Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
ETHNOPHARMACOLOGICAL RELEVANCE: Cutaneous leishmaniasis is a neglected disease with a high incidence in French Guiana, mainly in the middle and upper Oyapock basin, where Amerindian and some Brazilian people live. The main goals of this work were (i) to assess the knowledge about leishmaniasis in the different populations of the middle and upper Oyapock basin, (ii) to study the therapeutic strategies adopted by people affected by leishmaniasis and (iii) to document the use of phytotherapeutic remedies for leishmaniasis. Knowledge, attitudes and practices (K.A.P.) related to this disease and its treatments have been studied according to cultural group and geographical settlement. Within the Wayãpi group, the evolution of the knowledge of phytoremedies over the last 20 years has been characterised by literature-based comparisons. MATERIALS AND METHODS: A total of 144 questionnaires were administered in all the villages of the upper Oyapock and Camopi basins. Correspondence analyses were used for multivariate analysis. Plant species were identified at the Cayenne Herbarium (CAY). RESULTS: The biomedical concept of leishmaniasis correlates well with the Teko and Wayãpi concepts of kalasapa and kalasapau. Although the vector of this disease was not correctly identified, the most commonly cited aetiology (74.5%) was vector-borne, and related epidemiological schemes correlate well with the one encountered in French Guiana. Theoretically and practically, health centres were the most commonly used resource for diagnostic in instances of leishmaniasis infection (65.9%), independently of the patient's cultural group, along with the use of pharmaceutical drugs (85.3%). Pharmaceuticals were commonly utilised despite the frequent (51.5%) use of phytotherapeutic remedies, alone or in combination with drugs. The most cited medicinal plant species for the treatment of leishmaniasis included Eleutherine bulbosa (Mill.) Urb. (Iridaceae, cited 14 times), Euterpe oleracea Mart. (Arecaceae, 9), Cecropia obtusa Trecul (Cecropiaceae, 8), Jatropha curcas L. (Euphorbiaceae, 7), Ceiba pentandra (L.) Gaertn. (Bombacaceae, 6) and Carica papaya L. (Caricaceae, 6). Multiple correspondence analyses demonstrated that the species used in leishmaniasis remedies are more prone to vary by the user's place of residence than by their cultural origin, which indicates that exchange of knowledge about leishmaniasis remedies has occurred across different cultural groups. Literature-based comparisons between the remedies for leishmaniasis used by the Wayãpi during the 1980s showed a striking evolution, both in terms of diversity of species and number of plants used. The large number of species shared with other Guianese groups argues for intercultural exchange and may explain the majority (57.1%) of the newly used species highlighted in our study. CONCLUSIONS: Leishmaniasis is a well-known disease in the studied area. Phytotherapeutic treatments are still in use, although they are not the main source of remedies, and should undergo pharmacological studies to evaluate their potential therapeutic value.
ISSN: 0378-8741

pasteur-00634597
https://hal-riip.archives-ouvertes.fr/pasteur-00634597
DOI : 10.1016/j.jep.2011.07.044
PUBMED : 21816216

Éditeur(s) : HAL CCSD Wiley-Blackwell
Résumé : International audience
This paper aims to decipher the thermal evolution of the Montagne Noire Axial Zone (MNAZ,southern French Massif Central) gneiss core and its metasedimentary cover through determination ofP–T paths and temperature gradients. Migmatitic gneiss from the core of the dome record a clock-wise evolution culminating at 725 25 °C and 0.8 0.1 GPa with partial melting, followed by adecompression path with only minor cooling to 690 25° C and 0.4 0.1 GPa. Field structuralanalyses as well as detailed petrological observations interpreted in a petrogenetic grid indicate thatthe cover sequence experienced LP-HT metamorphism at <0.4 GPa. Apparent thermal gradientswithin the cover were determined with garnet–biotite thermometry and Raman Spectroscopy on Car-bonaceous Matter. High-temperature apparent gradients (e.g. 530 °C km1 along one transect) areexplained by late brittle–ductile extensional shearing evidenced by phyllonites that post-date peakmetamorphism. In areas where normal faults are less abundant and closely spaced, gradients of 20to 50 °C km1 are calculated. These gradients can be accounted for by a combination of domeemplacement and ductile shearing (collapse of isotherms), without additional heat input. Finally, thethermal evolution of the MNAZ is typical for many gneiss domes worldwide as well as with otherLP-HT terranes in the Variscides.
ISSN: 0263-4929

Droits : http://creativecommons.org/licenses/by-nc-nd/
insu-01290388
https://hal-insu.archives-ouvertes.fr/insu-01290388
https://hal-insu.archives-ouvertes.fr/insu-01290388/document
https://hal-insu.archives-ouvertes.fr/insu-01290388/file/jmg12188.pdf
DOI : 10.1111/jmg.12188

Éditeur(s) : HAL CCSD The Geochemical Society of Japan
Résumé : International audience
The Western Cordillera of Ecuador consists of Cretaceous crustal fragments of oceanic plateaux and superimposed insular arcs, which were accreted to the northwestern South American margin during the Late Cretaceous and Paleocene. Slices of high-grade metabasites, ultramafic rocks, gabbros and basalts, unmetamorphosed radiolarian cherts and scarce garnet-bearing metasediments were randomly exhumed along Miocene to Recent transcurrent faults crosscutting the Western Cordillera. The basalts show geochemical characteristics of oceanic plateau basalts (flat REE patterns, La/Nb = 0.85). The gabbros differ from the basalts in having lower REE levels, positive Eu anomalies, and negative Nb and Ta anomalies; they are interpreted as resulting from arc magmatism. The amphibolites and banded amphibolites have major and trace element chemistry similar to that of oceanic plateau basalts (flat REE patterns, La/Nb = 0.86) or to cumulate gabbros. The granulite shares with oceanic plateaus similar trace element chemistry (flat REE patterns, La/Nb < 1) and εNdi values (+7.6). Continent-derived metasediments are depleted in heavy REE (La/Y = 4.8) and have a negative Eu anomaly. Foliated lherzolites, melagabbronorites and pyroxenites consist of serpentinized olivine + cpx + opx ± Ca-plagioclase. Lherzolites, melagabbronorites and pyroxenites are LREE depleted with positive Eu anomalies, while the harzburgite displays a U-shaped REE pattern. The trace element abundances of the ultramafic rocks are very low (0.1 to 1 times the chondritic and primitive mantle values). The ultramafic rocks represent fragments of depleted mantle, deformed cpx-rich cumulate, and continental lithospheric mantle or mantle contaminated by subduction-fluid. Except the scarce quartz-rich metasediments, all these rocks likely represent remnants of accreted oceanic crustal fragments and associated depleted mantle. Since these samples were randomly sampled at depth by the fault, we propose that the Western Cordillera and its crustal root are mainly of oceanic nature.
ISSN: 0016-7002

insu-00679228
https://hal-insu.archives-ouvertes.fr/insu-00679228

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
BACKGROUND: The insecticide chlordecone was extensively used in the French West Indies to control banana root borer. Its persistence in soils has led to the widespread pollution of the environment, and human beings are still exposed to this chemical. Chlordecone has been shown to impair neurological and behavioural functions in rodents when exposed gestationally or neonatally. OBJECTIVES: The aim of the study was to evaluate the impact of prenatal and postnatal exposure to chlordecone on the cognitive, visual, and motor development of 7-month-old infants from Guadeloupe. METHODS: Infants were tested at 7 months (n=153). Visual recognition memory and processing speed were assessed with the Fagan Tests of Infant Intelligence (FTII), visual acuity with the Teller Acuity Card, and fine motor development with the Brunet-Lezine. Samples of cord blood and breast milk at 3 months (n=88) were analyzed for chlordecone concentrations. Postnatal exposure was determined through breast feeding and frequency of contaminated food consumption by the infants. RESULTS: Cord chlordecone concentrations in tertiles were associated with reduced novelty preference on the FTII in the highly exposed group (β=-0.19, p=0.02). Postnatal exposure through contaminated food consumption was marginally related to reduced novelty preference (β=-0.14, p=0.07), and longer processing speed (β=0.16, p=0.07). Detectable levels of chlordecone in cord blood were associated with higher risk of obtaining low scores on the fine motor development scale (OR=1.25, p<0.01). CONCLUSION: These results suggest that pre- and postnatal low chronic exposure to chlordecone is associated with negative effects on cognitive and motor development during infancy.
ISSN: 0013-9351

hal-00875939
https://hal.archives-ouvertes.fr/hal-00875939
DOI : 10.1016/j.envres.2012.07.006
PUBMED : 22910562

Éditeur(s) : HAL CCSD Geological Society of America
Résumé : International audience
We present the first recorded global positioning system (GPS) data from Myanmar measured at the northern tip of the Sagaing fault. This area is in a very complex geodynamic context, where rigid and semirigid plates interact. The 12 GPS sites measured in 2005 and 2008 in northern Myanmar show that the slip rate is 18 mm/yr and is localized along a single active narrow fault trace (<20 km wide). The same rate was previously demonstrated and remeasured, 500 km southward, in central Myanmar. Despite the geodynamic regional complexity induced by interaction between the Sunda and India plates, the Burma microplate, and the highly deformable eastern Himalayan syntaxis, the slip rate remains surprisingly constant along this fault. However, the modeled locking depth varies from 20 km in central Myanmar to 5 km in the north.
ISSN: 0091-7613

hal-00673712
https://hal.archives-ouvertes.fr/hal-00673712
DOI : 10.1130/G30872.1

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Two types of olivine occur in kimberlites from Greenland, Canada and southern Africa. The first, xenocrystic olivine, displays several different forms. Most distinctive are 'nodules', a term we use to describe the large (1-5 mm), rounded, single crystals or polycrystalline aggregates that are a common constituent of many kimberlites. Olivine compositions are uniform within single nodules but vary widely from nodule to nodule, from Fo81 to 93. Within many nodules, sub- to euhedral asymmetric tablets have grown within larger anhedral olivine grains. Dislocation structures, particularly in the anhedral grains, demonstrate that this olivine was deformed before being incorporated into the kimberlite magma. Olivine grains in the kimberlite matrix between the nodules have morphologies similar to those of the tablets, suggesting that most matrix olivine grains are parts of disaggregated nodules. We propose that a sub- to euhedral form is not sufficient to identify phenocrysts in kimberlites and provide some criteria, based on morphology, internal deformation and composition, that distinguish phenocrysts from xenocrysts. The second type of olivine is restricted to rims surrounding xenocrystic grains. Only this olivine crystallized from the kimberlite magma. Major and trace element data for the rim olivine are used to calculate the composition of the parental kimberlite liquid, which is found to contain between about 20 and 30% MgO. The bulk compositions of many kimberlites contain higher MgO contents as a result of the presence of xenocrystic olivine. The monomineralic, dunitic, character of the nodules, and the wide range from Fo-rich to Fo-poor olivine compositions, provide major constraints on the origin of the nodules. Dunite is a relatively rare rock in the mantle and where present its olivine is persistently Fo-rich. The dunitic source of the nodules in kimberlites lacked minerals such as pyroxene and an aluminous phase, which make up about half of most mantle-derived rocks. It appears that these minerals were removed from the mantle peridotite that was to become the source of the nodules, and the Fo content of the retained olivine was modified during interaction with CO2-rich fluids whose arrival at the base of the lithosphere immediately preceded the passage of the kimberlite magmas. Fragments of the resultant dunite were entrained into the kimberlite, where they were retained both as intact nodules and as disaggregated grains in the matrix.
ISSN: 0022-3530

insu-00543321
https://hal-insu.archives-ouvertes.fr/insu-00543321
BIBCODE : 10.1093/petrology/egp080
DOI : 10.1093/petrology/egp080

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Properties of composite materials depend on interatomic phenomena occurring between binder crystals. Experimental information of Atomic Force Microscopy (A.F.M.) is of prime importance; however understanding is helped by molecular modeling. As underlined in Section 1, the present study is able to simulate crystal interfaces in presence of a solution within apertures less than 1 Nanometer at a full atomic scale. Section 2 presents the case study of a gypsum solution between (120) gypsum faces, with related boundary conditions and atomic interactions. Section 3 deals with the mass equilibrium of the solution within interfaces <5 angstrom, using the original Semi Analytical Stochastic Perturbations (SASP) approach. This information becomes in Section 4 the key for explaining the peak of adhesion obtained in A.F.M. around an aperture of 3 A and gives enlightenments on gypsum cohesion. In conclusion, this illustration shows the potentialities of full atomic modeling which could not be attained by any numerical approach at a mesoscopic scale.
ISSN: 0008-8846

hal-00411868
https://hal.archives-ouvertes.fr/hal-00411868
DOI : 10.1016/j.cemconres.2007.09.022

Éditeur(s) : HAL CCSD
Résumé : This work focus on the characterization of the source and dynamic of compactional fluids during sedimentary burial, through two complementary examples of late orogenic oil‐field half‐grabens: The exhumed Lodève Permian Basin and a deep buried Jurassic basin in the North Viking Graben (North Sea).Constituting the main part of the thesis, a multi‐disciplinary approach was conducted in the Lodève Basin where Ba‐F‐Cu‐Pb polymetallic mineralized systems are trapped into synrift faults and paleokarsts in the carbonate basement at the hinge point of the rollover. The source, timing and P/T conditions of fluid migration were deduced from the analysis of the microfabric, the fluid inclusions microthermometry, and the isotopic (Sr, S, O, H) and Rare Earth Element (REE) signature. Results are then crossed with a structural and thermal modeling that consolidates the sequence and dynamics of fluid during burial.A similar approach was conducted in the North Viking Graben where fluid markers are restricted to 3D seismic and well core data. Comparable Ba‐Pb‐Zn veins are reported in basin margin, plugging one of the most important siliciclastic hydrocarbon reservoir in the substratum. This analysis provides additional constraints on basinal fluid behavior and allows us to propose a global dynamic model for various compositions of fluids and reservoirs.We conclude to a polyphase fluid sequence history including:(a) In the carbonate basement of the Lodève Basin, karstic paleocanyon incisions and associated cavities coupled to synrift fault, act as major drain for fluids. These structures are early affected by hypogen‐sulfuric karstification in response to the interaction between bacterial oxidation of sulfides entrapped within Lower Permian blackshales and the basement oxidizing aquifer.(b) Disequilibrium compaction initiates overpressure‐driven basinal fluid migration towards basin margins, characterized by temperatures around 150‐180°C and salinities between 9 et 18wt%eq.NaCl. Isotopic (Sr, S, O) and REE analyses reveal that Ba‐M+‐rich mineralizing fluids derived mainly from buried blackshales diagenesis. External fluids coming from the lower crust are also identified that play a key role in fluorite precipitation by the leaching of late hercynian granites (mean temperature of 250°C and salinity > 20wt%eq.NaCl).(c) During the synrift period, fluid overpressure is responsible for the periodic reactivation of fault plane according to seismic‐valve process, bedded‐control shearing and hydraulic brecciation at the basement‐seal interface. These mechanisms induce cyclic polymetallic mineralization by the mixing between in‐situ formation water and deep ascending basinal fluids.(d) Thermogenic fluids expulsion starts with last basinal fluids during late burial stage. Hydrocarbons thus migrate along the same regional pathways up to the rollover crest, where they are partly rerouted by the previous mineralized baffle.(e) In the Lodève basin, post‐rift exhumation of the margins led to the remobilization of synrift deposits by subaerial biochemical processes at the sulfate‐methane transition. The latter results from the interaction between the still active hydrocarbon dysmigration with a playa lake sulfate‐rich aquifer. Secondary low‐temperature barite fronts precipitate then within basement meteoric karsts.In addition to the « source to sink » model of basinal fluids, this work provides new insights on the early plugging of hydrocarbon reservoirs and for the metallogenesis of Mississippi Valley‐Type deposits.
Ce travail porte sur la caractérisation de la source et de la dynamique des fluides de bassin au cours de leur chargement à travers deux exemples complémentaires de demi‐grabens tardi‐orogéniques pétroliers : Le Bassin Permien de Lodève, aujourd’hui à l’affleurement et un bassin jurassique enfouis dans le North Viking Graben (Mer du Nord).Le coeur de la thèse concerne le Bassin de Lodève où, à partir d’une approche pluridisciplinaire intégrée, nous avons caractérisé l’architecture des minéralisations (Ba, F, Cu, Pb) piégées dans un réseau paléokarstique alimenté par les failles syn‐rift, dans le substratum carbonaté à l’apex du roll‐over. La source, le calendrier et les conditions de migration des fluides ont été approchés à partir de l’analyse de la micro‐fabrique, la microthermométrie sur inclusions fluides, les analyses isotopiques (Sr, S, O, H) et de Terres Rares. Les résultats analytiques ont été enfin croisés avec un modèle thermique et structural du bassin qui conforte la séquence et la dynamique du système fluide en cours d’enfouissement.Une démarche similaire, mais plus limitée, a été conduite dans le bassin du North Viking Graben où l’accès aux marqueurs fluides est restreint aux données de sismique 3D et de carottes. Comme à Lodève, les minéralisations Ba‐Pb‐Zn colmatent un réservoir dans le substratum à l’apex du roll‐over. Elles se présentent sous forme de ciments dans des grès ou des fractures. Cette analyse apporte des contraintes complémentaires et permet de proposer un modèle dynamique général avec des variantes en fonction de la nature des fluides et des réservoirs.On retiendra donc la séquence fluide suivante :(a) Dans le cas du bassin de Lodève sur substratum carbonaté, les chemins préférentiels de drainage se développent dans des paléocanyons N‐S couplés à un réseau de fractures et d’endokarsts météoriques. Ces derniers sont élargis en début de rifting par la dissolution hypogène sulfurique produite par l’oxydation bactérienne des sulfates et des pyrites des blackshales, au contact de l’aquifère oxydant du Cambrien.(b) Le déséquilibre de compaction initie la migration des fluides interstitiels en surpression vers les marges avec des températures autour de 150‐180°C et des salinités entre 9 et 18wt%eq.NaCl. Les analyses isotopiques (Sr, S, O) révèlent que la majorité des fluides provient de l’altération diagénétique des blackshales riches en métaux. Des interactions sont également mises en évidence avec des fluides profonds (entre 240°C et 260°C ; salinités > à 20wt%eq.NaCl), qui lessivent les granites tardi‐hercyniens.(c) Pendant le syn‐rift, les conditions de surpression de fluide permettent la réactivation cyclique des failles, les décollements stratigraphiques et la formation de brèches hydrauliques, favorisant la mise en connexion avec les réservoirs superficiels à l’apex du rollover. Le modèle de Sibson ajusté aux fluides de bassins est alors le moteur de la migration verticale.(d) Les fluides thermogéniques commencent à être expulsés avec les derniers fluides de compaction au cours d’un stade plus évolué de l’enfouissement en empruntant les mêmes chemins jusqu’à l’apex du roll over. Ils sont alors partiellement freinés et déviés par les colmatages minéralisés antérieurs.(e) A Lodève, la continentalisation des minéralisations antérieures au cours de l’exhumation post‐rift conduit à leur remaniement partiel au niveau de la transition sulfate‐méthane induite par l’interaction entre une playa évaporitique et la dysmigration des hydrocarbures. Des barytines secondaires de basse température, déprimées en Sr sont alors précipitées de manière synsédimentaire dans des karsts météoriques du socle.Outre l’illustration d’un modèle complet (source to sink) de dynamique des fluides dans un bassin, ce travail apporte de nouvelles contraintes dans l’approche du colmatage des réservoirs à hydrocarbures sur les têtes de blocs basculés et sur la genèse des gîtes miniers de type Mississippi Valley‐Type.
https://hal.archives-ouvertes.fr/tel-01457583

tel-01457583
https://hal.archives-ouvertes.fr/tel-01457583
https://hal.archives-ouvertes.fr/tel-01457583/document
https://hal.archives-ouvertes.fr/tel-01457583/file/th%C3%A8seLaurent2015V2.pdf

Éditeur(s) : HAL CCSD National Institute of Environmental Health Sciences
Résumé : International audience
Background: Glycol ethers (GE) are widely used organic solvents. Despite the potential neurotoxicity of several families of organic solvents, little is known about the impact of GE on the neurodevelopment of infants and children. Objectives: We investigated the relation between urinary concentrations of GE metabolites in pregnant women and neurocognitive abilities in their 6-year-old children in the PELAGIE mother-child cohort. Methods: Five GE metabolites were measured in first morning void urine samples of 204 French pregnant women in early pregnancy (<19 weeks of gestation). Psychologists assessed the neurocognitive abilities of their 6-year-old children with the Wechsler Intelligence Scale for Children IV (WISC) and the Developmental Neuropsychological Assessment (NEPSY). We analyzed the results with linear (WISC) and Poisson regression models (NEPSY), adjusted for potential confounders, including child's stimulation at home. Results: GE metabolites were detected in 90-100% of maternal urine samples. The WISC Verbal Comprehension score was significantly lower for children with the highest tertile of urinary phenoxyacetic acid (PhAA) [beta (third vs. first tertile)=-6.53; 95% CI: -11.44, -1.62]. Similarly, the NEPSY Design Copying subtest score was lower in those with the highest tertile of urinary ethoxyacetic acid (EAA) [beta (third vs. first tertile)=-0.11; 95% CI: -0.21, 0.00]. The other GE metabolites we studied were not significantly associated with WISC or NEPSY scores. Conclusions: Prenatal urine concentrations of two GE metabolites were associated with lower WISC Verbal Comprehension Index scores and NEPSY Design Copying subscale scores, respectively, at age 6 years. PhAA is the primary metabolite of 2-phenoxyethanol (EGPhE), which is commonly found in cosmetics, and precursors of EAA are frequently used in cleaning agents. Additional research is needed to confirm our findings and further explore potential effects of prenatal GE exposures on neurocognitive performance in children.
ISSN: 0091-6765

hal-01519256
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01519256
DOI : 10.1289/EHP39
PUBMED : 27740510

Éditeur(s) : HAL CCSD Geological Society of America
Résumé : International audience
Mechanisms that control seismic activity in low strain rate areas such as western Europe remain poorly understood. For example, in spite of low shortening rates of <0.5 mm/ yr, the Western Alps and the Pyrenees are underlain by moderate but frequent seismicity detectable by instruments. Beneath the elevated part of these mountain ranges, analysis of earthquake focal mechanisms indicates extension, which is commonly interpreted as the result of gravitational collapse. Here we show that erosional processes are the predominant control on present-day deformation and seismicity. We demonstrate, using fi nite element modeling, that erosion induces extension and rock uplift of the elevated region of mountain ranges accommodating relatively low overall convergence. Our results suggest that an erosion rate of ~1 mm/yr can lead to extension in mountain ranges accommodating signifi cant shortening of <3 mm/yr. Based on this study, the seismotectonic framework and seismic hazard assessment for low strain rate areas need to be revisited, because erosion-related earthquakes could increase seismic hazard.
ISSN: 0091-7613

insu-00817341
https://hal-insu.archives-ouvertes.fr/insu-00817341
DOI : 10.1130/G33942.1

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Wind energy production is very sensitive to instantaneous wind speed fluctuations. Thus rapid variation of wind speed due to changes in the local meteorological conditions can lead to electrical power variations of the order of the nominal power output. The high variability of this renewable energy source can caused a disruptive effect on power quality and reliability, in non-interconnected island networks as in Guadeloupe (French West Indies). To palliate these difficulties, it is essential to identify and characterize the wind speed distribution over very short time intervals. This allows anticipating the eventuality of power shortage or power surge. Therefore, it is of interest to categorize wind speed fluctuations into distinct classes and to estimate the probability of a distribution to belong to a class. This paper presents a method for classifying wind speed distributions by estimating a finite mixture of Dirichlet distributions. The SAEM algorithm that we use provides a fine distinction between three wind speed distribution classes. It is a new nonparametric method for wind speed classification.
ISSN: 0960-1481

hal-01527881
https://hal.archives-ouvertes.fr/hal-01527881
DOI : 10.1016/j.renene.2011.03.024

Éditeur(s) : HAL CCSD Elsevier
Résumé : The ultramafic–mafic complexes located at the base of obducted paleo-island arcs are commonly interpreted as evidence for intra-crustal fractionation of primitive (high-Mg#) mantle melts. The present study, realized on the Jijal mafic–ultramafic basal section of the Cretaceous Kohistan oceanic arc (N Pakistan), discards a crystal fractionation model from a single parental magma to take into account the geochemical and isotope variations observed between the plutonic crust and the underlying ultramafic section. The basal ultramafic rocks, i.e. dunites, wehrlites and clinopyroxenites, show high Mg#, extremely depleted REE patterns, no marked HFSE anomalies and high LILE enrichment. Cpx and leached whole rocks from this unit yield restricted εNd values (+ 5.5 to + 6.8), a large εSr range (− 5.9 to + 8.8) and mainly radiogenic 207Pb/204Pb ratios. The overlying mafic section, i.e. gabbroic rocks, displays low Mg# (46 < Mg# < 54), enriched REE patterns and marked HFSE anomalies. These plutonic rocks have also very homogeneous Sr and Pb isotopic compositions defining a restricted domain, which does not overlap that of the ultramafic samples. Moreover, Cpx from the basal ultramafics yield an Sm–Nd isochron at 117 ± 7 Ma interpreted as dating crystallization of the ultramafic section. Together, these results indicate that the mafic rocks on one hand and the ultramafic rocks on the other hand, originate from separate sources with specific emplacement underneath the subduction zone. A lherzolite lens, collected from the top of the mafic section, plots on the early Cretaceous Sm–Nd isochron and therefore yields the same 143Nd/144Nd initial ratio. This suggests that the ultramafic part of the lower Kohistan arc complex sampled the initiation stages of the subduction with production of magmas with boninite-like features. At this stage, the mantle wedge has been already modified by percolation of the first slab-derived fluids. On such a scenario the lherzolite lens would correspond to the lithospheric mantle underneath the arc before its initiation. A multi-stage history is proposed for the evolution for the Kohistan arc through not, vert, similar 30 Ma. Stage #1 reflects the spontaneous initiation of subduction associated with extensive boninitic affinity magmatism, stages #2 and #3 are related to arc building by tholeiitic melts and, a fourth step (stage #4) corresponds to the intra-crustal differentiation.
ISSN: 0012-821X

hal-00407206
https://hal.archives-ouvertes.fr/hal-00407206
DOI : 10.1016/j.epsl.2007.06.026

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
We show here that the Amalaoulaou complex, in the Pan-African belt of West Africa (Gourma, Mali), corresponds to the lower and middle sections of a Neoproterozoic intra-oceanic arc. This complex records a 90-130-Ma-long evolution of magmatic inputs and differentiation above a subducting oceanic slab. Early c. 793 Ma-old metagabbros crystallised at lower crustal or uppermost mantle depths (25-30 km) and have geochemical characteristic of high-alumina basalts extracted from a depleted mantle source slightly enriched by slab-derived sedimentary components ((La/Sm)(N) < 1; epsilon(Nd): +5.4-6.2; Sr-87/Sr-86: 0.7027-0.7029). In response to crustal thickening, these mafic rocks were recrystallised into garnet-granulites (850-1,000A degrees C; 10-12 kbar) and subject to local dehydration-melting reactions, forming trondhjemititic leucosomes with garnet-clinopyroxene-rutile residues. Slightly after the granulitic event, the arc root was subject to strong HT shearing during partial exhumation (detachment faults/rifting or thrusting), coeval with the emplacement of spinel- and garnet-pyroxenite dykes crystallised from a high-Mg andesitic parental magma. Quartz and hornblende-gabbros (700-660 Ma) with composition typical of hydrous volcanic rocks from mature arcs ((La/Sm)(N): 0.9-1.8; epsilon(Nd): +4.6 to +5.2; Sr-87/Sr-86: 0.7028-0.7031) were subsequently emplaced at mid-arc crust levels (similar to 15 km). Trace element and isotopic data indicate that magmas tapped a depleted mantle source significantly more enriched in oceanic sedimentary components (0.2%). Exhumation occurred either in two stages (700-660 and 623 Ma) or in one stage (623 Ma) with a final exhumation of the arc root along cold P-T path (550A degrees C, 6-9 kbar; epidote-amphibolite and greenschist facies conditions) during the main Pan-African collision event (620-580 Ma). The composition of magmas forming the Cryogenian Amalaoulaou arc and the processes leading to intra-arc differentiation are strikingly comparable to those observed in the deep section of exposed Mezosoic oceanic arcs, namely the Kohistan and Talkeetna complex. This evolution of the Amalaoulaou oceanic arc and its accretion towards the West African craton belong to the life and closure of the Pharusian Ocean that eventually led to the formation of the Greater Gondwana supercontinent, a similar story having occurred on the other side of the Sahara with the Mozambique Ocean.
ISSN: 0010-7999

hal-00639447
https://hal.archives-ouvertes.fr/hal-00639447
DOI : 10.1007/s00410-011-0624-5

Éditeur(s) : HAL CCSD
Résumé : International audience
Background: The aim of this study was to identify the predictive factors of HIV disclosure to the sex partner in HIV pregnant women in Cayenne (French Guiana). Methods: A case control study was conducted including all deliveries in Cayenne from 2003 to 2010. For each case, a standardized questionnaire including epidemiological, clinical, and biological data was administered. Thirty-four women in the first group and 95 in the control group were included in the study. Results: The logistic regression showed that the variables that independently predicted HIV disclosure to the sex partner were the existence of a profession (OR=5.62, IC95% =1.3-24.26, p=0.021), disclosure to the doctor (OR=12.65, IC95% =2.87-55.8, p<0.001), the negative representations of HIV (OR=5.99, IC95% =1.17-30.69, p=0.032). The partner's HIV status was also linked to the outcome (OR=0.01, IC95% =0.001-0.07, p<0.001). Conclusion: These predictive factors should be considered in positive prevention programs and prevention of mother to child transmission.
Epidemiol

inserm-00915113
http://www.hal.inserm.fr/inserm-00915113
http://www.hal.inserm.fr/inserm-00915113/document
http://www.hal.inserm.fr/inserm-00915113/file/2012_Elenga_-_Predictive_Factorssur HIV_Status_Disclosure_to_Sex_Partner_in_Pregnant_women_in_cayenne_french_guiana.pdf
DOI : 10.4172/2161-1165.1000116

Éditeur(s) : HAL CCSD Geological Society of America
Résumé : International audience
Because of its essential role in coupling climate and tectonics, denudation is a key parameter when constraining the history of Earth’s surface. This is particularly true at the Pliocene-Pleistocene transition, and the potential impact of the onset of Quaternary glaciations remains strongly debated. In the present study, we measured in situ cosmogenic 10Be within continuous late Cenozoic sedimentary sections that had already been dated using magnetostratigraphy. The new data were obtained from four sedimentary basins in the northern and southern Tianshan range (Central Asia). We first thoroughly discuss how in situ cosmogenic 10Be concentrations can be corrected for radioactive decay and for the contribution of postdepositional cosmogenic accumulation to derive the paleo–denudation rates. Our analysis shows that, in the four sedimentary records, the potential bias remains low enough to consider the derived denudation rates reliable. The four records, although likely influenced by local particularities due to lithological heterogeneity and local tectonics, display similar trends of continuously increasing denudation between ca. 9 Ma and the present. These rates have remained relatively high but steady since 4 Ma, ∼1.5 m.y. before the onset of the Quaternary glacial cycles. Though the rejuvenation of the Tianshan range since 11 Ma may explain most of the progressive increase (×5) in denudation, our data suggest that the Quaternary glaciations had only a limited impact on denudation in the Tianshan. Our data, however, indicate an increase in the spatial and high-frequency variability (<1 m.y.) of the denudation rates between 3 and 1 Ma. This may correspond to a transient readjustment of the landscape in response to the onset of Quaternary glacial cycles.
ISSN: 0016-7606

hal-01685766
https://hal.archives-ouvertes.fr/hal-01685766
DOI : 10.1130/B31475.1

Éditeur(s) : HAL CCSD Elsevier
Résumé : LA-ICP-MS and SIMS U–Pb analyses have been performed on detrital zircon grains from four heavy mineral rich metasediments collected at different levels of the Nathorst Land Group (Eleonore Bay Supergroup, Greenland). Zircons from high-grade samples collected in the sillimanite and migmatite zones exhibit modifications to their structure, which are lacking in grains from a low-grade sample (0.3 GPa and 350–400 °C). In the sillimanite zone (0.5 GPa, 650 °C), thin discontinuous rims (<20 μm) plating detrital zircon grains document a metamorphic overgrowth during the Caledonian event dated at 428 ± 25 Ma (2σ). In the migmatite zone (0.4 GPa, 700 °C), zircons underwent severe recrystallisation processes but no new zircon growth. Ilmenite, which constitutes over 50% of the heavy mineral layers, underwent recrystallisation in both high-grade samples and is likely to represent the main source of Zr available for growth of zircon rims in the sillimanite zone. However, in the migmatite zone sample, the metamorphic conditions allowed titanite overgrowth around ilmenite, which acted as a sink for Zr and inhibited new zircon growth. 207Pb/206Pb ages for 152 detrital zircons broadly range between 2800 and 990 Ma. The detrital zircon age signature is characterized by the large predominance of late Paleoproterozoic (1.85–1.60 Ga) grains in all analysed samples and by lesser amounts of Archean (2.7–2.8 Ga) and Mesoproterozoic (1.2–1.0 Ga) zircons. The overall age range indicates that detritus can be sourced from the Labradorian and Makkovikian provinces of northeastern Laurentia. The youngest grain analysed (987 ± 18 Ma) indicates that deposition took place during the Neoproterozoic, in a post-Grenvillian sedimentary environment and was likely coeval with the Mid-Neoproterozoic episode of aborted rifting that affected the eastern margin of Laurentia. The lack of detritus originating from Amazonia or Baltica, placed adjacent to Laurentia during the early stages of Rodinia fragmentation, suggests that these two continental landmasses did not constitute a topographic high during the Neoproterozoic or that the Mid-Neoproterozoic rifting opened toward an open ocean to the north of a combined Laurentia/Baltica, thus resulting in a general south to north direction of transport of the sediments.
ISSN: 0301-9268

hal-00407204
https://hal.archives-ouvertes.fr/hal-00407204
DOI : 10.1016/j.precamres.2007.01.002

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The identification of a large OIB-type volcanic sequence on top of an obducted nappe in the Lesser Caucaus of Armenia helps us explain the obduction processes in the Caucasus region that are related to dramatic change in the global tectonics of the Tethyan region in the late Lower Cretaceous. The ophiolitic nappe preserves three distinct magmatic series, obducted in a single tectonic slice over the South Armenian Block during the Coniacian-Santonian (88-83 Ma), the same time as the Oman ophiolite. Similar geological, petrological, geochemical and age features for various Armenian ophiolitic massifs (Sevan, Stepanavan, and Vedi) argue for the presence of a single large obducted ophiolite unit. The ophiolite, shows evidence for a slow-spreading oceanic environment in Lower to Middle Jurassic. Serpentinites, gabbros and plagiogranites were exhumed by normal faults, and covered by radiolarites. Few pillow-lava flows have infilled the rift grabens. The ophiolite lavas have hybrid geochemical composition intermediate between Arc and MORB signatures: (La/Yb)(N) = 0.6-0.9: (Nb/Th)(N) = 0.17-0.57; (Nd-143/Nd-144)(i) = 0.51273-0.51291; (Sr-87/Sr-86)(i) = 0.70370-0.70565; (Pb-207/Pb-204)(i) = 15.4587-15.5411; (Pb-208/Pb-204)(i) = 37.4053-38.2336; (Pb-206/Pb-204)(i) = 17.9195-18.4594. These compositions suggest they were probably formed in a back-arc basin by melting of a shallow asthenosphere source contaminated by a deeper mantle source modified by subducted slab-derived products. Sr-87/Sr-86 ratios and petrological evidence show that these lavas have been intensely altered by mid-oceanic hydrothermalism as well as by serpentinites, which are interpreted as exhumed mantle peridotites. The gabbros have almost the same geochemical composition as related pillow-lavas: (La/Yb)(N) = 0.2-2.3; (Nb/Th)(N) = 0.1-2.8; (Nd-143/Nd-144)(i) = 0.51264-0.51276: (Sr-87/Sr-86)(i) = 0.70386-0.70557; (Pb-207/Pb-204)(i) = 15.4888-15.5391; (Pb-208/Pb-204)(i) = 37.2729-37.8713; (Pb-206/Pb-204)(i) = 17.6296-17.9683. Plagiogranites show major and trace element features similar to other Neo-Tethyan plagiogranites (La/Yb)(N) = 1.10-7.92; (Nb/Th)(N) = 0.10-0.94; but display a less radiogenic Nd isotopic composition than basalts [(Nd-143/Nd-144)(i) = 0.51263] and more radiogenic (Sr-87/Sr-86)(i) ratios. This oceanic crust sequence is covered by variable thicknesses of unaltered pillowed OIB alkaline lavas emplaced in marine conditions. Ar-40/Ar-39 dating of a single-grain amphibole phenocryst provides a Lower Cretaceous age of 117.3 +/- 0.9 Ma, which confirms a distinct formation age of the OIB lavas. The geochemical composition of these alkaline lavas is similar to plateau-lavas [(La/Yb)(N) = 6-14; (Nb/Th)(N) = 0.23-0.76; (Nd-143/Nd-144)(i) = 0.51262-0.51271; (Sr-87/Sr-86)(i) = 0.70338-0.70551; (Pb-207/Pb-204)(i) = 15.5439-15.6158; (Pb-208/Pb-204)(i) = 38.3724-39.3623; (Pb-206/Pb-204)(i) = 18.4024-19.6744].;They have significantly more radiogenic lead isotopic compositions than phiolitic rocks, and fit the geochemical compositions of hot-spot derived lavas mixed with various proportions of oceanic mantle. In addition, this oceanic + plateau sequence is covered by Upper Cretaceous calc-alkaline lavas: (La/Yb)(N) = 2.07-2.31; (Nb/Th)(N) = 0.08-0.15; (Nd-144/Nd-143)(i) = 0.51271-0.51282; (Sr-117/Sr-116)(i) = 0.70452-0.70478), which were likely formed in a supra-subduction zone environment. During the late Lower to early Upper Cretaceous period, hot-spot related magmatism related to plateau events may have led to significant crustal thickening in various zones of the Middle-eastern Neotethys. These processes have likely hindered subduction of some of the hot and thickened oceanic crust segments, and allowed them to be obducted over small continental blocks such as the South Armenian Block.
ISSN: 0024-4937

hal-00443855
https://hal.archives-ouvertes.fr/hal-00443855
DOI : 10.1016/j.lithos.2009.02.006

Éditeur(s) : HAL CCSD Geological Society of London
Résumé : Permo-Triassic rift basins offer important hydrocarbon targets along the Atlantic margins. Their fill is dominated by continental red beds, comprising braided fluvial, alluvial fan, aeolian, floodplain and lacustrine facies. These relatively lightly explored basins span both the Atlantic and Tethyan domains and developed above a complex basement with inherited structural fabrics. Sparse data in offshore regions constrain understanding of depositional geometries and sedimentary architecture, further impeded by their deep burial beneath younger strata, combined with the effects of later deformation during continental breakup. This paper provides results from a multidisciplinary analysis of basins along the Atlantic margin. Regional seismic and well data, combined with geochemical provenance analysis from the European North Atlantic margins, are integrated with detailed outcrop studies in Morocco and Nova Scotia. The research provides new insights into regional basin tectonostratigraphic evolution, sediment fill, and reservoir distribution, architecture and quality at a range of scales. Regional seismic profiles, supported by key well data, indicate the presence of post-orogenic collapse basins, focused narrow rifts and low-magnitude multiple extensional depocentres. Significantly, Permo-Triassic basin geometries are different and more varied than the overlying Jurassic and younger basins. Provenance analysis using Pb isotopic composition of detrital K-feldspar yields new and robust controls on the sediment dispersal patterns of Triassic sandstones in the NE Atlantic margin. The evolving sedimentary architecture is characterized by detailed sedimentological studies of key outcrops of age equivalent Permian-Triassic rifts in Morocco and Nova Scotia. The interplay of tectonics and climate is observed to influence sedimentation, which has significant implications for reservoir distribution in analogue basins. New digital outcrop techniques are providing improved reservoir models, and identification of key marker horizons and sequence boundaries offers a potential subsurface correlation tool. Future work will address source and seal distribution within the potentially petroliferous basins.
Petroleum Geology: From Mature Basins to New Frontiers Proceedings of the 7th Petroleum Geology Conf

hal-00590618
https://hal.archives-ouvertes.fr/hal-00590618

Éditeur(s) : HAL CCSD American Geophysical Union (AGU)
Résumé : International audience
Observations from deep boreholes at several locations worldwide, laboratory measurements of frictional strength on quartzo-feldspathic materials, and earthquake focal mechanisms indicate that crustal faults are strong (apparent friction μ ≥ 0.6). However, friction experiments on phyllosilicate-rich rocks and some geophysical data have demonstrated that some major faults are considerably weaker. This weakness is commonly considered to be characteristic of mature faults in which rocks are altered by prolonged deformation and fluid-rock interaction (i.e., San Andreas, Zuccale, and Nankai Faults). In contrast, in this study we document fault weakening occurring along a marly shear zone in its infancy (<30 m displacement). Geochemical mass balance calculation and microstructural data show that a massive calcite departure (up to 50 vol %) from the fault rocks facilitated the concentration and reorganization of weak phyllosilicate minerals along the shear surfaces. Friction experiments carried out on intact foliated samples of host marls and fault rocks demonstrated that this structural reorganization lead to a significant fault weakening and that the incipient structure has strength and slip behavior comparable to that of the major weak faults previously documented. These results indicate that some faults, especially those nucleating in lithologies rich of both clays and high-solubility minerals (such as calcite), might experience rapid mineralogical and structural alteration and become weak even in the early stages of their activity.
ISSN: 0278-7407

hal-01211481
https://hal.archives-ouvertes.fr/hal-01211481
DOI : 10.1002/2014TC003716

Éditeur(s) : HAL CCSD BioMed Central
Résumé : International audience
Background: End-Stage renal disease (ESRD) causes considerable morbidity and mortality, and significantly alterspatients’ quality of life. There are very few published data on this problem in the French Overseas territories. Thedevelopment of a registry on end stage renal disease in French Guiana in 2011 allowed to describe the magnitudeof this problem in the region for the first time.Methods: Using data from the French Renal Epidemiology and Information Network registry (R.E.I.N). Descriptivestatistics on quantitative and qualitative variables in the registry were performed on prevalent cases and incidentcases in 2011, 2012 and 2013.Results: French Guiana has one of the highest ESRD prevalence and incidence in France. The two main causes ofESRD were hypertensive and diabetic nephropathies. The French Guianese population had a different demographicprofile (younger, more women, more migrants) than in mainland France. Most patients had at least one comorbidity,predominantly (95.3%) hypertension. In French Guiana dialysis was initiated in emergency for 71.3% of patients versus33% in France (p < 0.001).Conclusion: These first results give important public health information: i) End stage renal disease has a very highprevalence relative to mainland France ii) Patients have a different demographic profile and enter care late in thecourse of their renal disease. These data are closer to what is observed in the Caribbean or in Latin America than inMainland France.
ISSN: 1471-2369

inserm-01567222
http://www.hal.inserm.fr/inserm-01567222
http://www.hal.inserm.fr/inserm-01567222/document
http://www.hal.inserm.fr/inserm-01567222/file/2017%2C%20Rochemont%20-%20End%20stage%20renal%20disease.pdf
DOI : 10.1186/s12882-017-0614-6