un contexte extensif. Dans ce travail, nous avons étudié les mécanismes de déformation des péridotites et des pyroxénites afin de contraindre les modes d'exhumation du manteau lithosphérique sous-continental, depuis des conditions du facies des lherzolites à grenat, jusqu'au facies à spinelle et enfin à plagioclase. Nous avons combiné la cartographie des faciès tectono-métamorphiques et des structures ductiles de déformation, l'analyse des microstructures, la mesure d'orientations préférentielles de réseau (OPR), et la géothermobarométrie conventionelle couplée à la modélisation thermodynamique (PerpleX) afin de contraindre les conditions de pression et température de la déformation. Nous avons montré que l'exhumation précoce du facies à grenat au facies à spinelle était accomodée par une faille transtensive affectant le manteau lithosphérique. Dans ce contexte, la zonation tectono-métamorphique et le gradient thermique important (ca. 100ºC/km) préservés à Beni Bousera résultent de la juxtaposition mécanique de domaines lithosphériques initialement équilibrés à différentes pressions et températures, fossilisée à une profondeur de ca. 60 km durant l'Oligocène supérieur (ca. 25 Ma). L'exhumation finale du facies de lherzolite à spinelle au facies à plagioclase et l'emplacement final dans la croûte, mieux enregistrés dans Ronda, se sont produits par inversion et plissement de la section lithosphérique fortement amincie dans un contexte arrière-arc, probablement lors du retrait vers le sud de la lithosphère subduite et la collision de l'arc avec les paléo-marges maghrébines au Miocène inférieur (21-23 Ma).
https://tel.archives-ouvertes.fr/tel-00767700

tel-00767700
https://tel.archives-ouvertes.fr/tel-00767700
https://tel.archives-ouvertes.fr/tel-00767700/document
https://tel.archives-ouvertes.fr/tel-00767700/file/THESE_Frets.pdf

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Detailed structural and petrological mapping in the Beni Bousera peridotite (Rif Belt, northern Morocco) shows that this orogenic peridotite massif is composed of four tectono-metamorphic domains with consistent kinematics, marked by a pervasive, shallowly dipping foliation with a NW-SE stretching lineation that progressively rotates towards a NNE-SSW orientation in the lowermost part of the massif. From top to bottom, these domains are garnet-spinel mylonites, Ariègite subfacies fine-grained porphyroclastic spinel peridotites, Ariègite-Seiland subfacies porphyroclastic, and Seiland subfacies coarse-porphyroclastic to coarse-granular spinel peridotites. Microstructures and crystal preferred orientations point to deformation dominantly by dislocation creep in all domains, but the continuous increase in average olivine grain size indicates decreasing plastic work rates from top to bottom. This evolution in deformation conditions is consistent with the change in synkinematic pressure and temperature conditions, from 900°C at 2*0 GPa in garnet-spinel mylonites to 1150°C at 1*8 GPa in the Seiland domain. A pervasive diffuse dunitic-websteritic layering subparallel to the foliation suggests deformation in the presence of melt in the Seiland domain. Gravitational instabilities owing to local melt accumulation may account for <200 m wide areas exhibiting a vertical lineation in this domain. To account for the consistent kinematics and the tectono-metamorphic evolution, which implies a temperature gradient of c. 125°C km−1 preserved across the Beni Bousera massif, we propose that the entire massif records the functioning of a low-angle shear zone, a few kilometres wide, which accommodated exhumation of the base of the lithosphere from ∼90 to ∼60 km depth. Partial melting in the Seiland domain may be explained by fast decompression of the footwall, without the need for exotic heat sources. Moreover, if the present-day orientation of the shear zone is similar to that when it was active in the mantle, the stretching lineations at high angle to the metamorphic gradient imply that shearing parallel to the trend of the belt accompanied thinning; that is, a transtensional deformation of the margin.
ISSN: 0022-3530

hal-00950056
https://hal.archives-ouvertes.fr/hal-00950056
DOI : 10.1093/petrology/egt067

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Unusual high-pressure inner thermal aureoles are described from the Minador and Angico Torto epidote-bearing tonalitic plutons that emplaced into green schist-facies metasedimentary rocks of the Neoproterozoic Cachoeirinha-Salgueiro belt, northeastern Brazil. The foliated pelitic hornfelses display the mineral assemblage garnet, kyanite, staurolite, muscovite, biotite, plagioclase +/- quartz. Rare fibrolite is only found very close to the contacts. Hornfelses display steep mineral lineations and steeply-dipping foliations concordant with magmatic contacts. Leucocratic veinlets containing quartz, oligoclase, garnet, kyanite, staurolite, rutile and ilmenite suggest that limited melting conditions were reached very close to magmatic contacts (T >= 650 degrees C, P around 8 kbar). These high-pressure hornfelses form a few meters thick, rigid envelopes around the two plutons. Contrary to known examples of kyanite-bearing hornfelses that recorded high-temperature decompression, the nearly isobaric cooling down to ca. 450 degrees C is constrained by 3.20-3.30 Si contents of retrogressive phengites from both inner hornfelses and ductilely-deformed tonalite at the pluton margins. Isograds and bathograds are, therefore, apparently telescoped due to HP/LT shearing, possibly caused by subsequent differential vertical movements affecting these two solidified plutons. The unusual depth of emplacement of these syn-kinematic calc-alkaline plutons is explained by a tentative geodynamic model involving a pre-620 Ma-subduction setting.
ISSN: 0895-9811

hal-00424503
https://hal.archives-ouvertes.fr/hal-00424503
DOI : 10.1016/j.jsames.2008.09.005

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In orogenic systems, thrust faults play a major role in stacking different tectonic units and may act as conduits for the expulsion of large amounts of fluid of different origins (metamorphic, diagenetic, meteoric). This study focuses on the Monte Perdido thrust unit emplaced in the Paleogene Jaca thrust-sheet-top basin, in the SW-central Pyrenees. We aim to decipher the mechanisms and P-T conditions of deformation in fault zones and characterize the related fluid involvement, through combined microstructural, geochemical and microthermometry analyses. Two thrust faults cutting platform limestones, marls and siliciclastic turbidites of the lower part of the basin-fill (Paleocene-lower Eocene) have been studied. The fault zones are characterized by metre-thick shear zones with highly deformed, foliated clay-rich sediments. Foliation is underlined by preferentially oriented phyllosilicates. Several generations of shear and extension calcite, quartz and chlorite-bearing veins attest to fluid-rock interactions during a multi-stage deformation. Microstructural observations and stable isotope analyses on calcite from veins and host sediments suggest that deformation was aseismic and dominated by diffusive mass transfer from pressure solution sites along cleavage and stylolites to the precipitation sites in veins, with mineralizing fluids in equilibrium with the host sediments. Our results suggest an essentially closed hydrologic system, and imply the absence of significant fluid flow along the studied fault zones. Microthermometric study on fluid inclusions present in calcite and quartz veins, and calcite-quartz oxygen isotopic fractionation determined for the first generation shear veins, allow a geothermal gradient of 34 degrees C/km to be estimated. Analytical results demonstrate an evolution of the fault zones in three stages. The first stage was related to the emplacement of the Monte Perdido thrust unit during the middle Eocene at a temperature of similar to 208 degrees C and a burial depth of similar to 5.7 km. The second stage corresponds to a fault reactivation at a temperature of similar to 240 degrees C and a burial depth of similar to 6.5 km. The latter deformation may have been related to folding of the Monte Perdido thrust unit during the emplacement of the underlying Gavarnie thrust unit during the late Eocene-early Oligocene, with deeper burial resulting from aggradation of the thrust-sheet-top basin-fill. The last event corresponds to the formation of a dilatant vein system likely related to the exhumation of the massif.
ISSN: 0191-8141

hal-00644828
https://hal.archives-ouvertes.fr/hal-00644828
DOI : 10.1016/j.jsg.2011.06.006

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
This study presents microstructural evidence for deformation-controlled melt organization and for changes in olivine deformation associated with the presence of melt in an 80 m vertical section of the crust-mantle transition zone in the Oman ophiolite. This zone represents an 'end member' case for analyzing feedbacks between deformation and melt distribution in the upper mantle, since it experienced strong shear strains in presence of large melt fractions. It is characterized by a subhorizontal compositional layering at the mm to meter scale, from weakly impregnated dunites to olivine-rich gabbros, which parallels a pervasive foliation containing a strong stretching lineation. The parallelism between the compositional layering and the foliation, the diffuse limits of the layers, the alignment of elongated plagioclase-rich aggregates devoid of internal deformation structures with the elongation of olivine crystals in the dunitic layers, and the sharp compositional changes across some, but not all layer limits suggest deformation plays an essential role on the development of the layering. The variation on a mm-scale of the olivine crystal preferred orientation (CPO) symmetry as a function of the modal content: from axial-[100] symmetry in layers with <70% modal olivine to axial-[010] in more gabbroic levels (<40% olivine), which is repeated over the entire section, implies deformation in presence of variable melt fractions. Axial-[100] olivine CPO in olivine-rich layers is consistent with deformation by dislocation creep under high temperature, low pressure, dry conditions. Axial-[010] olivine CPO patterns imply additional sliding along preferentially wetted (010) grain boundaries, increase in the activity of [001] glide, or transpression localized in the melt-rich layers. Since the change in CPO symmetry is not accompanied by dispersion, instantaneous melt fractions must have remained <30-40% in all layers. The continuous variation in olivine CPO symmetry with decreasing olivine content implies therefore that the former depends on the cumulated strain in presence of melt rather than on the instantaneous melt fraction.
ISSN: 0012-821X

hal-00795508
https://hal.archives-ouvertes.fr/hal-00795508
DOI : 10.1016/j.epsl.2012.10.003

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Syn-orogenic detachments in accretionary wedges make the exhumation of high-pressure and low-temperature metamorphic rocks possible with little erosion. The velocity of exhumation within the subduction channel or the accretionary complex, and thus the shape of P-T paths, depend upon the kinematic boundary conditions. A component of slab retreat tends to open the channel and facilitates the exhumation. We document the effect of slab retreat on the shape of P-T paths using the example of the Phyllite-Quartzite Nappe that has been exhumed below the Cretan syn-orogenic detachment during the Miocene in Crete and the Peloponnese. Data show a clear tendency toward colder conditions at peak pressure and during exhumation where the intensity of slab retreat is larger. This spatial evolution of P-T gradient is accompanied with an evolution from a partly coaxial regime below the Peloponnese section of the detachment toward a clearly non-coaxial regime in Crete.
ISSN: 0040-1951

insu-00411771
https://hal-insu.archives-ouvertes.fr/insu-00411771
https://hal-insu.archives-ouvertes.fr/insu-00411771/document
https://hal-insu.archives-ouvertes.fr/insu-00411771/file/Jolivet-Tectonophysics-2010.pdf
DOI : 10.1016/j.tecto.2009.10.002

Éditeur(s) : HAL CCSD Geological Society of America
Résumé : International audience
his study describes the structural setting, petrogenesis, and geochronology of a suite of acidic magmatic rocks that are intruded in the metamorphic core of the Tertiary ophiolitic suture zone of the Sabzevar Range, NE central Iran. These intrusive bodies show tabular geometries with solid-state fabrics documenting syntectonic emplacement during crustal shortening. In the total alkalis-silica (TAS) diagram, their compositions define a medium-K calc-alkaline suite, spanning from basaltic andesite to the dacite and rhyolite fields. They show characteristic low MgO (0.15–0.60 wt%) and Ni (<20 ppm), high Sr contents, a negligible Eu anomaly, and extremely fractionated rare earth element (REEs), with high La/Yb and Sr/Y (up to 900) ratios, but very low Yb and Y contents. They also show zircon Hf isotope compositions compatible with a mid-ocean-ridge basalt (MORB)–type oceanic crust. Inverse and forward thermobarometry constrains conditions of magma crystallization in the upper-pressure field of the amphibolite facies (ca. 1.2–1.5 GPa and 750 °C). Integrated U-Pb zircon and 40Ar/39Ar white mica and amphibole geochronology constrains the Sabzevar magmatism to the late Paleocene (at ca. 58 Ma). Genesis of the Sabzevar magmatic suite is interpreted in terms of prograde, wet amphibolite melting during oceanic subduction, within a pressure-temperature range between a plagioclase-out and a hornblende-out boundary. Magma differentiation and high-pressure amphibole fractionation of pristine slab melts are proposed as the dominant factors that imparted the adakite signature in the Sabzevar structural zone. Implications in terms of the regional tectonic scenario are discussed and framed within the advancing and retreating evolution of the Neotethyan subduction during the Mesozoic–Tertiary time span.
ISSN: 0016-7606

hal-01122824
https://hal.archives-ouvertes.fr/hal-01122824
DOI : 10.1130/B30913.1

Éditeur(s) : HAL CCSD
Résumé : International audience
Understanding subduction rheology in both space and time has been a challenge since the advent of plate tectonics. We herein focus on "subduction infancy", that is the first ~1-5 My immediately following subduction nucleation, when a newly born slab penetrates into the upper plate mantle and heats up. The only remnants of this critical yet elusive geodynamic step are thin metamorphic soles, commonly found beneath pristine, 100-1000 km long portions of oceanic lithosphere emplaced on continents (i.e., ophiolites).Through the (i) worldwide compilation of pressure-temperature conditions of metamorphic sole formation augmented by pseudosection thermodynamic modeling, (ii) calculations of the viscosity of materials along the plate interface and (iii) generic numerical thermal models, we provide a conceptual model of dynamic plate interface processes during subduction infancy (and initiation s.l.).We show in particular how major rheological switches across the subduction interface control slab penetration, and the formation of metamorphic soles. Due to the downward progression of hydration and weakening of the mantle wedge with cooling, the lower plate (basalt, sediment) and the upper plate (mantle wedge) rheologies equalize and switch over a restricted temperature-time-depth interval (e.g., at ~800°C and ~1 GPa, during 0.1-2 My, for high-temperature metamorphic sole formation). These switches result in episodes of maximum interplate mechanical coupling, thereby slicing the top of the slab and welding pieces (basalt, sediment) to the base of the mantle wedge. Similar mechanical processes likely apply for the later, deeper accretion and exhumation of high-temperature oceanic eclogites in serpentinite mélanges, or for the accretion of larger tectonic slices.This model provides constraints on the effective rheologies of the crust and mantle and general understanding, at both rock and plate scale, for accretion processes and early slab dynamics.
AGU Fall Meeting 2015
San Francisco, United States

insu-01242103
https://hal-insu.archives-ouvertes.fr/insu-01242103

Éditeur(s) : HAL CCSD
Résumé : High Pressure - Low Temperature (HP-LT) rocks testify for burying and exhumation of crustal material in subduction zones. Their complete exhumation is the result of processes acting during (syn-orogenic) and after (post-orogenic) subduction is active, the latter partly obliterating the first. In the Aegean domain, the Attic-Cycladic Blueschist unit (ACBU) is a HP-LT unit exhumed in metamorphic core complexes (MCCs) in the back-arc domain of the Hellenic subduction zone. This study is an attempt to distinguish features related to syn-orogenic exhumation processes responsible for the first stages of exhumation This syn-orogenic "message" has to be read through the post-convergence structural and thermal overprint that accompanied the formation of the MCCs. Particularly, the geometry, the timing and the amount of the syn-orogenic exhumation has to be determined. We investigate these features with coupled field, metamorphic petrology and radiochronology studies First, based on observations on Ios (southern Cyclades), it has recently been proposed that syn-orogenic exhumation of the ACBU was accommodated by a basal thrust over the Cycladic Basement (CB) [Huet, et al., 2009]. The peak conditions, deduced from pseudosections calculation for the Ios main lithologies, are 500 °C-19 kbar for the ACBU and 550 °C-16 kbar for the CB. Exhumation until 400 °C-8 kbar is considered as syn-orogenic. Second, phengites populations, single grains and in situ 40Ar-39Ar geochronology has been carried out on samples from Tinos and Andros (northern Cyclades), Syros (central Cyclades) and Ios. The results gather in several clusters: 50-55 Ma, 40-45 Ma, 30-35 Ma, and 22-26 Ma. Based on these new P-T-t data and a synthesis of published data, we are able to refine the geometry and the timing of the exhumation of the ACBU. Data from the whole Cyclades exhibit little differences in ages and P-T conditions for the successive stages of exhumation. The peak of pressure (500±50 °C-18±1 kbar) has been reached at 50-55 Ma from Tinos to Ios. The onset of the exhumation occurred at 40-45 Ma in blueschist facies conditions, between a thrust at their bottom and a detachment at their top. The following decompression was accompanied by cooling until 30-35 Ma (400±50 °C-8±1 kbar). At that time, the boundary conditions switched to extension. Finally, we propose a model for the exhumation of HP-LT units accounting for these data. We also consider the rheological implications of the syn-orogenic structuration of the Aegean wedge on the post-orogenic evolution. B. Huet, L. Labrousse, and L. Jolivet [2009] Thrust or detachment? Exhumation processes in the Aegean: Insight from a field study on Ios (Cyclades, Greece), Tectonics, 28, 3, doi:10.1029/2008TC002397.
EGU General Assembly
Vienne, Austria

insu-00839054
https://hal-insu.archives-ouvertes.fr/insu-00839054
BIBCODE : 2010EGUGA..1214098H

Éditeur(s) : HAL CCSD Elsevier
Résumé : The Borborema Province, in the NE of Brazil, is a rather complex piece in the Brazil-Africa puzzle as it represents the junction of the Dahomeyide/Pharusian, Central African, Aracuai and Brasilia fold belts located between the West-African/Sao Luis, Congo/Sao Francisco and Amazonas craton. The correlation between the Dahomeyides from W-Africa (Ghana, Benin, Togo, and Mali) and the Borborema Province involves the Medio Coreau and Central Ceara domains. The inferred continuation of the main oceanic suture zone exposed in the Dahomeyides of W Africa is buried beneath the Phanerozoic Parnaiba Basin in Brazil (northwest of the Medio Coreau domain) where some high density gravity anomalies may represent hidden remnants of an oceanic suture. In addition to this major suture a narrow, nearly continuous strip composed of mainly mafic pods containing relics of eclogite-facies assemblages associated with partially migmatized granulite-facies metapelitic gneisses has been found further east in the NW Borborema Province. These high pressure mafic rocks, interpreted as retrograded eclogites, are located between the Transbrasiliano Lineament and the Santa Quiteria continental arc and comprise primitive to evolved arc-related rocks with either arc- or MORB-type imprints that can indicate either deep subduction of oceanic lithosphere or roots of continental and oceanic magmatic arcs. Average peak P-T conditions under eclogite-facies metamorphism (T=770 degrees C and P = 17.3 kbar) were estimated using garnet-clinopyroxene thermometry and Jd content in clinopyroxene. Transition to granulite-facies conditions, as well as later widespread re-equilibration under amphibolite facies, were registered both in the basic and the metapelitic rocks and suggest a clockwise P-T path characterized by an increase in temperature followed by strong decompression. A phenomenon possibly related to the exhumation of a highly thickened crust associated with the suturing of the Medio Coreau and Central Ceara domains, two distinct crustal blocks separated by the Transbrasiliano Lineament.
ISSN: 1342-937X

hal-00413584
https://hal.archives-ouvertes.fr/hal-00413584
DOI : 10.1016/j.gr.2009.01.003

Éditeur(s) : HAL CCSD E Schweizerbart Science Publishers
Résumé : The occurrence and preservation of aragonite in eclogite-facies rocks of north-eastern Corsica is linked to an uncommon microtexture. Aragonite exclusively occurs as oriented fibres in garnet crystals of a graphitic, more or less siliceous marble that immediately overlies a serpentinite body of the meta-ophiolitic unit. The arrangement of the fibres is grossly radial, but more clearly sectoral in subhedral garnet, the fibres growing perpendicular to the garnet/matrix interface. Raman mapping reveals that the carbonate is calcite in the matrix and in poikiloblastic garnet cores, and that the fibres in the garnet mantle are aragonite alone in the case of a carbonate matrix, and both aragonite and quartz (in distinct fibres) in a quartz–carbonate matrix. These features are interpreted as prograde intergrowths, the result of garnet nucleation and growth in a calcite and then aragonite matrix (±quartz). Upon further heating and/or decompression, the aragonite matrix transformed back to calcite while the carbonates included in garnet retained their original structure, in spite of the relatively high temperature attained (ca. 500 °C). These aragonite relics are one more example of the preservation of a high-pressure polymorph through mechanical shielding of inclusions in a rigid host. The aragonite–garnet intergrowths are similar to quartz–garnet intergrowths described in amphibolite-facies graphitic schists. They are evidence that oriented inclusions in garnet are not necessarily precipitates (‘exsolutions'). Unlike precipitates, their orientation is controlled more by the shape of the garnet growth front than by symmetry constraints.
ISSN: 0935-1221

hal-00411136
https://hal.archives-ouvertes.fr/hal-00411136
DOI : 10.1127/0935-1221/2008/0020-1892

Éditeur(s) : HAL CCSD
Résumé : International audience
The challenge is to implement research that can estimate the consequences ofclimate changes in terms of impact on terrestrial environments and resources.Emphasis should be placed on regions dependent on natural resources and forwhich demographic pressure is strong. Simulations obtained from climate modelprojections (using different Representative Concentration Pathways (RCPs))predict that the Mediterranean basin and its southern periphery are particularlyvulnerable to water resources and environmental impact (IPCC, AR5, 2013).An annual rainfall decrease by 30% is found for the projection period 2070-2099(IPCC, AR5, 2013) associated with a decrease in water resources by 30 to 50%(Milano, 2012). In addition, several studies using regional atmospheric modelsindicate an increase in the precipitation inter-annual variability with extremeevents and a spatial heterogeneous signature, superimposed on a decrease in thetotal precipitation amount (Giorgi and Lionello, 2008; Raible et al. 2010).Currently, regional climate projections are highly sensitive to the climate modelused. In particular, spatial resolution as well as local climate conditions seemto impact significantly on the simulations (Jacob et al. 2014).The Mediterranean region, at the interface between arid and temperate climateswith several mountainous areas, is a complex climate system affected by theinteractions between mid-latitude and sub-tropical processes. In this context,Morocco, located at the transition between a temperate climate to the North anda tropical climate to the south constitutes a key area for an impact and sensitivitystudy to global climate changes. The climate is influenced by the Atlantic Ocean,the Mediterranean Sea and the Sahara, together with a very steep orography inthe Atlas region. The precipitation distribution is therefore characterised by greatspatial variability, and exhibits a marked seasonality, a strong inter-annualvariability (Ouda et al. 2005) and in general a pronounced gradient from northto south and west to east. At a broader scale, Morocco is located on the subtropicalsubsidence path and between the Acores High and the Saharan Low (Agoussine,2003). Several studies have also identified strong links with inter-annualprecipitation variability and NAO index (Knippertz, 2003) as well as remoteclimate modes (Esper et al. 2007).Continental climate variability at a local/regional scale, if it is to be integratedin climate predictions, needs to be supported by long-term observation.Meteorological stations in Morocco provide climatic data mainly for the last40 years with only a few stations located in the mountainous region (Tramblayet al. 2012; 2013; Driouech et al. 2010). This climate database is also supportedby the IAEA network providing stations for which isotope tracers have beenapplied to daily/monthly rain and water vapour samples over 2 to 3 years between2000 and 2004. Besides the poor coverage of instrumented areas, lacustrinesystems can provide a climatic data set that offers access to short and long-termtime series of climate parameters when knowledge of modern lake water balanceis combined with lacustrine sedimentary-climate records. Lake sediment recordsideally provide high resolution climate/environmental information of the last10,000 years (Magny et al. 2013). This time interval (corresponding to theHolocene) is a key period to investigate short and long-term climate variabilityand to improve prediction in a warming climate.In this study we present an integrated approach focusing on a mountainous lake(Aguelmam Azigza). The modern lake system study is based on site monitoring(2012-2016) and available regional hydro-climatic data. These data show thatlake level changes during the instrumented period were mainly driven byprecipitation following the high inter-annual variability. These data are thencompared with accurately dated short sediment cores retrieved in the same lake.Micro-scale geochemical and sedimentological analyses of these sequencesenable us to identify various sedimentary facies that can be linked with periodsof high (low) lake levels over the past decades.
The Mediterranean Region under Climate ChangeLa méditerranée face au changement climatique

insu-01394690
https://hal-insu.archives-ouvertes.fr/insu-01394690
https://hal-insu.archives-ouvertes.fr/insu-01394690/document
https://hal-insu.archives-ouvertes.fr/insu-01394690/file/Vidaletal.2016-COP22-Chap1.pdf

Éditeur(s) : HAL CCSD
Résumé : EGU2012-6377- Geophysical Research Abstracts vol. 14
The hot geothermal fluid produced by the wells of the Bouillante power station, in Guadeloupe, contains various dissolved species such as silica or some metals (Zn, Pb, etc). During the exploitation, the geothermal fluid is flashing and cooling (from 260 to 160°C for the high-pressure steam-liquid separation and down to 110°C for the low-pressure phase separation of a part of the separated liquid at 160°C). Consequently, the dissolved species can form scale deposits such as amorphous silica or poly-metallic sulphides, according to the exploitation conditions, and cause serious scaling problems on the production and the surface installations. These minerals could also precipitate during the partial underground re-injection of the production fluids which is being set up in the Bouillante power station. In this study, in order to predict and prevent the possible silica precipitation at temperature lower than 160°C, during the partial underground reinjection of the production fluids of Bouillante or their thermal valorization down to 110°C temperatures, we propose to investigate on site the kinetics of silica precipitation as a function of temperature and pH. The experiments presented here were carried out on site on samples of separated waters collected after the steam-water separator at 160°C, containing about 600 ppm of SiO2, at four cooling temperatures: 22, 50, 75 and 90°C, and for pH ranging from 4 to 9. These experiments showed that the silica deposition was always initiated by a polymerization mechanism characterized by an order 2 kinetic law and the formation of a white colloidal gel, which slowed down the silica precipitation under solid form. This latter was observed much later, after the polymerization stage, and only in particular conditions (long time of atmospheric exposure, water stagnation,. . . ). The results also confirmed that the silica precipitation kinetics is strongly dependent on pH. In acidic solution, a transition period is observed before the beginning to the silica polymerization. At neutral-basic pH, there is no transition period and the rate of polymerization is maximal for pH close to 8. The undergoing modeling of these experimental data and specific surface area measurements on the colloidal gel will allow us to determinate the kinetics parameters useful for the prediction and prevention of silica precipitation under the specific exploitation conditions of Bouillante power station. This work is financially supported by ADEME (French Agency for Energy and Environment), BRGM and UAG.
EGU General Assembly 2012
Vienne, Austria

hal-00697627
https://hal-brgm.archives-ouvertes.fr/hal-00697627

Éditeur(s) : HAL CCSD Mineralogical Society of America
Résumé : International audience
Crystallization experiments were conducted at 200 MPa to determine the effect of small amounts of H2O on the liquidus temperature of basaltic melts in which plagioclase is the liquidus phase. The H2O concentrations in the quenched glasses, determined by infrared spectroscopy and Karl-Fischer titration, ranged from 0.02 to 4.2 wt% H2O. The dry liquidus temperature at 200 MPa was estimated from experiments at 1 atm (H2O-free) and from the known pressure dependence of plagioclase crystallization temperature. The effect of water (expressed as wt% H2O) on the plagioclase liquidus temperature is nonlinear and diminishing with increasing melt H2O concentrations. According to our new experimental data, it can be empirically predicted with following equation: Formula where CH2O is the water concentration in the melt (wt%), TDRY, and TWET are plagioclase crystallization temperatures in water-free and water-bearing systems, respectively. The relationship between CH2O and liquidus temperature worked out in this study is valid for a range of basaltic compositions, ranging from high-alumina basalts to basaltic andesites. The combination of the empirical equation predicting the liquidus depression of plagioclase with previous models predicting the olivine liquidus curve is useful to determine the liquidus temperature in various H2O-bearing basaltic systems in which either plagioclase or olivine is the liquidus phase.
ISSN: 0003-004X

hal-00757600
https://hal.archives-ouvertes.fr/hal-00757600
DOI : 10.2138/am.2012.4100

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
Introduction The Latitudinal Gradient Hypothesis (LGH) foresees that specialized metabolites are overexpressed under low latitudes, where organisms are subjected to higher herbivory pressure. The widespread macroalga Asparagopsis taxiformis is composed of six distinct genetic lineages, some of them being introduced in many regions. Objectives To study (i) metabolic fingerprints of the macroalga and (ii) its bioactivity in space and time, both as proxies of its investment in defensive traits, in order to assess links between bioactivities and metabotypes with macroalgal invasiveness. Methods 289 macroalgal individuals, from four tropical and three temperate regions, were analyzed using untargeted metabolomics and the standardized Microtox (R) assay. Results Metabotypes showed a low divergence between tropical and temperate populations, while bioactivities were higher in temperate populations. However, these phenotypes varied significantly in time, with a higher variability in tropical regions. Bioactivities were high and stable in temperate regions, whereas they were low and much variable in tropical regions. Although the introduced lineage two exhibited the highest bioactivities, this lineage could also present variable proliferation fates. Conclusion The metabolomic approach partly discriminates macroalgal populations from various geographic origins. The production of chemical defenses assessed by the bioactivity assay does not match the macroalgal genetic lineage and seems more driven by the environment. The higher content of chemical defenses in temperate versus tropical populations is not in accordance with the LGH and cannot be related to the invasiveness of the macroalgae.
ISSN: 1573-3882

hal-01681538
https://hal.archives-ouvertes.fr/hal-01681538
DOI : 10.1007/s11306-017-1169-z

Éditeur(s) : HAL CCSD
Résumé : Water vapour is highly variable in the atmosphere with concentration reaching saturation in the tropics and with dry areas over elevated continental region. Good knowledge of the amount of integrated water vapour in the air is necessary to predict phase changes and in particular precipitation. Water vapour variability measurements are still insufficient with standard observing systems. Moreover accurate GPS antenna positioning is affected by the refractivity index variation in the troposphere. Consequently, vertical positioning component estimation is difficult. This variation is directly linked to distribution of variables such as pressure, temperature and humidity along the path between satellite and receiver. Here we study more specifically heavy rains et notably Cevenols events. This thesis work consists to check the GPS measurement validity to quantify water vapour in comparison with measurements from radiosoundings and meteorological model outputs. GPS observations and flux surface information have been analysed to see if water vapour quantification by GPS allowed characterising heavy rain events (cumulative rainfall amount greater than 150 mm). Then, we tested the GPS data assimilation impact on cumulative precipitation forecasts using the high resolution Meteo France AROME model (2.5 km). Finally the quality and the contribution of GPS measurement on sea is evaluated for water vapour measurement. This study has been realised in the framework of VAPIMED experiment.
La vapeur d'eau varie largement dans l'atmosphère avec des concentrations allant de la saturation dans les tropiques à des zones presque sèches au-dessus des zones continentales élevées. Une bonne connaissance du contenu en vapeur d'eau dans l'air est nécessaire pour la prévision des changements de phases, notamment les précipitations. La mesure de la variabilité de la vapeur d'eau est une lacune des systèmes d'observation. Par ailleurs, il est apparu que le positionnement précis des antennes GPS était affecté par la variation de l'indice de réfraction dans la troposphère, ce qui rend particulièrement difficile l'estimation de la composante verticale. Cette variation est directement liée à la distribution des variables pression, température et humidité sur les trajets satellite-récepteur. On s'intéresse ici à l'étude des précipitations intenses et notamment aux épisodes Cévenols. Ce travail de thèse consiste à vérifier la validité de la mesure GPS pour la quantification de la vapeur d'eau en la comparant avec des mesures issues de radiosondage et des sorties de modèle météorologique. On cherche à analyser si la quantification de vapeur d'eau par GPS permet de caractériser les forts événements précipitants (cumuls supérieurs à 150 mm) à l'aide d'observations conjointes sur les flux de surface. On étudie ensuite l'impact de l'assimilation de données GPS issues d'un réseau GPS dense sur la prévision des cumuls de pluies dans le modèle à hauterésolution (2.5 km) AROME de Météo France. Finalement on évalue la qualité et l'apport de la mesure de vapeur d'eau par GPS en mer dans le cadre d'une campagne de mesure VAPIMED).
https://tel.archives-ouvertes.fr/tel-00444081

Droits : info:eu-repo/semantics/OpenAccess
tel-00444081
https://tel.archives-ouvertes.fr/tel-00444081
https://tel.archives-ouvertes.fr/tel-00444081/document
https://tel.archives-ouvertes.fr/tel-00444081/file/These_KBoniface.pdf

Éditeur(s) : Pêche thonière et dispositifs de concentration de poissons, Caribbean-Martinique, 15-19 Oct 1999
Résumé : In early 1980s, fad fisheries were introduced from the Philippines to Japan, mainly to Okinawa. The fisheries have well developed becoming one of the main fisheries in Okinawa where 210 fads are approved to deploy in 1999. The annual catch by roughly 1 000 boats (most of them are small) is 2500-4000 mt; average catch from one fad is about 20 mt; average catch by one boat on one day is 73 kilogrammes. fads are also important for easing the fishing pressures on bottom fish stocks. Most of the fads were deployed and managed by local fishermen's groups that have improved the structures of the system to withstand typhoons. The catches are strongly depending on the sites, usually the farther offshore, the better the catches. A variety of fishing methods are devised targeting each species and the size of the fish. Being most abundant and having relatively higher prices, yellowfin tuna is the most important and consists 68% of the total production. There have been conflicts among fishermen on the use of fads since the early stage of the fisheries development. Now, the number of fads is regulated by a management committee. Conflicts between fishermen and sport fishermen have become problems; on the other hand, the sport fishing could lead to further development of the fisheries. Degraded fish meat caused by high meat temperature and occasional oversupply have been major marketing problems since prices are strongly related to the meat quality and the fish supply.

Droits : Ifremer
http://archimer.ifremer.fr/doc/00042/15281/12667.pdf
http://archimer.ifremer.fr/doc/00042/15281/

Éditeur(s) : HAL CCSD American Chemical Society
Résumé : Experiments were conducted to assess the potential impact of fractured well-cement degradation on leakage rate. Permeability was monitored while CO2-enriched reservoir-equilibrated brine was flowed at constant rate through a single fracture in a class G cement core under conditions mimicking geologic sequestration environments (temperature 60 °C, pressure 10 MPa). The results demonstrate that, at least for the conditions used in the experiment, an initial leakage in a 42 μm aperture fracture (permeability = 1.5 × 10-10 m2) can be self-mitigated due to the decrease of the fracture hydraulic aperture after about 15 h. This decrease results from the development of continuous highly hydrated amorphous Si-rich alteration products at the edge of the fracture and the dense carbonation of the bulk cement that mitigate the penetration of the alteration front.
ISSN: 0013-936X

hal-00950088
https://hal.archives-ouvertes.fr/hal-00950088
DOI : 10.1021/es401317c

Éditeur(s) : HAL CCSD Elsevier
Résumé : Kyanite and zoisite eclogites from the Limousin area in the Variscan French Massif Central (FMC) have been formed by deep subduction to 100 km depth at peak pressure-temperature conditions around 660 degrees C and 2.9 GPa. They belong to a thin tectonic unit comprising ophiolitic bodies devoid of HP-UHP markers and forming a transported suture zone now separating the two main lithotectonic units of the FMC with contrasted tectono-metamorphic features (namely the lower and upper allochthons). Composition of kyanite-eclogites is similar to supra-subduction-zone basalts found in back-arc basins or island arcs (LREE depleted, negative Nb-Ta anomalies, epsilon Nd: +6 to + 9). Zoisite eclogites have the major-element fingerprint of ultrabasic iron-rich plagioclase cumulates common in continental intrusions or forming Fe-Ti oceanic gabbros. The distribution of immobile trace-elements is however more comparable to alkaline Si-undersaturated rocks, but the Sr-Nd isotopic composition (Sr-87/Sr-86: 0.706; epsilon Nd: -3 to -5) suggests the intervention of an old radiogenic crustal component during their petrogenesis. The chemical composition of hydrous zoisite eclogites does not correspond closely to a common magmatic precursor. It is thus suggested that, by analogy with well exposed worldwide HP-UHP terranes, at least a part of the trace-element signature and the isotopic compositions are controlled by channelled fluid-rock interaction at UHP conditions, leading to localised segregation of zoisite that hosts nearly all Sr and LREE budgets of the bulk eclogite. Sr-Nd isotopic composition of these samples is thus controlled by zoisite and probably represents the isotopic composition of the fluid phase present during UHP recrystallisation. Zircons extracted from a zoisite eclogite were dated in-situ by LA-ICP-MS. Crystallisation of the magmatic precursor is bracketed between 489 and 475 Ma and the UHP event is dated at 412 +/- 10 Ma, in agreement with published ages for the Eo-Variscan HP stage in the FMC. A late resetting of the U-Pb isotopic system at 382 +/- 7 Ma is related to an anatectic high pressure-medium pressure event, well known in the Limousin area. The oceanic eclogites dated in this study are tentatively linked to the Galicia-South Brittany Lower Paleozoic Ocean; they show evidence of the existence of an intra-oceanic subduction zone at the Lower Ordovician and of partial closure of this oceanic domain by ocean-continent subduction during Early Devonian.
ISSN: 0024-4937

hal-00512835
https://hal.archives-ouvertes.fr/hal-00512835
DOI : 10.1016/j.lithos.2010.05.013